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By C. Ernest Birchenall

As a basis for further progress in several branches of metallurgy, particularly the study of physical properties of solid solutions and the kinetics of solid-solid reactions, a more complete understanding of the structure of solid solutions and the nature of the metallic bond is necessary. Any investigation contributing to this understanding should be of primary interest to the metallurgist. Since the metallic bond is characteristic of an assemblage of atoms, it can be studied only where this assemblage exists. One of the most promising approaches to this study of the interactions in metals is through the general problem of binary metallic solutions. Although crystal structures of many solid metallic solutions have been determined and solubility limits for many systems are given in phase diagram studies, progress beyond this is irregular. Electromotive force and vapor pressure determinations have provided thermodynamic activity data for small concentration and temperature ranges in the amalgams and a few other systems.1 In two systems, however, copper-zinc and iron-carbon, data are available for the calculation of activities over wide ranges of temperature and concentration. This activity data for the brass system is summarized in. the preceding paper.2 A detailed study of the solubility and distribution of carbon in iron is given by Smith and Darken .3 Their treatment of interaction energies is applicable only to dilute interstitial solutions. The objectives here will be to derive from activity data given in the previous paper for the brasses and structural considerations as much new and detailed information as possible about the interactions between copper and zinc in metallic solid solution and the effect of these interactions in determining the short range structure of the equilibrium phases; that is, we shall investigate the energy of interaction between pairs of atoms of the same and different kinds, the deviations of the distribution of nearest neighbors from complete randomness, and show that the conclusions found are consistent with the observed behavior of the brass system. The method of treatment is fairly general for substitutional metallic solid solutions and will be applied to other systems. The determination of vapor pressures of the components of alloy systems is being undertaken in this laboratory to supply more data for this purpose. The information obtained from solid solutions may be extended by careful analogy to liquids as long as the metallic type of bonding is preserved. Since it will be necessary to employ the language of thermodynamics, a brief summary defining the terms used extensively in solution theory is given below.

Jan 1, 1947

By Thomas M. Brady

The Spokane Research Laboratory/NIOSH and the University of British Columbia (UBC) geomechanics group are focusing on the development of safe and cost-effective underground design guidelines for weak rock masses having an RMR in the range of 15 to 45. Weak ground conditions, ground support, and mining methods used in several North American underground mines were observed. The RMR values were calculated to update both manned entry span design and non-entry stability graphs, plus a database on underhand mining methods was created to reflect existing North American mining conditions. The immediate rock mass was characterized and analyzed in terms of prevailing type of ground support, potential failure mechanisms, and rock behavior to define how existing design curves must be modified for the existing weak rock mass. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making sound economic decisions that will also ensure a safe working environment.

Jan 1, 2006

By A. A. Bradley, P. J. D. Lloyd, A. J. Freemantle

Developments in centrifugal milling by A. A. BRADLEY,B.Sc. (Rhodes) (Visitor), A. J. FREEMANTLE, B.Sc. Hons. (Wits) (Visitor), and P. J. D. LLOYD, B.Sc. (Chem. Eng.), Ph.D. (Cape) (Fellow) The theoretical and experimental results of a study of centrifugalmills are reviewed. Means for the scaling up of such mills are suggested, and tests on a prototype mill are described. Despite the high lining wear in the centrifugal machine, which reduces its productive availability, its other advantages suggest that there is merit in pursuing its further development.

Jan 6, 1974

By D. S. Loubser

The technique of backfilling in the gold mining industry is dependent on the dewatering of slurry to form a solid support system. In many cases flocculants are added to the slurry to increase the rate of dewatering. To ensure that a stable support is obtained it is important that the chemistry, application and limitations of these flocculant additives are understood. Flocculant additives have to be added at a point where minimum shear will occur. (Shear occurs when a flocculant is exposed to excess energy resulting in breakdown, of the floc.) To ensure that optimum results are obtained it is important that personnel involved are trained to use the flocculant additives and dosing equipment correctly.

Jan 1, 1988

By Selby DW, Hamill J, Cauley ID, Thomas I, Thornton AJ

The main objective of sulphide flotation in a cassiterite concentrator is to remove sulphide minerals (pyrite, pyrrhotite and sometimes chalcopyrite) from the ore prior to gravity concentration. Tin losses in the sulphide flotation stage account for a significant proportion of the total tin loss. separate studies of the sulphide flotation circuits of Renison Ltd and Cleveland Tin Ltd were conducted to investigate reasons for the tin losses. Sampling surveys were conducted in the rougher-scavenger and also the regrind-cleaner sections of both plants. In both plants, the rougher circuits recover excessive quantities of liberated cassiterite, while recovery of the desired composite cassiterite-sulphide fraction is low. The regrind mills are successful in liberating the composite cassiterite in the rougher concentrate, but at the expense of increasing the proportion of very fine tin mineral. The cleaner circuits recover between 40 and 60% of the cassiterite received, and this is all lost.

Jan 1, 1978

By T. Sterry Hunt

BUT little was known of the coals of Southeastern Ohio until the present survey of the State under Dr. Newberry began its work. The results of the geological investigations of Prof. E. B. Andrews in this region, and of the chemical investigations of Prof. T. G. Wormley, both of which appear in the reports of the survey for 1869 and 1874, and more recent special reports by the former, together with some data for which I am indebted to the kindness of Dr. Newberry, and my own limited observations, have served me for the preparation of the following notice of the coals lying on the western border of the great Appalachian coal-basin in the region drained by the Hocking River and its tributaries, and belonging to the Lower Coal-Measures. Some uncertainty exists as to the place in the succession of the lower coals to be assigned to the seams known and mined in the Hocking Valley. It is the opinion of Prof. Andrews that the inequalities of the original surface were such that we cannot identify in that region the lowest coals known in Northwestern Pennsylvania and the contiguous parts of Ohio, but that we must rather count from above downwards. These conclusions Dr. Newberry is not prepared to accept, and further researches will be necessary before certainty can be attained in this matter. Meanwhile it seems, from a study of its relations to the Pomeroy or Pittsburgh seam, that what is known as the great vein of the Hocking Valley, occupies the horizon of the Upper Freeport coal, E of the Pennsylvania survey, or No. 6 in Dr. Newberry's enumeration, counting from the base. This seam, in the region in question. assumes certain characteristics which, taken in connection with its geographical position, give it a great importance among the coals of the State. The area to be noticed includes the whole or parts of several townships in Perry, Hocking, Vinton, and Athens Counties, lying near the margin of the basin over which the vein in question assumes the character of a dry-burning or splint coal, and has a thickness varying from six to ten and even twelve feet. Its precise limit southward cannot at present be clearly defined, but it has been found as far south as the line of the Marietta and Cincinnati Railroad, with a thickness of six feet, and is mined at various points along the valley of the Hocking River, near Nelsonville, where it attains six or seven feet. To the northward, along the tributaries of this river, Sunday and Monday

Jan 1, 1874

By M. Arias

"An attractive foreign investment legislation, an anti-mining framework in the jurisdiction where a head office is located, the geographical location of the mineral resources, a country that offers the technology needed by the industry for its operations -- these are some of the many factors that make mining and mineral exploration a global business. It is precisely in the complexity of this new era of globalization and market environment, that sustainability initiatives are challenged. Responsible management of mineral exploration and mining is no longer defined by the use of efficient technology and resource management. Sustainability is not only a report compliance exercise or a green revolution. Sustainability is like any business, a long term profitable proposition. This new approach encompasses four pillars: social, economic, environment, and culture. This new approach connects humans and corporations; it is the way to engage, respect and improve relations with the people with whom we work and our neighbours."

Jan 1, 2011

By P. G. Keohane, J. S. Drake

"Cominco's Polaris Mine is a lead-zinc underground operation that began commercial production in early 1982. The mine site is located on Little Cornwallis Island in the Canadian Arctic at a latitude of 75°23'N and at a longitude of 96°55'W. The nearest settlement, Resolute Bay, some 100 kilometres southeasterly from the mine, is accessed from the mine by light aircraft. The mine site can be accessed by sea during the six-week ice-free period each year. During this time all major operating supplies are brought to the mine and the lead and zinc concentrate products are shipped out to market.GeologyThe Polaris orebody lies near the top of the Thumb Mountain Formation of Ordovician age. This formation is a relatively homogeneous section of thin to medium bedded limestones which are brecciated and dolomitized in the area around the orebody. The deposit is described as a Mississippi Valley-type orebody. Ore minerals are sphalerite and galena with the waste being predominantly dolomite with calcite and marcasite. The ore is quite porous with voids being generally filled with ice as the mineralized zone lies entirely within permafrost. Reserves consist of about twenty million tonnes of ore grading 3.8% Pb and 14.3% Zn with a further three million tonnes of inferred ore at a slightly lower grade.The orebody strikes in a north-south direction with the hangingwall dipping at about twenty degrees to the east. It is generally conformable with the stratigraphy. The footwall in the western portion of the orebody, the Panhandle, lies about 10 to 30 metres below the hangingwall. To the east the footwall drops sharply, creating an orebody height of up to 110 metres in what is referred to as the Keel Zone. The Panhandle Zone has typically 80 - 110 metres of cover above the hangingwall , About 25% of the reserves are in the Panhandle Zone, the remainder being in the Keel Zone. Figure I illustrates a plan view of the orebody relative to other surface facilities on the property and Figure 2 illustrates a simplified section through the Panhandle and Keel Zones."

Jan 1, 1985

By Kimio Itagaki, Torn Matsumoto, Makoto Ohtsuka, Kentarou Harada

"The structure and hydrogen-absorption properties of LaNis thin films were investigated in the present study. LaNis thin films were prepared by a sputtering method with a radio-frequency power, Ws, of 50 -400 Wat substrate temperature, Ts, of323 -573 K. Nickel content of the films decreased with increasing Ws, however, there was no dependence on Ts. At low Ws and low Ts, amorphous films were deposited. In other conditions, the films were polycrystalline. The films prepared at high Ws and low Ts, or at low Ws and high Ts, exhibited only a (h k · 0) peak in the X-ray diffraction profiles. This indicates that the c-axis of crystalline films was oriented parallel to the substrate plane. At high Ws and high Ts, the films with columnar structure were obtained. Hydrogen-absorption capacity of the thin films increased with increasing Ws. The pressure plateau did not appear on the pressure-composition isotherms. The films deposited at high Ts represented a higher equilibrium pressure.IntroductionThin films of hydrogen storage alloys can be applied for an electrode of rechargeable battery or fuel cell, a filter for H1 purification and various kind of sensor. Some studies on the preparation of the thin films of LaNi5 intermetallic compound, which is a typical hydrogen storage material, have been done hitherto. Adachi et al. , 2) and Sakaguchi et al. 3) prepared amorphous and crystalline LaNi5 thin films using flash evaporation of alloy powders and measured the pressure-composition isotherm for the prepared film utilizing a quartz crystal mass monitoring (QC:MM) method. It was found that the prepared amorphous film absorbed hydrogen without disintegrating into the powders and the hydrogen-absorption capacity of the films increased with the degree of crystallinity. Sakai et al. 4) reported that the maximum hydrogen storage capacities of amorphous and crystalline LaNi5 thin films, fabricated by a RF sputtering method using combination targets, were about 40 mA h g-1 (LaNisHo.7) and 160 mA h g-1 (LaNi5H2.6), respectively. Uchida et al. 5, 6) prepared LaNi5 thin films using flash evaporation of alloy powders and measured volumetrically the pressure-composition isotherm for the prepared film. It was reported that the hydrogen-absorption capacity of the films changed by the annealing treatment."

Jan 1, 1998

By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012

By Douglas W. Fuerstenau

Technological innovation is needed to meet the challenges that face the mineral industry because ores steadily become lower in grade, more complex in mineralogy, and must be processed in the face of ever- increasing environmental constraints and increased costs. How periodic innovation in mineral processing helped overcome the challenges that faced the mineral industry is briefly traced from antiquity up to the present time.

Jan 1, 1989

B. F. TILLSON,* Franklin Furnace, N. J.-I would like to ask Major Yerkes if he will not give us more examples of the tests than are contained in the printed pamphlet. It would be of great interest to study them more carefully. ROBERT M. YERKES, Washington, D. C.-The reason for not reproducing the methods in any public print is that it lessens their value and necessitates the preparation of new test materials. BRADLEY STOUGHTON, New York, N. Y.-I hope that this matter will be of so much interest to the members of the Institute that the Directors will decide to appoint a committee which can bring further results of this practice before us. I understand that Columbia University, at least in some departments, has already adopted the B and A tests and is using them. I understand that some industries have considered seriously the question of grading their employees in accordance with

Jan 4, 1919

By B. J. Buys

Rock bolt integrity is a critical issue for the mining industry because of its influence on the safety of mining operations. Guided ultrasonic wave testing of the defects associated with resin-anchored rock bolts was investigated. Axisymmetrical and three-dimensional finite element models were built, one of a partially encapsulated bolt and the other of a bolt with a simulated local corrosion crack. Experimental bolts were then installed in a testing block and typical responses were compared to finite element models of different defect scenarios. Encouraging results were obtained for the smaller axisymmetrical and three-dimensional finite element models, as well as during the experimental investigation. It is recommended that software with energy-absorbing elements should be utilized to consider higher frequencies and longer bolts. Once the integrity of models such as these has been established, the models could in principle be used to train neural networks for use in commercial equipment to determine the integrity of the installed bolt.

Jan 1, 2009

By Albert Sauveur

SOME writers believe that when austenite transforms completely into pearlite on slow cooling through the thermal critical range, such transformation does not imply the formation of any of the so-called transition constituents: martensite, troostite and sorbite. Might it not be claimed with as much justification that when water freezes it does so suddenly, solid ice being obtained without passing through the intermediate stages of ice and water? Obviously, regardless of the speed of solidification, this would be erroneous. Before reaching the completed solid condition, this must of necessity pass through an unbroken series of stages when the system consists of mixtures of water and of ice, the former decreasing and the latter increasing in amount. Are not these "transition" stages in the freezing of water similar to the transition stages occurring in the transformation of austenite into pearlite? To clarify, let us consider in Fig. 1 the mechanism of the transformation of eutectoid steel from its austenitic to its pearlitic condition as it cools slowly through its thermal critical range. It is generally admitted that this transformation is the result of two distinct phenomena: (1) the allotropic change of gamma iron into alpha iron and (2) the crystallizing out of solution of the carbide Fe3C. Whether this crystallizing of Fe3C implies also its formation is immaterial for our purpose. In other words, whether it is the carbon in atomic dispersion which is present in gamma iron or molecules of Fe3C has no bearing upon the matter to be discussed. The transformation of gamma iron into alpha iron cannot take place suddenly. It must of necessity be progressive, regardless of the speed with which it may take place. At A, for instance, there would be present AB gamma iron and BC alpha iron. The distance MN does not refer to falling temperature, but to the passage of time. It may be assumed that the transformation takes place at a constant temperature (the Ar321 point). In a similar way, the crystallization of Fe3C out of the austenite solid solution must be progressive as depicted between M and N. At A there would be present AB gamma iron, BC alpha iron, CD carbon dissolved in gamma and in alpha iron and DE Fe3C. This condition may be described according to individual preference as martensite or troostite. To sum up, can the metal pass from condition

Jan 1, 1931

By M. Troyer

A coal shuttle car equipped with a pulsed laser optical ranging system to provide guidance for an automatic steering system was tested in production coal mining. Test results are presented for the two mines where testing took place, and some operator's reactions are included. Automatic steering control keeps the car cantered in an entry, and automatic turns are made at intersections as signaled by the operator. All other controls-tram, conveyor, brake, etc, remain manual and require operator control. Complete override of steering while in the automatic mode is retained by the operator, who may grab the steering wheel at any time and turn in opposition to the automatic signal by applying about 10 foot-pounds of torque.

Jan 1, 1976

By Steve Kral

The mining industry is no stranger to hard times. Throughout its history, the industry has faced the ups and downs of commodity prices, difficult-to-mine-and-process ore bodies, labor issues and other problems. Throughout it all, though, the mining industry continues to provide the materials needed for society —even in the face of attacks by those who seek to cripple the industry or have it go away. The reason the mining industry survives, of course, is that mankind requires the products the industry produces. And, in recent decades, the industry has developed new technologies and improved on existing ones to produce those products in environmentally sound ways. At the same time, the economic benefits have been enormous to communities throughout the world where mining takes place.

Jan 1, 2002

1. Book reviews A report by the Monopolies and Mergers Commission on the efficiency and. costs in the development, production and supply of coal by the NCB (Chairman G. Le Quesne). London, Her Majesty's Stationery Office, Jun. 1983. £20 for report and appendices (2 vols). Reviewer: M. J. Martinson Canadian mines handbook 1983-84, edited by M. R. Brown. Toronto, Northern Miner Press Ltd, 1983. 444 pp. $22. Reviewer: Northern Miner Review Editor 2. New publications Developments in geophysical exploration methods-5, edited by A. A. Fitch. Barking. Applied Science Publishers Ltd (Ripple Road, Barking, Essex IG II OSA, England), 1983. 255 pp. £35.75. High-pressure researches in geoscience--behaviour and properties of earth materials at high pressures and temperatures, edited by W. Schreyer. Stuttgart, E. Schweizerbart'sche Verlagsbuchhandlung, 1983. 545 pp. DM 188. Dynamics of oil and gas accumulations, by Alain Perrodon. Pau, Elf Aquitaine (Documentation Centre Micoulau, 64018 Pau, France), 1983. 368 pp. 240 FF. New paths to mineral exploration, edited by F. Bender. Stuttgart, E. Schweizerbart'sche Verlagsbuchhandlung, 1983. 169 pp. DM 58. Results of the First Workshop on Standards in Geothermics, edited by R. Haenel and M. Gupta. Stuttgart, E. Schweizerbart'sche Verlagsbuchhandlung, 1983. DM 98. E&MJ book of jlowsheets edited by Paul C. Merritt. New York, McGraw-Hill, 1983. 214 pp. $42. 1983 E&MJ international directory of mining. New York, McGraw-Hill, 1983. 808 pp. $70. The future of heavy crude and tar sands - volume 11. New York, McGraw-Hill, 1983. 1300 pp. $1l0. 3. Mineral Policy and Energy publications Aluminium, by A. Johnston. 12 pp. . Arsenic, by J. J. Hogan. 4 pp. Cobalt, by D. G. Fong. 6 pp. Selenium and tellurium, by A. G. Johnston. 7 pp. Stone, by D. H. Stonehouse. 13 pp. Uranium, by R. T. Whillans. 16 pp. 4. Mintek publications Report M88 'l'he recovery of platinum-group metals and gold by the lead-collectionstep of thefire-assay procedure. Report MI04 The preparation and analysis of reference materials, and the provision of recommended values. Progress report no. 5. Report Mll1 The determination, by flow-injection analysis, of iron, sulphate, silver, and cadmium. Special publication 3 A guide to the presentation of papers.

Jan 1, 1983

By Joe Maher

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Jan 1, 1976

By Guillermo Silva, P. Katsabanis

The conventional approach to design wall control blasts relies on the borehole pressure as the most important explosive parameter. Borehole pressure is intimately linked to explosion pressure, which in turn is related to the detonation pressure of the explosive. For fully coupled charges, the borehole pressure is equated to the explosion pressure, while for decoupled and decked charges its value is typically calculated under the assumption that the explosion products behave like an ideal gas when they expand into the volume of the hole.

Jan 1, 2003

By C. E. Roessler

Uranium and its decay series are associated with phosphate deposits of marine origin. Uranium concentrations are on the order of 100 to 200 ppm in matrix from the Bone Valley formation of Central Florida and about 25% this value in matrix mined from the Hawthorne formation in North Florida. Occupational radiation exposure due to this source has been under study in Florida since the mid 1970's (Windham, Partridge, Horton 1976; Roessler and Prince 1978). This report is based on findings of an industry-wide scoping survey conducted by the University of Florida during March 1976 through May 1977 and subsequent studies in selected individual facilities. PHOSPHATE MINING OPERATIONS Mining and beneficiation operations are diagramed in Figure 1. At the excavation site, electric powered draglines remove the overburden and expose the phosphate matrix (ore) which is then slurried and pumped to the beneficiation site. At the washer stage of the beneficiation plant, the matrix is subjected to washing and screening. A coarse product, "pebble" is produced and sent to storage piles while the fine fraction is passed through a series of cyclones to remove the clays. The generated clay suspension is sent to settling ponds while the remaining sand-sized fraction is sent to the flotation plant. At the flotation plant, phosphate particles are recovered from the fine sand particles of similar size through several stages of treatment with reagents, agitation and separation of floating and sinking fractions. The high grade concentrate produced is transferred to storage while the sand tailings are discarded. [ ]

Jan 1, 1981