Search Documents

The AG/SAG circuit discharge P80 is now increasingly referred to as the ?Transfer Size? or T80 for short. From the literature it is apparent that in circuit design some approaches to the sizing of AG/SAG mills as well as the ball mills that they feed use this parameter. This paper reviews whether the use of the T80 is appropriate in this context. In the course of the review examples of AG/SAG discharge size distributions measured from range of operating circuits are used to illustrate the arguments made.

Jan 1, 2012

By Joseph A. Corgan

The river- or dredge-coal industry of Pennsylvania is conducted on many of the rivers and creeks that drain the Pennsylvania anthracite fields. Coal thus recovered found its way into the streams as coal was being prepared for market by the anthracite industry proper, in the northeastern part of the State. The Principal rivers draining; the fields, those where dredging is taking place, are the Susquehanna, Schuylkill, and Lehigh. Several creeks - the Shamokin, Mahanoy, Wiconisco, and Swatara - also are productive sources of river or creek coal. Operations along the streams cover a wide territory, and along the Susquchanna alone; dredges are recovering coal for about 160 miles. Anthracite was a significant factor in the early industrial development of the United States. Industry used it to generate steam, and railroads used it as fuel for locomotives; but it probably was most important industrially in the smelting of iron ore. For more than a hundred years homes have been heated with this fuel. From the beginning of mining in 1807, to 1940, more than 4 billion net tons of anthracite had been prepared and shipped to market. In the preparation process much of the smaller-size coal and refuse found their way into rivers and creeks which carried the material many miles. This study is concerned with the recovery of that anthracite from those rivers and creeks.

Jan 1, 1942

By J. R. Ruark

This report presents results of the research and development work and operations performed during stage II of the gas combustion retorting research program conducted by the Colorado School of Mines Research Foundation and six major oil companies at the Bureau of Mines Anvil Points Research Facilities. The experimental program, including retort modification and air-gas distributor development, effects of shale quality and particle-size distribution, and other variables on the process, is discussed. Although operating problems are not fully resolved, it appears that the gas combustion retorting process can be successfully applied to achieve oil yields in excess of 85 percent of Fischer assay at mass shale feed rates of 500 pounds per hour per square foot of cross-sectional bed area, approximately twice the rate previously demonstrated to be reasonably practicable.

Jan 1, 1971

By R. J. Sawyer

The Greens Creek underground polymetallic mine restarted production in 1996 from a newly discovered high grade ore zone. Efforts to improve payable gold recovery have focused on gravity separation. The paper compares testwork and plant results for a newly installed gravity circuit.

Jan 1, 1997

J. S. UNGER, ? Pittsburgh, Pa. (written discussion ?).-Firebricks intended for, the same purpose, but supplied by different manufacturers, may be of entirely different clays, contain different proportions of flint, calcined and plastic clays; the particles may vary widely in size; the water used to make the brick will vary; the pressure in molding will vary, depend-ing on whether the brick is hand made or power pressed; and the degree of burning in the same kiln will differ. These variables affect the melting point and the strength of the brick when heated. An important property, of a firebrick is its ability to resist heat and, at the same time, weight or load without serious deformation. The soft-ening point and the melting point of a firebrick may be several hundred degrees apart, and two bricks may show considerable difference in their softening points, but the melting points may be approximately the same. Bricks are not usually employed at temperatures close to their melting points. If they must withstand very high temperatures, the firebrick is discarded and a brick of more refractory material is used. Under these conditions' it is doubtful whether the determination of the melting point of a brick has much practical value. If the determination of the melting point is necessary, the test should he made on a portion of the original brick and not on a specially prepared sample. A small triangular pyramid with a base about 1 1/2 in. and 3 in. high can be sawed from the corner of the brick with a thin-bladed car-borundum wheel, without injuring or destroying the size of particles, the bond, or degree of burning of the original brick. This specimen can then he compared with standard Seger cones or tested by any other method desired.

Jan 12, 1919

By A. E. Boudreau

Abstract-It has long been recognized that platinum-group-element (PGE) deposits in layered intrusions preferentially occur in intrusions that crystallized from high-Mg parent magmas. Recent studies suggest that evaluation of any given intrusion for economic PGE potential should also include assessment of the PGE, sulfur and chlorine concentrations in the cumulates and potential parent liquids. PGE: Magmas that contain relatively abundant Pt and Pd are the best candidates for forming economic deposits. Although analyses of coeval sills and dikes are the best indicators of primary magmatic PGE concentrations, analysis of the cumulates themselves is also valuable. For example, within the Stillwater complex, background PGE values in cumulates from the ultramafic sections of the complex contain, on average, several 10s of ppb Pt and Pd. Background concentrations of this order are suggestive that the magma was not depleted in the PGE. Sulfur: Conventional petrogenetic models for the formation of PGE deposits in layered intrusions require the PGE to have been concentrated during a magmatic sulfide-saturation event. In contrast, some hydrothermal models suggest that sulfur and the PGE were mobilized from footwall cumulates by upward- migrating, high-temperature hydrothermal fluids. Both models suggest that significant PGE deposits are likely to occur at and below the level where stratigraphic increases in whole rock sulfur concentrations occur. Chlorine: In both the Stillwater and Bushveld complexes the cumulate sequences below the major PGE-bearing zones contain anomalous Cl-rich apatite. The chlorapatite component of apatite in these rocks may exceed 40% and, in the Stillwater complex, typically exceeds 90%. It is stressed that pristine igneous mineral analysis and not whole rock data be used, as whole rock Cl concentrations may be affected by very localized (grain boundary), low-temperature alteration. Intrusions that crystallized from high-Mg, high-Cl magmas appear to have the best potential to host significant PGE deposits.

Jan 1, 1995

By J. Bennetts

As part of its mission to develop technology that will help increase the supply of critical and strategic minerals from domestic resources, the Bureau of Mines has investigated methods for beneficiating platinum-group metal ores from the Stillwater complex, Montana. This report presents the result of a bench-scale study employing froth flotation to recover a sulfide concentrate containing platinum-palladium values from a mineralized gabbro. Best results were obtained with a flotation scheme utilizing a mercaptobenzothiazone collector and sulfuric acid. Rougher concentrates containing approximately 11 oz Pt-Pd/ton and 90 pct of the metal values in the ore were obtained. Subsequently, cleaner concentrates containing approximately 26 oz Pt-Pd/ton and between 80 to 85 pct of the Pt-Pd values in the ore were prepared.

Jan 1, 1980

By M. Ghamgosar, Erarslan N.

Rock cutting includes many unknown parameters which result in different consequences of the different cutting conditions. However, based on the current suggested models for rock cutting, there are some critical parameters that control the fracture initiation and propagation in the rock domain. In general, there are two major cutting tools are used in rock cutting: drag bits and indenters. Different mechanical attacks of cutters result in different fracture models. For example drag bits break the rock parallel to the rock surface, which is called ‘undercutting’ while indenters cut rocks by pressing normal to the rock surface. Both tools cause rock failure by inducing tensile cracks in the rock. However, drag bits induce more tensile cracks compared with the indenters. The full benefits of improvement in rock cutting efficiency will arise from a clear understanding of rock fracture mechanics principles. Therefore, fracture mechanics principles will be applied to the rock cutting as the rock fragmentation process is based on the rock fracturing. The Oscillating Disc Cutting (ODC) has more advantages than drag bits and disc cutters. The forces transmitted back through the cutting head are much lower with ODC. Although ODC attacks rock in much the same way as drag bits, a combination of the oscillating action of the cutter and the undercutting mode produces the lower cutting forces and causes rock fatigue. Fatigue phenomenon in rock has advantages for the rock breaking by applying less effort and energy due to the cyclic loading. The aim of this study is using the Extended Finite Elements Analyses (XEFM) numerical modelling for simulating the ODC cutting with different cyclic loading conditions. An accurate prediction of numerical investigation requires detail laboratory experiments. A series of laboratory tests were performed to obtain the fracture toughness values of our Monsonite rock samples under various cyclic amplitude and frequency values. The numerical results showed different types fatigue damage mechanisms due to the various cyclic loading conditions. Thus, modelling and understanding the crack propagation behaviour depending on different amplitude and frequencies are believed very important for the dynamic rock cutting researches and rock cutting machine manufacturers.

Jan 1, 2015

By Holger Witthaus

Beside the traditional geomechanical evaluation methods the geotechnical parameters are recognized as important facts of the planning work for multiple seam mining. Standards for applied monitoring and investigation methods for geotechnical determination of drill cores, laboratory rock-tests and observation of roadheadings are the basics for rock mechanics classification and support design. The geomechanical classification is in this context an essential element. The planning procedure, as it is becoming more and more detailed, beginning with the panel layout up to the technical instructions of roadway development and design of roadheading machinery, nowadays uses a lot of geotechnical information that also are expanding to include quantitative determination of more parameters. The current monitoring system includes the description of separation planes using drill cores and roadheading observation as well as laboratory tests of rock-strength and geophysical borehole examinations. This information is analyzed within the geomechanical standard-classification. The re-engineering process of comparison the predicted support success to the actual monitoring results provides the opportunity for continuous optimization of the planning work und support design. This way of empirical analysis is used for basic planning work in Germany for decades. But using the technical standard of information technology and a centralized database now it is possible to reach quick-win effects in implementing research results on the one hand and actual experiences on the other hand.

Jan 1, 2006

By Robert M. Dreyer

Thirty years ago it was possible to locate a quarry site for crushed rock for concrete aggregate by finding the nearest solid rock bluff accessible by road, But times have changed and the location of a quarry site to furnish crushed rock for concrete aggregate now has become rather complicated, Although both sand and gravel can be used for aggregate, this discussion will be confined to crushed rock in the regions around a metropolitan area. Let us assume that a consultant has been retained to advise on the desirability, and the possibility, of opening a new quarry within a given area. The problems are geological and ecological. Since the geological problems are simpler, they will be discussed first. Generally, the first step is to make a market study of competitive aggregate sources within the projected area. Assuming that the quality of aggregate to be sold by competitors as well as their mining costs will, within narrow limits, be the same, the problem becomes essentially a study of haulage costs from established quarries into the projected new area. Since haulage cannot be effected along straight lines and since each quarry operator may have different unit haulage costs, a map showing lines of increasing cost intersecting points on roads available for truck haulage radiating from competitive quarries can be rather complicated. Such a map, more-over, changes each time a new haulage contract is negotiated by a

Jan 1, 1971

By Robert W. Miller

There are many problems faced by ventilation engineers in deep underground mining operations, not the least of which is controlling miner exposure to radon gas and its daughter products. Radon gas is commonly found in uranium mining operations, but may also be present in other deep metal mines. For example, tin mines in England, iron ore mines in Sweden, gold mines in South Africa, and molybdenum mines in the U. S. have potential radon exposures. This is because uranium and accompanying radium ore are ubiquitous to the earth's crust albeit at low levels. The fact that the activity represented by one WL can be caused by a relatively low concentration of radon gas increases the difficulty of control. Since the source of the radon gas is usually widespread throughout a mine, local exhaust ventilation is not a viable control schema. The technique used to control exposure is then dilution ventilation and, in fact, huge amounts of air must be moved in order to reduce potential exposures to an acceptable level. An interesting comparison can be made of ventilation rates in different types of mines. It is estimated in modern coal mines, which are generally acknowledged to have high rates of ventilation, that about eleven tons of air are moved for each ton of ore mined. A typical operating uranium mine may have ventilation flows of 14-15 tons per ton of ore mined. This provides an idea of the scope and importance of ventilation in modern mining operations where radon is a hazard. Further pressure is put on ventilation engineers by the steady downward trend in exposure limits set by national and international standard setting agencies. Much of this tendency toward lowered standards is based upon longitudinal mortality studies of miner populations. Another important factor is the limited number of experienced miners available in the labor pool. For optimum production, it is important to have as many experienced miners underground in each shift as possible. However, the average daily exposure in a U. S. mine must be less than .3 WL to permit the miner to work underground for a full year. The ventilation system then must provide enough uncontaminated air to maintain the WL below the .3 TTL level to maximize production efficiency and minimize personnel turnover and the problems associated with it. Ultimately, the goal of the ventilation engineer and health physicist is to protect the working miner from harmful exposures based upon currently acceptable standards. U. S. Federal regulations require that in uranium mines all active work sites must be monitored every two weeks if they measure above .1 WL. Areas that have .3 WL ratios or higher must be monitored on a weekly basis until five consecutive weekly samples show the level has dropped below .3 WL. Also, exposure records must be kept for all individuals exposed to levels exceeding .3 WL. These requirements provide a strong economic incentive to have a ventilation system that minimizes exposure of any personnel. A good ventilation system requires careful planning, operation and backup in order to fulfill its mission of providing adequate clean air. Its proper operation also requires coordination with production personnel so it can be adapted as new areas in the mine open up and old areas are sealed off. The ultimate indicator of ventilation efficiency to control radon daughter exposure is, of course, monitoring working levels. Historically, this has been done using the Kusnetz, Tsivoglou, and Rolle's methods, among others. These methods all require cumbersome equipment and tedious calculations to obtain the measurements that results in WL. More important, however, they require a significant time lag between sampling and counting, typically 40-90 minutes. This time lag is, in fact, what can cause significant economic losses due to unnecessary downtime as well as high WL exposures. In a typical mining situation, a sampling technician using the Kusnetz method takes a sample, moves to the next location and takes another sample and so on. Forty to ninety minutes after the first sample, the technician will stop, run the activity count on the filter and calculate the WL. The technician may be one-half mile away or several levels removed from where the first sample was taken when it is counted. If the WL ratio is high the technician must then backtrack to the sample position. There are then two options. If the sample area is a working stage, it can be shut down or a second sample can be taken. If the first alternative is chosen; i.e., shutdown and correction of the ventilation, then another sample must be taken, followed by a forty minute wait for results. If the ventilation adjustment didn't correct the problem, then the whole process must be repeated with a minimum of forty-five minutes per sample cycle when using the Kusnetz method. It has been estimated from operating uranium mines that the cost per hour for downtime on a production slope is about $1,50O/hour. The time lag between sampling and resultant data can be very costly. If the second alternative is chosen to verify the first reading, the miners may be unnecessarily exposed to high levels while waiting for the result. Clearly, such a sampling system can be markedly improved by eliminating the excessive time lag between sampling and analysis.

Jan 1, 1981

By Brandon M. Robinson, Osman F. Besler, Dominik Gaechter

With the increase in population over the last decade, and anticipated population growth over the coming years, Norway is making significant investments in the Country’s infrastructure. Part of this investment in development starts with the Intercity development project in South-East Norway, which is the largest transport project in Norway. The Intercity Development project consists of 270 km (167 mi.) of new doubletrack rail, capable of train speeds reaching 250 km/h (155 mph). The new stations are centrally located in the major cities, in South-East Norway, to provide the benefit to as many citizens as possible. The goal of the project is to reduce the increase in traffic, which is coupled with an increase in population, and reduce the travel times between the cities. The Intercity Development Project has an anticipated completion date of 2034. The Sandbukta-Moss-Såstad (SMS) project, part of the Intercity development, includes 10 km (6.2 mi) of new double-track railway and is situated on the Østfold Line, near the city of Moss, Norway shown in Fig. 1. The 10 km SMS-section covers three open stretches and two tunnels, including 630 m (2,066 ft) substructure for double-track railways on the open line at Sandbukta. The Moss tunnel is a 1720 m (5,643 ft) long tunnel from Sandbukta to Moss center, including a 420 m (1,378 ft) long concrete culvert. The new Moss station includes an 800 m (2,625 ft) long station area. The Carlberg tunnel is a 2350 m (7,710 ft) long tunnel from Kleberget to Carlberg, including a 200 m (656 ft) long concrete culvert.

Sep 8, 2021

By Gary Buchan

"Mine-wide ground control stability is essential to any mining operation to prevent catastrophic failure of underground structures. The ability to recognize or indicate the potential for ground control hazards in underground mine operations is highly desirable to reduce or eliminate ground-control-related injuries and fatalities. The acoustic emissions (AE) form of non-destructive testing has been used for decades to determine material or machine deterioration or potential failure. This paper presents the findings of research in AE with the results of laboratory bolt pull tests and comparisons to field experimentation, including AE sensors and bolt load data in an underground stone mine. The goal of the project is to compare laboratory results of AE sensors on roof bolt pull tests with field experimentation to determine the capability of predicting bolt failure or roof deterioration.INTRODUCTIONMine-wide ground control stability is essential to any mining operation to prevent catastrophic failure of underground structures. The ability to recognize or indicate the potential for ground control hazards in underground mining operations is highly desirable to reduce or eliminate ground-control-related injuries and fatalities. Typical ground control monitoring devices involve drilling into roof or rib, grouting or gluing of sensors, and dedicated cabling for data collection. One of the original goals of this research was to develop a methodology for a simple wireless device that could provide an indication or warning of potential roof bolt or roof failure. Various types of nondestructive testing (NDT) have been used for decades to determine material or machine deterioration or the potential failure of either. One type of NDT is acoustic emission (AE) monitoring, which has been studied for use in mining to predict rock bursts and mine failures since the 1940s (Obert, 1941; Obert and Duvall, 1942). The primary goal of the work was to compare laboratory results of AE sensors on roof bolt pull tests with field experimentation to determine the capability of evaluating bolt loading or roof deterioration in an underground stone mine. Bolt pull tests were conducted in the laboratory to establish a repeatable trend of AE activity versus bolt load. The second part of the project was to then install bolt load cells in an underground stone mine and monitor AE activity in the vicinity of mining."

Jan 1, 2018

By Albert C. Harding

FOR several years barite (BaSO4) production has topped such better known minerals as feldspar and fluorspar in annual tonnage and is now well established among our foremost nonmetallic industries. DESCRIPTION Of widespread occurrence in the United States, barite is relatively soft (hardness, 2.5 to 3.5), inert, heavy (specific gravity, 4.5), and is also called "barytes" (sometimes pronounced "bear-i-tease"), "heavy spar" and "tiff." It occurs with granular and earthy structure but usually has coarse, orthorhombic crystallization. It is commonly white, and although occurring in various shades of red, yellow, and gray, barite always gives a white streak and can be scratched by the ordinary prospecting pick. Its softness and weight are usually sufficient to establish field identification. Another aid is the "rotten egg" odor of H2S which sometimes emanates from freshly fractured surfaces. Barite can be readily distinguished from two other minerals which have somewhat similar occurrences and characteristics. The relatively rare celestite, strontium sulphate, has a specific gravity slightly less than 4.00 and gives a distinctively crimson color in a flame test. The very rare witherite, barium carbonate, has a specific gravity of 4.3 but readily effervesces with dilute hydrochloric acid. OCCURRENCE All known commercially important barite deposits in the United States occur as re placements or cavity fillings in schists, shales, limestones, dolomites, and quartzites, or as residual deposits from such formations. In Georgia, Tennessee, North Carolina, and Missouri, high-grade barite is recovered as fragments from residual clays covering quartzites and dolomites. In Arkansas, Nevada, and California, barite, usually of lower grade, is mined from replacement deposits. These seven states contributed the entire production reported by the U. S. Bureau of Mines for 1945 as given in Table I. [TABLE 1-Crude Barite Sold or Used by Producers in 1945 STATE SHORT TONS Arkansas260,660 Missouri225,467 Georgia110,393 Tennessee32,812 Nevada28,919 Other States37,811 Total 696,062] "Other States" included only California and North Carolina. Such a large part of this undistributed production came from California that that state probably outranked both Nevada and Tennessee. For the second consecutive year Arkansas was the leading producing state, particularly worthy of note because there was no commercial production of barite there prior to 1941 and because the entire production of Arkansas has come from one large deposit which is being operated by two companies. CONSUMPTION [The 1945 consumption as reported by the Bureau of Mines was: 482,442 tons as ground barite 139,288 tons in making lithopone 99,173 tons in producing barium -- chemicals Total 720,903 tons]

Jan 1, 1947

By J. Brian Anderson

Jointed micropiles were investigated to support bridge foundations where shallow rock was present. In this application, micropiles would have some amount of unsupported length, and would be subject to nominal lateral loads. Five lateral load tests were conducted on micropiles to demonstrate the impact of casing joints and rock socket embedment on lateral behavior. Load tests were simulated with FB-Multipier, a hybrid-finite element program for analysis of deep foundations, for proper design of the loading apparatus and instrumentation. The micropile sections were 2 m (6.56 ft) long, 273 mm (10.75 in) in diameter, 13 mm (0.5 in) thick walled, with a 50-mm (2-in) long threaded joint. Micropiles were made of one to three casing sections and were embedded 0.3, 0.6, 1.5, or 3.0 m (1, 2, 5, or 10 ft) into rock. In each test, two identical micropiles were pulled together using a simple frame until the weaker pile failed. All micropiles were instrumented with inclinometer casings while two contained strain gages at 0.76 m (2.5 ft) intervals. Load and displacement were measured at the pile heads. Tests showed the embedment of 0.6 m, 1.5 m, and 3.0 m (2 ft, 5 ft and 10 ft) sufficiently carried lateral loads over 180 kN (20 tons). The piles embedded 0.3 m (1 ft) were not able to maintain lateral load. In general, all micropiles tested to failure exhibited a brittle failure mode where there is small lateral deflection followed by a sudden failure at the casing joint. This was demonstrated in three of the load tests. In most cases, the micropiles were stiffer and stronger in the load tests than originally predicted numerically. The final test, where piles were not loaded to failure, verified that embedding vibrating wire rebar strain meters in the grout captured the bending moment profile of the micropile. The results showed the maximum moment in this case being carried directly across the threaded joint as predicted by the preliminary models. The results of these tests were used to calibrate the FB-Multipier numerical model. Using a load test that included bending strain measurements for a match, the soil properties were adjusted to produce reasonable matches for all of the load tests.

Jan 1, 2011

By G. V. Jere, C. C. Patel

Chlorination of the various constituents of ilmenite by different chlorinating agents in presence of various reducing agents, have been considered on the basis of the standard free energy and standard enthalpy changes as a function of temperature. The standard free energy change considerations show that it is beneficial to chlorinate ilmenite by chlorine in the presence of carbon and also that iron constituent of ilmenite can be preferentially chlorinated by clzlorine, titanium tetrachloride or their mixture. These findilzgs have been corroborated from the published work. METALLURGICAL processes involving the use of titanium tetrachloride have gained in importance because of the use of the latter in the manufacture of titanium metal. Since ilmenite is more abundant in nature than any other titanium mineral, the future of the metallurgical processes depends on the utilization of ilmenite for the production of titanium tetrachloride. In these laboratories, investigations have been carried out on the chlorination of ilmenite under a variety of conditions.1'2 During these studies, it was noticed that 1) preferential chlorination of iron was effected at low temperatures (400° to 600°C) and at low carbon content (6 to 7 pct), 2) carbonyl chloride retarded the chlorination of iron oxides and titania perceptibly, while 3) carbon-tetrachloride, compounds of sulphur and some other catalysts favored the chlorination. Moles3 has found that oxides of iron are chlorinated in preference to titania at high temperatures, while wilcox4 has claimed the preferential chlorination of titania between 1200" and 1500°C. It has been shown in this paper that preferential chlorination of titania claimed by Wilcox is not likely to occur. Daubenspeck and coworkers5,6 have claimed the preferential chlorination of iron by chlorine or by a mixture of titanium tetrachloride and chlorine between 700° and 1050°C in the absence of carbon. Even when plain titanium tetrachloride is employed as the chlorinating agent, pascaud7 noticed the preferential chlorination of iron and other oxides. The purpose of this paper is to explain from thermodynamical considerations, the various chlorination reactions studied so far. ILMENITE CONSTITUENTS AND THEIR CHLORINATION PRODUCTS Although the general composition of the ilmenite mineral is represented as FeTiO,, most of the ilmenites found in nature have variable quantities of TiO2 (44.6 to 64 pct), FeO (4.7 to 36 pct) and Fe2O3 (6.9 to 28 pct).8 The higher content of ferric iron in ilmenites was attributed by Millerg to the presence of arizonite (Fe2O3.3TiO2). But the X-ray studies by Overholt, Vaw, and odd" have shown that arizonite is a mixture of haematite, ilmenite, anatase, and rutile. Except for the anatase, similar views have been advanced by Lynd, Sigurdson, North, and Anderson8 from magnetic, X-ray, and optical and electron microscope studies. The ilmenite ores can, therefore, be assumed to consist of mineral aggregates of ilmenite, rutile and haematite. From the free energy of formation of ilmenite (FeTiO3), it has been shown by Kelley, Todd, and King11 that ilmenite is stable even up to its melting point (1367°C) and would not undergo decomposition into its constituent oxides. Schomate, Naylor, and Boericke12 have found that in the presence of a reducing agent the iron constituent of ilmenite is selectively reduced. The reaction of chlorine with ilmenite in presence of a reducing agent can, therefore, be synonymous with that of the reaction of chlorine with the constituents of ilmenite, viz., TiO2, FeO, and Fe2O3. Most of the reaction products of chlorination of ilmenite in the presence of reducing agents will be in equilibrium with their dissociation products, depending on the temperature. The titanium tetrachloride is, however, quite stable up to 1500°C due to its covalent nature. The equilibrium for the ferric chloride system has been investigated by Kangro and Bernstorff, 13, schafer14 and Kangro and petersen,15 and the results are summarized in Fig. 1, curves a, b, and c respectively. From these results, it is clear that the ferric chloride disociates as follows: 324° to 700°C FeaCl6(g) ?2FeCl2(c) + Cl2(g) [1] 324°to 900°C Fe2Cl6(g) =2 Fe Cl2 Reaction [I] (curve a) occurs in the forward direction to about 6 pct at 400°C but falls off very rapidly with increase in temperature and beyond 600°C, it is practically negligible, perhaps due to the formation of the stable monomer, FeC13(g). As the temperature is further increased, the amount of FeCl,(g) in-

Jan 1, 1961

By Irven A. Jacobson

This literature survey consists of references dealing with gaseous state thermal decomposition reactions of organic nitrogen and sulfur compounds. The reference source for the survey was the Chemical Abstracts from 1930 to 1956, inclusive. Original articles were not studied. The starting date was set at 1930 because previous to this time much of the work is questionable. This report is in three parts: Part I lists nitrogen compounds; Part II, sulfur compounds; and Part III, compounds containing both nitrogen and sulfur. The organization of the classes of compounds is alphabetical: Part I - amides, amines, amino acids, ammonia, azides, azines, azo compounds, heterocyclic nltrogen compounds, hydrazine, nitrates, nitriles, nitrites, nitro compounds and miscellaneous nitrogen compounds; Part II - disulfides, sulfides (including double and triple sulfides), thiols, thiophenes and xanthates; Part III - thioacid amides, thiazoles, thiocyanates and thiuram disulfides. A class formula is included with each class name. The R's used in these class formulas may refer to hydrogen or to the same or different radicals when more than one R appears.

Jan 1, 1960

By C. M. Mason

Bureau of Mines studies were made on the sensitivity of several ammonium nitrate-fuel oil (AN-FO) mixtures to bullet impact. The experimental work was done with one military rifle and two high-velocity sporting rifles with a variety of ammunition. For the three rifles used, the order of efficiency in initiating detonation in AN-FO mixtures was 220 Swift >300 Weatherby Magnum >30-&apos;06. The velocity of the bullet was found to be a decisive factor in the initiation. The sensitivity of various materials studied increased as follows: Clay-coated prills with 4 percent oil <fresh surfactant-coated prills with 4 or 6 percent oil <surfactant-coated prills with 4 or 6 percent oil and aged 270 days <crushed prills with 6 percent oil <very low-density, surfactant-coated prills (micronized), with 4 percent oil.

Jan 1, 1963

By J. Bigu

A theoretical radiation mine model, suitable for underground uranium nines, has been investigated. In this model, the rate of ventilation and/or the radon (thoron) gas emanation from mine walls are time-dependent. Several cases of practical interest have been investigated including sinusoidal, linear, exponential, stepwise, or a combination of two or more of the above. Analytical solutions were obtained for the time-dependent radon (thoron) gas emanation rate. However, because of the extreme analytical complexity of the solutions corresponding to the time-dependent ventilation rate case, numerical solutions were found using a special Runge-Kutta procedure and the Hamming&apos;s modified predictor-corrector method for the solution of linear initial-value problems. The mine model makes provisions for losses of radioactivity, other than by ventilation and radioactive decay, by, say, plate-out on mine walls, and by other mechanisms. Radioactivity data, i.e., radon, thoron, and their progeny. obtained with the above mine model for a number of ventilation and emanation conditions, are presented. Experimental data obtained in an inactive stope of an underground uranium mine for a time-dependent air flow case are shown. Air flow conditions (ventilation rate) were determined by tracer gas techniques using SF6.

Jan 1, 1987

By M. A. Schellhardt

The Bureau of Mines has made periodic back-pressure tests on numerous gas wells in the Texas Panhandle field luring the past several years to study the delivery capacities of the wells under different pressure and operating conditions and to determine the relationships between pressures and rates of delivery from gas wells.4/ However, information regarding the intake capacities of gas-well systems is meager, end in projects involving- the flow of gas into porous-rock reservoirs it has been necessary to determine intake capacities of gas wells by trial. Accordingly the fundamental intake characteristics of natural-gas wells have been studied to develop a method for determining intake capacities under different wellhead pressures from data descriptive of the "output" or producing characteristic of the wells.

Jan 1, 1936