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By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By Jason Ganley, Yingjia Liu, Adam Dekich, William Tilson, Jeffrey Fergus, Dileep Kumar CJ

"Manganese cobalt spinel oxide coatings have been shown to be effective for preventing chromium volatilization from interconnect alloys, and the associated cathode poisoning, in solid oxide fuel cells. During high temperature exposure a reaction layer consisting of chromium containing spine! forms due to reaction with the chromia scale formed on the alloy. The electrical conductivity of this reaction layer is much lower than that of the coating material and thus can increase the overall area specific resistance (ASR) of the system. The approaches to reducing the ASR are to reduce the thickness and/or increase the electrical conductivity of the reaction layer, which includes both the high-chromium spinel phase and the chromia scale. In this paper the effects of transition metal dopants on the amount and properties of reaction products formed during the reaction of spine! oxide coating materials with chromia are presented.IntroductionThe high cost and difficulties involved with the processing of chromia based ceramic interconnect materials for SOFCs are driving the search for metallic interconnects [1, 2]. The reduction in the operating temperature of SOFC has allowed for the use of high chromium alloy steels for this application [3]. However, the volatilization of chromium from the chromia scale, and the associated poisoning of the cathode, remains a problem which needs to be addressed [ 4]. Though the application of manganese cobalt oxide spine! coatings on the alloy surface substantially reduces chromium poisoning of the cathode [5], the low electrical conductivity of the reaction layer formed between the chromia scale and coating affects the performance of interconnect. Incorporating transition metal ions in the reaction layer could alter the electrical characteristics and improve the performance. Copper and nickel doped manganese oxide spinels are widely used as thermistors due to their high electrical conductivity and negative temperature co-efficient of resistance characteristics [ 6, 7]. Hence doping of copper and nickel in manganese-cobalt spine! oxide composition may improve the electrical characteristics of interaction layer as well and is attempted here."

Jan 1, 2012

By Earl Oliver

SEVERAL notable papers, and free discussion on many controversial subjects, marked the various sessions of the Petroleum Division at the annual meeting. The Division first convened on Tuesday afternoon, Feb. 16, and wound up with a dinner and technical meeting on Thursday night. H. C. Fowler presided at the opening session, which was devoted to problems of engineering research and production engineering. Joseph Chalmers abstracted his paper on the flow of air and gas through porous media, in the preparation of which E. L Rawlins and D. B. Talia-ferro contributed. G. H. Fancher told how much he and his associates at Pennsylvania State College were interested in this field, and described the problems they had met in conducting test work. He made a plea for standardization of testing methods. Mr. Fowler then read an abstract of written discussion by Professor Barb, which was followed by discussion by Dr. Fancher and Mr. Chalmers of technical points in connection with the Chalmers' paper. H. H. Hill abstracted written discussion from Messrs. Wilde and Moore, of the Humble company. The second paper, by K. B. Nowels, on computing pressure drop in the pipe of flowing oil wells, was abstracted by the author. Messrs. Blair Smith, G. W. Coggeshall, and I. I. Gardescu participated in the discussion, and the chairman abstracted written discussion prepared by Mr. Rawlins. Most of this had to do with the viscosity of gas¬oil mixtures, on which subject Mr. Nowels said there was great need of accurate technical information.

Jan 1, 1932

By McKenzie P

The techniques of geological control developed by the Coal Geology Sections of the Broken Hill Proprietary Company Limited and Australian Iron and Steel Proprietary Limited in providing geological service in the coilieries operated by these associated companies cover the provision of geological control for both planning and production in each of which the significance of geology has in the past been only poorly appreciated by the coal mining industry.While the adoption of similar techniques is well within the capacity of major companies there is considerable scope for the development of government geological services providing specialized assistance of this nature for smaller scale producers.INTRODUCTIONThe coal mining industry in Australia can instance many notable mistakes caused by failure to obtain sufficient geological information or by incorrect interpretation of available geological evidence both before the commencement of mining and during the progress of operations. Substantial development undertaken in, areas with insufficient or inferior coal reserves, difficult mining conditions caused by failure to adjust operations to geological circumstances, and the irregular development of mine workings caused by unexpected geological features, all bear witness to the lack of geological foresight by the industry.Along with the more widespread general use of applied geology, an increasing acceptance has developed during the past ten years of the valuable contribution which can be made by this science to the exploitation of coalfields. In spite of the advances which have been made, there is still a wide scope for further detailed application of geology throughout the coal mining industry in Australia.

Jan 1, 1963

By M. Duncan

Lightweight, high-pressure cylinders for compressed hydrogen storage are essential components for fuel cell vehicles. Storage volume and mass are two key considerations. Current on-board hydrogen storage systems are based on a maximum pressure of 350 bar. While 350 bar systems are excellent solutions for many applications, some situations require higher storage densities due to space restrictions. As a result, significant research and development work has been expended by cylinder manufacturers, systems providers, testing agencies and automotive manufacturers to develop 700 bar systems with reduced storage volumes. Dynetek Industries Ltd. has proactively developed several 700 bar storage cylinders based on a seamless aluminum liner over wrapped with a carbon fiber composite. This paper presents the challenges and processes involved in the design, testing and certification for Dynetek Industries Ltd. 700 bar cylinders. This paper also provides reasoning for further volume and mass optimization of compressed hydrogen cylinders through the establishment of realistic cylinder usage parameters in standards. In particular, the overly conservative fill life requirement for cylinders is examined.

Jan 1, 2005

Mining is both a high risk and a long term business. This is dramatically illustrated by the fact that, on average, the explorer will expend over $30 million in a ten year period for each significant economic discovery. The time required to complete the exploration process is one of the most substantial commitments made by any mining company. For example the time lag between the implementation of an exploration programme and an economic discovery is variously estimated to take two to ten years. The ore definition phase following discovery currently takes between two and five years while subsequent mine development may take one to two years in easy situations and up to 8 in difficult environments. In most countries the critical path through the early stages is determined largely by technical considerations but in almost all countries the path through the later phases is dictated by the plethora of permits, licences and community involvement steps.

Jan 1, 1982

By F. R. A. Jorgenson

The ignition of chalcopyrite and pyrite was studied using laminar flow furnace and thermal analysis techniques which were supported by XRD and optical microscopic examination of the products. In air, chalcopyrite and pyrite ignited at temperatures of 400-500'C and 500-600?C respectively. The phase assemblages predicted from thermodynamic analyses were compared with those found by experiment, and the onset of ignition was correlated against changes in the phase compositions. Pyrite and chalcopyrite ignited when pyrrhotite and intermediate solid solution formed thus opening up the structure and allowing ready access of oxygen.

Jan 1, 1989

By U. S. Chattopadhyay

The estimated requirement of the nation by the year 2020 is approx. 80 Mt of steel and more than 0.2 million MW installed capacity of the electricity, thereby increasing the consumption of the coking and non-coking coal, which is expected to be in tune of about 75 Mt & 500 Mt respectively. One of the major deleterious factors in achieving the goal is the deteriorating quality of the feed coal used in both steel and power industries. Indian coking coals, in general, are typified by high ash, high inert (both organic and inorganic), low rank, low reactive macerals content, heterogeneous petrographic make-up, inferior coking properties and poor amenability to washing, thereby necessitating suitable washing measure. Coke-based steel industries in India require washed coking coal containing ash % varying between 17-19. The situation demands taking on immediate challenges to fill up the gap between the requirements and supply of coking coal. This paper reviews the R&D attempts in this laboratory and throws light on the key measures as long-term solution to the problem. Search for alternative source of coking coal, like LVC coal and their judicious preparation technology. The low volatile coking coal (LVCC) constitutes about 50% of the total coking coal reserves in India. These coals are characterized by high raw coal ash content (37 to 40%) and very difficult washability potential. If these coals are treated in the existing washeries, which are generally 2 or 3-product systems, the cost of clean coal is high as the byproduct sale value is low. It has been proposed to produce a new type of by product, which enjoys high demand and good coking properties.

Sep 1, 2012

By A. Sauveur

In an important paper on The Critical Ranges of Pure Iron presented at May, 1913, meeting of the Iron and Steel Institute…

Jan 1, 1915

By G. S. Scott, G. W. Jones

"INTRODUCTION An important phase of the accident-preventing program of the Bureau Mines is the determination of the explosion hazards of various combustible gases, vapors, and liquids encountered in mining and allied industries and the development of methods of eliminating or mitigating them.Recently, isobutane has become a commercially important raw material in the production of aviation gasoline by the alkylation process. 4/ in which isoparaffins are combined with olefins to give higher molecular weight compounds of branched-chain structure.Because of the anticipated commercial importance of isobutane in industry, it has been deemed necessary to study and determine its general explosion haz¬ards. This report gives its limits of inflammability, minimum ignition temper¬atures, and the amounts of nitrogen and carbon dioxide required to render isobutane-air mixtures noninflammable."

Jun 1, 1947

By D. J. Brunner, S. Mathur, D. McKinney

With the advent of faster micro-processors, the use of numerical methods to simulate complex fluid dynamic phenomena in three dimensions for use in design has become prevalent in the automotive, and turbo-machinery industries. The Computational Fluid Dynamics (CFD) method divides the region of interest into small control volumes which form the mesh representing the physical characteristics of the problem, and uses the finite volume method to intergrate the equations for the conservation of mass, momentum, energy and species over each control volume. Recent developments in CFD software expedite mesh generation, and enable the use of unstructured grids, comprised of tetrahedral volumes in three dimensions and triangular areas in two. CFD more accurately represents complex geometries and allows for relative movement of meshes enabling simulation of multiple moving bodies. 'ibis paper presents two examples of how CFD simulation can be used to assess mine and tunnel ventilation problems formerly addressed by application of analytical solutions which were developed assuming ideal incompressible conditions. CFD simulation is used to evaluate the impact of varying the airflow in a descentionally ventilated airway on the layering along the roof of smoke and hot gases resulting from a vehicle fire. Control of the smoke layer is required to enable safe egress from the vehicle, particularly if the vehicle is for personnel transport, and to ensure control of the fire contaminants throughout the ventilation system. The airflow required to prevent layering against the ventilation direction, calculated from the Bakke and Leach relations (Bakke and Leach, 1962), is compared with the CFD simulation results. An evaluation of the pressures, generated as a vehicle enters a tunnel portal, using CFD simulation, is also presented for unflared and flared portal configurations. These simulation results are compared with predictions derived using an analytical method which assumes one-dimensional and incompressible flow. Results of the CFD simulation are presented in an animated video format. SIMULATION OF BACKLAYERING In designing a ventilation system for a transit tunnel, the ability of the ventilating air to control and prevent backlayering of smoke and hot gases resulting from a vehicle fire is of prime concern. The buoyant nature of hot smoke causes it to rise relative to the colder, fresh air provided by the ventilation system. If the vehicle fire occurs in a descentionally ventilated tunnel, the smoke may tend to move upgrade in a layer above the incoming ventilation airflow. The layer may become thick enough to engulf a substatntial part of the tunnel cross-section upgrade of the incident that comprises the evacuation route. This effect is termed "backlayering' and it is similar to the development of methane layers in mines for which most studies related to backlayering have been done. Prediction Techniques Analytical A number of studies have been conducted (Bakke and Leach, 1962) to define the characteristics of this phenomena and as a result have produced relations which are used both in the mine and transit ventilation fields to define the air velocities required to control layering. In the transit industry the air velocity required to prevent the backlayering phenomena from occuring during a vehicle fire is called the "critical velocity" (Associated Engineers, 1975) and is dependent upon a number of factors: tunnel height, cross-sectional area and grade; ambient air temperature and density; and the heat release rate of the fire. Common practice in transit ventilation design is to provide an airflow which meets or exceeds the critical velocity. In order to determine whether or not the critical velocity can be achieved with a particular ventilation system, a one-dimensional simulation of the tunnel network is typically performed using programs such as the Subway Environment Simulation program (SES) originally developed in the late 1970's (Associated Engineers, 1980). The results obtained from SES are compared to the critical velocity to determine the adequacy of the ventilation system. Computational Fluid Dynamics For the backlayering simulations, a commercial CFD code which has been used successfully in a wide variety of engineering applications, was used. It provides numerous options for modeling laminar and turbulent flows, multiple turbulence models, definition of multiple species and chemical reactions between them, a variety of boundary conditions (including constant pressure and constant velocity inlets) and the ability to apply user-defined FORTRAN subroutines. It includes the ability to model conductive, convective, and radiative heat transfer. FLUENT also permits the use of "body-fitted coordinates" to match the computational mesh or grid to complex real-world geometries. Computational Fluid Dynamics Model The model developed to simulate the backlayering phenomena is comprised of an airway of rectangular cross-section, 4 meters wide, 4.5 meters high, and 200 meters long. A laterally

Jan 1, 1995

By Peter R. Morris

The effecl of preferred orienlation on X-vay dzffvaction measurements of retained austenzte was investigated for four precipitation-hardening staznless steels in sheet form. A method is preserzted for estimating the ervor in measurement associated with a given samplirig direction. The method was used to select an "optimum" sampling direclion in order to minimize errors in measurement due to preferred orientation. hleasuremenls of retained austenite content employing lhe proposed sampling direction are conzpaved to measuretnents enzploying the more commonly used normal direclion for a series of sawzples. THE first application of X-ray diffraction to the measurement of retained austenite in steels is due to Sekito, 1 who employed a photographic technique in which the (111) reflection from a thin strip of gold affixed to a cylindrical sample was employed as a standard. Averbach 2 introduced the "direct comparison" method in which the ratios of observed to calculated random intensity are assumed proportional to the austenite and/or martensite contents. Averbach's work forms the basis of most subsequent X-ray diffraction methods for the determination of retained austenite. Subsequent improvements are due to: Averbach and Cohen,3 who employed a sodium chloride crystal to monochromate cobalt radiation; Averbach et a1.,4 who introduced a bent sodium chloride monochromator; Mager,' who used a bent quartz crystal to monochromate chromium radiation ; Littmam, who first used a geiger counter diffractometer for this purpose; Beu and Beu and Koistinen, 11,12 who studied effects of absorption factor, surface preparation, sample geometry, integrated intensity vs peak height, choice of radiation, monochromator, and filter. The possibility of errors in measured values due to orientation effects was noted by Miller,13 who suggested examination of a surface other than the plane of rolling. Lopata and Kula 14 have developed an experimental technique in which the preferred orientation is measured in each sample. They illustrated the method for a sample containing 42 pct retained austenite. Application of their technique to the 1 to 15 pct range typical for the precipitation-hardening stainless steels does not appear feasible. EXPERIMENTAL PROCEDURE The nominal compositions of the precipitation-hardening stainless steels investigated are listed in Table I. Ingots were solution-treated, hot-rolled to approximately 0.2 in., and reduced to 0.050 in. by a suc- cession of cold rolling and annealing operations. After this treatment the 17-4PH sample was in the marten-sitic condition, while the 17-7PH, PH 14-8Mo, and PH 15-7Mo samples were in the austenitic condition. Samples of 17-7PH and PH 15-7Mo steels in the mar-tensitic condition were obtained by heating to 1750'F for 10 min and holding at -100°F for 8 hr. A sample of PH 14-8Mo steel in the martensitic condition was obtained by heating to 1700°F for 1 hr and holding at -100°F for 8 hr, followed by aging at 950" for 1 hr. POLE FIGURE DETERMINATIONS Samples were thinned to 0.003 to 0.005 in. by etching in a solution containing 250 ml reagent-grade phosphoric acid (85 to 87 pct H3PO4), 250 ml technical-grade hydrogen peroxide (30 to 35 pct H 2 O 2), and 50 to 100 ml reagent-grade hydrochloric acid (37 to 38 pct HCl). The specimens were placed in an "integrating" sample holder which provided a 1-in. oscillation in the plane of the sample. The diffractometer was aligned to measure the intensity diffracted by planes of the particular {hkl} type being studied. The sample was Set for a given latitude angle, a, measured from the plane of the sheet, and diffracted intensity recorded as the longitude angle, 0, measured in the plane of the sheet from the rolling direction, was increased from 0 to 360 deg. After a 360-deg scan of B, a was incremented by 5 deg, and the process repeated. Random standards obtained by spraying suspensions of powdered iron (bcc structure) and nickel (fcc structure) in lacquer were used to correct observed intensities for absorption and geometrical effects. Zirconium-filtered molybdenum radiation was used to determine the transmission regions of the (111) (0to 45 deg), (200) (0 to 60 deg), and (220) (0 to 45 deg) austenite and (110) (0 to 45 deg), (200) (0 to 50 deg), and (211) (0 to 35 deg) martensite pole figures. Vanadium-filtered chromium radiation was used to

Jan 1, 1968

By M. Z. Emad, A. Hassan, M. A. Raza, M. U. Khan, S. A. Saki

Digital modelling of a surface is crucial for Earth science and mining applications for many reasons. These days, high-tech digital representations are used to produce a high-fidelity topographic surface in the form of a digital terrain model (DTM). DTMs are created from 2D data-points collected by a variety of techniques such as traditional ground surveying, image processing, LiDAR, radar, and global positioning systems. At the points for which data is not available, the heights need to be interpolated or extrapolated from the points with measured elevations. There are several interpolation/extrapolation techniques available, which may be categorized based on criteria such as area size, accuracy or exactness of the surface, smoothness, continuity, and preciseness. In this paper we examine these DTM production methods and highlight their distinctive characteristics. Real data from a mine site is used, as a case study, to create DTMs using various interpolation techniques in Surfer® software. The significant variation in the resulting DTMs demonstrates that developing a DTM is not straightforward and it is important to choose the method carefully because the outcomes depend on the interpolation techniques used. In mining instances, where volume estimations are based on the produced DTM, this can have a significant impact. For our data-set, the natural neighbour interpolation method made the best predictions (R2 = 0.969, β = 0.98, P < 0.0001).

Feb 6, 2023

By T. A. Rickard

The notion prevails that writing is a knack, that the skilful use of the pen is a gift of nature. This is an error. Dogberry may be responsible for it; he said: "To be a well-informed man is the gift of fortune, but to write and read comes by nature". Because Dogberry said it, we may be sure that Shakespeare thought otherwise. Ability of any sort may be partly innate, but my own observation and experience lead me to conclude that most of the easy writers have become so by constant practice. As I recall the names of men successful with the pen, I remember that most of them have written a great deal and have taken particular pains to improve their style. The suggestion that proficiency in the difficult art is a happy accident provokes a sardonic smile. The larger part of the great writing in our literature is the result of persistent effort. An easy fluency has been the undoing of many; their flamboyant and fantastic scribbling has proved as perishable as froth. This criticism applies to technical writing also; in order that a technical description or discussion may hold the interest of the reader, at least long enough to cause him to read it to the end, the writing must be done carefully and systematically; otherwise it will fail in its purpose of conveying information. Clearness is absolutely essential. "It is not enough to use language that may be understood; it is necessary to use language that must be understood."* The purpose of writing, at least of that which is meant to be read by others, is not only to express ideas but to communicate them. Lack of perspicuity may prove as %ad as

Jan 1, 1931

By Susanne Pignolet-Brandom

Fourteen samples of crushed Duluth Complex rock were characterized by the QEM?SEM automated scanning electron microscope image analysis system to evaluate the application of the system to mining waste rock characterization. The system can reliably distinguish the iron sulfides, the copper-iron sulfides and the nickel-iron sulfides. Calcite was distinguished from all other minerals except fluorite. The volumetric abundances were verified by comparing elemental abundances calculated using the QEM"SEM volumetric percentages and appropriate mineral compositions with elemental abundances determined by standard laboratory procedure. The pH and sulfate concentrations of rinse water from laboratory leach experiments correlated well with the mineralogical data.

Jan 1, 1989

By C. M. Loeb, A. M. Gaudin, J. H. Brown

R. E. Carter (General Research Laboratory, Schenec-tady, N. Y.)—Brown, Gaudin, and Loeb in their study of intergranular comminution by heating attempt to find one explanation for all types of rock in terms of the properties of the phases present. The only necessary condition for intergranular cracking by heating is the setting up of high stresses at the grain boundaries. Such stresses may be set up in multiphase isotropic mixtures if the thermal expansions of the phases are different, in non-cubic single phases because of the anisotropy of thermal expansion in the various crys-tallographic directions, and in materials containing quartz because of the a-p&apos; transformation at 575°C. In addition, for intergranular comminution by heating, the cooling and not the heating is most important.

Jan 1, 1960

By J. H. McMillan

Most of the recent papers read before the Institute have dealt with purely scientific matters, or with experiences in the various phases of mining operations. Very little, if anything, has been said concerning the part played by the human element in the industry. It is now opportune to consider this vital factor if we are to cope with the complex work of the present-day miner and, at the same time, meet the demands of the executive for greater efficiency. It is time we made an inventory of our knowledge to determine if we are absorbing the information so essential to modern mining practice. We must keep in close touch with all new ideas and developments in our chosen field and keep ourselves up-to-date in regard to everything pertaining to mining operations in general. The man who ceases to study ceases to advance. There are men who on attaining an executive chair give up all study, because they think they have reached the pinnacle of success. Modern industrial business, and coal-mining is no exception, demands that executive officers shall be &apos;live wires&apos; -- men who are not only well-informed as to their immediate duties, but who are closely in touch with all matters of importance affecting the industry as a whole. We may be graduates of schools and colleges, but the training we receive in these institutions is only the foundation for our later work. Certainly no executive officer can know too much concerning the work he is engaged in, and the more he knows the more pleasure he will get out of his work.

Jan 1, 1925

By F. X. Tartaron

This report describes work done by the Bureau of Mines to simplify the design and operation of the vortex cone, a new device for prerefining blast furnace iron. Three new apparatus arrangements were tested. Results with one of these arrangements average 74.2 pct silicon removal and 61 pet oxygen efficiency (disregarding removal of carbon and manganese).

Jan 1, 1965

By J. L. Tomlinson, B. D. Lichter

Electrical resistivities 01 liquid Cd-Bi, Cd-Sn, Cd-Pb, In-Bi, and Sn-Bi alloys were measured using an electrodeless technique. The resistivities ranged from 50 to 160 microhm -cm, temperature dependences were positive, and no sharp peaks in the composition dependence of the resistivity were observed. On the basis of these observations, it was concluded that the alloys are typical metallic liquids. The electron con-cent9,ation was calculated from the measured resis-tizlity and available thermodynamic data using a model which attributes electrical resistivity to scattering by density and composition flzcctuations. A correla-tion was shown between the departure of the electron concentration from a linear combination of the pure component valences and the value of the excess integral molar free energy. Calculation of the temperature dependence of the electrical resistivity showed a need for more detailed thermodynamic data in these systems and led to suggestions for improvement in the concept of residual resistivity in the fluctuation scattering model. THE electrical resistivity of liquid metals provides information regarding interatomic interactions and their effects upon structure. In this experiment an electrodeless technique was used to measure the electrical resistivities of liquid alloys of Cd-Bi, Cd-Sn, Cd-Pb, In-Bi, and Sn-Bi, and the results were used with thermodynamic data to calculate a parameter which reflects the tendency toward localization of electrons due to compositional ordering. It was found that the resistivities of these alloys are generally metallic in magnitude and temperature dependence. The electrical and thermodynamic properties are discussed in terms of the fluctuation scattering model&apos;22 which supposes that the electrical resistivity arises from scattering due to a static average structure and departures from the average due to fluctuations in density and composition. Further, this model is compared with the pseudopotential scattering model of Ziman et al.3-5 EXPERIMENTAL PROCEDURES Alloy samples were prepared from 99.999 pct pure elements obtained from American Smelting and Refining Company (except tin which was obtained from Consolidated Smelting and Refining Company.) J. L. TOMLINSON, Member AIME, formerly Research Assistant Division of Metallurgical Engineering, University of Washington, Seattle, Wash., is now Physicist, Naval Weapons Center, Corona Laboratories, Corona, Calif. 0. D. LICHTER, Member AIME, is Associate Professor of Materials Science, Department of Materials Science and Engineering, Vanderbilt University, Nashville, Tenn. This work is based on a portion of a thesis submitted by J. L. TOMLINSON to the University of Washington in partial fulfillment of the requirements for the Ph.D. in Metallurgy, 1967. Manuscript submitted May 31, 1968. EMD Weighed portions were sealed inside evacuated silica capsules, melted, and homogenized before the resistivity was measured. The resistivity of a liquid alloy was measured by placing the sample inside a solenoid and noting the change in Q. According to the method of Nyburg and ~ur~ess,~ the resistivity of a cylindrical sample may be determined from the change in resistance of a solenoid measured with a Q meter as T7--5--W =R7JT^ =&apos;Kc-lm(Y) [1] where L, R, and Q = wL/R are the inductance, series resistance, and Q of the solenoid. The subscript s refers to the solenoid with the sample inside; the subscript 0 refers to the empty solenoid. Kc is the ratio of the sample volume to coil volume and y = 2 [bei&apos;0(br)-j ber&apos;o(br)~\ br\_bero(br) +j bei0 (br) expressed with Kelvin functions which are the real and imaginary parts of Bessel functions of the first kind with arguments multiplied by (j)3&apos;2. The argument of the function Y is hr where r is the sample radius and b2 = po~/p, i.e., the permeability of free space times 271 times the frequency divided by the resistivity in rationalized MKS units. Since Eq. [I] cannot be solved explicitly for p, values of Kc. lm(Y) were tabulated at increments of 0.1 in the argument by. A measurement of Q, and Q, determined a value of Kc . lm (Y) and the corresponding value of br could be read from the table. From the known r, uo,, and w, the resistivity, p, was determined. The change in Q was measured after letting the encapsulated Sample reach equilibrium inside a copper wire solenoid. The solenoid was contained in an evacuated vycor tube in order to retard oxidation of the copper while operating at high temperatures and heated inside a 5-sec-tion nichrome tube furnace capable of obtaining 900°C. Temperature was determined with two chromel-alumel thermocouples, one in contact with the solenoid 30 mm above the top of the sample and the other inserted in an axial well at the other end of the solenoid and secured with cement so that the junction was 2 mm below the bottom of the sample. Temperature readings were taken with respect to an ice water bath junction, and the voltage could be estimated to the nearest thousandth of a millivolt. The lower thermocouple was calibrated by observing its voltage and the Q of the coil as the temperature passed through the melting points of samples of indium and tellurium. The upper thermocouple reading was systematically different from the lower thermocouple reflecting the temperature difference due to a displacement of 60 mm axially and 6 mm radially. Calculations show that the gradient over the sample was less than 2 deg. Q was measured by reading a voltage related to Q from a Boonton 260A Q meter with a Hewlett Packard

Jan 1, 1970

By M. P. Oommen

This paper provides a brief look at a proposed short-longwall for coal, development. The proposed method is an attempt to realize the advantages of longwall mining in deposits that, historically, would only be minable by continuous mining methods. An overview of the proposed layout, development requirements, production rate, ventilation scheme and other associated features is provided. This mining method could help operators in above-drainage seams where minable areas are smaller. It may also have application in areas that are peppered with gas wells and in environmentally sensitive areas which preclude the use of conventional longwalls.

Jan 1, 1993