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By Chad W. Brown

"A study of five commercially available solvent-extraction diluents in combination with three commercially available extractants under sub-Saharan African copper solvent-extraction conditions yielded intriguing results. A variety of physical and chemical property analyses showed that the diluents have some property differences, but overall the properties are similar and provide comparable solvent-extraction performance. Although each physical chemical property technique provides useful information, no individual test result suffices for prediction of diluent performance. Furthermore, a diluent should be evaluated within the conditions for which it is targeted to determine a true measure of performance. Overall, the diluents studied possess appropriate physicochemical properties for sub-Sahara Africa copper solvent-extraction conditions and can be utilized to achieve efficient, safe and reliable operations. INTRODUCTION Background Today, commercial SX diluents are available globally from a limited number of manufacturers. Production quality and consistency of these diluents have improved tremendously over the past 20 years. For example, diluent flash points have been increased incrementally to improve transport and handling while reducing fire hazards. In addition, properties have been successfully modified to minimize evaporative losses, ultimately reducing SX plant raw material costs. Diluent manufacturers have also focused on meeting performance requirements of SX plants, including eliminating components detrimental to SX operations, such as olefinic groups that can react with various species resulting in changing phase-disengagement properties over time, as well as ensuring that proper hydrocarbon components are present within diluent mixtures to maintain good reagent–metal complex solubility. These challenges have been met in the midst of ever-increasing stringent environmental regulations. Sub-Saharan Africa copper SX operations pose a unique set of conditions for diluents due to inherent ore compositions and the associated high reagent concentrations required for complete copper extraction. Chevron Phillips Chemical Company, LP has been manufacturing hydrocarbons and hydrocarbon-based diluents since the mid-80s, applying this experience to identify the physical properties considered crucial for proper performance in SX operations. This paper documents the findings of a study utilizing commercially available diluents in combination with extraction reagents commonly utilized in African SX operations to evaluate the relative performance of the diluents under sub-Saharan Africa copper SX conditions."

Jan 1, 2015

By Gabriella Mendez

Worthy of note in Miss Bailey's paper are her comments on the attitudes of mining companies and their managers where women were employed, she says, "..another possible pitfall is reverse discrimination where in an effort to avoid being branded as having shown a person favouritism, supervisors end up treating the person in a manner much less than they deserve. This is manifested in denying an employee such things as challenging work, educational opportunities, promotions, or in the case of staff, fair merit increases." and further she says, "It has been observed that the treatment of women in non-traditional roles such as mining is different than for men in the same environment. There are people who treat women worse and some who treat them better simply because they are of the other sex." These statements may sound unjustified to today's audience, and whilst we need to credit pioneering women with having tolerated, understood and worked towards improving the mining culture, the move towards total inclusion of women in the workplace is still growing.

Jan 1, 1995

By Sullivan BJK

The 1100 orebody is a massive copper sul- phide orebody which contains a major portion of the Isa Mine copper ore reserves of 130 million tonnes at 3.2%. The underground mining of a deposit as large as the 1100 orebody is technologically a complex operation as extraction strategies have to be evaluated with reference to 1. rock mechanics considerations, 2. safety and environmental standards, 3. production and operating require- ments and 4. metal recovery and costs. The mining philosophy in the orebody has undergone considerable change over the past five years as a result of experience and improved technology. At this stage, primary stopes are extracted by high rise sublevel open stoping and pillars by slot and mass blast drawn either under rock fill or as an open Stope.

Jan 1, 1978

By Tony B. Szwilski

"The efficiency of operation and life of an advancing longwall coalface depends, to a great extent. on the face-end roof strata conditions and the stability of the gateroads. The factors that influence the rate of closure of gateroads are examined, in particular the gateside pack and the coal rib (crush) pillars. The performance of mechanized packing systems is briefly discussed. Gateroad deformation surveys were carried out at two coal mines to determine the influence of the rib pillar width on gateroad stability; also, the influence of the gateside pack on the immediate roof and floor strata is analyzed based on strata bed displacement measurements from instruments installed in the gateroad and pack-hole of a longwall advancing face operating in a thick seam (7.55 m). Concluding, an evaluation of the fac e-end systems examined is given and recommendations made f or the most suitable rib pillar width. face-end geometry and roof strata reinforcement.IntroductionKevword s: Coal mining, Pillars, Rib pillars, Ground control, Longwall mining, Gateroads , Packing systems, Roof control. The face-end region of a longwall advancing face is the center of mining activity, being the turn-around point for the coal cutting machine. and the place of gateroad formation and movement of special face-end supports. The design of face-end layouts can be aided by knowledge of strata control parameters, such as the effective loading of the immediate roof strata , convergence of the roof and floor, magnitude and distribution of fractures in the roof strata around the face-end , optimum placement of supports, coal seam thickness and strength characteristics, geometry of layout and interaction from neighbouring workings. Generally, the gateroad is formed by one of three face-end methods: (a) advanced headings, (b) in-line system (gateroad formed at the face) or (c) conventional ripping with or without stable elimination (also halfheading). The quality of gateroad is influenced principally by the face-end system employed, standard of gateside pack and width of pillar. A good standard of gateroad is generally achieved by employing the half-heading face-end system, the gateside pack and coal rib pillar having comparative support/ yield (stiffness factor) characteristics. However, the halfheading is often not favoured due to face operation restrictions."

Jan 1, 1981

A GIFT of $10,000 to the endowment of Engineering Foun-dation, made by the Central Hudson Gas and Electric Corporation, has been announced. In transmitting this gift T. R. Beal, president of the corporation, made the follow-ing interesting statement: "You may be interested to know that this amount was in fact earned by our employees by their more efficient opera-tion of the physical properties under their care. It rep-resents $10,000 of return premiums paid during the past year on accident insurance, as the result of the company's excellent record in preceding years, so that we take greater satisfaction in making this gift as it is related, in some degree at least, to the higher standards of engineering and operating practice to which the work of the Foundation per-tains."

Jan 4, 1928

By R. J. McGregor

The Internet has revolutionized worldwide communications. Any real or perceived mining incident or environmental spill, no matter how small or remote, can become a disaster of "biblical proportions" through the judicious use of the Internet by environmental and anti-mining groups. In addition, mining companies' own Web sites and unofficial message boards can provide plenty of additional ammunition to the anti-mining forces. This paper explores how the Internet and readily available information are used by anti-mining groups active on the Web.

Jan 1, 2001

By C. D. Mishra

The recycling potential for any gainful utilisation of the waste products is dictated by their quality, especially the chemical characterisation. The methods commonly used for the analysis of fly ash e.g. wet chemical, AAS, ICP-AES etc are time consuming. The paper describes a rapid XRF-based method for routine analysis of fly ash which involves preparation of local standards, optimisation of sample preparation technique and use of a simple PC-based software to account for interelement effects. The matrix corrected values are found to agree well with the wet chemical data.

Jan 1, 1992

By J. Rothschild

I would like to thank the Society of Mining Engineers for inviting me as well as the other distinguished panelists to spend a morning reviewing and discussing the handling and shipping of industrial minerals. I also would like to thank my management, Cometals. Inc. for permitting me to take time out from the daily hectic pace of marketing and trading to share with you some of our experiences and expertise. Cometals, Inc. is a wholly-owned subsidiary of Commercial Metals of Dallas. The transportation and handling costs of industrial minerals frequently are a major component of the value of the goods marketed and, therefore, it is only natural that close attention should be paid to them. Many of the industrial minerals require special handling to assure that the material reaches the consumer without being contaminated or getting wet. I invite you to accompany me through the various steps involved in "delivering the goods" to the consumer.

Jan 1, 1989

By Fred W. Brackebusch

"The use of paste technology for surface tailings disposal may offer economic, technical, safety, and environmental advantages for both underground and surface mining operations. Paste is a non-Newtonian fluid having some shear strength during transport and placement. The strength is augmented after placement by consolidation, water loss, and by addition of chemicals. Economical dewatering systems are necessary to the success of surface paste tailings disposal. In an underground mine, the paste backfill plant can produce paste for surface disposal about 50% of the time because only about 1/2 of the tailings are needed for backfill. The distribution of paste to the surface stack involves expensive pumping equipment and thus a nearby location of the stack is desirable. The viscosity of paste can often be manipulated by modifying pH. Placement of the paste in a designed stack configuration depends on topographic and climatic factors as well as paste properties.INTRODUCTIONThe use of paste technology for mine backfill is becoming accepted for underground mines mainly because of ground control and economic reasons. Paste technology is just starting to be applied for tailings disposal with only a few hardrock metal mines worldwide using the technology; however, it has been used extensively for red mud disposal in the aluminum industry. The disposal of dry tailings is very attractive from environmental and safety points of view because of limited water which might potentially escape and pollute river systems. Dry stacking systems, however, are expensive because of filtration and truck transportation costs. Paste can be produced from most tailings streams by special types of thickeners. Furthermore, it can be transported in pipelines, therefore paste technology may be more economic than dry stacking but still have some of the major advantages. Understanding of paste technology has improved through experience with operating underground backfill systems in recent years and because of testwork and research programs by mining companies, consultants and equipment vendors. Thus we may be on the verge of taking a new look at tailings management using paste technology."

Jan 1, 2002

By Franklin H. Sharp, Kenneth L. Clifford

During the last few years the New Lead Belt of Southeastern Missouri has become the main source of lead in the United States. It also produces significant amounts of zinc, copper and silver. The mines are located on a narrow, mineralized trend extending southward from Viburnum, MG. for about 35 miles. The ore occurs as replacement deposits in the Bonneterre lime- stone formation which is about 1000 ft below the surface. In most of the mines, enough water is produced to supply the milling requirements without any reuse. There are dry areas, however, and at least two mills must rely on water reclaimed from their tailings lake to augment the mine water. These mills have no choice but to utilize recycled mill water.

Jan 7, 1973

By Virgil Miller

Bureau of Mines Reports of Investigations 3244, 3245, 3246 and 3264 give data of detailed studies on smelting in the lead "blast furnace handling zinciferous charges at Trail, B. C. The present paper gives more on analyses of the gases leaving the top of the charge and on accretions formed on the walls of the blast furnace. New data are presented to show the effect of the temperatures at the tuyere zone on the lead content of the slags made. The greater part of this paper, however, deals with a much debated subject, namely air used in lead blast furnaces. Original data are presented to show the effects on smelting lead 'products when air is supplied to a lead blast furnace under volume versus under pressure control.

Jan 1, 1940

By Kevin Beauchamp

In many cases traditional support designs cover the many variations in ground conditions and bolt performance by a conservative factor of safety. The result is that most bolts are ineffectual most of the time and yet the response to occasional roof collapses is an even more conservative design. The probabilistic analysis presented in this paper takes several important parameters of a support design into account such as span, bolt strength, bolt length, water pressure, seismic accelerations, joint orientation, bed thickness and joint strength and allows the effect of variations in these parameters to be evaluated simultaneously. The analysis demonstrates the application of the probabilistic approach to both blocky, wedge-dominated conditions and bedded deposits dominated by laminations. All mine excavations have a designed stand-up time. By taking into account of the possible variations in the design parameters explicitly, it is possible to produce a support system designed to ensure stability over a given period of time. Rather than use a factor of safety criterion, the approach uses a percentage reliability or probability of failure. By understanding the probability of failure of the support system, it is possible to improve the performance of ground support without any increase in cost or conversely to decrease the cost while maintaining the performance of ground support. This approach reduces reliance on empirical experience and leads to a better understanding of the key factors that influence stability and can provide a much more accurate and optimized assessment of support design and performance. The result is a more cost-effective support system and we hope that a broader application of this approach to ground support in underground mines will lead to a greater acceptance in the industry of probabilistic analyses and of terms such as Probability of Failure and Reliability of Support.

Jan 1, 2003

By F. C. Blake

The best method for the estimation of copper in ores and secondary products is that proposed by Dr. Steinbeck* for the award offered by the Mansfeld'schen Ober-Berg-und Hutten-Direction. It is based upon the decolorization of the blue ammonia solution of copper by potassic cyanide.7 It is necessary for the accurate estimation of copper in arsenides that the arsenic be separated from the copper before the ammonia solution is made. The presence of a notable amount of arsenic renders the titration by potassic cyanide inaccurate, the end reaction being obscured by the appearance of a yellowish-green tint towards the end of the titration. The change of the color of the ammonia solution from blue to the tint caused by the presence of arsenic cannot be used for an end reaction, for the intensity and quick appearance of the latter color depend upon the amount of arsenic present in the solution. In the analysis of speise, the method of separating the copper by an oxidizing and reducing treatment in the muffle, to volatilize the arsenic, gives poor results, and there may easily be some loss of the weighed sample. The separation of the precipitated sulphides of arsenic and copper by treating with sodic sulphide, gives good results, but the process is tedious. I have used the two following methods, which are simpler and more expeditious than those mentioned, with good results

Jan 1, 1881

The society in which we live is one of change, and we professionals are part of that society. The importance of this simple and obvious statement is often overlooked. My Presidential Address examines the question: can professionalism survive in our changing society?There is ample evidence to show that our society is changing, and that the rate of change is exponential. This rapid and accelerating rate of change is what Alvin Tomer refers to as "future shock". Rapid change means that we do not have time to become accustomed to what is happening around us and to feel comfortable with it; the greater the rate of change the greater the discomfort. The effect that this has on people is varied; the change may be either expected or totally unexpected.The rate and extent of change in society is not the same for all countries nor for all industries or occupations. Change is more rapid in Japan, Korea or Taiwan, than in Australia. It is more rapid in our cities than in the bush, more rapid for professional businessmen than for farmers. In our minerals and petroleum industries, we are still adjusting to the great changes that have taken place over the last fifteen years. In the past, products from our industries were sold on a free and open market. Today, mineral development and production in most undeveloped countries and some developed countries is manipulated for political, social and economic reasons. Changes of this nature have had a devastating effect on the operations of established mineral producers in the democracies.Because of the accelerating nature of change, we must recognise that the past is not a reliable guide to the future.Although extrapolation of the past into the future is a basic ingredient of commercial survival, extrapolation is less and less reliable.I borrow from others in quoting the Irish proverb: "The future is not what it was".The future is where our business lies and most of us at this Conference must endeavour to understand it and adjust to it. I believe in the old adage that:You can't know where you're going if you don't know where you've been and where you are at.There are a number of major factors which have created change within our social, economic, and industrial environment in recent years.

Jan 1, 1985

A. G. Cockbain—The paper by Burlingame, Bitsianes and Joseph is of great interest in extending the work done on high grade sinters, particularly that of Hessle, and the development and application to them of the technique of McBriar, Johnson, Andrews and Davies on ironstone sinters. In this laboratory the work of McBriar et al. has also been continued and extended to cover high grade sinters, and a sectioning technique similar to that used by McBriar et al. was attempted on sinter cakes made in the laboratory sinter unit, using magnetite concentrates (containing 64 pct Fe). In these experiments no attempt was made to flush out the products of combustion with nitrogen before cooling. It was considered that free air penetration would occur on only a limited scale with the size of sinter cake made (14 in. sq x 12 in. deep). Chemical analyses of the zones showed generally similar features of those described by Burlingame et al. and especially the FeO rich region at and just behind the flame front, i.e. zones of ignition and combustion. This seems to indicate that the nitrogen atmosphere does not materially affect the states of oxidation in the sinter cake or at least that special care is not required unless the sinter cake is small. Burlingame et al. consider that FeO present has some significant part to play in the mechanism of sintering. This view does not find favor with the author. The reduction of iron oxides in the presence of red hot coke is a well known phenomenon, whether conducted in an atmosphere of nitrogen or in a crucible in air, and in view of the presence of some carbon in the hot sinter, especially just at the ignition zone, cessation of the progress of the flame front will in no way affect the reduction of iron oxides near hot coke. Even in a nitrogen atmosphere some CO and CO, will be generated by reduction and by continual oxidation and reduction of CO as the transfer agent, the oxidation state of the iron oxides can be lowered quite rupidly so long as free carbon exists with enough heat. Knowing the composition of the gas at the flame front (obtainable by probes), it would be possible to calculate the static oxidation state of Fe2O3/Fe3O2 in equilibrium with it and hence obtain a check on the chemical analyses to see if in fact direct reduction of the Fe2O3/Fe2O1 to FeO has taken place. Have the authors attempted this? It appears to this writer that what is required is some means of reducing rapidly the heat content of the ignition zone and immediately behind, and at the same time insuring no oxidation by the air. In ironstone sinters the difficulty of oxidation state of the iron did not arise on account of the very large slag bulk. However, in high grade sinters knowledge of this, and also the mechanism whereby high oxidation states can be obtained in the final sinter, is of great interest. R. D. Burlingame (author's reply)—The question has been raised as to whether the high FeO content found in high-fuel sinters is due to actual reduction at the advancing flame front or due to unavoidable direct reduction during the quenching period. For such direct reduction to have taken place in the freshly-formed sinter, a considerable amount of solid carbon would have had to escape combustion and be available throughout the hot sinter zone during the quenching period. A simple stoichiometric calculation with the limited data available indicates that a zone of freshly-formed sinter over 2 in. wide must have averaged roughly 2 pct C to accomplish the amount of reduction found. Furthermore, the presence of this amount of carbon would indicate that the fuel in the charge had not burned over a narrow front but over a zone at least 2 in. thick. In contrast to such a condition, the data of the present investigation indicate that the combustion of fuel is confined mainly to a narrow front in which high temperatures and reducing conditions favor. the formation of excess ferrous iron.

Jan 1, 1959

By Richard Moldenke

The author discusses some economic conditions which have made the career of the cast-iron pipe industry in the United States a checkered one. He next describes the two new developements in the manufacture of cast-iron pipe-both along the lines of centrifugal casting. The advantages and disadvantages of both processes are presented in some detail. Finally, statistics on the production of pipe in the United States at the present time are given, as well as the plants-and their capacities-so far as these are situated in the South. No SINGLE branch of the foundry industry has been brought to a production basis of huge tonnage, low manufacturing cost, and producing material of a remarkably high quality, as has the making of cast-iron pipe. The pipe shop is an excellent illustration of the fact that repetition work in specialties leads to mechanical equipment and manipulation that lower production costs to an. astonishing degree. Hence cast-iron pipe, in dull times, has been sold at a few dollars a ton over the selling price of the pig iron used. On the other hand, these same pipe, shops make fittings .of many varieties, and in much smaller quantities, where the cost is high, and when pipe may be sold, say, at $50 a ton, the fittings on the same shipment will be sold for nearly double that price. The history of pipe-making, in the United States, is a checkered one the mortality of plants is high and, from the nature of the industry, plants must be large to live. In spite of the fact that the best processes must be used to turn out this rather strict specification material, pipe is easy to make and a pipe plant is more of a tonnage mill than the really high-class specialty foundry it should be. Every time, therefore, that the demand for pipe is strong new shops spring up, only to close when the demand has ceased, but the financial damage to the more permanent plants has been done. Both the South and the North have had abundant experiences of this kind, and when recently a northern Public Service Corporation gave its order to France, the pipe plants thus adversely affected were content to have this occur rather than see-a plant started to supply the surplus demand.

Jan 9, 1924

By Lukaszewski GM

The indiscriminate surface disposal of coal waste in the past has created a serious fire hazard in the bush of the northern New South Wales coalfields. Spontaneous or bushfire-induced combustion in large neglected dumps of this material has increased in recent years causing a rise in air pollution. Surface methods of coal waste disposal are still being practised, and in many cases new material is being added to old dumps, many of which are burning. CSI RO has conducted research on methods of preventing and controlling fires in coal waste and recommends practical methods of overcoming these problems. Some laboratory and on-site investigations are described and the hazards of improperly constructed dumps are considered. The available techniques of fire prevention and control are discussed in relation to Australian conditions. Proposals for the safe and economical disposal of coal waste are outlined.

Jan 1, 1970

By Bin Xu, Qian Li, Xiaoliang Liu, Yongbin Yang, Tao Jiang, Yan Zhang

The cohering behavior of iron ore pellet powder in kiln cannot be reflected entirely through the conventional briquetting method, so a novel natural stacking method was proposed in this paper. The results showed that in the two methods the cohering strength of powders from different iron ore pellets (numbered A, B and C) rose with the increase of roasting time and temperature andpresented the same result, i.e., C > B > A. Comparatively, the natural stacking powders obtained much lower cohering strengths under the same roasting condition. The structure analyses of ring from the kiln tail and cohering briquette by the natural stacking method indicated that the occurrence of crystallized particles of them were extremely similar. Therefore, the initial information of pellet powder’s cohering behavior could be provided by the natural stacking method, improving the methods to study the actual ringing process and mechanism of pellet powders in kiln.

Mar 1, 2017

By M. J. Ferrante

Enthalpy and entropy increments above 298.15° K were determined for cop-per sulfate between 298° and 1,000° K and for copper oxysulfate between 2980 and 1,146° K by the method of copper-block drop calorimetry. Enthalpies, entropies, and heat capacities are tabulated for both compounds. In addition, free-energy functions are tabulated for the sulfate. Equations representing the enthalpies are given for each compound.

Jan 1, 1972

By Steven G. Jansto

Carbon content and continuous casting parameters affecting solidification behavior, such as super heat, mold level fluctuation, heat transfer, fine grain chill zone depth and other process solidification parameters directly influence the surface and internal quality of the steel strand. The carbon content, resultant fine grain chill zone depth, the equiaxed-columnar transition zone and the strain energy are the primary drivers that govern hot ductility behavior. These factors influence the propensity for crack formation during the unbending section in the continuous casting process. Elements such as microalloys exhibit secondary or tertiary root causes for crack formation and are not the primary crack formation root cause. This solidification research identifies that the traditional hot ductility as measured via the percent reduction in area (%RA) at elevated temperature grossly overstates the minimum ductility required to assure crack-free casting of microalloyed steels. The strain at the ultimate tensile strength exhibits a very high correlation coefficient with strain energy while an extremely low correlation coefficient is exhibited with %RA.

Oct 30, 2017