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By Pekka Taskine

In the Kokkola zinc smelter, as in most other zinc roasting plants, there is now a trend towards using concentrates with an increasing impurity content. This also often means that the size distribution of the concentrates gets finer. Iron is present in sulfidic zinc concentrates with the highest percentage as a single impurity. The behavior of iron in zinc roasting was studied in laboratory experiments. Commercial zinc concentrates with a low and high (1.5 - 16 wt-%) iron content as pyrite or in the sphalerite lattice were oxidized to various degrees to establish the reaction mechanisms of iron in roasting. Microscopy studies were carried out on the calcine, and the findings were presented in numerous photographs of the polished cross sections. SEM/EDS techniques were used for analyzing the phases and particle morphologies present in the samples. An oxidation mechanism of zinc concentrates with a high iron content was suggested.

Jan 1, 2002

By A. K. Mahto, B. Samanta

"A heuristic model was developed to simultaneously generate the ultimate pit and production scheduling at a mining project. The method consists of a preprocessing step to select a starter pit, the implementation of a genetic algorithm to optimize the pit and schedule of the starter pit, and a network-flow algorithm–based postprocessing operation to finalize the ultimate pit and production scheduling. Applied to an iron ore mine, the model pit and schedule produced a net present value 21% higher than the reference pit and schedule prepared by experienced field engineers.RÉSUMÉ Un modele heuristique a ete developpe pour generer simultanement l’ordonnancement de la fosse finale et de la production dans le cadre d’un projet minier. Cette methode comprend une etape de pretraitement visant a selectionner une premiere fosse, la mise en oeuvre d’un algorithme genetique pour optimiser la fosse et le calendrier d’execution de cette premiere fosse, ainsi qu’une operation de posttraitement basee sur des algorithmes de flux reseaux pour finaliser l’ordonnancement de la fosse finale et de la production. En l’appliquant a une exploitation de minerai de fer, ce modele de fosse et d’ordonnancement a genere une valeur actualisee nette (VAN) superieure de 21 % a l’approche de reference pour la fosse et l’ordonnancement developpee par des ingenieurs de chantier chevronnes. INTRODUCTIONLong-term planning for an open-pit mine involves two important activities: developing the ultimate pit and determining the optimum production schedule. To accomplish this, an ore deposit is discretized into a number of smallsized elements called blocks, which are presented in a 3D block model structure. Because of economic and slope criteria, only a certain set of mining blocks can be extracted from the deposit constituting a pit. During mining, these blocks must be extracted in a specific sequence known as the production schedule."

Jan 1, 2017

By H. F. Ramstad, F. D. Richardson

The equilibria (a) SiOz +Hz =SiO +H20 and (b) Si + SiO, = 2Si0 have beet1 studied at temperatures of 1425"to 1600°C ad 1310°to 1485°C respectively. The stattdard free energy changes for the tzrro reactions are given by the equatiotts Combination of the results for both equilibria leads to tiotz removes certain anomalies in existing high-terlzperature data for equilibria involving silica and silicon in iron. In many metallurgical processes and in many laboratory investigations silicon monoxide undoubtedly plays an important role. It is unfortunate therefore that wide differences exist between the results obtained by different investigators1-7 in their studies of such equilibria as In an attempt to put our knowledge of SiO on a surer basis, an exhaustive study has been made of equilibria [I] and [2] at temperatures ranging from 1300" to 1600°C. Reaction [I] was studied by measuring the amounts of silica which could be condensed from streams of Hz or Hz + HzO which had previously been brought into equilibrium with silica at temperatures ranging from 1425" to 1600°C. Reaction [2] was studied by measuring the material that could be condensed from streams of Hz or argon which had been brought into equilibrium with mixtures of silicon and silica at temperatures ranging from 1310" to 1485°C. EXPERIMENTAL Materials. The silicon was "superpure" grade and contained less than 0.1 pct impurities. The silica was prepared from pure mineral quartz; this was crushed and treated with concentrated hydrochloric acid to remove particles of iron, washed with water, and finally dried at 120°C. For the hydrogen + silica reaction, the silica was sized to —20+100 mesh. For the silicon + silica reaction, the two materials were ground to a fine powder in an agate mortar. The hydrogen and argon were commercial oxygen-free gases. The gas streams were controlled with capillary flow meters and the volumes were measured by wet gas meters. After passing through the meters, the gases were partially dried by silica gel. The hydrogen for the HZ + SiOz reaction was then passed through palladised asbestos at 300°C and dried with magnesium perchlorate. The efficiency of oxygen removal was checked throughout the experiments by passing the gas over an electrically heated strip of nichrome, used as an indicator as described by Rathman and de itt.' When mixtures of HZ + Hz0 were required, the partial pressures of water vapor (1.8 to 22 mm) were obtained by passing the hydrogen through oxalic acid dihydrateg' lo held at various controlled temperatures, O.l°C, by means of a water bath. The hydrogen for the Si + Si02 reaction was purified by passing it over a mixture of 3 parts of magnesium to 5 of lime heated to 600°."l1 u The argon for this reaction was passed through titanium powder (-3/16 in. + 100 mesh) heated to 900°C. The nitrogen used to prevent the reaction products escaping from the condenser (see later), was deoxidized by copper or iron at 600°C. All these gases were finally dried with magnesium perchlorate. Furnace, Temperature Contr01, and Measurement A molybdenum resistance furnace was used for both sets of experiments. The reactions were conducted inside a high-grade alumina tube, 36 in. long and 1 in. in diam as indicated in Fig. 1. With this arrangement an even temperature zone (2"C) 4 cm long was satisfactorily obtained. The temperatures were kept constant by means of a proportional controller actuated by a Pt-Pt 13 pct Rh thermocouple. This was placed between the two alumina tubes, so that the temperature at the junction was 1400" to 1450°C. Up to 1485"C, the temperatures were measured with Pt-Pt 13 pct Rh thermocouples. For higher temperatures an optical pyrometer was used, this being sighted (through the glass window 1 in Fig. 1) on the end of the alumina tube, that held the SiOz or Si +SiOz mixture, 10 in Fig. 1. The optical pyrometer was recalibrated whenever a change was made in any part of the apparatus situated in the hot zone. Successive readings with the optical pyrometer were reproducible to within 1"C. Equilibrium Apparatus and Procedure. Hydvogen and Silica Reaction. The apparatus is shown in Fig.

Jan 1, 1962

By G. Shen, W. R. Tyson

In most fracture toughness test standards, such as ASTM E 1290 and BS 7448, crack-tip opening displacement (CTOD) is measured by using three-point bend (SE(B)) or compact (C(T)) samples with deep cracks. The loading mode and crack depth in these tests sometimes are different from that of pipelines. Pipelines usually have shallow defects and experience tensile loading when the supporting ground moves. As a result, the CTOD measured by these samples is lower than that of pipeline in tension. Recent researches suggest using single-edge-notch tension (SE(T)) samples to measure fracture toughness for pipelines. In the present study, shallow and deep SE(T) samples under fixed grip loading were analyzed by using the finite element technique. An equation to relate the CTOD to the area of the load/plastic crack mouth opening displacement (CMOD) is proposed. With this equation, the CTOD of a SE(T) sample can be evaluated by measuring the area under the load/plastic CMOD curve of a SE(T) sample.

Jan 1, 2005

By Sivell W

We discuss the origin of the Patuki ophiolite complex and the Dun Mountain ultramafics of Middle Permian age in Nelson, New Zealand. It is shown that the Patuki volcanics have strong affinities with tholeiites of mid ocean spreading ridges transitional to alkaline basalts similar to those from fracture zones and ocean islands. At D'Urville Island, typically pillowed alkaline basalts enriched in rare light rare earth elements (LREE) - ophitic spilites - are associated with LREE-depleted (N-MORB-like) tholeiitic spilites with intergranular textures. The metabasalts are associated with a wide variety of sediments, and with sediments are intruded by conformable sheets of serpentinite. Coarsely crystalline mafic and plagiogranitic rocks signify vents and magma chambers, and we propose that the group developed as ocean crust from a slowly spreading mid-ocean ridge, transform association, overwhelmed at intervals by volcaniclastic sediment. Detailed mapping at a scale of 1:5000, and stratigraphic and geochemical development and structural coherence, show that the group is not melange in the Franciscan sense. The Dun Mountain Group, of serpentinites, peridotites, dunites, gabbros and other rocks, intruded the upper Patuki Group as a linear series of aligned pods and sheets. They carried up with them tectonic inclusions of older rock, which were metasomatised, and altered wall-rock, and one low angle dike passed several hundred metres into overl~ing sediment, at moderate temperatures (500 C). The rocks did not act as a floor (and alleged source) for the Patuki, but partly post-dated and were emplaced into Patuki.

Jan 1, 1987

By E. C. Lane

This paper is the second report of the results of the United States Bureau of Mines twenty-third semiannual survey of motor fuel marketed in the United States. The first paper, reporting data relating to gravity, vapor pressure, and distillation range of the samples, was published as Report of Investigations 31293. A third and concluding paper giving the results of other tests will be published as soon as these tests have been completed. The present paper deals with the data of the twenty-third semiannual survey presented in accordance with the revised specifications for United States Government motor gasoline. The sample numbers used are identical with those used in Report of Investigations 3129, with additional data included for copper strip corrosion (method 530.22).4 and sulphur content by the lamp method.5 Three hundred and twelve samples were collected and analyzed in this survey. Two hundred and seven samples were competitive-price gasolines and one hundred and five samples were premium-price motor fuels.6

Jan 1, 1931

By E. C. Lane

This paper is the second report of the results of the United States Bureau of Mines twenty-third semiannual survey of motor fuel marketed in the United States. The first paper, reporting data relating to gravity, vapor pressure, and distillation range of the samples, was published as Report of Investigations 31293. A third and concluding paper giving the results of other tests will be published as soon as these tests have been completed. The present paper deals with the data of the twenty-third semiannual survey presented in accordance with the revised specifications for United States Government motor gasoline. The sample numbers used are identical with those used in Report of Investigations 3129, with additional data included for copper strip corrosion (method 530.22),4 and sulphur content by the lamp method. Three hundred and twelve samples were collected and analyzed in this survey. Two hundred and seven samples were competitive-price gasolines and one hundred and five samples were premium-price motor fuels.

Jan 1, 1931

By Sastry Putcha, Santosh Mummaneni, Avasarala Swamy

"Inspection of bored pile hole bottom prior to placement of concrete is one of the most crucial element of foundation design and construction, especially for end bearing piles. Pile hole bottoms that are not cleaned well for sediments could potentially result in settlement. Although many projects have specifications in-place for drilled pile hole inspection, they are rarely implemented as the current available tools are either unsafe or cumbersome and costly, thus making it very unattractive for owners and contractors. Further, sometimes the post-construction nondestructive quality control testing such as PIT or sonic logging on piles resulted in unanswered questions related to soft bottom. This generates costly disputes with additional testing including concrete coring and possible repairs. Currently, there are several bored pile bottom inspection devices in USA, namely, SID, DID, and SQUID which can either provide video and photo documentation or measure sediments.“ShaftCam”, a patented advanced Digital Borescope, was invented to address the issues related to pile hole bottom inspection with its ability to measure sediments as well as photo and video documentation. Shaftcam device consists of 8-inch diameter bell with a camera, led lights, air hose connection and penetrometer with digital measurement that are connected to a control power box and laptop through a cable. The bell is fitted with a round clear open fiberglass skirt to form an open chamber. A simple motorized winch frame allows the user to lower the ShaftCam equipment gently to the bottom of the shaft at the desired location. Once the bell with camera is lowered to the bottom of the hole, air is pumped into the clear chamber to displace the water/slurry/polymer and get a clear view of the hole bottom to record the conditions and measure the sediment thickness and resistance. The skirt can also be enclosed and lowered to the desired location to allow for inspection of shaft walls.ShaftCam weighs less than 15 lbs. (6.8 kgs) in water and allows for inspection of the hole by one person in less than 30 minutes. Use of ShaftCam has saved significant time and money and thus allowed owners and contractors to readily accept and implement the quality control measures in many projects in USA over past few years."

Jan 1, 1900

By V. N. Mackiw, D. E. Weir, D. J. I. Evans

The world's largest reserves of nickel are found in lateritic ores. Commercial exploitation has been carried out for almost one hundred years; however, none of the plants currently in operation produce pure nickel but rather ferronickel, matte, impure nickel oxide or mixed sulphide precipitate. Over the past decade Sherritt has studied various processes, including the modified reduction roast-ammonia-ammonium carbonate leach process, for the production of pure nickel powder and briquettes from laterites. Nickel can be reduced to the pure elemental form at elevated temperatures and pressures from impure basic nickel carbonate slurries. Several methods were studied in the development of the process for working up the pregnant leach liquor and basic nickel carbonate to produce feed for the aqueous hydrogen reduction step in which pure nickel powder is produced. This paper is concerned only with the laboratory studies using the basic nickel carbonate slurry reduction procedures.

Jan 1, 1973

By Hennessy F. L

It is generally recognised that slags are active participants in pyrometallurgical processes, and not merely inert liquids which must be produced. to effect separation of gangue material in smelting, or of impurities in refining. The importance attached to slag-metal reactions in steelmaking is shown by the numerous investigations in this field. However, there are still many important reactions of slags which require explanation. In this paper some new aspects of the reactions of slags will be discussed, as far as possible quantitatively.FREE AND COMBINED OXIDESMetallurgical experience indicates that variations in the composition of slags produce changes in the chemical behaviour of the various components. These variations have been generally ascribed to changes in the proportions of free and combined oxides, i.e., compounds have been assumed to be present in the liquid slag.Considerable support for this view has been adduced from the existence of compounds such as metallic silicates, phosphates, etc., in the solIdified slag. However, this does not imply that such compounds necessarily exist in the molten slag.The most direct evidence as to the nature of molten slag is to be obtained from a study of the liquid state. In...

Jan 1, 1950

By R F. G Phelps, C J. S Sangster, G S. C

Narrow vein metalliferous mining in the UK has a long history, but there are only two small gold operations at present (Clogau and Gwynfynydd). Four further gold properties are at various stages of evaluation (Calliachar, Cononish, Curraghinalt and Maestryfer). The South Crofty tin mine closed earlier in the year. Narrow veins are exploited underground and are challenging to evaluate because of their geologically variable nature. They are generally less than 3 m wide, discordant, of variable dip (

Jan 1, 1998

By T. I. Kunkel

The economic prosperity of many Canadian communities depends on resource extraction within the traditional territories of Indigenous people. The geographic sites where these resources are situated are also areas where these Indigenous people have sustained themselves for millennia through hunting, fishing, trapping, and gathering activities. These traditional activities provide not only sustenance, but also cultural and spiritual values, and the ability to transmit oral Indigenous cultures and customs from generation to generation. The multimillion dollar revenue mine project proposed within the Cariboo Chilcotin region of British Columbia is situated geographically in a location which has sustained the Tsilhqot?in people for millennia. However, this group of people have important social and cultural values nested within the traditional activities at this location. These values are typically not at the forefront of resource development. Using Indigenous research and grounded theory, this research paper briefly outlines Aboriginal values of the First Nations communities within the Cariboo Chilcotin region and some lessons learned from the Tsilhqot?in people during the environmental assessment of the mine proposal.

Aug 1, 2013

By R. G. Treuting, W. C. Ellis

The twinned state is characterized by a lattice of coincidence sites. Imperfections are required at stable lateral twin interfaces. Twinned regions can occur with relative ease in the diamond cubic IN recent contributions1,2 on the origin and growth of cubic annealing twins, attention has been directed to the orientation relations between such twinned components and their parent matrix. There are some aspects of twinning which may be illuminated by a more detailed consideration of the twinned state" alone. As an extreme example, the dense twinning in cast ingots of germanium,&apos; as contrasted with the rarity of twins in cast face-centered cubic metals, is yet to be accounted for. It has been this that has led us to the present work, which, it will be noted, uses methods and constructions in many respects similar to those of Kronberg and Wilson.&apos; In the cubic systems, a 70" 32&apos; rotation about a <110> axis is angularly equivalent, as to twinning, to the more usually considered 180" rotation about a <111> axis. Figs. 1 and 2 show a (110) projection of a twinned face-centered cubic lattice and a twinned diamond cubic lattice. In both figures, the two adjacent planes A and B, shown by the larger and smaller circles, are sufficient to represent the entire array. In each case a section of lattice, the original atom sites of which are shown by open circles, has been rotated as indicated through 70" 32&apos; to bring an original. [112] direction into coincidence with the [112] diiection. The latter is the intercept on the (110) projection of the (ill) plane normal thereto, the twinning plane. In the face-centered cubic case the rotation can be performed about an axis passing through an atom-site; the mirror plane then is also a composition plane containing atoms common to both twinned and untwinned lattices. The diamond cubic lattice may be construed as two interpenetrated face-centered lattices. Its (111) planes recur in a sequence of alternately short and long interspacings. Consequently a mirror plane for twinning cannot be a composition plane, but must be the bisector of one of the spacings. When the longer spacing is selected, the closest distance of approach across the mirror plane in the [ill] direc- tion is identical with that in the untwinned structure. In each case periodically recurring (ill) planes (parallel with the twinning plane) are found, on which there is coincidence of atom sites of the pre-twinned and twinned orientations; these are indicated by the cross-hatched circles. In the face-centered lattice there is such coincidence every third (ill) plane; in the diamond cubic lattice, on two adjacent planes in every six. At the twinning interface in the latter, there is on each side of the mirror plane a (ill) plane of atoms common to both twin components. Conceivably, there is little influence on a plane of atoms about to be adhered to such a pair of coincidence planes, whether it be laid down in a normal or in a twinned position with respect to the previously formed structure. Slawson% as attributed the high incidence of twinning in diamond to this boundary state. Further examination shows that the motion of intermediate planes can consist of various pairs of equal and opposite translations, for example of (ill) planes in the [l&apos;;i2) direction, the familiar twinning shear, indicated in the small schematics in the figures. Since the translations form a system of shears of alternating sign between coincidence planes, twinning could take place by such a mechanism over an extended region without extensive shear; in fact, in this case any atom moves but the distance in the [1i2] direction. One alternative construction for the face-centered cubic lattice leading to the same end result is illustrated in Fig. 3. The plane (711) with respect to the pretwinning orientation (the twinning plane of Fig. 1) is given, the twinned region arbitrarily bounded by <110> and <112> directions. The coupled shear is identical to that of Fig. 1. The "rotational" movement about coincidence sites generating the same twinned position could consist as shown of the translation a,/d% for each atom of a group of three in the B layer in a different one of the three <112> directions, and a similar translation of the underlying three atoms in the C layer in either the same or the opposite sense. This is not dissimilar to Kronberg and Wilson&apos;s construction for their 22" rotation of three adjacent (111) planes.

Jan 1, 1952

By Lei Zhang, Zhibo Ma, Pingye Guo

The mechanical behavior of hard roofs often leads to significant deformation and strong mine seismicity in gob-side entry retaining (GER) of the longwall mining, affecting the mining safety and efficiency of coal mines. Field investigations indicate that the failure process of the retained entry by hard roofs can be divided into three stages. In this paper, theoretical analysis and numerical simulations are first used to evaluate the damage process of the retained entry under the hard roof. The results show that the instability of the retained entry in the conventional GER method results from the combined static-dynamic loads (in stage II and stage III) from the hard roof. Then, an innovative method, through fracturing roofs to maintain entry (FRME), based on GER with the hard roof is introduced to solve this problem. In this method, the roof of the mining area is pre-fractured, and when the coal seam is mined, the direct hard roof will collapse along the fractured surface due to its deadweight and mining pressure. The hard roof control effect on the static and dynamic loads, taking into account the innovative method, is verified with simulations and theoretical analyses. The results are compared with those of the conventional GER method. Furthermore, based on the numerical simulation study of dynamic responses, it is found that compared to the GER method, the dynamic response of the retained entry using the innovative method is more moderate and more conducive to the stability of the entry. Field application also validated the effectiveness of the innovative method to control the mechanical behavior of the “massive sudden collapse” of the hard roof.

Aug 14, 2023

By K. Whysner

The recycling of metal resources in mining influenced water (MIW) requires a paradigm shift from within the mine water treatment industry. The potential to recover zinc for beneficial use in the micronutrient fertilizer industry was investigated through a survey of zinc micronutrient fertilizer representatives. An application of the findings to a case study of the Argo Tunnel influent MIW was then implemented. It was concluded that the potential to beneficially reuse MIW residuals in fertilizers exists; the current process sequences of treatment will need to be modified if metal recycling is to be prioritized.

Feb 27, 2013

The importance of understanding the behaviour of cemented paste backfill (CPB) within the framework of the effective stress concept is highlighted in this paper. Only through an understanding built on this concept can problems such as barricade loads, the rate of consolidation and arching, be fully understood. The critical importance of the development of stiffness during the hydration process, and its impact on factors such as barricade loads, is used to illustrate why conventional approaches that implicitly ignore the effective stress principle are incapable of capturing the essential components of CPB behaviour.

May 1, 2007

By V. J. Decarlo, J. J. Gilman

POLISHING pure zinc differs somewhat from polishing less reactive metals. The problem is not that of finding a suitable reagent, but rather of producing the polish in such a way that the surface remains polished after it is removed from the polishing bath. In other words., the anodic film that is vital to the polishing mechanism&apos; must be tightly adherent and nonporous. It is usually desirable that it be thin. Polishing solutions consist of proper proportions of an acid and a strong oxidizing agent. In electro-polishing, the external circuit acts as the oxidizing agent. The proportions are critical because the essential surface film must be maintained at approximately constant thickness during the polishing process. In the case of zinc, chiefly two oxidizing agents, chromic and nitric acids, have been used. The simplest polishing reagent is concentrated nitric acid. However, it has certain disadvantages. It tends to pit: an excessive amount of heat is evolved during polishing; and the oxide film that it produces is not very stable, so that the polished sur-

Jan 1, 1957

By J Wiklund

The impact of non-ferrous smelters on their local surroundings is well monitored and guarded by various actors: the owners looking for profitability, the villagers looking for employment, the consumers asking for ever cheaper products and services, the government collecting taxes and all cherishing the environmental impact. Recent challenges facing the industry are various new doomsday projections: that we will be running out of base metals, that the ground we dwell on will be contaminated by the use of products. Smelters, such as BolidenÆs R÷nnskSr Smelter have a long history of increasing non-ferrous resources by recycling. It is shown that extraction and recycling of metals together with energy recovery can be integrated in a modern, profitable and clean smelter. Examples of efforts to further improve the business will be discussed such as flowsheet rationalisation, environmental investments, new feed from recycling and energy utilisation.

Jan 1, 2000

By Jerry Ran

Stope back caving in a mine using open stope mining interrupts the planned mining sequence and causes oversize muck and dilution with adverse economic implications. As many underground mines are mining or have plans to mine at depth, stope back caving could have significant impact on the mine sustainability. Therefore understanding the caving mechanism is important in preventing future occurrence and improving the mine economic performance. Falconbridge Ltd Kidd Mine is an underground mine using open stope method producing more than 2 million tonnes per year. Its current lowest mining level is approximately 2070m below surface and the lower portion of the orebody is being developed. In years of 2002 and 2003 the back of three stopes of approximately 1900m and 2040m below surface caved and caused substantial mining difficulties at the mine. As these caved stopes are subject to stress concentration, seismic activities and near major geological structures, the caving mechanism is much more complex than that of stopes near surface. In addition to the recorded caving history by site observations, the mine carried out cavity surveys and test drilling to define the caved profiles. The mine seismic monitoring database provided information at these stopes. Stress modeling work conducted by an external consultant provided the stress patterns at the caved stopes. Based on the field collected data and stress and seismic information, this paper presents details of the stope caving process and cavity surveyed profiles, reviews the predictability of the stability graph approach for these cases, discusses the caving mechanism and proposes preventive measures to stabilize the stope back.

May 1, 2004

By Jintao Gao, Zhancheng Guo, Chong Li

A new approach to enrich MFe and RO phase from the converter slag by super gravity was investigated. The samples obtained by the gravity coefficient G=600 and cooling rate V=5K/min from 1623K to 1373K appeared significant stratification and the MFe gathered at the bottom of sample. With the help of metallographic microscopy and X-ray diffraction, it is found that large quantity of white RO phase gathered at the lower part of the sample as the concentrate, with volume fraction appearing gradient distribution along the direction of super gravity, while the upper part was mainly composed of dicalcium silicate as the tailing. The mass fractions of the FeO, MgO and MnO in the concentrate are up to 40.46%, 6.9% and 3.91%, while that in the tailing are just 11.65%, 2.15% and 1.55%. The recovery ratios of FeO, MgO and MnO in the concentrate are 60.35%, 58.45% and 72.24%, respectively.

Jan 1, 2016