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By K. M. O’Connor

Time Domain Reflectometry (TDR) is a pulse testing technique developed by the telecommunications and power industry for use in locating breaks in cables. Variations of this principle have been utilized in applications pertinent to closure and reclamation of coal operations. This paper focuses on applications of TDR technology in the mining industry including monitoring of slope movement, abandoned mine subsidence, ground water levels and subsurface LNAPLs, landfill cover performance, and consolidation of mine tailings. TDR technology has been particularly effective for remote automated monitoring, and alarm systems have been implemented for monitoring subsidence.

Jan 1, 2003

By John J. Jonas, Sang-Hyun Cho, Ki-Bong Kang

"The recrystallization behavior of Nb micro alloyed steels containing Cr, Mo, Ni and Ti. was studied using hot torsion testing with the aim of modeling the recrystallization processes and the mean flow stress taking into account the microstructural behavior during hot rolling. The kinetics of static and metadynamic recrystallization were characterized and appropriate expressions were formulated for the recrystallization kinetics. These are shown that the recrystallization kinetics depend on steel composition and the processing conditions. The stress-strain curves were determined in order to derive new equations for the peak stress, peak strain, mean flow stress and softening kinetics. The peak strain is influenced by the presence of alloying elements; their addition, which has a solute drag effect, retards the rate of grain boundary motion, shifting the peak to the right. The addition of Nb to the steel results in a significant increment in the activation energy for hot deformation, and Mo has smaller effect than Nb, but Cr has the opposite effect. It was also found that the deformation activation energy in these steels was not altered by the addition of Ni. The rate of metadynamic recrystallization increases with strain rate and temperature and is observed to be independent of strain, in contrast to the observations for static recrystallization.The mean flow stress (MFS) calculations, based on the Sims analysis, are then compared with the predictions of a model based on an improved Misaka mean flow stress equation in which solute effects, strain accumulation, as well as the kinetics of static and metadynamic recrystallization are accounted for. Good agreement between the measured mean flow stresses, which is obtained from the mill logs of POSCO Kwangyang #3 HSM (hot strip mill), and 'predicted ones is obtained over the whole range of rolling temperatures. The results demonstrate that dynamic recrystallization followed by metadynamic recrystallization, supported by the unexpected load drops, sometimes occurs for the rolling schedules studied in the present analysis."

Jan 1, 2001

The Kalgoorlie Tailings Retreatment Project (or "Kaltails") involves the reclamation and retreatment of approximately 50 million tonnes of gold tailing situated on the Golden Mile at Kalgoorlie, Western Australia. Tailing is reclaimed and retreated at the rate of 42 million tonnes per annum. The project is a Joint Venture between Poseidon Limited and Gold Corporation, with Poseidon being the major participant (90%) and manager of the operation through its wholly owned subsidiary Kaltails Mining Services Pty Ltd. The marginal nature of the tailing retreatment project dictated that a detailed feasibility study be undertaken. Extensive sampling and metallurgical testing of the tailing permitted the development of an optimum economic processing route. A sensitivity analysis undertaken as part of the feasibility study indicated the project to be very sensitive to gold price and unit operating cost variations, and relatively insensitive to capital cost variations.

Jan 1, 1990

By P. A. Laxen, H. R. Spedden, A. M. Gaudin

WHEN a mineral particle is fractured, bonds between the atoms are broken. The unsatisfied forces that appear at the newly formed surface1 are considered to be responsible for the adsorption of ions at the mineral surface. A knowledge of the mechanism and extent of ion sorption from solution onto a mineral surface is of interest in the development of the theory of flotation.2,3 Study of the adsorption of sodium from an aqueous solution on quartz offers a simple approach to this complicated problem. The availability of a radioisotope as a tracer element meant that accurate data could be obtained.4,5 Three main factors which appeared likely to affect the adsorption of sodium are: 1-concentration of sodium in the solution, 2-concentration of other cations in the solution, and 3-anions present in the solution. Hydrogen and hydroxyl ions are always present in an aqueous solution. By controlling the pH, the concentration of these two ions was kept constant. The variation in the amount of sodium adsorbed with variation in sodium concentration was then determined under conditions standardized in regard to hydrogen ion. The effect of concentration of hydrogen ions and of other cations was also measured. A few experiments were made to get a preliminary idea on the effect of anions. The active isotope of sodium was available as sodium nitrate. Standard sodium nitrate solutions were used throughout these experiments except when the effects of other anions were studied. It was found that sodium adsorption increased with sodium-ion concentration, but less rapidly than in proportion to it. Increasing hydrogen-ion concentration, or conversely decreasing hydroxylion, brings about a comparatively slight decrease in sodium-ion adsorption. Increasing the concentration of cations other than hydrogen or sodium decreases somewhat the adsorption of sodium ion. It would appear as if the kind of anion is a secondary factor in guiding the amount of sodium ion that is adsorbed. Materials and Methods Quartz The quartz was prepared as in previous work in the Robert H. Richards Mineral Engineering Laboratory4 except for the refinement of using de-ionized distilled water for the final washing of the sized quartz, prior to drying5 To minimize the laborious preparation of quartz, experiments were made to determine whether the sodium-covered quartz could be washed free of sodium and re-used. The experiments were successful as indicated by lack of Na' activity on the repurified material and by its characteristic sodium adsorption. Table I gives the spectrographic analyses of the quartz used. The quartz ranged from 16 to 40 microns in size, averaging about 23 microns (microscope measurement), and had a surface of 1850 sq cm per g (lot I), 2210 (lot II) and 2000 (lot III) as determined by the Bloecher method.6 Radioactive Sodium Method of Beta Counting for Adsorbed Sodium: Na22, the radioisotope of sodium, possesses convenient properties.7 It has a half-life of 3 years, thus requiring no allowance for decay during an experiment. On decay it emits a 0.575 mev ß radiation and a 1.30 mev ? radiation. The decay scheme is illustrated in the following equation: [Y Nam S. - 'Net 3 years] The ß radiation is sufficiently strong to penetrate an end-window type of Geiger-Mueller counting tube. This, in turn, makes it possible to use external counting, a great advantage in technique. Furthermore, it permits the assaying of solids arranged in infinite thickness, while assaying evaporated liquors on standardized planchets. The equipment used was standard and similar to that employed by Chang8 The original active material was 1 ml of solution containing 1 millicurie of Na22 as nitrate. This active solution was diluted to 1000 ml. Five milliliters of this diluted active solution was found to give a quartz sample a sufficiently high activity for accurate evaluation of the sodium partition in the adsorption measurements. Also, 1 ml of final solution gave a sufficiently high count for precision on the liquor analyses. The sodium concentration of the diluted active solution was 1.2 mg per liter, so that 6 mg of sodium for 60 ml of test solution and 12 g of quartz was the minimum amount used. The active solution was stored in a Saftepak bottle. Procedure for Adsorption Tests: The method consisted of agitating 12 g of quartz with 60 ml of solution of known sodium concentration for enough time to establish equilibrium between the solution and the quartz surface. The quartz was separated as completely as possible from the solution by filtering and centrifuging. The activity on the quartz and in the equilibrium solution was measured and the partition of the sodium was calculated from the resulting data. The detailed procedure for the adsorption test is set forth in a thesis by Laxen5 In brief, it included the following steps: 1-Ascertainment of linearity between concentration of Na22 and activity measured. 2-Evaluation of factor to translate activity on solid of infinite thickness in terms of activity on an evaporated active film of minute thickness, on the various shelves of the counter shield. 3-Taking precautions to avoid evaporation of water during centrifuging.

Jan 1, 1952

By G. D. Elliot, R. L. Grayson, G. L. Winn

For the years 1990 and 1991, West Virginia's underground coal small-mine fatality rate was approximately 10 times higher than the national coal-industry fatality rate. Although the number of fatalities went down from 22 in 1991 to 17 in 1992, West Virginia still led the nation in coal-mining fatalities. A team of mining and safety professionals from West Virginia, interfacing with the Mine Safety and Health Administration and the West Virginia Office of Miners' Health, Safety and Training, studied this problem. A clear path for formal intervention was determined and is presented here.

Jan 1, 1996

By Brinkmann J. R

In the narrow stopes of South African gold mines, rockbreaking is carried out by drilling and blasting with safety fuse and igniter cord being used as the initiation system. The fuse/gniter cord system is used primarily because of its low cost, however several limitations of this method include: inaccurate delay time, unreliable firing, inflexible application to varied configurations, and the absence of dynamic interaction between holes. Alternative initiation systems that incorporate millisecond timing are being developed to overcome the limitations of fuse(tgniter cord systems. Current investigations by the Stoping Technology Division of the Chamber of Mines Research Organization (COMRO) into the effects of millisecond initiation are being conducted at a deep test site. Experimental blasts using various millisecond delays and the independent firing of holes with fuse/igniter cord are being studied in order to quantify the influence of delay time on the blasting process and to identify the best methods of applying millisecond initiation systems. The effect of design variables such as delay time, hole firing pattern, stemming, and panel layout are discussed. Blast results including throw distance and direction, muckpile profile and rock cleaning times are used in the discussion of different combinations of blasting variables.

Jan 1, 1990

By Joseph W. Leonard, T. S. Spicer

INTRODUCTION Reasons for Thermal Drying The continuing increase in the percentage of minus %-inch coal produced as a result of the increased use of mechanical mining methods has, over the years, tended to shift considerable portions of the work of producing saleable coal to the fine coal cleaning section of the preparation plant. Because a given weight of fine coal will contain substantially greater surface area than an equivalent weight of coarse coal, it follows that, when subjected to wet cleaning processes, the fines will absorb and retain consider- ably more moisture than coarser fractions. Increased moisture pickup in the finer sizes complicates fine coal cleaning since beneficiation may not be limited to the removal of ash and sulfur but often must be expanded to include the additional step of thermal drying to remove excessive moisture. Thus, water which provides the medium for cleaning fine coal is in itself detrimental and, like ash and sulfur, reduces coal quality. Removal of surface moisture by drying is done for one or more of the following 1 reasons: (1) To avoid freezing difficulties and to facilitate handling during shipment, storage and transfer to the points of use; (2) to maintain high pulverizer capacity; (3) to reduce heat loss due to evaporation of surface moisture from the coal in the burning process, thus increasing heating efficiency; (4) to improve the quality of coal used for special purposes, such as in the production of coke, briquettes, and chemicals; (5) to decrease transportation costs; and (6) to facilitate dry coal-cleaning processes. Because benefits to coal transportation and utilization are the most common reasons for thermal drying, the following sections will examine these areas in greater detail. Benefits to Transportation Initial benefits from drying are the reduction of shipping costs from the mine to the point of utilization since more coal can be concentrated into a given weight of product when worthless moisture is removed. Non- combustible~ such as water and mineral matter in railroad shipments of coal are billed the same as coal at $3.32 per ton, according to the recent average costs. Savings of 10 to 20 dollars from drying on the shipment cost of each 50 to 60 tons of coal contained in a typical railroad car is common. Savings on coal shipments from individual mines which result from coal drying can be expressed in terms of hundreds of thousands of dollars and more each year. For example, a reduction of shipping charges of only 5 percent on one million tons per year would mean a savings of 166,000

Jan 1, 1968

By T. J. Joiner

A critical demand exists to develop new mineral resources, and the need for exploration techniques to supplement costly test drilling is becoming; more acute. In the past few years more industries have begun experimenting with geophysical methods to locate and define mineral deposits and delineate reserves. The new techniques have proven profitable in many instances. As a part of a broad long range program to study the mineral resources of Alabama, and in response to requests from land owners and mining companies, the Geological Survey of Alabama is investi¬gating the occurrence of bauxite and kaolin deposits in the Eufeula area. This project is supported by special funds appropriated for this purpose by the Alabama Legislature.

Jan 1, 1966

By Daniel W. H. Su

The ability to predict the effects of longwall mining on topography and surface structures is important for any coal company in making permit applications and anticipating potential mining problems. The sophisticated finite element model described and evaluated in this paper is based upon five years of underground and surface observations and evolutionary development of modeling techniques and attributes. The model provides a very powerful tool to address subsidence and other ground control questions. The model can be used to calculate post-mining stress and strain conditions at any horizon between the mine and the ground surface. This holds the promise of assisting in the prediction of mining-related hydrological effects.

Jan 1, 1986

By D A. Aitzhanova, E Zh Omirzakova

The Republic of Kazakhstan has well developed mining and metallurgical complex. In modern conditions, when deposits of useful minerals are running thin, it is very important to find additional sources for obtaining necessary products. As our investigations showed different kinds of waste may be used for producing of different kinds of products, which are successfully applied in different branches of KazakhstanÆs economy. Analysis of ways for increasing of complex use of mineral raw materials of different deposits, widening raw mineral materials base and decreasing negative effects on the environment, are presented in this paper.

Jan 1, 2003

By C Garlick, O Gregory, H Rogers, B I. Winters, Z C. Ye

BHP New Zealand Steel produces iron from titaniferous ironsand by a direct reduction process comprising multihearth furnaces/rotary kilns/electric iron melters. The electric iron melter is a six-in-line rectangular submerged-arc furnace which takes the partially reduced ironsand (80 per cent metallisation) from the rotary kiln and completes the reduction process to produce iron of nominally three per cent carbon. As the melter operates at around 1500¦C and under very hostile conditions, it is near-impossible to obtain any basic operating parameters such as the velocity and temperature distribution in the slag and in the molten iron. As a first attempt to understand the operating conditions inside the melter, a scaled room-temperature model using wax and water to represent the slag and iron, was constructed. This paper will report on some of the preliminary model results on the temperature distribution.

Jan 1, 1995

By R. F. Mehl, C. S. Barrett, A. H. Geisler

THE complicated nature of the property changes that accompany age-hardening has made it necessary to reconsider and to elaborate the simple dispersion theory.1 It has been apparent for some time that more direct information is needed concerning the atomic mechanism of precipitation from solid solution if the theory of age-hardening is to be developed past a purely qualitative stage.‡ Fortunately, in recent years information has been developed which allows us to trace in detail the lattice changes accompanying the process of precipitation from solid solution. This information relates chiefly to the sequence of the several stages of lattice alteration by which the matrix lattice is transformed to the equilibrium precipitate lattice, and permits reasonable inferences to be drawn concerning the states of internal strain that accompany these stages. This information is most complete for the solid solution of copper in aluminum. The equilibrium precipitate is the ?' phase," CuA12." This forms in plates, parallel to the {100} matrix planes. The atom pattern and atom spacing on the plane in ?' lying parallel to this plane are roughly similar to those opposite it in the matrix.' The formation of ?', however, is preceded by the formation of a transition lattice ?', which again lies parallel to the matrix {100} plane, but in this case the matching of atom pattern and spacing across the matrix-precipitate interface is nearly perfect; thus there is lattice coherency across the interface and the interface is a plane of separation in only a very limited sense.4-8 Particles of ?' may be recognized microscopically and form a well-defined Widmanstätten figure.* The ?' lattice is recognized by the occurrence of diffraction lines on powder photograms or of spots on Laue photograms which may be analyzed in the usual ways to determine the lattice type and the lattice spacings. Very recent research 6.7,1 has shown, however, that streaks occur on the Laue photogram at an earlier point in time during the aging process. These streaks have been attributed to a preferential clustering of copper atoms into small platelike elements of only a few atoms in thickness and a few hundred atoms in diameter, probably of the composition of "CuA12," which may be designated as Guinier-Preston zones or aggregates.1 It is difficult if not impossible to determine the lattice type and lattice spacing in these aggregates. It is possible1 that these aggregates are in fact merely ?' in a high state of dispersion; the inclination to argue this is strong, as we shall see later. Never-

Jan 1, 1941

By Helmut Lerchs

An open-pit mining operation can be viewed as a process by which the open surface of a mine is continuously deformed. The planning of a mining program involves the design of the final shape of this open surface. The approach developed in this paper is based on the following assumptions: 1. the type of material its mine value and its extraction cost is given for each point; 2. restrictions on the geometry of the pit are specified (surface boundaries and maximum allowable wall slopes); 3. The objective is to maximize total profit-total mine value of material extracted minus total extraction cost. Two numeric methods are proposed: A simple dynamic programming algorithm for the two-dimensional pit (or a single vertical section of a mine), and. a more elaborate graph algorithm for the general three-dimensional pit. ASURFACE mining program is a complex operation that may extend over many years, and Involve huge capital expenditures and risk. Before undertaking such an operation, it must be known what ore there is to be mined

Jan 1, 1965

The overall mineral assemblage of the Broken Hill orebody is similar to that of a skarn. However unlike the classical skarns it does not represent contact metamorphism of pre-existing limestone beds. It is a stratiform accumulation of exhalative-sedimentary silica, sulphides, (Ca, Fe, Mn) silicates and carbonates, fluoride and phosphate that has later undergone regional metamorphism. The resulting development of coarse-grained quartz, sphalerite, galena, rhodonite, bustamite, mixed carbonates, fluorite, apatite and many minor phases has produced a sulphide-rich skarn- like mass that like many others of its kind, might best be referred to as a stratiform skarn. Recent investigations of occurrences of this type are showing that the incidence of concentrations of particular metamorphic minerals in and adjacent to such orebodies are closely related to bedding and to former sedimentary facies patterns. From this it appears that the mineral assemblages may be used to deduce not only the nature of the materials laid down in the beds, but also the physico-chemical conditions under which sedimentation took place. Several stratiform deposits, including Broken Hill, are used as examples to show that variations in these conditions may have a profound influence on the subsequent response of the rock to regional metamorphism and hence on the mineral assemblages that finally develop.

Jan 1, 1983

By Scott A. Anderson, Benjamin S. Rivers, Derrick D. Dasenbrock, Silas Nichols

Unknown geotechnical conditions are a major source of risk. Unexplored places vastly outnumber the sampled and tested ones, and widely spaced boreholes with intermittent tests and samples are the norm. Sometimes site-specific planning and thought goes into locating these special, tested places, such as basing them on the geologic understanding or anticipated key locations for the structure; more often they are simply evenly distributed. We demonstrate a holographic model that allows viewers to see real data in real space, scaled or not, and to visualize where measurements are taken, what those values are indicating, and where there exists more unknown and more risk. The holographic model shows in an intuitive way, values from Standard Penetration and Cone Penetration tests, and surface geophysics. The mixed reality of this future is that a wide audience – owners, designers, project managers, contractors, and stakeholders interact together in a real space where they see and talk to each other, while at the same time are individually looking all around below or above ground, like a gopher, in a virtual one. Risk in the future will be better managed through more thoughtfully designed investigations and better communication of 3D data in a world of augmented reality. INTRODUCTION This paper explores the use of augmented reality to convey understanding of the subsurface conditions of a bridge site. This is in contrast with the current state of practice where this information is contained in a geotechnical report, and the ideas are also applicable to other structures, earthworks, and excavations. “Augmented reality” describes a situation where a 3D holographic model is displayed for users in such a way that the users experience both the model and the real environment of their setting- such as at a desk, in a meeting room, or in an open space at a project site (Figure 1). The 3D holographic model is used to directly visualize underground features, to see through the earth to the actual locations where explorations are made, samples are obtained, or measurements are taken, design values are assigned, or construction is planned. An immersive model provides the following three powerful functions for users:

Jan 1, 2019

By S. B. Christy

The practice of the cyanide-process of gold-extraction has brought to light many important contradictions of familiar chemical analogies, which still obscure both the theory and the practice of the art with distinctions subtler and more difficult to make or follow than those which delighted the heart of the old-time metaphysician. Yet Nature herself has drawn these distinctions; and if we hope to succeed in this modern search for the Golden Fleece, we must be able to follow her through the winding labyrinth. There are so many phases of this question that I shall attempt to touch on only one of them at this time, but it is one that lies at the root of many others. In reviewing my paper on " The Solution and Precipitation of Cyanide of Gold,"* Mr. E. B. Wilson contends† that" in the solution of gold by means of alkaline cyanides the various reactions are determined, as to their order and intensity, by the relative position of the elements concerned in the electro-chemical series, or series of voltaic tension." In a modified form this statement is probably true. That is to say, the difference of electrical potential in any closed electrical circuit determines the nature of the reactions which ensue. But the matter is not so simple as Mr. Wilson assumes. Recent investigations show that the order of the metals in the electro-chemical series depends not only on the nature of the elements themselves, but also on the chemical composition of the solution in which they are placed; its degree of concentration; its temperature; and, in the case of gases, on the pressure. Unless all these conditions are taken into account, inferences drawn from the electro-chemical series are likely to prove more

Jan 1, 1901

The outlook for suppliers of energy to the expanding economies of the Pacific Basin region is essentially positive, but particularly for exporters of high quality steam coal. This paper argues that economic growth in the Pacific Basin region has exceeded world economic growth for some years and that this will continue to be the case for the next decade at least. It looks briefly at the link between economic growth and energy demand and at the relationship between energy demand and the demand for electricity.Changing preferences in fuel mix for electrical generation in the region are noted and tentative forecasts made about variations in this mix. The pros and cons of various forms of fuel used to generate electricity are considered from the point of view of the consumer.

Jan 1, 1990

By G. Portillo

Electrospark Deposition (ESD) is a pulsed-arc micro-welding process characterized by using high current electrical pulses, of a short duration, to deposit an electrode material on a metallic substrate. The short duration of the electrical pulse allows for a low heat input over the substrate and an extremely rapid solidification of the deposited material. As a result, the ESD is capable of a wide variety of microstructures like micro-segregationfree solid solutions, nanostructured grains, metastable structures, and amorphous phases. The present work shows a microstructural analysis of rapidly solidified Al-Ni alloys coatings by the ESD process. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD) were performed to present the microstructural evolution as a function of the welding parameters. The phases and non-equilibrium metastable structures present in the alloys, and their distribution, were found to be a sensitive function of the alloy composition; hence its formation is governed primarily by thermodynamic considerations.

Jan 1, 2011

By Arthur C. Spencer

HAVING suggested magmatic waters as the probable agents of vein- and ore-deposition in southeastern Alaska in a paper entitled, The Geology of the Treadwell Ore-Deposits,1 it is with particular interest that I note W. Lindgren's application of the hypothesis of igneous emanations to the gold-quartz veins of Victoria and of California.2 Mr. Lindgren says: "In the above paragraphs I have repeatedly called attention to remarkable similarities in vein-filling and metasomatic action between the Victorian quartz veins and those of Sierra Nevada. Another striking similarity is that in both of these regions the veins were formed just after the intrusions of vast masses of granite or dioritic magma into crumpled and compressed sediments. I am convinced that these similarities are due to closely similar modes of formation. With some confidence, I would formulate the hypothesis that the gold and the quartz in this type of veins have been deposited chiefly by `eruptive after-effects;' in other words, chiefly by hot ascending waters originally contained in the granitic magma and released from it by decreasing pressure, due to its eruption into the upper parts of the lithosphere. It is quite possible that atmospheric waters may have played a certain part by aiding the precipitation and by effecting certain forms of concentration in the deposits." There are many reasons for extending this hypothesis to southeastern Alaska. This region and the Sierra Nevada belt of California are undoubtedly parts of one geologic province, throughout which the main events of geologic time are evidenced by identical or closely similar records in the rocks. Our knowledge of the former region is still fragmentary, to be sure, but the origin-dates of the most prominent features of

Jan 1, 1913

By R. P. Marshall, L. P. Costas

The solid solubility of lithium in aluminum was determined by two independent techniques, electrical resistivity and microhardness, and the results are in close agreement. The solubility limits X-ray diffraction studies of the intermetallic compound LiAl indicate that its composition is nearly independent of temperature when in equilibrium with the terminal solid solution of aluminum. THE investigation of the aluminum-rich portion of the aluminum-lithium system at the Savannah River Laboratory was prompted by the observation that over-aged alloys consistently differed from the equilibrium states predicted by the latest published diagrams. Chemical analyses of these alloys showed their impurity contents to be quite low; therefore, the results obtained should have very nearly coincided with true equilibrium. A survey of the literature disclosed that previous studies had been made with metallographicig or electrical resistivity methods,4'5 but that agreement between results and technique was poor as evidenced in Fig. 1, which also includes the present results for comparison. The discrepancies have been attributed to impurities,3 and this is undoubtedly true in the early work.1'4'5 The latest Studies,''~ conducted with starting materials of higher purity, employed metallographic analysis, a technique that is quite sensitive to local homogeneity and depends strongly on subjective interpretation. In the present work the problem of defining solubility limits was approached in two ways. The first measured a physical property, electrical resistivity, at the equilibrium temperature. The second, a micro-hardness characterization of a diffusion zone, is a room temperature evaluation of a mechanical property under conditions removed from equilibrium. A close correlation between two such basically different approaches would strongly justify confidence in the results. I) MEASUREMENT OF SOLUBILITY OF LITHIUM IN ALUMINUM BY ELECTRICAL RESISTIVITY Experimental Procedure. Alloys for electrical resistivity measurements were made by melting and

Jan 1, 1962