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By John McEwen, Ian R. Jonasson, David H. Watkinson

"Mine Gallen is a zinc-rich pyritic volcanogenic massive sulphide deposit that occurs in a fault-bounded block of intermediate volcanic rocks. The block is completely surrounded at the present erosion level by the eastern part of the Lac Dufault granodiorite. The volcanic succession includes a massive feldspar porphyry that is probably a subvolcanic intrusion, an andesitic flow unit and lapilli tuffs. The latter are variably sericitized and pyritic, especially in the vicinity of the massive sulphide into which they grade.The ore body is predominantly pyritewith local sphalerite contents as high as 20%; minor chalcopyrite and trace galena are disseminated, but are found mainly along late cleavage. Most ore is a breccia of massive to banded pyrite-sphalerite, veined by massive and complexly banded sulphides. These structures formed by repeated blocky jointing, cracking, sealing, healing and annealing as hydrothermal fluid repeatedly passed through a developing sulphide mound. The deposit is interpreted to have grown on the seafloor in a manner similar to active mounds in the Galapagos rift.RESUME La Mine Gallen exploite un gisement de sulfures massifs volcan géniques comprenant essentiellement de la pyrite riche en zinc. Ce gisement se trouve a /'intérieur d’un bloc de roches volcaniques de caractère dacitique a andésitique, limite par failles et entoure de tout cote par la granodiorite du Lac Dufault. La séquence volcanique comprend des coulées andésitiques et des tufs à lapilli ainsi qu'un porphyre feldspathique massif sub-volcanique. Les tufs sont sericitises et pyritises, tout particulièrement au voisinage des sulfures massifs."

Jan 1, 1990

By Jamal Rostami, Richard Kastner, Ahmad Ramezanzadeh

Improving the accuracy of the performance prediction models for hard rock Tunnel Boring Machines (TBMs) is important in estimation of the schedule and cost of tunnelling in related projects. The effects of rock mass on performance of TBMs has been studied extensively, yet due to the complex nature of the process, impact of many parameters influencing machine advance rate are not very clear and there is still room for improvements. More accurate estimates can be obtained by better understanding of operating parameters in various geological conditions and can lead to matching machine specifications with job conditions, optimizing machine performance, and avoiding long delays and downtime for increased productivity. This paper will offer review of two case histories including Queens Water tunnel in New York and KCRC project in Hong Kong. The analysis of the available field data, including the geological back mapping and results of laboratory testing of rock mechanical properties, machine operational parameters and achieved rate of penetration will be presented. This includes statistical analysis of available field data to provide a better understanding of the influence of rock mass properties on performance of hard rock TBMs as well as related formulas to improve performance estimates.

Jan 1, 2005

By E. J. Mayhew

Bentonite and newly discovered deposits of sepiolite, saponite, and hectorite are now being processed and marketed from the Amargosa Valley of Nevada. All of these deposits are large. The bentonite has been known for decades and is the whitest known. The only other sepiolite deposit is in Spain. The only other commercial hectorite deposit is at Hector, California. No other saponite deposit is known. All the components except bentonite are hydrous magnesium silicates. The bentonite is mixed layer Na-Ca. All the materials have characteristics unique to their locale and type, such as high yield point for drilling muds and liquid suspending agents. The sepiolite has geothermal stability. Figure 1.

Jan 1, 1979

By Charles S. Ney

"THE WRITER'S acquaintance with Kootenay King mine is limited to a brief geological excursion in the vicinity. This paper has been compiled largely from maps of J. Sullivan, mine geologist in 1952, kindly made available to the writer by Transcontinental Resources; a 1942 private report by W. L. Brown; and personal communications with J. Sullivan. Remarks on regional geology, and the comparison with Sullivan mine, are specifically the writer's.The Kootenay King mine is situated in the westernmost range of the southern Canadian Rockies at an elevation of 7,300 feet. From the Sullivan Mine at Kimberley, B. C., it lies 19 miles due east. Six miles of this distance are represented by the pronounced topographical and structural gap of the Rocky Mountain Trench. Mineral claims were locat-ed in the area prior to 1898. The deposit was first seriously explored in the late 1920s, and a small orebody was then outlined and developed. Mining and milling were undertaken in 1951.52. The orebody, amounting to about 14,000 tons, was mined out, and no significant new ore was revealed.The orebody is a replacement of dolomitic argillite by fine-grained galena, sphalerite, and pyrite. The sulphides are finely laminated in the direction of bedding, following out minor folds faithfully. The grade of ore estimated from diamond drill holes (W. L. Brown, 1942) was 11 ·I per cent zinc, 11 ·I per cent lead, and 3·8 ounces per ton of silver. The mineralized zone extends about 250 feet horizontally, 160 feet vertically, with a width of six to twenty feet.General GeologyThe country rocks are sediments of the Aldridge formation of late Precambrian age. For several thousand feet stratigraphically above and below the mine, the formation consists mainly of thinly laminated argillite and siltstone. Several horizons contain appreciable carbonate. About 2,800 feet stratigraphically below the mine, predominantly dolomitic beds mark the top of the underlying Fort Steele formation. The medium-bedded fine quartzites, which characterize about 10,000 feet of the Middle Aldridge in the Purcell range, have a restricted development amounting to only 2,000 feet in the Rocky Mountains. This member is about 2,200 feet above the mine horizon."

Jan 1, 1949

By R. M. Schuster

This study attempts to compare the costs of transporting coarse coal by pipeline, versus the more conventional use of belt conveyors. Hydraulic conveying of crushed (not pulverized) coal has not had widespread commercial acceptance. However, there is little doubt that the technology is available, so that, should this method be proven economical for a given application, implementation of this technology will become more acceptable. Hydraulic transport by pipeline between the mine stockpile and the coal preparation plant, for distances normally considered practical for an overland belt conveyor, should be an ideal application. In this application there is no need for dewatering facilities at the receiving end of the pipeline, because, the receiving screens at the plant serve this purpose. Further, clarified water from the preparation plant can be recirculated back to the mine, a plus for water resource and environmental considerations.

Jan 1, 1982

By W. C. Lacy

Urban development in semi-arid portions of the Southwest has upset a natural balance of geological conditions resulting in broad-scale and local subsidence or heaving ground conditions, Subsidence can be traced to two general causes: irrigation of reclaimed desert lands that have dry, low-density soils; and depression of the water table by ground water withdrawal. Accumulation of weathered volcanic tuff produces areas with swelling characteristics. Soil and subsidence studies made in the Tucson area in Arizona illustrate foundation problems typical of the Southwest that must be considered in the design of building codes. Anticipation of problems and the adoption of corrective measures in the design of engineering structures, establishment of pertinent building codes, and urban planning and zoning to obtain optimum land usage and conservation of natural resources demands a thorough understanding of geological conditions of a developing urban area. In the arid to semi-arid southwestern United States erosional and depositional processes result in special situations that require special precautions in building practices. A series of studies currently underway in the Tucson area, prompted by foundation failures and breaking of buried service lines, serves to illustrate some of these relationships between the geological environment and history and engineering problems. ENVIRONMENT The desert region of the Southwest is characterized by isolated mountain ranges rising abruptly from low valleys or plains — the ranges generally occupy less area than do the intervening valleys. In southern Arizona the valley floors step up from near sea level to 2000 ft or more in elevation, and the ranges may rise to over 7000 ft. Desert and steppe-type climates predominate — climate is controlled more by elevation than it is by latitude. Both climate types are characterized by a lack of precipitation, the former more so than the latter. Practically all the rain that falls in the region evaporates; runoff or recharge generally occurs only during the wettest period. Water table levels are generally being depressed. Vegetation is restricted and consists mainly of creosote bush, cacti and sage brush on the deserts, and mesquite, pinon juniper and various types of grass on the steppes. Precipitation varies from about 3 in. on the warm deserts to about 12 in. on the steppes. Most of this falls in the summer or winter, with only rare storms in other seasons. Summer thunderstorms, often accompanied by hail, bring cloudbursts which send torrents of water streaming down the mountains onto

Jan 1, 1964

By F. Aurelian

The Banat district in Romania was an important uranium mining area for the last 45 years until its closure in 1997. Uranium was present as finely dispersed pitchblende into solid bitumen lens and layers. Due to the mining activities, radioactive wastes have been disposed of in different places of the Banat area. These sites contain uranium, radium and radon and exhibit high contamination potential for environmental receptors (soil, air, waters, sediments and vegetation). Therefore the risk for human health through external and internal irradiation is considered high. The main pollution sources in this uranium mining area are mine and surface waters, waste and low grade ore heaps, dumps as well as release of radon. In this paper studies concerning recognition of pollution sources, delimitation of maps, uranium and radium solubilization and migration from dumps as well as environmental contamination of specific areas related to exploitation and exploration are presented. The risk assessment is based on the relationship ?source-pathway-target? in order to assess environmental risks and identify targets for rehabilitation. The sources causing significant contamination problems were identified by examining the pollutant linkage. The remediation plan for the Banat uranium mining complex involves mine flooding, treatment of water and leachates, as well as modification of heap slopes, application of covers and establishment of vegetation.

Jan 1, 2005

By Patrick K. Wong, Richard Kelly

"The variability in strength and compressibility of in situ deep soil mixing products can be greater than the variability of the natural soil. However, satisfactory performance can be achieved by careful construction and an appropriate QA/QC program. This paper presents a case study on the use of deep dry soil mixing columns to support several embankments over soft clay along a highway project. Post-construction settlement monitoring indicated that good performance is achieved where the acceptance criteria are met, except in an area with high organic content. Embankments with contrasting performance are compared to the quality control test results which comprised laboratory testing of core samples as well as in situ test results such as pull-out and push-in vanes and conventional cone penetration tests. Drawing on the performance results and quality control testing, discussions and guidelines are given on quality assurance acceptance criteria and construction control testing regime for future projects.INTRODUCTIONBetween 2008 and 2012, the largest deep dry soil mixing (DSM) contract during that time in the southern hemisphere was carried out for the Ballina Bypass project. The project, comprising 12 km upgrade of the Pacific Highway located in northern New South Wales close to the border of Queensland, was commissioned by the Roads and Maritime Services (RMS) of NSW. The ground improvement contractor was Keller Ground Engineering (KGE) Australia. Seven different types of ground improvement techniques were employed for the project, ranging from low embankment strategy with nominal preloading, to surcharge with wick drains, light weight bottom ash fill, DSM, vibro-replacement stone columns, dynamic replacement, and vacuum consolidation (installed by Menard Bachy Pty Ltd). Different techniques were chosen depending on time program, cost, and performance requirements relative to proximity to piled structures (e.g. bridge abutments) and post-construction settlement and differential settlement for either rigid or flexible pavements at different locations.DSM was the most utilized ground improvement technique employed on the project, comprising a total of about 285 km of 0.8 m diameter columns to depths up to 18 m for the purpose of supporting bridge approach embankments and culverts with embankment heights up to 6 m. DSM was chosen due to the very soft nature of the clay soil with moisture content practically at liquid limit, and the relative speed and economy of the system. Dry cement powder at rates of 160 kg/m3 to 200 kg/m3 were pneumatically discharged via the hollow stem of the mixing tool, and mixed with the soil (using multiple horizontally mounted paddles on a single vertical stem) at high speed as the mixing tool is withdrawn."

Jan 1, 2015

ON Oct. 5, 1926, the day before the general ses-sions of the fall meeting of the American Insti-tute of Mining and Metallurgical Engineers at Pittsburgh, a round table conference on the combus-tibility and testing of coke was held at the Bureau of Mines Experiment Station. There were about fifty present, with A. C. Fieldner, chief chemist of the Bureau of Mines, as chairman. The following organi-zations were represented: American Institute of Min-ing and Metallurgical Engineers, American Society for Testing Materials, American Gas Association, Eastern States Blast Furnace and Coke Oven Association, Gas and Fuel Division of, American Chemical Society, and Southern Ohio Pig Iron and Coke Association. In opening the proceedings, Mr. Fieldner explained that the meeting had been called at the suggestion of several members of the Institute and members of other organizations. The subject is of interest to the pro-ducer and the user of coke whether it be in a blast furnace, cupola furnace, house-heating furnace, open grate, gas producer, or in a water-gas generator. There has been much confusion on this subject largely because there is no common definition of combustibility. Does the blast-furnace superintendent, the coke-oven operator, and the fuel engineer have the same under-standing of the term "combustibility"? If a common understanding can be reached, many differences of opinion will disappear. COMBUSTIBILITY OF COKE R. H. Sweetser of Columbus, Ohio, disagreed with the statement of P. H. Royster, T. L. Joseph, and S. P. Kinney in Reports of Investigations, Serial No. 2524, of the Bureau of Mines, in which it was stated that the coke-oven op-erator cannot change coke combustibility by modifying oven practice. Mr. Sweetser held that the coke-oven man can change the combustibility of coke. Blast-furnace men know that coke that will burn easily with low pressure and will. come down in the regular way in the furnace can be pro-duced from a given mixture of coal. His idea of the combustibility of coke is the rate of flow through the com-bustion zone of the blast furnace. If the coke does not pass through in normal manner it is highly incombustible. H. J. Rose of the Koppers Co., Pittsburgh, objected to being pinned down so closely on this phase of the com-bustibility and incombustibility of coke. Coke-oven men are frequently obliged to change oven conditions to make a coke which gives blast-furnace men what they want. The size of the coke and the screening have an important bear-ing on combustibility, and there are many cases on record where by simply changing the different sizes of the coke, everything worked smoothly, and that is a much more combustible coke.

Jan 1, 1927

By Charles Means

A THOROUGHLY modern coal-handling system has been installed at the Pittsburgh Terminal R. R. & Coal Co.'s new No. 8 shaft, or Coverdale mine, about 11 mi. (17.7 km.) from Pittsburgh on a spur f the Montour R. R. The Pittsburgh seam, which is the one worked, is reached at a depth of 342 ft. (104 m.). Power is delivered to the mine at 22,000 volts over a transmission line of the bow-arrow type of construction. A private telephone line connecting the various mines and the main office in Pittsburgh is carried on the same poles. The high-tension line is brought to an outdoor, step-down, transformer substation, where three 833-kv.-a., single-phase, 60-cycle, oil-insulated, self-cooled transformers reduce the potential to 2300 volts. The transformers are protected by electrolytic, aluminum-cell lightning arresters, horn gaps, and choke coils. High and low-tension busses, together with fuses, choke coils and air-break horn-gap switches with their remote-control operating mechanism are mounted on a substantial structural-steel tower 25 ft. (7.6 m.) in height. MINE SUBSTATION The transformer substation is adjacent to a pressed-brick building that houses direct-current substation equipment together with switchboards, etc., for the control and distribution of power. This building also contains the hoist for the men and supplies.

Jan 9, 1921

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By B. K. Gorain

"Mining of low grade deposits along with the necessity to design and operate flotation plants with high throughput presents unique metallurgical and environmental challenges that need to be addressed to reduce project risks, improve project economics and to sustain the profitability of operations over the life of a mine.Some of the key challenges include poor recovery of valuables and concentrate quality issues due to complex mineralogy, the need to use poor quality water such as brackish or sea water, reduce environmental impact from the process, integrate flotation with hydrometallurgy to maximize precious metals recovery, escalation of capital and operating costs, use of unproven technology and constant use of larger equipment, high ore variability, worldwide constraints on resource availability and an ever increasing need for reliable metallurgical input to financial models to evaluate economic viability of projects.The need to develop effective solutions to these problems in a short time frame is becoming a key to the success of any new project and for sustaining the profitability of a mining operation. An integrated multi-disciplinary approach to problem solving is crucial with the need for a more lateral thinking along with strategic partnerships and collaboration involving the right players. This paper presents some of the key findings based on experiences from a large number of challenging projects and operations focused on solving complex flotation problems.INTRODUCTIONThere are various challenges to successful development of mineral resources. Most of the ore bodies being developed worldwide are of lower grades requiring high throughput to be economical. Many of these lower grade ore bodies have significant occurrences of deleterious and penalty elements that could render a deposit unworthy of development unless there are technological solutions to process them economically in a sustainable manner with minimal environment impact. Even in a high metal price scenario, the economics for some of these low grade ore deposits is marginal. From a metallurgical perspective, these ore bodies have complex mineralogy and use of any off-the-shelf technology is not always effective. Development of innovative processes are often required, which is expensive, time consuming and sometimes risky.This paper will provide a broader perspective on the steps involved in solving flotation problems for operating plants and for greenfield development projects. In addition, some of the key challenges in flotation of complex low grade ore bodies along with the economic benefits in developing solutions to these problems will be presented."

Jan 1, 2013

By P. J. Foster

A common theme running through recently introduced mining health and safety legislation in many parts of the world is risk assessment. Most recently, risk assessment legislation has been introduced across the mining industry of South Africa and the view that the introduction of risk assessment based legislation provides an ideal opportunity to improve on past health and safety performance is presented. Risk assessment techniques range from highly complex safety system techniques that are used in high technology process industries, to subjective techniques based on simple judgements that are finding use in many other industries. The objective of this paper is to shed some light on risk assessment, not by detailing the risk assessment process but by identifying the crucial elements that need to be considered if risk assessments are to be successful in changing health and safety performance. A case study is presented illustrating the introduction of risk assessment into the Ingwe Coal Corporation, one of South Africa?s largest mining houses, to indicate how the system was developed and how it is being used.

Jan 1, 1998

By S. J. Sindeband

Prior to discussing the metallurgy of sintered chromium borides, it is pertinent to outline some of the reasoning behind this investigation and the purposes underlying the work. This study was initiated as an aproach to the ubiquitous problem of a material for service at high temperatures under oxidizing atmospheres, and it was undertaken with a view to raising the 1500°F (816°C) ceiling to 2000°F (1093°C) or better. For the reason that no small, but rather a major, lifting of the high temperature working limit was being attempted, it was felt appropriate that a completely new approach be taken to this problem. A summary of the thinking behind this approach was published recently by Schwarzkopf.' In briefest terms, it was postulated that the following requirements could be set up for a material which would have high strength at high temperatures. 1. The individual crystals of the material must exhibit high strength interatomic bonds. This automatically leads to consideration of highly refractory materials, since their high energy requirements for melting are related to the strength of their atom-to-atom bonds. 2. On the polycrystalline basis, high boundary strength, superimposed on the above consideration, would also be a necessity. Since this implies control of boundary conditions, the powder metallurgy approach would hold considerable promise. Such materials actually had been fabricated for a number of years, and the cemented carbide is the best example of these. Here a highly refractory crystal was carefully bonded and resulted in a material of extremely high strength. That this strength was maintained at high temperature is exhibited by the ability of the cemented carbide tool to hold an edge for extended periods of heavy service. Nowick and Machlin2,3 have analytically approached the problem of creep and stress-rupture properties at high temperature and developed procedures whereby these properties can be approximately predicted from the room temperature physical constants of a material. The most important single constant in the provision of high temperature strength and creep resistance is shown to be the Modulus of Rigidity. On this basis, they proposed that a fertile field for investigation would be that of materials similar to cemented carbides, which have Moduli of Rigidity that are among the highest recorded. The cemented carbide, however, does not have good corrosion resistance in oxidizing atmospheres and without protection could not be used in gas turbines and similar pieces of equipment. It would be necessary then to attempt the fabrication of an allied material based upon a hard crystal which had good corrosion resistance as well. It was upon these premises that the subject study was undertaken and at an early stage it was sponsored by the U.S. Navy, Office of Naval Research. Since then, it has been carried on under contract with this agency. Chromium boride provided a logical starting point for such research, since it was relatively hard, exhibited good corrosion resistance, and, in addition, was commercially available, since it had found application in hard-surfacing alloys with iron and nickel. That chromium boride did not provide a material that met the ultimate aim of the study results from factors which are subsequently discussed. This, however, does not detract from the basis on which the study was conceived, nor from the value of reporting the results which follow. Chromium Boride While work on chromium boride proper dates back to Moissan,4 there has been a dearth of literature on borides since 1906. Subsequent to Moissan, principal investigators of chromium boride were Tucker and Moody,5 Wede-kind and Fetzer,6 du Jassoneix,7,8,9 and Andrieux." These investigators were generally limited to studies of methods of producing chromium boride and detennining its properties. Some study, however, was devoted to the chromium-boron system by du Jassoneix,7 who did this chemically and metal-lographically. This system is not amenable to normal methods of analysis by virtue of the refractory nature of the alloys involved, and the difficulties of measurement and control of temperature conditions in their range. Dilatometric apparatus is nonexistent for operation at these temperatures. Du Jassoneix made use of apparent chemical differences between two phases observed under the microscope and reported the existence of two definite compounds, namely: Cr3B2 and CrB. These two compounds, he reported, had quite similar chemical characteristics, but were sufficiently different to enable him to separate them. The easiest method for producing chromium boride is apparently the thermite process, first applied by Wede-

Jan 1, 1950

By A. Blake Caldwell

The Anaconda Company, an organization of mining people, enters a new world of copper production as it brings on stream its recently constructed Twin Buttes operation some 25 miles south of Tucson, Ariz. Twin Buttes comprises the largest earth-moving task performed in the history of mining. Some people liken this job to moving enough earth and rock to complete the famed Aswan High Dam in Egypt. In all, some 236 million tons of overburden and rock were removed from over the ore deposit.

Jan 1, 1970

By De Jong HJ

During the forthcoming reline of No.3 Blast Furnace at the Newcastle Steelworks of the Broken Hill Proprietary Co. Ltd., facilities for the screening and weighing o' coke will be installed. The equipment is needed to optimise the sizing and the quantity of coke immediately prior to it being charged to the furnace. Up till the time the furnace was blown out in November, 1982, coke was charged to the furnace by volume, ie by skip fulls only. This resulted in variation to the ore/coke ratio charged due to bulk density changes and erratic skip filling levels. This in turn affects the heat balance of the furnace and causes fluctuations in hot metal chemistry and temperature. A coke rate penalty has to be paid also. Coke layer thickness in the furnace burden cannot be controlled closely, resulting in loss of control over gas distribution in the furnace. A grizzly type screen was incorporated in the skip loading chute but this ineffective method left a great amount of fines with the coke being charged to the furnace. Furnace permeability was therefore reduced, particularly in the hearth.

Jan 1, 1984

By V. V. Zubkov

The systems of geophysical monitoring have been already put into operation at coal mines and ore mines. Since at present it is rather difficult to conduct mine experiments; it is necessary to start a new step in joining of geomechanics and seismic. The linking geomechanical and geophysical monitoring at coal mines and ore mines today became possible due to progress in development of numerical methods of modeling of stress state and technology for processing of seismic information. This paper describes one potential step in linking geomechanical and seismic monitoring at coal mines and ore mines.

Aug 1, 2013

By P. Cavanagh

Summary This paper discusses the fundamental principles which allow the development of a new method for studying the deformation and failure of metals in terms of 'internal microstrains'. Internal microstrains mechanical and magnetic properties are defined and their influence on of metals is outlined. A research programme at present in progress will determine whether magnetic measurements of internal microstrains give sufficiently accurate values for predicting the performance of metals under service conditions. These magnetic test techniques are also being used to detect the beginning of plastic deformation and to trace the development of deformation processes and failure. Results of the experimental work in each field will be published. Introduction Any attempts are being made to develop a complete theory embracing the mechanical behaviour of metals. In spite of the amount of experimental data available, the theoretical approach is rather difficult, since most of the mechanical properties of a metal are determined by deviations from the pure chemical composition or the perfect crystal. Both types of deviation are difficult to reproduce experimentally and to describe theoretically. In general, there are three main avenues of approach to the problem being followed today.

Jan 1, 1950

By K. C. Li

The scope of this subject is a broad one. The demand for a metal with high refractory properties, great strength at elevated temperatures and high nuclear cross section, has put tungsten in the foreground as: the most promising metal to fill some of these requirements. Recently developed techniques have made it possible to roll large tungsten sheet and-the availability of fabricated tungsten is already upon us. More and more, the demand is for purer and still purer metals. Tungsten is no exception. As technology improves, we are learning more about the effect of foreign elements in minor amounts upon the chemical and physical properties of metals. As equipment and technology improve, specifications become more rigid, and reasonably so. Pure metals have revealed properties hitherto unknown in metals produced by former technology.

Jan 1, 1961

By J. B. Mackintosh

The general method which has been followed since the time of Heinrich Rose, and perhaps before, for the determination of phosphorus in iron and steel, is to dissolve the sample either in nitric acid, aqua regia, or some other oxidizing agent, in order to convert the phosphorus into phosphoric acid. In 1832 Rose* recommends HNO3, or aqua regia, preferably the former. Wohler, in 1854,† directs that the iron should be oxidized by burning in a stream of oxygen for the determination of carbon, and the resulting oxide of iron containing all the phosphorus as phosphoric acid be treated as an ore. In the fourth English edition of Fresenius' Quantitative Analysis,† pp. 666-667, we find directions to dissolve the iron in aqua regia or bromine; and, coming down to more recent times, we find F. A. Cairns § directing the employment of a boiling solution of potassium chlorate and hydrochloric acid for the oxidation and solution of the sample to be analyzed. It is unnecessary to multiply quotations from the literature of the subject, though they might be extended almost inclefinitely, since it would only be a repetition of the above mentioned series of methods in one form or another; and the references given have been selected to show how little essential variation there is in the type-methods of solution used. In fact it seems to be universally accepted as a necessary first step in the determination that some such method of solution should be followed. One chemist, however, struck out on a different line of thought, and to the Lest of my knowledge only one, M. V. Tantin, who, in

Jan 1, 1886