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By G. L. Boxer, R. A. Metz, C. B. Smith, W. J. Atkinson

Since the inception of the Ashton (formerly Kalumburu) Joint Venture in 1972 the parties have expended $24 million in exploration for diamonds in the Kimberley region. This has resulted in the discovery of the currently subeconomic Ellendale deposits in 1976/77 and the economic Argyle - Smoke Creek Deposits in 1979/80. In addition to Argyle and Ellendale, some 90 kimberlitic and lamproitic bodies have been discovered grouped broadly into three provinces, on the west, east and north margins of the Kimberley block. These bodies range in size from dyke-like features less than 1. m (3 ft) in width to pipes with a surface area of 128 ha (316 acres). The bodies with larger surface area are volcanic crater deposits, infilled with air-fall and water deposited tuffs and epiclastic sediments. Diamond content ranges from trace to economic concentrations. The exploration discoveries were facilitated by early recognition that the petrography, mineralogy and chemistry of the diatremes varied from the classical kimberlites of Kimberley, South Africa, to unusual more highly fractionated, alkaline, silicic varieties having affinities with leucitelamproite. Indirect methods of exploration were used, primary reconnaissance work being stream gravel sampling for kimberlitic indicator minerals. Evaluation showed Ellendale diamonds are 90% gem and near gem, but the low grades and tonnage render the deposits unpayable at today's diamond prices. After discovery in late 1979 and completion of a feasibility study by the end of 1982, evaluation studies proved Argyle to be economic. Alluvial diamond mining commenced in 1983 producing 6.2 million carats (Mct) that year, 60% being of industrial quality. Open-pit mining of the AK1 lamproite should start in 1985/1986 at a rate of 3 million t/a (33 million stpy) and produce 25 Mct/a, making this mine, and Australia, the world's largest producer of diamonds by weight. The revenue from diamond deposits is a function of the grade and the value of the diamonds. The grade is the product of the frequency of occurrence of the diamonds (stone density) and the mean stone size; the value of the stones is strongly related to their size distribution. During evaluation of the West Australian deposits, the diamond distribution was found to vary markedly in stone density and stone size. These variations corresponded with changes in the rock type hosting the mineralization. As a consequence, geological mapping of individual lamproites within the multiple vents and careful monitoring of the diamond distribution became an important part of the evaluation work. Similar variations in stone size and frequency were found to accord with separate alluvial terraces and fan gravels derived by erosion from the Argyle AM lamproite.

Jan 1, 1992

By A B. Christie, R Barker

Recent studies carried out to support the development of a strategy for the New Zealand mineral industry by the NZ Minerals Industry Association have included investigations of mineral potential, and the development of scenarios for realising this countryÆs mineral potential by 2010. New economic research is applying a general equilibrium model to quantify the opportunity cost of this potential. The model analyses separately four categories of land (private land and three categories of Crown land) and identifies four distinct mineral classes û precious metals, industrial minerals, coal and aggregate. It investigates the economic effect of the increased availability of mineral resources on the mining industry itself, on other industry sectors and on the NZ economy generally, including its impact on unemployment, GDP and household welfare.The analyses suggest that increases in the level of GDP of between 1.9 per cent and 3.4 per cent may be obtained by utilising New ZealandÆs mineral wealth to varying degrees. The mineral industry sectors are significant beneficiaries under all scenarios; mineral output increases by between two and five times its current level. However, the flow-on effects to the rest of the economy, and to households, are also significant. The analyses show that household income, adjusted for changes in consumer prices, can be expected to increase by between 1.6 per cent and 2.7 per cent. This results largely from increased employment.

Jan 1, 2002

By Luis Ángel De Montreuil

El oro nativo es un elemento inerte de condiciones primarias que en muchos depósitos se encuentra en las zonas de oxidación. Sin embargo, el destino del oro durante los procesos de oxidación es controlado principalmente por la naturaleza y tamaño de las partículas de oro en los depósitos primarios. En ese sentido, el presente texto describe este proceso de oxidación y el posterior enriquecimiento secundario de los yacimientos de oro. Para ello, se realiza una estratigrafía de las zonas de óxidos y sulfuros supergénicos de los yacimientos auríferos a través de muestreos sistemáticos, mineragrafía, petrografía y ensayos químicos. Dicho proceso permite establecer una mejor planificación del tratamiento metalúrgico y releva la presencia de ricos horizontes auríferos en un yacimiento, en cuyo caso el tratamiento metalúrgico puede ser selectivo.

Jan 1, 1985

By Robert J. Ramsey, N. Finkelstein, Robert D. Jeppson

Introduction The Utah Copper Division of Kennecott Copper Corporation will present its contribution to the A. M. Gaudin Flotation Symposium in four parts. The first two segments will discuss briefly the historical development of the Utah Copper Division and describe the ore body. The third segment will review the facilities and operating procedures for the Utah Copper Division's newest plant, the Bonneville Concentrator. The fourth segment describes flotation process circuitry, including molybdenite recovery procedures, at the Arthur and Magna concentrators. (The Bonneville concentrator is a crushing and grinding unit and does not have its own flotation plant). 1. Historical Development Progress through change has been the key to the successful operation of the Utah Copper Division for more than 70 years. As the original low-grade copper operation, the pressures to remain competitive and profitable have dictated the timing and extent of each change. Much of the change has occurred through technological and economic advancements in the area of ore concentration. The Utah Copper Division of Kennecott Copper Corporation had its origin June 4, 1903, when the Utah Copper Company was organized. The initial mill of 300 tpd (tons per day) capacity was built at Copperton a few miles below the present Bingham Canyon mine site. From 1904 to 1910, the Copperton mill was expanded to a capacity of 1,000 tpd, and all of the known apparatus for gravity concentration were evaluated.

Jan 1, 1976

By Sridhar Krishnan

This paper presents the results of a comprehensive pre-production pile testing programme for the US$ 800 million 1400MW Coal-Fired Jimah Power Plant Project in Negeri Sembilan, Malaysia. The testing programme included high-strain dynamic testing and fully instrumented static axial and lateral load testing of driven prestressed concrete piles and bored cast-in-place piles. A highlight of the testing programme was the pioneering use of the Global Strain Extensometer (GloStrExt) Method, a deformation monitoring system that uses advanced pneumatically- or hydraulically-anchored extensometers and a novel analytical technique to monitor loads and displacements down the shaft and at the toe of driven prestressed concrete piles. The experience with the testing programme for the Jimah Project also demonstrates the possibility of achieving notable breakthroughs, not only in the monitoring, evaluation and reporting of pile foundation behaviour dynamics but also in our understanding of the mechanisms that underpin such behaviour. These significant gains are undeniably a direct result of the committed and co-operative relationship among the project owner, design/builder, specialist piling subcontractors, pile suppliers and pile instrumentation and testing specialists.

Jan 1, 2006

By Earl L. Phillips

The Bureau of Mines conducted laboratory tests on samples of pozzolanic-cement concrete to develop a low-strength backfill. Results show that support costs can be lowered by replacing a portion of the portland cement in mine backfill with pozzolan (fly ash) and lime. Unconfined compression tests on various ratios of fly ash to cement in 84 samples produced compressive-strength curves that can be used to estimate the best backfill mix for any mine.

Jan 1, 1981

By R. L. Amelunxen

"In January 1983, Gibraltar Mines Ltd. started an exploratory program on Column Flotation with hopes of improving performance of the Molybdenum Cleaning circuit. The encouraging results led to a column test trial in the Bulk Copper Cleaner circuit where the test unit has per¬formed well. A program was undertaken to understand the mechanics of column operation. A year and a half later, Gibraltar is considering the replacement of existing Bulk Copper and Moly Cleaning flotation cells with a fully computer con¬trolled Column Flotation circuit.BRIEF SUMMARY OF TESTWORKInitial testwork was done with a home made 20 inch diameter x 31 foot high column, equipped with a doppler flow-meter at the tail line and automatic level conrol. This loop maintained constant level in the column by throttling the tail valve. This column was placed in a variety of locations around the Moly circuit as shown on Figure 1 a, b. Test re¬sults indicated that the column could achieve much higher grades than the conventional cells, but recovery wise, the performance was low. Spillages from overloaded pump boxes were a common frustration during this time.Column control strategy was reviewed; and, in light of information received from McGill University, changed to conform with the methods that had been employed by D. Wheeler, of the Column Co. of Canada4 and Gaspe Copper Mines3.The column was tested replacing a portion of the bank, figure lc. The results obtained were more or less equal to the circuit. However, as we had Nitrogen gas connected to the column and not the regular cells, the column was kept in service. With the use of Nitrogen in the column, the usual copper depressant, Sodium Cyanide could be replaced with Sodium Hydrosulphide, hence lower operating cost.As time went on, a 10 inch diameter column was added in series to re-treat the concentrate of the 20 inch diameter column with hopes that the copper content would decrease from 0.6% down to 0.3% in order to save on subsequent leach¬ing costs. So far, results indicate there has been some im-provement, hut we are not achieving 0.3% copper. (See figure 1d)."

Jan 1, 1985

By Ariel Orellana Wiarco

Para diseñar un sistema de ventilación de una mina subterránea se debe determinar la cantidad total de aire necesario y la caída total de presión. Con estos datos se planean las obras y se selecciona el equipo de ventilación adecuado Así, el objetivo de este diseño de sistema de ventilación es proporcionar condiciones ambientales subterráneas seguras, sanas y saludables. En este sentido, el presente texto refiere la forma en que la fricción, densidad, humedad, temperatura, determinación de requerimientos de aire, dimensiones, contaminantes de escapes de motores diesel, ventilación natural, envases y difusores entre otros factores afectan el diseño de sistemas de ventilación para minas subterráneas.

Mar 1, 1983

By Carolina Gomes Dias Ribeiro

The modern composite materials, especially those reinforced with synthetic fibers such as glass and carbon, have been used since last century to attend the demands required by most technological fields, from home appliances to aerospace. Natural fibers composites with biodegradable polymer matrices are considered environmentally friendly materials and currently accepted as possible substitutes for synthetic composites. These green composites can be safely discarded or composted at the end of their life without harm to the environment. Another alternative for synthetic composites is to apply natural lignocellulosic fibers as reinforcement of conventional polymer matrices and already used in the automobile industry. In addition to the environmental and societal advantages of the green composites, the lignocellulosic fiber reinforced conventional polymer composite also has economical and technical advantages. In the case of a fiber collected as a waste, the price of the composite can be considerably lower than “fiberglass”. Furthermore, with high strength lignocellulosic fibers such as sisal, ramie and malva the specific strength of a composite may approach that of “fiberglass”. Therefore the objective of the present work is to investigate the mechanical behavior of polymer matrix composites reinforced with high volumes of natural malva fibers subjected to tensile stresses.

Aug 16, 2017

Sasol Roche Blasting Services (SRBS) and its former owners have been in the process of developing and utilising low-density explosives over the last ten years. Many blasts have been fired in varying strata types in a number of mining operations. This has led to a good understanding of the product and the best methods to exploit its characteristics when designing blasts. Unlike some other low-density products, SoftLOAD« is a homogeneous mix that is easily handled and able to be loaded at high load rates. This paper discusses the physics of SoftLOAD« low-density explosives and how through correct utilisation, blasting outcomes can be significantly improved. It also touches on the various side benefits that can provide the blast designer with a more controlled blast.

Jan 1, 2004

By Arthur Darby

The city of Kuala Lumpur was founded in 1857 by miners seeking tin near the confluence of the Klang and Gombak rivers. The rapid development of the city and surrounding area since independence has led to more rapid runoff during rainstorms and to gradual canalisation of the rivers with some restricted sections. The outcome has been more frequent and more severe floods (Abdullah 2006). At the same time the centre of Kuala Lumpur has become a modern inter-national city with tall office buildings, hotels, and shopping centres connected by a network of wide roads and commuter rail systems. With these the cost of dislocation during floods has risen as has the cost of making good damage afterwards. The Government of Malaysia considered these consequences unacceptable and sought ideas from the private sector for a solution. Potential solutions consisted of variations on the themes of bypassing the city centre with a flood relief tunnel or of providing off channel storage or a combination of both. Since under Malaysian law a tunnel cannot be constructed under private property unless this is first purchased or agreement reached with the owner, it was necessary for most of the tunnel alignment to run below existing heavily congested roads. After considering these facts Gamuda Berhad and MMC Berhad, two leading Malaysian development and construction companies, decided to propose to Government an innovative solution in which the tunnel would be used to carry road traffic except during floods.

Jan 1, 2008

By Rolland L. Blake

The Bureau of Mines is investigating the potential for in situ leach mining "(ISM) of gold and silver mineralization. This preliminary study examined samples from several types of deposits using light optical microscopy and the electron microprobe to characterize the ore and gangue minerals and their microscopic characteristics, including the spacial relations between the target minerals and likely natural fluid channelways. Low grade disseminated deposit types from the western U.S. were found to contain fracture-hosted or matrix-hosted gold and silver minerals, some of which are encapsulated by quartz or pyrite. Geologic features readily observed microscopically include ore and gangue mineral identity, size, and their association with each other and with fractures. Successful ISM application to gold and silver deposits needs this data to: (1) select the proper lixiviant based on chemical reactivity of the host rock, ore, and gangue minerals, (2) determine potential permeability characteristics when designing lixiviant flow patterns, and (3) understand potential problems of the lixiviant reaching encapsulated ore minerals. Careful examination of the geologic characteristics of each ore body is required because of the observed diversity of characteristics in deposits from the same "class" and even within the deposit itself.

Jan 1, 1989

By G. R. Wilms

A study has been made of the structural changes in polycrystalline high purity aluminum during the tertiary stage of creep under conditions of constant tensile load. It appears that there is no basic modification in the particular mechanism of deformation that characterized the preceding secondary stage of creep, but that the changes in crystalline structure produced during the tertiary stage are only a consequence and not a cause of the accelerated strain. Intercrystalline fissures were observed on entry into the tertiary stage, and these might supplement the accelerated rate of strain owing to local stress concentrations. There is evidence that the formation of these fissures may be associated with the presence of surface imperfections, and it is suggested that a more generalized treatment of the results may explain certain creep characteristics of commercial alloys. IN previous work'-4 a study was made of the changes produced when specimens of annealed aluminum were deformed at various temperatures and rates of strain, especially under conditions leading to creep under constant tensile load. It was shown that, as the temperature was increased or as the rate of strain was decreased, elements of the substructure produced within the grains became coarser, and with the strain rate constant at a given temperature, their size tended to an equilibrium value. The preliminary process of the breaking down of the grains into a substructure was identified with primary creep.' The subsequent equilibrium, condition was associated with secondary creep. The question then arose whether the tertiary stage corresponded to any further significant change in the substructure. The question is also of interest in view of the opinion, expressed for instance by Andrade,5 that the tertiary stage is merely an accelerated rate of strain due to the reduced area of section of a specimen under continuous tensile load, and the other opinion, as suggested by the observation by Sully, Cale, and Willoughby6 of a tertiary stage in com-pressive loading, that this third stage is a real effect in its own right. The object of this paper is to record some observations on the tertiary stage of high purity aluminum. Experimental Procedure The material was aluminum of 99.98 pct purity as previously used. The specimens had a rectangular section of l/8 x l/2 in., and extensions were measured over a 1 in. gage length. After machining to shape, the specimens were annealed to give a standard grain size of 0.2 mm and then electropolished. The general procedure involved metallographic and X-ray diffraction examination at progressive stages of elongation (marked by arrows on the curves shown in Figs. 1 and 2), the specimen being extended to fracture under constant load at a given temperature. The X-ray tests were made by the back-reflection method from a stationary specimen, using CoK radiation. The longer edge of the micrographs in the paper corresponds to the direction of applied stress. Results The previous work showed that, in the secondary stage of creep in aluminum, three basic types of structure could be developed according to the temperature and rate of strain. These were: 1—slip, which predominated at the lower temperatures and higher rates of strain and produced the finest and least perfect substructure; 2—cell structure, which superseded slip as the temperature was raised and the rate of strain decreased and which was characterized by a coarser and more perfect structure and an absence of slip lines; and 3—a stage termed "boundary microflow," which predominated at still higher temperatures and lower rates of strain when the cell size had increased and become comparable

Jan 1, 1955

By E. O. Afreh, R. J. Bowell, E. Hanssen, D. Pohl, S. Abe, R. K. Yao, N. d'A. Laffoley

In the largely preserved laterite profiles at Syama mine, in the savanna region of southern Mali, element geochemistry in the mottled-clay horizon and below can be related directly back to the protolith, but above this, in the ferricrete and cuirasse horizons, the hypogene signature is much modified by pedogenic processes. In tropical rainforest terrains extensive remobilisation can result in wide but weak geochemical targets for gold and pathfinder elements. At the Hire concession in central Ivory Coast, intense recent alteration of the largely intact laterite sequences has modified soil-geochemical dispersion patterns extensively, producing Fe-rich nodular stone lines and obliterating previous patterns and features. Where the upper horizons of the laterite profile have been removed or reworked, as at the Senoufo concession in northern Ivory Coast (savanna) or the Kubi prospect in Ghana (rainforest), all soil horizons can be related directly to hypogene geochemistry. In these truncated profiles, gold and base metal anomalies are essentially those of the lower weathering profile and form narrow but strong dispersion haloes. A good understanding of the geochemical processes active in deeply weathered profiles is required if targets are to be recognised effectively

Apr 1, 1996

By Sandin E. Phillipson

The Mine Safety and Health Administration?s Roof Control Division responded to a massive ground failure at an underground marble mine in northern Georgia. The ground failure occurred in a benched area that had been abandoned in the early 1990s. It involved the failure of an estimated 19 pillars, in conjunction with a massive roof fall of an undetermined extent that was at least 60 ft high. Pillars in the benched area had been mined nominally 40 x 40 feet to a height of 50 feet ft, with 40-ft mining widths, although it seems likely from measurements and accounts from mining personnel that pillars were even smaller than intended. Average overburden depth was 500 ft, and the rock mass was characterized by three sets of intersecting geological discontinuities that not only defined very blocky conditions that were conducive to pillar spalling and volume loss, but they were also adversely oriented in such a way as to cut diagonally through pillars at a high angle. The recently released S-Pillar software from NIOSH was used to determine pillar safety factors in the failure area and indicated that pillars were undersized for the conditions. S-Pillar was used to assess pillar stability in active areas to evaluate the likelihood of experiencing similar collapses in the future. S-Pillar correctly identified the pillars in the bench area as having been at risk for instability, in light of their ultimate failure. A two-dimensional finite element model was used to evaluate the possible stages of failure and to assess the likelihood of continued failure in the benched area that might affect more distal mine openings. Although stone mines are generally characterized as having more forgiving conditions than those found in softer sedimentary rocks, the failure shares some characteristics with domino-style massive pillar collapses experienced in coal and trona mines. First, the minimum dimension of the benched area approached 350 ft; second, the pillars defined by benching had small width-to-height ratios (0.8), and; third, the pillar failure area was slightly greater than 4 acres. The massive pillar collapse and associated roof fall illustrate the importance of incorporating pillars that have been properly sized for depth and for the final bench height. Furthermore, the designed dimensions must be adhered to during the actual mining process. Finally, the importance of understanding the geological conditions and their effect on the rock mass is critical.

Jan 1, 2012

By Allen D. Look

In the prevention of accidents in milling operations, the proper installation and guarding of electrical and mechanical equipment, safe clearances, good housekeeping, adequate fire protection, adequate ventilation, dust and fume control, and good illumination, as well as safe practices, are essential. In the new concentrator of the Magna Copper Co., Superior, Ariz., many safeguards were incorporated and safe practices instituted to minimize accident hazards. The purpose of this paper is to describe some of these features and practices.

Jan 1, 1951

By A D. Campbell, G R. Power

Many caving mines use numerical flow models to simulate mine production, forecast recovered ore grades and optimise the draw strategy. In sublevel caving (SLC) mines, the effects of blasting and fragmentation at an individual ring scale generally cannot be included in these models. Previous attempts to use results from marker recovery trials to calibrate numerical flow models have been limited due to difficulties in accounting for blasting effects at a ring scale. This paper outlines how an empirical criterion for blasting and fragmentation was used to attribute variable flow properties into a numerical flow model based on the blast design and modelled fragmentation. The flow model was then validated using data from a number of full scale marker recovery experiments. The result of this approach was a significant improvement in forecast accuracy when compared against the same modelled cave marker recovery without the inclusion of these blasting effects. Improvements in the flow model are currently being adopted within the mine scale model to further improve the accuracy of grade forecasting, optimise the draw strategy and increase net present value. The integrated modelling approach is also being used to simulate the effects of different drill and blast designs on cave recovery. It is suggested that, if implemented, the technique would lead to improved blast designs in other SLC mines, increase the value of marker trial data and reduce costs associated with large scale blast design trials.CITATION:Campbell, A D and Power, G R, 2017. Improving calibration of flow models against SLC marker trials by linking blasting effects to particle mobility, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 11–22 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By K. M. Tompson, R. L. Armstrong, C. I. Godwin

"Tungsten skarn deposits on the Clea property in the Selwyn Mountains, Y. T., are related genetically to a quartz monzonite stock, about 500 metres in diameter at the surface. Lower Paleozoic sedimentary rocks are metamorphosed for a distance of 3 km from the stock. Tungsten-bearing skarn mineralization within the altered sedimentary rocks is of two types: sulphide-rich pods and calc-silicate beds. The most significant scheelite concentration is in calc-silicate beds near or adjacent to the quartz monzonite stock. Discordant K-Ar and Rb-Sr isotopic dates indicate that the stock is probably of early Late Cretaceous age, 94 Ma or slightly older, and that it cooled slowly. High initial 87Srl86Sr ratios and disequilibrium relationships between K-jeldspar phenocrysts and groundmass minerals in the porphyritic phase of the granitic rock , and between different granitic rock specimens, indicate contamination of crystallizing magma by old sialic continental crust which extends westward under the Selwyn Basin.This study is significant to regional tungsten exploration. Granitic rocks associated with tungsten deposits, in this part of the Canadian Cordillera at least, appear to have specific isotope characteristics that indicate they were generated at a specific time and in a particular way.IntroductionThe Clea tungsten skarn property (Fig. I) is owned by Canex Placer Limited, and lies in the Selwyn Mountains (Bostock, 1948) near the eastern margin of the Selwyn Basin (Wheeler and Gabrielse, 1972), Yukon Territory. The property covers a 20-square-mile area centered near latitude 62°47 ' north and longitude 129°52' west, and is accessible by helicopter. An airstrip and the terminus of a summer-use gravel road at MacMillan Pass, Yukon, are about 20 miles to the northnorthwest.This paper deals mainly with the geochronemetry of granitic rocks from a stock associated with tungsten mineralization on the Clea property. We show that these rocks have specific characteristics that not only define the genesis of this stock, but also have significance for regional tungsten exploration around plutons in the Canadian Cordillera."

Jan 1, 1980

By J. Alfred Berger, O. M. Katz

The Zv-Hf-H ternary system was studied between 500° and 900°C at pressures less than 1 atm of hydrogen gas between 1 and 60 at. pct H. A new and unique microgravimentric apparatus was used. Cizanges of slope on pressure-hydrogen composition isothernis delineated phase boundaries. These boundaries separatecl the three regions, a, 0, and y—so designated to correspond to the regions of the Zr-H binary system—from the multiphased areas between them. A eutectoidal decomposition was found with the ß region phase or phases decornposing into a lamellar product on quenching to rool ter,zperatuve. Reproducible decomposition-pressure hysteresis occilrved lnainly at lower hydrogen cornpositions and at lower temperatures across multiplzase vegions between a and 0 and a and y. Tire effects of hqfniur7z on the hydriding charactevistics of zirconiurrz weYe as follows: 1) stabilization of the a and y vegions while destabilizing the 0 region; 2) a/?preciable elevation of the decomposition pressrkres in the multiphase region between the a and /3 field; 3) ~nouenzent of the eutectoid reaction to high te~nperatures; 4) reduction in the total qiiantity of hydrogen absorbed under one atmospheve of Hz p7-essure; and 5) introduction of a split deconzposilion at the eiitectoiclal poinl in pa?? of the ternavy. Assuru~ptions based on an ir-2terstitial vandonl-solulion rtioclel 0.f hydrogen in metals slzowed that the bindit~g energy between solute sites prednnzinatecl at low /i?!dvogen concentrations. However, at high hydrogen contents the entropy was the predorninatlt factor in determining the stability of the Zr-Hf-H al1o.s. This was interpreted to mean a scarcity of filrtlzer itltevslilinl solute sites caused by hydrogen-hydvogen intet-actions in the metal lattice. INTEREST in the reaction of hydrogen with metals has increased in the past few years for the following reasons: 1) the formation or use of high hydrogen potential environments in nuclear reactors; 2) the reaction of hydrogen with alloys in nuclear reactors with the accompanying deleterious effects on the mechanical and corrosion properties; 3) the theoretical implications of thermodynamic data on the theory and rules of alloy formation in the metal-hydrogen systems; 4) the use of hydrogen-containing fuels in rocket engines; 5) the need for a process of making fine metal powders of high-melting reactive metals; and 6) the beneficial impregnation of superconducting alloys with hydrogen. In nuclear pressurized-water reactors, the problem exists of limiting the hydrogen pickup of zirconium alloys which are utilized as fuel cladding, heat shields, and support members. In general, zirconium alloys have good mechanical and corrosion-resistant properties in high-temperature water. However, hydrogen is absorbed from the corrosion reaction between metal and water, greatly accelerating the formation of the corrosion product ZrOz as well as mechanically embrittling the underlying metal. In addition, recent observations1 at zirconium to hafnium welds showed that secondary elements in zirconium can have an appreciable, and somewhat unexpected, effect on hydrogen absorption. This paper lists the thermochemical data in the range 500" to 900°C for the equilibrium reaction of four high-purity Zr-Hf alloys with hydrogen. Phase boundaries and thermodynamic functions are determined while the structural data will be presented in a future paper. In general, the Zr-Hf-H system approximates the well-known, eutectoidal, Zr-H diagram2,3 with modifications introduced through the behavior of hafnium.4,5 The Hf-H system,' published while this work was in progress, provided a consistent trend with the Zr-Hf-H data. PREPARATION OF Zr-Hf ALLOYS Table I presents a complete flow chart of the preparation procedure. The zirconium and hafnium crystal bars were completely immersed in high-purity kerosene and slowly cut into thin wafers. Wafers were then cold-sheared into approximately 1-g pieces, thoroughly cleaned, weighed, and inserted into the furnace. The alloys, B-2, B-4, B-6, and B-8, were then nonconsumable arc-melted under 500 mm of purified argon. Additional purification of the argon was accomplished by melting a large titanium button each time an alloy was re-melted or a different alloy melted. Each alloy button, which weighed 25 g, was remelted four times in an approach to complete homogeneity. Material losses were less than 0.02 wt pct. Alloy buttons were alternately cold-rolled and vacuum-annealed into 10- and 20-mil sheets. Table I1 gives the composition of the four alloys used. Very little elemental segregation existed be-

Jan 1, 1965

By Ray E. Williamson

One of the prime objectives of the mine industry is to develop a low cost way to clean up what has been called "The Rape Of Mother Nature". The project falls under the broad umbrella of reclamation, which is now considered an essential part of the mining cycle. As such, it is being given full consideration in the initial planning of all surface operations. In most areas, if a proposed mining system does not lend itself to proper reclamation, it is not an acceptable system. By combining mining and reclamation plans, a producer not only can minimize reclamation costs, but can also restore the land to usefulness and insure continuing profits after a deposit is depleted. As long as fifteen years ago, many of the larger mining companies were already deeply involved in this extra cost work. Even then the involved companies were projecting a great need for a bigger bulldozer, Bigger than anything commercially available. At that time, the D9 tractor weighed about 60,000# bare weight.

Jan 1, 1975