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By Akira Usui

Occurrence of hydrogenetic ferromanganese crusts has been well documented over inactive seamounts in the central and southern Pacific Ocean. It has been thus believed that the hydrogenetic crusts develop preferentially at water depths between about 800 to 2500 meters. In fact, according to the Manganese Crust Database (F. Manheim, 1988), only two occurrences are known at water depths below 5000 m out of 819 occurrences cited in the database. Unexpectedly, we found typical hydrogenetic ferromanganese crusts from deep-sea floors; 1) outcropping old volcanic basement over the Philippine Sea Plate (abandoned spreading centers and subducting old oceanic crusts) and 2) one from the slope of an abyssal hill in the Central Pacific Basin (Cretaceous deep-sea basin) at water depths ranging between 5200 to 6100 meters. We report their occurrences with submersible observations from Shinkai 6K, physical parameters (such as thickness of crusts about 2-4 cm in maximum), chemical composition, petrology of substrate, and results of Be-10 dating for some samples in comparison with typical Co-rich manganese crusts from the Central Pacific seamounts. The preliminary chemical and mineralogical analyses reveal that they are of typical hydrogenetic origin, and typical of iron-manganese oxide mineral, vernadite, slow and probably continuous growth, and lower content of Co than the Central Pacific seamount crusts. The occurrences and nature of the crusts indicate that deep-sea floors are also optimal for the growth of hydrogenetic crust even at 5000 m water depth or deeper, only if oxygenated deep waters are supplied and the sea-floor morphology keeps stable enough for significant geological time period. Additional details of chemical analyses will be prepared by November and to be shown in the conference.

Jan 1, 2001

By W. H. Adams

At the present time all the larger and better chemical works of Europe and the United States have introduced, as essential factors in the economical manufacture of sulphuric acid, both Glover towers and Gay-Lussac absorbing columns. The clear exposition of facts given by Bode and Lunge in their very valuable technical contributions since 1870 has slowly but surely brought about radical changes from the old methods of manufacture ; but while the Gay-Lussac column has been known since 1827 and the Glover tower was originated in 1869, yet no theoretical treatise covering the subject fully was given to the world until 1876, when the various contrivances for demonstrating nitrous vitriol were described and criticized by Fr, Bode in a paper "On the Glover Tower" which obtained the great prize of the Berlin Society for the Promotion of Industry.*

Jan 1, 1887

By J. Pang, S. Chander

The mechanisms of chalcopyrite oxidation in alkaline solutions have been studied using cyclic voltammetry and impedance spectroscopy techniques. The cyclic voltammetry was used to elucidate oxidation/reduction reactions, whereas impedance spectroscopy was used for in-situ characterization of the interface. To analyze the impedance spectra, equivalent circuit models were constructed based on a layer- wise growth of reaction products. Parameters of the equivalent circuit were calculated by comparing the experimental spectrum with that expected on the basis of equivalent circuit. From the value of equivalent circuit parameters, properties of the surface layers were inferred. These properties change substantially with the change in oxygen and/or collector concentration in solution. From such changes the effect of oxygen and collector concentration on the contact angle and flotation behavior of chalcopyrite were interpreted.

Jan 1, 1991

By Igor Wilkomirsky

Professor Ralph Harris was interested in minor elements behavior in nonferrous pyrometallurgical processes. His approach always considered fundamental aspects and technological considerations for the assessment of different challenges that today are becoming critical, particularly for Andean sulfides ores, where the content of Va elements (As, Sb and Bi) has challenged available technologies. This reviews the status of control and monitoring of As in copper smelters to give a general framework for this now-common problem. Some selected results of R & D programs at the University of Concepción are presented in the field of roasting, presenting a novel proposition for flue dust treatment as an alternative to the classical hydrometallurgical processes for these type of materials. This presentation seeks to open a broad but precise discussion about the needs of research in this area with further experimental and physicochemical modeling. The pioneering visions developed by Professor Harris with his students are now a source of inspiration and an unavoidable source of information.

Jan 1, 2013

By George Mishra

In mid-1979, J&L Steel Corporation experienced rapid failure of pillars after only two weeks' operation with a combination of full retreat and partial mining in the 154 Road Section of its Nemacolin Mine, Greene County. The rate of advance of the "squeeze line" was very rapid for the first 500 feet, but it slowed down considerably as it approached some large coal blocks and gas well barrier pillars. After moving all section equipment out tc a safe distance, all accessible headings and crosscuts were filled with cribs and tri-set posts to prevent further spread of the squeeze. At one time, there was great apprehension by mine management that without implementation of some immediate corrective measures the safety of #3 airshaft and the only haulage and access road to the 8 Road mining area would be in jeopardy. In September, 1979, the U.S. Bureau of Mines established convergence monitoring stations outby the squeeze area. Readings were taken at weekly intervals until January, 1980, and monthly thereafter. Mathematical calculations, plot- ting of contour maps, and graphing of total convergence at different stations were used to follow and analyze the progress of the squeeze and provide guidelines for mining plans in the adjoining areas.

Jan 1, 1981

By Ray Y. Lin

This study explores the formation of sodium pyrosulfate in molten sodium sulfate resulting from dissolution of SO3 at temperatures between 1160 and 1250 K. Solubility of SO3 in Na2SO4 melts at temperatures between 1160 and 1250 K under gas mixtures of SO2, O2 and argon was investigated applying a thermogravemetric analysis (TGA) technique. The activity of Na2O in the melt was determined with a high temperature electrochemical cell (ECC). Results showed that the SO3 solubility in molten Na2SO4 increases with decreasing temperatures and increasing SO3 partial pressures. Enthalpy of SO3 dissolution in molten Na2SO4 was calculated to be -119 kJ/mol for infinite dilute solutions. Thermochemistry of Na2SO4-Na2S2O7 melts was analyzed based on information obtained from both TGA and ECC techniques. Detailed examinations of the earlier low temperature measurements in the Na2SO4-Na2S2O7 system along with data from this study reveal that the solution behavior between Na2SO4 and Na2S2O7 can be satisfactorily treated as regular with the interaction parameter, , being 2.7 kJ/mol. The phase diagram and the field of SO3 partial pressure has been generated with the thermodynamic calculation using a regular solution approach.

Jan 1, 2006

By S. K. Nandy, K. F. Unrug

The behavior of the immediate shaly roof within a drift mine in eastern Kentucky, operating in the Coalburg seam, was monitored with roof bolt dynamometers. The dynamometers used were capable of providing readings up to a maximum load of 66.72 kN (15,000 lbs), + 0.022 kN (5 lbs). To observe the influence of moisture on the rate and extent of roof deterioration, 57dynamometers were installed on roof bolts anchored in intake and neutral airways. Monitoring was conducted during the period January 1985 through January 1986, in order to cover a full cycle of dry and wet mine conditions associated with seasonal changes. Analysis of the data showed a trend of roof deterioration induced by condensation and eventual penetration of moisture within the immediate roof bedding planes, leading to rapid disintegration of the mine roof.

Jan 1, 1987

By Lisa Shevenell

Three pits at the Getchell Mine contained water during a hiatus in mining activity (1968-1983). For this period, expected concentrations of As, C1, SO4 and TDS resulting solely 16om evaporative concentration were computed. Computed values are 1.6 to 2.3 times greater than those measured in local groundwaters. However, computed values fix As, SO4 and TDS are lower than measured values in the pit lakes. In some cases, the computed values are only 8% of the measured pit lake values, indicating a major control on water quality via water-rock interactions. In contrast, computed C1 values exceed measured pit lake concentrations.

Jan 1, 2000

The paper deals with the taking of soundings in connection with coal mining operations under part of the Pacific Ocean adjoining John Darling Colliery.INTRODUCTIONIn the early days of mining in the Newcastle District there did not appear to be any definite law specifying the limits to which mine workings, other than certain borings, could extend under tidal waters.As time went on, a figure of 120 ft. was fixed as the minimum thickness of strata between the roof of the seam and the sea bottom; beyond this mining operations are disallowed. The laws relating to working coal under tidal waters are as follow:-The minimum width of pillars to be left shall be eight (8) yards and the maximum width of bords or other excavations shall be six (6) yards, but the lessee may at his discretion increase the minimum width of the pillars or decrease the maximum width of the bordsor other excavations so as to increase the general safety.The eight (8) yard pillars shall be left unwrought.In on-road of every pair of Winning-off or leading headings, a bore shall be kept going ten (10) feet in advance for the purpose of foretelling the presence of any fissure, wash-out, open joint, fault, dyke, or otherwise, and all winning-off headings shall be driven atleast one hundred (100) yards in advance of the working bords.The most accurate and trustworthy information shall be obtained by the lessee not only' of the depth and character of the ocean bed, river, lake, or estuary deposit, but also of the strata overlying the coal seam.When working under the ocean, strata shall be bored through and proved a minimum thickness of thirty (30) feet at the face of the leading headings or levels immediately such headings or levels are under the ocean, and...

Jan 1, 1947

By W. H. Su, S. S. Peng

Extensive investigation has been conducted to determine the causes of a series of roof falls occurring in an underground coal mine located in southern West Virginia. Underground observation, along with laboratory testings and finite element analyses, were conducted to search for possible mechanisms for the roof falls. Results of the investigation have led to a better understanding of the mechanisms involved in the roof falls. Necessary modifications of mine layout and roof support plan are proposed for improving safety and profitability at the mine.

Jan 1, 1987

By E. E. Duncan, G. Derce

REVIEW of the literature on hydrogen in steels indicates that inadequate consideration has been given to the influence of temperature gradients on segregation of this element. Even when segregation has been taken into account, the interpretation of the data has been seriously handicapped by incomplete understanding of the mechanism by which it occurred. Recognition of a mechanism which will be described as "thermal segregation" appears to rationalize many of the observed effects so well that it will be reported here with some preliminary experimental evidence. The complete quantitative evaluation of the factors controlling the mechanism will require extensive experimentation. The operation of the mechanism can be described in relation to fig. 1, which shows the temperature dependence of the solubility of hydrogen in iron at

Jan 1, 1951

By James R. Coldwell

Mining and processing cost analyses were conducted by the U.S. Bureau of Mines on stratiform zinc-lead-silver, coal, and stratiform barite deposit types that are found in the Colville Mining District. Reserves and gross revenues which would allow these deposits to be minable were modeled. A 15% Discounted cash-flow rate-of-return economic threshold was selected as the minimum acceptable return on investment for the three deposit types. The economic modeling indicated combinations of grades and tonnages for stratiform sulfide deposits that could be economically viable for orebodies ranging in size from 25 to 130 million metric tons. The gross revenues for a surface mine range from $200/mt for a 5,000 mtpd operation using the proposed South corridor to $140/mt for a 17,000 mtpd mine using the proposed North corridor. The economic modeling indicated underground coal mining was subeconomic for deposits ranging in size from 42 to 250 million metric tons. The required gross revenues ranged from $300/mt for a 2,200 mtpd mine to $21 D/mt for a 13,000 mtpd mine. The economic modeling indicated supplying projected in-state barite demand was subeconomic for the three seasonal surface mines modeled. The required gross revenues ranged from $600/mt for a 90,000 mtpy mine to $840/mt for a 6,000 mtpy mine.

Jan 1, 1995

By Forsythe DJ, Sun S-S Andrew AS

Paragenetic, fluid inclusion, stable isotope, and 87Sr/86Sr and 143Nd/144Nd isotope studies of the Mt Carbine tungsten deposit in North Queensland provide information on the sources of the mineralising components and record the history of fluid-rock interaction during the hydrothermal process. The ore minerals , wolframite and scheelite , are contained in quartz veins which post-date the major deformations in the Siluro-Devonian Hodgkinson Formation . Mineralisation was immediately preceded by the emplacement of the Mossman Batholith (280 ¦ 7 Ma). Two major stages of mineralisation are present and separated by a brittle fracturing episode . The stable isotope and Sr and Nd isotope data suggest that the ore fluids during stage I and most of stage II mineralisation were a mixture of magmatic water and non-magmatic water (connate or metamorphic) which had experienced a long residence time and had extensively exchanged with the sediments at high temperature. Subsequent mineralisation events were dominated by fluids of meteoric derivation with a short residence time. The data imply that other solutes, such as W, were probably derived in minor part from local country rock sources with the major contribution coming from a magmatic source related to the granite batholith.

Jan 1, 1987

By J. B. Darby, P. A. Beck

IN a previous publication,' the 1200°C isothermal section of the Cr-Mo-CO system was surveyed. It was found that starting from the binary (Cr,Co)a, the u phase extends deep into the ternary system in the form of a narrow band, which, when extrapo-

Jan 1, 1956

This paper presents the findings from an experimental study of the effects of shock and gas penetration breakage mechanisms in rick blasting. A blasthole liner method, which realistically seperated these two basic sources of energy in blasting, was developed and utilized. The use of four different explosives with contrasting detonation behaviour produced a wide variation in the nature of explosive energy transfer to the rock. Through extensive field experiments it was found that, relative to low VOD dynamite, the high VOD emulsion imparted greater shock to the rock and therefore produced finer fragmentation and greater back damage. The comparatively lower heave energy of the emulsion caused less immediate blast results were obtained with watergel and ANFO explosives, which have detonation behaviour and energy partitioning charecteristics lying between emulsions and dynamite.

Jan 1, 1990

By J. D. Miller, A. Cortez, J. Hupka

The separation efficiency of the hot water digestion-flotation technique used for bitumen recovery from various domestic tar sands was evaluated. Bitumen viscosity was found to be the most important tar sand property in determining the success of the bitumen separation. Bitumen viscosity of the tar sand war controlled by changes in digestion temperature and/or changes in diluent (kerosene) addition. Complete and uniform dilution of the bitumen phase was achieved by providing a sufficient presoaking, or penetration time, for a given tar sand type. For all the tar sand samples tested, an excellent correlation was obtained between the coefficient of separation and the bitumen viscosity. To achieve a satisfactory coefficient of separation, it was found that the bitumen viscosity must be reduced below 1.5 Pa.s (16 P) at the temperature of digestion. This was the case regardless of the tar sand type, grade, or origin.

Jan 1, 1984

By Earl Redman

The Juneau Gold Belt portion of the Juneau Mining District has historically had the greatest mining and exploration activity within the district. Between 1880 and 1983, the mines within the Juneau Gold Belt produced 6.7 MM oz gold, 3.1 MM oz silver, and 45 MM lbs lead, which had a total value of about $157,000,000 at the time of production. This report summarizes Bureau of Mines work completed in 1986, the second year of the Juneau Mining District study. Fifty mines, prospects, and occurrences were examined and 638 samples were collected for analysis during 1986. Metallurgical samples were collected from seven deposits and preliminary tests of cyanide amenability have been completed for five of these. The simultaneous discovery by private industry and the Bureau of gold-bearing quartz veins cutting diorite gneiss recently exposed by the retreat of the Herbert Glacier is the most notable result of work during 1986. This location yielded gold values up to 7 oz/st.

Jan 1, 2011

By G. P. Karmakar, K. K. Chandan

"The drilling mud is an essential part of the drilling process, which plays a major role in keeping safe and efficient oil and gas well drilling. In the oil industry, bentonite clay dissolved in water produces the simplest type of drilling muds. Bentonite clay contains montmorillonite particles. These particles are dispersed uniformly in water and such dispersions are used in various industrial products like paints, ceramics, pesticides and drilling muds. The bentonite clay easily dissolves in water and increases the viscosity of the water, which is one of the most important properties of a drilling mud. Bentonite has the highest swelling capacity, which is responsible for building up of the viscosity of the clay-water system. The flocculation behavior of bentonite is one of the major concerns for the performance of the water-based drilling mud in the oil and gas well drilling process. The behavior of drilling mud greatly depends upon the quality and quantity of bentonite clay, as well as the additives that are used in their formulations. In this work, a comprehensive study has been carried out to find out the effect of added polyacrylamide (PAM) polymer, surfactant, pH and salt concentrations on the dispersion/ flocculation characteristics of bentonite clay-water system. It has been observed that the increase in PAM dosage reduces the residual turbidity and improves the settling rate of the bentonite particles. The flocculation rate has also been found to be better under higher pH conditions. The combined effect of salt concentration and PAM dosage improved the overall flocculation efficiency of the system.INTRODUCTIONIn the oil industry, bentonite clay dissolved in water produces simplest type of drilling muds. Bentonite clay containes montmorillonite particles. These particles are dispersed uniformly in water. Such dispersions are used in various industrial products like paints, ceramics, pesticides and drilling muds (Akther et al., 2007). The bentonite clay easily hydrates in water and increases the viscosity of the mud system (Razi et al., 2013; Meng et al., 2012). Bentonite clay in the drilling mud increases the viscosity which is one of the most important prop erties of a drilling mud. Bentonite has the highest swelling capacity, which is responsible for the building up viscosity of the clay-water system (Sonmez et al., 2013). The drilling mud is an essential part of the drilling process, which plays a major role in keeping a safe and efficient oil or gas well drilling (ASME, S. S. C., 2005). The flocculation behavior of bentonite is one of the major concerns for the performance of the water-based drilling mud in the oil or gas well drilling process. This behavior of drilling muds greatly depend upon the quality and quantity of bentonite clay, as well as the additives that are used in their formulations (Yu and Amanullah, 2005; Akther et al., 2007). Bentonite particles form aggregate under certain conditions including high temperature, and high concentration (Luckham and Rossi, 1999). If the quality of bentonite is not sufficient to accomplish intended viscosity of the muds, it is essential to add certain additives to increase the viscosity and prevent aggregation of the system (Razi et al., 2013). The anionic polymer bearing sample can build up inter-particle bonds between the polymer and clay particles. The addition of various additives like, polymers control the dispersion and enhance the viscosity of the mud by controlling the flocculation of montmorillonite particles in bentonite dispersion (Heller and Keren, 2002; Mahto and Sharma, 2004)."

Jan 1, 2018

Goodenough and Fergusson Islands, in eastern PapuaNew Guinea, lie in an area of crustal extension on the western end of the Woodlark Basin seafloor spreading system. The islands are made up of a number of mountainous domes of complexely deformed basement, and these are intruded by large bodies of granodiorite. The domes are bounded by curved shear zones and faults dipping outwards at angles of around 25 to 45¦. The cores of the domes contain lower crustal rocks of eclogite and granulite facies, these rocks have undergone retrograde metamorphism in the outer sheared zones. Movement indicators on the shear zones indicate a complex moverm.-It geometry which does not fit the models proposed by earlier workers. These dome-like structures are similar to the metamorphic core complexes of the western United States Cordilleran region, however there are a number of aspects which do not fit with the models proposed for the development of metamorphic core complexes. Uplift of the metamorphic basement probably resulted from a combination of forces associated with the extension of the crust and the intrusion and emplacement of granodiorite plutons.

Jan 1, 1990

By D. W. Kestner

Recent developments and trends in the state of the art as being commercially applied to the pelletizing and sintering of metallic ores, concentrates and reverts will be reviewed. Both ferrous and non-ferrous materials will be covered. The influence of environmental considerations on the decision to build, the process selection, and design of the plants will be discussed. Use of coal in iron ore pellet induration will also be reviewed as the availability and price structure of oil and gas becomes a consideration to the plant operators.

Jan 1, 1980