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By B. Chalmers, L. Bäckerud

The growth temperature of dendrite tips has been measured in a binary alloy system, Al-Cu, as a function of rate of formation of solid phase. Metallographic examination has rerealed the dendritic structure dereloped during different stages of the freezing process and factors influencing the undercooling, such as solute buildup, surface tension, and kinetic effects, have been estimated. Practical implications of the results are discussed. THE development of a dendritic growth pattern during the solidification of metals and alloys has an influence at least equal to that of grain size on the properties of the casting or ingot being produced. and consequently much interest has been devoted to the study of this phenomenon. A review of the knowledge gathered up to 1964 has been given by Chalmers.' Among recent publications in the area the works of Jackson et al 2 and Flemings and his coworkers3,4 are of special interest. This work is an experimental study of the factors which influence the development of a dendritic pattern during the solidification of a typical binary alloy system, A1-Cu, when there is no heat source in the liquid. This means that the temperature and the temperature gradient are controlled by the heat extraction from and latent heat evolved by the growing crystals. EXPERIMENTAL PROCEDURE Samples were prepared from a master alloy made up of aluminum, 99.995 pct, and copper. 99.99 pct, of the concentrations given below and of sufficient size to fill cylindrical graphite molds of 35 mm ID and 35 mm height. Bottom. wall. and lid of the graphite molds were all of 6 mm thickness, Fig. 1. Thin ceramic thermocouple shields could be introduced at different positions in the sample through holes in the lid. The assembly was heated in a small vertical resistance furnace to a suitable temperature. 700° to 720°C. which is well above the melting point of the sample. It was thereafter taken out of the furnace and chilled at selected rates, and the temperature changes in the sample were recorded. For high sensitivity in the temperature recordings, a reference thermocouple was held in a solidifying pure aluminum melt. which was very well insulated and therefore was at a constant temperature. 660°C, for nearly half an hour. The thermocouples were connected so that the difference voltage was fed into the recorder of which the most sensitive range was 1 mV. Temperature variations could be read to within 0.l°C. The thermocouples used were of the Chromel-Alumel type (28- or 38-gage wires) and the recorder a two-pen Moseley strip chart recorder. The different rates of chilling were obtained in the following way. a) The graphite crucible was wrapped in one or two layers of an insulating. feltlike material (Fiberfrax paper from the Carborundum Co.). The drop in temperature per unit time after complete solidification could thereby be varied from 8" to 18°C per min. This corresponds to a rate of heat extraction in the given samples from 0.08 to 0.17 cal cm-' sec-I. 6) The bare graphite mold was placed free on a piece of firebrick. The measured temperature drop was around 50°C per min (-0.5 cal cm-" ' sec- I). c) By blowing compressed air through a tube with many holes surrounding the mold in a ring shape. the rate of heat transfer could be raised to 150' to 200°C per min (-1.7 cal cm-3 sec- I). d) Cooling rates around 1000 C per mill (-9.4 cal cm-3 sec-l) were obtained by substituting the air in the device used in c by water. The range of cooling rates used in these experiments correspond to technical casting processes from slow solidification as obtained in sand molds to very rapid freezing which occurs in some continuous casting and welding processes. EXPERIMENTAL RESULTS The A1-Cu system was chosen for the experiments: the relevant part of the phase diagram is reproduced in Fig. 2. Observation of the Center Temperature. When a thermocouple is inserted in the center of the melt. the type of cooling curves obtained at slow solidification rates differs little from numerous published curves from similar systems. and the solidification pattern

Jan 1, 1970

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By E. S. Bartlett, D. N. Williams

QUANTITATIVE values for the oxidation rate of unalloyed molybdenum in air at temperatures above the melting point (1460°F) of the characteristic oxide are contained in the literature as a result of previous investigations. Lustman' reported values corresponding to 0.36 in. penetration per day (IPD) at 1500 and 1600°F in still air, noting essentially no variation in rate with temperature. Jones, Spretnak, and Speiser' reported values corresponding to 0.14 and 0.13 IPD at 1500 and 1800°F, respectively, in still air, attributing the decreased oxidation rate at higher temperatures to a lesser accumulation of the corrosive molten oxide on the surface at the higher temperature as a result of increased volatilization rate. Harwood3 ecently summarized work in the field, presenting generalized data corresponding to 0.48 to 0.96 IPD at 1800°F and 0.55 to 0.83 IPD at 1700°F in slowly flowing air. In a recent program at Battelle, it became desirable to know more about the characteristic oxidation behavior of molybdenum under varying conditions of temperature and atmosphere. Using oxidation-test apparatus designed for dynamic, continuous recording of weight change during testing,' values for the oxidation rate of molybdenum were obtained at temperatures from 1400 to 2150°F. In addition the effect of air flow on the oxidation rate was studied briefly at temperatures of 1600, 1800, and 2000°F. Exhaust of the contaminated atmosphere from the oxidation chamber was effected by an impeller pump attached to a 3/16-in.-diam opening in the oxidation chamber. The volumetric exhaust rate (cubic feet per hour) was normally maintained slightly in excess of the input rate to avoid condensation of MOO,,' on the sample suspension rod. The entering atmosphere was preheated prior to admission to the oxidation chamber by a 1 1/2-in.-diam cup packed with shredded asbestos. The experimental data are presented in Table I. Comparing conditions 2 and 3 (taking into account the temperature difference) and conditions 8 and 9. shows that in the absence of forced exhaust an atmosphere of moving air results in greater oxidation rate than a stagnant atmosphere. The use of forced exhaust, as shown by comparing conditions 3 and 4 and conditions 14 and 15: resulted in an even greater increase in oxidation rate. By virtue of the size of the atmosphere input and exhaust openings, it was calculated that the exhaust velocity was about 60 times that of the input velocity for essentially equal volumetric flow rates. Because of the proximity (about 3/4 in.) of the exhaust port to the specimen, it is logical to assume that cleansing of the atmosphere immediately surrounding the specimen was accomplished much more efficiently by the exhaust flow than by the input flow at a constant-volumetric flow rate. Also, it can be seen by comparing conditions 4 through 7 and conditions 11 through 13 that increasing the rate of atmosphere flow (by increasing input velocity with a proportional increase in exhaust velocity) above some optimum value has little, if any, further effect on the oxidation rate. These results suggest that there is a maximum oxidation rate for molydenum at a given temperature which is obtained when conditions are maintained such that the partial pressure of MOO3 in the atmosphere surrounding the specimen is at a low value. By controlling the partial pressure of MOO, surrounding the sample, it is possible to control the rate of volatilization of MOO:, from the surface. This, in turn, affects the rate of oxidation, since the thickness of the MOO3 layer determines the amount of oxygen which will be able to reach the reaction surface.' When the liquid oxide layer is less than some critical thickness, i.e., when the volatilization rate is high, enough oxygen is transported to the active surface to permit oxidation to proceed at the maximum rate allowed by the kinetics of the oxidation reaction. However, if the volatilization of MOO,, is suppressed, the thickness of the layer of MOO3 on the surface increases, and the diffusion of oxygen through the oxide layer becomes the rate-controlling step in the oxidation process. The lack of agreement between the present results and those of previous investigators is presumed to be due to differences in removal of the oxidation product (Moo,) from the immediate vicinity of the sample. By comparing conditions 1, 5, 10, 12 and 14, it is seen that when forced exhaust was used the oxidation rate of molybdenum increased with increasing temperature. A rapid increase was observed between 1400 and 1600°F, attributable to the effects

Jan 1, 1959

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006

By Huai-ying Ma, Jun-hua Zhao, Xia Zhao, Si-bin Zhang, Wen Pan, Zhi-xing Zhao

Ignition is the start point of the sintering circuit, which plays an important role during the whole sintering process. The gas consumption accounts for 80% energy cost in the sintering ignition process. Therefore, gas flow reduction is of great significance to energy conservation in the sintering ignition process. In current study, the concept of comprehensive ignition intensity (CII) was introduced to determine the ignition effect. The experimental results indicate that the value of CII increases with higher air-fuel ratio at gas flow of 550 and 600 Nm3/h. From another point of view, given constant CII value, lower gas flow can be achieved with higher air-fuel ratio. Based on the comprehensive ignition intensity, the ignition parameters were optimized and the gas flow was subsequently reduced. By increasing the air-fuel from 5.5 to 6.6, the gas flow is reduced from 450 Nm3/h (8.1 GJ/h) to around 350 Nm3/h (6.3 GJ/h).

Mar 1, 2018

By D. Warkentin, T. Yeomans, R. Tavakoli, A. Nacu

"One of the most successful commercial methods of extracting gold from ores involves solubilizing gold as a gold cyanide complex, followed by adsorption of the complex onto activated carbon. The gold cyanide is subsequently eluted from the carbon to produce a concentrated gold solution suitable for electrowinning to recover the precious metals. Stripped carbon is treated in a kiln under a flowing steam atmosphere to reactivate its surface, allowing it to be reused. The aim of this study was to investigate the gold elution using a mixture of sodium hydroxide and isopropyl alcohol in both batch and continuous tests, with the eluates being electrowon on carbon foam cathodes. The effects of various factors, including alcohol content and sodium cyanide addition were studied. The addition of alcohol considerably improved gold elution kinetics, while the presence of sodium cyanide did not have a significant impact on either elution efficiency or kinetics. In all cases, efficient electrolysis was shown to be an important factor in maintaining effective carbon circuit operation.INTRODUCTION Gold dissolved as Au(CN)2- complex during cyanidation is recovered either by cementation with zinc powder, also known as the Merrill-Crowe process, or by adsorption into activated carbon through Carbon-in-Pulp (CIP) or Carbon-in-Leach (CIL) processes. Activated carbon loaded with gold is then eluted and gold is subsequently recovered by electrochemical methods. Conventional elution processes such as atmospheric and pressurized Zadra processes, involve stripping with a cyanide (0.1–0.2% NaCN) and sodium hydroxide solution (1–2% NaOH) at high temperature (90–140°C) over long elution times of 8 to 72 hours. In the Anglo American Research Laboratories (ARL) elution process, the acid-washed loaded carbon is pretreated with a strong sodium cyanide and sodium hydroxide solution (1–5% NaCN and 1–2% NaOH), followed by elution with water at 110–130°C. Solvent-assisted elution processes have also been reported, such methods use varying concentrations of alcohols (methanol, ethanol and isopropanol), ketones, or glycols to enhance atmospheric elutions at temperatures up to 95°C (Muir et al., 1985; Ubaldini et al., 2006; Espiell et al., 2008; Soleimani & Kaghazchi, 2008). The present work investigates the efficiency of isopropanol in the gold elution process, as well as the methodology of evaluating gold stripping processes in the lab setting"

Jan 1, 2017

By R. W. Geehan

The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. Bureau engineers made a preliminary examination of the Morefield mine early in 1943 and recommended investigation by trenching and diamond drilling, The Bureau of Mines conducted work from August to December of 1943, which indicated that the Morefield mine was a favorable location for an experimental mining program. The Bureau of Mines carried on such a program from September 1947 to March 1949. The property investigated is 30 miles southwest of Richmond in Amelia County, Va. (fig. 1). During World War II mica and beryl were shipped from the Morefield mine, but after the high prices and premiums paid during the war years were not available the mine was closed.

Jan 1, 1953

By P. Crouse, J. Obermeyer

"INTRODUCTION Site location and history The Holden Mine is a former underground copper mine that was developed and operated by the Howe Sound Mining Company (Howe Sound) from 1938 to 1957. The mine is located in north-central Washington State, U.S., near Lake Chelan in the area shown as Holden Village in Figure 1. Although Rio Tinto never owned or operated the mine, they are managing and funding a several hundred million dollar clean-up to prevent future water and soil contamination and to reclaim the former mine site under the United States Environmental Protection Agency (USEPA) Superfund process. The former mine included an onsite mill and a nearby housing complex for the miners. Howe Sound developed the mine as a series of near-horizontal drifts and tunnels, interspersed with stopes and shafts that connect different mine levels underground. The tunnels that were excavated to develop the mine total nearly 100 km in length.During development of the underground workings, Howe Sound removed more than 230,000 cubic meters (m3) of waste rock from the tunnels and deposited this material in two waste rock piles. Ore was processed from the mine in the onsite mill to produce a copper concentrate that was shipped off site for smelting. Roughly 10 million tonnes of tailings were produced as a by-product of the milling operation, most of which were deposited in three large impoundments (Tailings Piles 1, 2 and 3) directly south of and adjacent to Railroad Creek. Howe Sound closed the mine in 1957. In 1961, the property was transferred to Holden Village, Inc. (Holden Village), a not-for-profit corporation that maintains a year-round community and operates an interdenominational religious retreat in the former miners’ town. With the exception of the patented private land, the remainder of the Site is on National Forest lands and is administered by the U.S. Forest Service. The mine is remote. It is only accessible by boat or float plane from Chelan, Washington, up Lake Chelan to Lucerne, nearly 40 km. Vehicle access from Lucerne to the mine is provided through a 17.5-km-long winding gravel road that climbs 640 meters in elevation. The general site features are shown in Figure 2. Physical setting The Holden Mine is located on the eastern slopes of the Cascade Mountain Range at an elevation between 975 and 1,050 m above mean sea level. Holden Mine was developed adjacent to Railroad Creek, which lies in a glacial U-shaped valley carved into the igneous and metamorphic bedrock with steep-sided slopes (Figure 2)."

Jan 1, 2017

By V. Rajaram

The Metropolitan Water Reclamation District of Greater Chicago (MWRD) imposed a no-blasting specification (blasting is restricted to the construction shaft and shaft bottom or boot) on the Deep Tunnel project in 1988. This was prompted by numerous complaints from the residents in the vicinity of the project, and controversies experienced on previous projects from blasting the rock overlying the tunnel. This paper will describe the methods utilized by two major contractors who are driving 20 km (12.5 of tunnel along with drilling over 36 shafts under this restrictive specification. The impacts on design, construction, schedule, cost, and the environment are detailed.

Jan 1, 1991

By Noel Dent

The Electrodet@ Electronic Detonation System Wilere are we going with regard to Accurate, Reliable, Easy to Use and Cost Effective Initiation using electronic initiation techniques? Improvements and applications in theJierd

Jan 1, 1995

By Yuting Xue, Gamal Rashed, Zoheir Khademian, Morgan Sears

Mining has been recognized among the most hazardous industries in the United States, despite the significant reduction in injury and fatality rates over the past century. This study focuses on the ground-fall incidents classified in the Mine Safety and Health Administration (MSHA) database as “fall of roof, back, or brow from in-place” and “fall of face, rib, pillar, side, or highwall.” The main objective of this study is to conduct a comprehensive statistical analysis of the reported ground-fall incidents from 2010 through 2019 including both coal and metal/non-metal mines. Since most of the ground-fall injuries and fatalities occurred in underground coal mines and were attributed to falls of roof and rib, an additional analysis was directed to evaluate roof- and rib-fall incident trends in underground coal mines associated with the mining method, coal-seam thickness, mine size, and the seasonal effects.

By D. K. Matlock, D. J. Hamre, J. G. Speer

Ultrafine ferrite (UFF) grains may be produced in surface layers of plate steels using controlled intermediate cooling followed by deformation. Experiments were conducted using a 0.12 C - 1.26 Mn steel on a Gleeble 1500 hot deformation simulator. Taguchi designed experiments were used to evaluate prior austenite grain size, intermediate cooling rate, intermediate cooling temperature, intermediate hold time and amount of reduction in order to observe the effects of variables and their interactions on the final microstructure while minimizing the number of required test runs. Evaluation of resulting microstructures and mechanical properties revealed a preferred thermal and mechanical history for developing ultrafine microstructures in surface layers of plate steels. Application of the fundamental concepts of phase transformations to industrial plate rolling is considered.

Jan 1, 2004

By Pedro Cunha Alves, Wagner Viana Bielefeldt, Vinicius Cardoso da Rocha, Augusto Lachini Pereira, Julio Aníbal Morales Pereira

The capacity of steelmaking slags (CaO-SiO2-Al2O3-MgO) on inclusion removal from liquid steel was investigated through experimental conditions. Laboratory experiments with slag and steel samples (with inclusion population known) were performed using a vertical electric resistance furnace at 1600 ºC. After the melting experiments, slag and steel samples were separated and analyzed regarding their chemical composition and inclusion population evolution. The capacity of slags on inclusion removal was evaluated based on the thermodynamics (solid and liquid phases proportion, phase composition and effective viscosity of slags) calculated using the FactSageTM 7.2. Results indicated that changes in the composition of slags (regarding CaO/SiO2 e Al2O3) presented effects on the steel cleanliness. The total inclusion density decreased in all steel samples and the removal of inclusions by slags shows a tendency to improve as their viscosity decreases (< 0.23 Pa.s).

Oct 1, 2019

By B. K. Cantrell, K. L. Rubow

"The US Bureau of Mines and the University of Minnesota have developed design and performance criteria for a personal diesel exhaust aerosol sampler for underground coal mines. These are based on the premise that size can be used to separate diesel exhaust aerosol, which is mostly submicron in size, from coal dust aerosol, which is mostly greater than a micron in size. The sampler has three stages: a respirable aerosol preclassifier, a 0.8-um aerodynamic diameter inertial impactor to collect mineral dust and a final filter to collect the diesel aerosol. Using a sample flow rate of 2 L/min and gravimetric analysis to within 0.1 mg, the measure sub-0.8 um diesel aerosol has an a-priori limit of detection of 0.3 mg/m3.A miner working in an underground coal mine with diesel equipment is exposed to a wide array of pollutants from the diesel exhaust. These include CO, CO2. NO, NO2, SO2, diesel exhaust aerosol, and a variety of hydrocarbon compounds. A quantitative definition of the health risk resulting from these exposures remains elusive. During the past several years, though, progress has been made in defining the problem.Results from epidemiological studies by Garshick et al. (1988 ), animal inhalation studies by Mauderly eta). (1986), Iwai et al. (1986), and Brightwell et al. (1986) and in vitro studies by Lewtas et al. (1986) have provided sufficient data for the National Institute of Occupational Safety and Health (NOSH) to recommend that ""whole diesel exhaust be regarded as a 'potential occupational carcinogen,' as defined in the Cancer Policy of the Occupational Safety and Health Administration"" (NIOSH, 1988). NIOSH further stated that ""though the excess risk of cancer in diesel-exhaust-exposed workers has not been quantitatively estimated, it is logical to assume that reduction in exposure to diesel exhaust in the workplace would reduce the excess risk.""The Mine Safety and Health Administration (MSHA) has also been directed by an advisory committee to establish a diesel exhaust aerosol standard and to establish regulations to minimize exposure to diesel pollutants in underground coal mines (MSHA,1988). Both reports point out the need for development of measurement techniques for respirable diesel aerosol.In the past four years, the US Bureau of Mines (Cantrell,1987 and Cantrell, et al. 1987), in cooperation with Marple, et al. (1986), at the University of Minnesota's Particle TechnologyLaboratory (PTL), have studied the use of size-selective sampling techniques to measure the mass concentration of diesel aerosol in underground coal mines. Results from these studies have been used to develop design and performance criteria for a personal diesel exhaust aerosol sampler for use in underground coal mines.These criteria are based on the premise that size-selectivesampling techniques,can be used to separate diesel exhaust aerosol, which is predominantly submicron in size, from coal dust aerosol, which is mostly greater than a micron in size. In addition to the performance criteria, this paper discusses the laboratory and field test data used to develop the criteria."

Mar 1, 1992

By G K. N Subasinghe

Metallurgists operating Knelson Concentrators (KC) often rely on manufacturerÆs recommendations for selecting operating parameters, such as fluidising water flow rate and cycle time. Recent studies have shown that these parameters are not only dependent on the machine parameters but also on the feed characteristics, such as size distribution of the gold and gangue particles and the composition of its constituent minerals. It is known that a particle entering a KC initially traverses a circular path within the bowl. For a particle to maintain a given orbit, the required centripetal force must be supplied by external means. It has been argued that this centripetal force, which is dependent on the mass of the particle, its radial position and the rotational speed of the bowl, is provided by the fluid drag force created by inwardly moving fluidising water and the BagnoldÆs force created by the particle/particle collisions. Depending on the fluidising water flow rate, one of two situations can occur where the porosity of the bed increases or decreases, which influences the amount of material retained within the bowl. The amount of material of a given size and density retained in the bowl is thus dependent on the extent of the centripetal force provided. Based on the above concept, a criterion that can be used to predict the amount of material recovered in the bowl has been derived and validated by experimental data. It may also be construed that this criterion demarcates the transition of the bed from a packed-bed state to a fluidised state. By identifying the transition values for the different constituent mineral particles in the feed, it is possible to estimate the optimal fluidising water flow rate that would maximise gold recovery while minimising gangue recovery. In addition, the kinetics of gangue displacement by incoming heavy mineral particles were also studied using synthetic mineral mixtures. The experimental data suggests that this process follows first order kinetics and that the build-up of heavy mineral reaches a maximum. A model has been proposed to predict the optimal batch cycle time for a KC in terms of the feed characteristics and machine operating parameters.

Jan 1, 2006

By A. Brian Hawkins

"When pyrite oxidizes in dark grey/black, calcareous, mudrocks or in argillaceous limestones, ferrous sulfate is formed and sulfuric acid is released. The sulfuric acid combines with the calcite present in the rock and calcium sulfate (gypsum) develops. When this occurs on the outer edges of aggregate particles, the gypsum forms in the matrix hence there may be little expansion of the general material. However, when the chemical reactions occur within the rock fragments, particularly on microscopic, clayrich, laminae, the developing crystals exert a significant pressure on the host material. If the rock is medium strong to strong, the force of crystallization splits the rock along the weaker planes, facilitating the ingress of the oxidizing agents and the continuation of the chemical reactions. In addition to causing dilation/heave, some of the engineering properties of the material are changed, including the strength, Los Angeles value, water absorption etc. As a consequence material, which at the time of quarrying would be acceptable for use beneath floors or hardstandings, would no longer be considered suitable.INTRODUCTIONMudrocks accreting in aerobic environments are frequently disturbed by organisms and as a consequence there is often little sign of bedding. In contrast, sediments which have formed in anoxic environments commonly have distinct bedding planes which, because of the grain size of the accreting material, are often smooth and planar. These rocks are frequently referred to as shales, which O’Brien and Slatt (1990) define as “characterised by a finely laminated structure, which imparts a fissility approximately parallel to the bedding.” This should not be confused with rhythmic bedding where the variation in grain size results in lithological laminations or colour changes.Early geologists, in the stratigraphic naming of rocks, often used the term shale for material which is now more likely to be described as mudstone or mudrock (Hawkins and Pinches, 1992). In many contexts, the width of the bedding is an important factor, not only in determining the rock name but also in indicating the potential engineering characteristics. Until recently a shale was considered to have bedding separations of less than 20mm, i.e. the bedding was described as laminated. However, in an engineering context, EN 14689: 2003, Annex A, defines shale by specifying a bedding thickness of < 6mm; such a material would be described as thinly laminated in BS 5930:1999. Ideally the term shale should be abandoned and be replaced by fissile mudstone or fissile mudrock."

Jan 1, 2015

By W. Breytenbach

Traditionally, dithiocarbonates (xanthates) have been the preferred collectors for the flotation of platinum-bearing sulphides. However, collector development has led to trithiocarbonates (TTC), which have proven to be very effective bulk sulphide collectors. The interest in TTC flotation behaviour is currently focused on the interaction of these collectors with other collectors, specifically the dithicarbonates. Batch-flotation research has shown synergism to exist among dithiocarbonate, dithiophosphate and trithiocarbonate collectors. Increased sulphide recoveries, both for the first-minute and final concentrate, were realized using mixtures of these collectors relative to the standard.

Jan 1, 2003

By M. Akser

Ilmenite, rutile, and zircon deposits of commercial importance have not been reported to-date from Turkey. However, information from recent reconnaissance activities indicates the possibility of an economically viable heavy-mineral deposit along the Black Sea coast of Turkey in the vicinity of Ormanli, northwest of Istanbul. Consequently beach and sand dune samples were collected from that area for additional analysis. Laboratory methodologies, designed to simulate standard industrial heavy-mineral plant practices, were used to analyze and evaluate the samples. Based on the analyses, and current market needs, none of the deposits in the Ormanli area qualify as a commercial heavy-mineral deposit.

Jan 1, 1995

By Robert C. Stanley

Early History Probably the first use of nickel by man was in the fashioning of implements, and later swords, from nickel-bearing meteorites, masses of metal that have fallen from time to time at many points on the earth&apos;s surface and which consist normally of iron carrying substantial amounts of nickel. Meteorites were perhaps the first metal known to man. The falling star, sought out with fear overborne by curiosity, was found to be a better stone than the earth-given, truly a boon from the gods. Archeologists tell us there is good evidence that the ancient oriental peoples learned at an early date to make these stones into useful implements. The invincible blades of the great warriors of old in China, Persia, and in northern Europe, were Heaven-sent, a fable which sounds significant of meteoric iron. Probably some of the ancient swords of Khorassan and of Damascus were of meteoric nickel-bearing iron (1). Fifty centuries were to pass before men learned to isolate nickel and add it to iron to produce the same alloy for much the same purpose. Meanwhile, man had found another natural alloy of nickel, known first to the Chinese as paktong, or &apos;white copper.&apos; It was obtained from complex copper-nickel sulphide ores of Yunnan in southern China. This metal was brought by caravan through India into Bactria, a country north of the Hindu-Kush mountains, in what is now known as Russian Turkestan. The earliest specimen extant is a Bactrian coin attributed to 235 B.C. The rough reddish-white metal was also sent in the form of triangular rings to Canton, where zinc ores were added and the whole smelted to a more malleable alloy, also known later as paktong. This alloy was the forerunner of German-or nickel-silver. Specimens of this alloy, wrought into ornamental candlesticks and boxes, were brought from Canton to Europe by the East India Company in the early days of the China trade. Paktong was highly prized for its beauty as well as its eastern origin in far-away China. By 1760 the unwrought metal was imported into England for domestic manufacture.

Jan 1, 1935

By S. Rash Ahmadi

Welding is highly reliable and efficient metal joining process. In welding the metal adjacent to the weld joint is subjected to severe thermal conditions. As a result, complex changes in metallurgical structure occur in this region. These changes in structure depend on the material and the temperature history experienced. Friction stir welding (FSW) is relatively a new welding process in which, heat is generated by friction between the tool and the workpiece. The amount of heat conducted into the workpiece determines the quality of weld, residual stress and distortion of the workpiece. The objective of the current work is to study the transient temperature in a friction stir welding. So, a three dimensional transient analytical model is used to study the thermal distribution during the welding. Heat input from the tool shoulder alone is considered in the model. The process parameters like axial load, welding speed and tool rotational speed, used in actual FSW process are taken to build the model. This analytical model is very useful for select the optimized affected parameters in friction stir welding. The model illustrates the comprehensive equation including actual affected parameters in FSW and it can be used for different materials. In addition to the above the thermal history finds application in design of welding tools.

Oct 1, 2011