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By C. C. Martin, M. C. Fuerstenau, R. B. Bhappu

Experiments revealed that quartz could not be floated in conductivity water at any pH with a long-chained sulfonate as collector. Various cations, Fe+++, Al+++, Pb++, Mn++, Mg++, Ca++, are shown to function as activators when the pH is such that the cation hydrolyzes. As the solubility product of the various cation-sulfonates was exceeded at the concentrations involved, precipitated cation-hydroxy-sulfonates, e.g. Fe (RSO3)2OH must be functioning as the collector in these systems. A number of interesting and important phenomena were revealed during a study of the response of beryl to sulfonate flotation.' Perhaps the most important observation is the effect of various cations on flotation response. Experiments showed that in the vicinity of pH 3.0, about three ppm Fe+++ increased recovery of leached beryl from about 60 pct to 100 pct, whereas about four ppm Ca+ + reduced the recovery from 60 pct to 2 pct. With the exception of ferric iron, all of the other cations investigated reduced flotation recoveries drastically at this pH. As postulated in the paper Sulfonate Flotation of Beryl,' even with low concentrations of polyvalent cations and sulfonate (on the order of one ppm), cation-sulfonates are precipitated immediately in solution. That is, blueish-white clouds were noted to form after given additions of salts to known solutions of sulfonate. Furthermore, it was also shown that one-hundred-fold more ferric iron than necessary to form the precipitated cloud had to be added to effect complete flotation. In other words, some form of solid ferric sulfonate was found to function as the collector in these systems. The form of the compound was suggested to be Fe(RCO3)2OH and that bonding to the surface occurs through the hydrogen of the hy-droxyl. As the form of this compound was shown to be dependent on the extent of hydrolysis of ferric iron, it is to be expected that ferric iron will be unique in some pH region. Further, if the presence of hydroxyl in the neutral precipitated compound is of primary importance, then other cations should function similarly but at different values of pH, since they will hydrolyze at different concentrations of hydroxyl ion. To determine whether the premise of hydrolysis is correct, the study was extended to quartz systems in the presence of various cations at various values of pH. EXPERIMENTAL MATERIALS AND METHOD Sodium alkyl aryl sulfonate was chosen as the collector for the experimental work. The reagent, sup plied as a courtesy sample by the Shell Chemical Co., has the following physical properties: Physical form Solid — Finely ground Sulfonate content, pct wt 95 to 97 Molecular Weight 450 to 470 Number of carbon atoms in hydrocarbon chain 25 to 30 Melting Point, OF 250 to 260 Solubility Soluble in water with gel formation at concentrations higher than 25 pct by weight sulfonate This particular reagent was chosen because of its high active sulfonate content, long-chain length, and solid form. With the exception of the frother and sulfonate, all other chemicals were of reagent grade quality. Conductivity water was used in the experimental work. This water, made by passing distilled water through an ion exchange column, had an average measured conductivity of one micromho. Experiments were conducted at room temperature in a small glass flotation cell with the following procedure: 1) A redetermined amount of water and salt solution (e.g. CaC12 . 2H2O) were combined and the pH adjusted to a given value. 2) A given amount of sulfonate was added so that final solution volume was 130 cc. 3) One drop of Dow 250 frother was added. 4) Five g of quartz were added and the system conditioned for five minutes. 5) The pH of the system was measured (termed flotation pH).

Jan 1, 1963

By Alden B. Greninger

Although the crystallography of lattice transformations has been studied extensively during the past few years, these studies have been limited, with few exceptions1'2, to specimens in which the transformed lattice appears as a segregate phase. A realization of the technical importance of the segregation mechanism, especially in the formation of martensitic structures and in age-hardening phenomena, has undoubtedly stimulated research in this direction. In the crystallographic studies of segregation, the general problem has been to relate the orientation of the parent crystal to that of the segregate crystals. The technique has been complicated by the fact that it has been necessary to deal with the presence of as many as 24 ideal segregate orientations within one parent lattice; furthermore, the segregate lattices are invariably scattered (seldom less than ±2º, often as much as 15" or 20') about these ideal positions. It is probable that a more complete picture of phase transformations may result from a study in which complete lattice relationships between individual grains are evaluated, thereby providing an additional parameter which when it is necessary to work with multiple segregate orientations, cannot be evaluated. The present paper presents the results of such a study, ? wherein a peritectic reaction is made use of to produce the transformed lattices. Matebials and Methods Pem'tectic Reaction.—In Fig. 1 is reproduced a portion of the copper-zinc equilibrium diagram, which includes the peritectic reaction a + liq. —ß. A liquid of composition between B and D upon solidifying will

Jan 1, 1937

I trust you know now or will know by the time you havecompleted your degree and added a little on-the-job experience,how to make the product from the mine you are working for. Butyou may not know the process to turn it into dollars, which ofcourse will be the life blood of your company. I am not going topromise to turn you into super salesmen, but I hope I can takeyou beyond the level of believing that selling our mineralproducts is as simple as putting in it on to a train, waving itgoodbye and waiting for the cheque to turn up in the mailbox afew weeks later.

Jan 1, 1994

By H. M. Boylston

Metallic manganese was first produced in 1773, by Sven Rinmann, a Swedish mineralogist. In 1799, William Reynolds, of Ketley, England, obtained a patent on the use of manganese dioxide in the manufacture of steel, and in 1808 an English patent was granted to John Wilkinson covering the use of manganese ore, or manganiferous ore, as an addition to iron ore in the blast furnace for the production of a superior grade of pig iron. Karsten showed in 1816 that manganese increased the hardness of iron without decreasing its malleability or toughness, while it caused pig iron to be more white in fracture and more fusible. The first practical application of manganese to steel-making, however, is attributed to Josiah Heath who discovered in 1839 (less than 90 years ago) that manganese conferred upon steel the properties of being more easily worked and welded under the hammer. When Bessemer invented the pneumatic process of steel-making which now bears his name he was at first successful because, as it afterward developed, he was using a Swedish pig iron high in manganese. When his supply of this material ran out, he used a low-manganese pig from English sources and failed signally to produce a steel which could be rolled, while his Swedish licensees were continuing their successful application of his method. And it was not until Robert Mushet, in 1856, suggested the addition of manganese in the form of spiegeleisen to the molten product of the converter that success again came to Bessemer. In 1866, William Siemens patented the use of ferromanganese as an addition to molten steel to counteract the bad effects of sulfur. It was in 1888 that Robert Hadfield published at some length his account of the effect of manganese as an alloying element in steel and described the unique properties of the now famous Hadfield manganese steel containing about 12 to 14 per cent. manganese and 1.25 per cent. carbon. Function or Manganese in Steel-making Bessemer's failure at one period of his experimental work to make steel which could be forged successfully was due to the fact that the

Jan 1, 1927

By Yoshio Masuda

Cobalt-rich crust in rich Co, Ni, Mm and Pt will be a potential resources for island country such as Republic. Marshall Islands. This study was conducted for Marshall Islands by the President Kabua?s request. It covers crust resources, CLB mining, processing, and economic estimation, and study concluded feasible veiw.

Jan 1, 1991

By T. Janke

When Homestake Mining Company's Mclaughlin Gold Project was being evaluated for development, it was apparent that recovery of gold from mined ore would be difficult and relatively expensive. The ore was refractory, averaging less than 50% recovery in conventional direct cyanidation milling tests. Extensive testing narrowed the processing choices to either autoclave or roaster oxidation before cyanidation. Roasting was ruled out due to higher capital and operating costs --the Mclaughlin mill would be the first large-scale application of autoclave oxidation of a refractory gold ore.

Jan 1, 1989

By J. O. Edstrom, G. Bitsianes

Parabolic rate constants were determined for the formation of wiistite by the solid state reaction between magnetite and iron. The reaction was diffusion controlled and inert marker studies indicated that the mass transport through the wiistite layer was accomplished by means of iron migration. Relationships between rate constants and self-diffusivities are discussed. The transport capacity for iron through dense wustite layers was found to be sufficient to carry on reduction, even in gaseous reduction processes. REDUCTION of iron oxides has been the subject of many investigations. Most of the work, however, has been done on rather crude material and there have been difficulties in correlating the data on a quantitative basis. The reverse process of the oxidation of iron has been studied more thoroughly and usually by starting from the pure metal. As a result, the mechanisms of oxidation are now fairly well known.It has generally been found that the oxidation of metals follows the so-called parabolic 1aw;Q hat is, when the oxides are formed as dense layers, their thicknesses are proportional to the square root of the reaction time. This parabolic law follows directly from Fick's first law of diffusion The flux, J, is defined as the quantity of diffusing substance passing per unit time through unit area of a plane at right angles to the direction of diffusion. This flux is proportional to the concentration gradient of the diffusing substance, and the factor D, known as the diffusion coefficient, is introduced as the proportionality factor with dimensions of (length)'/time. If the flux is measured as the increase of thickness of the oxide layer (Ax) per unit time (t) and the assumption is made that the concentrations of the reactants at the phase boundaries of the layer are independent of time, Eq. 1 reduces to Integration of this expression yields the parabolic function ax = k . t. [31 The product of the diffusion coefficient and the concentration difference across the oxide layer is included in the constant k. When iron is exposed to a highly oxidizing atmosphere, the oxide phases are formed normally in a topochemical fashion, i.e., the interfaces between the phases maintain parallel positions to the original surface of the specimen. Above 570°C, the phases are orientated usually in the order of iron, wiistite, magnetite, and hematite, a condition in conformance with the requirements of the Fe-0 system. Below 570°C, the wiistite phase is unstable and has not been found as a normal constituent in the oxidation products of iron. There is a strong probability that continuous layers of the solid oxides are formed as the specific volumes of the phases increase in direct order from iron to hematite.' , ' Regarding mass transport through dense solid oxide layers, Wagner' has postulated that diffusion in oxides generally may be interpreted as migration processes of ions and electrons. There must be normally a concentration gradient across the growing oxide layer for diffusion to occur. This condition requires that there be deviations from the ideal stoi-chiometric composition of the oxide and accordingly deviations from the strict order of an ideal lattice. Such "lattice defects" include interstitial ions, cation and anion vacancies, quasi-free electrons, and electron holes and are decisive for all migration processes.' Cations, anions, and electrons all may have some mobility in the oxides but the movement of one of the particles generally far exceeds that of the others. Previous work', 1,2,7 has shown that during the oxidation of iron the migration through the wiistite layer, and probably also the magnetite layer, is confined to the movement of iron ions. Migration through hematite, however, has been found to take place by oxide ion movement. These behaviors are in direct agreement with the type of vacancies present in the respective oxides. Reduction of Iron Oxides The gaseous reduction of iron oxides, like the oxidation of iron, takes place in a topochemical fashion at distinct interfaces between the appearing phases."-'" Porosities might be expected in these reaction products, since their specific volumes are less than that of the starting material. Frank and van Der Merwe" have shown, however, that it is theoretically possible for nonporous layers to form if the degree of misfit in specific volume is less than about 15 pct. These aspects on porosity formation

Jan 1, 1956

By Denise Y. Dizon

The objectives of this study were to document the hydrologic impacts of longwall mining on streams, identify the factors affecting the extent of stream dewatering, and develop empirical trends to predict the extent of dewatering and recovery of streams in advance of mining. This study on stream impacts is a companion to a stud; conducted on ground water impacts from longwall mining, which was done as part of the same research project at the' same locations and times. The study areas are three mine sites in north- central West Virginia. Mine A, located in Upshur County, has relatively thin mine overburden under the valley streams (105-115 feet). Stream monitoring there continued the earlier work of Cifelli and Rauch (1). Stream dewatering was severe with streams often going dry over the longwall panels during baseflow conditions. The lost water was probably flowing to the mine. Dewatering began in streams over the mine entry areas adjacent to the panels and as much as 380 feet from the nearest panel edge. The angles of dewatering influence ranged 22 to 72 degrees with respect to the nearest mined panel edge. Discharge then typically increased as the streams- flowed across the panel edge, but then decreased again over the panels. These streams were often ponded by local reversals in hydraulic gradient caused by land subsidence, and often dried up after flowing a few hundred feet across the panels. This occurred over panels that were previously mined up to eight months before. Mine B, located in Monongalia County, has relatively thick mine overburden (475-485 - feet) under the major stream. Stream dewatering was severe there during warm season baseflows, with complete dewatering occurring then over the longwall panels. This dewatering occurred over mined panels up to five years old, probably in response to a major anticlinal axis lineament and fracture zone in the stream valley. Mine C. located on the West Virginia -Pennsylvania border, has relatively thick mine overburden (about 585-630 feet) under the monitored streams there. stream dewatering was only partial, and these streams typically recovered their lost discharge downstream of the mine, indicating that lost water was not recharging to the mine. Only longwall panels less than one year old were associated with stream dewatering.

Jan 1, 1990

By Walter C. Woodmansee

The only reported mineral production in 1977 was small output of alluvial gold, valued at an estimated $54,320.2 In addition, marine shells are gathered for use in lime manufacture, although output was not reported. Proposed development of a bauxite mine and smelter, involving Rennell and Vaghena Islands, was deferred in June. Conzinc Riotinto of Australia Ltd. (CRA), in partnership with Mitsui Mining & Smelting Co. Ltd., and the Solomon Government, with- drew from the project, and Mitsui, which conducted a feasibility study and metallurgical testing of the bauxite, decided to defer further work because of slack demand for aluminum in Japan and difficulties in arranging financing. The Mitsui feasibility studies reportedly indicated that the project could be viable despite technical difficulties and relatively high initial investment costs. The project was to produce 1.5 million tons of bauxite and 600,000 tons of alumina per year from reserves totaling 60 million tans at 45% to 50% A1203.

Jan 1, 1981

By E. L. Smyth, A. Button

The apparent absence of significant Tertiary auriferous palaeoplacers in the Yilgarn Block of Western Australia can be explained by the dissolution of the placer gold into the highly saline, acid, oxidising ground waters which currently occur in upper portions of the palaeochannels proximal to the gold sources. The dissolved gold has then been redeposited in redox fronts further downstream. The placer gold is preserved in more distal portions where the ground waters are reducing. Exploration for these placers can be effective using the gravity contrasts that exist between the Tertiary sediments and the Archaean bedrock and SIROTEM which can detect the highest salinity zones which occur in the deepest parts of the channels. Final assessment of the gold content of the sediments must be determined by drilling.

Jan 1, 1989

By Rayner B

Five wells have been drilled in the Basker/Manta Block of VIC/P19, Gippsland Basin, resulting in sub-economic Intra-Latrobe Group oil and gas discoveries at Basker-1 and Manta-1. A total of 21 individual hydrocarbon bearing sandstones were intersected by the two wells. These reservoir sand bodies were deposited by fluvial processes in a lower coastal plain environment. The modelling of sand body orientation and geometry is a critical component in the evaluation of the two accumulations. Seismic resolution of the thin (average 2 m to 5 m) sand bodies is inadequate for mapping their orientation and distribution. Dipmeter data has been successfully applied to the problem of orienting the sand bodies using FMS images acquired during the drilling of Gummy-1 and reprocessed HDT data from Basker-1 and Manta-1. Prediction of lateral extensiveness (geometry) of individual sand bodies has also been attempted. Interpreted palaeocurrent direction from all three wells is dominantly from the NW to the SE. Reservoirs in the Manta-1/Gummy-1 area are interpreted to be predominantly channel sands, deposited by relatively low sinuosity streams. As such they would tend to have a laterally extensive, elongate geometry. Sand bodies deposited in the Basker-1 area show a predominance of laterally accreted cycles deposited by meandering streams. Channel geometry may then be limited in the downstream/upstream direction by internal permeability barriers such as clay plugs.

Jan 1, 1992

By F M. Dantini, P Berry

An experimental investigation on the trend of cratering induced by explosives placed on rock masses was carried out. By using various types of explosives and rocks having different geomechanical parameters, it was possible to evaluate the influence of the explosive-rock coupling. Furthermore, the importance of the parameters defining the rock and the explosive for the absorption of energy induced in the rock mass, is pointed out.

Jan 1, 1981

By Dennis A. Swyt

In current post-industrial America, U.S. manufacturing is undergoing major changes both in the technology of its production and in the size and composition of its workforce. At the same time that computers and robotics move the shop floor toward becoming the unmanned "factory of the future" [1], they increase the need within the overall production enterprise for new types of technicians and engineering professionals [2]. Based on previous works which examined, first, the evolution of the technology of manufacturing toward the flexibly-automated factory of the future and, second, the technical- professionalization of U.S. manufacturing sectors [1,3], this paper looks briefly at the workforce of the U.S. metals industry.

Jan 1, 1989

By R. J. Davidson, N. Schoeman

SYNOPSIS The paper describes each of the stages in a carbon-in-pulp (CIP) or carbon-in-leach (CIL) plant, and details the steps that can be taken to achieve effective carbon management by referring to practices at the Daggafontein CIP plant. This approach was adopted because of the difficulty in summarizing current carbon management in the many varying operations in South Africa, Daggafontein being chosen as a high-tonnage dedicated well-run plant of recent design. Because of the major role played by the consumption of carbon in the operating costs of CIP and CIL plants, an attempt is made to develop a series of indexes based on quality parameters and price that can be used as a guide In the selection of carbon.

Jan 1, 1991

By S. W. Stogran

"Chemical and limited biological monitoring of mine and mill effluents are being used by regulatory agencies to monitor and control discharges to the environment. Amendments to the Federal Fisheries Act may make it mandatory for mines to conduct Environmental Effects Monitoring (EEM) which will change the emphasis from monitoring effluents to monitoring impacts on receiving waters. The EEM amendments may expand the scope of present environmental studies to include: effluent mixing zone delineation; inventory and classification of resource, habitat, and historical receiving environment; effluent quality determination; chronic and acute bioassay testing; tissue analysis; benthic invertebrate monitoring; fish population surveying; fish tainting evaluation; and the evaluation of impacts on fish habitat, invertebrate communities and fisheries resources. The requirements for EEM have not yet been worked out by the mining industry and the government committee. Experience at Lakefield Research in conducting biological monitoring studies for the mining industry has shown that biological monitoring may be useful for assessing environmental impacts only if programs are planned and executed to collect relevant data, thus minimizing costs and maximizing effectiveness.IntroductionThe chemical monitoring of effluents and water bodies receiving effluents is common practice in the Canadian mining industry and has been used routinely by regulatory agencies to control discharges to the environment. Biological monitoring has also been used on a limited basis, primarily to augment chemical data collected. A number of regulatory bodies, primarily in Canada and the United States, have been incorporating biological monitoring into environmental regulations.Various forms of biological monitoring techniques have been used in Canada and the United States to help assess the impact of mining operations and effluents on the environment. Biological monitoring includes a wide range of activities, from monitoring metal uptake in individual organisms to examining the population dynamics in ecosystems. The most commonly employed biological monitoring techniques are the chronic lethality toxicity tests. Also becoming widely used are in situ and chronic toxicity tests."

Jan 1, 1994

By Charles R. Holmes

MORE than 70 igneous pipes and dikes are known to occur in Cambrian sediments throughout an approximately circular area of about 75 sq miles, in southwestern Ste. Genevieve County and southeastern St. Francois County, Mo., across the southern portion of the Farmington anticline, which is outlined in fig. 1. From evidence obtained from fossil fragments taken from some of the intrusives, and from the similarity in composition of the more basic intrusives to those of known age in surrounding states, these pipes and dikes are believed to be at least post-Devonian and probably Cretaceous in age. As first postulated by Rust[1], these intrusives are believed to represent explosion tubes, or diatremes, punched through great thicknesses of solid rock by gaseous pressure.

Jan 11, 1950

By Misra V. N, Spottiswood D. J

In recent years the column flotation process has gained worldwide acceptance for processing various types of minerals under different circuit configurations. In an age when real prices of many mineral commodities are in decline and mining and labour costs are rising in real terms, it is more important than ever that concentration processes be not only efficient but also cost-effective. The column flotation process can give better metallurgical performance as well as involve lower capital and operating costs compared to conventional mechanical cells.This paper reviews the literature on columns and the effects of various column parameters on performance of the column flotation process. The history and principles of operation of the column flotation process are briefly discussed by way of introduction.

Jan 1, 1995

As the worldÆs population and global standard of living increase, the role of metals in the economy will not diminish in the 21st century, despite substitution and dematerialisation trends. Industrial Ecology is an emerging science that attempts to bring together physical, biological and social scientists and develop the tools for good management of the planet in the long run. In engineering terms, Industrial Ecology is defined as the reconfiguring of industrial activities with full knowledge of their environmental consequences. Production and use of materials must take into account the needs of both market and environment. Dispersive uses of metals will be phased out, as is being done with lead in gasoline, and post-use recovery of materials and energy will increase. This will result in an advantage for metallurgical processes that can use as feed materials concentrates as well as metal scrap and waste streams, such as bath smelting processes and slag resistance electric furnaces. The paper also discusses how metal extraction technologies, developed in the 20th century to provide essential materials to humanity, can be applied for the benefit of both mankind and environment in the 21st century.

Jan 1, 2000

By S. Hunt, D. de Vries

Kansanshi Copper Smelter began operation in March 2015. The smelter features a single Isasmelt furnace for smelting, one 6-in-line electric furnace for matte-settling and slag-cleaning duties, four Peirce- Smith converters and two rotary anode furnaces. A 1,450 t/day oxygen plant and a 4,085 t/day sulphuric acid plant are included in the smelter operations. This paper gives an overview of the operational performance to date with summary data for each smelter section. Challenges such as an unforeseen refractory failure in the Isasmelt furnace in 2016 are discussed. Design improvements around the electric furnace are mentioned. Plans for potential future improvements are put into context. A consistent focus on operations, maintenance and continuous improvement has seen the smelter easily achieve its nameplate capacity of 1.2 million tonnes per annum of copper concentrate throughput. The smelter now operates consistently at a concentrate throughput rate of 1.38 million tonnes per annum of copper concentrate. INTRODUCTION The smelter was commissioned in March 2015. Design and commissioning of the smelter have been discussed by de Vries, Hunt, Hanschar and Louie (2016). The smelter rapidly ramped up to achieve nameplate production (1.2 million tonnes per year concentrate) and in 2018 operated consistently at the rate of 1.38 million tonnes per year concentrate. This paper presents major operational data for each section of the plant and describes significant events and improvements during the first four years of operation. The smelter flowsheet is shown in Figure 1.

Jan 1, 2019

Jan 1, 1916