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By J Garritsen, P F. Wells, M Xu

IncoÆs Clarabelle mill currently processes ores from eight mines in the Sudbury basin area in Ontario, Canada. The ore from the Garson mine contains a much higher concentration of arsenic than the other ores. Adding this ore into the feed to the mill has resulted in an increase in arsenic content of the Cu-Ni bulk concentrate to a level that significantly affects the smelter operation, and more importantly the efficiency of Cu-Ni separation in the Matte separation plant. The arsenic occurs mainly as gersdorffite (NiAsS), with a small amount being in the form of cobaltite (CoAsS). Extensive laboratory tests on depressing arsenic in Garson ore flotation have been conducted and two reagent suites have been identified as effective arsenic depressants. One is the so called MAA depressant which is a mixture of magnesium chloride, ammonium chloride, and ammonium hydroxide. This reagent combination was reported to depress other arsenide minerals such as arsenopyrite (FeAsS) and enargite (Cu3AsS4). However, in this study for the first time it has been shown to have a depressing effect on gersdorffite. The other reagent suite, a mixture of triethylenetetramine (TETA) and sodium sulfite, that has been reported as an effective pyrrhotite (Fe1-xS) depressant in pentlandite ((NiFe)9S8) flotation, has not been reported as gersdorffite depressant before. The effectiveness of both reagent suites is more pronounced when the arsenic minerals are oxidised through pulp aeration or the addition of hydrogen peroxide. With a flow sheet consisting of a magnetic separation, rougher- scavenger flotation, followed by regrinding and cleaning of combined magnetic and scavenger concentrate, the arsenic recovery to the final Cu-Ni bulk concentrate was reduced from 73 per cent in baseline test to less than 30 per cent with either reagent suite at no decrease in nickel recovery. The TETA/sulfite reagent combination has the advantage over the MAA suite in that pyrrhotite is also depressed, rather than being activated, and the copper and nickel concentrate grades are therefore increased.

Jan 1, 2005

By P. J. D. Lloyd

INTRODUCTION The mining of gold commenced on the Witwatersrand in 1884, and reached a mature state by about 1910, when nearly 20 million metric tons were mined. Mining has continued on the central Witwatersrand, the area of the first mining, at a similar rate until recent years. As a result, well over 1 billion tons of gold mining wastes have been dumped along a line over 80 km long, centred on Johannesburg and stretching from Randfontein in the west to Nigel in the east. (see Figure 1). The population of this conurbation, which straddles the line of mining, has grown to about 5 million. In 1922 uranium was first discovered as a constituent of the ore (and thus of the wastes). Investigations in the 1940's revealed that values near Johannesburg were low, but that, at the western and eastern ends of the central Witwatersrand line, and in the new areas centred on the towns of Carletonville, Klerksdorp and Welkom up to 200 km from Johannesburg, values were adequate to permit uranium recovery. Commercial production commenced in 1952, and by 1979 over 100 000 tons of uranium oxide had been produced. There thus arises on the central Witwatersrand nearly 1,3 billion tons of slimes containing an average of about 0,005% uranium and about 1,8% FeS2. The material grading is about 70%-75µm, and the primary mineral is silica (over 85%). The material is contained in dams constructed hydraulically. A typical dam has an area of about 100 hectares and there are over 6000 ha under slimes dams in the area of concern. The treatment of these dams for uranium recovery commenced in 1977. The situation has thus arisen whereby potential uranium ores have unwittingly been dumped in significant quantities within a major metropolis over a period of nearly a century. The purpose of this note is to review the experience arising from the potential hazard over a considerable time.

Jan 1, 1980

By Mario Santillán

El objetivo del texto es señalar el aprovechamiento de zonas mineralizadas, cuya explotación por métodos convencionales no tuvo resultados económicos, sino solo a través de un sistema racionalizado de minería sin rieles. En este sentido, la explotación de los block mineralizados se realiza a un nivel mínimo de producción de 150 a 160 T.C.S diarias, donde las rampas de acceso para la explotación de otras vetas se constituyen en una forma integral de explotación. Asimismo se considera el planeamiento operacional a corto, medio y largo plazo, se evalúan las condiciones operacionales, la explotación, método de minado, cargui, extracción, sostenimiento, relleno, las necesidades de personal y selección de equipos y los costos de producción e inversión.

Nov 20, 1978

By M. Hakan Morcali, Onuralp Yücel, Haldun Gürcan, Serdar Aktas, Semih Özbey, Alper Keskin

"This work presents a method for the precipitation of cobalt sulfate by alcohols, specifically ethanol and methanol. The effect of the initial concentration of cobalt, the volumetric ratio of alcohol to cobalt sulfate solution, the addition of sulfuric acid and ammonia, and the effects of common ions on the precipitation percentage were investigated. The performances of ethanol and methanol were compared in terms of the precipitation percentage of cobalt sulfate, and explanations for different performances are offered. In the sulfate-based solution, the alcohol was shown to displace water ligands from the first coordination sphere of the cobalt(II) cations, which led to the precipitation of the cobalt ions as cobalt sulfate heptahydrate. SEM analysis revealed that the particle sizes of the powders produced by this method are smaller than those of commercially available cobalt sulfate. The scientific literature contains no data on the solubility of cobalt sulfate in ethanol. In this study, the solubility product constant (Ksp) for cobalt sulfate was experimentally calculated to be approximately 1.15 x 10-5.IntroductionCobalt sulfate, which is one of the most important compounds of cobalt, is used in the electroplating and electrochemical industries. The addition of cobalt sulfate to nickel-plating baths makes the treated metals brighter, harder, smoother and more ductile (Armstrong et al., 1988). It is also used as a desiccant for lithographic inks, varnishes, paints and linoleum, as well as in storage batteries, e.g., nickel-cadmium (Ni-Cd) and lithium-ion (Li-ion) rechargeable batteries (Kang et al., 2010). Cobalt sulfate is employed as a coloring agent in ceramics, enamels and glazes to prevent discoloration and as a copigment for the decoration of porcelain. In addition, cobalt sulfate has been used in animal feeds as a mineral supplement (Budavari et al., 1996; Kirk and Othmer, 1999).In the past, brewers used cobalt sulfate to prolong the life of beer foam (Kesteloot et al., 1968). Ranchers have dosed livestock with cobalt sulfate or used fertilizer enriched with this mineral to ensure that their animals obtained sufficient amounts of the trace mineral, which is essential to the production of vitamin B12. Cobalt sulfate has also been used in veterinary medication to prevent and treat cobalt deficiency in ruminants, which causes a reduction in feed intake and body weight, accompanied by emaciation, anemia and debility.Cobalt sulfate is a water-soluble bivalent cobalt salt. Cobalt sulfate heptahydrate dehydrates entirely at 420° C, and the dehydrated salt forms red monoclinic crystals."

Jan 1, 2015

By Andrew M. Leszcykowski

A 1981 U.S. Bureau of Mines investigation indicates the Panamint Dunes Wilderness Study Area (WSA) has one active (intermittent) mine,--borrow pit MS 242 owned by the California Department of Transportation (Cal Trans). This mine produces cinders for road base and traction grit. It contains about 900,000 tons of inferred reserves. Examination and sample analyses indicate the Panamint Dunes deposit, covering about 480 acres of the WSA, may have silica resources and the Green Quartz Claim may have copper resources. Carbonate rocks occur in the WSA, but stone resources have not been identified. Adjacent to the WSA, the Big Four Mine contains 35,000 tons of inferred subeconomic zinc-lead-silver resources, and may have additional resources. Sample analyses indicate the Apple 1 Claim, also adjacent to the WSA, may have silver-lead-zinc resources.

Jan 1, 1985

By Gerald R. Coonan

Early in the open session of the 1979 SEE Fifth Conference panel discussion, someone asked a question of the panel concerning the future intent of the Office of Surface Mining and the regulatory limits established for ground vibration and air blast. The "gist" of the question was: "What assurances do we have that OSM will not promulgate a limit of 0.5 inch per second ground vibration, or some other number within the next two years or so."

Jan 1, 1979

By Thales Renó Grilo

O presente trabalho teve como objetivo analisar as diferentes microestruturas do aço inoxidável duplex UNS S32304 obtidas pelo processo de soldagem Gas Metal Arc Welding (GMAW). As regiões do metal base, zona fundida e zona afetada pelo calor foram investigadas nos corpos de prova com diferentes aportes térmicos. As microestruturas obtidas foram caracterizadas utilizando-se a microscopia óptica (MO). As imagens de Mo obtidas na zona afetada pelo calor mostram que a fração de austenita aumentou com o aumento do aporte térmico. Este aumento está relacionado ao alto teor de cromo e molibdênio presentes no metal de adição utilizado na soldagem. Na zona fundida, a fração de austenita de widmansttaten foi observada com maior frequência na microestrutura do corpo de prova soldado com o aporte térmico de 1,87KJ/mm. Essa maior fração de austenita de widmansttaten observada para o aporte térmico de 1,87KJ/mm está relacionada com o maior tempo de permanência em altas temperaturas deste corpo de prova em relação aos outros corpos de prova investigados. Vale ressaltar que a adição de nitrogênio também promove a formação desta fase. De modo geral, os resultados da metalografia quantitativa mostram que a porcentagem de ferrita foi superior a 65% nas zonas termicamente afetadas e fundidas.

Aug 17, 2017

By Gligorije Stankovic

This paper describes the fluo-solids roaster and acid plants at the new 40,000-TPY Trepca electrolytic zinc plant. The electrolytic zinc plant units were constructed to the design of Singmaster and Breyer, New York and began operation in mid-1967. The fluo-solids roaster plant, constructed according to the design of Dorr-Oliver, Paris, includes concentrate handling and storage facilities; two independent concentrate roasting circuits, each with a 110 to 155 TPD fluo-solids roaster; waste heat boilers; cyclones; electrostatic precipitators; calcine coolers; and calcine conveyors. The acid plant uses the "Petersen system" contact process. The plant has one acid circuit with a capacity of 230 tons of monohydrate per day. Gases for the acid plant are obtained from roasting zinc concentrates. When the roaster plant is operating at maximum capacity, excess SO2 is used in two other Petersen System circuits in the near vicinity.

Jan 1, 1970

By David H. Browne

Nickel has always been a fruitful mother of problems. Previous to the year 1906 nickel was regarded as an element replacing iron in copper-mattes, and it was believed that the same laws which governed the elimination of iron could be applied to nickel. This conception has lately undergone a complete change, and nickel in all its stages is now regarded as an element replacing copper; in other words, copper-nickel is considered not as two elements, but as one metal. When we commenced our investigations on Monel metal we made a great many experiment* on the conversion of mattes, both high copper and high nickel. We studied closely the composition of the mattes and the changes produced by the blow. We found in all cases certain agreements which me believe are due to some law. Briefly stated, our conclusions are as follows : 1. Nickel is not an element replacing iron in matte. 2. Nickel-copper alloys act in the matte-blow like one metal. 3. Nickel-copper alloys follow, during the matte-blow, exactly the same laws that govern the behavior of copper alone. This brings up the question: What are the laws governing the production of metallic copper, and what are the relations of copper to sulphur and iron during the Bessemer blow?

Jan 1, 1911

By Roy H. Grau

The trend in underground room-and-pillar cod mining is to employ remote-control continuous mining machines to take extended cuts of 40 A or more. Roof fall safety hazards to the mine worker associated with 4ed cutting are not completely de6ned but are known to include removal of the miner operator from the protective canopy, non-compliance with approved cutting depth and CM operator positioning. This report summarizes ground control research performed by the National Institute for Occupational Safety and Health (?-JIOSH) researchers at the Pittsburgh Research Laboratory concerning extended cuts. A combination of statistical analysis and underground investigations have been conducted. Statistical analysis of extended cut use, along with roof fall accidents and fatalities data delineate the extent of the problem in U.S. coal mines. Additionally, an underground study is described where the long-term roof stability of extended cut areas are compared to standard cuts.

Jan 1, 1997

By R. A. Corley, W. R. Wilcox, J. R. Teviotdale

Chemical vapor deposition of hafnium carbide yielded whiskers, needles, dendrites, faceted crystals, and adherent coatings. The gas stream compositiom and the mass transfer conditions determined the habit of the deposit. The deposits were obtained at temperatures ranging from 1100" to 1800°C. HAFNIUM carbide has the highest melting point of any binary compound; therefore, its various potential applications are a subject of vital interest to the aerospace industry. The experiments described herein were performed to investigate the chemical vapor deposition of hafnium carbide with particular interest being placed upon the possible production of high-strength single-crystal whiskers for composite materials. In 1931 Moers 1 used a gaseous mixture of HfC14, Hz, and toluene to vapor deposit crystalline hafnium carbide on a tungsten filament heated to 2400°to 2800°C. More recently Lepie 2 deposited hafnium carbide on graphite using HfC14 and methane in a helium gas carrier. The pyrolytic depositions described here were accomplished in graphite tubes by using various gas mixtures and dopants. The resulting crystal habits included whiskers, needles, needle dendrites, bulbous dendrites, faceted crystals, and smooth, adherent poly-crystalline layers. EXPERIMENTAL The depositions were carried out in an induction-heated graphite tube, 1.2 cm ID, which was contained in a vertical 9-cm-ID quartz tube. (A more detailed account of the experimental procedures and results is given in Ref. 3.) Refractory oxide fiber and tubes and graphite felt were utilized jointly and singly for therma1 insulation. A typical temperature distribution is shown in Fig. 1. The reactant gases were introduced at the top and removed at the bottom of the tube. Table I summarizes the experimental conditions and results. Many deposition habits were obtained. X-ray analyses showed that they possessed the hafnium carbide structure. Almost invariably these formed well above the point of maximum temperature in the graphite tube. The habit depended strongly on the gas composition. In a series of runs (e.g., run A) using HfC14 and toluene in H 2, hafnium carbide coatings, Fig. 2, were reproducibly obtained at the position where the tube wall was 1400°C, and bulbous dendrites, Fig. 3, were

Jan 1, 1969

By H. D. Mtegha

The Southern African Development Community (SADC) aims to harmonize mineral policies and regulatory regimes in the minerals sector. This paper provides a review of the progress made towards harmonization of mineral regimes in the region. It singles out only the mining fiscal environment, as this is normally one of the key issues of interest to potential investors as well as the host state. Indications are that the region is slowly progressing towards a more harmonized approach, and there is evidence that the ?race to the bottom? has been prevented, which is the basis for an integrated mineral sector that the region aspires to.

Jan 1, 2011

Cameco Corporation is in the process of revitalizing the Key Lake mill. As part of this process, the company is considering installing the Rabbit Lake style strong acid stripping in solvent extraction. This would lead to using hydrogen peroxide for uranium precipitation. The process currently employs ammonia stripping and ammonia precipitation. As part of the process evaluation, an indirect fired drier pilot plant test was conducted. This paper will discuss the results of that test work, including the relationships between the following: ? Drying temperature and product grade ? Drying temperature and product colour ? Drying temperature and product reactivity with water ? Drying temperature and energy input requirements ? Drying temperature and shipping costs

Aug 1, 2010

By J. D. Miller Discussion by N. P. Finkelstein, M. C. Fuerstenau

The point designating 10 -4 nole/per liter sulfonate addition in Fig. 1 has been presented incorrectly. This figure, with the corrected scale, is shown at right. N. P. Finkelstein (National Institute for Metallurgy, Johannesburg, South Africa) - The qualitative conclusion the authors of this paper have reached in evaluating the influence of hydrocarbon chain length on collector effectiveness agrees with conclusions in several published reports. However, in two other

Jan 1, 1969

By J. S. Kennedy, R. G. Omeara

Beryllium is a strategic metal of ever-increasing peacetime importance because of the unusual properties of beryllium-copper alloys. These unusual characteristics are the combination of high strength and hardness, high fatigue resistance, and high wear resistance in alloys that have the corrosion resistance of copper. The principal industrial source of beryllium is the mineral beryl, a beryllium-aluminum silicate that occurs in pegmatites associated with quartz, feldspar, mica, and smaller amounts of various accessory minerals. The beryl is usually recovered in processing the pegmatites for the recovery of some of the other mineral constituents. Pegmatite deposits are found in various parts of the United States, but those in the Black Hills of South Dakota are the source of most of domestic production. The beryl marketed from the South Dakota pegmatite deposits occurs as coarse crystals, which are obtained by hand sorting. These pegmatites also contain other valuable minerals.

Jan 1, 1948

By A. M. Tweedy, Felix A. Vogel

Since the publication of Prof. J. W. Richards's paper on The Schumacher Briquetting Process,' this process has been in operation on a practical scale in two plants in the United States, and a few notes on the results obtained may be of interest. An experimental plant, consisting of a toggle press and a hydraulic press, was installed at Johnstown, Pa., together with the necessary bins and other equipment, and an attempt was made to briquette a mixture of Mahoning fines and blast-furnace flue dust, in a ratio of 7 parts of ore to 3 parts of dust. The results were unsatisfactory, in that the briquettes made were not hard enough to stand the severe handling to which they were subjected in the various transferences necessary between the press and the furnace. The trouble was due to several causes: First, the mechanical arrangement of the plant, which did not lend itself to a proper hardening and loading of the briquettes into the cars. Second, the irrrgular composition of the flue dust, as to both its lime and its fine coke contents. Third, the variability of the moisture content of the ore, and its viscosity when wet. Fourth, the ratio of fine ore to flue dust; that is, it was attempted to bind in too large a quantity of fine ore for the small amount of flue dust used. The first trouble could be overcome, and has been improved upon in the plant as it stands to-day. The second trouble was important, because of the small amount of dust used as a binder, and might have been easily removed by mixing the flue dust of the different furnaces, which, however, was never done. The third difficulty was more serious, but could have been partly solved, had it been possible to meet this along with the fourth difficulty, by decreasing the percentage of ore in the briquettes. It was proposed to do this, but it seems that the problem at the works in question is, primarily, to prepare Mahoning fines for reduction in the blast furnace, and only secondarily to use up the flue dust, and a solution along this line did not seem to be interesting.

Jan 1, 1914

By Shreyas Giridharan, Fursan Hamad, Sujith Gowda, Christian Moormann

"Pile installation in soil is a dynamic process which exhibits large deformation in the soil region. Experimental investigation of pile installation is both time and resource intensive. Numerical investigation can be a helpful tool for the analysis of the installation process. Furthermore, numerical analysis allows simulating various soils and loading conditions with ease. Finite Element Method (FEM) – a widely used framework for numerical simulations - fails to perform well for soil mechanics where large deformation and heavy material movement exists. In order to alleviate this shortcoming, Material Point Method (MPM), advancement to FEM has been used. In MPM, material points (particles) are used to represent the domain which carry the information and move over a fixed computational mesh where the governing equations are solved.In the present work, a variation of MPM, called CPDI (Convected Particle Domain Interpolation) is utilised which handles large deformation problems better than the classical MPM. Here, the material points are represented by a spatial domain which deforms according to the particle deformation. This eliminates stress oscillations while particles cross the grids. Implementation is validated and applied to pile installation in dry and saturated soil conditions. A 2D axisymmetric model is chosen, with penalty function method being used for evaluating contact between soil and pile. Sand is modelled via the hypoplastic constitutive description that takes into account large deformation, as well as small strain stiffness. From these simulations, various parameters like stress, void ratio and friction angle are studied.INTRODUCTIONOffshore piling is challenging in terms of testing and execution. Before the execution, predicting an efficient installation method requires study of various parameters, like soil conditions, type of loading, force requirement etc., and are the minimum parameters to be known beforehand. To obtain these parameters, testing a real scale prototype under different conditions is not feasible. Scaled model tests in lab can support in making certain decisions, but fail to replicate real behavior fully. Therefore, the need for a numerical simulation technique emerges, which can provide early predictions easily and accurately. This later can be extended to real scale tests, reducing the number of experimental investigation required.Simulation of displacement pile installation in sand involves large deformation due to penetration process, thereby making the application of FEM impossible, where large deformation causes heavy mesh distortions. Due to this, meshless methods are developed to treat large deformation in a better way. Among various meshless methods, Material Point Method (MPM) shows more applicability to geomechanical problems. This is mainly due to the ease of handling soil, structure and water in a unified manner."

Jan 1, 2017

By M. G. Hester, G. S. Adisoma

To address the problem of grade estimation in a general three-dimensional shape and the uncertainty associated with the estimate, the technique of jackknifing/ block-kriging shortcut is proposed. A new estimator called jackknife kriging is introduced first. Through the jackknife variance, a confidence limit for the reserve-grade estimate can be calculated. Unlike the kriging variance, which is more a measure of data configuration and which is independent of data values, the jackknife variance reflects the true variability of the data. This approach provides a simple way to set a confidence level for global estimation of resources.

Jan 1, 1997

By Laird CH

Large quantities of brown coal are excava ted from open cut mines in the Latrobe Valley to fire the base load thermal power stations of the Victorian Electricity System. Most of the coal is removed using bucketwheel excavators which have been modified or specially designed for the conditions encountered. The actual digging efficiency of the bucketwheel excavator is strongly influenced by such factors as wheel speed, slewing speed and tooth design and arrangement. The coal deposit, although not difficult to work, is not uniform and the operation of the machine is influenced by the stability re- quirements of the excavation face.

Jan 1, 1978

By C. L. Emery, A. V. Corlett

"The stress equilibrium is disturbed in a body of rock by a mine opening and is restored by a redistribution of the stresses around the opening. The pattern of the redistribution of unilateral stress around an opening has been established by mathematical analysis and photoelastic measurements. The pattern for multilateral stress is found by superimposition of unilateral fields. The mathematical analysts do not use the elastic moduli as parameters and they are not significant in photoelastic work. The medium is isotropic. The concept of unilateral stress from vertical loading and the classical pattern of its stress distribution around openings does not explain commonly observed failures around the perimeters of mine openings. They show evidence of compression where tension is postulated.When it is recognized that few minerals and perhaps no rocks are Hooke Solids, most rocks must be St. Venant Solids. The components have varying degrees of elasticity and viscosity. The assembly will be-have elastically to rupture under shock loading, but when loaded short of rupture will adjust viscously to equilibrium. Similarly, the highly elastic components may initiate rupture before equilibrium can be established when stress is instantaneously relieved. Polycrystalline adjustments may produce permanent deformation. The mechanics of consolidation, especially in sedimentary deposits, ac-quire a stress component normal to the direction of compaction which can exceed that of the loading. It is one source of prestress. There are others. The principles of prestress design are based on the normal beam reactions, modified by a built-in compression in the lower chord. When the beam is loaded to design limits, the lower chord retains some compression and the whole beam depth is effective in compression. Some of the . common evidences of failure in compression over a mine opening can be duplicated in a prestressed experimental model.When the triaxial stress pattern is recognized and suitable measuring techniques are devised, mine design can be done on a rational basis."

Jan 1, 1959