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The paper discusses the improvements achieved after an external sparger flotation column was installed as a final cleaner at the Northam Platinum Ltd. UG 2 concentrator in South Africa. It further discusses the improvements achieved after the conversion of a conventional flotation column, utilized as cleaner in the Merensky concentrator, to an external sparger flotation column. Finally, the application of the above knowledge in the design and commissioning of an external sparger flotation column as final cleaner in the furnace slag concentrator, is also discussed. 1. FINAL CLEANER AT THE UG 2 CONCENTRATOR The MF2 designed UG 2 concentrator is processing 75 000 tonnes run of mine ore at a head grade of 4.0 g/t 3PGM+Au and a feed Cr2O3 concentration of 28 %. Since commissioning of the plant in 2001, Cr2O3 in final concentrate amounted to approximately 5 % of the total mass. Although final concentrate produced from the UG 2 concentrator is blended with final concentrate obtained from the Merensky concentrator before smelting, blended Cr2O3 values in excess of 1.6% lead to difficulties in the subsequent smelting process. Several options for reducing the amount of Cr2O3 in final concentrate have been evaluated namely:- ? Differing types of depressants at various dosing rates. This test work did not reduce the amount of Cr2O3 reporting to final concentrate by any significant extent. ? Reduction in mass pull to minimize the entrainment of Cr2O3 in the concentrate stream.. This process change had a detrimental effect on PGM recovery. Conclusions were drawn that conventional mechanically agitated flotation cells could not achieve the required selectivity without sacrificing PGM recovery. As a consequence an alternative mechanism needed to be incorporated for the final cleaning of PGM concentrate.

Jan 1, 2007

By Liu Run, Jia Zhao-lin, Yan Shu-wang

"Piles with diameter larger than 2m in engineering can be defined as large diameter pile, and piles used for oil platform foundation in Bohai Gulf, are usually over 100m long and 2m in diameter. Such long piles have to be manufactured by segments before installation, because of transformation and hoisting difficulties. The segments of the pile are assembled by welding during installation one to another. Normally, assembling two pile segments takes one day or even a longer time, which mainly depends on construction conditions. After pile segment assembling, it proves to be difficult to restart the successive penetration. The mechanism of pile refusal is discussed and the process of driving a segmented pile is simulated with a finite element program. The calculating results show that, when the stick-up stability was satisfied, increasing the length of the last segment of the pile and assembling the pile segments when the pile tip penetrates into a clay layer could greatly ease the difficulty of driving the pile. Furthermore, cutting down the pile extension time is also one of the most effective measures to minimize the refusal risk.1. InstructionIn recent years, more and more oil platforms with six or eight legs have been adopted in Bohai Gulf, China. The leg piles with diameters of 2m or more have to be driven to about 100m below the sea bed. Such long piles have to be manufactured by segments before installation, because of transportation and hoisting difficulties. The segments of the pile will be assembled during installation, in which a successive segment will be attached to a formerly penetrated one by welding (Fig.1). The assembling work often takes one day or even a longer time."

Jan 1, 2014

The following brief observations on the mineral composition of the Mt. Oxide copper ore are intended to supplement the geological description of that ore-body recently published by Blanchard (2).'" The Mt. Oxide copper mine is situated about 45 miles W.N.W. of Dobbyn, in the Cloncurry district of Queensland (Fig. 1). A representative suite of specimens from the mine was obtained through the kindness of Mr. P. B. Nye, Executive Officer of the Aerial, Geological and Geophysical Survey of Northern Australia, and Mr. Jack Hall, the tributor of the Mt. Oxide mine. The specimens, as shown in Fig. 2, were nearly all from the sulphide zone, between the l04-ft. level and the 300-ft. level. Several additional specimens, together with information which will be referred to later were kindly sent to me by Mr. Roland Blanchard.MINERAL COMPOSITION OF THE COPPER OREThe mineral composition of the ore is relatively simple. It consists essentially of chalcocite, with varying, but minor figures...

Jan 1, 1940

By A. L. MacAllister

"Keymet Mine lies on the Elmtree River 4 miles west of Petit Rocher and about 18 miles northwest of Bathurst, Gloucester County, New Brunswick. A good gravel road runs through the property.The deposit was discovered in 1880 when a vein 7 to 8 feet wide was re-ported. In 1883 the first shaft was sunk as part of an exploration program which was carried out sporadically until 1897, when the company dissolved. Activity on the property was intermittent until 1946 when the property was again staked and during the next year diamond drilling intersected the vein in several places. In December 1949 Coulee Lead and Zinc Mining Company optioned the property and held it until its sale to Keymet Mines Limited in June 1952. By July of the same year work had begun on a three-compartment shaft.Early development work was concentrated on the 150, 300 and 450 foot levels but the shaft has since been sunk to I,228 feet to allow for eight levels at intervals of 150 feet. Little lateral work has been done to date below the 600-foot level.The first mill constructed to treat the ore was to go into production in the spring of 1954, but was destroyed by fire. A second mill, having a capacity of 200 to 300 tons a day, was officially opened October 25th, 1954. Present shipments are zinc and copper-lead-silver concentrates.The rocks of the area are shale, conglomerate, limestone, and quartzite with minor interbedded volcanic rocks, all probably of Silurian age. Small plugs of Devonian acidic intrusions occur 3 miles east and about 5 miles northwest of the mine. Minor dykes of both acidic and basic rocks occur on the mine property. In many of the fine-grained sedimentary rocks the more brittle laminre have been brecciated and give the rock the appearance of an argillaceous conglomerate."

Jan 1, 1949

By R Morrison, P Owen

Particle breakage is an essential part of mineral processing. The aim is to reduce run of mine mineral ore to an optimal size for liberating target minerals and for subsequent recovery by separation processes such as flotation. This size reduction is typically accomplished in a series of stages in a grinding circuit tailored to the properties of the particular mine ore. Commonly this involves two or more classes of equipment starting with crushers, followed by SAG mills and then sometimes ball mills. Occasionally, high pressure grinding rolls or other novel devices are substituted. Broadly, energy consumption increases and energy efficiency decreases with the fineness of the material produced by each piece of equipment. For many operations, up to 50 or 60 per cent of total greenhouse gas emissions from a plant arise from the operation of the comminution circuit with the majority produced by the finest grinding parts, such as the SAG and ball mills. Wear of mill liners and grinding media also add to greenhouse gas emissions generated by their manufacture. The need for continual cost reduction and increasing regulatory and social pressure relating to greenhouse emissions create a strong need for improvements in comminution energy efficiency. Traditional experimental and modelling approaches are not well placed to create the required insights into comminution fundamentals or facilitate radical step changes in performance. This paper discusses the role that advanced modelling (based on coupled DEM and CFD) can play in improving the energy efficiency and performance of existing mainstream grinding equipment and in the development of new ones with radically superior performance. Achieving this goal will also require an improved understanding of ore breakage and methods to include sufficiently realistic breakage models within the DEM models. Developmental issues for the modelling and the critical need for validation of the advanced model features are highlighted.

Jan 1, 2004

By G Zhao, S Hapugoda, E R. Ramanaidou, P Hapugoda, Y Jin, G O’Brien

In 2021 the ports of Port Hedland and Dampier in the Pilbara Region of Western Australia handled 900 Mt of iron ore. This ore was produced in the Hamersley’s mines and transported by trains to the ports for subsequent export. Dust, which is generally considered to be particles less than 100 μm in diameter, is generated at all steps in the supply chain. Whilst all dust may have potential impacts on human health and mangroves and buildings a proportion of the dust is classed as respirable (PM10) dust, which consists of particles <10 μm in diameter. In 2021, in response to the community concern with iron ore dust, CSIRO commissioned an internal study to characterise and benchmark the dustiness of the different ores and to develop targeted strategies to minimise dust impacts, without affecting other iron properties, such as stickiness during transportation. A specific concern is that that the dust in the PM10 fraction may contain significant amounts of particulates, such as free silicates which may have health implications for the workers and residents. This study provided detailed mineral and chemical characterisation of the dust generated from the railed fine ore products for five generic Australian ore types: Australian Channel iron Deposit (ACID), Australian Brockman (AB), Australian Marra Mamba (AMM), Australian Pilbara (AP) and Australian magnetite (AM). The dust from these fine ore products were compared to that generated from a sample of Brazilian Hematite (BH) type ore fines. The ores were evaluated for their physical, chemical and mineralogy properties, dust generating potential and understandings of the relationship between the dustiness of iron ores and their physiochemical properties. The size distributions of the railed fine ore products were determined and a suite of analyses were conducted on subsamples of total (-106 μm) and fine (-38 μm) dust. For all the ores, the total dust fraction contains less Fe and more contaminants (SiO2 and Al2O3) than did the bulk ore. The fine dust fraction contained even less Fe and more contaminants (SiO2 and Al2O3) than the total dust fraction. This suggests that the iron ore dust contains more clay and potentially free silica than does the bulk ore. These findings were supported by optical and Scanning electron microscopy analyses of the samples. Dustiness measurements were made for each of the different ores (-106 μm) to investigate the relationship of dustiness of various iron ores with their physiochemical properties and assess their responses to dust suppression by the application of water sprays.

Sep 18, 2023

We can look at the water treatment and management strategies at some recently commissioned mines and minerals processing sites to see the likely future of water in mining. The future of water in mining will be based on a holistic approach to understanding the site water balance, appropriate treatment, reuse where possible, and environmentally managed discharge where required. This paper describes advanced and innovative water treatment and reuse processes as used by mines and mineral processing operations from around the world. Underground mining can often require dewatering to prevent groundwater seeping into and flooding the mine workings. Mining and processing often accumulates wastewaters in a tailings dam. The mine water can contain contaminants such as dissolved salts, iron, arsenic, manganese, heavy metals and acidic and odorous sulfates. On-site reuse, environmental discharge requirements, as well as community needs for water, drive mine operators to consider the most appropriate water treatment process. Mining water treatment for the future is described using case studies of innovative processes. The case studies include treatment of mine dewatering water for beneficial application from Australian mines, Ballarat Goldfields and Bendigo mining, treatment of produced water from oil and gas projects, and treatment for arsenic removal of tailings water from mining and processing at Goldcorp mines in Canada. Advanced and innovative processes including membrane filtration, reverse osmosis at extreme conditions, advanced biological treatment and water management are all part of these case studies. This paper uses real case studies of advanced and innovative mine water treatment processes to explain and examine the technology and the reasons for designing specific processes. The focus is on innovative processes that may be more widely used in future mining û where the water is used for sustainable environmental discharge or treatment to a quality that can be beneficially used by the mine or the local community.

Jan 1, 2008

By C. O. Tarr, G. V. Smith, R. F. Miller

METALLURGISTS have long recognized that the Fe3C type of carbide is not a stable phase in steel and that, given sufficient time, it will decompose with formation of graphite, at least at temperatures below about 2050°F.1 This slow graphitization has never been of much concern to users of hypoeutectoid steels, for in such steels it occurs only during prolonged exposure at elevated temperature. In 1935, Kinzel and Moore2 reported complete graphitization of the carbide of a 0.1 5 per cent carbon steel that had been in senrice for about 26,000 hr. at a temperature of about 1100° to 1200°F. In discussing this paper, both Mathews and Sauveur reported graphitization of slightly hypereutectoid steels. In an extensive investigation of graphitization of high-purity iron-carbon alloys, Wells1 produced graphite at 7o0°C. (1290°F.) in an alloy containing as little as 0.13 per cent carbon, and showed that graphite may precipitate either directly from austenite or from decomposition of Fe3C, also that the rate of graphitization tends to increase with increase of temperature, at least up to a certain point, and with the presence of graphite nuclei. Jenkins, Mellor and Jenkinson,3 studying the structural changes in carbon steels ranging from 0.17 to 1.14 per cent carbon during stress-rupture tests at elevated temperature, obsenred graphite in an aluminum-killed 0.40 per cent carbon steel after fracture in 4340 hr. under a stress of 17,900 lb. per sq. in. at 840°F. and in many of the steels after stress-rupture test at 1200°F. Unstressed samples of 0.60, 0.86 and 1.14 per cent carbon steels graphitized almost completely in 360 hr. at 1200°F., while samples of 0.90 and 1.10 per cent carbon steels were somewhat graphitized, and steels containing 0.24, 0.40 and 0.57 per cent carbon showed no sign of graphite. Their results indicate that graphite precipitates the more readily the higher the carbon content, though this tendency is influenced to some extent by deoxidation practice, and that graphitization is accelerated by plastic deformation. In a recent study of the graphitization of 0.4 and 0.6 per cent carbon steel strip, made by M. A. Hughes,4 it was found that at 1200°F. graphite appeared after 72 hr. in aluminum-killed but not in silicon-killed steel, and that the rate of graphitization was increased by slow cooling from 1600°F. and by cold-working prior to annealing. In creep tests of normalized o. I 5 per cent carbon steel killed with 2.5 lb. of aluminum per ton, at the U. S. Steel Corporation laboratory at Kearny, spheroidization and some graphitization were found after 3000 hr. at 1000°F. under a stress as low as 15m lb. per sq. inch.

Jan 1, 1944

By Thiago de Souza Amaral

Os aços de alta resistência microligados ao nióbio têm mostrado ser uma boa opção para fabricação de perfis estruturais, utilizando os conceitos já desenvolvidos para a indústria de gás e óleo. Entretanto, a definição das reais necessidades em termos de soldagem desta família de aços não está bem descrita nas normas de soldagem mais utilizadas pelo setor. Este trabalho demonstra uma metodologia de avaliação destes aços, através de simulações térmicas físicas (Gleeble e dilatometria) e ensaios mecânicos de amostras simuladas, de forma a elaborar um atlas de soldagem orientativo para melhor definição das faixas de parâmetros para soldagem deste material. A metodologia proposta foi aplicada a um aço BLAR bainítico da classe 65 ksi. Foi possível determinar com mais segurança a faixa de energia de soldagem recomendada, inclusive quanto à necessidade ou não do uso de pré-aquecimento, e evidenciar que as simulações são comparáveis a soldas reais. Esta abordagem mostrou trazer benefícios, como redução de custos com processo de pré-aquecimento desnecessário.

Aug 17, 2017

By Aly M. Abdel-Rehim

The present work deals with a study of the mechanical activation of processing of Egyptian monazite by its simultaneous ball-milling and pressure leaching in order to improve the recovery of thorium and lanthanides from monazite. Experiments of simultaneous ball-milling and alkaline leaching of monazite contrary to autoclave leaching were carried out in stainless steel ball-mills of cylindrical shape under different conditions of temperature, pressure, time and alkali amount and strength. The ball-mills were heated and mechanically rotated in an electric furnace by means of roll mechanism. The effective rotation speed was fixed at 130 rpm in all tests. The charge of steel balls of different diameters was equivalent to 45% of the total mill volume. Monazite was charged in ball-mill without preliminary grinding. It is found that high rate of monazite leaching by ball-milling leaching method is achieved at lower temperature, shorter time and lower expense of alkali than in autoclaves. The results obtained show that complete recovery of thorium and lanthanides from monazite (99.8%) by simultaneous ball milling and alkaline leaching is attained at 140°C within 2 h. It is concluded that processing of monazite by its simultaneous ball-milling and leaching is mechanically activated and accelerated as a result of grinding action of steel balls that caused the continuous removal of the hydroxide product from reacting particle surfaces. This leads to the exposing of fresh and activated monazite particles surfaces to alkali leach solution and consequently the acceleration of the reaction of monazite processing.

Jan 1, 2006

By Thomas Schuman, Jaan Kers, Lucas N. W. Damoah, Xiangjun Zuo, Lifeng Zhang

"Rapid technological innovation has propelled the use of electronic equipment leading to the generation of more and more waste electrical and electronic equipments (WEEE). Printed wiring board (PWB) is a component made of one or more layers of insulating material with electrical conductors. To investigate an environmentally friendly process to recycle PWBs, PWB samples with and without additives were pyrolyzed. Liquid, gas and solid products were achieved with different conversion fraction. Analysis of the exhaust gases from the experiments using GC-MS and MS showed that without CaCO3 additives poisonous gases such as C6H6 and HBr were produced which were adequately controlled if CaCO3 was added.IntroductionPyrolysis is one of the best methods for treating complex mixtures of waste polymers and to recover the material and energy content. The process consists of thermal decomposition at moderate temperatures in total absence or small amount of oxygen in which the structures of polymers break down into smaller intermediate products "". The decomposition temperature of a substance is the temperature at which the substance breaks up into smaller substances or into its constituent atoms 2). Thermal treatment of PWBs were reported using DC Arc Plasma furnace 3), and fixed bed reactor 4). One drawback in dealing with thermal treatment of PWB scraps is the likely production of super-toxic halogenated dibenzodioxins and dibenzofurans from the bromine containing structures. Pyrolysis of organic materials contained in waste PWBs leads to the formation of gases, oils, and chars which can be used as chemical feedstock or fuels ""'. Dehalogenation of the pyrolysis product of electronic scraps is essential to make it commercially acceptable. It would be obviously the most advantageous solution as pyrolysis and dehalogenation are carried out simultaneously. Reported pyrolysis investigations are at experimental stage and have been carried out in vacuum, molten salt, fluidized bed, rotary kiln, entrained, stationary, and moving bed reactors 7). Comparing to the incineration and combustion of PWBs, the pyrolysis process has several characteristics: 8'"">) 1). Converting the organic solid substance into fuel gas, fuel oil and carbon-black as storage energy; 2) Emitting toxic substances such as sulfur, bromine and heavy metals in wastes; and 3) Keeping metals from being oxidized. Although many researches into the pyrolysis of PWB wastes have been reported, most of the works have been carried out using analytical pyrolysis techniques or very small batch reactors ""~'5). Also, most of the works for the pyrolysis of PWBs haves concentrated on the composition of the organic products, particularly the brominated organics. The current study is to investigate the pyrolysis of PWB powders in a small TG-DTA scale and a 50-gram tube furnace scale."

Jan 1, 2011

By Edmund J. Cardoza

The Detroit Water and Sewerage Department (DWSD) provides water and wastewater services to the Greater Detroit Metropolitan Area. Sewerage is treated at the DWSD Wastewater Treatment Plant (WWTP) located at 9300 W. Jefferson Street south of the City of Detroit, Figure 1. PARTICIPANTS Engineering and design of the project for the DWSD was performed by Harza Engineering Company, Inc., C.C. Johnson & Malhotra, P.C. and their sub-consultants, including Worley Engineering and Wade Trim. The Prime Contractor is a Joint Venture of Traylor Brothers, Inc. and Jay Dee Construction. The shaft drilling and riser installation was performed by The Millgard Corporation in joint venture with the Prime Contractor (MTJD). The selection of specialized drilling equipment and the supervision and performance of the access shaft and riser installations was primarily the responsibility of The Millgard Corporation (TMC).

Jan 1, 2001

By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012

By E. S. Grumell

THE correct sampling of coal and coke is becoming important to an ever increasing number of producers and consumers. This, therefore, may be an opportune moment to examine where we stand with regard to existing and proposed methods. In this paper an attempt will be made to review, as briefly as possible, some of the considerable amount of painstaking research which has been done in the last 10 years, and which has unquestionably led to a much better understanding of the subject. In so doing we shall try, on the one hand, to make clear where substantial progress has been made, and on the other hand, to draw attention to points that require further investigation. The paper is divided into sections in order to emphasize the major divisions of the subject; further, in order to retain this emphasis, detailed consideration of some of the points has been relegated to appendixes. No attempt has been made to give a complete survey of the literature, as this has already been done by L. A. Bushell.2 The following abbrevia-tions will be used: A.E., average error; P.E., probable error; S.W.R., size-weight ratio; B.S.I., British Standards Institution.

Jan 1, 1939

By Scott W. Hazen

This report describes the design, analysis, and results of a special experimental mine-sampling project conducted as part of the Bureau of Mines continuing program on sample-methods research. The experimental project was conducted at the Bureau?s Denver Mining Research Center and at the Climax molybdenum mine within the framework of a cooperative research agreement between the Bureau and Climax Molybdenum Co., Division of American Metals-Climax, Inc. The primary objective of the project was to investigate the interrelation-ship between sample volume, number of samples, the standard deviation of an assay distribution, and the precision required for an estimate of grade of ore, and to develop this interrelationship into a relatively simple method of application for use in mine sampling.

Jan 1, 1962

By Edward Halse

Normal banded structure,* exhibiting bands or layers of mineral symmetrically arranged from the sides to the center of the vein, appears to be by no means common in the Republic of Mexico. When the bands of quartz form interlocking crystals in the center (" comb-structure "), the evidence that the filling has taken place in an open space is complete. This also applies in the case of any mineral the fibers of which are perpendicular to the walls, and which presents here and there, in a central line, cavities or vugs lined with crystals (geodes); but it does not follow that the whole width of the banded vein represents that of the original open fissure. The opening and filling may have been slow and gradual processes, advancing

Jan 1, 1902

By C Vejrazka1

The occurrence of airblasts is one of the principal mining hazards in caving operations between the time of cave establishment and breakthrough of the cave to surface. As such, it needs to be managed continuously and risk assessments need to be reviewed on a regular basis for applicability to changing conditions. The likelihood of an airblast occurring is based on a range of geotechnical factors over some of which engineers on-site only have limited control. However, the impact of an airblast to the underground mine, if it does occur, can be managed by following established safety guidelines for the production from the cave.This paper outlines how the Caving Airblast Simulation Tool in Ventsim was used to determine a risk management strategy for a sublevel and a block cave at a mining operation in Australia. The block cave has a footprint of 14 500 m2 with the extraction level located 1250 m below surface while the sublevel cave currently has a footprint of around 18 000 m2 operating between 660 m and 800 m below surface. Both caves are currently in their early operational periods. The risk analysis provided valuable information for the production planning of the caves including confirmation of extraction ratios for the block cave undercut, locations of airblast walls and maximum allowable air gaps for different muck pile heights to ensure safe operation is achieved.

Oct 12, 2022

The old De Beers mine, which lies northwest of Dutoitspan mine at Kimberley, was the mine which launched Cecil Rhodes (In his historical career. It was the nucleus of the De Beers Mining Co. Ltd., formed in 1880, which later became De Beers Consolidated Mines Ltd. Inactive for more than a half century, the De Beers Mine is being rejuvenated for a new era of operations. Both mines were on the Vooruitzicht farm owned by the De Beers brothers, who had bought it from the Orange Free State Government ten years previously for £50. Although the brothers sold it soon after the discovery of diamonds at Dutoitspan, they are remembered for having given their name to the foremost diamond mining company in the world. Diamonds worth nearly R180,000,000 have come from this ground, and more will be recovered when the mine is re-opened.

Jan 9, 1963

By James E. Hill

TECHNOLOGY is best nurtured by a sympathetic climate that is a composite of many factors. Necessity is a highly motivating factor as illustrated by the abnormal surge of technologic development curing wartime. Other factors include appropriate timing, economic pressures, available personnel, and in some instances, legislative action. Problems of recent concern to mining technology have been the quality and quantity of available technical personnel and the possibilities of restrictive legislation. The quality and quantity of technically trained personnel may be inadequate to meet the rapidly increasing complexity of modern technology coupled with the growing demand for qualified personnel. The question of appropriate training was a subject for debate.2 The curriculum and methods of teaching have changed. Questions have been raised on the relationship of scientist and engineer, interdisciplinary versus specialized curriculum, undergraduate versus graduate training, and the place of the smaller schools versus the large university-research complexes that have developed at some universities. Various aspects of the subject of engineering education for the mining industry were discussed at the meeting on Mining and Mineral Engineering Manpower at the Michigan College of Mining and Technology, November 18-19, 1963. Meanwhile, the trend toward interdisciplinary training gathers momentum as illustrated by the establishment of the School of Engineering Science at Johns Hopkins, the Schools of Engineering and Applied Science at Columbia, Princeton, and Yale, the Division of Engineering and Applied Physics at Harvard and, more recently, the School of Engineering Science at Florida State University which cuts across the conventional areas of civil, mechanical, electrical, and chemical engineering.

Jan 1, 1964

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019