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By E. H. Crabtree, T. G. Chapman, V. W. Winters

IN 1939 one of the authors* described advances in carbon-cyanidation for the period 1932 to 1939 • T. G. Chapman: A Cyanide Process Based on the Simultaneous Dissolution and Adsorption of Gold. Trans. AIME (1939) 134, 207. and included: (1) the dissolution of gold in an ore pulp by cyanide and its simultaneous adsorption by carbon, (2) the stage addition of adsorptive carbon and its movement countercurrent to the flow of the ore pulp, and (3) the recycling of adsorptive carbon. Considerable additional experimental and pilot plant work have been done by the authors since 1939 and the results of such work E. H. CRABTREE, JR., Member AIME, is Director of Milling, Eagle-Picher Mining and Smelting Co., Miami, Okla., V. W. WINTERS is Superintendent, Sahuarita Concentrator, Eagle-Picher Mining and Smelting Co., Tucson, Ariz., and T. G. CHAPMAN, Member AIME, is Dean, College of Mines, University of Arizona, Tucson. AIME Sun Francisco Meeting, February 1949. TP 2744 B. Discussion (2 copies) may be sent to Transactions AIME before March 31, 1950. Manuscript received March 3, 1949. have been sufficiently encouraging to justify a second paper. Developments from 1939 to 1948: In 1941, Verne W. Winters did the first experimental work in eliminating agitation during dissolution and adsorption and thereby demonstrated that the dissolution of gold by cyanide and its simultaneous adsorption by carbon take place essentially to completion in a stagnant pulp. Shortly thereafter, and as a result of the stagnant pulp experimental work, Winters and Chapman demonstrated that soluble gold, in a cyanide ore pulp, would migrate from the ore pulp through a perforated container and be adsorbed by carbon within the container. During the same year, the Eagle-Picher Mining and Smelting Co. erected a 25-ton capacity pilot plant at the Harquahala mine about 9 miles from Salome, Ariz. Experimental work at this plant comprised chiefly the stagnant pulp modification of carbon-cyanidation although considerable work was done in the grinding and activation of carbon, and testing various methods of extracting adsorbed gold from carbon. Soon after the completion of the Harquahala

Jan 1, 1951

By S. J. Ma

With the very effective depressant and collector developed by China Bluestar Lehigh Engineering Corp (hereinafter referred to as LEHIGH), satisfied results are obtained from laboratorial beneficiation tests on phosphate samples from Karatau, Republic of Kazakhstan by the direct flotation process. In this paper the effect of single factors on performance of flotation is studied and their applicable ranges are proposed. The final test results are described as follows: As the feed contains 23.20 % P2O5, and 3.96% MgO, a phosphate concentrate assaying 29.77%P2O5 and 1.54% MgO is produced, and the P2O5 recovery in concentrate is 88.28%. The beneficiation tests make it possible to simplify existing technology with fine grinding-desliming, followed by reverse & direct flotation system and consequently improve the concentrate grade and recovery for the future beneficiation plant

Jan 1, 2014

(Under this heading will be published notes sent to the Secretary of the Institute by members or other persons. ) An experienced gold and silver metallurgist. specializing in cyaniding is desirous of obtaining a position in America. Speaks Me icon Spanish fluently. A member, a technical graduate, with four years' experience in railroad work and general construction, two years' on mine examination and geological reconnaissance, and two a half years' drilling exploration in placer work and petroleum, together with prospecting and geological interlope-tion, desires a position as a mining engineer or mining geologist. An experienced mine superintendent, manager, or field engineer, is open for engagement. Ire has had 12 years' experience as superintendent and manager of large mines in the United States and Mexico, and experience in mine examination. A member of the Institute with several years? experience in mining in the Lake Superior copper district, is open for engagement. A member, at present in the Southeast, desires a position as assistant superintendent or assistant. manager with a mining company operating in Washington or Alaska. Experienced assayer and engineer.

Jan 7, 1913

By Heinrich CA, Wall VJ, Walshe JL

The Porgera Gold Mine, located in the highlands of Papua New Guinea, has produced over 5 million ounces of Au, since its opening in late 1990. The deposit is located within Upper Cretaceous Papuan Platform sediments approximately 25 km south of the Lagaip Fault, and is spatially and temporally associated with the 6 Ma alkaline Porgera Intrusive Complex.

Jan 1, 1995

Coal-bearing beds underlie 23,000 square miles, about one third of Missouri's total area. Twelve out of more than twenty named coal seams have been or are being commercially mined. The remainder are too thin for commercial production. The coal is high volatile bituminous, with reserves estimated to be six billion tons, 1.24percent of U.S. coal reserves. Coal-bearing strata are generally thin seams which can be up to five feet thick. Typically, mined seams are about 28 inches thick. Coal deposits were first mined in Missouri in the 1840s, with the coal used primarily for domestic heating and blacksmithing. Production increased with the introduction of steamboats on the Mississippi. Coal production in 19 17 was six million tons. Production has steadily declined from a high of nearly seven million tons in 1984 to 2.3 million tons in 1991. Declining production is the result of several factors, including competition from other energy sources and the high sulfur content of Missouri coal. Today, coal-fired electric generating plants are the biggest consumers of Missouri coal. The Missouri regulatory program was conditionally approved November 21,1980, and fully approved January 17,1983. Its Abandoned Mine Land program was approved January 29, 1982.

Jan 1, 1992

By Pieter Steeneklm, Mazi’ Rejaee

"EXECUTIVE SUMMARYThe automotive industry's search for increased fuel efficiency through component weight reduction has driven the growth in consumption of magnesium metal in the form of die cast alloys. This trend, which began in North America and should soon accelerate in Europe, will require enhanced recycling services since each tonne of metal used for die cast parts production produces about 500 kg of scrap.Currently, the European die cast market is plagued by very high tolling prices for scrap recycling due to lack of competition and high transport costs due to the distances between the scrap generator and the recycling facility. This situation clearly increases the cost of magnesium die cast components and reduces magnesium's competitiveness with other materials. The challenge for the magnesium industry in the short term is to provide cost ·effective recycling solutions for the die cast industry. In addition effective recycling, in the medium to long term, is needed for the anticipated large volumes of secondary or used scrap that will become available as the die cast components reach the end of their life cycle. This paper will present The Antheus Integrated Magnesium Project as a Novel approach addressing some of the key recycling related issues facing the magnesium industry, in particular the die casters. The paper outlines the many advantages of an integrated magnesium metal park, in an overall goal of increasing magnesium metal's competitiveness."

Jan 1, 2000

By Moxon N. T

A series of low shock energy water resistant emlulsion based explosives have been developed by combining inert materials, such as Perlite P500, into the formulation. The material handling, water resistance and explosive properties of these mixtures were determined as a function of inert additive type, density, charge diameter and emulsion base. Of the emulsion bases tested Emulite produced the best and most stable low density mixtures ranging in density from 0.8 to 1.35 g/cm3 producing velocity of detonations (unconfined) ranging from 3000 to 5500 nits. The mixtures could be detonated successfully at these densities at diameters as low as 25mm. Low shock mixtures formed by combining Emulite with Perlite P500 were successfully trailed at the Cadjebut zinc mine in Western Australia. The performance of the explosive, at three densities, was monitored using both continuous and point to point VOD techniques. The fragmentation produced by the blasts were compared by photographic analysis. During this trial the low shock emulsion mixtures were shown to be as effective as the currently used explosives (packaged emulsion) at a significantly reduced cost.

Jan 1, 1990

By R G. Barker

The NZ Minerals Industry Association has continued to advance the interests of the minerals sector through leading the establishment of a Minerals Industry Advisory Committee, and the preparation of a technology strategy with funding assistance from the Foundation for Research, Science and Technology. The current moves mirror those of more than 30 years ago when a government initiative led to a resurgence of exploration through amending the mining legislation, redirecting Government research priorities and tax changes. The economic and political and commercial environment in 2001 is very different from that of the 1960s and success of these new initiatives depends on the continuing support and involvement of all sectors of the minerals industry, and building an improved relationship with the Government and the public.

Jan 1, 2001

By M. Holuszko, I. Mikhalev

"Previous studies described by Galvin et al. (2017) have shown that for Australian bituminous coal fines, both in batch and in continuous process, the new improved oil agglomeration procedure based on the use of high-internal-phase (HIP) emulsions, as compared to the conventional “pure oil” agglomeration process, enables a significant reduction in the amount of oil while reaching a high yield of clean coal (approximately 90% of agglomerates greater than 355 µm in size) in a significantly shorter time. The HIP emulsion used in these experiments comprised up to 95% vol. aqueous solution of sodium chloride (3% wt. concentration) and for the rest, a mixture of kerosene (oil) and sorbitan monooleate (SMO emulsifier) in a 1:1 ratio as a binder. This study evaluates the applicability of the new HIP-oil agglomeration process to treat Canadian bituminous ultra-fine coal and Russian sub-bituminous coal fines and compares results from agglomeration to the flotation response of both coals. Oil agglomeration is known to be sensitive to surface properties of coal. Since surface properties of coals depend not only on the rank of coal but also on their origin (depositional environment) and mineralogical composition, both the applicability of this new improved agglomeration process to the non-Australian coals and its efficiency became the motivation for this study. To evaluate the applicability of the new process to both Canadian bituminous and Russian sub-bituminous coals, a series of bench-scale tests were carried out under conditions similar to those described by van Netten et al. (2016) for the Australian coals. Based on the results obtained in this research, new boundary conditions for the application of the HIP emulsion-based oil agglomeration process have been outlined and conclusions on the viability of the new process to treat ultra-fine coal from Western Canada and Russian sub-bituminous coal fines have been reached.INTRODUCTION In most cases, to meet the market requirements, the mined coal has to be processed to reduce the ash content by the removal of mineral matter and thus to increase the quality of the coal products (van Netten et al., 2016). Generally, flotation is used for processing fines from high rank coals; however, there are high losses of very fine coal due to the inefficiency of this process. Furthermore, difficulty in dewatering the fine coal results in excessive moisture levels causing coal handleability issues, which increases costs in the coal-cleaning industry (Capes & Darcovich, 1984). Much of the development that has occurred in fine coal cleaning has taken place with higher-value coal, often metallurgical (Klima et al., 2012). If the fine coal is deemed to be too difficult or expensive to process, it may be discarded as waste (van Netten et al, 2014). Such disposal not only creates an environmental liability but may also result in the loss of a valuable, high quality product that is better liberated than the coarser fractions of coal."

Jan 1, 2018

By P. B. Barton, P. M. Bethke, R. O. Rye

Rhyolitic welded-tuff wallrocks of the epithermal base and precious metal veins of the Creede district were pervasively altered by the addition of more than two billion metric tons of potassium some 1.5-2 million years before mineralization. Sodium, calcium and magnesium were strongly depleted, yielding a nearly binary quartz + potassium feldspar assemblage containing as much as 13 weight percent K 0. This large-scale metasomatism, originally noted by Steven and Rattle (1965), took place progressively by initial alteration of plagioclase phenocrysts to orthoclase or microcline followed by alteration of the groundmass feldspar to orthoclase and gradual change of the sanidine phenocrysts to more Or-rich compositions. Oxygen isotope and chemical studies show that the metasomatism resulted from the interaction of the tuffs with deeply circulating heated ground water and suggest that the potassium metasomatism of rhyolitic rocks is the facies equivalent of propylitization of volcanic rocks of more basic composition.

Jan 1, 1985

By Anatoly F. Usov, Vyacheslav A. Tsukerman

"The Russian scientists have developed a new energy saving method for an efficient destruction of the sturdy and hard materials (rocks, ores, frozen soils, concrete blocks ets.) - the Electric Pulse Discharge method of materials destruction (EPD). The detailed researches of a broad circle of problems connected to development EPD-disintegration of materials of a various nature and area of use are executed. The electrical and power characteristics of process, physical fundamentals of selectivity of a breakdown and destruction are investigated, the means of electric pulse splitting and refinements of materials are developed, the technological efficiency of disintegration of industrial minerals estimated.One of the most important characteristics of the EPD-disintegration of ores is the high selectivity of destruction, which provides a large ratio of useful minerals' grains opening, and at the same time, it destroy them less. This ensures in the subsequent stages of beneficiation of ores considerable increase of the extraction and improving the quality of concentrates.The technological tests of various industrial minerals have shown a possibility the EPD-disintegration, as a process that provides the best efficiency of disclosure of useful minerals in all types of ores. Technological and economic efficiency of the method of ore beneficiation is the highest for difficult beneficiated ores with rather low extraction by existing methods. The increase of extraction in this case can reach several percents. As a rule, at a EPD-disintegration the disclosure of mineral grains happens in earlier stages of material comminution than at a mechanical comminution, and with less damage of products. This promotes a simplifying the process of ore preparation and for reducing the power consumption."

Jan 1, 2003

By J. G. Pharoah

Over the last two decades a variety of models for solid oxide fuel cells (SOFCs) have emerged ranging from one dimensional (1-D) to 3-D models, from steady-state to transient models; single- and half-cell and entire stack models. A majority of these models have focused either on the transport processes or on the chemical/electrochemical processes. The approach taken by our research group is to develop a comprehensive SOFC model framework based on the considerations of detailed electrochemical reaction mechanism and by accounting for complex transport processes occurring in the porous media at the micro-scale level. In this paper, we review the state-of-the-art in SOFC modeling and identify the existing gaps that need to be filled in.

Jan 1, 2005

By James R. Hein

Manganese nodules form at the sediment surface of abyssal plains throughout the global ocean at water depths of about 4000-6500 m. The nodules form a continuum from purely hydrogenetic (all metals from seawater) to purely diagenetic (all metals from sediment pore waters), which will determine which metals of potential economic interest are enriched in the nodules. Another important factor in metal enrichment is whether diagenesis in the bottom sediment is oxic or suboxic. There are several nodule fields in the deep ocean that have received much attention with regards to economic potential, the most important being the Clarion-Clipperton zone (CCZ) in the NE Pacific, where the International Seabed Authority (ISA) has signed 12 contracts for exploration areas, each spanning 75,000 square kilometers. Those nodules are rich in nickel (mean 1.3 wt. %), copper (mean 1.1 %), and manganese (28%), with moderate amounts of cobalt (mean 0.2%), molybdenum (587 g/t), and lithium (129 g/t). A conservative estimate is that there exists 21,100 million dry tonnes of nodules in the CCZ, yielding more manganese, twice the nickel, three times the cobalt, and four times the yttrium than the entire land-based reserve base (economic plus marginally economic plus subeconomic reserves) for each metal. Total rare-earth elements (REEs) as oxides average 0.09% in CCZ nodules, a potential byproduct even at that grade because the heavy REE complement averages 26%, compared to less than 1% for the large land-based carbonatite REE deposits. The price for HREEs is much greater than for the light REEs. For comparison, the REEs in deep-ocean ferromanganese crusts are 3 to 5 times greater than nodules and the HREE complement averages 18%. Of the 12 CCZ contracts, 7 are with States (China, France, Germany, Japan, Korea, Russia, and a group of States (IOM); and 5 are with companies: G-Tec Sea Mineral Resources NV, Nauru Ocean Resources Inc. (NORI); Tonga Offshore Mining Ltd (TOML), UK Seabed Resources Ltd (Lockheed UK), and Marawa Research and Exploration Ltd. Three other nodule fields that have received attention are in the Peru Basin, which has nodules very rich in manganese (34%) and lithium (mean 311 g/t), the Penrhyn Basin (Cook Islands Exclusive Economic Zone), with nodules very rich in cobalt (mean 0.4%); and the Central Indian Ocean Basin (CIOB), where India has an exploration contract with the ISA. CIPB nodules have mean nickel, copper, and manganese contents of 1.1%, 1.0%, and 24% respectively.

May 1, 2013

By Richard L. Ash, J. H. Kelley, W. H. McCracken, William Bellano, J. D. Morgan, D. R. Mitchell

Rubber-tired shuttle cars are finding increased use as gathering units in under-ground mines. As the name implies, they shuttle back and forth between the loading machine and the section transportation system. In many mines their use has in-creased the efficiency of the loading and gathering operations, resulting in increased output per man employed and decreased costs per ton. A car motivated by cable reel is shown in Fig I, and a car with battery power in Fig 2. A brief chronological account of the development of rubber-tired haulage equip-ment follows: 1936. J. H. Fletcher1 installed his first unit for the Blue Bird Coal Co., Carrier Mills, Illinois. This unit consisted of a battery-powered industrial tractor and a trailer with drop-bottom doors. The coal was transported for short distances to a hopper for discharge into mine cars. 1938. A battery-powered self-contained shut-tle car with rubber-tired wheels was built by the Joy Manufacturing Co. Two units were installed for the Katherine Coal Co., Lumberport, West Virginia. The shuttle car consisted of a materials-receiving body with a conveyor in the bottom to move the coal forward during loading and to unload the coal at the discharge station. 1938. A cable-powered shuttle car with four-wheel drive and four-wheel steer was developed by A. L. Lee. Special wheels mounted on king pins on the car permitted all four wheels to be steered. The cable reel was driven by a torque motor to give the cable proper tension during the payout and uniform tension when rewound on the reel. 1940. A Joy shuttle car equipped with trolley poles and a cable reel was developed to operate on a double trolley-wire system.2 This unit was installed at a potash mine of the International Minerals and Chemicals Corporation at Carlsbad, New Mexico. It is believed to have been the first installation of its kind, and the first of shuttle cars for handling material other than coal. 1941. Truck haulage3 was introduced in the Tri State District by the Eagle-Picher Mining and Smelting Company. Storage battery electric trucks were rebuilt to handle a bottom-dump trailer. 1941—Joy shuttle cars were installed in a mine of the United States Gypsum Company, Oakfield, New York. 1943—Joy shuttle cars were installed in several bauxite mines.4,5 1945—Joy shuttle cars installed in a lime-stone mine. Because of the nature of bituminous coal beds trackless equipment has had its greatest application in bituminous coal mining. Usually a shuttle car is filled by a continuous type of loader. In Fig 3 is shown a continuous machine loading coal into a battery-powered shuttle car, 48-in. coal. However, intermittent types of load-

Jan 1, 1949

By F. S. Thurner

This paper, a description of the new ore-unloading and stockpiling facilities at the Sydney Works of DOSCO Steel Limited, deals with a new approach to arrive at the most economical solution to combine ore unloading facilities for common bulk carriers and for different types of self-unloading vessels. Also discussed is the design and installation of a 1-mile-long steel-cord belt conveyor sys-tem with a most modern type of mobile belt conveyor stacker, along with automatic and semi-automatic controls for the entire ship-unloading and stockpiling operations.

Jan 1, 1968

By S. Gqebe, A. Lewis, M. Rodriguez-Pascual

"Gravitational sedimentation of suspensions in various precipitation processes is hindered by colloidal stability. This is due to the high surface charge of the suspension and results in strong attraction/interaction between the ions on the particle surface and counter-ions in solution. Moreover, this strong interaction results in a charge build-up that renders the suspension stable. In order to induce gravitational sedimentation of these particles, a redistribution of ions close to the particle surface is required. We therefore sought to redistribute ions close to the particle surface by applying a magnetic field. This results in the reduction of interparticle electrostatic repulsive forces and a subsequent increase in the zeta potential of a suspension. For the purpose of this study, a copper sulphide suspension was used. Copper sulphide particles were exposed to a range of field strengths for set exposure times and their zeta potential was measured before and after exposure. All particles had an initial zeta potential value equal to or less than –40 mV prior to magnetic field exposure. A significant increase in zeta potential was observed, with values reaching a maximum of –16.5 mV when exposed to a 2 T field strength for 40 minutes. This is due to Lorentz ion shifts resulting from the Lorentz force exerted by the magnetic field on the particle surface. IntroductionMetal sulphide precipitation is a process for treating industrial waste streams with high residual concentration of mixed metal ions and acid mine drainage. This process has been reported to achieve higher metal removal compared with the industrially prevalent lime precipitation, due to the sparingly soluble nature of the metal sulphide precipitates formed. However, precipitation is governed by high levels of supersaturation which favour the formation of fine particles (Lewis, 2010). Consequently, some of the metal sulphide fines formed exhibit slow settling dynamics and thus tend to remain suspended in solution."

Jan 1, 2016

By Kuniaki Murase

Cadmium telluride (CdTe) semiconductor has been well investigated as a CdS/CdTe heterojunction solar cell material since its band gap is suitable for energy conversion from sunlight into electricity. In this paper a new electrochemical processing of thin-layered CdTe using basic aqueous electrolytes is reviewed from the standpoint of thermodynamics using a potential-pH diagram. The cathodic electrodeposition of the stoichiometric CdTe with a flat surface morphology took place at more positive potentials than that of the Nernst potential for the bulk-Cd deposition and at more negative potentials than that for the hulk-To. In this potential region deviation from the stoichiometric composition of eleetrodeposited CdTe was controllable by the Cd(II)/Te(IV) concentration ratio, pH, or concentration of complexing agent for Cd2+ ions of the electrolytes, The deposition behaviors for ammoniacal media were well accounted for by the potential-pH diagram of the Cd-Te-NH3-H2O system devised by a combination of those of the Cd-NH3-H20 and the Te-H2O systems, Diagrams for other complexing agents, ethylenediamine and diethylenetriamine, were also constructed to investigate and discuss the electrodeposition conditions regarding the corresponding media.

Jan 1, 2003

By J. Zegarra

"Si bien el anhidrido sulfuroso es considerado como un contaminante atmosférico, puede ser utilizado en la concentración de minerales por flotación a través del reemplazo del NaCN/CaO. En ese sentido, el presente texto señala la aplicación de este reactivo en el proceso de flotación, así también como se presenta los trabajos realizados a escala de laboratorio con el objeto de determinar su aplicación a la flotación selectiva directa de mineralessulfurados y en el mejoramiento del grado de concentrados de zinc. "

Jul 1, 1976

By LeRoy Scharon

EACH year it becomes apparent that geophysical activities in the fields of mining and engineering are increasing in the number and variety of applications. Many mining companies are including, as part of their exploration programs, geophysical surveys. The value of geophysics in highway and structural foundation investigations has been realized and is now an important part of subsurface investigations in conjunction with soil and rock borings. United States of America One of the major orebody discoveries of the year is that of the Grace mine near Morgantown in Berks County, Pa. This orebody, now under development by the Bethlehem Steel Co., was discovered by an airborne magnetometer survey carried out by the Aero Service Corp. of Philadelphia. The orebody, the geological occurrence of which is similar to those existing at Cornwall, Pa., was found at a depth of 1500 ft under a cover of Triassic sediments and is reported to have a reserve of well over 100 million tons. Shaft sinking and other construction work has started at the site. Resistivity work was carried out at proposed dam sites in New York and in connection with the search for fluorspar veins in Kentucky. Spontaneous polarization investigations were pursued in the Appalachian region at various localities from North Caro¬lina up into Virginia. This work was done in connection with the search for sulphide-bearing structures. Several indications were proven by subsequent drilling to correspond to unknown sulphide deposits, a few of these occurring in the vicinity of properties long under exploitation. Refraction seismic methods applied to bedrock depth determinations as related to water problems on the Marquette Range and the extension of the. regional gravity survey on the Menominee Range to learn the major structural features of the area have been reported by, Lloyal O. Bacon. A gravity survey has been completed in the vicinity of Tioga, Bradford County, Pa. with a gravity profile being observed from Tioga east to the Delaware basin. The Indiana Geological Survey is concerned with a state-wide gravity survey. Judson Mead, University of Indiana, reports that the bulk of the State Survey's geophysical work, however, has been "seismic refraction work in connection with drift thickness problems. The survey has made almost 1000 determinations in areas of moderately thick drift. The results of this work are of interest to both the coal mining industry and to the stone industry." In the southeastern Missouri lead belt, magnetic electrical resistivity, and electromagnetic applications for the discovery of new lead deposits have been used with success. A gravity survey of the residual-barite deposits in Washington County, Mo., was made during the summer season with preliminary computations of tonnages checking with tonnages mined. Robert M. Dryer, of the University of Kansas has had considerable success in mapping structural features in southwestern Kansas with the gravity meter and is now engaged in tracing shoestring sands in eastern Kansas by resistivity surveys. Several, foundation sites were investigated in greater St. Louis using electrical resistivity and seismic refraction methods with success. A minimum amount of drilling data was available for checking and interpreting the geophysical results (Fig. 1). It is to be noted that geophysical methods are finding a place in subsurface investigations for highway and foundation problems. Interest has been so keen in this field that the American Society for Testing Materials, at its annual meeting in June of this year, devoted one session of its symposium on surface and subsurface reconnaissance to geophysical papers involving the application of the electrical resistivity and seismic refraction methods to subsurface studies. At least three major mining companies in the United States have entered the field recently in geochemistry. The program of research and development of geochemical techniques by the U. S. Geological Survey continues. Experimental field projects were conducted over lead-silver, cobalt, copper and zinc deposits in Idaho, Oregon, California, Wisconsin and Montana. Similar experiments were carried on by M. P. Nackowski in the Illinois-Kentucky fluorspar district and in the Tri-State Zinc district by R. Maurice Tripp with favorable results. Geophysical activities of the U. S. Geological Survey for 1951 were extensive and varied. About 21,000 miles of airborne magnetic and 10,000 miles of airborne radioactivity traverse were flown in 1951 by the U. S. Geological Survey. A total of 35,000 miles of aeromagnetic traverse were compiled, 57 aeromagnetic maps were published and 14 preliminary maps were placed on open file. Airborne surveys were made in Aroostook County, in the Katahdin and Dead River areas in Maine; in northwest Washington; over the Mother Lode district in California; in northeastern and northwestern Minnesota; and in the New York-New Jersey highlands. Of special interest were the surveys in Washington, where highly magnetic Eocene lavas gave information on structures in the overlying Miocene sedimentary rocks and in northeastern Minnesota over the Duluth gabbro. The latter survey was made following the discovery of nickel-copper mineralization in the gabbro near its contact with the Virginia slate. The principal ground geophysical surveys for metalliferous deposits and related purposes were made in the Colorado Plateau region, where electrical surveys assisted in prospecting; in Aroostook County, Maine, where ground magnetic surveys, following aeromagnetic surveys, have permitted tracing

Jan 1, 1952

By E. Pothas, P. R. Jochens, L. B. McRae, D. D. Howat

Discussion H. J. S. Kriek*: During 1956 Iscor became interested in the acid smelting in a blast furnace of siliceous ores containing 15 per cent silica. This interest was as a result of the successful acid smelting in Germany at a CaO/SiO2-ratio of between 0.4 and 0.8. Acid smelting can become an economic proposition due to a reduction in slag volume accompanied by a lowering of the coke rate. Paschke and Hannel1 found that a free flowing slag (i.e. viscosities of less than two poise) would not be obtained at C/S-ratios lower than 0.82 and that the addition of 3 to 4 per cent alkalies became necessary. In titanium bearing slags it was established that maximum fluidity is obtained with 10 per cent TiO2. Acid smelting resulted in increased sulphur pickup with decreasing O/S-ratio and desulphurization with soda-ash outside the blast furnace was necessary. At Iscor Mr B. B. Segal established that, for slags with (CaO+MgO)/SiO2-ratios of 0.5, 0.6 and 0.7, the addition of alkalies and TiO2 resulted in a substantial decrease in melting point and also of viscosity. At a (CaO+ MgO)/ ratio of 0.53 the addition of 10 per cent TiO2 is as effective as the addition of 3.75 per cent alkalies. This means that a blast furnace can be run without the addition of alkalies and consequently the detrimental effect of alkalies on the lining can be avoided; also that fluid slags with 5 to 15 per cent MgO and 8 to 10 per cent Al203 can be obtained with 10 per cent TiO present. (CaO+ MgO)/SiO2-ratios smaller than 0.5 the addition of titania resulted in a decrease in melting point and also in an increase in viscosity. In ceramic crucibles the slag did not become more viscous with time but thickened appreciably when held in graphite crucibles. No titanium carbonitride could be detected and only Ti20a was found. Prof Howat also did not obtain the TiC-TiN solid solution and therefore it appears that the thickening of the slag is not solely due to the formation of the titanium carbonitrides. This is in agreement with the work of Michailov and Belyakova2 who found that TiO2 decreased the viscosity of acid slags and increased the viscosity of basic slags; that titanium sesquioxide (Ti203) and titanium monoxide (TiO) increased the viscosity of both acid and basic slags and that titanium carbide, which is found in larger amounts in basic slags than in acid slags, considerably increases the viscosity of both acid and basic slags. Patzak et al3 describes the following oxygen deficient titanias, viz Ti2O, TiO, Ti203, Ti3O5, Ti4O7, Ti5O9, Ti6O11- Ti10O9,Ti7O13,Ti8O15 and Ti9O17. Until about 1959 a fair amount of data was available on the viscosity of normal slags to which titania was added2, 4, 5, 6, 7, 8, 9. At Iscor an electromagnetic viscometer based on the viscometer developed by Bockris10 was built. Progress was very slow as our main attention was centred around problems associated with the operation of the Rotor process. During 1962 and 1963 two papers containing fundamental work on the viscosities of slags in the systems CaO-SiO2-TiO211 and CaO-SiO2-TiO2 at 0 per cent A1203, 10 per cent Al203 and 20 per cent Al20312 appeared. The work of Ross and Ohno obviated the necessity of any further work by Iscor on the viscosity of blast furnace slags containing titania. Ross gave the following optimum compositions for blast furnace slags containing titania. Titania % Lime % Silica % Lime/Silica-ratio 20 30-42 38-50 0.6-1.10 30 27-36 34-43 0.63-1.06 40 24-32 28-36 0.66-1.14 The optimum temperature is 1,500°C because at this temperature the largest workable composition range exists. Higher temperatures result in narrower optimum composition ranges and in increased rates of thickening. The factors affecting the rate of thickening were also investigated by Ross and Ohno, as the main problem with slags containing titania is not finding compositions which are fluid at operating temperatures but the thickening due to a lack of oxygen. With these slags when there is insufficient oxygen to co-ordinate each silicon atom with its own individual shell of four oxygen ions, some sharing of oxygen ions must occur, resulting in the formation of large silicate ions and a rise in viscosity. The formation of oxygen deficient titania can be prevented as long as iron oxide or manganese oxide remain in the liquid slag. Iwase13 and also Viens, Camp bell and Rogers14 obtained in the experimental smelting of ilmenite ores fluid slags with more than 3 to 5 per cent manganese oxide and ferrous oxide in the slags. It appears that titaniferous ores can be smelted in blast furnaces under the following conditions: (1) Acid slag operation, i.e. at C/S-ratios from O.6-1.0. (2) Dolomite can be used as a flux as MgO is a network modifier. (3) The Al2O3-content must be less than 15 per cent as alumina promotes thickening of the slag and decreases the optimum composition range. (4) The hearth temperature must not exceed 1,500°C. According to Ross a definite amount of energy is required for each ton of iron produced and in order to increase production an increase in heat

Jan 6, 1969