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By K. T. Valsaraj

The separation process called solvent sublation for the removal of two hydrophobic compounds (penta-and tri-chlorophenols) from the aqueous phase is discussed. A steady state mathematical model for the process is discussed. The process was conducted in a continuous countercurrent mode. The underlying mechanisms, theory and experimental details on the effects of process variables on removal efficiency are reported.

Jan 1, 1992

By A. Noble

"Linear circuit analysis (LCA) is a fundamental tool that may be used to evaluate, design and improve the performance of mineral separation. The traditional LCA methodology provides a comparative evaluation of circuit designs purely from the unit interconnections. The quantitative approach uses the analytical circuit solution to evaluate the slope of the circuit’s partition curve at the midpoint. Since the partition slope is often associated with a separation’s general selectivity, this numeric value is used to compare and rank alternative configurations. Unfortunately, the partition curve slope only reflects the separation potential of middling material. By itself, this value does not account for the relatively high unit dollar value of pure material or the gains and losses in mass yield associated with alternative circuit configurations. Realizing the value in the LCA methodology, but respecting the limitations of the partition slope valuation, the authors have derived two new performance indicators that quantitatively address pure particle misplacement (the Partition Moment of Inertia) and circuit mass yield (the Yield Score). Together, these parameters provide a better indication of separation economics in typical mineral and coal separation systems. Since the two parameters provide independent information on circuit selectivity and circuit yield, a Pareto efficiency, multi-objective function selection approach is proposed for preliminary circuit selection.IntroductionOver the past 30 years, numerous scientific and industrial studies have proposed various mineral processing circuit design methodologies that attempt to optimize the allocation of separation resources within the processing plant. Over this period, the methodologies have undergone various transitions, including the increased inclusion of process models and computationally intensive algorithms, as well as a general shift from a purely technical solution (Lauder and McKee, 1986) to partially economic solutions (Abu-Ali and Sabour, 2003; Cisternas et al., 2014). Today, circuit design is largely driven by flowsheet simulation; however, no consistent design methodology is used across the industry.One intriguing approach for circuit evaluation is linear circuit analysis (Meloy, 1983a). This method evaluates the separation potential of the circuit solely considering the unit configuration and stream interconnections. No preliminary data other than the basic circuit configuration is required to use the approach."

Jan 1, 2015

By Alberto Tremea

The eddy current system is universally recognized as a most suitable method to point out discontinuities or modifications on the roll surface. The automation of the controls through the implementation of sophisticated equipments on the grinding machine has favoured its employment in the roll shop. A big effort is still going on to clarify the best way to promptly identify situations that could be really unsafe for the roll life. The results presented in this paper have been obtained through an intensive activity conducted in field by Innse Cilindri on work rolls of finishing stands of hot strip mills. The correct interpretation of the eddy current signals and a good calibration of the automatic system have allowed, in many cases, a substantial optimisation of regrinding practices.

Aug 16, 2017

By R. A. Brown

RIGHT NOW the Canadian oil business is suffering from growing pains brought on by developments outside our borders. I would like, therefore, to place our industry in perspective for you in two ways. I would like first to describe it briefly and let you see it in relation to the world oil industry. Then I would like to bring it back and place it into perspective against a strictly Canadian background. Naturally, in such a discussion, it is necessary to use a certain amount of statistical material. I'll endeavour, however, to keep it to a minimum. Eleven years ago, before the discovery of Leduc, Alberta could boast of having 21,000,000 barrels of crude oil reserves. Five years ago we had 1,810,000,000 barrels. At year end, 1957, our remaining recoverable reserves totalled more than 3,000,000,000 barrels. In 1957, our potential production in Alberta reached an all-time high of 756,000 barrels a day. Unfortunately, our actual average daily production dropped from 393,000 barrels per day in 1956 to 376,000 barrels per day in 1957. And in 1958, to date, it has dropped sharply to around 300,000 barrels per day.

Jan 1, 1958

By G. W. Neumann, J. R. Schnarr

The lead-zinc-copper-silver ores mined by Brunswick Mining and Smelting Corporation Limited at their No. 12 underground mine and No. 6 open-pit operation, and treated by distinct concentration processes in separate plants, present difficult metallurgical problems because of the extremely fine dissemination of the valuable minerals with pyrite and pyrrhotite. The problem of concentration is further complicated, in the No. 12 ore, by the presence of a varying content of graphitic carbon. This paper describes the milling of No. 12 ore and the production of copper, lead and zinc concentrates by differential flotation.

Jan 1, 1971

By Adriano Gonçalves dos Reis

In the development of the structural materials for the advanced applications, as in the aerospace industry, there is a constant strive to increase both strength and toughness. Maraging steels are iron-nickel alloys designed to combine both properties that are achieved through the age-hardening of low carbon martensite. This alloy have a metastable martensitic structure that can revert to austenite when heated in temperatures close to the aging temperature, and this effect can be enhanced with the temperature increasing and time of treatment. Therefore, the study of creep behavior in elevated temperatures has technological importance to the development of this material. In this work the creep behavior of a maraging 300 steel solution annealed is evaluated by carrying out creep tests at 650ºC and in a stress of 200, 300 and 500 MPa. Creep parameters, such as steady state creep rate (?????), final creep time (tf), and stress exponent from secondary creep (n) are determined, considering that they are important to evaluate the creep resistance of the material.

Aug 7, 2018

By J. C. Swartz

New measurements of graphite and cementite solubilities in ferrite have been obtained to resolve disagreements among previous data. To measure graphite solubility, specimens of iron were equilibrated with rarious carburizing atmospheres at temperatures be-twee~z 480" and 1435°C. The carbon activity of each atmosphere relative to graphite was taken from published data. After quenching from each equilibration treatment the concentration of carbon (typically 10 pprn by wt) was determined from the height of the Snoek peak in the internal friction spectrum. A few inclividual analyses by combustion support the reszdts of Smith on the solubility of graphite near the eutectoid temperature. Combination of these combustion and internal friction analyses determines In a, (at 0.01 wt pct) = 24,000/RT - 12.72, where a, is the activtity relative to graphite in ferrite at fixed cornposition. The same specimens were used to determine the solubility of self-stressed cementite precipitates. The results indicate solubilities of 6.3, 23.2, and 68 pprn carbon by wt at respectively 400°, 500". and 600°C. The once large discrepancy between the cementite solubility determined by internal frictiori and that calculated from flee energy data has been almost completely resolved. A recent study1 (hereafter designated I) on the solubility of cementite in a iron did not fully resolve the disagreement among previous data. The remaining disagreement is illustrated by the phase diagram in Fig. L The data of I are represented by the line labeled "stress-free" cementite. They determine a heat of solution of cementite of (14.8 * 0.2) kcal per mole which contrasts with the (20 * 1) kcal per mole derived from Smith's graphite solubility2 and the formation energy of cementite.3 Toward resolving this disagreement we have obtained new data on the solubilities of graphite and cementite. METHODS As in I the Snoek peak in the internal friction spectrum was used to measure the concentration of carbon dissolved in ferrite. This method relies on the relation C=kQ-1 [1] in which C is the concentration of dissolved carbon, Q-I is the Snoek peak height, and k is a proportionality factor which is a function of the peak temperature, polycrystalline texture, and other parameters characteristic of the ferrite lattice. To determine true heats of solution via Eq. [1], it is necessary to establish that k is independent of the temperature from which the specimen is quenched. Some evidence on this point is contained in a separate report.* Additional evidence is shown by the data points in Fig. 1. These represent the Snoek peaks of two specimens carburized to about 10 ppm C, copper plated, and quenched first from 888º then from 588°C. The copper plate was removed before each Snoek peak measurement. These data show that there is no detectable dependence of k on quenching temperature. The solubility of graphite was determined by repeatedly carburizing various specimens of iron wire with gas mixtures of known carbon activity relative to graphite. To cover a wide temperature range within the a phase boundaries it is desirable to use as low a carbon concentration as is compatible with reasonable precision. With the present internal friction apparatus the best compromise of these desires is a concentration near 10 wt ppm. The dashed line in Fig. 1 was used to approximate the activity of carbon* for

Jan 1, 1970

By N. M. Levine

This work defines and systematizes the physical factors of the problem of leaching and demonstrates for the first time the utility of macropore volume, micropore volume, specific surface, pore size distribution and permeability as parameters of leaching based on a study of the recovery of uranium from the Top Black member of Chattanooga Shale.

Jan 1, 1962

By L. J. Murphy

The production of crude oil in the United States is exceeding consumption by one-quarter million barrels per day and, with the possibilities of West Texas, this condition of overproduction, unless controlled, is likely to continue for some time. The resulting low price of oil has caused the operator to observe closely his lease operating costs. The installation of more efficient and reliable machinery has followed and it can well be said that the art of producing oil is on the threshold of a new era. In this advancement electricity has played a leading part. This paper covers only the problem of electricity as applied to lease operation and does not consider other phases of the industry, such as drilling and pipe-line pumping, in which electric power has been utilized economically. In considering electrification of pumping wells, the first question the operator asks is whether or not his costs will be reduced and the second question is whether or not the production will be increased. The third question, although in effect it is closely allied to the first, is the cost of power. The last question can be answered only after a thorough analysis of operating conditions and a study of the power rates prevailing in the particular field under consideration. Within the past few years, the power companies have realized the desirability of a steady 24-hr, pumping load, have made their rates for oil-field service particularly attractive, and in general have shown splendid cooperation in assisting the oil companies in the satisfactory application of electric power to their leases. When everything is taken into consideration, the first cost is practically the same for electric drive as for gas engines when pumping on the beam with individual motors. This cost, at prevailing prices, should aver-age approximately $2200 to $2400 per installation when using 15 to 35-hp., two-speed pumping equipment, including motor and control, countershaft, motor house, belt, installation charges, and a prorated portion of the cost of transmission lines and transformers for serving a number of wells. Since there is practically no difference in the cost of the two installations, it is evident that electricity, to justify its consideration, must have a lower operating cost or produce more oil.

Jan 1, 1928

By Patrik Yrjas, Daniel Lindberg, Emil Vainio

Recovery of trace elements from different industrial waste streams is important in realizing the goals of the circular economy. Ash streams from waste combustion can contain high levels of both toxic and valuable trace elements. These elements can be separated during the combustion process based on volatilization and condensation, as well as being separated in post-combustion processes, through thermal or leaching treatment. In this study, an overview is given of the thermal methods for recovery of valuable elements from ash fractions derived from waste incineration. In addition, a case study is presented of the behaviour of ash-forming elements in combustion of MSW and demolition wood, with special focus on the elements Co, Cu, and Sb. In conclusion, it is shown that thermodynamic modeling of high temperature processes can be a useful tool to predict ash behavior both during combustion and in the post combustion treatment of the ash.

Mar 1, 2018

After a five year period representing the strongest resource and commodity rally ever experienced, we are now faced with a subdued recovery following the global financial crisis. This renewed economic growth will be steady but eventually attain levels that reignite export demand out of China and other emerging nations, which are now reliant on increasing domestic demand to support their economies. This backdrop of weaker share prices and less available investment capital creates a greater imperative for company management to ensure that its share price is fully valued. The mining geologist plays an important role in achieving this outcome through direct estimation of asset value (resources) but also in strongly communicating the æupsideÆ value opportunity in both mine site and adjacent brownfields exploration and an efficient and technically sound mining operation. The contribution of mining geologists to assist in conducting analyst site visits should not be underestimated, particularly with reduced analyst coverage of the resources sector and some simplification in company analysis through ranking companies on Reserve and Resource positions.

Jan 1, 2009

By R. Gray

"Experience from Australia has identified what is referred to as non-conventional surface subsidence behaviour. This occurs under irregular surface topography, resulting in valley closure, valley floor uplift or “upsidence”, and far-field horizontal movements – even occurring beyond conventional “angle of draw” limits. This paper discusses such behaviour recently observed in Pennsylvania and focuses on the 2005 case of Duke Lake Dam in Ryerson Station State Park. In July 2005, there was a significant increase in water leakage through a number of growing cracks in the dam leading to the dam being breached to avoid an uncontrolled failure. An underground longwall mine was located approximately 900ft to the north, mining at depths of 330 – 720ft. Investigations (including a subsequent ground movement monitoring program) found a range of evidence in the vicinity suggesting that valley closure and far-field horizontal movements may have occurred resulting from the adjacent mining. The paper discusses the phenomenon of non-conventional subsidence behaviour and the Ryerson State Park case study, including an assessment of mining, geology and subsidence impacts and suggested ground behavioural mechanisms. INTRODUCTION Non-Conventional Subsidence The conventional understanding of coal mine subsidence on which most current subsidence understanding and prediction techniques are based, includes the concept of angle of draw which effectively limits the lateral extent of subsidence effects and impacts. Within this zone – above and marginally beyond the boundary of mining – downward vertical subsidence is the dominant component, together with localised horizontal movements towards the mined region, with related tilts and strains. However, more recent experience from Australia over the last two or three decades has identified what is referred to as non-conventional surface subsidence behaviour. This is found to occur in areas of irregular surface topography or variable terrain, and is characterised by phenomena such as valley closure, valley floor uplift or upsidence, and far-field horizontal movements, all of which can occur beyond the conventional angle of draw limits. NSW Department of Planning (2008) defined the conditions for both conventional and non-conventional subsidence behaviour as follows: “The conventional or general model of surface subsidence, which finds worldwide acceptance, is based on assuming the following site conditions:"

Jan 1, 2015

Determine the appropriate spacing and alarm levels for carbon monoxide and smoke sensors used for fire detection in underground coal mine conveyor belt entries. Background Fire represents one of the most severe hazards in underground coal mines. Early-warning fire detection in underground coal mines is essential to successfully implement and execute evacuation and control measures. Both carbon monoxide (CO) and smoke sensors have the ability to provide reliable early-warning capability, provided that they are spaced properly and set at the appropriate alarm levels. The U.S. Bureau of Mines conducted a series of large-scale experiments where a small coal fire was used to ignite a conveyor belt at air velocities of 0.76 to 6.1 m/s. The test configuration was purposely designed to model a worst-case fire scenario for fires that develop within conveyor belt entries in underground coal mines. During the tests, CO and smoke levels were continuously measured to determine alarm times and alarm levels as the fire intensity progressed. The data from these tests indicated that for a given sensor spacing, the time to reach a preset alarm threshold depends upon the belt entry air velocity and cross-sectional area. Analysis of this data resulted in the equations and nomographs for CO and smoke sensor spacing, and alarm levels contained in Bureau of Mines RI 9380, "Fire Detection for Conveyor Belt Entries."

Jan 1, 1993

By Arnold E. Lamm

The author addressed a keynote session for all divisions at last October's SME Fall Meeting in Phoenix, Ariz. Discussing the competition from gas, oil, hydroelectric and atomic energy, he said that the market can only be wrested from them "by endeavoring to lower costs far beyond anything we thought possible a few years ago." He saw the rate of return for the industry as "grossly inadequate." Looking ahead, Mr. Lamm saw only a few extremely large generating plants being built. "Purchase of coal for such plants," he said, "will probably be confined to a single source on long-term contracts. Only those coal companies who are able to locate huge reserves, close to adequate cooling water, capable of being mined and transported at the lowest cost in relation to quality, will be able to compete. . . While the market for coal will be very large in terms of tons, it will be most selective and confined to a few transactions of very great magnitude. "Coal offers a proven and tried method of producing energy. The available strippable reserves of Western coal and mineable underground reserves offer the cheapest source of energy available. History will attest that coal has been a steady and stable source of energy. Up until recently, the energy market of the West has had to depend on natural gas which product has had a long and steady price escalation. Statistics show that, where coal is available, the price of gas is quite stable, but where gas is the only available fuel, it has traditionally followed a steady and upward price trend.

Jan 11, 1965

By G. P. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Stress-corrosion cracking (SCC) tests were conducted in the near-neutral pH standard solution, NS4, and in an actual soil solution, using four-point bending at high a stress ratio and low frequency conditions very similar to those of operational pipelines. Pitting incubation appeared first and then pitting initiated and grew in both solutions although there were many more pits on the specimen tested in soil purged with 5% CO2 + 95% N2 than in the specimen tested in NS4 solution purged with the same gas. These observations show that samples in soil solution are more susceptible to pitting than those in NS4 solution. When the pit reached a critical size, the increased stress concentration around the pits, resulted in the transition to a crack.

Jan 1, 2005

By Jorge Munoz Reyes

There are three main oil areas in Bolivia (Fig. 1) although so far only one has yielded petroleum in commercial quantities. The Sub-Andean zone is along the easternmost ranges of the Andes, bordering the large eastern and northeastern lowlands. It extends from the Peruvian frontier, north of Lake Titicaca in a southeasterly direction towards the city of Santa Cruz and from there southward to the Argentine border. This zone forms a belt about 1200 km. long by 100 km. wide, and comprises a series of parallel, very rugged, low ranges. Oil has been known and utilized by the natives in these regions since colonial times, from the large number of seepages, which in modern times have led to the discovery of many fields. The second oil zone of Bolivia lies along the eastern and southern borders of Lake Titicaca, on the Andean high plateau, at an average altitude of 13,000 ft. above sea level. It comprises an area of approximately one million hectares (2,470,000 acres). Several seepages are known here, but little development has taken place, because of the difficulties encountered, as the greater part of the territory is covered by volcanic tuffs and ashes, which conceal the structure underneath. The third area is called the "Central zone," and is in the heart of the country, in the Department of Cochabamba, covering approximately five million hectares (12,350,000 acres). This area consists mainly of broad valleys flanked by low rolling ranges. Natural seepages are not known to exist, but there are secondary evidences of the presence of oil. The outcropping rocks are mainly Paleozoic (Silurian and Devonian sandstones and shales). Albertite and other forms of polymerized petroleum have been found in this region. Of these three main oil areas, only the first one is at present productive on a small commercial scale. This zone, developed almost exclusively by the Standard Oil Co. of Bolivia, a subsidiary of the Standard Oil Co. of New Jersey, is divided from south to north into the following local fields: 1. Bermejo (On the Argentine border) 3. Sanandita 5. Camatindi 2. San Telmo 4. Caigua 6. Machareti

Jan 1, 1935

By R. Hogg

Sintering is a process in which the pore structure of an agglomerated powder is modified. For many applications, it is desirable to be able to control the pore structure in order to optimize such properties as mechanical strength and reactivity (availability and accessibility of solid surfaces to reactant gases, for example). In general, these properties will be determined by the total porosity and the pore size distribution of the agglomerate. In the work described in this paper, a physically realistic mathematical model for the sintering process has been developed. The model is based on the usual assumption that the pore system in an agglomerate can be treated as a network of interconnecting, cylindrical pores of continuously varying size. It is further assumed that the total pore length is conserved during the course of the sintering process. Using standard expressions for the rate of shrinkage of an individual pore, the model can be used to predict the changes in total porosity and pore size distribution as sintering proceeds. Experimental pore size distributions, obtained by mercury intrusion porosimetry, for the sintering of oxides appear to be in general agreement with the predictions of the model.

Jan 1, 1977

By G Noonan, S Thomas, M Limbert

Stuck drill rods (often referred to as bogged rods) in production ‘upholes’ are a common problem in the underground mining industry. Bogged and broken off drill rods have the potential to fall out of the hole without warning, posing a serious hazard to personnel and equipment below.Current industry practice to alleviate this hazard can be to either grout the hole in order to lock the drill rods in place, or to ‘plate over’ the hole with a rock bolt. Each of these operations seriously delays mine production as both require demobilisation of the production drill and mobilisation of alternative personnel and equipment to address the hazard. Both methods have been assessed for safety and efficiency and were found to be expensive, time consuming and in the case of plating over, ineffective.To address the safety and efficiency short-comings of the traditional practices, the long hole plug (LHP) has been developed to safely secure the lost rods in the hole. The LHP when struck by falling drill rods behaves similar to an expansion shell anchor transferring the axial forces from the falling drill rods horizontally into the rock mass. It is installed using standard production drills allowing work to safely continue with little interruption.Extensive testing has been carried out on the LHP in the laboratory and underground at the Rosebery mine on the west coast of Tasmania, Australia. Testing has included static pull testing, full scale drop testing and underground trials.The outcome of this work has proven the LHPs ability to add safety, volume and cost benefits to the Rosebery underground operation and it is currently in use at that site. It enables proven elimination of a common workplace hazard immediately, thus eliminating delay on the mine’s production cycle.CITATION:Thomas, S, Noonan, G and Limbert, M, 2017. Long hole plug – addressing the hazard of bogged rods in ‘upholes’, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 305–310 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By George C. Carter

It was just a little over three years ago that the "Go" button was pushed to start operations on the blending piles at Oro Grande. As is usual with any new installation, there were problems that had to be solved. This paper will concern itself with those problems directly related to quality control. To obtain a consistent outgoing quality level at the most economical level for a finished product requires two main points: 1. Measurement of variations in the process, 2. A method of making a predictable change to adjust for variations. The manufacture of cement requires a relatively high degree of accuracy if a consistent outgoing quality level is to be maintained. The blending piles were our solution to this problem.

Jan 1, 1962

By R. W. Gurry

IN the course of a series of measurements of the rate of diffusion of carbon in austenite at about 960°C. (1760°F.) and 1110°C. (2030°F.), it became necessary to determine carbon concentration when austenite is saturated with graphite, because of indications that the hitherto accepted value of the solubility of graphite in this temperature range is too low. Specimens of carbonyl iron were saturated at temperature in a hydrogen-toluene atmosphere which was in equilibrium with graphite. The carbon content of the steel was measured either by combustion or by the loss of weight after substantially complete decarburization in an atmosphere of hydrogen saturated at room temperature with water vapor. The absence of carbide or graphite as a phase at temperature was demonstrated by microscopic examination of saturated specimens that had been drastically quenched. The mean result of concordant measurements is that gamma iron saturated with respect to graphite contains 1.39 per cent carbon at 957°C. (1755°F.) and 1.89 per cent at 1110°C. (2030°°F.). These two values, plotted along with what appears from the literature to be the best value (0.69 per cent) at the iron-graphite eutectoid temperature (738°C. or 1360°F.), yield a curve that is almost linear, and which, continued upward through a short interval, leads to a limiting solubility of 1.98 per cent at the iron-graphite eutectic temperature1135°C. (2095°F.) instead of the commonly accepted value of about 1.7 per cent. EXPERIMENTAL PROCEDURE The samples of carbonyl iron, with the exception of those for microscopic examination, were cylinders 3.8 cm. long, 0.475 cm. in diameter. They were placed in a graphite holder and suspended in a vertical furnace, the temperature of which was controlled precisely by means of the resistance of the platinum winding.1 In the empty furnace the range of temperature over a distance of 4 cm, at the heat center was 9°C. (16°F.) but at a given location the temperature remained within ±0.5°C. (0.9°F.); it was measured by inserting a platinum-rhodium couple calibrated at the melting point of palladium, 1555°C. Since the presence of the sample probably improved the uniformity of temperature, it was decided to consider the average temperature of the sample to be 3°C. lower than the maximum measured in the empty furnace with the same setting of the controller. Data were obtained in the vicinity of two temperatures, 960°C. (1760°F.) and 1110°C. (2030°F.). The samples for microscopic examination, 2.2 cm. long, 0.475 cm. in diameter, were suspended individually on pure iron wire; for these no temperature correction was applied. The carburizing gas passed into the furnace was dry, oxygen-free hydrogen saturated at room temperature with

Jan 1, 1942