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By J. -C. Tedenac, C. Colinet, X. Tao, P. Jund, R. Viennois

"We report an ab-initio study of the stability and electronic properties of transition metal silicides in order to study their potential for high temperature thermoelectric applications. We focus on the family M5Si3 (M = Ta, W) which is stable up to about 2000 °C. We first investigate the structural stability of the two compounds and then determine the thermopower of the equilibrium structure using the electronic density of states and Mott’s law. We find that W5Si3 has a relatively large thermopower but probably not sufficient enough for thermoelectric applications.IntroductionIn the search of new sustainable energies, thermogeneration of electricity is one of the promising ways, notably because it is able to produce electricity from different kinds of heat wastes and to its portability. However, despite recent progress in the field, the state-of-the art materials have specificities making their mass-production difficult or even impossible: toxicity (thallium, chalcogen or/and pnictogen based alloys), weak abundance (tellurium based alloys) or cost (germanium or rare-earth based alloys). For all these reasons, finding thermoelectric materials without these drawbacks is vital if we wish to use high temperature thermoelectricity for generating electricity in the near future. Due to their abundance, low cost and low toxicity, transition metal silicides are candidate materials of primary interest and the slightest advance in this field would immediately find an application for the thermogeneration of electricity."

Jan 1, 2011

By Kazuyuki Kakegawa

"Sintered body of lead zirconate titanate (PZT) was prepared through the spark plasma sintering (SPS) technique. When the mixture of raw materials was calcined at 800°C and sintered at 900°C for 10 min. with SPS technique, the sintered body had almost theoretical density but was a mixture of lead titanate (PT) and PZT. When a calcining temperature of 1100°C was employed, sintered body had a single PZT phase but a lower density. High dielectric constant was obtained for a sample calcined at 800°C, sintered with SPS tecbriique and fired again in the air at 1100°C.IntroductionSpark plasma sintering (SPS) is a recently developed technique for sintering metals and ceramics1. The scheme of SPS is shown in Fig. 1. Sample is put in a graphite die in a vacuum chamber. It is pressed and pulse voltage is applied. The electric current heats the die. It is said that the pulse causes a spark-plasma between particles in the sample. Because of the spark- plasma, sample can be sintered at temperatures lower than that in the ordinary sintering by several hundred degrees of Celsius. The sintering period is also very short2Low sintering temperature and short sintering period in SPS technique cause low reaction rate. It is both disadvantage and advantage. In some cases, the reaction cannot be completed under the SPS conditions. If a mixture of several compositions having different properties can be sintered without a compositional change by the diffusion during the sintering, combination of properties, and therefore a design of property will be possible3. The low reaction rate of SPS may enable such combination."

Jan 1, 2000

By John G. Hall

The unstable metal market during 1949, with resulting lower metal prices, has focused every mine operator's attention on the problem of reducing operating costs. Improvement in mining, methods, use of modern mechanical mining equipment, and increasing the efficiency of the labor force are the tools with which we will have to work. Careful planning is necessary to coordinate all phases so that no one phase is overdone. A mine may become over-mechanized if, for instance, capital charges against new equipment exceed the savings in labor costs, or where a large enough tonnage is not produced. The cooperation, of labor is essential to any mechanization program. There have been too many instances where mechanization and improvements have done nothing more than make up for a decrease in labor efficiency, thus bringing the production of labor back to its old standard. The operator has gained little and labor has gained only a "softer job." In any mechanization program there are gains to be had by both the operator and labor. By the efficient application of modern equipment and improved mining methods the operator should gain by decreased costs, and labor may profit by receiving a share of these decreased costs.

Jan 1, 1950

By J. H. Zietsman, M. W. Erwee, Q. G. Reynolds

Pyrometallurgical furnaces, essential for metal extraction, operate at temperatures exceeding 1600°C and represent complex multiphase systems that challenge direct industrial research. Multiphysics models play a key role in shedding light on their intricate behaviours, supporting the refinement of design and operational strategies. Integral to the operation are the tap-holes, which facilitate the removal of molten products and are routinely opened by lancing, a process comparable to the use of a cutting torch, where high temperatures result from oxygen reacting with an iron lance. When the lance pierces the clay, oxygen gas enters the furnace, which could influence the behaviour of the molten material inside. In this work, a multiphase fluid flow model was used to investigate bulk flow dynamics, with a focus on the effects of the lancing process on the inside of the furnace, immediately behind the tap-hole. Incompressible and compressible multiphase fluid solvers were used and compared with respect their performance – the intention was to assess whether using a compressible solver would yield a different solution to the incompressible one. It was concluded that there are negligible disparities in bulk fluid flow behaviour between the solvers for the case studies examined, indicating that solver selection might be less consequential for certain aspects of oxygen lancing.

Apr 16, 2024

By J. Szarkowski

"INTRODUCTION The Butte district of Montana is well-known as one of the biggest historic producers of copper in the world. It is also a classic example of a porphyry Cu-Mo system that has been overprinted by zoned, polymetallic (Cu-Zn-Pb-Ag) lode mineralization. After copper, silver was the next most important metal mined from Butte, with over 700 million ounces of total Ag production between 1880 and the present day. Although many papers have been written on the mineralogy of the early porphyry Cu-Mo mineralization and the high-grade Cu-rich lodes in the center of the district, relatively little information exists on the mineralogy of silver in Butte. The purpose of this paper is to summarize past and present silver production trends for the district, and to combine previously published work with new research to examine the mineralogy of silver in the Butte mining district. BUTTE HISTORIC SILVER PRODUCTION According to a recent USGS compilation1, Butte is one of the most Ag-rich porphyry deposits in the world, both in terms of average Ag grade (8.6 g/ton) and total production + reserves (Fig. 1). It is also the 2nd biggest Ag-producing mining district in the U.S. (after the Couer d’Alene district, Idaho). Annual silver and copper production data for the Butte district, compiled from various sources2,3,4, are summarized in Figure 2. Peak production of Ag and Cu was in 1917. While Ag production gradually declined in the ensuing decades, Cu production remained strong until the years leading up to the closure of the Berkeley Pit in 1982. In 1984, mining of the nearby Continental Pit resumed under a different operator, and continues to the present day. The Continental mine produced an average of 35,000 metric tons Cu and 575,000 oz Ag per year between 1984 and 20044. These figures do not take into account a period of mine closure in 2001-2003 due to an unexpected hike in utility prices. The long-term decline in Ag/Cu ratio of ore mined in Butte (Figure 3) is due to several factors, including: 1) changes in metal prices; 2) a downwards decrease in Ag/Cu ratio of most of the lodes with depth below surface; and 3) a shift in mining methods from selective underground mining of high-grade veins to open-pit mining of the bulk rock."

Jan 1, 2016

By V. K. Chandaliya

N-Methyl-2-pyrollidone (NMP) has already been proven a good solvent for extraction of coal. It is believed that organic components of coal are likely to be dissolved with the solvolytic power of NMP. During dissolution process, original coal also gets disintegrated and thus helps in further extraction. Coal extraction highly depends on temperature, coal to solvent ratio, N-Methyl-2-pyrollidone (NMP) to Ethylenediamine (EDA) ratio and the size of coal particles. The process has been established in the laboratory. There is no reference available beyond lab scale. In present study, we are running a bench scale plant with 40 kg/batch capacity. Design of experiment was done in such a way that the optimum zone of the process gets evaluated for clean coal having low ash with high yield. Bench scale plant trial was conducted based on optimum zone developed during design of experiments (DOE). From the DOE analysis it was observed that feed size and coal to solvent ratio are important parameters for this process. Total 27 experiments (four factors with 3 level of variation) were designed through Box-Behnken model. It was observed that -0.5 mm feed size of coal, 150 °C extraction temperature, 17:1 NMP to EDA ratio, 1:9 coal to solvent ratio was optimum conditions. The results obtained at optimum conditions are 50% clean coal yield with 5% ash.

Sep 1, 2012

By Jian Wang, Kun Li, Hao Wu, Juan Nan

In this paper, in order to solve the problems of low accuracy and slow speed of fire flame recognition, an extreme learning machine (ELM) method based on improved Harris hawks optimization (IHHO) is proposed for fire flame recognition. A novel Harris hawks optimization (HHO) is used to solve the problem of parameter selection of ELM. In order to solve the problem that the original HHO is prone to fall into local optimum, firstly circle mapping is used to initialize the population to solve the problem of uneven distribution and small range of the initial population. Then the formula of escaping energy of HHO is modified to make the population have a large range in the middle and late iterations while gradually decreasing in the whole iteration process. Thus, the exploitation stage in HHO is improved to make the search range smaller near the optimal solution to accelerate the convergence process. Finally, at the end of each iteration, a certain number of individuals are selected to perform Gaussian and Cauchy hybrid mutation to prevent the IHHO from falling into local optimization. Through three groups of experiments, the effectiveness of the proposed IHHO and IHHO-ELM is verified. In experiment 1, the convergence performance of IHHO is significantly better than that of the other remaining algorithms in the test results of six benchmark functions. In experiments 2 and 3 of real fire flame recognition case, IHHO-ELM outperforms other remaining algorithms on the whole and has significant advantages in some indexes.

Jan 17, 2023

By Joel L. Morrison

The preparation of coal-water slurry fuel (CWSF) has the potential to be a commercially viable technology for the coal industry. The technology base required to prepare stable CWSF using grinding circuits has been developed over the past decade and is now being applied to the preparation of CWSF from wet coal fines which are generated during coal beneficiation. When preparing CWSF, the optimum CWSF formulation must be determined to ensure that the fuel will be stable while having acceptable atomization and combustion properties, and the production run must be monitored closely to ensure that the CWSF quality is maintained. This paper describes the CWSF formulation process, CWSF preparation circuits, and some of typical problems encountered in, and solutions to, the transportation and storage of CWSF.

Jan 1, 1993

By Alice V. Peter

Meerschaum or sepiolite is employed principally in tobacco pipes and cigar and cigarette holders, although a few other uses of minor importance are Down. The unique value of a meerschaum pipe is derived from the owner's pleasure in watching the color deepen with smoking and in having the color "set" at the desired shade. The name "meerschaum" (German for "sea foam") is applied because the material, when pure and dry, will float on water. Owing to its resemblance to the porous, bonelike structure of the cuttlefish, or septa, it is also known as sepiolite. There are a few scattered deposits of meerschaum in. the United States which have yielded a small product ion, but the world's supply of the' material is obtained fined principally from Asia Minor, Meerschaum deposits near Eski-Shehir, Turkey, are said to have been worked 2,000 years ago, but commercial exploitation is a development of the last hundred years DESCRIPTION AND PROPERTIES Meerschaum is a hydrous magnesium silicate (H4Mg2Si3010) having the following theoretical analysis: Si02, 60.8 percent; MgO, 27.1 percent; H20, 12.1 percent. It is a soft. (H.2 - 2.5), fine-grained, earthy, white, gray, or yellow material. It is very light weight when pure (specific gravity, 1 to 2) and is highly absorbent. Because of its porosity the proportion of water present in the mineral is affected by the humidity'of the atmosphere. In a moist atmosphere the water content may be as much as 21.7 percent. Then wet the material is soft and somewhat plastic. When dried again it becomes lard and tough. The toughness is especially apparent in some forms that have a fibrous or leathery texture.

Jan 1, 1934

By Richard P. Stahura

During the next five years, there will be a trend toward performing belt cleaner maintenance while the conveyor is in operation. Most mines and industrial sites that use belt conveyors have an in-house safety rule that the belt must be stopped before maintenance work can be performed on any belt-cleaning device. This is a good rule. Most cleaning devices are positioned against the belt with hardware that requires the service technician to reach or climb into the chute to change the cleaning blades. But this simple rule becomes more complicated as production demands require higher conveyor availability and provide fewer conveyor outages. In many cases, today’s conveyors are expected to be available 98% to100% of the time.

Jan 1, 1996

By Nicholas Zabaras, Deep Samanta

"Solidification of metal aluminum and aluminum alloys is modeled on uneven surfaces characterized by sinusoidal curves. Wavelengths and amplitudes of these sinusoidal surfaces are varied to study their effects on processes like solidification, macro-segregation and inverse segregation. Solidification and macro-segregation are modeled using a slightly modified form of a stabilized finite element method developed recently to model high Rayleigh number solidification and porous media flows. For pure metal solidification, the effect of varying amplitudes and wavelengths is observed in heat transfer, fluid-flow ~nd phase change processes. The relative importance of shrinkage driven flow and solutal convection on the redistribution of solute for an alloy solidifying in a rectangular cavity is compared. The analysis is then extended by modifying one of the surfaces to a sinusoid. In this case the effects of varying amplitudes and wavelengths are studied in heat transfer, fluid flow, phase change, macro-segregation and inverse segregation processes.1 IntroductionTransport phenomenon during solidification of alloys is a major cause ofcasting defects such as segregation, micro-voids, hot tears, porosity, internal and surface cracks. Heat flow across metal and mold surfaces directly affects the phase change process and plays an important role in determining freezing conditions within the metal. In alloys, natural convection and shrinkage play an important role in determining the final solute redistribution, macrosegregation and evolution of solid macromorphology. Surface unevenness plays an important role during the early stages of solidification. It influences the heat transfer rate and fluid flow in the melt, which in turn affect the morphology and shape of the solid-liquid interface. The effect of surface unevenness on solute redistribution is important during solidification of alloys, where solute driven flow in the mushy zone is prominent. Thevik and Mo in [7] and [8] used a one dimensional model for studying surface segregation and macrosegregation in alloys under the influence of exudation and solidification shrinkage. Air-gap formation in their model was expressed through a variable convective heat transfer coefficient at the boundary. Tsai et al. in [3] and [4] have modeled macrosegregation in an aluminum-copper alloy driven by shrinkage and solutal convection. They used a single domain model based on mixture theory and solved the transport equations using finite difference methods. Our aim is to model solidification of aluminum followed by macrosegregation and inverse segregation in aluminum-copper alloys on uneven surfaces by finite element methods. These surfaces are modeled as sinusoids characterized by amplitudes, ?s and wavelengths, As, By varying As and ?s, changes in heat transfer, fluid flow, phase-change and macrosegregation are studied."

Jan 1, 2004

By A. S. Haugh

OHSAS 18001 is a series of international standards for occupational health and safety management. It is comprised of two parts, 18001 and 180029. OHSAS 18001 was formulated by international certifying bodies and is based on BS8800 and was first published in 19996,11. OHSAS 18001 was developed to be compatible with ISO 9001 and ISO 14001 in order to facilitate integration of quality, environment, and occupational health and safety management systems5. It is a voluntary standard and the overall aim of OHSAS 18001 is to enable organizations to control their occupational health and safety (OH&S) risks and improve overall health and safety performance5. OHSAS 18001 is widely accepted in the UK, Europe, and Asia, is gaining momentum in North and South America, and it was used as the basis and conforms to the requirements of ANSI/AIHA Z.10-2005: American National Standard for Occupational Health and Safety Management Systems. It defines a set of requirements for an occupational health and safety management system suitable for any kind and size of organization4. Businesses of all sizes are developing and implementing occupational health and safety management systems (OHSMS) that are in compliance with the OHSAS 18001 standard.

Jan 1, 2012

Proposed by outstanding electrochemist and electrometallurgist Prof. Raphael Agladze (191 1- 1989), process of copper and manganese co-electrowinning was enhanced to the pre- electrowinning stages: low,temperature co-leaching of copper and manganese containing materials, and to high-temperature co-roasting of the same materials with consecutive leaching. The report presents results of experimental investigations of the processes mentioned above, as well as results of thermodynamic investigations of co-roasting processes, and co- leaching processes computer modeling.

Jan 1, 1997

By John W. Cahn, John E. Hilliard

Single crystals of copper and silicon-iron were cold rolled in orientations chosen to produce individually the major components of the poly crystalline deformation texture. The orientation dependence of the recrystallization kinetics was studied relative to the primary recrystallization textures of these specimens. It is not possible to rationalize the poly crystalline re crystallized textures on this basis. The results suggest an important role of the interaction of adjacent crystals during the deformation of aggregates. BRICK and Williamson1 first noted evidence that the recrystallization temperature was different for straight-rolled and cross-rolled copper given comparable reductions. Michalak and Hibbard2 investigated quantitatively the effect of rolling procedure on the kinetics of recrystallization of cold-rolled copper and found that material cold-rolled the same amount by straight-pass, cross-pass, and compression-pass techniques developed different deformation and recrystallization textures, different 1-hr recrystallization temperatures, and different recrystallization kinetics. However, the temperature dependence of the rate of recrystallization was essentially the same for all techniques. Similar results were obtained on iron. Dunn and Koh3 in studying the recrystallization textures of cold-rolled silicon-iron single crystals reported large differences in the annealing temperatures and times required to recrystallize specimens of different orientations cold-rolled the same amount. Liu4 and Liu and Hibbard5 utilized the concept of different recrystallization temperatures for different orientations of cold-rolled crystals to rationalize the difference in recrystallization textures found in various face-centered-cubic metals. Their explanation predicted a significant difference in the recrystallization kinetics of deformed (110) [112] crystals as compared to (358) [352] crystals, and, in fact, Liu4 reported evidence that this difference existed at least qualitatively. Verbraak6 who rolled and recrystallized a series of copper single crystals found that the double (112) [111] rolled orientation is related to recrystallized cube texture formation. The effect of rolling intensity on the relative amount of cube component suggests an important role of recrystallization kinetics. Walter and Hibbard7 while trying to relate the behavior of rolled and recrystallized single crystals of silicon-iron to the behavior of polycrystal-line silicon-iron again noted that differences in recrystallization kinetics were necessary to rationalize their results. The purpose of the present investigation was to obtain quantitative kinetic data on the recrystallization of single crystals of both copper and silicon-iron rolled to initial isolated individual orientations corresponding to those found in the polycrystalline deformation textures. These data might indicate the importance of the deformation orientation, i.e. the range of available nuclei, the deformed matrix orientation into which these nuclei grow, and the orientation dependence of their growth rate during primary recrystallization on this texture. I. COPPER Experimental Procedure—A single crystal of 99.98 pet purity copper, grown by the Bridgman technique, was purchased in the form of a bar 1 1/2

Jan 1, 1962

By Ken MacLeod

A development at 83 Queens Road in Melbourne, Australia required construction of a three level basement. The normal geotechnical constraints of excavating adjacent to an existing relatively new building were challenging enough for the complicated soils profile occurring at the site. An additional significant challenge faced by the designers, was the requirement to excavate underneath the entire footprint of an existing heritage listed building, known locally as the Mansion, in the centre of the site. Maintaining the structural integrity of that building was afforded the highest priority during the 10m excavation. This paper describes geotechnical aspects of the analysis, design and construction of the secant retention system adjacent the new building and support of the Mansion enabling the 10m excavation to proceed without causing damage to the structure. The secant wall comprised hard-soft interlocking piles constructed using CFA methods. CFA piles along the length of the Mansion provided short term support, with the building load being transferred to the piles by large steel beams jacked under the building. Survey results confirmed that movements of the retaining wall and also the load bearing piles were minimal and well within design expectations.

Jan 1, 2006

By G. L. Oldright, Virgil Miller, F. K. Shelton, Keck. W. E., Horst Sieg

Potash is one of the principal foods and is necessary for the growth of most vegetables, grains, and fruits. For many years, this country depended entirely upon foreign sources for its supply of potassium compounds. However, during the last 15 years the domestic production of potash has gradually increased, as shown in table 1. 7/ Imports now supply only half of the American market. In 1936, the equivalent of 207,000 tons of K20 was imported, and 210,000 tons was produced domestically. In 1935, domestic consumption was approximately 420,000 tons of potash, a 57 percent increase over that for 1934 and surpassing previous peaks of 1928 and 1930.

Jun 1, 1937

A dedicated tunnel construction version of the Caterpillar 328D LCR compact radius excavator is proving highly productive on the A9 Autoroute construction project near Visp, in Switzerland. It is the first machine of its kind to operate on a Swiss contract and uses a special dedicated front attachment designed and constructed by German Caterpillar dealer Zeppelin. The machine offers a powerful, stable and compact solution for tunneling contractors. A rear overhang of just 305 mm (12 in.) provides a tail swing radius of just 1.9 m (6.2 ft). The 328D LCR is ideal for the restricted working areas within a tunnel construction site. The machine is equipped with the wide tracks from the 330D L conventional crawler excavator, ensuring maximum stability when operating. In addition, the boom mounting has been moved further toward the center of the machine for the tunnel model, creating an increased lift capacity over the front end compared with a standard 325D L. The boom itself features a robust box section construction, with high-strength steels, additional supporting struts and reinforced bearings for maximum durability. All pins have hard-chromium plating for optimum protection against wear. Stick digging force is a powerful 134 kN, with up to 212 kN of bucket digging force available, for maximum penetration in blasted material. The 328D LCR is also equipped with a heavy-duty dozer blade as standard. This ensures outstanding stability when working and providing a useful secondary tool for clearing and leveling within the jobsite. Two 45° tilting mechanisms in the boom construction, allow the boom to be swung to 45° on either side of the machine. So the specially designed attachment linkage provides increased rollback for access to the roof of the tunnel. A Caterpillar CW45S mechanical quick-coupler allows rapid changes between specialist tunneling attachments, standard Caterpillar buckets and a range of Caterpillar work tools. The machine is powered by a Caterpillar C7 diesel engine. This six-cylinder EU Stage IIIA diesel motor [ ] offers 8 percent more power than its predecessor, with 140 kW (190 hp) available at just 1,800 rpm. Caterpillar?s ACERT combustion technology results in lower fuel consumption and reduced exhaust emissions. However, the tunnel machine is also equipped with a diesel particulate filter as standard, to further cut exhaust gases within the tunnel working. The 328D LCR is designed for use in transport tunnels of 6.8 m (22.3 ft) in height. With the tunneling boom in place, the machine has an operating weight of 42,540 kg (93,783 lbs), yet retains a transport height with the tunnel boom of just 3.9 m (12.8 ft). Transport width with 600 mm (23.6 in.) track shoes, is just 3.2 m (10.5 ft). On the A9 tunnel contract, the machine is being used by a consortium of Swiss and Austrian companies working for the canton of Valais? Routes Nationals Construction (RNC) department. The 31.8-km (19.7-mile) A9 Autoroute construction project will connect Sierre in the west and the town of Brig to the east. The tunnel that is bypassing the town of Visp is just one of a number along the mountainous route.

Jan 1, 2009

By Douglas M. Matson, Rongbiao Gu, Christopher San Marchi, Anil Saigal

"Hydrogen embrittles most structural metals, although the form and magnitude of embrittlement depends on the source of the hydrogen as well as the stress in the metal. Hydrogen fuel cell systems typically store gaseous hydrogen fuel at high-pressure, which provides both a source of hydrogen and high stresses in the containment materials. Understanding and measuring the effects of hydrogen on the mechanical properties of common structural metals, especially fatigue properties, is important for safe, long-term operation of such systems. This work explores the use of thermography to efficiently and quantitatively evaluate hydrogen-assisted fatigue of type 304 austenitic stainless steel. In particular, thermographic analysis was used with rotating-beam fatigue testing and shown to provide repeatable results which are in general independent of test cycle frequency while reducing test times by several orders of magnitude. The effects of hydrogen were studied by thermally precharging fatigue test specimens in gaseous hydrogen prior to thermography-assisted fatigue testing and then compared to testing of non-charged specimens. Hydrogen-precharging increased the strength of this type 304 austenitic stainless steel and increased the fatigue life by a factor of about 50-100.IntroductionThe world is facing a severe energy and environmental challenge: how to provide competitive and clean energy for its citizens in light of an escalating global energy demand and concerns over energy supply security, climate change and local air pollution. As a carbon-free energy carrier, hydrogen provides a promising vector for storing and distributing renewable energy. Hydrogen is an important industrial gas that is used extensively in many industries. However, with growing demand for clean energy, hydrogen fuel cell systems are being developed for use in consumer products, such as fuel cell vehicles, which changes the landscape for safe design of high-pressure gaseous hydrogen systems."

Jan 1, 2012

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By Bennett McLaughlin

The Penna Shaft is the deepest single?lift shaft in North America. AGNICO-EAGLE started sinking the Penna shaft in 1995 with a hoisting plant capable of hoisting 1 800 tonnes per day from a 2 240-metre deep shaft. Exploration success at depth lead to the replacement of the existing double drum hoist by another double drum hoist capable of hoisting 7 000 tonnes per day. The use of another double drum hoist, instead of a Blair Multi-Rope winder, to hoist 24,5-tonne skips was only made possible by lowering the safety factor. This paper describes recent experiences at Penna and in South Africa, and examines the possibility of extending the double drum hoisting system to a depth of three kilometres.

May 1, 2003