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By N. B. Gray, R. V. Culver, W. S. Boundy, N. W. Stump

The kinetics of sulfation of single crystals of lead sulfide to lead sulfate have been studied between 969" and 1073°K in gas atmospheres of known composition using a thermobalance technique. The data are described by an equation derived on the basis that diffusion outward through the Product layer is the major controlling step. The rate of sulfation is linearly related to the logarithm of the sulfur trioxide partial DESPITE its industrial significance the oxidation of lead sulfide has received limited attention. The oxidation reactions have been studied using beds, briquettes, single crystals, or thin films of lead sulfide. Lead oxide and lead sulfate (PbSO,) were formed when Mclntoshl and Gardner2 roasted beds of galena pressure and the temperature coefficient of reaction is 40 ± 5 kcal per g mole. Gold marker experiments show that the sulfate layer grows by outward movement of ions through the sulfate layer. Initially the PbSO, adheres to the PbS but later forms an irnpewious spheroidal envelope; PbS vaporizes and pb2' ions diffuse through the envelope to react at the external surface. in air at temperatures up to 800°C. In a more extensive investigation, Tchizhykov3 obtained Pb, PbO, and PbS04 in accordance with Eqs. [1] to [4], when a bed of -200 mesh galena was oxidized in O2-N2 mixtures at 700° to 900°C.

Jan 1, 1968

By Guillermo Zuloaga

The iron deposits of the Imataca Range of Venezuela, which occur along the Orinoco River, in the northern border of the Guayana Highlands, have lately attracted attention on account of their economic possibilities. Many deposits occur in this area; some of slight economic importance and others that may rank with the largest masses of high-grade iron ore of the world. The geology and the character of the ores seem to be remarkably similar to those of the large iron deposits of Brazil. In the investigation of the Venezuelan deposits a definite relationship has been found between the mineralization of the large orebodies and igneous intrusions, especially norites and granites. The following paper is the result of a field and laboratory investigation of the ore deposits. The field work was done during the months of February and March of the year 1929, partly in the company of Prof. W. H. Newhouse. The laboratory studies have been made in the Massachusetts Institute of Technology, under the supervision of Professor Lindgren and Professor Newhouse. GENERAL GEOLOGY OF GUAYANA HIGHLANDS General Geography and Physiography The Sierra de Imataca proper occupies a narrow belt along the south bank of the Orinoco River, in the northeastern part of the State of Bolivar and in the western part of the Delta Amacuro Territory of Venezuela. The State of Bolivar is generally known as the Venezuelan Guayana, as it forms part of the same physiographic province of the Guianas and northeast Brazil. In general the Venezuelan Guayana is an extensive plateau, sloping gently towards the Orinoco River to the north and towards the Atlantic Ocean to the east. In the northern part mountains are rare, and consist mainly of elongated low hills. Towards the British Guiana-Brazil boundary, table mountains with vertical cliffs are found forming the ranges of Parima, Roraima and Pacaraima. General Geology The Guayana Highlands are the northern extension of the Brazilian Archean shield. Only a few scattered masses of sediments remain on its

Jan 1, 1935

By Guillermo Zuloaga

The iron deposits of the Imataca Range of Venezuela, which occur along the Orinoco River, in the northern border of the Guayana Highlands, have lately attracted attention on account of their economic possibilities. Many deposits occur in this area; some of slight economic importance and others that may rank with the largest masses of high-grade iron ore of the world. The geology and the character of the ores seem to be remarkably similar to those of the large iron deposits of Brazil. In the investigation of the Venezuelan deposits a definite relationship has been found between the mineralization of the large orebodies and igneous intrusions, especially norites and granites. The following paper is the result of a field and laboratory investigation of the ore deposits. The field work was done during the months of February and March of the year 1929, partly in the company of Prof. W. H. Newhouse. The laboratory studies have been made in the Massachusetts Institute of Technology, under the supervision of Professor Lindgren and Professor Newhouse. GENERAL GEOLOGY OF GUAYANA HIGHLANDS General Geography and Physiography The Sierra de Imataca proper occupies a narrow belt along the south bank of the Orinoco River, in the northeastern part of the State of Bolivar and in the western part of the Delta Amacuro Territory of Venezuela. The State of Bolivar is generally known as the Venezuelan Guayana, as it forms part of the same physiographic province of the Guianas and northeast Brazil. In general the Venezuelan Guayana is an extensive plateau, sloping gently towards the Orinoco River to the north and towards the Atlantic Ocean to the east. In the northern part mountains are rare, and consist mainly of elongated low hills. Towards the British Guiana-Brazil boundary, table mountains with vertical cliffs are found forming the ranges of Parima, Roraima and Pacaraima. General Geology The Guayana Highlands are the northern extension of the Brazilian Archean shield. Only a few scattered masses of sediments remain on its

Jan 1, 1935

By A. McLean, X. Men

"With high quality sulphide ores diminishing, nickel production from low-grade oxide ores becomes increasingly important and a major concern is the high sulphur level in the resultant ferro-alloy. So, desulphurization of the ferronickel becomes an important consideration. Red mud is a waste product of alumina industry and causes adverse effects on environment. In the present study, experiments were conducted to determine feasibility of using red mud as a major ingredient of refining fluxes for ferronickel desulphurization. In view of their influence on slag-metal separation, contact angle measurements between ferronickel alloy and molten slag made from red mud were also determined. INTRODUCTIONNickel is a very important metal that finds a variety of applications including consumer products, building, automotive and electronics. There are two kinds of ores containing nickel, namely oxide and sulphide ores. Anthony and Flett [1] reported that about 55% of the world’s nickel production originates from sulphide ores while the balance of new nickel is derived from oxide ores. However, oxide ores count for about 70% of the worldwide reserves. Apparently, oxide ores will play a significant role in the production of nickel in the future. Most of nickel produced using oxide ores is from pyrometallurgical processes namely ferronickel smelting or matte smelting. So, we can draw such a conclusion that using nickel oxide ores to produce ferronickel will become more and more important .Before used to make stainless steel or other materials, the ferronickel need pretreatment to remove impurities especially sulphur and phosphorus that will cause negative influence on the properties of steel product. Red mud is a by-product during alumina production. Usually, about 1 to 1.5 tons of red mud will be produced when we get 1 ton of alumina. About 90 million tones of red mud are produced every year in the world [2].Red mud is deemed as a toxic industrial waste which needs treatment before discharge because of alkalinity and chemical and mineralogical properties. Until now, the main means to deal with red mud are to store it in impoundments or dump it in the sea depending on local environment. Nowadays, how to recycle red mud has become a pretty hot topic around the world. The last 40 years have witnessed a lot of patent applications concerning the ways of red mud utilization. However, a little amount of red mud is consumed until now due to the limitations of recycling red mud."

Jan 1, 2012

By W. W. Weller

Heat capacity measurements of anhydrous cobalt sulfate (CoSO4), copper sulfate (CuSO4), nickel sulfate (NiSO4), and zinc sulfate (ZnSO4) were conducted over the temperature range 51° to 298° K. The results were used to evaluate the following entropies at 298.15° K (cal/deg mole): CoSO4, 28.1; CuSO4, 26.8; NiSO4, 24.8; and ZnSO4, 26.4. Entropies were combined with heats of formation to give free energies of formation.

Jan 1, 1965

By John S. Brown

IN 1925 the writer undertook a detailed statistical study of all producing areas in the Joplin district as a basis for evaluating programs and measuring objectives. For this purpose, the published figures in the yearly volumes of Mineral Resources were used, supplemented for earlier years by publications of the Missouri Geological Survey and other local and less official sources. When all else failed, the available data were projected backward to hazard a reasonable guess as to the unrecorded early output of important areas. Fortunately, the proportion of such prehistory production is not a large factor in any of the totals. These results were used during the next few years to measure the relative importance of various producing areas and to predict the peak period of development of the all-important Picher field. For the purpose of this review, the charts have been completed to the end of 1950. During World War 11, the U. S. Bureau of Mines became interested in a similar study and issued comprehensive statistical tabulations of data up to 1945 ( Info. Circular 7383), which have been checked against the figures used herein. This tabulation, however, does not include all the earlier data used by the writer nor does it offer any estimates of the wholly unrecorded era in the beginnings of the earlier camps. The area covered in this study is shown in Fig. 1 on which are indicated the relative location and approximate outlines of the principal producing camps. This also shows the approximate yield to date of each major camp in terms of combined lead and zinc concentrates. The output of zinc concentrates is roughly seven times that of lead. Hence, the economy of the district has depended primarily on the price of zinc, with lead as an important byproduct. Over much of the productive period, lead concentrates averaged about twice the value of zinc concentrates per ton, and in certain mines or areas the proportion of lead to zinc was substantially above average. The Joplin district is largely flat prairie but is partly moderately dissected, partially wooded land with a relief generally less than 100 ft. The rocks are almost flat-lying, nearly parallel to the surface, and the chief ore formation is the Mississippian Boone limestone, including its cherty phases. This formation either outcrops in the producing areas or is covered by a thin veneer of Pennsylvanian shales. Virtually all the ore occurs within 400 ft of the surface, and a large part at less than 300 ft in depth. Most of the land was divided into small farms or town lots before mineral development; tracts seldom exceeded 160 acres, and averaged considerably less. Mineral rights followed the surface ownership, segregation was rare, and a system of leasing for mineral development became well established early in the region's history, many landowners deriving small to sizable fortunes from royalties. Because of the shal-lowness of the ore and other factors, prospecting and mining was cheaper than in almost any comparable mining district in the United States. This situation, coupled with the widely divided land ownership, offered a fertile field for promoters and speculators and led to the rise of many small mining concerns. Only in its later history, under stern economic compulsion, has control tended to centralize in a few companies. Under these conditions, any important new discovery or successful development had much the effect of a gold rush or an oil boom. Every property in the area was leased quickly, promptly drilled, and, if ore was found, it was soon on the market. Many companies and individuals participated, and the average producing lease-hold probably was about 40 acres in extent. Any important field thus was attacked by anywhere from 10 to 100 or more producers. Production zoomed, eventually steadied or wavered, and ultimately subsided, leaving a desolation of tailings mountains, cave-ins, empty housing, and wreckage. The object of this paper is to depict the pattern of this process, so far as metal production is concerned, and to note the way in which it reacted to economic and political pressures. Production Charts In Fig. 2 is charted the production record, in tons of lead and zinc concentrates combined, of eight of the principal camps, which together account for approximately 99 pct of the total district production, over the years from 1870 to 1950. This period covers all but the very minor beginning of mining history. Two important camps are divided by state lines; hence, it has been necessary to combine production records for the two portions, based on estimates that may be slightly in error. Certain camps are sub-dividable into important units for which separate figures are available in whole or in part and have been charted as fractions of the major unit. The corresponding price of zinc is shown above all the charts. Three camps, Aurora, Neck City, and Galena, show a remarkably symmetrical graphic pattern, which is interpreted as the norm. The curves rise steeply to a peak, level off for an irregular interval, and then drop sharply to zero on a slope corresponding roughly to that covered by the initial rise. The three portions of these charts seem appropriately characterized by the designations of youth, maturity, and decline. On the whole, with some irregularities, the production in each of the three periods seems to be almost equal. A fourth camp, Granby, fails to conform to the normal pattern. It exhibits a very long period of reasonably uniform, stabilized production corresponding to maturity, followed by a rather precipitate decline. Its youth is hidden in the era of prehistory. This habit of steady, long-continued production at an even keel is attributable to the fact that this camp, more than any other, was controlled largely by a single principal owner at any given period over most of its history and this permitted the imposition

Jan 1, 1952

By Walter C. Lawson

The primary objective in laying track in panel sections is to reduce the number of track laborers required. This is possible because the work is mechanized. Moreover, because the work is mechanized and each of the operations needs only a few men, and each is self-contained, the work can be carried on at night as well as in daylight; therefore, the method provides a means of preparing tracks on more than one shift. The laying of tracks in open pits and quarries in panel sections is not new but new methods have been made possible by the introduction of new types of equipment. The purpose of this paper is to describe the methods that are followed in the Morenci open pit. General Mining Operations Full-scale ore production at Morenci is about 50,000 tons daily. The normal yearly output of ore and waste is 32,000,000 tons, of which 30,000,000 tons is handled by rail haulage. This requires the building of approximately 47 miles of loading and other temporary tracks during a 12 months' period (Fig I). Broken ore and waste is loaded into 90-ton capacity dump cars with 5-cu-yd full-revolving electric shovels. Shovel banks are uniformly 50 ft high. They are blasted with churn drill holes and the broken material from a blast is loaded out with two shovel cuts, the first one being called (locally) the "splatter" cut and the second one the "clean-up" or "face-up" cut. When a shovel is making its clean-up cut, the loading track is about 70 ft from the toe of the bank and, under normal conditions, a bank is blasted against it without removing the track. It is thus evident that each track is used for two shovel cuts before relocation is necessary, inasmuch as a single position serves for both the clean-up cut prior to blasting and for the splatter cut following the blast. The normal advance of a solid bench by a single blast is 40 ft (Fig 2). Preparation OF Panel Grade In preparation of panel grades bulldozers and rooters are used for the bulk of the work and an auto-patrol road grader for the final stage. At Morenci, bulldozers have always been used for track-grade preparation, but before the introduction of the other two types of equipment grades were uneven and irregular at best, and always necessitated a big gang of track laborers to hand-block under the ties with rocks after a track was laid into place. High blocking also made poor track because of instability and caused frequent derailments. Under these conditions derailments were generally bad as re-railing became difficult. Much track was torn up and many tics broken in the process. The inadequacy of the hand-blocked track, together with the inefficiency of hand blocking, constantly pointed, to the desirability of reducing the amount of labor required, so various means were tried to improve conditions, such as wood

Jan 1, 1949

By Jeremy Morris

The city of Indianapolis has more than 25,000 homes currently on septic systems. Many of these systems do not function well because of their age and surrounding soil conditions. As Indianapolis has worked to eliminate septic systems and install sanitary sewers in large unsewered areas on the north-west side, capacity of the existing Belmont North Interceptor (BNI) became a concern. The BNI system currently services an area of approximately 80 km2 (31 sq miles) located within the northwest quadrant of the city (Fig. 1). Monitoring of the existing interceptor indicated portions of the sys-tem flowing half- to two-thirds full during dry weather conditions and surcharging during some wet weather conditions. Further analysis of the BNI based on growth projections coupled with increased sewershed yield resulting from the city?s septic tank elimination program (STEP) indicated dry-weather flows could potentially triple over the next 20 years. Based on these modeling results and current wet weather capacity issues, the city determined further STEP projects could not be performed within the BNI service area until

Jan 1, 2011

By O. F. Oxtoby, J. E. Olsen, M. W. Erwee, Q. G. Reynolds

"The extraction of molten products and wastes through smelting furnace tap-holes during the tapping process is a complex procedure involving many coupled thermophysical effects. Insight into the fluid flow behaviour in such systems can be gained by using computational mechanics tools to build highfidelity models of the fluid flow and other relevant physics. Previous work using such models indicates that the nature of the flow in the tap-hole, as well as operational parameters such as the tapping flow rate, depends strongly on the properties of the material being tapped and the geometry of the tap-hole channel. Additional complications arise when multiple fluid phases (for example, slag and metal) are present simultaneously, when porous coke beds hinder flow to the tap-hole entrance, and when the geometry of the tap-hole changes over time due to cycles of wear and repair. In the present work, challenges with the coupling of phenomena such as multiphase flow and porosity into computational fluid dynamics methods for tap-hole modelling are discussed in the context of electric furnaces used for ferromanganese production. Qualitative and quantitative results of computational models of flow through tap-holes are presented and compared as a function of material parameters to determine sensitivity effects, and in response to operational parameters to determine typical process behaviour over the duration of a tap. IntroductionPyrometallurgical production using electric furnaces accounts for substantial portion of the world supply of ferroalloys and other strategic materials (Degel et al., 2015). A range of different furnace designs may be used depending on the metallurgical process, with circular three-electrode submerged arc furnaces (SAFs) powered by alternating current being the most common for commodities such as ferromanganese and silicomanganese (Olsen, Tangstad, and Lindstad, 2007).As shown in Figure 1, manganese furnaces typically operate with a deep charge consisting of an upper layer of loose burden (onto the upper surface of which is fed solid raw material), a molten slag layer partially or completely filled with unreacted carbonaceous reductant (generally metallurgical coke), and a molten metal layer which settles to the bottom of the furnace due to its high density. The solid particles present in the slag and burden layers form porous beds which hinder the fluid flow of molten process material and gases inside the furnace (Olsen, Tangstad, and Lindstad, 2007).In order to remove material from the furnace during normal operations, a single tap-hole is built into the sidewall of the vessel near to the level of the hearth. Tapping involves removing both slag and metal phases through the same tap-hole channel, which makes tap-hole design, operation, and maintenance particularly complex. In the case of processes such as ferromanganese, which operate with no external gas injection or open arcs present at the furnace electrodes, flow of material out of the tap-hole is driven primarily by the hydrostatic pressure generated by the weight of the solid and liquid phases above the tap-hole."

Jun 1, 2019

By W. O. Philbrook

Reduced-scale models have long been used in hydrodynamics, aerodynamics, and heat transfer for studying fundamental flow relations or the performance of prototype designs under prescribed conditions. The pilot plant is a common tool of chemical engineering for investigating process variables and as an integral step in developing a new process. The metallurgical industry was rather slow to recognize the applicability of these techniques to some of its established and rather complex processes, but there has been a rapidly increasing number of applications of the principles of modeling in process metallurgy since World War II. Not only have pilot-scale operations been employed for developing methods of extracting metals that have recently achieved commercial importance, as well as new processes for some of the commoner metals, but models have also been used for engineering studies aimed at better understanding of the controlling, variables of time-honored conventional processes, It appears that the principles of similitude have become accepted as a useful tool, when properly applied, in metallurgy as in other fields of engineering. Much of the work of the Pyrometallurgical Laboratory, Region V, involves study of high-temperature smelting and refining processes for ferrous and related metals in pilot-scale equipment, such as the experimental blast furnace, converter, open-hearth, arc furnace, and rotary kiln. It was appropriate for the work of this laboratory that guiding principles for designing apparatus and interpreting results should be set down and that a bibliography of related work should be available for reference. A summary of the principles of model study and a brief review of some of the more noteworthy general papers have been published elsewhere.3/ Also, the Bureau of mines plans to publish a report of investigations describing its experimental work in this field. The bibliography is presented here as a service to others who may have use for it.

Jan 1, 1958

By D. B. Dow

This paper on the physical chemistry of oil-field emulsions is the last of a series of three prepared as a result of a study of oil-field emulsions. The first paper3 deals with the factors responsible for the formation of emulsions, find the second4 with methods now utilized for dehydrating oil-field emulsions. A more complete report of the whole investigation is in preparation. The laws governing the formation and resolution of oil-field emulsions fall in that branch of physical chemistry doling with colloids. Much work has been done by the physical chemist on colloids And emulsions, and, although most of this work was on commercial and pharmaceutical emulsions, yet the principles developed apply in a general gray to oil-field emulsions.

Jan 1, 1925

By Ameir Altaee

Unconventional means and methods were utilized to install over 650 contractor-designed micro-piles for the replacement of the Bronx approach to the Bronx-Whitestone Bridge in New York City. The method utilized reverse circulation (RC) drill rods and down-hole-hammers (DHH) along with grouting through the DHH bit. The overall construction sequence of drill-down, grout-up, place reinforcing is similar to auger-grout piling. The extremely tough drilling conditions required the use of a percussive DHH. The piling subcontractor refers to this pile as a hammer-grout pile. Project background, constraints and subsurface conditions are given. The proposed means and methods as well as the collaboration between stakeholders are detailed. Results of load testing and production installation are summarized.

Jan 1, 2010

By Ernest Hersam

THE rate of output of a rock crusher is based upon a certain space relation, the calculation requiring that the size and position of the jaws, the principle of motion, and the speed of the machine be known. The result is a calculated maximum output. The purpose of this paper is to develop a method of calculating this maximum output, to judge the general applicability A utility of such a calculation, and, so far as possible, to record calculated values as a basis for the comparison of actual results, or for estimating the capacity of a new crusher or of a standard crusher working under new conditions. A method for calculating the capacity of crushing rolls, which has been in common use for a long time, is well presented by R. H. Richards.1 The output is conceived as a ribbon of rock, of which the breadth, thickness and length are governed respectively by the width of the rolls, the space, between them, and their peripheral velocity. The weight of the rock thus crushed in a given time can be calculated from its specific gravity, after applying a factor representing the percentage of voids in the hypothetical ribbon. The calculation of crusher capacity is made in a somewhat similar manner. While the action of rolls is simple, with few irregularities in operating conditions, in rock crushers the material advances intermittently, usually under the force of gravity alone, and is subjected to a variety of variable conditions. The effect of these variable influences upon' the calculation of capacity is now to be shown. In this paper, capacity will be discussed quite apart from any consideration of mechanical efficiency; that is, results will be stated not in terms of output per horsepower, but of output for a given machine when operated at a known speed, constructed and adjusted to receive material of a known size, and to yield a product having a definite maximum coarseness.

Jan 7, 1922

By Alan de Sousa

O presente trabalho tem por objetivo revisar o atual plano de lubrificação de um laminador a frio modelo Sendzimir, tendo como foco principal determinar por meios analíticos, a confiabilidade dos processos de relubrificação à graxa de mancais de rolamento. Para a determinação dos parâmetros de relubrificação do restante dos conjuntos, que não são mancais de rolamento, foi realizada a consulta dos catálogos dos fabricantes para a determinação dos intervalos e quantidades, conforme recomendação destes. Para a realização deste trabalho, foi necessária uma extensa revisão bibliográfica, de normas e literaturas referentes a este tema. No final deste, objetiva-se a obtenção de um aumento da confiabilidade dos equipamentos, além de uma redução de custo com mão de obra e lubrificante durante os períodos de relubrificação.

Oct 30, 2017

By Stoyan N. Groudev, Ioannis Paspaliaris, Irena I. Spasova, Kostas Komnitsas

"Acid mine drainage waters generated in the uranium deposit Curilo, western Bulgaria, were treated by means of a constructed wetland located in the deposit. The waters had a pH in the range of about 2.5 - 4.1 and contained uranium, radium, some heavy metals (iron, manganese, copper, zinc, cadmium, cobalt, nickel, lead), arsenic and sulphates in concentrations much higher than the relevant permissible levels for waters intended for use in the agriculture and/or industry. The wetland covered an area of about 140 m2 and was characterized by an abundant water and emergent vegetation and a diverse microflora. Typha latifolia, Typha angustifolia and Phragmites australis were the prevalent plant species in the wetland but species of the genera Juncus, Eleocharis, Scirpus, Carex and Poa as well as different algae were also well present.The water treatment was started in July 2001 and until now (August 2002) the wetland effluents were characterized by pollutants concentrations decreased below the relevant permissible levels. The water flow rate through the wetland during this period varied in the range of about 0.2 - 1.0 l/s. The water clean-up markedly depended on the temperature but was efficient even in the cold winter months at air and water temperatures close to 0oC. The removal of pollutants was due to different processes but the microbial dissimilatory sulphate reduction and the sorption of pollutants on organic matter (viable and dead plant and microbial biomass) and clay minerals played the main role. Negative effects of the pollutants on the growth and activity of the indigenous plant and microbial communities were not observed."

Jan 1, 2003

By M. M. Austin

Pure metallic tantalum, from a practical standpoint, is one of the newer developments in the metal field. Although it was used as filament in incandescent lamps in 1906, only within the last, five years has the metal been available in sufficient quantity and suitable form for more general application. In addition to corrosion-resisting properties and high melting point, the metal has an ability to withstand unusual amounts of cold working. It affords some striking demonstrations of block movement during plastic flow. Strength and Ductility of Tantalum Since there is no good way of defining working properties numerically, illustrations will be used. It is possible to roll a bar of pure tantalum 0.4 in. thick to sheet 0.001 in. thick, without heating or annealing. The sheet produced will be sound and may be bent upon itself at right angles to the direction of rolling. Longitudinally the sheet will be somewhat brittle. A disk of annealed metal may be cupped and drawn to the form of a capsule 3/16 in. dia. by 146 1? in. long. If carefully handled this capsule can be further deformed by drawing to a tube having an outside diameter of 0.050 in. Disks of tantalum may be spun into tubes of 39 in. dia. and 1½ in. long. In the form of rod, reductions may be made from 0.4 in. to 0.001 dia. In the latter process, it is necessary to heat the wire four or five times to 500" C., at intervals between 0.040 and 0.001 in. Although the melting point of tantalum is 2850" C., these heatings at 500" C. are sufficient to distinctly anneal it. Published figures on the strength and ductility of tantalum are not particularly accurate. This is due to the fact that these properties vary widely, depending on the extent to which the metal is contaminated by gas. There are no sharp critical points in these changes with gas content; samples of metal will vary from a springy or actually brittle condition to one of leadlike softness. Samples that have had a prolonged heating at high temperatures in a good vacuum, under conditions such as would be provided in vacuum-tube experimentation, will yield a product of about the hardness of annealed copper. The usual commercial metal will have the hardness of annealed mild steel.

Jan 1, 1930

By N. M. Safaya

Moderate to acute deficiency of plant available phosphorus is very common in western coal mine spoils and topsoils. Although some of the spoils are known to contain seemingly adequate amounts of total phosphorus, the plant available phosphorus is so low that it constitutes a serious plant growth limiting factor in the mined lands. For the revegetation of these spoils, the use of species, varieties and ecotypes exhibiting greater efficiency for P uptake and utilization, or conversely, lesser susceptibility to P deficiency would be highly desirable. To identify such plants, quick and adequate methods of screening germplasm should he available. In the present growth chamber study several plant species were screened using continuous flow culture and spoil culture systems to provide information on their relative susceptibility. In flow cultures, P was maintained at 0.25, 2.5, and 25 moles; while in spoil cultures it was applied at 0, 25, and 75µg/g to a P-deficient spoil. Phosphorus deficiency symptoms appeared in alfalfa cultivars, birdsfoot trefoil, emerald crownvetch and yellow sweetclover within 7-10 days upon transfer of their seedlings to U.25 or 2.5 µM P solutions. Burning bush and Russian thistle, found abundantly as pioneering species on mine spoils, showed no deficiency symptoms; their shoot dry matter yield in the 0.25µM P treatment was 24% and 36%, respectively of their maximum yield obtained with 25 µM P. However, the percent increase in the dry matter yield of legumes with 0.25 µM P ranged from 7-13% over their maximum yield. With the increase in solution P concentration, the root dry weight ratio in the legumes increased from an average of 0.22 to 0.43, while in the weeds from 0.14 to 0.30. The low susceptibility of Russian thistle to P deficiency was also demonstrated in the spoil culture experiment. Legumes showed greater response to P-fertilization on the spoil than did the two weeds. With increasing concentrations of P in the solution, the root weight ratio of all the species decreased. At 25 µM P, weeds invested only 14% of their total dry matter yield in the root fraction, where as legumes and grasses invested as much as 24% and 33% respectively. Weedy species averaged higher P concentrations than the legumes and grasses. The mean P concentrations of alfalfa cultivars were the lowest among legumes. In general, P concentrations increased with the increase in P supply. In the flow culture system, P supply increased the Ca levels of legumes. The mean Mn concentrations were highest in the weedy species. The increases in P supply decreased Zn levels in all of the species. File effects of P fertilization on the tissue concentrations of Mn and Zn in spoil culture were similar to that of flow culture system. From this preliminary study, it may be concluded that the continuous flow culture system is efficient in rapid screening of a large number of species under controlled conditions for their efficiency in adapting to mineral stresses.

Jan 1, 1982

By Rees J. Llewellyn

High chromium white irons can be formulated to provide required combinations of abrasion and erosion wear resistance, toughness and capability to withstand corrosion attack. As a consequence, they are used widely in casting form throughout the mining/mineral processing industry, particularly as components for slurry pumps and also as mill and crusher liners, laminated wear plates in chutes and hoppers and in valves, nozzles and cyclones. Traditional cast chromium molybdenum and high chromium white irons for wear applications are covered in ASTM A532 Classes 11 and 111 and are also available as comparable proprietary alloys. They rely on heat-treated, hypoeutectic microstructures containing a high volume fraction of very hard eutectic/secondary metal carbides and martensite to provide extremely high wear resistance. The ability to increase the carbide volume fraction and hence achieve higher wear resistance, has been limited because of severe casting difficulties encountered when carbon and chromium contents are raised and hypereutectic alloys with structures also containing coarse acicular primary metal carbides are produced. The limitation has been overcome and cast hypereutectic chromium white iron pump components have established themselves in a wide variety of mineral processing service applications. Comparisons will be made between the microstructures and wear test performance data for the various alloy types and details will be provided of the service performance improvements that have been achieved through the use of hypereutectic chromium white irons.

May 1, 2004

By Demetrius Da Rós Ruy

O lingotamento contínuo é uma das etapas mais importantes na produção de aço, sendo um método rápido e eficiente na fabricação de placas ou tarugos através de processos de resfriamento onde o aço líquido é moldado e solidificado. Contudo, têm sido historicamente observado problemas de processo corrosivo acentuado na câmara de exaustão e na estrutura das máquinas da ArcelorMittal Tubarão. Os mecanismos deste processo corrosivo em máquinas de lingotamento contínuo, em geral, são variados e diretamente relacionados às condições operacionais da máquina, conduzindo a elevados custos de manutenção, diminuição da vida útil das máquinas, causando insegurança e interferindo na qualidade do produto. Este trabalho objetiva descrever as causas principais deste processo corrosivo e mostrar o desenvolvimento de testes que foram conduzidos visando a minimização deste fenômeno na máquina de lingotamento de placas #1 da ArcelorMittal Tubarão no ano de 2017.

Oct 30, 2017

By R. R. Culbert

Several thousand parts per billion of uranium are present in some alkaline lake and ground waters of the Okanagan region, British Columbia. To a major extent the uranium content of these highly anomalous waters is controlled by their levels of dissolved bicarbonate. In lakes, dissolved bicarbonate and the organic content of the sediment largely control the partitioning of uranium between sediment and water. This relationship is found to a lesser extent in alkaline creeks, and transported geochemical anomalies in soils appear where uranium-bearing alkaline ground waters have encountered organic materials. There is a possibility that young, near-surface deposits (with very low radioactivity) are forming from these uraniferous waters.

Jan 1, 1978