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By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By Derek J. Fray

The need for on-line sensors is outlined and it is demonstrated that the control of many processes is prevented by the availability of these devices. The use of solid electrolytes is described for the sensing of elements in molten pyrometallurgical phases. In the cases where there is no suitable electrolyte, the addition of a second phase of a compound containing both the element to be measured and the element whose ion is mobile in the electrolyte can be used. For the measurement of high concentrations of an element a method based on current measurement is proposed.

Jan 1, 1994

By J. M. B. Scarborough

This paper deals with measures taken to maintain effective operation of heavy-duty equipment in open-pit mining. at Pine Point, N.W.T., during periods of extreme cold weather. The points covered include equipment modifications designed to improve cold-weather performance, effective lubrication of machinery that is vulnerable to extreme cold and operating procedures designed to prevent equipment damage.

Jan 1, 1966

By Fiseha Tesfaye, Pekka Taskinen

"Thermodynamics of the equilibrium phase assemblage Ago_9Cul.lS-Cu2-xS-CuS have been studied by an EMF -method. The ternary phase was synthesized from the pure Cu2S and Ag2S in vacuum furnace at high-temperature and mixed with appropriate compositions of Cu2S and CuS to form the cathode electrode. The EMF-measurements were made on the solid-state galvanic cell Pt(-) I Ag I RbAg,ils I Ago9Cu1.1S-Cu2-xS-CuS I Pt(+), in a temperature range from 316 K to 498K.Based on the measured EMF vs. T relations, thermodynamic functions (?fG° , ?fS and ?fH°) of stromeyerite (Ag0.9Cu1.1S) in equilibrium with Cu2-xS and CuS have been determined. The obtained experimental values have been compared with the available literature values. New experimentally determined thermodynamic properties of the solid solution (Ag,Cu)2Sss were determined.IntroductionDue to intense mining of high grade sulfide ore minerals in the past, recently, the available sulfide ores are poor in metals and becoming increasingly complex; such that, the production of high grade metals by the conventional pyrometallurgical processes is compromised. Consequently, smelters are in need to modify their operating flow sheets and strategies for processing more complex feed materials economically, while meeting the strict environmental regulations. To make the appropriate modifications, accurate thermochemical data of phases and phase assemblages which exist in these complex ore minerals are essential.Silver-bearing sulfosalts are encountered in ore minerals for the production of base metals and are common sources of silver. Among the silver-based sulfosalts, stromeyerite (Ag0_9Cu1.1S) is relatively common ore mineral in most hydrothermal vein and replacement deposits [1]. Recently, the ternary chalcogenide compound Ago0.93Cu1,07S has been studied, intensively, due to its high ionic conductivity and gradual disorder in the sequential phase transitions [2]. Therefore, accurate knowledge of the thermodynamic properties of stromeyerite has considerable fundamental and practical interest in many aspects of extractive, chemical and physical metallurgy."

Jan 1, 2014

By Charles Jones

(San Francisco Meeting, September, 1915) IN any discussion of this very large subject we are confronted at the outset with so many obstacles that at best only a fragmentary and rather disconnected presentation can be made of it, and my hope is that building from the few facts I have to offer a more complete knowledge may be secured. In the whole intermountain and Pacific. Coast region, west of Pueblo, Col., and from Canada to Mexico, there is no production of pig iron, and steel production is confined to the manufacture of a small amount of open-hearth steel from scrap. When we consider the area, the resources, and the several centers of population, this condition seems anomalous, even in. the face of every counter argument as to cheap water transportation, or other means of transport from the Atlantic Seaboard or from the iron and steel centers of the Middle West. This comatose condition, if such a term may be applied, is certainly riot due to a lack of all the essential materials and factors for success in iron and steel smelting, but is rather, I think, due largely to the general fact that it is only within a comparatively few years that the centers of population on the Pacific Coast have attained a size that would entitle them to the position of distributing or freight centers, or that the "back country" has been enough built up to make it sufficiently interesting to the railroads to foster trade from the local centers to the interior points rather than seek to supply such local centers and the interior by a transcontinental haul.

Jan 9, 1915

By B. A. Eaton, K. E. Brown, C. R. Knowles, D. E. Andrews, I. H. Silberberg

This paper presents the resitlts of an investigation of two-phase, gm-liquid flow in horizontal pipelines. Experimental data were taken in three field-size, horizontal pipelines, two of which were constructed for this purpose. The data were obtained using water, distillate and crude oil separately as the liquid phase, and natural gas as the second phase. Experimental pressure-length traverse, liquid holdup and flow-pattern data were collected for each set of flow rates. These data were used to develop three correlations that are presented herein. The liquid-holdup values correlated with various flow parameters without regard to the existing flow pattern. The same was true for the energy-loss factors. A new flow-pattern map is presented that appears to be quite reliable, but not required for the pressure-loss calculations. The liquid-holdup correlation and the energy-loss factor correlation are used in conjunction with a two-phase flow power balance, developed during this study, to predict the pressure losses that occur during gas-liquid flow in horizontal pipelines. A recommended calculational procedure is given, as well as a statistical analysis of the results. This procedure lends itself to computer application, since several small pressure decrements are needed to calculate a pressure-length traverse. The correlations are shown graphically, but may be curve fitted with existing curve-fitring computer programs. INTRODUCTION Due to the frequent occurrence of gas-liquid flow in pipelines and the desire to accurately calculate the pressure losses that occur in these lines, two-phase flow is of considerable interest to the petroleum, chemical and nuclear industries. In the petroleum industry, gas-liquid mixtures have been transported over relatively long distances in a common line due to the advent of centralized gathering and separation systems. Long two-phase flowlines are usually accompanied by large pressure drops which influence the design of the system. Gas-lift installations are designed on the basis of known tubing pressures at the wellheads. The horizontal flowline connecting the wellhead and the separator system must be correctly sized in order to minimize the horizontal flowline pressure losses and the wellhead tubing pressure. Practically all oilwell production design involves horizontal two-phase flow in pipeknes. All of the flow processes of oil and gas production must be studied simultaneously to insure good well design. Since the beginning of offshore oilfield development, long horizontal flowlines have been constructed. Because pressure losses greatly influence the performance of producing wells, a method is desired that can be used to predict such pressure losses and select optimum flowline size. Several types of gas-liquid flow exist, and many of these are discussed by Gouse The study of pressure gradients, fluid distributions and flow patterns that occur in horizontaI multiphase flow is made difficult by the great number of variables involved. The various flow regimes give rise to changing velocities of the fluid particles in all directions. These instabilities of the interface between the gas and liquid prohibit the determination of actual vector velocities of fluid particles in each phase. Also, it is practically impossible to arrive at correct sets of boundary conditions. Therefore, most investigators have concluded that a solution to the problem by the classical fluid dynamics approach, whereby the Navier-Stokes equationsM are formulated and solved, is far too complex. Other methods must be utilized to develop general correlations that will predict the behavior of gas-liquid horizontal flow systems. Multiphase flow studies have sought to develop a technique with which the pressure drop can be calculated. Pressure losses in two-phase, gas-liquid flow are quite different from those encountered in single-phase flow; in most cases an interface exists and the gas slips past the liquid. The interface may be smooth or have varying degrees of roughness, depending on the flow pattern. Therefore, a transfer of energy from the gaseous phase to the liquid phase may take place while energy is lost from the system through the wetting phase at the pipe wall. Such an energy transfer may be either in the form of heat exchange or of acceleration. Since each phase must flow through a smaller area than if it flowed alone, amazingly high pressure losses occur when compared to single-phase flow. Most investigators of horizontal two-phase flow phenomena have chosen to separate their experimental data into several groups of observed flow patterns or regimes.

By Darcey Baker

Quarry Blasting is usually boring, and that is how we like it. By this, boring means routine, straightforward, meat and potatoes blasting. Quarries typically will not utilize cast blasting, coyote tunnels, or any of the other more spectacular blasting techniques – just plain, old day-in and day-out quarry production and possibly overburden blasting. Differences in material characteristics, mining method, equipment availability, and target markets all play a part in determining the blasting procedures employed at any given location. However, variables exist everywhere and with foresight and planning, effects of tangible variables can be minimized. Variables caused by geology, weather, neighbors, or limitations caused by major plant or mobile equipment are, generally speaking, intangible; and leave the operator with finite options to improve or modify blasting procedures.

Jan 1, 2009

By A Dunne, R Kruger, H Coleman, P G. Laurens

External and internal challenges in mining are increasing the difficulty and complexity of operating mines. The external mining environment has a big impact on mining operations and is driving the focus on safety, sustainable mining, green issues, profitability and productivity. There is a very high emphasis on ‘reducing cost to improve’, lower mining and beneficiation costs by eliminating waste/inefficiencies (reduce people, use less consumables, multiskilling, etc). The internal mining environment is getting tougher to operate in, with the deposits being more difficult to mine, more difficult to manage due to external pressure along with issues associated with maintaining quality, etc.Technological and environmental developments too numerous to mention, mean that cost control models, reduction in human resource numbers, as well as other drastic measures to curtail expenditure and increase profitability have become part of everyday business. The capability to manage the mining environment in a systemic manner has been lacking and this increases the pressure for performance on those individuals operating and managing mines.Working smarter has become crucial to ensure that businesses optimise the use of their resources, become more safety conscious, more productive and remain cost-effective, while recognising the importance of sustainable mining now and in the future. The logic of determining and managing to the capability of the mining value chain will be examined and the underlying assumptions or beliefs guiding behaviour and decision-making will be highlighted.In order to identify the obstacles in the mining value chain that hinder achievement of its full potential, the following questions have to be asked:What are the factors that influence the performance of a mining value chain?What is the design capacity of the mine?How can the inherent flow and value capacity of a mine be determined?What types of solutions will allow a mine to operate at its inherent flow and value capacity?This article will discuss the way we plan, measure, assess and manage the mine value chain, by addressing the following factors:balanced capacity versus flow and value capacity designthe use of averagingoptimising individual components in a value chain versus optimising the whole value chain.Optimising flow and value through the mining value chain is one of the three pillars of Mineral Resource Throughput Management (MR™). MR™ is an entrenched and academically supported philosophy that has been successfully applied in the past decade in various mines throughout the world by EXXPLEO, a mining and beneficiation consulting company. EXXPLEO has partnered with HCL (a global IT company) to embed the MR™ philosophy, methodology and toolsets into a formal software product called Synchronised Digital Mining (SDM). The SDM system will provide mining companies with a sustainable platform to effectively apply the MR™ principles and toolsets effectively across all operations targeting increased productivity, efficiency and profitability without having to train operations and management staff into expert MR™ practitioners to successfully achieve the desired results.CITATION:Dunne, A, Laurens, P G, Kruger, R and Coleman, H, 2015. Optimising flow in the mining value chain, in Proceedings Iron Ore 2015, pp 437–442 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Yuexin Han, Wenbo Li, Xinran Zhu, Pengchao Li

A multi-stage fluidization magnetization roasting is a promising method to treat limonite ore. The dehydroxylation of limonite ore is a key reaction in the pre-heating stage. In this study, the dehydroxylation mechanism of limonite was studied in a laboratory fluidization roasting reactor. The samples were characterized using in situ X-ray diffraction, Fourier transform infrared spectroscopy, and simultaneous thermogravimetry and differential scanning calorimetry analysis. The phase transformation and kinetics analysis were studied. Results indicated that the dehydroxylation occurred at the temperature of 250–350 °C with the vanish of hydroxyl functional groups (-OH). The dehydroxylation kinetics followed the 2-D diffusion (Jander) reaction model G(α) = [1 − (1 − α)1/2]2, and the calculated activation energy was 113.43 kJ·mol−1. This study is conducive to exploiting limonite ore resources using magnetization roasting technology.

Nov 2, 2023

By O Dominguez

Mine value chain reconciliation (MVC) is a necessary procedure to evaluate a mine’s performance against the assumptions and models used to plan mining and processing operations. Using nomenclature from Parker (2012), F2 reconciliation is the ratio between material received at the mill, compared with material sent to the mill, commonly reported in terms of tonnes, grade and metal. Measurements of material sent to the mill can be estimated in many ways, including: fleet management system (FMS) records, truck counts, or volume reduction. Most time-based reconciliations (for example, month-end reconciliation) use short-term model depletions of in situ rock measured by periodic topographic scans or surveys.

Mar 22, 2022

By L. Patts, J. Rohrbaugh

The Mine Safety and Health Administration (MSHA) has received several reports of filters igniting when high-temperature disposable filters were used on non-cooled diesel exhaust systems in underground coal mines. Based on laboratory testing (to determine the ignition temperature of these filters, which were loaded in the field with diesel particulate matter, or DPM), MSHA determined a maximum safe operating temperature for high-temperature disposable filters. When the results of the laboratory filter ignition testing were reported to the Coal Diesel Partnership (comprised of members of the Coal Industry, Labor, NIOSH and MSHA) the Partnership charged NIOSH with investigating the safe use of high-temperature disposable filters. This paper reports on the design, fabrication and testing of a unique exhaust gas cooling device and the ability of this device to successfully lower filter inlet temperatures and thus reduce the potential for fires.

Jan 1, 2009

By Ken J. Brouwer

Stillwater Mining Company commenced construction and development of the East Boulder underground mine in 1998. This new PGM mine is situated adjacent to the East Boulder River approximately 35 miles south of Big Timber, Montana. Project planning and development incorporated detailed collaboration between the regulatory agencies, concerned citizens and mine personnel. A unique ?good neighbour agreement? was established with a local environmental group who have become actively involved in the review of ongoing site development and the implementation of environmental and compliance monitoring. Environmental management systems allow for integrated management of tailings, waste rock and water in order to minimize surface disturbances and to prevent adverse impacts to the East Boulder River. Long-term site development plans contemplate implementation of comingled waste rock and paste tailings. Water management capabilities allow biological treatment of all excess mine water in order to reduce nitrogen loadings prior to land application disposal by means of spray evaporation, snow making and land application. The comprehensive waste and water management plans have also been integrated with staged mine development and interim reclamation requirements.

May 1, 2002

By Don Eby

The application of electric arc furnace smelting of lead, antimony, and tin bearing slag from a reverberatory furnace will be discussed. The selection procedure for the 4.0 MVA electric arc furnace in Indianapolis, Indiana is presented. The design criteria for the transformer, electrodes, refractories and associated equipment is presented. The operation of the furnace including chaJ:9ing, bullion tapping, slag tapping, ventilation, slag composition, metal recoveries, and toxic leach results of thra.1 away slag are discussed. Flow charts and the equipment specifications are given.

Jan 1, 1990

By R. Meyjes, P. Davies

Keywords: Pyrometallurgy, furnace, smelter, engineering company Metix is a private smelter engineering company wholly owned by its management. Its main lines of business in the ferro-alloy industry being: - turnkey smelter projects (LSTK) - engineering, project, and construction management projects (EPCM) - specialised furnace equipment comprising: ? complete electrode columns, including forged copper pressure rings and contact shoes, as well as fail-safe slipping devices ? water-cooled roofs ? bus-tube systems ? feed systems ? cooling systems ? linings ? off-gas systems ? tap-hole drills & clay guns - furnace power supply systems - ore agglomeration & sinter plants - feasibility studies & due diligence reports - technical consulting for investment banks - project procurement & cost control Metix management experience includes around 130 combined years of contacts and experience in the South African smelter industries. Over 30 furnaces have been built, for processes including FeCr (high, medium, and low carbon), FeSi, FeMn (high and medium carbon), SiMn (ultra low carbon), Si metal, and FeV.

Jan 1, 2006

The Johnny Mercer lyrics 'You've got to accentuate the positive, Eliminate the negative, Latch on to the affirmative à' would best sum up the traditional approach to community relations in the mining industry. This '90s 'Public Relations spin' approach, usually backed up by scientific data, technical reports and graphs outlining risk probability and the impact potential on people and communities, is being challenged. Challenged by communities who have greater access to information, demand greater levels of transparency and corporate responsibility of large corporate operations and possess greater awareness of the communities they live in.   The growth of the environmental movement, of anti-globalisation, anti corporatism, apprehension of a large corporate's ability to deal with community issues, and a lack of faith in the abilities of regulators to regulate corporate activities, means our industry faces challenges on multiple fronts. It must now be able to address these from a personal/community perspective if it is to remain relevant within communities.   One of the keys to this is linking the internal activities and responsibilities to the externals concerns and demands for higher levels of operation and care.   This presentation draws on Corporate Public Affairs trends, functions and approaches and the application to External Affairs activities within Newmont Waihi Gold's operations in Waihi and regional exploration activities throughout the Hauraki Goldfields.   The approach presented works on the philosophy that communities don't necessarily have to like what we do, but should be able to identify and recognise the way in which we involve them in decision making, communicate our intentions and respond to issues.

Jun 1, 2010

By Wolfgang Pietsch

DR iron') is a generic term for metallized product that results from the direct or solid state reduction of iron ore. In direct reduction, iron oxides are reduced to metallic iron in the solid state without an intermediate melting step. MIDREX ® Iron is the DR iron material produced in the MIDREX ® Direct Reduction Process. Except for some thermal and mechanical degradation, the external physical form of as-reduced DR iron is the same as the feed material. Chemically, oxygen associated with iron is removed leaving a very porous structure. Figure 1 is the scanning electron micrograph (SEM) of the internal surface of a MIDREX Iron pellet obtained from a Swedish oxide pellet during reduction at 760 °C. Figure 2 is the SEM of a polished and etched cross-section through the same pellet showing the amount of intraparticle porosity. As a result of this high porosity, apparent density of DR iron is relatively low, typically a¬round 2 g/cm3, and specific surface is extremely high, typically around 1.0 m2/g or more. Both density and specific surface depend on the raw materi¬al and the operating conditions of the direct reduction plant. Normally, more than 97% of the available iron is reduced into metallic iron with the rest mainly in the form of wustite (FeO). During direct reduction, the gangue in the iron remains essentially unchanged. Removal of oxygen and the corre¬sponding reduction in weight result in a slightly higher percentage gangue in the product than in the raw material.

Jan 1, 1976

By John Blatchford, H. O. Hofman

The leading antimony mineral is stibnite. In smelting stibnite ore two processes are available, precipitation and roasting-reduction. The former is suited only for high-grade ores. As low-grade ores are more common than high-grade, roasting-reduction is of greater importance than precipitation. In the roasting process the aim may be to leave the oxidized antimony in the ore, or it may be to volatilize as much of the antimony as possible, collect the volatilized oxide as a rich intermediary product and smelt it for antimony, leaving the gangue poor enough to be considered a waste product. Whichever way the roast is conducted certain difficulties inherent in stibnite are encountered. These are: 1. The low melting point of stibnite which, according to Pélabon,' is 550°C., according to Wagemann2 540°C., and according to Borgstroma 546°C. 2. The ignition temperature: According to Friedrich,4 stibnite, if heated in air, begins to oxidize at 290°C. if the size of a grain is 0.1 mm. in diameter; at 343", if 0.1 to 0.2 mm.; and 430" if 0.2 mm. 3. The fusibility of a mixture of Sb2S33 and Sb203 which in the form of kermesite (Sb2S3)z.Sbz03 melts at 517°C.6 4. The volatility of Sb2Ss and SbzOs, for which no numerical data appear to exist, although practical experience has shown that they are volatile at low temperatures. As regards the oxidation of metallic antimony, we have the experimental evidence of C. F. Plattner6 that when fused and brought to a red heat, it burns with a bluish-white flame to Sb2Oa which passes off as a

Jan 1, 1916

By M. D. Vance, G. R. Corbett, S. D. Butt

Surface wave imaging is a relatively new seismic technique that generates subsurface depth images without having to drill boreholes into the ground, and is rapidly becoming a standard tool in non-destructive geotechnical characterization. This paper presents a case study of the application of these surface wave techniques to image shallow abandoned mine workings at the Montague Gold Mines district near Dartmouth, Nova Scotia. This district has numerous steeply dipping narrow vein workings from historical mining activity, and has actively subsiding and collapsing crown pillars. Due to the rugged conditions at the site and the relative narrowness of the openings (often less than 1 m), a surface seismic system was developed that had improved portability and lateral resolution over other available seismic imaging systems. Seismic surveys were conducted over two sites where independent evidence indicated the presence of shallow mine workings. At one site, a comparative gravity survey was also conducted. The seismic data was processed to generate velocity vs depth images. Overall, the velocity images show vertical zones of zero velocity in the same lateral positions where historical mapping, current subsidence and gravity surveys indicate the presence of steeply dipping workings. Further, the velocity sections are consistent with the thickness of the till cover at each site and the possible weakening of crown pillars at one of the sites.

Jan 1, 2005

By J E. Powalisz

Obtaining a representative sample of bulk materials in process industries is critical to providing valid data for process control and custody transfer (valuation). The accuracy of a sample, that is to say how well the sample represents the material in the process, is directly related to how well the process can be controlled and to how much a product may be worth. Sampling accuracy then is in fact related to bottom line profitability.Sampling theory offers information and equations on how to take a representative sample from a process, however, the actual practice of extracting a sample from the process can be more of an art.Key sampling variables include product specifications such as bulk density, particle distribution, material conveyance, practical sampler location, sampler type and sample frequency and volume/mass.This paper discusses basic sampling theory, sampling methods, types of samplers, how to develop a ‘real world’ sampling system and current manual and automated samplers.Key points include ‘practical precision and variance’, material properties, flow properties, direct sampling versus indirect sampling, sampler types and applications.CITATION:Powalisz, J E, 2014. Bulk solids sampling, in Proceedings Sampling 2014 , pp 179–188 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By Tasuku Fuwa, John Chipman, David H. Kirkwood

Fe-C-Si alloys in silica crucibles were held at 1600°C in a controlled atmosphere of CO and Co2 and the approach to equilibrium was obsertsed. Results were not of sufficient precision to establish the activity and interaction coefficients. Observations 012 the equilibrium provided an average value for the standard free-energy change which differed by + 1.1 kcal from the earlier accepted value. The C-SL relation at other temperatures is calculated and shown graphically. IN the refining of steel in an acid-lined furnace, it is well known that, unlike in basic refining, a very significant amount of silicon may remain dissolved in the metal even when the carbon content approaches a final endpoint. Further, it is known that the residual silicon increases with increasing temperature. The quantitative relation between silicon and carbon can be calculated for equilibrium conditions from data already available on the Fe-C-O and the Fe-Si-O systems. Such equilibrium calculations could show us approximately the limitations within which the reaction would be expected to operate in practice. In the oxidation of a bath containing both carbon and silicon it is well known that at low temperatures silicon is preferentially oxidized first. It can be shown by calculation that at high temperatures carbon will be oxidized preferentially. It is the purpose of this paper to record direct observations on the Si-C relation by means of experiments carried out in an atmosphere of carbon monoxide for Fe-C-Si alloys contained in silica crucibles. When such a system is brought into equilibrium, at a fixed temperature, the composition of the liquid metal is governed by the following equations: Both K1 and K2 are known with a fair degree of accuracy, and may be calculated from the tabulated In general the percentage of CO2 is extremely small compared to that of CO and in the experiments to be described the partial pressure of the latter was generally only slightly below 1 atm. EXPERIMENTAL METHOD The induction furnace employed was the same as that described by Rist and chipman' and by Fuwa and chipman.2 It was modified slightly in view of the change from alumina to silica crucibles. The small silica crucible was surrounded by a thin susceptor of molybdenum sheet which in turn rested inside a zirconia crucible. Since the zirconia was subject to breakage, it was supported inside an alumina crucible. The charge consisted of 30 to 35 g of electrolytic iron along with the required amounts of refined silicon and graphite to produce a melt of required composition. Purified carbon monoxide and carbon dioxide were passed into the furnace through carefully calibrated flow meters. Two separate and independent series of experiments were carried out. In Series I (D.H.K.) the melt was held in the furnace at 1600°C for periods of time up to 6 hr. Samples were taken at intervals in silica tubes and were analyzed for carbon and silicon. The results of the last one or two samples taken from each experiment and the direction in which equilibrium appeared to be approached are shown in Table I. In Series II (T.F.) the silica crucibles were of less satisfactory strength and the melts were held at 1600° C for periods of only 2 to 4 hr. In heats number 29 to 45 inclusive, the metal was cooled in the furnace and the ingot itself served as a sample for analysis. In heat 46 and all subsequent heats, samples were withdrawn in silica tubes at the termination of the heat, and these samples were analyzed. The results of all of these experiments in which equilibrium appeared to be approached are listed in Table II.

Jan 1, 1965