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By Reginald S. Dean

Manganous oxide is readily soluble in concentrated ammonia solutions containing ammonium salts. Lixiviants of ammonia and ammonium carbamate permit ready extraction of manganese from reduced ores and the manganese in such solutions may be precipitated by heating to transform the carbamate to carbonate. THE widespread occurrence of manganese in low grade oxide and carbonate ores not amenable to mechanical concentration has led to extensive investigations of hydrometallurgical methods for producing a pure manganese compound suitable for further treatment. Manganese carbonate is the preferable compound. This product when fully crystalline and of not too fine crystal size is easily filtrable and stable in air. It can be converted to other compounds such as the oxides by heating in air or can be reacted with acids for producing salts. A useful hydrometallurgical process must produce relatively concentrated solutions that can be purified easily, reagents must be cyclically used, and heat requirements must be small. Neither the ammonium sulphate nor sulphur dioxide leaching processes that have been tested extensively fulfill these requirements. Other heretofore proposed processes have obvious limitations and have not been tried on a large scale. The present process is based on the discovery by the writer of a new group of aqueous manganese-ammonia complex solutions highly concentrated in ammonia, which permit rapid solution of manganous oxide to concentrations of 80 to 100 g Mn per liter and from which a fully crystalline, easily filtrable manganese carbonate is precipitated by the addition of carbon dioxide and partial ammonia removal. Although the process may be carried out with many ammonium salts, commercial advantages dictate the use of ammonium carbamate, which is obtained when CO2 is passed into concentrated aqueous solutions of ammonia. If the carbamate is used, the only reagents, ammonia and CO2, are volatile and may therefore be recovered from solutions and residues by heating, thus eliminating washing and extensive evaporation. Impurities are controlled easily as most metal oxides are either insoluble in the lixiviant or fail to precipitate with the manganese carbonate. Others are controlled by sulphide addition. The process has been tested extensively on a small scale on a wide variety of ores, including Three Kids, Artillery Peak, Cuyuna, and Chamberlain, as repre-

Jan 1, 1953

By Reginald S. Dean

Manganous oxide is readily soluble in concentrated ammonia solutions containing ammonium salts. Lixiviants of ammonia and ammonium carbamate permit ready extraction of manganese from reduced ores and the manganese in such solutions may be precipitated by heating to transform the carbamate to carbonate. THE widespread occurrence of manganese in low grade oxide and carbonate ores not amenable to mechanical concentration has led to extensive investigations of hydrometallurgical methods for producing a pure manganese compound suitable for further treatment. Manganese carbonate is the preferable compound. This product when fully crystalline and of not too fine crystal size is easily filtrable and stable in air. It can be converted to other compounds such as the oxides by heating in air or can be reacted with acids for producing salts. A useful hydrometallurgical process must produce relatively concentrated solutions that can be purified easily, reagents must be cyclically used, and heat requirements must be small. Neither the ammonium sulphate nor sulphur dioxide leaching processes that have been tested extensively fulfill these requirements. Other heretofore proposed processes have obvious limitations and have not been tried on a large scale. The present process is based on the discovery by the writer of a new group of aqueous manganese-ammonia complex solutions highly concentrated in ammonia, which permit rapid solution of manganous oxide to concentrations of 80 to 100 g Mn per liter and from which a fully crystalline, easily filtrable manganese carbonate is precipitated by the addition of carbon dioxide and partial ammonia removal. Although the process may be carried out with many ammonium salts, commercial advantages dictate the use of ammonium carbamate, which is obtained when CO2 is passed into concentrated aqueous solutions of ammonia. If the carbamate is used, the only reagents, ammonia and CO2, are volatile and may therefore be recovered from solutions and residues by heating, thus eliminating washing and extensive evaporation. Impurities are controlled easily as most metal oxides are either insoluble in the lixiviant or fail to precipitate with the manganese carbonate. Others are controlled by sulphide addition. The process has been tested extensively on a small scale on a wide variety of ores, including Three Kids, Artillery Peak, Cuyuna, and Chamberlain, as repre-

Jan 1, 1953

By Bruce Macdonald

Operational monitoring of slope stability can be achieved by space based InSAR monitoring platforms. Natural and man-made rock slopes are monitored using a novel stack-based InSAR method that exploits both persistent point scatterers (PS) as well as coherent distributed scatterers (DS) such as areas of pavement and sparsely vegetated surfaces. The new method, Homogenous Distributed Scatterer (HDS)-InSAR identifies InSAR targets by using adaptive multilooking of statistically homogenous pixel neighbourhoods combined with thresholding the differential temporal coherence of each target candidate with respect to its surroundings. HDS-InSAR preserves PS and therefore forms a direct generalization to our proven DualScale-PSI method. The density of HDS exceeds that of PS by more than an order of magnitude often providing essentially continuous coverage over urban and industrial landscapes featuring a mix of infrastructure with mostly bare soils or rock surfaces. The improved coverage enables better definition of surface motion and underlying geology, which will lead to superior interpretation of the geophysical mechanisms causing the surface deformation, e.g. through improved integration with 3D deformation modeling. We illustrate the performance of our new HDS-InSAR method compared to DualScale-PSI using displacement results from Vancouver, Canada; Bingham mine, USA; and the Palabora mine, South Africa.

Jun 1, 2012

By Laurence F. Kelley

This paper is one of a series being prepared by the United States Bureau of Mines on shaft-sinking methods and costs at individual operations in various mining districts of the United States. The methods and costs described herein are those of The Consolidation Coal Co. at one of its operations in the Tug River district, McDowell County, W. Va. ACKNOWLEDGMENT The author is indebted to Frank R. Lyon, vice-president, Thos. G. Fear, general manager of operations, and Chas. Enzian, chief engineer, of The Consolidation Coal Co., for valuable assistance and collaboration in the preparation of this paper. W. A. Cole, manager of the E. J. Longyear Development Co. furnished valuable data on methods and performance averages.

Jan 1, 1932

By Sidney H. Haughton

FOLLOWING the discovery of diamonds in 1870 and the Witwatersrand gold fields in 1886 South Africa changed from a predominantly pastoral country with a scattered white population into a land whose economy came rapidly to be based primarily on mining. The total value of the mineral output of the Union in 1944 was approximately $493,000,000, to which gold contributed 84 per cent. Gold furnished some 33 per cent of the Union Government's total revenue in that year, and approximately half the country's population obtained its livelihood directly or indirectly from the gold mining industry. In any review of the Union's mining activities and in any consideration of the country's future, gold mining must occupy a prominent place. It is generally conceded that the present structure is not properly balanced and that an economy based on a preponderance of a single nonpermanent factor possesses potentialities of serious instability.

Jan 1, 1946

By T. C. Boberg, R. B. Lantz

This paper presents a method for calculating the producing rate of a well as a function of time following steam stimulation. The calculations have proved valuable in both selecting wells for stimulation and in determining optimum treatment sizes. The heat transfer model accounts for cooling of the oil sand by both vertical and radial conduction. Heat losses for any number of productive sands separated by unproductive rock are calculated for the injection. shut-in and production phases of the cycle. The oil rate increase caused by viscosity reduction due to heating is calculated by steady-state radial flow equations. The response of successive cycles of steam injection can also be calculated with this method. Excellent agreement is shown between calculated and actual field results. Also included are the results of several reservoir and process variable studies. The method is best suited for wells producing from a multiplicity of thin sands where the bulk of the stimulated production comes from the unheated reservoir. The flow equations used neglect gravity drainage and saturation changes within the heated region. INTRODUCTION This paper presents a calculation method which can be used to predict the field performance of the cyclic steam stimulation process. The calculation method enables the engineer to select reservoirs that have favorable characteristics for steam stimulation and permits him to determine how much steam must be injected to achieve favorable stimulation. While the calculation represents a considerable simplification of physical reality and the results are subject to numerous assumptions which must be made about the reservoir, it has been found that realistic calculations can be made of individual well performance following steam injection. The duration of the stimulation effect will depend primarily on the rate at which the heated oil sand cools which, in turn, is determined by the rate at which energy is removed from the formation with the produced fluids and conducted from the heated oil sand to unproductive rock. A complete mathematical solution to this problem is a formidable task, and finite difference techniques would undoubtedly have to be used. The calculation method pre- sented here utilizes analytic solutions of simple related heat transfer and fluid flow problems. The method is sufficiently simplified that it can be used as a hand calculation, although the calculations are somewhat lengthy and laborious. For that reason, the analysis was programmed for an IBM 7044 digital computer. Well responses observed at the Quiriquire field in eastern Venezuela&apos; have been matched using this program after making suitable approximations for reservoir and wellbore conditions. One of the most valuable uses of this calculation method is to assess the effect of reservoir and proc-cess variables on the stimulation response. This paper contains results of several studies made of key reservoir and process parameters. Among the most important of these is the influence of prior wellbore permeability damage. If a well is severely damaged prior to stimulation, a higher stimulation response will be observed than if it is undamaged. If a portion of this damage is removed, a permanent rate improvement will occur. THEORY I)ES(:KJJ&apos;TION OF CALCULATION METHOD The process of cyclic steam stimulation is essentially one of reducing oil viscosity around the wellbore by heating for a limited distance out into the formation through the injection of steam. Suitable modifications of the calculation technique presented here can be made so that stimulation of wells by hot gas injection or in situ combustion can also be calculated. A schematic drawing of the heat transfer and fluid flow considerations included in the calculation method is shown in Fig. 1. In brief, the calculation assumes that the oil sand is uniformly and radially invaded by injected steam. For wells producing from several sands, each sand is assumed to be invaded to the same distance radially. In calculating the radius heated rn energy losses from the wellbore and conduction to impermeable rock adjacent to the producing sands are taken into account. After steam injection is stopped, heat conduction continues and oil sands with r < ra cool as previously unheated shale and oil sand at r > r, begin to warm. The effect of warming of oil sand out beyond r, has little effect on the oil production rate compared to the effect of cooling of the oil sand nearer the wellbore than ra. Thus, in computing the oil production rate, an idealized step function temperature distribution in the reservoir is assumed where the original temperature exists for r > rn and where an average elevated temperature exists for r < rn. The average temperature in the oil sand for the region r < rn is computed as a function of

Jan 1, 1967

By Carlos G. Valenzuela

The value generally accepted for stacking-fault energy, of copper has been approximately 40 ergs per sq cm based on Fullman&apos;s2 value for the coherent twin-boundary energy and the assumption that is twice the twin boundary energy However, Thornton and coworkers8 determined that the lower limit of for copper is approximately 60 ergs per sq cm, based on measurements of dislocation-node radii. They suggested that the assumption of = 2t is invalid. It is the purpose of this note to present results which indicate that the values of obtained by measurement of twin-grain boundary intersections and the values obtained by measurement of dislocation-node radii are actually compatible. The most reliable values for of the a brasses, based on electron-microscope observation of dislocation nodes, are probably those values reported by Smallman and Green6 who applied the Siems correction (1961) to data obtained by Howie and Swann.3 These values shown in Fig. 1 give an extrapolated value of approximately 70 ergs per sq cm for pure copper. In the present work, Fullman&apos;s method for determining the stacking-fault energy of copper was extended to the a brasses. High-purity copper (99.999 pet) and high-purity zinc (99.999 pet) were mixed in proportioned amounts and melted in sealed and evacuated quartz tubes. The alloys were homogenized for a week at 750°C and chemically analyzed by means of X-ray fluorescence. These alloys, along with a specimen of pure copper, were rolled to 98 pet reduction and a thickness of 0.009 in., resealed, and annealed for 40 hr at 715°C. Values for the ratio of twin-boundary energy to the grain-boundary energy, it gb, were obtained from measurements of dihedral angles formed at the intersections of twin boundaries and grain boundaries by using Fullman&apos;s2 mechanical analogy of surface tensions acting at the intersection of an annealing twin and a grain boundary. The angles between the twin traces and the grain boundaries were measured for a large number of twin-grain boundary intersections at a magnification of X500 using a rotating mechanical stage on a Reichert metallograph. The rotary stage has a calibrated angle scale with vernier so that measurements can be made to 0.1 deg. The mean twin-grain boundary energy and standard deviation were calculated for copper and each of the brasses by the use of an IBM 7072 computer. It was found that the mean value of gb stabilized after approximately 100 twin-angle measurements. This was determined by plotting the mean against the number of angles measured. Since the measured angles deviate from true dihedral angles, a correction factor for grain orientation, discussed below, was applied. The stacking-fault energy was then calculated from these values and the values of grain-boundary energy derived by Taylor.7 The data obtained are tabulated in Table I. Values for stacking-fault energy are plotted in Fig. 1. The value of gb for the specimen of 1.03 pet Zn is close to the value obtained by Fullman2 for OFHC (99.98 pet) copper, 0.045. It is believed that the purity of the copper affects gb significantly. The 99.999 pet purity Cu used in this investigation yielded a value of yt/ygb, 0.76, which is much higher than that obtained by Fullman. Additional evidence suggesting that the purity of

Jan 1, 1965

By Mostafa Benzaazoua, Emilie Ré, Raphaël Mermillod-Blondin, Hassan Bouzahzah, Jean-François Wilhelmy, University of Québec in Abitibi-Témiscamingue

"We analyzed two copper and lead flotation concentrates from the LaRonde mill using MLA technology (Mineral Liberation Analyzer) to identify the contaminants and to quantify their size and liberation. The MLA mineral quantification was compared with traditional mineralogical techniques (Scanning Electron Microscopy, Optical Microscopy, X-Ray Diffraction and Chemistry). The accuracy of MLA data was then quantify in application to metallurgical decision (mineral identification, mineral quantification, particle sizing and liberation quantification). We prepared five well-known materials from pure minerals and analysed them by MLA. MLA concentrates analyses showed the lead concentrate is mainly contaminated by pyrite and sphalerite. These minerals are liberated above 70 % and present a floatable size around 15 to 35 µm. Surface activation by dissolved lead from galena is therefore assumed for these contaminants. The analyses of the known samples show that mineral quantification and size distribution given by the MLA are consistent with the chemical analyses and the laser particle sizer. The liberation measurement is affected by the stereological effect. Modelling quantifies the overestimation of the particle liberation. Based on the modelling, the stereological shift on liberation should not impact metallurgical conclusions on the concentrate contaminations.INTRODUCTIONTo face the diversity of mineral processing challenges, the process mineralogy includes phase quantification, measurement of mineral size, liberation by exposure and by grade, association, surface contact proportion and texture. In the last decades, two SEM commercial tools emerged: MLA and QEMSCAN R. Both are based on specific combinations of backscattered electrons and X-ray images as well as image analysis routines developed at CANMET (Petruk & Pinard, 1976, Petruk, 1989), CSIRO (Frost, O'Hara, Suddaby, Grant, Reid, Wilson & Zuiderwyk, 1977, Reid, Gottlieb, MacDonald, & Miller, 1984) and JKMRC (Hall, 1977, Gu & Sugden, 1995). Recently, TIMA (TESCAN) and Mineralogic MiningR (ZEISS) supplied automated mineralogy for mining industry (Bouzahzah, Benzaazoua, Graham & Cropp, 2015, Gottlieb & Dosbaba, 2015a). In parallel, home-made routine were developped to resolve mineralogy challenges in mineral process but also in geometallurgy and mining environment (Kahn, Mano, & Tassinari, 2002, Knight, Klassen & Hunt, 2002, Mermillod-Blondin, Benzaazoua, Kongolo, de Donato, Bussiere & Marion, 2011, Hunt & Bradshaw, 2015). SEM mineralogy become essential to operation by setting units on mine sites (MacDonald, Latti, Adair, Bradshaw, & Dunn, 2011, Goergen et al., 2013, Dobbe et al., 2014, Gottlieb & Dosbaba, 2015b)."

Jan 1, 2016

By H. Thomas, I. N. M. Nday

"*Paper written on project work carried out in partial fulfilment of BSc.Eng (Mining Engineering) degreeThe optimization of the cycle time to increase productivity at Ruashi Mining was an on-site project investigation conducted from December 2017 to January 2018. The main objective of the investigation was to determine the actual cycle time components. These comprise the queuing time, loading time, hauling time, and dumping time of ADTs (articulated dump trucks). Data was also collected on two hydraulic shovels to identify where these could be optimized. The actual cycle time obtained was compared to the theoretical cycle time to ascertain the constraints, which affect productivity. By applying Systems Thinking to the cycle time, man-made constraints of the actual cycle time were identified and recommendations to mitigate them suggested to optimize the cycle time. However, rainfall is a natural constraint that adversely affects the actual cycle time, and which cannot be mitigated.In addition, both the theoretical and actual cycle time were analysed, as well as the theoretical and actual productivity for the year 2017. Based on the findings, conclusions and recommendations were made to optimize the cycle time. IntroductionThe aim of the project was to increase Ruashi Mining’s productivity by 39%, from about 7.537 Mt of broken material mined to 12..367 Mt targeted in 2017.BackgroundRuashi Mining is a copper (main commodity), cobalt (by-product), and acid producer located in the Democratic Republic of Congo (DRC), 10 km from the city of Lubumbashi. Figure 1 shows the location of the Ruashi Mining open pit.Ruashi Mining started production in 1911 and in 2005 the mine was registered as a DRC company owned by Metorex Group Limited. In November 2013, the Chinese company Jinchua Group International Resources Co. Ltd. bought a majority stake in the business. Ruashi Mining currently produces 38 000 t of copper and 4400 t of cobalt per annum. The company has contracted NB Mining (a contract mining company) to transport its ore. To optimize the productivity of the mine, considering ore flow delivery at Ruashi Mining, the cycle time is the indicator used in this project. The cycle time components were recorded on site using a stopwatch."

Jul 1, 2019

By Melvin I. Esrig

Lime Cement column stabilization of soft clay and sand in Salt Lake City, Utah and in San Francisco California is described and discussed. Stabilization permitted the construction, in a single stage, of a 14 m MSE wall on "medium" clay in Salt Lake City. It was used to mitigate the potential for liquefaction in San Francisco and to stabilize the Young Bay Mud beneath the BART extension to San Francisco Airport. These applications are described and the field measurements of performance are reported.

Jan 1, 2000

By S. N. Yu

Tele-operation manipulators applied in this paper are systems for the remote handling and management of pyroprocessing related facilities in an Argon cell of the KAERI (Korea Atomic Energy Research Institute). Generally, these kinds of systems are composed of a master-slave system and its peripherals installed along the wall of the cell, with the master transmitting the user?s own motion to the gripper directly. This study introduced various considerations and modifications to improve the remote handling performance. The analysis of an operator&apos;s ability using his/her own upper arm motion range while manipulating the MSM, and considerations of its manipulation margin and the related tool modifications are also included. Finally, the test results of several remote handling tasks are presented, and an adequate operation strategy for the tele-operation system of hot-cell type facilities is proposed.

Aug 1, 2013

By J. M. Bowen, P. Wemyss

"Gold losses to natural carbonaceous matter during cyanide leaching have been investigated for over a century. The variation in the severity of the problem from one ore to another has led to a range of different processes being implemented at different mine sites. Most commercial options utilise one or more of the following processes: roasting, carbon pre-flotation, organic blinding, CIL, chlorine passivation, pressure oxidation, biological passivation, elevated temperature CIL, RIL and thiosulfate. This paper provides a background to identify the most appropriate process or combination of processes for a particular ore. It also presents information on how these processes may be implemented, drawing on information in the literature and from current or recent applications at operations such as the following: Stawell, Kumtor, Penjom, Twin Creeks, Macraes Flat, Kittilä, Fosterville, Inata, Carlin, Goldstrike, and Jerritt Canyon. Various process options have been dismissed, or deemed unsuccessful due to limited knowledge available on the strengths and weaknesses of the different options and their implementation. The authors have collectively been involved in flowsheet development and project implementation in four commercial plants that have treated preg-robbing ores.INTRODUCTION Cyanide processing has been the mainstay of gold recovery for well over a century. It is generally a very effective process with over 90% recovery on free milling ores, but complex and refractory ores may only give 0–50% recovery with conventional processing (La Brooy et al., 1994). People have written about gold losses to natural carbonaceous matter during cyanidation for over a century e.g. Feldtmann, (1915). The earliest reports related to African operations, but the issue has since been reported in Canada, North and South America, Australia, Russia and China. The phenomenon is usually referred to as ‘preg-robbing’ dating from the times before the use of granular activated carbon for gold recovery, when gold was lost from the pregnant solution before it could be separated from the leach solids and recovered by cementation. Many excellent reviews have been published e.g. Dunn et al. (2013), summarising the options considered and where they have been applied commercially."

Jan 1, 2017

By De-qing Geng, Guang-liang Wu

The waste slag generated by the LF refining process of Q345B low alloy hot-rolled steel, still has some refining capabilities. If recycled, it can reduce environmental pollution, and save the economic costs. A research on melting Characteristics of Q345B steel LF refining waste slag was investigated by using orthogonal experimental method, and the effect laws of composition on that were analyzed. Through variance analysis and significance criterion, it is concluded that the optimum ingredient of the regenerated LF refining slag is 25%A12O3, 12%CaF2, 7%MgO and R= (CaO)/ (SiO2) =2.5. And the regression analysis is carried out by using SPSS software, to get the mathematical relationship between ingredient with high reliability and melting temperature of refining slag T=1451.3-6.25CaF2+2.36 R.

Jan 1, 2016

By W. S. Hyler, L. W. Berger, R. I. Jaffee

Hydrogen additions of 390 ppm to A-55 titanium and 368 ppm to Ti-8 pet Mn have no deleterious Hydrogenadditionseffect on the unnotched and notched rotating-beam fatigue properties of these materials. &apos;These amounts of hydrogen, however, are sufficient to cause severe notch-impact thesematerials.embrittlement in A-55 titanium and pronounced loss of tensile ductility in Ti-8 pet Mn. The lack of embrittling effect in fatigue in the latter alloy is consistent with the postulated strain-aging mechanism of hydrogen embrittlement in a-ß alloys. There is a significant strain-agingincrease in the unnotched endurance limit of A-55 titanium with the addition of hydrogen. This increase may be explained as the result of internal heating effects which would dissolve the hydride and cause solid-solution strengthening. TITANIUM and its alloys may be seriously embrittled by relatively small amounts of hydrogen. The form which this embrittlement takes has been shown to vary with alloy type. The a alloys, for example, suffer most strongly from loss of notch-bend impact toughness&apos; when sufficient hydrogen is added, and this effect has generally been associated with the presence of hydride phase in the micro-structure. In a-ß alloys, on the other hand, hydrogen is most detrimental to tensile ductility in slow-speed tests,2-1 and the embrittlement may be detected in a most convincing manner by means of rupture tests at room temperature. This particular kind of embrittlement has not been associated with a change in microstructure, but has been classified rather generally as associated with a strain-aging type of mechanism.&apos; In the present paper, the effect of an embrittling amount of hydrogen on the rotating-beam fatigue properties of both an a and an a-ß titanium alloy is covered. For this study, annealed commercially pure (A-55) titanium was chosen as an a alloy, and equilibrated and stabilized Ti-8 pet Mn as representative of a typical a-ß alloy. Nominal hydrogen levels of 20 and 400 ppm were evaluated, the latter amount having been shown previously to be severely detrimental to the impact toughness of commercially pure titanium and to cause pronounced strain-aging embrittlement in the Ti-8 pet Mn alloy. The only report of the effect of hydrogen on the fatigue properties of titanium is given by Anderson et al.,° in which a push-pull type of fatigue test was conducted on as-received commercial-purity titanium sheet. Much scatter was found in the results, but generally the presence of hydrides slightly decreased the fatigue strength of unnotched specimens in the longitudinal direction. The results of notched tests were masked too greatly by scatter to be significant. Experimental Procedure Preparation of Materials—Analyses of the A-55 titanium and the Ti-8 pet Mn alloy used in this investigation are given in Table I, which indicates the 8 pet Mn alloy to be more nearly a 6 pet Mn alloy. This alloy will be referred to as Ti-8 pet Mn, however, since this is the commercially designated composition. Both alloys were received in the form of5/8-in. diam rod and, after suitable surface preparation, 5-in. lengths were vacuum annealed at 820°C. Half of the rods for each material were then hydrogenated at 820°C to a nominal hydrogen content of 400 ppm. The hydrogenated and vacuum-annealed A-55 rods were hot swaged at 700°C from 5/8-in. diam to 1/4-in. diam, and then annealed 1 hr at 800°C and air cooled prior to preparation into test specimens. Fabrication of the Ti-8 pet Mn alloy was by hot swaging to 3/8-in. diam at 760" and then 1/4-in. diam at 704°C. This material was then annealed 1 hr at 704", followed by furnace cooling to 593"C, and finally air cooling to room temperature. Evaluation—In order to examine more completely the effects of hydrogen on the particular materials studied, slow-speed tensile and notch-bend impact properties were determined in addition to fatigue data. Tensile specimens were of the standard ASTM type with a reduced section of 1/8-in. diam and a gage length of 1/2 in. A subsize cylindrical Izod specimen was used for impact tests. These specimens had a 45" notch with a 0.005-in. radius and a 0.150-in. root diam, and the stress concentration factor of this notch in bending was Kr = 3. Both the ten-

Jan 1, 1959

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng

The recycling of waste tires has been a big environmental problem. About 280 million waste tires are produced annually in the United States and more than 2 billion tires are stockpiled, which cause fire hazards and health issues. Tire rubbers are insoluble elastic high polymer materials. They are not biodegradable and may take hundreds of years to decompose in the natural environment. Microwave irradiation can be a thermal processing method for the decomposition of tire rubbers. In this study, the microwave absorption properties of waste tire at various temperatures are characterized to determine the conditions favorable for the microwave heating of waste tires.

Jan 1, 2015

By Fred Leighton, Wilson Blake

The microseismic method of detecting instability and high-stress zones in underground mines was developed by the U.S. Bureau of Mines (USBM) in the early 1940&apos;s.l,2 For about 25 years this method has been used throughout the world by mining and construction companies in assessing the stability of underground and surface excavations. Rock noises are the release of small amounts of stored strain energy propagating outward from their source as a seismic wave that can be detected with special geophysical equipment. This release of strain energy is caused by a rock mass undergoing load changes resulting in small-scale displacement adjustments such as microcracking, shearing, sliding, and crushing of crystal grains, some even as small as the elastic displacements themselves. No detailed field studies of any of these mechanisms have been made, and knowledge about the origin of rock noises is relatively incomplete. Laboratory tests have shown that when rocks are stressed in a testing machine, the rock noise rate-the number of rock noises generated per unit of time increases with increasing applied stress.3 This increase is most pronounced as the ultimate strength of the rock is approached. The standard field procedure has been to monitor a rock structure at intervals and plot rock noise rates vs. time, thus gaining a semiquantitative estimate of the behavior and stability of the structure. The success of such monitoring, however, has depended almost entirely on the experience and knowledge of the operator, his interpretation of the data, and his equipment. Very little study has been devoted to the basic properties of the vibration record of a rock noise. USBM decided that the microseismic method was being used sufficiently by various mining and construction companies

Jan 1, 1970

By Jay R. Hitchings

A technique that enables excellent color photograph production from black and white negatives of electron microprobe x-ray images is described in this paper. The photographs are made by superimposing one, two or three negatives of black and white x-ray images individually through assigned primary color filters directly onto color print paper. When used to examine metallurgical or geological microstructures, the resulting color photograph provides detailed, qualitative information about spatial arrangements, elemental associations and relative concentrations of at least three elements. The technique is simple and straightforward, requiring only standard darkroom equipment. The use of color to display or present complicated microprobe data also allows a non-technical reader or audience to better understand the data.

Jan 1, 1981

By G. G. Hatch

FOLLOWING World War II there was an urgent need for the development of domestic sources of ilmenite to take care of the expanding needs of the titanium dioxide pigment industry. In addition, there was the interest by the pigment manufucturers and others in titanium metal. Prior to the war the pigment industry in the United States had obtained its major tonnage of ilmenite, analyzing 55- ?60 per cent Ti02, from India. However, as a result of the shipping situation which developed during the war, the pigment manufacturers had to consider the use of lower grades of ilmenite located on this continent .and several companies undertook extensive exploration programmes to locate and develop such orebodies. Probably the most significant deposit that was found as a result of these ?programmes was the orebody .at Allard Lake, Quebec, owned by the Quebec Iron and Titanium Corporation. This ?Company was formed in 1948 by the Kennecott Copper Corporation and the New Jersey Zinc Company to mine this ilmenite ore and treat it in electric furnaces to produce titanium dioxide slag for the pigment industry and iron for the steel industry.

Jan 1, 1956

By David T. Day

IN 1897 I published a proposed explanation t for the variation in color and specific gravity of Pennsylvania oils. A resume of this subject was also presented at the First International Petroleum Congress, in Paris, in 1900. Since that time much experimental work bearing upon this explanation has been carried on by myself, in the United States Geological Survey, and under my direction, by Dr. J. Elliott Gilpin, Marshall P. Cram, and 0. E. Bransky, at the Johns Hopkins University. The experimental results thus accumulated seem to throw considerable additional light upon the variations in color and specific gravity of petroleum, as found in different parts of the world, and also upon the variations in chemical composition. Therefore, it seems as if a, summary of the evidence thus obtained might be of value to those members of the Institute who are interested in the examination of oil-fields. The summary is here presented for that purpose. The phenomenon has often been observed in many oil-fields that oils of different color, specific gravity, and chemical composition may be found within short distances of each other. A conspicuous example of this is the occurrence at Jennings, Welsh, and Anse la Butte, La., of petroleum chemically somewhat similar to Russian petroleum; that is, characterized by the presence of naphthenes. Another characteristic is the presence of considerable percentages of asphaltic compounds, sufficient in quantity to disguise the presence of solid paraffin wax, and perhaps also to render that paraffin wax more soluble * Published by permission of the Director of the United States Geological Survey. 1 Proceedings of the American Philosophical Society of Philadelphia, vol. xxxvi., No. 154, pp. 112 to 115 (January, 1897).

Jun 1, 1910