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Jan 1, 1923

Jan 1, 1923

By John F. Elliott, John P. Hager

The standard free energies of formation of the lowest stable sulfides of chromium, molybdenum, and tungsten in equilibrium with the corresponding metal hazle been determined by reacting the sulfide and metal with H2(g)/H2S(g) mixtures. The reaction is A method for estimating the standard ~nolav entropies and standard entropies of formation at 298°K of the sul-fides of refractory metals is presented. The standard free energies of formation of the lowest sulfides of the metals in group VIa of the periodic table are probably best determined with the reaction* is known with greater accuracy than is that property for any other sulfur-bearing compound or solution which might serve as a reference phase to establish the chemical potential of sulfur for the essential re- However, there still remain significant problems to the use of Reaction [I] in studying these sulfides. First, the equilibrium gas ratios (Ph2S/PH2) are very small, and with the most stable sulfides in the series the ratios tend to be at the limit of the range for precise chemical analysis (10-4); and second, the reaction rate for the formation or reduction of these sulfides appears to be relatively slow. A primary reason for the latter problem is that the gas phase near the equilibrium concentration has very little capacity for transport of sulfur. It is to be noted that the thermo-dynamic properties obtained from the experimental results by Eq. [I] apply for 1 g-atom of sulfur in the metal-saturated compound even though the exact composition of the compound has not been determined. The work reported here is a study of the standard free energies of formation of the lowest sulfides of chromium, molybdenum, and tungsten, and of copper, by Reaction [I]. In planning the experimental program, it was decided that the technique that has been used previously3"' could be used with modification and that an improved analytical method was needed for determining H2S in the gas phase. THE EXPERIMENT The once-through flow of gas was selected in preference to recirculating the gas, a) because of the low sulfur capacity of the gas, b) because of the relatively slow rate of reaction and the danger of the

Jan 1, 1968

By Steven Wright

The reduction of a slag produced 6om the recycling of lead batteries was studied in a kilogram scale laboratory investigation by reacting with graphite at temperatures of 1180 and 1200°C. Simultaneous reduction of PbO, Fe203, Sb203 and As203 occurred with the Sb and As reporting to the metal while the lead content in the slag was above 2 wt%. The Sb and As distributions between metal and slag were strongly affected by temperature and slag oxidation state. The rates of reduction of PbO and Sb203 increased with increasing slag basicity and temperature and decreased as the PbO content in the slag decreased. The reduction rate of PbO from these slags was similar to other industrial lead slags at the same CaO/SiO2 ratio and temperature. The implications of the behavioural similarities of the antimonous slags during reduction with carbonaceous reductants and other lead slags are briefly discussed.

Jan 1, 1994

By C. R. Austin

THE investigation described in this paper deals with the development of high-temperature alloys of the Konel series over a considerable period of time at the Research Laboratories of the Westinghouse Electric and Manufacturing Co. The word "Konel" has been coined to designate a class of alloys which are essentially nickel-cobalt-iron with other elements added, usually in small quantities. Most of these alloys contain titanium, usually about 2.5 percent. The main consideration related to strength at high temperatures but the thermionic characteristics of the alloys was also of considerable importance. It is, however, with the mechanical properties at elevated temperatures that we are herein concerned. Much attention has also been devoted to their age-hardening characteristics. There is little need to stress the utilitarian aspect of this subject, as it has been discussed frequently. Alloys exhibiting superior properties at normal or elevated temperatures rapidly find many suitable applications. There may be some question, however, as to what constitutes a "superior alloy, " or an alloy that may have good service possibilities at high temperatures. The problem is complex and various means have been employed to predict the useful life that may be expected of a material. In recent years the "creep limit" has been used as the best means of evaluation. Such tests necessarily are prolonged and hence collection of data is very slow. In a general survey of many alloys therefore the creep test is not desirable and recourse must be had to much shorter time tests in order more rapidly to select alloys which appear to show promise. For this reason the present survey has been made using the high-temperature tensile test and a bend' test developed by Howard Scott.1 In the tensile test the conditions have been standardized for all tests, so that values obtained are at least comparable, one alloy with another, although the absolute values recorded merely indicate the mechanical properties at the given temperature under a definite rate of loading.

Jan 1, 1931

By J. W. Craig

CHROME ore, which is used in Canada in the production of ferro-alloys, in a variety of refractories, and indirectly in many chemical industries, is both commercially important and scientifically interesting. The sight of chromium metal is familiar to all of us in the home, the office, the automobile. Chromium is synonymous with armaments: it is understood to be one of several essential metals in tanks, which played an important role in the defeat of France in the spring of 1940. Chromium, in other forms, comes into our daily lives by way of paint and leather, of the familiar green ginger-ale and beer bottles, and more indirectly in every pound of steel produced in the .Dominion. Necessary to our civilization in peace and war, the ores of chromium occur in many corners of the earth. This paper attempts to describe the chemical constitution of chrome ores, their world distribution, and the various chrome products and their industrial applications in Canada.

Jan 1, 1940

By Dennis Asmussen

The peatlands of the U.S. and Canadian parts of the Upper Great Lakes region have a long history of modest utilization in agriculture, forestry, horticulture, and as natural undisturbed areas. Only recently have they been assessed as potential sources of non-renewable or renewable energy. This new interest in peatlands, should current proposals be realized, might mean the commitment of millions of acres to energy production purposes. The magnitude alone of this potential utilization of peatland signals the possibility of substantial environmental disturbance, local resource shortages, resource use conflicts, and social and economic change. Peat- land resource managers in the region are just beginning to weigh the advantages and disadvantages of large-scale peatland utilization. The Minnesota Department of Natural Resources has made a considerable effort to study peat resource management issues and will shortly make recommendations to the state legislature regarding utilization alternatives. What follows is a general discussion of peatland utilization and management trends in the region with a focus on Minnesota and its peatland management efforts.

Jan 1, 1980

By Raymond E. Sandiford

"The redevelopment of the World Trade Center (WTC) provided an opportunity for the Port Authority of NY and NJ to complete a long sought underground connection between all of Lower Manhattan’s transit lines, the World Trade Center and the World Financial Center (WFC) (Figure 1). Creating this connection was a challenge because the WFC lies west of the heavily trafficked Route 9A, also known as West Street. The previous connection was a bridge that required pedestrians to make significant level and directional changes to navigate the crossing. The positioning and elevation of the Route 9A pedestrian tunnel was established to provide pedestrians with a clear, single level, climate controlled corridor from the new WTC Transit HUB to escalators leading into the WFC Winter Garden.As the most direct link to the WFC, tens of thousands of people a day will use the pedestrian corridor. To accommodate this large number of pedestrians and provide an obstruction free passage, the tunnel has a clear width of 50 ft (15.2 m). Although only 250 ft (76.2 m) long, that short length presented many technical challenges.Here I describe how the challenges were overcome during the construction. However, some of the truly problematic issues arose from coordinating the phasing of this project with adjacent construction activities at the WTC, the reconstruction of Route 9A, and the WFC’s redevelopment program. The limited access to the excavation areas and confined site logistics were further complicated by having to maintain six lanes of traffic on Route 9A at all times. The efforts were so intertwined that, well into the underpass construction, the Port Authority Construction Department decided to merge a portion of that work into the WFC redevelopment."

Jan 1, 2012

By L. C. Raymond

Good afternoon. I have entitled my talk "Investment for Progress," implying thereby a spark of friendly competition by private enterprise with such government-inspired foreign aid and investment programs as the Alliance for Progress. While the subject of foreign investment is hardly a new one, the perpetual flux of the political and economic surface of this earth we inhabit makes it forever timely and forever interesting. Especially do tremendous opportunities for international investment constantly present themselves to the mineral industry, and just as often must the industry approach these opportunities with a great deal of investigation and caution. This is not to say that the mineral industry--no less than any other industry--should be unenthusiastic about the foreign scene, but like everyone who proposes to put his money where his hope is, it should consider all the factors and weigh the possible disappointments as well as the rewards.

Jan 1, 1964

By R. J. Smith

Tar sand deposits in Utah represent more than 25 billion barrels of in-place bitumen, 96% of the known U.S. reserves. The technological development of a hot water processing strategy for the Canadian tar sands and the commercial Production of synthetic crude oil from this natural resource suggest that similar success may be possible for the utilization of Utah tar sands to provide our country with a new domestic source of synthetic crude oil. In this regard an active research program to develop a hot water processing strategy for Utah tar sands has been sustained at the University of Utah for the past five years. The hot water process for Utah tar sands differs significantly from that used for Canadian, tar sands due to the inherent differences in the respective bitumen viscosities and the nature of the bitumen-sand association. These differences have led to the identification of certain design criteria necessary to achieve satisfactory phase disengagement during digestion. (8,9) Subsequent flotation of the digested tar sand is a subject of current attention and is considered in this contribution for the Asphalt Ridge tar sand deposit. Although contact angle measurements of pure Asphalt Ridge bitumen indicate moderate hydrophobicity, air bubble attachment to the bitumen concentrate taken from a 37 liter flotation cell is not possible. This surprising result suggests that the flotation separation is dependent on air bubble entrapment rather than on attachment due to surface hydrophobicity. The occlusion of air bubbles in the bitumen is apparent from visual examination of the concentrate, especially at lower temperatures. It seems that a bitumen bubble agglomerate forms in the impeller region of the flotation cell, the effective density of which is such to allow the agglomerate to float to the surface. A factorial design of the major operating variables in the flotation separation indicated that the quality of separation was significantly dependent on the flotation temperature and to a lesser extent on the degree of agitation. For a flotation temperature of 77C recovery of 96.7 percent was realized at a grade of 61.0 percent bitumen. The improved separation at higher flotation temperatures was found to be due to the decrease in bitumen viscosity resulting in more effective rejection of coarse sand from the concentrate.

Jan 1, 1980

By J. A. Relf

The construction of refineries and gas conservation plants in the general Edmonton area in the early 1950's made available large quantities of by-product liquified petroleum gases (LPG). These gases, together with discovery of increasing reserves of natural gas in the Edmonton area, provided Canadian Chemical Company with two of the necessities for petrochemical production, namely, available and reasonably priced raw materials and fuel. This paper outlines the development of the $83 million Edmonton plant from its origin, together with a brief description of the processes and some of the interesting features involved. Several economic aspects of the petrochemical industry are high-lighted including its importance to the local community and the province. The paper reviews the relationship between the oil and gas industry and petrochemical manufacturing and indicates some of the factors that may affect the future growth of the petro-chemical industry in Wes tern Canada.

Jan 1, 1962

By Shantanu Chakrabarti, Khursid Alam Khan

"Globally, the use of metallic coated steel sheets in the automobile industry is increasing. The sheet should have excellent formability, weldability, paintability and corrosion resistance. Since bare cold rolled steel sheets have certain limitations, application of galvanized steel sheets is steadily expending. Galvannealed steel sheet fulfills all requirements and has become of major interest in the automobile industry.The success of Galvannealed (GA) steels in the body-in-white depends upon material design and parameters of various processes involved, like cold rolling, continuous annealing, hot dipping and galvannealing. In the present work, powdering resistance, one of the important product characteristics of GA, has been studied and a relation is established between the process parameters and the powdering value. The product obtained through optimization of the process parameters have been successfully used by major automotive producers without any powdering problem, for internal as well as external automotive applications.IntroductionThe present automotive industry demands that steel for the auto components should have excellent formability, weldability, paintability, corrosion resistance etc. In addition to this there is specific requirement for some particular components like high surface quality for skin panels. Corrosion resistance of panels is important requirment which determines the life of the particular component and brand value of the automotive. Among all the zinc based steel coating used in the automotive industry coating produced by Galvannealing process has received most attention because of its excellent weldability along with superior corrosion resistance and better paintability."

Jan 1, 2012

By A. L. Sweetser

EXPERIENCE has shown how difficult it is to obtain information regarding laboratory-tests in connection with the chlorination-process for the extraction of gold from its ores, and I therefore present the following method, somewhat in detail, for the benefit of those who may desire to pursue research work in this field. The ore chosen was a partly-decomposed porphyry, extremely siliceous and comparatively soft, and of an average value per ton of from $25 to $26 in gold and $0.68 in silver. The chemical analysis gave : Fe2O3, 3.35; FeS, 1.5; MnO2, 0.75; ZnCO3, 4; Al2O3, 3.20; H2O, 0.7; SiO2 and insol., 83.50 per cent. The ore, first crushed to pass a 5-mesh screen, was coned and quartered until a 45-lb. sample was obtained. Samples for assay and analysis, taken from this lot by means of riffles, were crushed to pass a 100-mesh screen. The original sample was divided into 10-lb. lots, of which one was crushed to pass a 10-mesh screen; another through a 12-; the third through a 20-, .and the last through a 30-mesh screen. Because of the production of an excessive quantity of fine material it was deemed inexpedient to crush finer than 30-mesh size-a decision the wisdom of which is proved by the data in Table I., showing the increasing ratio of slimes, in proportion as the ore is crushed finer. In order to determine the percentage of fines in the sizes of mesh selected, a weighed sample of ore was taken from each mesh, and a sample from the 10-mesh lot was passed successively through 20-, 40- and 100-mesh screens, and the percentage remaining on each screen determined. This process was repeated with the 12-, 20- and 30-mesh lots, with the results given in Table I.

Sep 1, 1907

By François Robichaud

"The Laronde mill has been in operation since 1988. Actual milling rate ranges from 7,000 to 8,500 mtpd. Laronde uses SAG/ball mill grinding followed by copper and zinc flotation circuits. A cyanidation/Merrill-Crowe process recovers the remaining gold and silver in the flotation tails.In 1999, the carbon in pulp circuit was replaced by a Merrill-Crowe circuit in order to cope with a much higher ratio of silver/gold associated with the discovery of the Penna shaft. Marine type diatomaceous earth was used as filter aid in both clarifier pressure leaf filters and recessed pressure filter presses from 1999 to 2005. In 2005, this filter aid was gradually replaced by alpha-cellulose after several laboratory and plant filtration trials. The selected cellulose is considered to be much less sensitive to parameters such as pH and reagent concentration and have increased clarifier and filter press filtration performance. Also, since cellulose is exothermic, replacing diatomaceous earth with cellulose as filter aid in the filter presses has increased calcining and oxidation rates in the calcining ovens since cellulose is exothermic. Finally, better calcining conditions have resulted in energy and reagent savings at the arc furnaces.This paper describes how the filter aid replacement has contributed to increasing productivity and Net Smelter Return of the refinery while reducing worker’s hazards and operating cost.INTRODUCTIONAll Merrill-Crowe circuits in the world are operated with filter aids. For years, the market for precoat filter aid has been dominated by mineral filter aids such as diatomite and perlite. Flowsheet and equipment selection at the Laronde refinery were performed in the late nineties. At that time, some key parameters of the design criteria had clearly identified marine type diatomaceous earth (DE) as the most successful filter aid. Parameters such as reagent cost and availability, clarity of the filtrate solution and good historical filtration performance in other concentrators had designated DE as the best suited filter aid. Pregnant solution processed in the refinery from its start-up through 2001 was fairly stable in flow rate and reasonable in terms of impurity content (cationic and anionic compounds)."

Jan 1, 2007

By Heinz W. Sternberg

A method for the electrochemical reduction of the benzene ring was developed and applied to the electrochemical reduction of coal. Successive electrochemical reductions of a vitrain from low-volatile bituminous coal in ethylenediamine saturated with lithium chloride resulted in the addition of 53 hydrogens per 100 carbon atoms. Ultimate analyses and pyridine solubility of the vitrain recovered after each reduction showed that hydrogen added at the beginning has a much greater effect on solubility than hydrogen added at a later stage. Surprisingly, the removal of sulfur from the vitrain takes place only after the more reactive aromatic rings are reduced. Nuclear magnetic resonance analysis and average molecular weight determination of the extracts of the reduced vitrain samples, representing about 18 percent of the vitrain, showed that these fractions had 95 percent of their hydrogen content on saturated carbon atoms and an average molecular weight of 800 to 900. A study of the effect of operating variables on current efficiency showed that current efficiency is highest with aluminum as cathode material and with lithium chloride as electrolyte. A substantial increase in current efficiency of difficulty reducible olefinic double bonds was achieved by adding a proton donor. This result is significant in connection with the electrochemical reduction of coal which proceeds from readily reducible aromatic double bonds to difficultly reducible isolated double bonds. It is proposed that reduction is achieved by electrolytically generated and subsequently solvated electrons and hence does not require prior adsorption of the substrate at the electrode surface. This offers a distinct advantage for electrolytic reduction of sparingly or insoluble substrates such as coal.

Jan 1, 1967

By PAUL DYER MERICA

PAUL DYER MERICA, who has been awarded the James Douglas Gold Medal for his achievements in non-ferrous metallurgy, is a Hoosier, having been born at Warsaw, Ind., in 1889. His father, a clergyman and educator, was president of the University of Wyoming from 1908 to 1913. After graduating from the University of Wisconsin in 1908, young Merica (not yet twenty years of age) went to China, where he was professor of chemistry in Chekiang Provincial College, Hangchow, until 1911. He then went to Germany to s t u d y and was fortunate enough to receive his Ph.D. from the University of Berlin just a few months before the outbreak of the World War in 1914. Returning to America, his first position was as special investigator at the En¬gineering Experiment Station of the University of Illinois, but before the year was out he joined the staff of the U. S. Bureau of Standards as associate physicist. Since 1918, he has been superintendent of research for the International Nickel Co. His work during those years is excellently summarized in the following quotation from the statement of Zay Jeffries recommending him for the award.

Jan 1, 1929

By J. L. Morning

During recent years, the Bureau of Mines has conducted an extensive investigation of the materials for making iron and steel. This work includes iron ore concentration, agglomeration, direct reduction of iron ores and concentrates, the production of pure manganese, chromium, and cobalt by electrolytic processes, the production of ferroalloys from low-grade domestic ores, and the development of special alloys to utilize these products. As a part of this general program, a Congressional appropriation allowed the con¬struction of an electric-furnace, semicommercial, ingot-producing plant at Shasta Dam near Redding, Calif. The primary objectives of the pilot plant were to determine the costs and operating problems involved in the production of steel and ferrous alloys in which sponge iron was used as melting stock, and to determine the physical properties of the materials produced. The pilot-plant equipment and the results of sponge iron-melting tests in the basic lined, electric arc furnace have been reported in previous publications.3/4/

Jan 1, 1953

By William P. Blake

THE use of diamonds upon a large scale in drilling rocks, and the substitution to a certain degree of rotary diamond drills for the ordinary steel percussion drills, marks a new era in the art of mining. Since the invention by Leschot of the diamond drill, it has steadily advanced in its utility and range of application, and in the appreciation of miners and engineers. I t must be claimed as one of the many gifts of science to the arts ; and it is, in particular, one of the fruits of the scientific education given at the Ecole Centrale, at Paris. Members are all, doubtless, more or less familiar with the construction of the drill and of the machinery by which it is applied in boring. I t is, therefore, my present purpose only to direct your attention to some recent marked improvements, made by the American Diamond Drill Company, by which the economy and efficiency of the machines have been increased. Form of Bit.-The annular or ring form of the drill-head or bit was, I believe, the earliest; and it is still in use, without essential modification, wherever it is desired to obtain a sample " core" or specimen of the rock traversed. But for mere drilling, regardless ~f the preservation of a test-core, a solid-head bit is preferred, except for very large holes. Until recently, these solid-head bits were made with a pointed cutting face shaped like an obtuse cone. This form was assumed to be the best, being most in accordance with the experience obtained with percussion drills. I t is found, however, that the exact reverse

By A. W. F. Smith, P. B. Prangnell, D. N. Crowther, P. J. Apps

It is well known that the refinement of grain size in metals leads to a significant improvement in important mechanical properties. As part of a European collaborative project, processing schedules have been investigated aimed at producing a homogeneous ultra-fine ferrite and spheroidised carbide aggregate microstructure structure in high carbon (CMn) steels (0.6-1.2wt%C), via conventional 'warm' rolling and innovative Equal Channel Angular Extrusion (ECAE). Suitable deformation schedules were determined from dilatometry and thermo-mechanical Gleeble simulations. Evidence of an ultra-fine ferrite and carbide aggregate microstructure following 'warm' rolling is given. A significant improvement in tensile strength, particularly proof stress (0.2%) was also noted in comparison to material deformed at higher temperatures. Concurrent Equal Channel Angular Extrusion (ECAE) experiments investigated microstructural evolution with incremental strain. Extensive analysis was carried out using various techniques, including high resolution Electron Back Scattered Diffraction (EBSD). Evidence of ferrite grain refinement was noted in a eutectoid composition steel. A sub-micron ferrite structure was observed following high strains (E-3.33) and the mechanical properties exhibit a marked increase in tensile strength.

Jan 1, 2004

By E Kasai, D Maruoka, Y Konno, T Murakami

The iron ore sintering process produces approximately three per cent of carbon dioxide emission in Japan because a large amount of coke breeze is used as the main agglomeration agent. Therefore, its suppression has been required. A promising method is to replace the coke breeze with biomass char and iron-bearing materials. In this study, the effect of the utilisation of metallic iron with coke or palm kernel shell char (PKS char) as an agglomeration agent on its oxidation behaviour was examined by a series of experiments using a sintering simulator. The use of PKS char leads to a larger decrease in the pressure drop difference of the sintering bed compared to the case using coke. Furthermore, the oxidation rate of metallic iron was larger in the case using PKS char together than that using coke. It was considered that the oxidation of metallic iron was promoted because the bed-temperature increased at a faster rate and achieved a higher temperature.

Nov 8, 2021