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By M. Misra

The dielectric properties and flotability of different ranks of Argonne Premium Coal samples are presented. The flotability of different ranks of coal are correlated with the dielectric properties and intrinsic moisture (or bound water) content. Measured dielectric properties of as-received coals and other constituents are incorporated into a mixture equation to calculate the dielectric properties of bound water present in the different ranks of coal. The nature of bound water present in low-rank hydrophilic coals is significantly different from that present in high-rank hydrophobic coals. The water molecules present in low-rank lignite have an oriented dipole-dipole interaction and are tightly bound to the surface. For high-rank coals, the water molecules are not bound to the surface and have a randomly distributed clathrate ice-like structure. Controlled thermal treatment can modify the structural nature of bound water present in low-rank hydrophilic coals and increase their flotability.

Jan 1, 1990

By J. T. Norton, A. L. Mowry

The monocarbides of the A subgroup elements in the fourth and fifth group of the periodic table in addition to being hard and refractory are of special interest in that they are isomorphous in crystalline structure. They are cubic with a sodium chloride type structure in which the metal atoms are essentially close packed in a face-centered cubic arrangement with the carbon atoms placed in the interstices between. Interstitial structures of this close packed type were first investigated systematically by Egg1 and he gave the rule for their formation, stating that the radius ratio of the nonmetal to the metal atom should not exceed the value of 0.59. The carbides of interest are those of titanium and zirconium of the fourth group and vanadium, columbium and tantalum of the fifth group. Table 1 shows the radius ratio using the Goldschmidt radii for 12 coordination for the metal atoms and the diamond radius for the carbon atom. It will be noted that while there is considerable variation in the size of the metal atom, in all cases the ratio is smaller than the limit of 0.59 placed by Hägg. It has been known for some time that these cubic carbides are soluble in one another, at least to some extent or, in other words, the metal atoms can be replaced, one by another without destroying the stability of the structure. Since the stability of these close packed interstitial substances appears to depend more upon geometry than upon the exact chemical nature of the atoms involved, it is of interest to examine the possibilities of replacement in these carbides in some detail. Hume-Rothery2 has pointed out the importance of the difference in size of solute and solvent atom as a factor in limiting the solubility in simple binary solid solutions. Largely on an empirical basis, he states that if the difference in size between solvent and solute atom is more than 14-15 pct of the solvent atom, the range of solubility is very restricted. The atom size was based on the distance of closest approach in the elements involved. While there is some question as to how one should calculate the size of the metal atom in the carbide structures, reference to Table 1 will show that zirconium is the largest and vanadium the smallest of the group and that the difference is about 15 pct. The Ti-Zr difference is about 9 pct and the others are smaller. Thus one would predict that if the size factor controls the solubility, all of the pairs except VC-ZrC would have wide or complete solubility whereas this latter pair is on the border line and might have restricted solubility. The purpose of the present investi- gation was to examine the solubility of the several pairs of carbides by heating them together until equilibrium was established and then examining the product by X rays. Previous Work Agte3 and his associates prepared various transition metal carbides and determined the melting points of binary mixtures. He concluded from the shapes of the melting point curves that there was extensive solubility in the case of the cubic carbides. Umanskii and his colleagues made an investigation of a number of pairs of the cubic carbides, using X rays and plotted lattice parameter vs. composition curves for the systems TaC-Tic, CbC-Tic, TaC-ZrC and CbC-ZrC. All pairs showed a continuous series of solid solutions. The first two pairs gave a linear relation while the latter two showed a negative deviation from Vegard's law. Kiefer and Nowotny, in a paper which became available after the present work was well advanced, investigated the binary pairs of the five cubic carbides by means of X rays. Relatively few points were obtained and results indicated that in some cases, at least, equilibrium was not reached at the temperatures used. The results indicated that solubility in the VC-ZrC system was not complete. All of the results of previous investigations indicated the desirability of a more detailed study. Materials The raw materials used were mono-carbides of titanium, zirconium, vanadium, columbium and tantalum and were the purest which could readily be obtained commercially. Spectrographic qualitative analysis showed that the CbC and TaC contained less than 1 pct

Jan 1, 1950

By Zwaan J, Kepa J

Ok Tedi mine has become one of the major copper producers in the world. In the process of becoming of age, it overcame the challenges of operating in a locality which is young in geological terms, experiences very high rainfall and has a topography which gives rise to frequent landslides. This paper discusses some of the geological, mine and geotechnical engin- eering aspects of the Mt Fubilan ore deposit.

Jan 1, 1991

By Haeussler P, Christie A, Bradley D, Skinner D

Mesothermal gold deposits of southern Alaska and Westland, New Zealand have both formed at the seaward edge of major collisional zones in the Pacific basin. In Alaska, production of large fluid volumes correlates in time with the addition of heat into the lower parts of the accreted terranes in the late stages of collisional orogeny. This heat was critical for driving both the metamorphic reactions that released the large volumes of fluid that carried the gold, and the contemporaneous widespread anatexis and magmatism. In Alaska's Chugach terrane, this heat was produced by subduction of a spreading ridge beneath the North America continental margin in the Eocene. The resulting products were the S-type granites and gold-bearing veins. The similar widespread S-type plutonism and gold veining in Westland's Buller terrane suggest that a similar tectonic event could have triggered ore formation along the southeastern edge of Gondwanaland. Based on the Alaskan model, a Devonian or Early Carboniferous age is favoured for high volume metamorphogenic fluid generation and gold vein formation in Westland.

Jan 1, 1995

In connection with the presentation of his paper in oral abstract, Mr. Hansell exhibited samples of briquettes, showing their porosity, and the change of surface produced by burning. Alfred H. Cowles, Sewaren, N. J.—I am familiar with this furnace, and I wish to point out that the larger it is, the greater is its efficiency, and the longer its life. In Europe, experiments have been made with small, short furnaces of this character, accommodating narrow cars; whereas Mr. Hansell says that there is in this country a furnace 180 ft. long .and 10 ft wide. The American furnaces, moreover, differ in design from those used in Europe; and we may expect from these larger furnaces not only greater efficiency, but also greater durability —the latter advantage being due to the fact that, in these large furnaces, projecting brick walls of greater thickness can be provided, to prevent the heat from attacking the sides of the cars, by means of bricks which, over-reaching these iron surfaces, furnish a protective cover to them. In other words, in these

Jan 1, 1913

By R. V. Ramani, R. Stefanko, P. C. Thakur

The effects of diesel exhaust on mine ventilation systems are discussed. Mathematical models for emission of gaseous pollutants from diesel engines and their dispersion into mine air have been developed. Situations likely to prevail in mines were originally modeled using partial differential equations, but only simplified solutions are presented here. Validity of these models has been established by field observation of the growth of carbon monoxide concentrations in mine air environment. Consequently, these models can be used for air requirement calculations for diesel engines in underground mines.

Jan 1, 1977

By R. Altindag

The rock brittleness is one of the most important rock properties that affect the drill-ability of rocks. It is supposed that the increase in rock brittleness causes the increase in penetration rate. The drill-ability of rocks depends on many factors. These factors can be separated as two parts depending on a machine, bit type, rotational speed, thrust, blow frequency, flushing, and rock properties, brittleness, compressive strength, structure, hardness, etc. In this paper, the relationship between brittleness and drill-ability index, which is used in the prediction analysis of the penetration rate of rotary blast hole drills, were examined using regression analysis. It is also seen that significant correlations exist between brittleness and the drill-ability index.

Jan 1, 2002

By D. F. Scott

"DEFINITION OF THE REGION AND ITS BOUNDARIESTHE REGION of Western Canada covered by this re-port lies between the Precambrian rocks of the Canadian Shield and the structurally deformed rocks of the eastern Cordillera, extending northward from the international border to the 60th parallel. It is some 487,000 square miles in area, with a total sedimentary fill of about 535,000 cubic miles0>. It includes parts of the prairie provinces of Manitoba, Saskatchewan and Alberta and the northeast corner of British Columbia and forms part of the geological region known as the Interior Platform, commonly referred to as the Western Canada Sedimentary Basin. The bedrock comprises carbonates and evaporites of Paleozoic age that lie on Precambrian crystalline rocks and are over-lain by a relatively thick blanket of Mesozoic and Tertiary elastic rocks. The nearly flat-lying bedrock, covered by a thick mantle of glacial drift, forms the Interior Plains physiographic province."

Jan 1, 1970

By Davide Onesti

Electrode regulation is the technology at the heart of the AC and DC Electric Arc Furnace. As such, in the last decade it underwent continuous improvement to maximize the EAF performances, in terms of process efficiency, machine utilization and operator safety. Given this background, Danieli Automation’s efforts in the field of electrode regulation have been focused on fast response to scrap cave-in, compensation of supply variations, automatic resonance detection, transformer protection, dynamic regulation of the electrical and chemical set-points, coordination and control of slagging and foaming agents, arc irradiance supervision. An extensive analysis of operator utilization and feedback was also carried out to develop an innovative system HMI. In this field, the choice of the variables shown to the user is the key aspect to allow a prompt process evaluation by the operator, who can refer to a condensed set of useful data. This paper will describe the innovative features and embedded models of the electrode regulation module (Q-REG+) and the supervision HMI, together with the effects of their application on EAF process efficiency and system usability.

Oct 30, 2017

By N. Brown

Australian mining companies are actively exploring for and developing mineral deposits throughout the world with interests in emerging markets such as Africa, Asia and South America. It is important to understand emerging market risk as this will affect the willingness of mining companies and financial institutions to invest in a country, especially with reference to their key asset, the mining licence or operating/concession agreement. Mining companies looking to develop new projects in emerging markets have different risk profiles than projects in countries such as Australia and Canada. Examples of key risks faced in emerging markets include: 1. political - expropriation, nationalisation, contract frustration, currency inconvertibility, war, terrorism, strikes, riots and civil commotion; and 2. legal - mining legislation, arbitration and dispute resolution, trade agreements. There is a problem in the difference in risk perceptions between mining companies, financial institutions and insurers. This can cause different stakeholders to carry out different evaluations of the risks faced by a project, resulting in confusion about the risk margin attached to any project. In a time where resource nationalisation and energy security are prompting governments to become more involved in the mining sector we run through some recent examples of mining companies that have had problems due to the key risks highlighted earlier. Importance of carrying out the right due diligence to replace perceptions with reality: ? early identification of risks - detailed due diligence on emerging market risks that may arise will help with their identification and mitigation, ? make use of companies that can help identify risks and suggest solutions, ? control the cost of financing - risk margin applied to a project ? finance loan will be influenced by the risks faced, and ? risk management and using political risk insurance. There are plenty of opportunities in emerging markets but it is important to recognise the associated risks. Detailed due diligence at an early stage will provide long-term benefits.

Jan 1, 2007

By Charles W. Daugherty, Robert Nyren

The replacement of Boston’s elevated Highway I-93 running north to south through the heart of the city with 8-lane tunneled roadways, coupled with the underground extension of Highway I-90 eastward to Logan Airport, has earned the Central Artery/Tunnel (CA/T) Project the position of the largest infrastructure project in the U.S. today. The gigantic interchange featuring numerous ramps where these two main branches of the Artery intersect required the construction of three huge jacked tunnel boxes that were pushed beneath eight active Amtrak and commuter rail tracks that had to remain undisturbed in spite of poor geology and a minimum of cover between the track beds and the tunnel crowns. Ground freezing was chosen as the method of stabilizing the soil over the tunnels, and it was extended in one area to stabilize the ground at the intersection between the tunnels and an abutting deep cut-and-cover excavation. Because many standard geotechnical instruments consist basically of open standpipes filled with water, it was a major challenge to keep them de-iced and in a condition to provide data on vertical and lateral ground movements. The efforts to do so are herein described.

Jan 1, 2003

By Wen Songlin

This paper presents an experimental program to investigate the behavior of a pile with wings under horizontal loads in sand at laboratory. The work focused on evaluating the lateral resistance behavior and the geometric effect of wing board on the horizontal resistance. Based on the measured data and observed phenomenon, the following behaviors have been observed: 1) A pile with wings is not only a powerful means to improve the horizontal bearing capacity of a pile foundation but also economy and feasibility; 2) The horizontal bearing capacity of a pile with wings increases with increasing of it?s wing board?s area; 3) The pile lateral capacity is also influenced by the wing board?s geometric shape. Under a certain soil and pile condition, there is a critical embedment depth of the wing board, which will yield the maximum horizontal bearing capacity. It was further observed that when the displacement of the pile head increases, part of the horizontal bearing capacity of the pile is developed by the so-called shaft?s anti-pulling capacity.

Jan 1, 2007

The paper outlines the development of a solvent extraction process for the recovery of scandium, yttrium, thorium, and heavy lanthanides from waste sulphate liquor at the Port Pirie uranium treatment plant. A summary is given of known solvents for these elements, including the recently developed alkyl-phosphoric acid esters which are applicable to sulphate solutions.A kerosene solution of di- (2'-ethylhexyl) phosphoric acid (EHPA) has been suggested by some workers as a suitable solvent for fractionation of the lanthanides. Experimental work with this solvent showed that it could be used for initial recovery of the above elements from low concentrations in the complex sulphate liquor. In particular, scandium could be recovered as a high grade product by extraction with 0·lM EHPA, followed by a purification strip with 9N sulphuric acid, and final stripping of scandium with sodium hydroxide solution.To enable alkaline stripping to be used successfully, the kerosene solution of the reagent was modified by the addition of a small proportion of nonanol. Experimental work included laboratory scale batch tests and small pilot scale continuous tests.A proposed extension of the process for the separate recovery of individual heavy lanthanides, yttrium, and thorium is described.INTRODUCTIONAt the Port Pirie uranium treatment plant of the South Australian Government, large volumes of "barren liquor", free from 'uranium, are at present run to waste. This "barren liquor" results from sulphuric acid leaching of Radium,Hill uranium concentrate, followed by separation of solid residues and removal of uranium from the clear solution by ion exchange. The mineral davidite, from which the uranium is derived, contains other potentially valuable components, notably vanadium, chromium, thorium, yttrium, scandium, and the lanthanides. These constituents are...

Jan 1, 1961

By Shepherd J

Megascopic and microscopic studies of cleats and mining induced cleavage in Ihe first workings at Leichhardt Colliery reveal the presence of four distinct fracture sets. Microscopic studies confirm underground observations of the fracture sets.The most likely order of formation of the fractures is (i) "butt" cleats (ii) facc cleats (iii) shallow dipping faults (iv) mining induced cleavage. Three fracture sets apparently formed by tensiIe failure. Microscopy shows that the mining induced cleavage surfaces have preferred starting or lerminating points at the extremity of a "butt" cleat and a vitrite-dull coal band boundary. It is postulated that the induced cleavage begins at 'butt' cleats which behave as Griffith flaws under high compression around Leichhardt Colliery faces. Instantaneous outbursts of coal and gas are associated with only those workings which are affected by mining induced cleavage and occur at or adjacent to working faces.

Jan 1, 1981

By H. M. Castrantas

Caro's (peroxymonosulfuric) acid has been reported to destroy WAD (weakly acid dissociable) CN-but, until recently, the technology has not been demonstrated in other than a laboratory setting. During the last two years, Caro's acid has been shown to successfully detoxify WAD CN-in tailings at two large North American gold mines. Using on-site FMC generators, Caro's acid reduced the WAD CN-from 40-55 ppm to below 20-35 ppm WAD CN-, the target range for the two mines. The detoxification costs using Caro's acid were less than 50% of the treatment cost of using hydrogen peroxide, the previous oxidant of choice. In addition to the considerable savings in CN-detoxification costs, lower WAD CN-values were achieved and the detoxification time with Caro's acid was greatly reduced compared to hydrogen peroxide.

Jan 1, 1995

MRS. SIDNEY J. JENNINGS, President MRS. ARTHUR S. DWIGHT, First Vice-President MRS. KARL EILERS, Second Vice-President MRS. H. W. HARDINGE, Third Vice-President MRS. BRADLEY STOUGHTON, Recording Secretary MRS. AXEL 0. IHLSENG, Corresponding Secretary MRS. HARRIS K. MASTERS, Treasurer Welfare Committee MRS. C. C, BURGER, Chairman Sub-Committees Americanization Belgian Relief MRS. LEVI HOLBROOK, Chairman MRS. HENRY H. KNOX, Chairman Emergency MRS. HERMAN A. PROSSER, Chairman A very successful meeting Of the Council of the Woman's Auxiliary was held Wednesday, July 18, and plans for war relief work were thoroughly discussed. The Belgian Relief Committee has sent out the following letter to the ten local sub-committees, which were formed to raise money to feed the Belgian children: "The Commission for Relief in Belgium announced in a letter from Mr. Hoover that after the first of June the United States Government would take over the relief of Belgium and Northern France and called attention to the following paragraph: ?Naturally, having built up such an effective organization you will desire to keep it alive as far as possible, and we venture to suggest that, although the general relief of the countries involved will now be met by the Government appropriations, emer-gencies and special conditions may arise which could only be met by private donations. In such circumstances your organization will afford a ready means of meeting the demands of the situation, whatever they may be. Should any of your contributors

Jan 9, 1917

By Giles St. Pierre

"The purpose of this paper is to report in a general way on the use of the Portaspec X Ray Spectrograph.At Manitou Barvue, we are milling two types of ores, copper and zinc. The control assay practice was to take grab samples at 4 hour intervals. These samples were dried in the mill, then taken over to the Assay Office where two operators would process them. Three hours later results were available at almost the same time as the operator was ready to take his set of grabs again, leaving no time for adjustments, if any were needed.After a reduction of personnel, there were no assays available on night shift. This practice was slow and inadequate, and a new way of doing control assays was investigated.After investigation the Portaspec was found suitable for the type of operation that we had in mind. The Portaspec is a conventional dispersive type of X Ray spectrograph. The instrument consists of three parts:The Power Supply The Spectrographic Head The Digital ScalerIn our case, where dried powder samples are analyzed, the instrument was provided with a two sample holder using one for the standard and the other for the sample. The operation of the instrment does not require any degree of skill or knowledge of chemistry or spectrography.Previous to buying the instrument, six sets of six to ten samples were sent to the supplier along with the assay for each sample. These samples were Cu. HDS., Cu. Conc., Cu. tls, - Zn. HDS., Zn. Conc., Zn. tls. A definite pattern was observed. For example - six Cu. HDS. samples ranging from .40 to .90 gave 10400 counts for the lowest to 16.040 counts for the highest. The number of counts were then plotted to give percentages."

Jan 1, 1971

By Robert E. Manning

The Federal Coal Mine Health and Safety Act of 1969 has placed stringent limitations on the noise levels in which employees may work. This act can result in both increased labor costs because of noise-exposure time limitations and in high capital costs for modification of present equipment, and the design of new equipment, to comply with the law. The development of new noise-control systems is thus of immediate interest to industry. A current Research program at U. S. Steel is aimed at developing methods of controlling both the exhaust-air noise and the mechanical noise of a Stoper drill, a pneumatic percussive tool used for roof-bolting purposes in coal mines which has an approximate air consumption of 100 cubic feet per minute. This program is being performed under a contract between USS Engineers and Consultants, Inc. and the Pittsburgh Mining and Safety Research Center of the U. S. Bureau of Mines. In previous work at U. S. Steel, kidney-shaped mufflers were designed that wrap around the air leg of the drill for control of the exhaust noise. These mufflers were designed with the aid of a digital computer program that predicts the acoustic performance of mufflers.

Jan 1, 1975

By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore 'as mined' generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By A. Tsubouchi, F. Noguchi, T. Takasu

"A high current density operation is desired to improve the productivity in copper electrorefining. However, a lot of problems still remain such as passivation at anode, dendritic deposition at cathode and impurity behavior during the electro refining.Effects of the current densitY on the morphology of copper deposition on the cathode, and passivation at the anode were investigated at various fluid velocity of electrolyte in the present study.Although a granular appearance of the copper deposition was obtained with increasing high current density, it was depressed by an increase of the fluid velocity of the electrolyte. A uniform deposition on the cathode was also observed when the fluid velocity of the electrolyte become higher. It was ascertained that passivation at the anode was suppressed by circulating electrolyte during electrolysis. INTRODUCTIONIt is desirable to operate at high current density in copper electrorefining in order to improve plant productivity without enlarging the size of electrodes(1). However, there are many problems in copper electrorefining at high current density with the usual commercial practice, for example, anode passivation, dendritic deposition and an increase of impurities in the cathode.In general, it is effective to agitate the electrolyte in order to suppress these problems(2). Smith et a1.(3) have performed electro refining experiments at various current densities in the range of 8 to 32 Aldm2 and at electrolyte fluid velocities in the range of 40 to 120 mlmin, and they obtained well consolidated, void free copper even at high current density in a high electrolyte velocity. However, they did not discuss the recovery ratio and the passivation behaviour at the anode. Walsh et a1.(4)(5)(6) experimented with the rotating cylinder electrode, and ascertained that electrolysis can be carried out at high current densities under the condition of pure electrolyte.With regards to anode passivation, there are several papers by previous workers(7)(8). Our group ascertained the process of producing anode slime during electrolysis(9). However, these experiments were carried out without forced circulation of electrolyte. Therefore, in the present study, to solve these problems, we electrolyzed at current densities in the range of 4 to 50 Aldm2 with circulating electrolyte in the range of 0 to 48 mlrnin. The effect of electrolyte fluid velocity on the surface morphology of deposited copper at cathode and passivation at anode were investigated when electrolysis were carried out with circulating electrolyte at high fluid velocity and at high current density."

Jan 1, 1997