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By J. Loredo

In some rural regions of Peru, artisanal gold mining is currently an essential activity as it provides an important source of income. In the Huanca region (Ayacucho Department) gold deposits are not attractive for mining companies due to their reduced size, but they have enough interest for artisanal mining because of the ease and low cost of mining operations. Artisanal gold mining represents an important damage for the environment, because operations related to amalgamation processes using Hg result in special environmental problems besides the typical ones commonly associated to all mining activities. A preliminary sampling has been made in soils, materials from tailing ponds and surface water of the Acarí River, at the site of the Huanca village, according to networks specially designed for the particular conditions of the area. Studies accomplished revealed high mercury concentrations in soils and tailings. Chemical analyses of soils directly collected in the area of the active or abandoned ?quimbaletes? show mercury concentrations ranging from 15.3 mg?kg-1 to 44.2 mg.kg-1. Mercury concentrations in soils decrease as a function of distance from the before mentioned sources. Water quality of the Acarí River that flows through the area does not present important changes as a consequence of the mining and processing operations.

Jan 1, 2006

By Robert Maddin

crystal prior to, polishing in order to eliminate coring. This treatment may be accomplished by wrapping the single crystal tightly in very thin, dead soft, brass foil and annealing in the presence of air for 20 hr at 800°C. Since the wrapping encircles the sptcimen three to four times, only a very slight amount of oxidation occurs on the specimen surface. On unwrapping one of these cylindrical single crystals. in. in diam by ro in. long (72.75 pct cu, 27.23 pct Zn, 0.01 pct P11, 0.01 pct re), mall light-gray depnrrits in the form of circular arcs werenoted on the part nf the foil which had been in contact with the single crystal, Fig r. (By superim- approximatetl). These deposits, which, from their color, suggest the appearance of sublimated zinc, were found to coincide roughly with a set of octahedral planes nearly perpendicular to the rod axis. The pattern shorn in the figure held no relation to the profle of the sample since the markin~s on the crystal More annealing werc attributed to traces of cube planes. It seems very likely that the deposits were formed by sutllimation of zinc diffusing from octahrdral planes since diffusian would Eogically take place along planes of maximum atomic spacing. However, it is difficult to understand why a continuous sublimation of zinc should occur from a single crystat in contact with a wrapping roil OF the same composition, and why diffusion would take place along specific octahedral planes and in a regular pattern.

Jan 1, 1949

By Henry F. Adams, Guy H. Ruggles

In this paper the authors aim to chronicle the experience and salient points brought out in changing flotation reagents at a concentrator which had probably been using a minimum amount of oil at a minimum cost per ton, to a more complicated system requiring a partial chemical control. The original oils were coal tar and pine oil. The new reagents are lime, xanthate and pine oil. It was found that there were no insurmountable difficulties and eventually the cost of the new reagents per ton of ore proved to be very little more than that of the old. Lime Plant When the question of handling lime came up there were two propositions open: (1) to handle the lime dry; (2) to handle it wet in the form of an emulsion. Granting that a dry lime feeder would function properly, delivering lime uniformly, the chief objection was the dust that would be raised when these feeders were being charged or operated, as the only possible location was on a gallery beneath which men were working. With this objection the handling of lime as an emulsion seemed to be the better scheme. The lime plant which was first installed was for experimental work on one section. This was gradually changed and developed until it was of sufficient size to accommodate 20 sections. The various changes will not be discussed and the following description deals only with the fully developed plant. Crude as it is, and perhaps somewhat expensive to operate, the lime-handling plant has been quite successful. Much has been learned which will pave the way for a better installation in the future. Burnt lime is received loose in standard gage box cars. This is the product of the kilns and has had no screening or sorting. A grab sample is taken from each car as it is unloaded. An average of the analyses of samples from 44 cars gave the following: Available CaO Total CaO, Oxide and Hy- MgO, Fe²O³ + Al²O³, Insoluble, Per Cent. drate, Per Cent. Per Cent. Per Cent. Pek Cent. 88.3 79.2 1.6 ' 1.3 2.2

Jan 1, 1928

By Bowles Oliver

"Modification of Quarry Process.Limestone beds are formed by processes of nature, processes that have been in operation for thousands and perhaps millions of years. Therefore, their com- position and physical properties are long-established and unalterable features over which man has no control. He must take them as he fields them.It is undoubtedly true that the character of lime depends largely on the nature of the parent limestone. A high-calcium lime cannot be manufactured from a dolomite, nor can a pure lime result from the calcination of an impure raw material. However, in the process of turning limestone into lime man is not entirely helpless in his control of quality. Even though a deposit is variable in character a single lime product of uniform quality may be produced by judicious quarrying. A single grade of product may not always be desired, the producer may wish to supply the needs of a variety of users each demanding U different grade or quality of lime such a series of graded products may be produced in part at least by modifying the quarry method. Thus, by changes in quarry practice a single product or a variety of products may be made. The latter problem will be considered at a later time, and the present paper devoted to the first named question' that of producing a single grade of lime from a deposit of variable rock,It is realized of course that uniformity in the product is influenced greatly by manufacturing processes such as calcining' hydrating' grinding or storage, but the present discussion is confined to the influence of raw materials only. In considering the various devices that may be employed it is realized that much remains to be learned, and it is hoped that many operators will contribute to the discussion as they have already done in connection with previous papers of this series."

May 1, 1923

By M. L. Rudee, R. A. Huggins

Samples of iron containing nitrogen or carbon have been given treatments similar to those used in cold-work peak (CWP) measurements and examined by transmission electron microscopy. It was observed that the unusual and nonreproducible behavior of the carbon CWP can be explained by a strong tendency for carbon to form grain boundary precipitates at temperatures below those used for CWP measurements. These precipitates dissolved at the temperatures used in the CWP measurements. There was no evidence for nitrogen precipitation at grain boundaries. There was no indication of precipitation along dislocations in either carburized or nitrided samples given treatments similar to those of CWP measurements. Although it is possible that subelectron-microscopic clustering had occurred, this observation supports the theories of the CWP that are based on continuous atmospheres rather than on individual precipitates. In an earlier paper,' the present authors developed a new distribution function to predict the occupation of sites for interstitial impurity atoms around a dislocation. When this distribution was applied to the case of carbon and nitrogen in iron, it predicted that, if the temperature dependence of the concentration of solute atoms in the matrix was controlled by the presence of equilibrium carbide or nitride precipitates, the tendency for nitrogen to segregate to dislocations would be greater than that for carbon even though their binding energies to dislocations are identical. The cold-work internal-friction peak (CWP) is considered by most authors to be produced by the interaction of interstitial impurities with dislocations. Many investigators have studied the CWP in iron containing carbon and nitrogen and have observed a significant difference between its behavior in the two cases. In this paper a series of experiments will be reported that were initiated to determine whether the application of the new distribution function would explain the observed differences between the carbon and nitrogen CWP. Although it was found that the distribution function, pev se, did not explain the differences, the differences became clear, and some insight into the mechanism of the CWP was realized. Before reporting the present experiments, the literature pertaining to the differences between the carbon and nitrogen CWP in iron and the various mechanisms proposed for the CWP will be reviewed. LITERATURE REVIEW Snoek2 first observed the CWP in iron specimens containing nitrogen, but also reported a weak and unreliable peak in carburized samples. Later, Ke3 established that the CWP height was proportional to the degree of deformation. The presence of nitrogen alone would produce a peak of the same size as found in a sample containing both nitrogen and carbon, and KG concluded that the CWP was caused by nitrogen. In a discussion of G's paper it was reported that Dijkstra had investigated the CWP in samples that contained only carbon. He found it to be much smaller than the nitrogen peak and "unstable". KG et al.4 charged specimens of iron with both carbon and nitrogen. They observed that the carbon CWP was much smaller than that observed in nitrided samples, but that aging at 300°C caused the carbon peak to increase. A similar treatment produced no change in a nitrogen peak. Annealing at higher temperatures caused the height of the CWP in both the nitrogen and carbon samples to decrease. This behavior was also observed by Kamber et al. 5 who found that the activation energy for the annealing of the CWP was identical with the activation energy for the self-diffusion of iron. They concluded that the annihilation of dislocations by climb caused the reduction in the CWP height. Kamber et al. studied the "unstable" carbon peak in detail. They measured both the Snoek and CWP during various aging treatments. In carburized samples, aging at 100°C caused the Snoek peak to disappear, although the CWP peak remained small. However, a subsequent treatment for 5 hr at 240°C caused the CWP to reach a maximum. They proposed that an additional location for the carbon, other than whatever site produced the CWP, is present. In nitrided samples the CWP was completely developed as soon as a measurement was made; additional sites are not present. No explanation of either the additional site or the difference in the behavior of carbon and nitrogen was offered. petarra5 performed a systematic study of the effect of composition on the CWP. Using three kinds of "pure" iron, he showed that there was a residual CWP when the carbon and nitrogen concentrations had been reduced to less than that detectable by Snoek-peak measurements. He observed the same general annealing behavior and composition dependence as previous investigators, with the following exceptions. On first measuring the carbon CWP, it was found to be identical with the residual peak, and essentially independent of the carbon content. If the CWP was measured a second time in the same sample, it increased in size, but was still only about one-fourth the size of a CWP in a sample of the same iron nitrided to the same composition. On the other hand, a series of annealing experiments showed that the nitrogen CWP was not al-

Jan 1, 1967

By A. M. Hanna

This paper presents the experimental investigation on the ultimate skin friction of batter piles. The model piles were pushed in medium dense sand deposits at different inclinations up to 30 with respect to the vertical and tested under axial compression loads. The decrease in the total skin resistance with increasing pile inclination can be explained in terms of the reduction of the ave­rage mobilized angle of friction between the pile shaft and sand. The analysis, which takes into account asymmetrical earth pressure distributions around the pile shaft, showed good agreement with experimental results.

Jan 1, 2010

By S. Redik, C. Wenzl, D. Gregurek, A. Spanring

Zinc is a component of many input materials used in various pyrometallurgical processes, for example primary lead and zinc production from Pb/Zn ores and recycling processes dealing with zinc-containing residues (e.g., copper recycling, WAELZ process). Hence, zinc and its compounds are present in the respective metallurgical vessels and interact with the refractory lining. In the present work the zinc attack on the refractories out of various primary and secondary furnaces is briefly introduced and discussed. At the prevailing processing temperatures in the metallurgical vessels, zinc oxide is highly corrosive for the brick components. The knowledge of the wear behavior is based not only on a detailed chemical and mineralogical characterization carried out on provided post mortem samples, but also on FactSage calculations. This together with results obtained by practical testing in the RHI pilot plant represents an important prerequisite for product development and brick selection for the individual customer application.

Jan 1, 2016

By J. T. Chen, S. Winkler, M. J. Worswick, O. Orlov

This paper presents a review of research conducted at the University of Waterloo concerned with the application of aluminum alloy sheet and tube in automotive structures and body panels. The research has focussed on formability prediction and results using a range of damage-based formulations. These models include continuum-level damage approaches and, more recently, a so-called percolation damage approach intended to capture microstructural heterogeneity effects on damage development. This paper presents applications of these damage approaches to simulate formability of experiments considering stretch flange panels. The experiments consider drawbead effects associated with the bend/unbend deformation as the material flows through the drawbead. Recent work on simulating in situ X-ray tomography experiments that capture damage evolution during tensile deformation will also be reviewed.

Jan 1, 2006

By Andrew Higgins, Jamey Rosen

This presentation will demonstrate some recent advancements in the applications of Project Information Systems (PIMS) technology to seepage barrier walls in the context of evolving Owner Specifications. The use of geospatial technology in particular is used to track, visualize, and analyze data from a variety of sources and serve those data to contractors and owners via dashboards and as-built drawings. Data describing the geometry of construction elements (including diaphragm panels, secant piles, and jet grout columns) is of particular importance on these projects, and this presentation will include case studies in the United States of how these data are used to determine if a barrier wall is constructed as designed and if it meets the owner specifications with respect to tolerance (i.e., if each element is sufficiently close to vertical) and overlap (i.e., do adjacent elements overlap sufficiently to prevent leakage).

May 1, 2022

By T. Karlkvist, H. R. Kota, F. Andreas, B. I. Pålsson

"Separation of different calcium minerals have long been an interesting and challenging problem. In this investigation calcium mineral separation is examined by: microflotation, zeta potential measurement and adsorption, using novel collectors having two functional groups instead of one. In theory, by varying the distance between the functional groups, it could be possible to preferentially target one calcium mineral by matching the spatial distance between the sites on the mineral surface. In this investigation two new surfactants have been tested to estimate their ability to float apatite and/or calcite. Preliminary findings show that an increase in distance between the functional groups favors one mineral over the other, and this might be due to differences in the mineral surface structure. INTRODUCTION Apatite is a strategically important mineral which has both great value for industrial use as a precursor to phosphoric acid; and in the agricultural industry as an important source of phosphorous in fertilizers. This has led both the European Union and the United States to recognize it as an important resource for the future. Currently there is no lack of apatite in the world, but it is important to develop the beneficiation to ensure future supply. A common problem in apatite flotation is the selectivity towards calcite, which it is commonly associated with. Although calcite is an important industrial mineral its abundance makes it not usually worth to extract from apatite ores unless it is easy to separate1,2. Both apatite and calcite are semi soluble minerals with calcium as one of their constituents. The most common way to separate apatite and calcite is to use flotation. A process that involves making the mineral particles to extract from the system hydrophobic by adsorbing a collector on the mineral surface. One way to study collector adsorption on a mineral surface is by zeta potential measurements. The zeta potential is the charge at a slip plane a short distance from the surface. By measuring the zeta potential with and without the presence of collector it is possible to investigate if the collector is present at the surface or not, a change is indicative of collector adsorption. The zeta potential of fluorite, apatite and calcite without collector can be seen in Figure 1. The small difference in zeta potential between apatite and calcite shows the similarity in their surface properties and gives an indication of their separation difficulty. One additional problem with semi soluble minerals is their tendency to slightly dissolve in the pulp and thereby change the ionic composition of the solution. This makes separation and research problematic as the freed ions may readsorb on the mineral surface and interfere with the collector adsorption on the mineral surfaces3–5."

Jan 1, 2016

By Yi Luo, Hua Jiang

A roof bolting drilling operation in an underground coal mine can expose the operator to a high concentration of respirable coal and crystalline silica dusts (smaller than 10 µm). Overexposure of high-level quartz dust for a roof bolter operator can lead to the development of silicosis in as little as three years [1]. This study proposes a drilling control algorithm for the bolt hole drilling process. This algorithm can be integrated into a current drilling control system on the roof bolter machinery and is expected to reduce the generation of respirable dust while enhancing the energy efficiency of the roof bolter machine. In addition, the drilling efficiency and bit condition can be evaluated while drilling based on the real-time feedback parameters. This capability enables the algorithm to ensure the drilling is performed under a relatively high energy efficiency with less respirable dust generation and to avoid drilling with an excessively worn bit that can cause bit clogging or steel buckling failure.

By J. P. Morgan, J. R. Dawson

A review of Jones & Laughlin's Vesta coal preparation plant flowsheet in 1959 indicated that, of the three sizes making up the company's metallurgical product, the -48-mesh fraction offered the greatest potential for improvement. Efforts to improve quality and yield were directed toward the use of froth flotation. After laboratory and plant tests were completed, it was decided that treatment of the entire -@-mesh fraction of the coal mix by flotation was a significant step forward in providing better coal quality and recovery. Reduction of ash in the metallurgical coal from 6.75 to 6.25% provided material savings at the coal washer, coke plant and blast furnace. The Vesta preparation plant of the Jones & Laughlin Steel Corp. is located on the Monongahela River, eight miles south of Brownsville, Pa. This plant is capable of cleaning 2400 tph of a mixture of Pittsburgh seam high volatile coals from the Vesta and Shannopin mines to produce a metallurgical coal of 6.75% ash and a steam coal containing 14% ash. Heavy media vessels are utilized to upgrade the coarse coal while launders and tables handle the -1/4-in. fraction of the raw coal feed. Cleaned -1/4-in. coal goes to boot classifiers where the 48 mesh material settles and is removed by bucket elevators. This 1/4x48 mesh material is then sent to centrifugal dryers for dewatering. As designed, the -48 mesh fraction overflows the boot as a 7 to 8% solids slurry and is recovered by cyclones and a thickener and then dewatered by filtration. The products of the heavy media circuit, the launder-table-boot-dryer circuit and the cyclone-thickener-filter circuit, are combined to constitute the shipped metallurgical coal. The Vesta-Shannopin mix is combined at Jones & Laughlin's Pittsburgh and Aliquippa Works with purchased low and medium volatile coals for the production of metallurgical coke. A review of the preparation plant flowsheet in 1959 indicated that of the three sizes making up the metallurgical product, the -48-mesh fraction, containing 16.7% ash, offered the greatest potential for improvement of coal quality. This fraction was considered low, averaging 55%, while the rejects averaged only 33% ash. It was evident that while the boot overflow fraction represented only 6% of the product mix, a reduction in ash to 6 or 7% would reduce the ash of the metallurgical coal by 0.5%. The original plant flowsheet handling the boot overflow (Fig. 1) consisted of ten 14-in. cyclones treating 70% of the overflow and producing a 48x150-mesh underflow and a -150-mesh overflow. The cyclone overflow was combined with the remaining 30% of the boot overflow to constitute the feed to a 150-ft thickener. The cyclone underflow and the 48x325-mesh thickener underflow were fed to vacuum disk filters for dewatering prior to combination with the coarse metallurgical coal. The thickener overflow stream containing the -325-mesh material was split, 40% being recycled directly to the plant water system and 60% being flocculated and clarified in an 85-ft thickener. The underflow of this thickener was pumped to waste. Efforts to improve quality and yield on the -48-mesh coal were directed toward the use of froth flotation early in the investigation. A review of the fine coal flowsheet indicated that three streams should be considered for treatment by froth flotation. These were the -325-mesh thickener overflow, the -150-mesh cyclone overflow and the -48-mesh boot overflow. Flotation of the thickener overflow was considered basically to improve recovery by upgrading the reject stream so that it could be fed to the filters along with the thickener and cyclone underflows. The overflow from the thickener contained 3.7% solids and had an ash analysis of 33%. Flotation of the cyclone overflow and boot overflow were considered to upgrade coal quality as well as yield. Treatment of the cyclone overflow, a 5.4% solids slurry averaging 27% ash, would eliminate the coal thickener and provide a feed of flotation concentrate and cyclone underflow to the filters. Treatment of the boot overflow would eliminate both the cyclones and thickener and feed only flotation concentrates to the filters. Flotation feed in this

Jan 1, 1962

By R. B. Smith, D. C. Brady

"A review of the major renovation of the fifty-year old C-I headframe facilities at NERCQ's Con Mine, Yellowknife, N. W.T. is provided. The project was complete with only two 3-day shutdowns of the facility .Work consisted of four major phases: structural reinforcement of the adjoining mill building prior to dismantling; relocation of virtually all mine and mill utilities which transited the headframe collar en route from the adjacent powerhouse; dismantling of the entire headframe facility and portion of the mill building, including the removal of asbestos siding; and erection of a new headframe, idler rower, collarhouse and mill wall.This paper describes the work and methods used by NERCQ, J.S. Redpath Mining Consultants Limited, Acres International Limited, and others to bring the project to a successful completion. The history of the project is discussed from the planning phase through construction, including; design, procurement, and construction scheduling. The paper discusses the unique elements of the project, the problems encountered, and the methods used to achieve success.IntroductionThe Con Mine is a 800 tpd gold operation located in Yellowknife, Northwest Territories. Originally owned and operated by Cominco Limited , the Con Mine was sold in December 1986 to NERCO Minerals Company, and officially renamed NERCO Con Mine, Ltd. The Con Mine has been in operation for over 50 years. The first gold brick ever produced in the Northwest Territories was poured at the Con Mine in 1938. The original C-1 shaft was sunk in 1937 to a depth of 235 ft. In 1941 the shaft was deepened to a depth of 950 ft, and the original timber head frame was replaced with a steel structure. Following the discovery of the Campbell Shear in 1946, the C-l shaft was again deepened to its present depth of 2443 ft. Over the years, mine production gradually moved deeper and further from the C-l shaft."

Jan 1, 1991

By Worthen Bradley

A BETTER understanding of what is happening in the domestic quicksilver industry, and what is likely to happen, can be had after reviewing some of the highlights of the past four years. Hitting the high spots in chronological order, they are: February 1939-Army and Navy Munitions Board starts investigation on civilian and war needs of certain "strategic materials," including quicksilver, with a view to recommending stock piles. Every known producer is canvassed by the end of the year.

Jan 1, 1942

SOME notes on the works of the Electrolytic Refining and Smelting Company of Australia will no doubt be of interest to members of the Institute, more especially as much of the work is new to Australasia.As many of the members who may read this paper have not been in a position to visit works of this kind, and are consequently not thoroughly acquainted with all the operations carried on, the author has taken the liberty, in some cases, to enter into explanation which would otherwise be unnecessary.The works are situated at Port Kembla (New SouthWales), about fifty miles south of Sydney, and are approachable both by rail and water. The Government has recently built a low-level jetty upwards of five hundred feet long, and intends installing at an early date an electrically operated portable crane to facilitate the handling of material to and from the boats. Thi.s will mean a considerable reduction in the length of time that boats are laid up at the jetty. There are also under construction two breakwaters, which, when complete, will materially assist shipping operations. The works as they exist are capable of turning out 1200 long tons of refined copper per month. It is gratifying here to note the unqualified success with whichthe E.S.A. refined copper met with on first being put on the market.

Jan 1, 1911

By Jonas Addai-Mensah

Despite the fact that nickel (Ni) laterites accounts for about 60 % of the world?s nickel mineralization, commercial processing of complex, low grade Ni laterite ores by conventional beneficiation (e.g. magnetic, electrostatic and flotation separation) still presents intractable challenges, particularly in heap leaching. Invariably, low grade laterite ores require aggressive hydrometallurgical techniques (e.g., highly acidic lixiviant leaching at ambient or elevated temperatures) for Ni and cobalt (Co) extraction. As a precursor to heap leaching, agglomeration of the multi-mineral phase feed particles into robust and porous granules of 4-10 m permeable bed, is essential. In the present work, several basic and applied studies of the agglomeration behavior of real Ni laterite ores and selected oxides and clay minerals (hematite, quartz smectite and kaolinite) which constitute the predominant host gangue phases of typical laterite ores are performed. Isothermal, batch agglomeration tests involving sulphuric acid solution as a binder were carried out to produce coarse, narrow-sized (5 ? 40 mm) granules which were well characterized. The influential role of feed ore characteristics (e.g., mineralogy/chemistry and primary particle size distribution) and binder composition (30 vs. 44% w/w H2SO4) and dosage (15-25 wt.%) in agglomeration behavior and granule properties were examined through several characterization techniques including granule size, compressive strength, bed percolation and re-wetting stability and 3-dimensional micro-structure analyses. Links between feed mineralogy/chemistry and size, binder formulation, agglomeration behavior, curing conditions and final granule properties and structural characteristics are established. The implications of the findings to Ni laterite plant agglomeration for enhanced heap leaching are discussed. Keywords: nickel laterite, complex low-grade ores, agglomeration, heap leaching, micro-structure

Sep 1, 2012

By J. A. Finch, Zhenghe Xu

The competitive adsorption of xanthates on sulphide minerals in a binary mineral system (pentlandite and pyrrhotite) was studied using the pseudo-in-situ technique of attenuated total-reflectance FTIR spectroscopy. The minerals were placed in the same collector solutions, either separated by a glass wall or in direct contact with each other before magnetic separation and separate analysis. The effect of mineral interaction on xanthate adsorption was clearly demonstrated spectroscopically for the first time. At low concentrations of xanthate, its adsorption on pentlandite was activated by physical contact with pyrrhotite; the effect may be attributed to the enhancement of electron transfer through electrical contact between the two minerals. The results emphasise the need for caution in extrapolating results obtained from single-mineral studies to flotation practice

Jun 18, 1905

By Jaki Wilson, Les Armstrong, Neville T. Moxon

Low shock energy ANFO (ANFO) mixtures have been developed for use in fragmenting weak overburden materials and reducing damage.outside the blast zone in dry conditions. These mixtures can be readily produced on a minesite using conventional equipment and are formed by mixing low density additives such as polystyrene, bagasse and sawdust with ANFO.

Jan 1, 1990

By Donald W. Foss

The Shiloh Church deposit is a very significant molybdenum occurrence in an ususual, perhaps unique, geologic environment. Work done to date indicate that several million tons of "ore" may be present, occurring as a matrix in limestone and dolomite breccias. Mineralized rocks cored to date are at or near the surface and the deeper resource potential has not been tested. The prospect is located in Polk County, north- western Georgia (Fig. 1). The "ore zone" was outlined by North American Exploration, Inc. (NAE) using geochemical prospecting techniques. Extensive geological work, including core drilling, has been conducted on the properties, together with geochemical and geophysical surveys. The geology, geochemistry and geophysics of the prospect are discussed. It is hoped that these data can be used to formulate exploration programs in similar terranes located elsewhere in the eastern U.S.A.

Jan 1, 1983

By G. V. Smith, C. O. Tarr, R. F. Miller

Metallurgists have long recognized that the Fe3C type of carbide is not a stable phase in steel and that, given sufficient time, it will decompose with formation of graphite, at least at temperatures below about 205o°F.l This slow graphitization has never been of much concern to users of hypoeutectoid steels, for in such steels it occurs only during prolonged exposure at elevated temperature. In I935, Kinzel and Moore2 reported complete graphitization of the carbide of a 0. I5 per cent carbon steel that had been in service for about 26,000 hr. at a temperature of about IIOO° to 12oo°F. In discussing this paper, both Mathews and Sauveur reported graphitization of slightly hypereutectoid steels. In an extensive investigation of graphitization of high-purity iron-carbon alloys, Wells1 produced graphite at 7oo°C. (I29o°F.) in an alloy containing as little as 0.13 per cent carbon, and showed that graphite may precipitate either directly from austenite or from decomposition of Fe3C, also that the rate of graphitization tends to increase with increase of temperature, at least up to a certain point, and with the presence of graphite nuclei. Jenkins, Mellor and Jenkinson,3 studying the structural changes in carbon steels ranging from 0.17 to 1.14 per cent carbon during stress-rupture tests at elevated temperature, observed graphite in an aluminum-killed 0.40 per cent carbon steel after fracture in 4340 hr. under a stress of 17,900 lb. per sq. in. at 840°F. and in many of the steels after stress-rupture test at 12oo°F. Unstressed samples of 0.60, 0.86 and I.I4 per cent carbon steels graphitized almost completely in 360 hr. at I200°F., while samples of 0.90 and 1.10 per cent carbon steels were somewhat graphitized, and steels containing 0.24, 0.40 and 0.57 per cent carbon showed no sign of graphite. Their results indicate that graphite precipitates the more readily the higher the carbon content, though this tendency is influenced to some extent by deoxidation practice, and that graphitization is accelerated by plastic deformation. In a recent study of the graphitization of 0.4 and 0.6 per cent carbon steel strip, made by M. A. Hughes,4 it was found that at I2oo°F. graphite appeared after 72 hr. in aluminum-killed but not in silicon-killed steel, and that the rate of graphitization was increased by slow cooling from I6oo°F. and by cold-working prior to annealing. In creep tests of normalized 0.15 per cent carbon steel killed with 2.5 Ib. of aluminum per ton, at the U. S. Steel Corporation laboratory at Kearny, spheroidization and some graphitization were found after 3000 hr. at Iooo°F. under a stress as low as 1500 lb. per sq. inch. .

Jan 1, 1944