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Cobalt mostly occurs as a minor, but valuable, constituent in most nickel and a few copper ores, however it is not generally found alone in commercially viable deposits. Its concentration and extraction are therefore intimately linked to the recovery of the primary metals and the major task for the metallurgist is to extract cobalt of commercial grade from a much larger mass of either nickel or copper and sometimes both. With a particular focus on Vale Inco?s operations, this paper provides a brief overview of the mineralogy of the main deposits being currently exploited that contain cobalt as a co or by-product. The concentration and then extraction to metal are reviewed and some advances released into the public domain are discussed.

May 1, 2009

By W. W. Mason

The US began exporting coal in the late 1800s, at first in very small quantities to Canada and, beginning in 1897 and 1898, to the east coast of South America. Shipments to European countries began on a very limited basis in 1902 and these shipments increased gradually until World War I when shipments overseas increased from 7.3 Mt/a to 20 Mt/a. After the war exports dropped as fast as they had increased and, with the exception of exports to Canada, remained at very low levels until just after World War II when the US again emerged as a major coal exporter. World War II left the coal industries of Europe in ruin. As the US was the only country able to supply large quantities of coal at reasonable prices needed for reconstruction of the European economy, the US coal exports overseas expanded rapidly to 38.6 Mt in 1947. Additionally, we shipped 23.8 Mt of coal to Canada in that year for a total export of 62.3 Mt. Unfortunately, that level was not reached again until 1957 when exports reached an all-time high of 69.3 Mt - a high that has not been reached since. Over the years the level of US coal exports has fluctuated fairly widely. Approximately 80-90% of all US coal exports are high quality metallurgical grade coal so our exports level depends directly on world-wide economic conditions and world steel production levels.

Jan 1, 1982

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar, J. M. A. Geldenhuis

The successful application of solid electrolytes in electrochemical cells for high-temperature thermodynamic studies depends to a large extent on an accurate knowledge of the P. value of the electrolyte (the oxygen partial pressure at which the ionic conductivity and n-type electronic conductivity of the electrolyte are equal). Consequently, the P. value of an electrolyte must be determined prior to its use in electrochemical cells. This paper describes the successful application of a coulometric titration technique in the quantitative assessment of the P. values of a commercially available ytria-stabilized zirconia electrolyte that has been used extensively by local investigators. The experimentally determined P. values of the electrolyte are reported and compared with P. values reported in the literature for a similar electrolyte.

Jan 1, 1988

By Rick Deschamps, Brian Barkauskas, Aled Hughes, Abigail Stein

In central Washington, six miles south of the small town of Vantage, the flow of the Columbia River is harnessed by the Wanapum Dam which is part of the Priest Rapids Hydroelectric Project owned and operated by Grant County Public Utility District (GCPUD). Extending more than 8,300-feet from bank to bank, the dam includes left and right earth embankments, left and right concrete gravity sections and a 10-unit powerhouse. Adjacent to the right embankment is a concrete gravity spillway featuring radial gates measuring 50-feet-wide and nearly 70-feet-high. In the early 1960’s when Wanapum Dam was built, these seven-story spillway gates were the highest in the world. In late February 2014, 50-years into its service life, during a routine maintenance inspection, observant workers noticed a slight misalignment in the roadway deck curbs and handrails located on top of the spillway. Further survey and inspection efforts uncovered a 65-foot-long by two- inch-wide crack that spanned the full length of Monolith 4. On discovering the extent of the damage, GCPUD initiated immediate drawdown of the reservoir to relieve pressure on the spillway monoliths. Wanapum Reservoir and the areas directly downstream of the dam were immediately closed, boat ramps and inlets were left completely dry, campsites were closed and boating activity was banned on the lake until further investigations and remedial procedures were in place and completed. An extensive root cause analysis ultimately led to the conclusion that errors in the initial design calculations and late changes to the final spillway design led to a condition that generated tensile stresses in the concrete at the upstream face, which over a period of 50-years resulted in the formation of a crack along a horizontal lift joint located about 85-feet below normal pool elevation. Further analysis showed that, although visible distress was found at Monolith 4, there was nothing preventing this issue from happening at other locations along the dam spillway. Although no visible cracking was found in the other monoliths, repair procedures for Monolith 4 would have to be replicated at the remaining monoliths.

Jan 1, 2018

By M. Melashvili

"The SART Process was introduced to the gold mining industry in the late 1990s and several commercial plants were built over the following 10 to 15 years. Most of these plants have operated well and enjoyed plant performance in line with expectations based on the underlying chemistry of the process. However, two of the plants have consistently suffered from high reagent consumption and poor product quality, which has motivated a re-examination of the process fundamentals.The primary product in the SART Process is synthetic chalcocite, Cu2S, and the stoichiometric requirement for sulphide addition is therefore 0.5 moles per mole of copper in solution. It is shown here that when sulphide is added in excess of this amount (generally with the express purpose of lowering residual copper in solution) it not only fails in its intended purpose, but can have a negative impact on the settling and filtration characteristics of the copper sulphide product, as well as the final product quality. Moreover, these problems are exacerbated the higher the selected operating pH in the pH 3 to 5 range, and the longer the residence time of slurry in this pH range.Freshly precipitated copper sulphide compounds are known to be very fine and slimy, with poor settling and filtration characteristics. It is therefore important to engineer the SART Process in such a way as to encourage growth in the average particle size of the precipitate crystals. This was the rationale for recycling a portion of the thickener underflow to the primary reactor when the SART Process was developed. However, the theory of crystallization predicts that compounds of extremely low solubility, such as chalcocite (Cu2S: KSP = 10-48), are unlikely to experience growth in crystal particle size through heterogeneous nucleation and are more likely to grow through aggregation. On this basis, the SART practice of recycling a portion of thickener underflow to the primary reactor in the commercial plants is unlikely to lead to crystal growth via nucleation, and could in fact promote breakage of the aggregates that formed in the thickener. Recycling thickener underflow could therefore have the opposite of the desired outcome. The result of testwork that is reported here lends credence to this theory and questions the wisdom of recycling in the SART process."

Jan 1, 2016

In general, it cannot be assumed that the strength of coal pillars remains constant over long periods of time. Field observations indicate that a coal seam, especially when it contains a parting layer, deteriorates over time, reducing the load-bearing capacity of the pillars. This paper discusses a unique approach to determining the time-dependent strength of coal pillars in the field. Three coal pillars that were developed 5, 15, and 50 years ago were chosen for the study. Holes were drilled in coal and parting layers in each pillar, and the strength profiles were determined for each hole using a borehole penetrometer. The strength data were treated statistically to establish time-dependent strength equations for different layers. The results can be used to help estimate the loss of pillar capacity over time.

Jan 1, 2012

Over the past few years, the School of Mines of Paris has carried out a program of research* on the grade-tonnage relationships in the border zones of porphyry copper deposits. The initial problem was quite difficult : how does the grade vary at the border of the known orebodies? Does it decrease regularly, or do some thresholds exist, where the grade diminishes abruptly? The answer to these questions have important repercussions on the prediction of the future reserves in the fringe of the orebodies. If the grade decreases regularly, very important reserves could exist; if not, there would be strong limitations to the possible recoverable reserves. The first step of our study was a critical study of previous work done on the subject. It appeared that, following Lasky's pioneering paper (Lasky, 1950), most of the authors used what we can call an historical approach to the problem. In this, the grade-tonnage relationships are calculated from the available figures for production and reserves and the results are then extrapolated to the future. The strong limitation of this model are brought out in this article.

Jan 1, 1982

By Donald D. Smythe

Tars paper describes briefly the topography and geology of the region where the mica-bearing pegmatites are found and discusses prospecting, the quality of the mica, its preparation, and evaluation of the deposits. Muscovite mica occurs in a number of widely separated localities in Brazil, but production has come largely from deposits in the southeastern and eastern part of the State of Minas Gerais (Fig. I). There the deposits form a discontinuous zone, which starts at a point 90 km. north of the city of Rio de Janeiro and extends north for some 500 km., roughly parallel to the coast. A maximum width of 180 km. is reached along the Rio Doce. To the west in Minas Gerais, and extending east into the states of Espirito Santo and Rio de Janeiro, the mica zone proper is fringed by areas in which there are scattered occurrences of mica-bearing pegmatites. A few of these outlying deposits have produced commercial mica, but most of them are unimportant. To the southwest, in the State of São Paulo, there are a number of mines, which at one time produced a very considerable amount of sheet mica, largely as a by-product of kaolin mining. These deposits, and, a few others lying between them and the main productive areas to the northeast, appear to be the southwestern continuation of the strong Minas Gerais mica zone. In the vicinity of Conquista, just north of the Minas Gerais boundary in the State of Bahia, and still farther north, near Jacobina, there are several known mica deposits. Their location indicates that they may be the northern continuation of the main mica zone. The major part of Brazilian mica production has come from four areas within the mica zone proper; from north to south, Governador Valadares, Raul Soares, Espera Feliz, and Muriaé. The first is 190 km. from north to south and reaches a maximum width of 180 km. The Raul Soares area extends 135 km. from northeast to southwest, and in places is 80 km. wide. The Espera Feliz area is 100 km. from north to south, and reaches a width of 35 km. The Muriaé area extends 150 km. from northeast to southwest and its width reaches 40 kilometers. Between the known productive areas, and in the areas directly to the southwest and to the north of them, little mica has been produced. These gaps, as well as certain irregularities in the outline of the mica zone itself, are to be ascribed either to lack of prospecting or to conditions preventing the discovery of mica, rather than to its nonexistence. Elsewhere in Brazil mica has been reported from eastern Goiaz, Ceará, Pernambuco, Rio Grande do Sul, Matto

Jan 1, 1946

By Thomas M. Barczak

State-of-the-art longwall roof supports provide effective strata control, but failures of these support systems still occur. To identify failure mechanisms and the impact these failures have on the safety of the support system, the U.S. Bureau of Mines has been conducting research on shield mechanics in the Bureau's unique mine roof simulator, as well as field studies of in situ support loading and investigations of longwall failures, Three types of failures are discussed: (1) inadequate support capacity, (2) structural failure, and (3) instability. Hypothetical situations with proposed courses of action and case studies of actual longwall failures are described. This information is intended to assist the Mine Safety and Health Administration (MSEIA) and industry mining personnel in safety evaluations of longwall roof support systems.

Jan 1, 1989

By J. A. Benell

DIOXIDE of silicon, commonly called silica, is one of the greatest single constituents of modern in-dustry. It is brought most clearly to the mind when we consider the various kinds of sand and their rela-tion to industry. The major portion of.all sand is silica, and should be its principal component part in building materials. As an abrasive for cutting, polish-ing and sand-blasting, sand serves a vital purpose in many industries. Even lumber is now being sand-blasted, to cut away the softer grains of wood, leaving the harder grains in relief. The result not only in-creases the beauty of the wood, but adds to it an ap-pearance of antiquity. The common uses of silica in industry may be classified about as follows: Chemical industries-filtering medium; manufacture of carborundum; manufacture of water-glass. Paint-inert extender. Mineral fillers-wood filler; filler in rubber, hard rubber, pressed and molded goods, phonograph records.

Jan 5, 1928

By Noris Costa

La posibilidad de construir presas hechas con los propios relaves que van a ser contenidos posteriormente, es una alternativa común en la minería. Sin embargo, durante el levantamiento histórico de estas estructuras, se identifican diversas rupturas, liberando las masas contenidas en las presas y contaminando el medio ambiente. En este sentido, el presente trabajo señala los geoindicadores como herramientas de monitoreo de presas de relaves -en tanto el estudio de estas características ha posibilitado discusiones al respecto de la seguridad de estas estructuras, así como propuestas de medidas de control.

Sep 9, 2007

By H. Yoshida, B. G. Liebmann, R. E. Green

In recent years considerable work has been undertaken in order to gain an understanding of the mechanisms responsible for the generation of recrystal- lization textures in face-centered-cubic metals. Two theories have been proposed, that of oriented growth1 and that of oriented nucleation,' and several attempts have been made to check these theories directly by recrystallizing deformed single crystals.3-5 Two groups, Graham-Cahn and Liebmann-Liicke-Masing, studied the orientation of recrystallized grains and their rate of growth, both using strained aluminum single crystals of commercial purity (Graham et al., 99.6 pct, Liebmann et al., 99.8 pct). Surprisingly, the results obtained by the two groups were completely

Jan 1, 1960

By Clemens Jones

The difficulties attending the reduction of ferric sulphate in the determination of metallic iron by the method of Marguerite, are often serious, and affect time, patience and accuracy. They depend upon the condition and purity of the zinc used, the state of saturation of the solution, acidity, and temperature. D. J. Caruegie (Chem. News, lvii., No. 1481), says that ferric solutions are instantaneously reduced by the use of zinc-dust. But there are obvious objections to its employment in quantitative work. Dr.

Jan 1, 1889

Almost from the beginning of civilisation the inhabitants hadlearned the art of recovering and working copper to produceitems which were of use to society.From the early beginnings of the use of copper which can betraced back 6000 years and more, there has been an evolutionaryprocess accentuated in more recent times in which the art ofproducing alloys particularly with tin and latterly zinc and otherelements, has given society a wide range of useful alloys for usein industrial, domestic and architectural applications.

Jan 1, 1995

The use of systematic review methods, derived from System Safety approaches used in the North American nuclear power industry, have become an accepted approach for seeking "approval" for new coal mining equipment and operational changes in NSW. Based on risk analysis, they provide a valuable and needed framework for the reduction of losses related to people, equipment and production.

Jan 1, 1991

By P. R. Janisch

This paper reviews the sources, production, and technology of gold in South Africa. First of al it details the geographical distribution of gold-bearing materials, together with the mineralogy and distribution of gold within those materials. It goes on to the geological origins, and to the discovery and early exploitation, of the gold deposits. The laws relating to the mining and disposal of the metal are explained, after which an outline is given of gold exploration, processing, and refining. The economics of gold production are discussed briefly, and it is concluded that, although present expertise in the financial and technological aspects of a gold-mining venture have largely reduced the risks involved, one severe risk remains: that the rate of cost inflation will not be matched by the rate of escalation in the gold price.

Jan 1, 1986

By Anderson DR, Tassell G

A major environmental impact study carried out in the sand dunes of eastern Cape York used image analysis of remotely sensed data to both select sites for ground investigation and categorise the different ecological units present. The approach adopted was particularly suited to the type of environment in question and allowed a high degree of quantification, at a high level of confidence, at costs several orders of magnitude less than conventional Methods.

Jan 1, 1987

By Richard Klimpel

This paper describes the effects of slurry viscosity on the selection-for-breakage and breakage distribution parameters in the wet grinding of ores. A series of experimental tests were run on laboratory scale ball mills. Slurry viscosities were modified by varying the solids/water ratio with and without the presence of selected chemicals. Very consistent and predictable correlations are shown to exist. The grinding parameters were calculated using a computerized back-calculation technique developed by Klimpel and Austin. Industrial scale circuit calculations and preliminary plant trial data suggest that considerable increases in throughput and/or fineness of grind can be achieved through the judicious use of chemical additives.

Jan 1, 1977

Five types of mineral resource were known in the sedimentary cover of the oceans and seas floors prior to the 1980's :1) hydrocarbon fields including some very large zones of oil and gas accumulation; 2) "Red Sea" type thermal oozes with increased concentrations of noble metals; 3) ferromanganese nodules; 4) concentrations of metallic sulphides ("Black Smokers"); and 5) cobalt-bearing ferromanganese crusts on the summits and slopes of seamounts. Since then, the so called "White Smokers", containing sulphides of copper and zinc, have been discovered. The ore horizons (manganese, copper, nickel and other metals) of the sedimentary cover of deep-sea basins comprise a sixth type of mineral resource in the oceans. These horizons have not only a theoretical, but also a principal economic significance

Jan 1, 1995

By Hendrix JL, Nelson JH

Three ores (sulfidic, oxidized and carbonaceous) were analyzed to determine the effects of leaching time, ore depth, and ore mineralogy on cyanide species concentration. NaCN solutions were percolated through opaque columns filled with milled ore. Column design made liquid sample collection possible from various depths at specific times. The concentrations of weak acid dissociable(WAD) and total cyanide, Fe(CN)63 , Fe(CN)64 , SCN , and Cu(CN)43 were determined for each sample. Extended percolation time led to increases in WAD cyanide concentra- tions and decreased SCN and Cu(CN)43 concentrations regardless of ore depth. WAD cyanide concentration decreased while Fe(CN)64 concentra- tion increased with ore depth. Highest concentrations of Fe(CN)64- SCN and Cu(CN)43 were found in the sulfidic ore, with expected low WAD cyanide concentrations. Lowest concentrations of Fe(CN)64 , SCN 3 and Cu(CN)4 were found in the oxidized ore. Intermediate concentra

Jan 1, 1988