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By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By K. Marutiram, T. Umadevi, R. Sah, K. Abhishek

Low-grade iron ore received from the West Singhbhum area of Jharkhand state in India was used to develop a beneficiation flow sheet to remove alumina (Al2O3) and silica (SiO2 ) from the ore to get iron (Fe)-rich product for steel plants. Mineral characterization showed that the main mineral constituents present in the head sample are goethite, limonite, hematite, quartz, clay and gibbsite. The head sample contained about 49.2 percent Fe, 8.79 percent alumina and 12.01 percent silica. The received iron ore sample is amenable to upgradation through beneficiation to get pellet grade concentrate. The beneficiation process was established, involving crushing, screening, jigging, spiral separation, size reduction, desliming and magnetic separation. The process showed significant enrichment in Fe values to 63.5 percent Fe in concentrate, from 49.2 percent Fe. From the developed flow sheet, it is possible to obtain pellet grade fines with 63.5 percent Fe, 2.92 percent SiO2 and 2.61 percent Al2O3 with 50.6 percent weight recovery. The overall tailing loss is 49.4 percent with 34.3 percent Fe, 21.28 percent SiO2 and 14.64 percent Al2O3

By K. M. Mayhew, G. D. Barr, T. M. McCoy, C. T. Knilans

"Teck Resources Limited (“Teck”) has developed and extensively tested on a continuous basis the CESL Technology hydrometallurgical process for treating copper and nickel sulphide concentrates, including bulk copper-nickel concentrates. Copper, nickel and cobalt are leached efficiently into solution, utilizing CESL process conditions. Total precious metals including gold, silver, platinum and palladium are recovered from the residue stream via sulphur flotation. This paper describes the CESL Technology testwork on a bulk copper-nickel concentrate derived from Twin Metals Minnesota?s (TMM) deposits within the Duluth complex and evaluates the economic benefits (increased cash flow, increased revenue certainty) and investment criteria (capital cost, payback and cash flow) of incorporating CESL Technology into the staged development of TMM?s deposits.INTRODUCTION Mineral Processing and the Role of Hydromet in the Duluth Complex The Duluth Complex in northern Minnesota, United States (US), represents one of the largest undeveloped accumulations of copper, nickel, gold, and platinum group metals (PGMs) in the world, ranking second in copper and PMs and third in accumulation of nickel. The figure below identifies some of the larger known deposits within the Complex (see Figure 1). Copper, nickel, PM and PGM mineralization within the Duluth Complex is hosted by mafic to ultramafic intrusive rocks that are part of the overall intrusive complex.One of the mineral processing challenges of Cu-Ni-PM-PGM deposits in this Complex is the complicated, polymetallic nature of the mineralization1: copper occurs primarily as chalcopyrite and cubanite with minor occurrence of talnakhite; nickel occurs as pentlandite and refractory nickel oxide/silicates; iron sulphides are present as both pyrrhotite and troilite; and PMs/PGMs occur in both the sulphide matrix as well as discrete minerals. An additional challenge for the Duluth Complex is the ratio between copper and nickel; in most of the identified deposits, copper grade is three to four times greater than the nickel grade, which precludes the production of a simple bulk concentrate due to the lack of a traditional smelting market for a bulk concentrate of this character."

Jan 1, 2017

By Jonathan K. Hrica, Brianna M. Eiter

The ability to identify hazards during a workplace examination is a critical skill for mineworkers to have in order to maintain a safe workplace. While research suggests that being able to successfully recognize hazards requires a complex set of competencies, it is unclear which competencies are most critical to adequately perform a workplace examination. This paper presents a hazard recognition competencies framework as an explanation of the competencies that affect mineworker hazard recognition. To better understand how the industry is selecting and preparing workplace examiners, researchers from the U.S. National Institute for Occupational Safety and Health (NIOSH) interviewed nine health and safety (H&S) professionals at surface stone, sand and gravel mine sites throughout the United States. These interviews verified that the competencies included in the hazard recognition competencies framework agree with perceptions of the interviewed H&S professionals, who also provided validity for the critical role these competencies play. Finally, the results of this study are presented within the context of current NIOSH research findings related to hazard recognition.

By M. T. Ityokumbul

Flotation columns and their variations are increasingly replacing conventional cells in mineral processing circuitry. While the operational characteristics of columns differ from those of conventional cells, the same scale-up methodologies are being employed in design. This practice may be attributed to poor understanding of the factors controlling throughput. The use of tall flotation columns is frequently justified on the requirement for increased particle residence time. It is shown that longer particle residence times in the column cell alone do not translate into increased recoveries. Throughput data from several industrial flotation column installations is presented. An attempt at using dimensional analysis to provide scale-up methodology for the factors controlling column throughput is made.

Jan 1, 1995

By A. Toulet

Mining in Mexico has an immensely long tradition. In his first letter reporting to his sovereigns from Mexico in July 1519, Hernan Cortes wrote, "To our mind it is probable that this land contains as many riches as that from which Solomon is said to have obtained the gold for the temple ... " 1 But not only precious metals drew his attention; in 1524, short of tin needed for casting guns, he found it in Taxco. As an added bonus, those who went to find it "came upon a vein of iron which according to experts is of exceeding richness." 2 Since then, the mines of Mexico have yielded up enormous amounts of mineral and continue to do so. Mexico is one of the ten principal producers of minerals world-wide both in production volume and diversity. 3 Tens of thousands of tons of iron, sulphur, and coal come from its earth annually; it is the world's second largest producer of barite; third of antimony, fluorite, and graphite. 4 Copper, zinc, silver, molybdenum, arsenic and cadmium and others are wrested from its mines. The wealth is there; but maximizing its potential requires investment, technology, and markets that the government cannot itself provide. Thus mining, since the Mexican Revolution severely restricted by both law and policy, today looks to private investment to develop its potential. Beginning in 1989, Mexico's government cautiously moved to liberalize private sector involvement in mining; 5 using the experience gained from these initial regulatory changes, the current new Mining Law was adopted in 1992 6 and new Regulations were promulgated in 1993. 7

Jan 1, 1994

By Dean, R. S.

THE numerous theories of hardening which have been advanced in recent years are all satisfactory in accounting for some of the phenomena observed in hardening metals, but none so far presented account for all of the facts observed. Some years ago one of the authors, R. S. Dean,' presented a theory to account for some of the properties accompanying work hardening. The present paper develops this theory further in the light of recent experimental work and extends it to other forms of hardening. Many of the ideas included have come from the writings and personally communicated thoughts of others. We have attempted to give proper credit in every case, but it is possible that we have not always done so. As an historical basis it is desirable here to review very briefly the hardening theories which have been current. The first comprehensive theory of work-hardening phenomena was due to Sir George Beilby.2 He contributed the idea that with cold work part of the structure of the metal was rendered amorphous and that-it was to this amorphous material that the cold-worked metal owed its difference in properties. According to Beilby's theory this amorphous material was a supercooled liquid and, therefore, had the characteristics of a vitreous material. That such a theory is not capable of explaining the property changes in metals has been repeatedly pointed out. This theory also allowed a slip to take place only once on a given plane, which, as has been pointed out by Jeffries and Archer13 is not consistent with the observed length of an, individual slip and the amount of elongation which can be obtained by wire drawing. The modifications, which have been proposed to this hypothesis to make it coincide with the experimental facts, have to a considerable extent robbed the theory of its clean-cut characteristics. The commonest of these modifications replaces the amorphous phase with an

Jan 1, 1927

By R Fletcher

Pacific Hydro, a leading renewable energy company from Australia, is developing a series of cascading run-of-river hydro electricity projects in the Cachapoal Valley at the base of the Andes Mountains some 100 km south of Santiago in Chile.These projects involve extensive tunnelling and underground works. The first of these projects is called Chacayes (110 MW installed capacity) and is now under construction with Astaldi SpA of Italy and Fe Grande of Chile as the EPC contractor. Astaldi SpA also has an equity stake in the project. It involves 6 km of tunnels between 5 m and 7 m diameter, of which 2.3 km is by tunnel boring machine (TBM) (5 m diameter).This paper outlines the local and regional geology, the scope of the Chacayes project, actual tunnel excavation rates and support, and compares the decision making on Chacayes between a choice of traditional drill and blast excavation versus TBM.The paper also outlines the next project planned to be developed by Pacifi c Hydro in the valley – the 140+MW Nido de Aguila project involving a main tunnel drive of 11 km with two intermediate adits, plus a 388 m shaft and underground powerhouse. The main tunnel drives are likely to be excavated by two hard rock TBMs (5 m diameter) but will need to be able to withstand high overburden pressures of up to 1300 m.Subsequent projects in the planning stages include the downstream Coya II project with two tunnels totalling approximately 10 km, one of which may be by TBM.

Mar 8, 2011

By B. J. Sauer

Misapplication of AC induction motors for mine crusher and mill applications has long been a frustration for both the driven equipment supplier and the mine operator. Proper selection of AC induction motors is critical to providing efficient production. This paper focuses on the selection of AC induction motors for gyratory crusher, cone crusher, and grinding mill applications. The criteria for motor selection includes: proper enclosure, driven equipment torque requirements, bearing life, temperature rise, starting requirements, ambient temperature, altitude and accessory requirements.

Jan 1, 1999

By Charles Himrod

In presenting this paper it is not intended to enter into any discussion of the theory of the blast-furnace, but simply to give the results of a number of determinations of CO and CO 2 in furnace gases, and some conclusions arrived at, and the result of an experiment made in hopes of increasing the production of CO 2. In the first table, on page 198, is given the averages of a number of analyses of gases of different furnaces, and in the second, of two stacks of different sizes under varying circumstances. The conclusions arrived at as to what influences the production of CO2 are as follows: lst,. Kind of fuel. Bituminous coal not permitting the formation of as much CO, as coke. 2d. Kind of ores. Rolling-mill cinder being much less favorable to formation of CO2 than hematite ores, magnetites probably less than hematites, but more than cinder. 3d. Length of time of contact of gases with ore. Small furnaces and too rapid driving both waste fuel by riot allowing enough time for conversion of CO into CO2. 4th. The temperature of blast. The hotter the greater the quantity of CO2. 5th. Regularity of passage of stock through the furnace. The hanging and dropping of the stock, however slight, seems to pack it more solidly in the hearth, increases the resistance to the blast, and decreases the quantity of CO2. These are the most common causes noticed which influence the production of CO2, unless we except the one that might be considered the greatest of all, the one that has spoiled so many tons of iron, and the amiability of so many furnacemen, the one most dreaded, the great unknown. It would seem a self-evident proposition that the better the contact of the gases with the ore and the less with the fuel, the greater would be the amount of CO2 produced. To prolong the contact of gas with the ore furnaces are enlarged with advantage, and pains are taken to charge the stock in such a manner as will best promote it. Still, with furnaces of most approved construction and most skilful manipulation, the gases leave the furnace so rich in CO, that not half the heating power of the fuel is obtained, and the highest

By E. M. Frost

"A new apparatus has been devised for quickly and precisely analyzing natural gas for its helium content. The following outstanding advantages make it far superior to any equipment now available for the purpose.3/4/5/6/1. It enables more rapid determinations to be made.2. It has far greater sensitivity than previous apparatus. 3. It is portable.Fifty or more samples may be analyzed in an 8-hour day with the new apparatus and procedure. A maximum of about 10 samples per day could be analyzed with previous apparatus. In the apparatus described, the volume of pure helium obtained from a sample is determined by measuring the pressures created by that pure helium when it is expanded into a constant calibrated volume. In older methods the pure helium separated from a sample is pumped into a burette and measured at atmospheric pressure. The new apparatus and Procedure used with it reduce the average time for an analysis from about 40 minutes to less than 10 minutes,Samples containing a few thousandths of a percent helium may be analyzed as readily as samples containing 1 percent or more, This was not possible with former apparatus. Duplicate samples containing a few thousandths of a percent helium have been analyzed, results checking to one ten-thousandth of a percent. Attempts to measure a corresponding volume of helium in a burette at atmospheric pressure become futile. The ability to determine very small quantities of helium has become of great importance recently in gas- and oil-field engineering studies such Os the utilization of helium as a tracer gas in following the movement of gases through underground structures.A complete apparatus was recently carried more than a thousand miles in a passenger automobile. It arrived without breakage, was .set up and ready to make an analysis in a few hours. .Former apparatus was not portable. The portability of the present apparatus permits taking the apparatus to the field for more efficient prosecution of field engineering problems. The only services required in the field are electricity, tap water, and a source of liquid air or liquid nitrogen.The principle involved is based upon the fact that large volumes of all the constituents usually found in natural gas, except helium, are adsorbed quantitatively on cocoanut charcoal that has been cooled to the temperatures of liquid air. A volume of sample is measured and transferred to a tube of cocoanut charcoal maintained at the temperature of liquid air. After adsorption of all the constituents other than helium, the charcoal tube is connected to a sensitive pressure-measuring device, and the Percentage helium originally in the sample is calculated from two pressure readings and the volume of the original sample."

Jun 1, 1946

By Kota Nakashima

Residues from titanium smelting tend to contain scandium. The scandiumis discarded because no suitable process exists for its recovery from the residue. Valuable-metal recovery from discharged residue is critical for environmental conservation and to achieve a sustainable society. Since 2015, JXNippon Mining&Metals has been developing a process for scandium recovery from the residue of a titaniumsmelting process. The process consists of the following steps: scandium concentrating by classification or neutralization, selective scandium leaching, impurity removal by neutralization, solvent extraction of scandium by using D2EHPA, purification, and roasting. We optimized the above steps to achieve an effective process to obtain scandium oxide (Sc2O3). In this paper, we introduce results from the bench-scale test of the scandium recovery flowsheet developed by JX Nippon Mining & Metals.

By P Crittenden

Thiess Pty LtdÆs Australian Mining business unit used 7.6 PJ of energy in the 2007/2008 financial year. This represented more than 85 per cent of Thiess Pty LtdÆs total energy use and therefore meant that the Australian Mining business unit is required to conduct energy efficiency assessments and report publicly on the outcomes by December 2008 under the Federal GovernmentÆs Energy Efficiency Opportunities (EEO) Act. Thiess Pty Ltd has a policy commitment to sustainable development throughout its operations. This includes minimisation of its carbon footprint and the Australian Mining business unit has a strong focus on efficiency in all of its operations. It approached the energy efficiency assessment as an opportunity to further improve and build on its energy efficiency and greenhouse gas reduction focus in the business. As a mine contractor, Thiess faced a number of challenges in designing an assessment process that would be both effective and efficient to deliver. For example, unlike most other companies involved in the Energy Efficiency Opportunities program, the energy use associated with the Australian Mining business unit is not fixed to any single geographic location in Australia. Mining vehicles are moved from site to site according to the specific requirements of mine owners and the timing associated with the commencement and completion of contracts. Thiess departed from a traditional æsite by siteÆ based assessment and designed a ærepresentative assessmentÆ approach that involved detailed investigation of data across all sites and a focused assessment on a single site.Data and analysis was an essential part of the assessment and indicators at company, mine and site level were essential in identifying opportunities and tracking progress. Forty-six potential energy saving opportunities were identified and four of these are currently being implemented. The projects being implemented are: payload management, automating mobile lighting equipment, plant idle time management, and turbo idle downtime. The potential savings from the four major projects that have been identified are approximately 150 800 GJ/annum, equivalent to 10 600 tonnes of CO2-e/annum with a simple payback period of less than two years. Beyond the fuel savings however, there are a number of other benefits from the assessment, including operational efficiency, reduced maintenance costs and even a potential reduction in the number of vehicles required to complete the work. The EEO assessment has significantly increased the importance and urgency of energy efficiency and facilitated the sharing of good practice across all Thiess operations. Not only have four projects been adopted for immediate implementation but a further pipeline of projects is available for future possible implementation. This case study describes: how Thiess conducted its assessment including the use of energy data and indicators, the opportunities identified that are currently being implemented, and the lessons learnt and how other organisations can use these to improve their approach to energy efficiency assessments. This case study is a more comprehensive version of a case study developed for the Commonwealth Department of Resources, Energy and Tourism. The assessment results reported in this case study are drawn from the Thiess Energy Efficiency Opportunities Report 2008.

Jan 1, 2009

By J. E. Pahlman

Spontaneous oxidation and combustion of sulfides and resultant fires are serious problems in underground mines. The Bureau of Mines has con-ducted fundamental thermal gravimetric analysis (TGA) research to deter-mine the mechanisms and factors governing the rate of low-temperature pyrite oxidation, and to identify possible inhibitors to spontaneous oxidation and combustion. The mechanism of low-temperature pyrite oxidation was found to be topochemical, meaning that the oxidation process is controlled by the chemical reaction at the interface between pyrite (FeS2) and iron sulfate (FeS04)' An activation energy of 8.9 kcal/mol FeS2 was obtained for oxidation of minus 500-mesh pyrite in an atmosphere of 60 vol pct water vapor and 40 vol pct . Water-vapor content of the atmosphere was found to be the critical factor in the rate of spontaneous oxidation of pyrite, with a water-vapor content greater than 20 vol pct needed for accelerated oxidation. An atmosphere of pure oxygen resulted in negligible oxidation. The rate of pyrite oxidation is also greatly affected by the particle size of pyrite. Pyrite-oxidation rate increased drastically for particles less than 40 ~m. Room-temperature pyrophoric behavior was observed for freshly ground unoxidized pyrite (55 pct minus 5 ~m) upon exposure to air. Addition of water-adsorbing materials such as activated alumina (Alz03) decreased the rate of pyrite oxidation.

Jan 1, 1986

By H. A. Johansen

Recent advances in the metallurgy of chromium have enabled this metal to begin to take its place among the refractory metals. Considerable work is being done on the development of high-temperature alloys containing high percentages of chromium.1/2/ In spite of the relatively large amount of work done on these alloys, little is known of the properties of the pure metal. Information in the literature concerning the tensile properties of pure chromium metal is quite scant. This deficiency maybe explained by the great difficulty of preparing test specimens from such a brittle material, resulting in many losses in each phase of the specimen preparation and testing procedure.

Jan 1, 1954

By C. P. Fang, V. A. Marple, K. L. Rubow, P. H. McMurry

"It has been known for some time that sizes of aqueous particles may be affected by flow-induced relative humidity (RH) changes. The RH of air flowing through an impactor decreases as a result of pressure drop through the impactor and increases because of aerodynamic cooling within the high-speed jets, as illustrated in Figure 1. Because the sizes of aqueous particles depend on RH, the impaction stage on which such particles are collected may be different from the stage where they ought to be col¬lected, based on the particle size at the sampler inlet.Fuchs (1980) reviewed literature on water vapor condensation in impactors. The reviewed impactors operated at jet velocities of 100-250 m/s. Particle size increases ow¬ing to water vapor condensation were found in all cases. In one case (Khorguani et al., 1970), it was found that very small droplets (Dp <_ 0.02 um) containing sodium chloride and silver iodide were collected in an impactor with a cut point of 0.32 µm and a jet velocity of 100 m/s. Fuchs believed that such particles could not be captured in an impactor without having been enlarged by condensation. Winkler (1974) sampled at¬mospheric dust with a rectangular nozzle impactor that had a nozzle cross section of 0.3 x 15 mm, a cut size of 0.4 um, and an average jet velocity of 100 m/s. No adhesive was used on the impaction plate. The collection efficiency increased as air humidity was increased from 20% to 100%. The effect was especially noticeable in the increased collection efficiency for hygroscopic particles, and was attributed to condensation.Extensive theoretical and experimental research work on the distortion of the particle size distributions in impactors was done by Biswas and coworkers (1985, 1987). The impactors employed in the study were a low-pressure impactor with high jet velocity stages (Hering et al., 1978, 1979) and a conventional six-stage impactor, Sierra's model 226, operated in the incompressible regime. Ammonium sulfate aerosols were chosen for the study. In the low-pressure impactor, an orifice operating at a Mach number of 1 causes a sudden pressure drop, significantly reducing the RH in the next two stages (stages 5 and 6). This results in a 0.15-um diameter ammonium sulfate droplet shrinking to about 0.07 um at stage 5 when the inlet RH is 95%. In stage 7, the tempera¬ture drop is considerable because the jet speed is sonic. For an inlet RH of 95%, a 0.03 um droplet grows to about 0.06 um. However, the same size droplet at an inlet RH of 25% grows to only 0.04 um. For the Sierra model 226 cascade impactor that is operated with a Mach number of 0.27 at the last stage (stage VI), it was found that for an inlet RH of about 67%, particle growth would occur in stage VI. At 80% RH, both stages V and VI were affected. Biswas et al. (1987) stated that Mach number alone does not determine the size biasing; the type of aerosol, the inlet conditions, the temperature and pressure ratio, and the impactor geometry (throat length, jet-to-plate distance, etc.) must be considered for each stage in evaluating the distortion of the particle size distribution."

Mar 1, 1992

By Victor E. Kral

The Valery fluorspar deposit , also known as the Hamilton deposit , is northeast of Lovelock and 4 miles by poor dirt road east of U. S. Highway 40 . It is in the Humboldt Mining District , on the west side of the Humboldt Range , at an altitude of 6,000 to 6,500 feet . The property was examined by the Bureau of Mines on February 83/ and April 8 , 1944.4/ The last examination was made with an engineer of the Geological Survey.5/ Exploring by means of trenches , cuts , shaft sinking , coyote holes off the shaft , and a small amount of prospecting with short drill holes , was begun in January 1945 and was completed June 30 , 1945. An engineer6/ of the Geological Survey visited the property in April and again in June 1945 to complete a topographic map of the area and to note the results of exploration by the Bureau of Mines . Only minor surface exploring had been done on fluorspar occurrences previous to the Bureau's work . No mining equipment or living facilities are on the property .

Feb 1, 1947

By E. Watkins, S. J. Schatzel, V. Gangrade, R. Kimutis, J. Addis, C. Hollerich

The recent shale gas revolution in the United States has led to the drilling of hundreds of unconventional shale gas wells in active and future coal reserves in traditional coal-mining regions of Pennsylvania, West Virginia, and Ohio. This paper summarizes the impact of a shale gas well breach on the mine ventilation system of an operating longwall panel. This study utilizes a 1:30 scaled Longwall Instrumented Aerodynamic Model (LIAM) to simulate a single-panel longwall operation. The LIAM will be utilized to identify flow pathways and distribution patterns of gas from breached gas well scenarios in an operating longwall in the Pittsburgh Coal Seam. Sulfur hexafluoride (SF6) tracer gas is utilized to simulate a breached gas well. Preliminary findings suggest that the breached gas is diluted to regulatory levels and does not accumulate in the mine entries or in the longwall gob when the longwall panel is adequately ventilated. Overall, this study characterizes the potential interaction between shale gas wells and the mine environment in the event of a gas well breach, which provides critical information to the industry and regulatory agencies for improving safety, health, and welfare of miners.

Mar 2, 2022

By William P. Blake

The importance to the growing steel industry of the United States of a domestic supply of ferro-manganese or "spiegel" of a high grade, induces me to bring to your notice some details of the method by which a superior article is produced in the Austro-Hungarian Empire. At Reschitza, Hungary, and probably at Laibach also (the Krainische Industrie Gesellschaft), ferro-manganese is made in a blastfurnace, with charcoal as fuel, and limestone as the flux. The ore is a ferruginous mixture, containing about 37 per cent. of sesquioxide of manganese. It is silicious, and somewhat, resembles, in its appearance, the manganese ore from Red Island, in the Bay of San Francisco, California. It contains about 29 per cent. of silica and some alumina, shown by the subjoined analysis:

By Vinod K. Sikka, René Cooper

"Cohoes, New York 12047 Intermetallics are an attractive class of advanced materials. The aluminide intermetallics offer advantages including: (1) lower density, (2) oxidation resistance, (3) carburization resistance, and (4) interesting mechanical properties because of their ordered crystal structure. Even though the attractive properties of the aluminides and other intermetallics have been known for nearly four decades, their practical applications have not been developed for two reasons: (1) the poor ductility (in some cases, both ambient and high temperatures) and (2) the lack of processability into meaningful components. Recent advances such as ductilization of Ni3Al by small additions of boron and the knowledge that environmental effects are the major cause of poor ductility in Fe3Al and FeAl systems have brought the intelmetallics into the forefront of research and their commercial applications. This paper has described a method for melting Ni3AI-based alloys that successfully utilize the exotherrn for the formation of NiAl from the elemental materials. The reaction-synthesis method has also been utilized for the production of NiAI and NiAI-based alloy powders from the elemental powders. The reaction-synthesized powders of NiAI and NiAI-based alloys were consolidated by hot extrusion and evaluated for tensile properties over a temperature range from room temperature to 1050ºC. The powder-processing conditions have been found to have more influence on the ductile-to-brittle transition temperature of NiAI than the powder-production method.IntroductionIntermetallics are an attractive class of advanced materials [1-11]. The alum in ide interrnetallics offer advantages including: (1) lower density, (2) oxidation resistance, (3) carburization resistance, and (4) interesting mechanical properties because of their ordered crystal structure. Even though the attractive properties of the aluminides and other interrnetallics have been known for nearly four decades, their practical applications have not been developed for two reasons: (I) the poor ductility (in some cases, both ambient and high temperatures) and (2) the lack of processability into meaningful components. Recent advances such as ductilization of Ni3Al by small additions of boron and the knowledge that environmental effects are the major cause of poor ductility in Fe3Al and FeAl systems have brought the intermetallics into the forefront of research and their commercial applications. The paper will briefly review the processing techniques being pursued for the commercial applications of Ni3Al-based intermetallics. The major emphasis of the paper will deal with synthesis of Ni3Al and NiAI intelmetallics."

Jan 1, 1994