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By Walter Rose

Experimentation which measures differences in pressure across the interfaces of immiscible fluids in the interstitial spaces of porous media may be termed "capillary pressure experimentation". In the literature of petroleum technology since 1941 there have appeared twelve papers popularizing capillary pressure concepts and developing applications of these concepts for the solution of problems of practical reservoir engineering importance, such as the determination of connate water, fluid distribution. in transition zones, reservoir rock textural properties, and oil recovery from petroleum reservoirs. Although a review of the literature would be justified at this time in order to reconcile the conflicting viewpoints which are contained in the cited papers, the object of this note will be of more limited scope. It is believed that the recent paper of Muskat alls sufficient attention to many of the uncertainties which arise upon examination of the published literature. such that until satisfactory counter-proposals can be made it will serve our purpose only to mention some other like uncertainties. This will emphasize further the need confronting petroleum technologists to re. consider and reformulate the application possibilities of capillary pressure experimentation. In particular, I sug- gest that we examine the thesis that capillary pressure experimentation as above defined can lead to measurements reflecting the recovery of oil from petroleum reservoirs, as was proposed first" by Amyx and Yuster and was first reduced to practice by the experimentation of Welge . In fact. I shall deal exclusively with the Welge papers since it is the principle one on this subject which has appeared to date. I shall attempt to show that the possibility of describing oil recovery features in terms of capillary pressure phenomena has not been established entirely. The Welge paper was a pioneering effort to evaluate this recovery application possibility. P. P. Reichertz' comments on the Welge paper state that non-wetting phase discontinuities are developed occasionally in the Welge experiment, and restate Muskat's argument that discontinuous fluid elements (partially saturating the interstices of porous media which are elsewhere saturated with some other immiscible phase or phases) are not subject to the requirements of hydrostatic equilibrium. It is the purpose of my comment to show that it is unnecessary to make Reichertz' postulation regarding non-wetting phase discontinuities (however valid) when it is desired to criticize Welge's theoretical treatment of his problem. It can be shown that Welge's method of measuring values for ''capillary pressure" is invalid in many instances of application, such that his reported curves of capillary pressure Versus fluid saturation often have no physical meaning, even throughout the interval of fluid saturation where it might be otherwise suspected that no phase discontinuities occur. By considering established principles of capillary pressure experimentation it can be shown that the pressure difference experimentally observed between wetting and non-wetting fluid phases which are contained in external reservoirs will reflect on the capillary pressure difference at the interfaces of contact between these phases only when the following conditions are satisfied: (a) There shall be a balance between the opposing forces of gravity and capillarity, as obtains under conditions of hydrostatic equilibrium when the positions of the interfaces of contact become fixed in pore spaces of certain geometry (b) The wetting and non-wetting fluids within the interstitial spaces shall everywhere be continuous with the external wetting phase reservoir and the external non-wetting phase reservoir, respectively. It will become apparent immediately that in any instance when a greater pressure is recorded in the external wetting phase reservoir than in the external non-wetting phase reservoir, one may establish either that static equilibrium has not been attained or that discontinuities in one or more of the fluids have been developed. This is because the pressure otherwiee is always gereatest in the non-wetting phase at each static interstitial interface of contact with the wetting phase. such that the externally measured pressure in the non-wetting phase likewise must be greatest if the above conditions are to be satisfied.

Jan 1, 1949

By J. Finch, J. Yianatos, N. W. Johnson, R. Espinosa-Gomez

A method of determining the maximum concentrate solids rate or carrying capacity is described for given column operating conditions. The method requires alteration of the feed rate of solids to the column at a fixed residence time by manipulation of the % solid of the column feed pulp or the bias rate. The carrying capacity was measured for five streams at the Mt. Isa Mines Pb/Zn and Cu concentrators. As a potential scale up parameter, the mass of solids per unit time per unit column cross section (Ca, g/min.cm2) is explored. Ca is tentatively related linearly to the 80% passing size (d80) of the concentrate. For d80 < 15 pm Ca was less than 4 g/min.cm2 (8 lb/min.ft2) which makes it a critical consideration in scale-up for such fine feeds. An alternative carrying capacity parameter, mass of solids per unit volume of gas Cg was not as useful as Ca since Cg varied inversely with gas rate.

Jan 1, 1988

By H. W. Camp

ALTHOUGH the situation in the oil industry during the past year has. not been conducive to large expenditures for development and research, there is little indication that such expenditures have been curtailed. While few outstanding achievements have been reported, considerable progress has been made in the development of new products and the adaptation of petroleum derivatives to new uses. The most important question facing the refiner today is the anti-knock quality of his gasoline. This year has seen the widespread adoption of the term "octane number" as a measure for anti-knock values, and in the latter months of the year the public has been made acutely aware of this condition through competitive advertising. Gaso-line is no longer priced on volatility and gravity alone, but on octane number as well; and premiums are being paid for material of relatively high octane rating. The situation has grown more and more competitive and has forced refiners continually to raise the octane rating of their regular and com-petitive grades, and at this writing the same situation exists for premium grades which have possessed relatively high anti-knock properties for some time. Straight-run gasoline produced from paraffin-base or semiparaffin-base crudes has an inherently low anti-knock value, and in order to convert this material to a higher quality it has been found necessary to crack an increasing percentage of the crude oil charge. By completely cracking the heavier portions of the crude, and blending back with the straight-run gasoline, it has been possible to produce an average of 63 to 65 octane number gasoline&apos; on average Mid-Continent crude. This operation carried to the fullest extent does not suffice, however, and the recent and rapid development of the so-called "re-forming unit," has resulted. The straight-run gasoline fraction is cut into two parts: a light, low boiling point gasoline; and a heavy gasoline or naphtha. The latter containing the low anti-knock portions of the gasoline, is sent through a re-forming unit and subjected either to high temperature ,or pressure, or both, which materially increases its octane number. On average Mid-Continent the blend of low boiling point straight-run,

Jan 1, 1932

By Li Jiuping, Zhong Gang, Chen Yong Zhang, I. Michael Gowring

The Liaoning Dahuofang Reservoir Water Transfer Project is an important development for the Department of Water Resources of Liaoning Province in northeastern China. The 85.3 km water conduit will transport water from the Hun River downstream of the Huanren Reservoir to the outlet on the Suzi River leading to the Dahuofang Reservoir. The additional water is required to sustain the growing cities of Fushun, Shen-yang, Liaoyang, Anshan, Panjin and Yingkou. The project is divided into seven contracts. Three TBM contracts comprise almost 75% of the work and the others are drill and shoot. The focus of this paper is about the creditable TBM performances achieved and some of the problems encountered by Chinese contractors; notably two having had no previous TBM experience.

Jan 1, 2007

By D. E. Sherwood

Twelve toe grouted, and eleven ungrouted piles, founded in very dense sands have been analysed to establish how toe grouting enhances pile performance. It is shown that pile stiffness is greatly increased, and that pile bases work effectively. This is in contrast to ungrouted piles, where some milli­meters of base movement may be required before the base is mobilised. Grouting appears to recover most of the disturbance caused during construc­tion, but in general does not enhance the ultimate bearing capacity of undisturbed ground.

Jan 1, 1989

By Y. -H. Chang, Y. -J. Jou, T. -S. Ueng, I. -H. Peng

In order to systematically study the size effect on the shear strength of rock joints, this study used the computer-aided-manufacturing system to reproduce the artificial rock joints for saw-toothed joints, Barton&apos;s standard joint profiles of JRC = 4~6 and 18~20, and natural rock joint profiles. We divided, enlarged, reduced, and assembled these joint profiles to obtain joint specimens of various sizes ranging from 75 mm to 300 mm in length. The shear strengths of these joint specimens were tested under different normal stresses using a direct shear test apparatus. The surface conditions of the joints at failure were also examined. The size and geometry effects on the shear strengths of these joints of various sizes and configurations were evaluated based on the test results. Um die künstlichen Trennflächen für reguläre dreieckige Trennflächen, Bartonsche standardmäßige Querschnitte der Trennflächen von JRC = 4~6 und 18~20 und natürliche Querschnitte von Trennflächen wiederherzustellen, benutzt diese Forschungsarbeit das Computergestützte-Erstellungssystem, damit die Maßstabswirkung auf die Scherfestigkeit von Trennflächen systematisch untersucht werden kann. Die Querschnitte werden geteilt, vergrößert, verkleinert und zusammengesetzt, um Trennflächenproben in Längen variierend von 75 mm bis 300 mm zu erhalten. Die Scherfestigkeit dieser Trennflächenproben wird unter unterschiedlichen Normalspannungen mit einem Direktscherversuchsgerät getestet. Die Querschnittszustände der Trennflächen bei Versagen werden ebenfalls untersucht. Nach den Untersuchungsergebnissen werden die Maßstabs- und Geometriewirkung auf die Scherfestigkeit dieser Trennflächen verschiedener Größen und Konfigurationen ausgewertet. Pour étudier systématiquement l’effet de la dimension des fractures des roches sur leur résistance au cisaillement un système de creation de fractures artificielles à l’ordinateur a été employé. Des fractures artificielles triangulaires, profils de fractures de Barton avec JRC = 4~6 et 18~20, et profils de fractures naturelles ont été reproduits. Les profils des fractures ont été arrangés de manière à obtenir des échantillons de longueur entre 75 et 300 mm. Une boîte de cisaillement a été utilisée pour étudier la résistance des fractures au cisaillement, sous plusieurs conditions de contraintes normales. Les conditions superficielles des fractures après rupture ont été étudiées. Les résultats de ces essais, effectués sur plusieurs échantillons de dimensions et configurations variées, ont contribué à établir l’influence des dimensions et de la géométrie des fractures sur leur résistance au cisaillement.

Jan 1, 2003

By Malcolm F. Hawkes, Robert F. Mehl

THE rate of isothermal transformation of austenite to pearlite depends upon the rate of nucleation, N, and the rate of growth, G, of pearlite in austenite.1.2 Values of N are given in terms of the number of nuclei forming in unit time per unit grain boundary area of unreacted austenite; values of G are given in terms of the linear rate of radial growth. Variations in the isothermal rate with temperature result from variation of -N and G with temperature. Depth of hardening of a steel depends fundamentally upon values of N and G; changes in carbon and alloy content effect changes in N and G and thus affect depth of hardening. Quantitative studies are available on N and G for the formation of pearlite in plain carbon eutectoid steels.3 Systematic studies in this field are necessary if the phenomena are to be well enough known to furnish. a proper basis for full rationalization and for theory. Accordingly, the studies are continuing, both with respect to the effect of alloying elements upon the values of N and G in the formation of pearlite, and to the values of N and G for the formation of ferrite in hypoeutectoid steels. The present paper is the first relating to the effect of alloying elements upon the values of N and G for pearlite. It offers special interest since cobalt is known to have an anomalous effect upon the rate of formation of pearlite, accelerating it, whereas all other elements retard it.&apos; It will be shown that cobalt increases both N and G for pearlite and that this effect is inherent in the Fe-Co-C system and not dependent upon factors relating to austenite heterogeneity nor upon any recognizable adventitious factor. Inasmuch as the rate of diffusion of carbon in austenite and the interlamellar spacing of pearlite are variables related to G and possibly to N (in a manner not yet certain), measurements of the "effect of cobalt upon them are also reported here. In the course of the work, measurements were made on the effect of cobalt upon the martensite temperature and these are given. COBALT AS AN ALLOYING ELEMENT IN STEEL PROPERTIES OF COBALT Cobalt resembles iron more closely than does any other chemical element. Its atomic number is 27, hence it is the element immediately following iron in the periodic system. The two differ in atomic structure only in the fact that cobalt contains seven electrons instead of six in the third, or transition, level of the third shell. The next shell, which is the

Jan 1, 1947

By C. C. Griggs

FROM its inception, a limestone quarry or mine should be under the direction of a capable engineer. Before it becomes a reality, he should outline the future results, plan the most economical methods for moving the materials and the most efficient equipment, and pilot the undertaking along the narrow pathway of success, avoiding the pitfalls of uneconomical production and the precipitous walls of scanty profits. Inspection of successful limestone properties shows that all have had difficult engineering problems, the solution of which have required keen engineering ability. In approaching a subject of this nature, it is logical to follow the progress of the limestone operation from its inception to the end, as reflecting the engineering required. There are four major divisions: Investigation, equipment, development, and operation.

Jan 2, 1925

The End of the Line for Roadway Development By Michael Kelly, CSIRO Exploration & Mining Michael Kelly highlighted that roadway development performance remains one of the threats to expansion of Australia underground coal exports to the growing Asian market. In a recent industry study, automation was highlighted as one of seven strategies for roadway development improvement. Growing Asian markets The expansion of the Asian coal market is a long term driver for expansion of the underground coal industry in Australia - if significant productivity improvements are made. Imports of steaming coal by Asian APEC members are predicted to rise by from 150 MT to 190 MT. Australia is one of the few countries which has a potential capacity larger than predicted internal needs. Predictions are for exports of black steaming coal from Australia to increase from 50.3 MT in 1992 to 106.3 MT in 2010. To meet this prediction, an investment of $10.7 billion (in 1992 dollars) will have to be made in mining and transport facilities. This is equivalent to the opening of a major new mine each year until 2010. Many of these mines will be underground operations. However, much of Australia&apos;s capacity to respond to increased Asian demand will depend on its ability to develop underground technologies and improve productivity. The inability to make sustained improvements in roadway development rates has to date been one of the main reasons why new underground projects have failed to deliver the expected returns.

Jan 1, 1997

By Zenjiro Asaki

The copper concentrate particles dissolve quickly into the molten matte in the smelting furnace of Mitsubishi Process, which indicates that the sulfide smelting is essentially a gas/liquid reaction. In this paper, theoretical calculation has been made on the rate of oxidation of FeS component in the matte to form FeO by rising gas bubbles using the penetration theory. The results showed that all the oxygen in the bubble of 1.2 cm in diameter, which is the maximum stable diameter, is consumed in 3 ms. This time required is sufficiently short, and it results in the actual operation of smelting furnace of 1100% oxygen-efficiency. These calculations indicate that most smelting reactions are completed just under the lance, except slag formation.

Jan 1, 2002

By Arthur F. Taggart

PROGRESS in a technical art is of several kinds. It springs .from many diverse sources. It comprises invention, mechanical improvement, operating advance, analytical study, education. Invention is, by definition, a relatively great, essentially individual step, taken quickly. Operating advance is the slow, cumulated march of practice; in contrast, it moves at the pace of the tortoise, but over, the years its effects rival and, in some cases, surpass those of invention. Mechanical improvement- is a usual concomitant of the reduction of invention. to operating practice; thereafter it is a primary tool of operating advance. Analytical study is the process of mental digestion of the fruits of invention and practice. Its purpose is to render these into a form assimilable by the art as a whole, and by the perennial crop of would be practitioners. Education, disseminating the results of such study, consolidates and maintains the positions gained. Thus, slowly at first, but continuously accelerating, the tide of progress grows- to flood. Such growth, in mathematical parlance, is expressible in the general form y = mxn, where x is time, n is some positive number greater than one, m is another positive number, and y is the state of the action at instant x. When n is 2, the readers will recognize the graph of the equation as one branch of the familiar square parabola, whose property it is to become parallel to the y-axis; i.e., to move at an infinite rate, in that never-never

Jan 1, 1947

By Smith I. T

Mine operators have long recognised that the results achieved in primary blasting are critical to subsequent mining activities. With the introduction of "in the hole" drills under- ground and the advantages offered by the use of water gels in conjunction with ammonium nitrate-fuel oil (ANFO) explosives, new mining methods have been developed and enabled improvements in older methods. Pumpable water gels have been used with varying success underground. These gels allow a high loading density even in ragged bore- holes. The problems encountered with slumping in upholes is recognised so the current trend is to use these gels in downholes where wet holes are prevalent. Cartridged water gel technology has advanced to the point where it has allowed the replacement of nitroglycerin (NG) based explosives and pumpable water gels. Today, gels can be made as a tampable product for use in development headings or as a slump- ing product for downholes to give an effective coupling. With the introduction of the Tovex« pneumatic loaders, the problems associated with a pumpable gel were eliminated and gave the user the ability to alter his loading density.

Jan 1, 1977

By Freeman Bishop

Copper production has been under Government scrutiny for many years because it&apos;s known as a concentrated industry which in turn creates what many economists label administrative prices. Neither of these conditions is illegitimate, per se, the Federal Trade Commission and the Justice Department have said time and again. But Justice spoke up once more. This time over a Puerto Rican copper development planned by American Metal Climax, Inc., and the Kennecott Copper Corp. Bureaucratic Dichotomy Creates Confusion and Conflict In the Copper Industry Ian MacGregor, chairman and chief executive officer of Amax, said Justice in a recent communique questioned the propriety of the proposal of a joint copper venture in Puerto Rico. At the same approximate time, Dr. Hendrik S. Houthakker, chairman of the President&apos;s Commission on Copper, was urging copper producers to expand production to help hold down prices by making more copper available to all consumers. This, Mr. MacGregor said, is creating confusion and conflict, since the Administration from one source is chastising the industry for doing what another branch requests.

Jan 1, 1970

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

By Webster SS

This paper uses computer modelling tech- niques to compare and contrast anomaly patterns obtained with fluxgate (vertical field) and proton precession (total field) magnetometers at typical latitudes in northern and southern Australia. The use of these modelling tech- niques is suggested as an aid to magnetic interpretation and field examples are included from Tasmania and the Northern Territory.

Jan 1, 1975

By E. K. C. Williams, Nathaniel Arbiter

INTRODUCTION The surface processes involved in preparing ores for flotation and for operations depending on their flocculation/dispersion characteristics * vary widely in agitation dependence. Most of the reagents used for these purposes are added to grinding circuits, pump sumps, launders, or directly to flotation cells with the turbulent flow conditions usually adequate both for mixing reagents and for surface reactions without special conditioners. However, some reagent systems do require specific control of agitation intensities and reaction times, the more important of these being the following: 1. Activation of ZnS with CuSO4. With the usual conditions pH about 10, with collector added with the CuSO4, Cu 2+ is almost completely precipitated as basic compounds and as collector salt. As a result the levels of reagent in solution are extremely low which probably accounts for the need for separate conditioning. The agitation intensities are at about the 0.01 HP/ton level.** 2. Flocculation with natural or synthetic polymers. In this case the agitation problem is two-fold; first, to insure adequate initial mixing of the viscous stock solution of the

Jan 1, 1980

By Thomas V. Falkie, R. Venkataramani

Anderson, L. B., 1963, "Multiple Regression Techniques Correlate Experimental Data," Chemical Engineering, V. 70, N. 12, pp. 223-228. Aubert, E. J., Lund, I. A., and Thomasell, A. J., 1959, "Some Objective Six-Hour Predictions Prepared by Statistical Methods," Journal of Meteorology, V. 16, pp. 436-46. Barrett, A. L., 1958, "Alternating Current in Continuous Mining," Mechanization, V. 22, N. 9, pp. 83-86. Bower, A. B., Jr., 1970, "Bit Design: Key to Coal Cutting," Coal Age, V. 75, N. 7, pp. 70-72. Bower, A. B., Jr., 1971, Personal Communication dated April 29, 1971; General Electric Company, Mining and Metallurgical Products Department, Detroit, Michigan. Burt, C., 1950, "Group Factor Analysis", British Journal of Statistical Psychology, V. 3, pp. 40-75. Cady, L., Gertler, M., Gottsch, L., and Woodbury, M., 1961, "The Factor Structure of Variables Concerned with Coronary Artery Disease", Behavioral Science, V. 6, pp. 37-41. Cattell, R. B., 1965, "Factor Analysis: An Introduction to Essentials I. The Purpose and Underlying Models," Biometrics, V. 21, N. 1, pp. 190-215. Christensen, R. W., Heins, R. W., Babcock, W., and Tonn, R., 1971, "The Effect of Material Properties on Materials Handling Processes," Six Month Technical Report, (August 1971) to Advanced Research Projects Agency, U. S. Department of Defense; The University of Wisconsin. Collins, G., 1961, "Factor Analysis," Journal of Advertising Research, V. 1, N. 5, pp. 28-37. Cooley, W. W., and Lohnes, P. R., 1962, Multivariate Procedures for the Behavioral Sciences, New York: John Wiley and Sons, Inc. Cree, J. 0., 1956, "Power for Continuous Mining," Mining Congress Journal, V. 42, N. 10, pp. 49-52. Draper, N. R., and Smith, H., 1966, Applied Regression Analysis, New York, John Wiley & Sons, Inc. Griffiths, J. C., 1966, "A Genetic Model for the Interpretive Petrology of Detrital Sediments," The Journal of Geology, V. 74, N. 5, pp. 655-672.

Jan 1, 1972

By T. D. Rourke, Fred H. Kulhawy, O&apos

From mid-1976 to early 1978, a 5.64 m diameter tunnel, 2491 m long, was excavated by a modified Robbins full-face TBM under shallow cover in highly stressed sedimentary rock in Rochester, NY. In-situ stress measurements were made, and tunnel behavior was monitored with MPBXs, inclinometers, tape extensometers, and instrumented steel ribs. Detailed geologic mapping was also done. In this paper, the as-monitored tunnel behavior is described, and the TBM performance is evaluated from field records. Recommendations are also made for future tunneling in similar geologic environments.

Jan 1, 1981

By Ronald E. Heuer

The significance of surface settlement over soft ground tunnels is well recognized. Cracked buildings, streets transformed into lakes, broken utility lines, to underpin or not to underpin--all are familiar problems. The basic causes of surface settlement are recognized. Possibly the most common and troublesome cause is "lost ground" during construction. Lost ground refers to removal of a larger volume of ground (Ve) than is eventually occupied by the final tunnel structure (Vt). A number of sources of lost ground in shield tunneling have been identified, as illustrated in Fig. 1. These include 1) face loss, 2) overcutting loss, 3) annular tail void loss, and 4) loss through the lining. The ground generally does not stand unsupported around the completed tunnel lining as illustrated in Fig. 1, but moves in to fill the lost volume, resulting in subsidence of the overlying ground surface as shown. As suggested in Fig. 1, lost ground and surface settlement associated with overcutting and the annular tail void tend to occur systematically along the tunnel length. This "systematic" lost volume is "limited" in the sense that it is restricted to an upper limit determined by the shield and lining geometry. Partially controlled face loss may sometimes contribute to this systematic loss. This lost volume is commonly a few percent of the nominal tunnel volume. The resulting surface settlement over the tunnel is commonly in the range of a few inches or less and develops over a period of hours to days. Although they may have a significant impact on surface facilities, systematic ground loss and settlement frequently have little adverse effect on tunneling progress.

Jan 1, 1976

Three major and two minor uranium deposits &apos;have been worked by open out mining since the discovery of ,the Rum Jungle field in 1949. Total production has been about 9679000 tons of uranium ore at 7;39 lb U308/ton and 4029000 tons of copper-uranium ore at 6.27 lb U308/ton and 2.7% Cu, with significant tonnages of base&apos;metal ores. The deposits occur in or near black pyritic slates of the Lower Proterozoic Golden Dyke Formation, near the contact with the under- lying Coomalie Dolomite. The mineralization is probably younger than the grahite complexes in the area, and a structural-stratigraphic control of ore deposition is used as a basis for uranium exploration.\

Jan 1, 1968