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By Kevin Tallent

The use of military-type energetic materials in commercial explosive products is not a new concept. In the United States, the techniques for utilizing significant quantities of surplus military explosive materials by commercial explosive manufacturers dates back to the 1950’s. At times, explosive companies have found surplus military high explosives and propellant materials to be suitable ingredients for their commercial explosive products. The availability of these military-type energetic materials has varied over the past 50 years, as a function of the military’s strategic defense needs and the advances in modern weapon technology. For the most part, the commercial explosives industry has been able to implement methods for safely incorporating military-type high explosives and propellant materials, whenever these surplus materials become available. During the past 5-6 year period, a large amount of military-type energetic materials have once again become available for recycling into commercial explosives. This situation can be attributed to a number of factors, such as the political changes in Europe, the development of more sophisticated weapons systems, and the increased EPA pressures on the U.S. Department of Defense for disposing of surplus energetic materials. As in the past, U.S. commercial explosive manufacturers have made efforts to recycle these surplus materials into their explosive products. This paper describes some of the commercial explosive products that are currently on the U.S. market, which contain rocket and gun propellants as energetic ingredients. Some U.S. explosive companies, such as DYNO NOBEL, ORICA and Slurry Explosive Corporation, have been able to recycle significant quantities of surplus smokeless powder and composite propellants as energetic ingredients into their commercial Blasting Agents. The successes enjoyed by these companies have once again shown recycling into commercial explosive products to be an economically and environmentally sound method for disposing of surplus military-type energetic materials.

Jan 1, 2000

By Ricardo Tadeu Meneses Sodré

Principalmente após a crise mundial de 2008, as grandes empresas brasileiras focaram na redução de custo como fator de sobrevivência, buscando manter, em contrapartida a produtividade e qualidade dos produtos. As normas brasileiras ABNT NBR ISO 55000/1/2, combinam atividades sistemáticas, coordenadas e práticas pelas quais uma organização gerencia de forma organizada e sustentável seus ativos tangíveis e intangíveis e sistemas, seu desempenho, bem como seus riscos e custos associados. A norma trata do ciclo completo do ativo, desde a concepção até o seu descarte. A implantação de uma norma deste porte requer compromisso de toda organização, principalmente da alta direção, no intuito de correlacionar os objetivos do negócio com as atividades de manutenção. O ponto principal é entender que a Manutenção é parte de um ciclo mais amplo que trata de todo o ciclo de vida do ativo, logo a Manutenção está contida dentro da Gestão de Ativos. O trabalho visa mostrar de maneira prática como a ArcelorMittal Tubarão está se estruturando para uma implantação futura da ABNT NBR ISO 5500X. Tal estruturação engloba atividades estratégicas, táticas e operacionais de alto nível visando à elevação da maturidade em Gestão de Ativos.

Aug 7, 2018

By S. Rajeswari, D. Gopi

"Pitting corrosion inhibition of 304 stainless steel (SS) in groundwater with a ternary inhibitor mixture (phosphonic acid + bivalent cation + various surfactants) was studied with different environmental variables such as temperature, pH, dissolved oxygen and chloride ions. Critical pitting potential and corrosion potential were calculated for these test media using electrochemical techniques. Under the tested condition, the localized corrosion resistance of 304 SS was determined and the results are discussed. IntroductionPitting corrosion of metals and alloys is a major cause of failure in chemical processing desalination plants, scrubber for flue gas desulphurization (FGD) plants, water storage tanks and pipelines, petroleum refineries, etc.Heat exchangers and condensers in inland thermal and nuclear powerplants utilize groundwater as a coolant, but materials of construction are generally prone to localized corrosion.Localized corrosion attack can be initiated when the passive film on the metal is disrupted. The presence of certain aggressive anions such as chlorides (Cl-) can migrate to the actively corroding area and stabilize pitting corrosion. Attention has been focussed on improving the resistance of stainless steel against localizedcorrosion in aqueous environments.One of the most accepted methods of avoiding corrosion is by the addition of chemicals (inhibitors). Over the past two decades, some phosphonic acids have been explored due to their good corrosion inhibition efficiency and low toxicity (Fang et al., 1993; Karman et al., 1998; Rajendran et al., 1998; Gopi and Rajeswari, 2000a). Bivalent cations like Zn2+ are often applied as additives to inhibit the metal dissolution (Sekine and Hirakawa, 1986; Aruna Bahadur, 1998)."

Jan 1, 2003

By Moshe Sheinkin, Burke O. Trafton

This paper describes the use of a computer in analyzing the expected return on a mining venture. The computer program is designed to incorporate all aspects of a mining project, including the mine, mill, smelter, and refinery. Data input may consist of the operating variables in each phase such as the mining rate, grades, reserves at the mine, and the technical operating characteristics of the mine, mill, smelter, and refinery. Detailed tax computations are shown for a domestic operating company, for a foreign company and for a foreign subsidiary. In addition, the use of the various options that are available such as expense write-offs or deferments to create tax credits during preproduction years are considered, and its effect on the DCF. The program is also constructed to accommodate changes in metal prices, and escalation of capital requirements and operating costs. Output consists of profit and loss statements for entire projects using different methods of depreciation, cash flows, discounted cash flows, net present value and returns on investment. Returns on investment are computed for equity investment, total investment, and total investment less tax credits. Allowances are made for bank and guaranteed loans. Additional financial statements can be made for the following: a) A mine-mill segment with a concentrate selling schedule b) A mine-mill-smelter complex with a smelter product selling schedule c) Profitability of the smelter separately d) Profitability of the refinery separately

Jan 1, 1969

By T. G. R. Rawlins, L. E. Brosselard

Direct platinum carbon replicas have been used to study substrates prior to growth and after initial nu-cleation of the layer. Replicas have been directly stripped and correlations have been made with other replica techniques. Mechanically polished substrates are very flat with occasional areas of "dirt", which is apparently silicon. When such substrates are etched in hydrochloric acid gas, scratches and hexagonal defects (thought to be polishing compound) are revealed, together with areas of apparent redeposition. Chemically polished substrates are much less flat although much more homogeneous in appearance. Heat treat)nents have no effect. Nuclei deposited on these surfaces, using a normal silicon tetrachloride system, have been examined. Nuclei on mechanically polished subsrates occur in random areas only, whereas on chemically polished surfaces they are more uniformly distributed. THE interest in the study of thin films and now their rapidly expanding use in many fields has increased over a period of years. Much of this current interest, particularly in the field of single-crystal or epitaxial thin films, has derived its stimulus not only from possibilities for application but also from fundamental electron-microscope studies which have indicated the manner of growth of such layers from the initial nuclei.1-5 Previous work involving study of growth processes may be divided into three categories. First, vacuum deposition, primarily of metals, on a variety of substrates has been studied by electron microscopy and electron-diffraction techniques. These have shown the three-dimensional aspect of nucleation and the remarkable liquidlike behavior of the growing nuclei which coalesce to form a complete layer. More recently this work has been expanded in two ways: by growth inside the electron microscope this has obvious advantages for kinetic studies; and by growth in ultrahigh vacuum—much of this work has been done on semiconductors.8-11 It is of interest to note that metals, specifically gold deposited on rock salt, will form only polycrystalline layers in ultrahigh vacuum unless the substrate surface is contaminated.12 In general the mode of growth for vacuum-deposited semiconductor films is the same as that for metal films. The second method of growth that has been studied is that of electrodeposition.13,14 The little that has been published suggests that the mode of growth is similar to the vacuum case, except that irregularities may perturb the electric field and disturb the growth process. The third and last primary method of growing epitaxial layers is by use of chemical methods. These techniques have generated much interest and much has been published on them. Considerable electron-microscope work has been done on the defects in the layers; however comparatively little work has been undertaken on the initial nucleation and early stages of growth. Confining ourselves now exclusively to the case of silicon, Charig et a1.15 have considered the growth of silicon on silicon substrates by hydrogen reduction of trichlorosilane, and studied the films by means of replica and transmission techniques. Subsequently they have studied the same system for growth on quartz,16 and with the addition of pyrolysis of silane on quartz and alumina.17 Also Manasevit el al. have studied deposits using silane and silicon tetrachloride on sapphire.18-14 Finally, in this volume studies of deposition on beryllia and sapphire are reported. Although Revesz and Evans20 have examined complete layers, grown by means of the widely used silicon tetrachloride reaction, no detailed examination similar to that published by Charig and Joyce21 for the trichlorosilane system has been given. Therefore this investigation has examined substrate surfaces prior to growth and then nucleation on these surfaces for the silicon tetrachloride system. EXPERIMENTAL In this work the surfaces have been studied by means of standard replica techniques. Because of the very real problems associated with artifacts introduced,22 different replicas and different cleaning

Jan 1, 1967

By M. Kawakami, K. Suzuki, T. Takenaka, S. Yokoyama

Molten NaNO3-NaNO2-KNO3mixture is used as a heat transfer medium at high temperature. One of the most important properties of this mixture is the heat capacity. In the present work, the enthalpy change with temperature was measured by the drop calorimetric method to evaluate the heat capacity. The results are summarized as follows: The enthalpy of the mixture increased linearly with the temperature. From the slope of the line, the heat capacity was evaluated. The heat capacity of pure NaNO3, NaNO2and KNO3was 0.129,0.110 and 0.142 kJ/mol/K, respectively. These values are in fairly good agreement with the published data. In the binary and ternary systems, the molar additivity of heat capacity, which is well known as Neumann-Kopp’s law, was obtained. The heat capacity of HTS1and HTS2, which are well known ternary mixtures of practical use, were in the range of published data.

Jan 1, 2004

By Petr Dvorak, Jana Selucka, Hong Vu, Petra Starkova, Tomas Frydl

Waste, generated during high pressure leaching of lateritic nickel ores, contains about 50% of iron in form of magnetite but high chromium content ( *3%) does not allow its extensive utilization as the raw material for pig iron production in blast furnace. The chromium removal from the waste was carried out by two methods: (1) oxidative alkali roasting with NaOH and/or Na2CO3, followed by water leaching and (2) oxidative leaching in KOH sub-molten salts solutions. The results show that about 90.1% of Cr was removed when the waste was roasted at 900 °C for 3 h with 33.1 wt% of NaOH. The removal of 88.2% of Cr was achieved if the waste was roasted at 900 °C for 3 h with 40 wt% of Na2CO3. The sodium content in the water-leached residues was reduced from 5% to about 0.5% by reaction with CaO in aqueous solutions at 80 °C for 2 h. About 70% of Cr was removed if the waste was leached at 190 °C in 73 wt% KOH for 8 h.

Mar 1, 2017

By Howard L. Hartman

Introduction The federal government's declining role in funding research has created a critical dollar gap for university departments of mining engineering. Industry, too, is affected by the drought. Research is lagging. Hardpressed universities are going to the private sector for funding. Mining companies should not shower universities with philanthropy, but a research partnership should be contracted on a pay-as-you-go basis. A model exists at The University of Alabama (albeit not in mining) that could be adopted by the mining industry. An equal partnership arrangement between a university and an industry for conducting research is proposed. The concept is not that a corporation sponsors and a university performs the research. Nor does it call for educational contributions or giveaways from industry. Rather, the corporation and the educational institution enter into a cooperative research endeavor, a full and equal partnership. Both parties contribute and both share the benefits. A key to the relationship is that it has a single objective: it must generate profits or reduce costs for the company. Working Model Recent literature is replete with examples of proposals for joint research endeavors, involving both contracts and grants, between industry and universities (Bronwell, 1971; Bugliarello, 1978; Branscomb, 1981; Sanford and Holland, 1982). They are all good proposals and offer something to both parties. They are, however, not widely supported. Few have received a favorable nod from the US mining industry. Though it may be logical, for example, to remake the American Mining Congress (or some new consortium) in the mold of umbrella-type industry organizations to fund cooperative research with mining institutions, such proposals have never flown. What model, then, will work? First, look for a model that has worked in industry in general. Second, seek to apply it to mining specifically. There is a model project that satisfies the first of those criteria. It is a project complicated by a third party, in addition to a corporation and a university. In January 1983, the "Factory of the Future Project" was initiated between The University of Alabama (UA) and General Motors Corp. (GM). The United Auto Workers (UAW) is a third party to the agreement. The factory was GM's Rochester Products Division manufacturing plant in Tuscaloosa, AL, also home of UA's main campus (Fig. 1). Saving a Plant The agreement came about at the initiative of GM and the UAW. Faced with having to close the plant because of excessive production costs, company and union officials proposed to the university that an applied research facility be established at the plant. The university would operate the laboratory, dedicated to $470,000 a year cost reductions for the company. The school would lease the 5.1 km2 (55,000 sq ft) space for $470,000 a year for three years. Any savings effected by the university's research effort would be credited toward to the rent. GM said the small factory, which made replacement carburetors

Jan 9, 1984

By Nikolaos Petropoulos, Ulf Nyberg, Daniel Johansson

A series of signature boreholes were blasted to observe any difference between confined and free face blasts. Four geophones were used to capture the compressive wave. The conventional approach, i.e. the calculation of vectorized peak particle velocity (vPPV) did not show any difference. Also a wavelet transform was tested.

Feb 1, 2020

Large GDP increases in the Pacific Rim countries have been accompanied by similarly large increases in demand for oil products. In the case of residual fuels, this demand has been tempered by the substitution of other energy products such as coal or gas.In the region's developing and newly industrialised nations, it has not been possible to make the very large investements in infrastructure which allow other energy sources to be used for transportation. As a result, GDP growth has been mirrored in the demand growth for automotive fuels. Other non-sustitutable products such as lubricants have also benefitted by the region's GDP growth.The combination of a number of years of sustained growth, coupled with increasing quality requirements is now stretching the upgrading capacity of the region's refineries. If, as seems likely, the region continues to enjoy a high GDP growth rate, then this will be accompanied by increasing reliance on finished products coming out of the Middle East. The owners of the most simple form of refinery in which crude is simply distilled and the naphtha reformed into petrol will face major capital investments. If they decide not to bear this cost, they will face increasing problems in selling their surplus residual fuel oil at an economic price. Quality will become an increasingly important issue. Not only in the well publicised areas such as unleaded petrol, but also for products such as lubricants which play a major role in the efficiency of modem equipment. Quality of service such as hours of opening, ease of access, and service station facilities will also become increasingly important as the oil companies use these to attract customers and gain brand differentiation.

Jan 1, 1990

By J. A. Vezina

The effects of particle size distribution on metal extraction have been determined from pressure leaching Renzy Mines Limited concentrate with oxygen. Using a pulp density of 30 per cent solids, an oxygen pressure of 80 psig, a temperature of 230°F, a grind of 2.5 hours and a retention of 8 hours resulted in the almost complete dissolution of the nickel and the cobalt and the decomposition of over 96 per cent of the chalcopyrite finer than 20 microns. Only 11 per cent of the chalcopyrite coarser than 20 microns was reduced to smaller than 20 microns.

Jan 1, 1973

By P. E. Venteer

The Grootegeluk coal-processing plant treats 3 kt of raw coal per hour to produce a middlings fuel coal and a coking coal fraction with ash contents of 35 and 10 per cent respectively. The plus 0,5 mm fraction is treated by heavy-medium processes, the final top size of the coal being 15 mm. About 400 t of minus 0,5 mm coal per hour is subjected to froth flotation. The routes originally considered for the processing of this fine coal were froth flotation, shaking tables, heavy-medium cyclones, and water only cyclones in combination with froth flotation. The results from tests on the fines arising from a small-trial open-cast mine are discussed. When the froth flotation route was decided upon, further tests were conducted on the selection of the equipment most suited to the particular requirements of this coal and the rest of the plant. Tests using different types of flotation cells and dewatering equipment are discussed. During the commissioning, several operational problems were encountered, and the work done to find the best solutions is discussed.

Jan 1, 1984

By Bruce A. Lamberton

In U. S. underground mines concrete work is not widely used. Timber and steel are cheaper, and there are few serious water problems. But in the Union of south Africa men dig deeper, more persistently, and probably more profitably than anywhere else on earth. Some gold mines near Johannesburg are below the 10,000 level and employ as many as 35,000 natives on a single property. Underground substations, pump chambers, and air conditioning plants have capacity to serve small cities. The complexity and extent of underground operations and the heavy subsurface water flows, especially in the new Free State gold fields, require heavy in a Deep concrete installations.

Oct 1, 1956

By Jacques B. Wertz

Even with the best geological maps, there is a constant need for further information and a constant demand for new clues, particularly in exploration work. New ideas and new thoughts are a necessity for progress. In the structural study of an area, be it in Arizona, Africa, or British Columbia, the basic fracture pattern has to be determined first. There is, however, no assurance that the trends shown on the map are really meaningful because they often are secondary in nature, having occurred as a consequence of an intrusion, of doming, or of gravity faulting. Thus, such trends often are a weak basis for assuming the presence of ancient and important zones of fractures that could constitute useful guides to mineral exploration.

Jan 6, 1969

By G. A. Crowder

Far infrared spectra, most of them in the region 15-200 microns and for both the liquid or solution state and for the vapor state, were obtained for twenty-seven compounds.

Jan 1, 1965

By Richard L. Jenkins

Systematic sampling, in reconnaissance fashion, of the continental shelves of the United States to define favorable areas of offshore mineral deposits, is one of the long-range marine mineral; programs of the U.S. Department of the Interior. In mid-1966 the Department of the Interior launched its Heavy Metals Program to stimulate domestic output of gold which is in serious short supply. The program is jointly conducted by the Geological Survey and the Bureau of Mines.

Jan 1, 1968

By J. O. Mogalanyane, N. Naudé, A. M. Garbers-Craig

The fines produced is not suitable as feed material for the subsequent rotary kiln and the electrical arc furnace. The need for briquetting the ferronickel ore is premised on the minimisation of fine particles in the rotary kiln as well as improving charge permeability in the furnace, and improving overall process safety. Briquetting may be defined as an agglomeration method in which fine particles are compressed under pressure. It consists of three different technologies: vibropressing, roller pressing and stiff extrusion. The current study focuses on evaluating the performance of ferronickel briquettes generated, using roller-pressing technology. Physical properties, chemical properties and metallurgical properties of the briquettes were used to evaluate their performance and quality. Standard ISO tests for iron ore pellets were used. Size degradation as a result of reduction was measured using the ISO 4696-1 test. The decrepitation of the briquettes at the point of entry into the rotary kiln was evaluated using the ISO 8371 test method at a temperature of 700oC. The degree of reduction was evaluated using the ISO 4695 test procedure. Average green briquette compressive strength of 559 N was reported at a moisture content of 16% with an average drop number of 19.1. Increasing the moisture content has a detrimental effect on both the compressive strength and the green briquette yield. The drop number is expressed as the number of drops until breakage, when a briquette is dropped from a 1 m height, decreased with an increase in moisture content. At a moisture content of 16% an average green briquette yield of 85.1% was reported. Keywords: Ferronickel briquettes, moisture content, curing conditions, physical properties, chemical properties

Jan 1, 2020

By H. A. Dakin

"An introduction to the metallurgical requirements of the Flin Flon concentrator reveals the magnitude of ore blending which is required in its operation of three flotation circuits. The resulting variability in flotation heads which has in-creased the separations complexity justified the development of an on-line analysis system.This paper provides a summary of the development and operation of that system. Particular attention is devoted to the problems encountered and where possible their solutions; as the requirements of accurate information and minimum downtime of the sampling system and x-ray analyzer are considered essential. The addition of a recess central computer has provided information in a more easily understood form and as well has allowed the start of automatic reagent control.An indication of the on-line analysis system's value to the concentrators' operation is provided by an examination of the plant in metallurgical data and reagent costs in previous years.The metallurgical plants of Hudson Bay Mining and Smelting lie adjacent to the city of Flin Flon on the Manitoba-Saskatchewan boundary. Plant operations commenced in 1930 treating copper-zinc ore from the local mine. In recent years ore bodies near Flin Flon and in the Snow Lake area, about seventy-five miles east, have been brought into production.By the beginning of 1973 the number of producing mines had increased to nine; with all the ore being handled by the Flin Flon concentrator. Figure l, showing mine ore assays during 1973 indicates the variation in metal content possible."

Jan 1, 1974

By Thomas J. Fisher, Thomas Novak

Strong circumstantial evidence suggests that lightning has initiated methane explosions in abandoned and sealed areas of underground coal mines. The Mine Safety and Health Administration (MSHA) investigated several of these occurrences within recent years. The investigated explosions occurred at significant depths, ranging from 500 ft to 1200 ft. Data from the National Lightning Detection Network indicate a definite correlation between the times and locations of the explosions with those of specific lightning strikes. This paper addresses the question, "Can lightning cause potential differences capable of igniting methane-and-air mixtures at overburden depths at which underground coal mining occurs?" A mine depth of 600 ft was selected for this initial study. Computer simulations were performed, with and without the presence of a metal- cased borehole extending from the surface to the mine level. CDEGSTU software from Safe Engineering Services & Technologies, Ltd (SES) was used for the simulation.

By Guy Bridges

Site formation works requiring excavation of rock at the Queen Mary Hospital redevelopment site was restricted due to extremely low ground vibration limits. Non-Explosive excavation method called Electro Power Impactor (EPI), sometimes called Plasma Blasting, was utilised to help ensure the rock excavation rate could meet the required programme.

Feb 1, 2020