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By A. Dorsey Lyon

INTRODUCTION A GREAT DEAL of attention has recently been given to the metallurgy of zinc, and much of that which has been said and written on this subject has been in the nature of a criticism. For instance, we are quite accustomed to hearing it said that the metallurgy of zinc has stood still, that it is antiquated, out of date, etc. We are, however, inclined to agree With George C. Stone1 When he says that, although there have been no such spectacular and radical changes as Were worked in the metallurgy of copper and iron by the introduction of converters, there has nevertheless been a decided and marked progress in the metallurgy of zinc, and especially during recent years. However, it must be admitted that, due to the fact that the chemistry of zinc is so different from that of the other metals, the retort process is the only process by which zinc is produced commercially; and, moreover, that losses which occur in the zinc industry-that is, in the mining, milling, and smelting of zinc ore-are very great, for it is stated' that probably less than 50 per cent. of the zinc mined, even

Jan 7, 1914

By David R. Sadedin

The highly negative Gibbs free energies of hydrogen atom reactions suggest that refractory oxides such as titanium dioxide should be easily reduced by hydrogen atoms. These reactions appear to be most favourable at low temperatures; oxides should be reducible even at room temperature. Since hydrogen atoms are produced in plasmas containing hydrogen a number of investigators have used hydrogen plasmas of various sorts to test these possibilities for reducing refractory oxides, in particular TiO2. None of these attempts has succeeded, a small degree of reduction being achieved in only a thin layer near the surface. A deeper consideration shows that several factors complicate the reactions expected on the basis of the negative Gibbs free energy. One factor is that the back reaction by water molecules produces molecular hydrogen, not hydrogen atoms, and the metal atoms that have been reduced may be immediately re-oxidised. In plasmas there are complications due to diffusion, thermal and charge boundary layers and charged particle reactions. Interpreting the results of hydrogen atom reactions is difficult. Hydrogen is not detectable by electron dispersive spectroscopy and amorphous products are not determinable by x-ray diffraction. Another consideration is economics. The cost of producing hydrogen atoms has a large bearing on the metals for which hydrogen atom reduction may be competitive. In this paper these factors are discussed, some necessary basic studies are highlighted and the general principles of a laboratory reactor are given, together with the results of tests using ZnFe2O4, ZnO and TiO2 as test oxides.

Jan 1, 2006

By Charles H. Mitchell

British Columbia is enjoying a period of sustained high-level activity in all aspects and sectors of its mining industry. The total value of mineral production for 1962 was in excess of $229 million. This was the greatest total value attained for any year to date, exceeding the previous record year of 1956 by more than $40 million. It appears reasonable to expect that value of production for 1963, stimulated by increased production attained during the year, and by improved metal prices for some of the major products, will be substantially in excess of that recorded for 1962. Elsewhere in this issue appears a detailed report of prospecting and exploration activity in the Province. For the purposes of this review it is sufficient to state that the level of prospecting and exploration activity during the past several years has been greater than at any previous time and that there does not appear to be any slackening in activity or interest.

Jan 12, 1963

By B. M. Larsen

SEVERAL articles have recently been published discussing the conditions necessary for accurate measurements of temperatures in the open-hearth steel furnace. In the course of a study of refractories service conditions in steel furnaces, the present writers have taken tempera; tunes in several open-hearth shops in the Pittsburgh district. The conclusions, as to conditions necessary for accurate measurements of temperature, are somewhat at variance with those of other investigators. The subject is closely connected both with the close-control of steel-making and the prevention of overheating of the silica refractories used in roofs and walls. It is becoming more and more important to obtain furnace temperatures of fairly definitely known accuracy. At present, the most useful instrument for such measurements is the disappearing-filament type of optical pyrometer. This method of measurement has formed the basis of most other discussions on the. subject and was also used by the writers.

Jan 8, 1926

By Jun Miao, Kang Liu, Jilai Xue, Jun Zhu

CO2 emissions must be reduced by at least 50 % by 2050, and hence the technical solutions to capture and convert CO2 into value–added products should be considered. A Cobalt(III) Schiff base complex (Salen–Co(III)) has been investigated as a catalyst for synthesis of cyclic carbonate from CO2 and epichlorohydrin(ECH) with tetrabutylammonium bromide (TBAB) as co–catalyst. To recover Salen–Co(III) for the next cycling operation, it was immobilized onto zeolite 13X through excessive impregnation method. The immobilized catalyst was characterized using XRD, SEM, BET and ICP–AES techniques. Catalytic tests showed that yield of cyclic carbonate reached 90 % using 0.5 mol % Salen–Co(III) at ambient conditions. The immobilized Salen–Co(III) exhibited better catalytic activity than the homogenous one when used at the first cycle, but the yield decreased by some 20 % after five cycles.

Jan 1, 2015

By C. J. Mwenifumbo

Preservation of groundwater quality is a major environmental concern. The disposal of hazardous material from urban waste dumps, milling wastes in tailings ponds, and industrial wastes in injection wells may contaminate potential sources of potable groundwater. The containment or migration of contaminants in the subsurface depends on bedrock characteristics and type of overlying sediments. Fractured bedrock and permeable sediments that may provide pathways for the transport of potentially harmful contaminants should be avoided when selecting a disposal site. The role of borehole geophysics in hazardous waste-site investigations is reviewed in three categories: (I) site selection; (2) determination of the extent of contamination at existing sites; and (3) long-term monitoring of migration of contaminants. In the first category, borehole geophysical techniques developed for lithology and fracture identification, and for porosity determination, provide some of the necessary information for understanding the subsurface hydrogeology. Lithological information can be obtained from gamma-ray, electrical resistivity, induction, magnetic susceptibility, and sometimes induced polarization logs; fracture detection and characterization can be accomplished with the use of caliper, density, resistivity, temperature, and acoustic televiewer logs. Estimates of porosity are derived primarily from neutron-neutron, resistivity, density, and soniclogs. Borehole geophysical techniques used in water quality determinations include self-potential, fluid resistivity, Eh (redox potentials) and pH measurements, and these can be used to map the extent of contamination at an existing waste site. Cross borehole and borehole-to-surface electrical methods can also be used in this application. Long-term monitoring of contaminant migration in boreholes can be accomplished with techniques that respond to changes in electrical conductivity, temperature and fluid chemistry caused by the presence of contaminants.

Jan 1, 1993

By H. Nematollahi

Numerous magnesite deposits are found in the south part of Khorasan state, east of Iran. During the past few years, production of high-grade magnesite ore was possible only by using selective mining method. The decreases of high-grade ore imply upgrading of the low-grade ore. To do so, the objective for the first phase is to obtain a material which contains less than 2.5% SiO2. The present study was carried out based on three different samples. The results obtained in laboratory indicate that the direct flotation of magnesite by fatty acids led to acceptable result.

Jan 1, 2003

By J. Buckle

"Recognition of the diamond potential of the Wawa subprovince was initially determined from regional data using a kimberlite model. The world’s largest stable Precambrian craton, the Superior Province, is considered to be favourable for the emplacement of diamondiferous kimberlite. The Wawa area is located near the intersection of intra-craton structures visible in the regional magnetic data.The Enigma project is located north of the town of Wawa in northern Ontario. From field evidence and background research, it became obvious that in the Wawa area there were at least two potentially diamond-hosting events, Archean lamprophyric volcaniclastics and Proterozoic kimberlites. The host lamprophyric rock does not contain the classical KIM signatures. However, to complicate the Enigma, stream sediment samples within 200 m of the diamond-bearing lamprophyre produced a typical suite of kimberlite indicator minerals.The micro- and macro-diamond content of the Wawa lamprophyric volcaniclastic rocks is typically 0.2 ct/t to 1 ct/t, although it can be higher locally. The economic diamond potential of these Archean dykes, sills and irregular lamprophyre bodies is still under-explored (Kaminsky, 2002, unpubl.). Oasis Diamond Exploration is currently exploring the area using geophysical, geochemical, and geological data."

Jan 1, 2002

Copper Recovery from Printed Circuit Board by Carbonisation

Sep 13, 2010

By J. Antrekowitsch

Keywords: residues, fluorides, chlorides, zinc, steel mill dust The recyclability of various nonferrous metal wastes often suffers from a relatively high fluorine and chlorine content. Both are inserted in most cases by the use of plastic contaminated scrap and a wide variety of different coatings. These halogens lead to poor product qualities and off gas contamination. Especially the history of zinc recovery from steel mill dusts shows, that the today common hydrometallurgical options are on their limit and therefore are not sufficient in most cases. This thermochemical study should give more information about different pyrometallurgical options, that offer both a chlorine and fluorine reduction and efficient zinc recovery, preferably in one process step. Selective evaporation in different atmospheres and conversion with the use of hydrogen are the main parts in this study. The results combined with the relatively small information available from literature should provide a basis for further investigations in this field.

Jan 1, 2005

The Osborne copper-gold deposit (within the Trough Tank project area) is located in the Cloncurry Shire about 195 kilometres south-east of Mount Isa. It is hosted by Proterozoic metasediments of the Eastern succession of the Mount Isa Inlier. The deposit is overlain by 25-40 metres of Mesozoic cover, so it represents a true "blind target". Placer Exploration has 100% outright ownership of the property, having purchased the remaining 10% interest in the property from Shell in early 1993.Intensive exploration, both surface and via drilling at Osborne, has taken place since 1985, when CSR Limited Mineral Exploration and Development Group (acquired by Placer in 1988) entered into a joint venture with Billiton Minerals. Exploration effort from 1985 to June 1988 outlined a 20 kilometre strike length of magnetic horizons, in what was termed the North-East, Central and Southern anomalies, which were drilled with weak indications of copper-gold mineralization in the North-East anomaly. During the later half of 1989, four core holes were drilled into the shallower northern partofthe North-East anomalywhere previous drilling had outlined economic intersections of mineralization. These holes encountered high-grade copper-gold mineralization confirming the potential for an economic deposit to be hosted within the ironstone sequence. Further drilling involving over 400 holes (100 kilometres of drilling) has brought the deposit up to its present resource status.The current resource inventory is 36 million tonnes grading 2.0% copper and 1.0 grams pertonne gold and includes a high-grade zone of 13 million tonnes grading 3.6% copper and 1.5 grams per tonne gold. The discovery of this potential economic mineralization resulted from a persistent exploration effort based on indications that a large mineralizing system existed within a sequence of ironstones.

Jan 1, 1993

By Charles R. Nelson

INTRODUCTION The support of openings in weak sandstones can be achieved by spraying on a liquid grout which will soak in and harden to form a shell. In the St. Peter sandstone of the Minneapolis-St. Paul area of Minnesota compressive strength is increased from about 0.7 MPa (100 psi) to over 7 MPa (1000 psi) to depths of 152 mm (6 in.). A shell of this strength and thickness can pro¬vide support much as shotcrete does but at lower cost. If the spray-grouted shell is inadequate for the support needed, it provides a good base for shotcrete application, which is often difficult in weak or friable sand¬stones because the fresh shotcrete peels off along with a thin layer of sandstone. The spray-grouted technique was initially developed at the Civil and Mineral Engineering Dept. of the University of Minnesota using funds provided by RANN Div. of the National Science Foundation. It was used as temporary support in a 3-m (10-ft) wide, 3700-m (12,000-ft) long storm water drain tunnel by the Minneapolis Sewer Construction Dept. Much of the field development at this construction project was carried out with the cooperation of the personnel of the city of Minneapolis. It also was used for temporary support in a 3.3-m (11-ft) wide, 1800-m (6000-ft) long storm water tunnel built in 1978-1980 for the Minnesota Dept. of Transportation in Minneapolis. In 1975, 2000 m (6500 ft) of 1.5-m (5-ft) wide utility tunnels were spray-grouted for final lining. A 50-m (150-ft) long, 1.2-m (4-ft) wide test tunnel built at the university in 1974 was sprayed for half its length and is being observed for long-term behavior which to date (1981) is good. GROUT MATERIALS The requirements for the liquid grout are more severe than those for injection grouting. Besides being able to penetrate the rock and develop sufficient strength, it must have the following properties: (1) be nontoxic, noncombustible, and have a low odor for spraying under¬ground; (2) have controllable viscosity and setting time for adjusting to the permeability of the sandstone and the required depth of penetration; and (3) must "wet" the sandstone and develop capillary "draw" to penetrate to the required depth. A sodium silicate-based grout with the proper setting agent meets these requirements in the local St. Peter sandstone which has a uniform grain size dis¬tribution curve with D,,, = 0.1 mm, permeability of about 10 to 20 darcys, a porosity of about 25%, and less than 5% of silt size or smaller. It is 97 to 99% pure SiO2. The grout mix consists of Philadelphia Quartz Co. Type N sodium silicate and Celtite 55 Terraset Spray Grade (SG) distributed by Celtite Inc., Cleveland, OH. A volume mix ratio of 100:9:125 for sodium silicate to setting agent to water produces a grout with two to four centipoise viscosity, and initial set at 20°C of 20 min. Setting time is temperature dependent, being longer at lower temperatures, but can be adjusted by varying the setting agent concentration a few percentage points. APPLICATION The application is simple. Spray the grout on the surface until the desired penetration is achieved. Penetration rates of about 5 mm (0.2 in.) per min. are realized in the St. Peter sandstone for up to 152 mm (6 in.) of penetration (30 min. of spraying). The set time must be longer than the spraying time. The spray nozzle should be moved back and forth at a rate that minimizes runoff due to surface buildup. Both a single large hand-propelled nozzle and multiple small machine propelled nozzles have been used successfully. The pumping and mixing equipment used consisted of: (1) a hand-held, hand-pumped, 11-L (3-gal) gar¬den sprayer for test patches (mix by shaking); (2) 76-L (20 gal) batch mixing in barrels with small electric pumps for spraying and mixing; (3) two component pumps consisting of Hypro Model 5300 piston pumps (Hypro Pump Co., St. Paul, MN) on a common shaft driven by an electric motor. The sodium silicate is premixed with a portion of the water and the setting agent is mixed with the rest of the water. The two components are combined and mixed just before the nozzle; and (4) a proportioner metering the setting agent just before the nozzle with the water and sodium silicate premixed and pumped from the surface. The proportioner permits the bulk of the grout to be pumped through a single pipe or hose with only the setting agent stored underground. This is efficient and low in cost. COST The grout mix costs about $0.20/L ($0.75 per gal) in 1978 dollars. Filling all the voids 100 mm (4 in.) deep (25% initial porosity) would have a materials cost of about $5.40/m2 ($0.50 per sq ft). The labor cost of application is usually less than the material cost for normal tunnel jobs. A pump and proportioner cost less than $1000. Sodium silicate storage tanks and pip¬ing costs would depend on the particular site conditions. REFERENCES AND BIBLIOGRAPHY Nelson, C. R., 1977, "Spray Grouting for Tunnel Support and Lining," Underground Space, Vol. 1, No. 3, pp. 241¬ 245. Yardley, D. H., Nelson, C. R., Stocker, T. H., 1974, "So¬dium Silicate Spray Impregnation of Tunnels in the St. Peter Sandstone," Research Report, University of Min¬nesota, 118 pp.

Jan 1, 1982

By Eliezer Martinez-Jimenez, Gretchen T. Lapidus

"Electro-assisted reduction is an effective pretreatment to render chalcopyrite less refractory towards oxidative leaching. In this process, chalcopyrite is selectively converted to chalcocite or copper metal in an electrolytic cell under ambient conditions, while ferrous ion is leached into solution. However, the reaction velocity is hampered by the formation of a ferrous sulfide passivating layer on the solid surface, especially at elevated solid to liquid ratios. In the present work, several strategies for overcoming this problem were evaluated. On one hand, specific ligands for ferrous ion were added in order to increase its solubility and, on the other, an anode material which promotes the oxidation of the sulfide ion was chosen. Leaching tests showed citric acid to be an effective ligand for both ferrous and ferric ions and, in combination with a lead-silver anode, significantly increased the kinetics of chalcopyrite reduction and subsequent copper leaching.IntroductionAttempts to oxidize chalcopyrite at a rapid rate in aqueous solutions, below their normal boiling point, have met with difficulties because of passivation by some of its own components. An alternative line of research explores reductive pretreatment, transforming the chalcopyrite into less refractory copper phases, which can later be oxidized. A recompilation of these efforts up until 2000 was published by Dreisinger and Abed [1]. However, this practice usually requires large excesses of reducing agents, such as copper, lead, aluminum or iron, and in this last case at near-boiling temperatures, in highly"

Jan 1, 2012

By Robert G. Lundquist

The Bureau of Mines compared longitudinal strain energy output of a percussive drill to energy determined by measuring maximum piston velocity. Strain gages were used to determine the strain-time waveform and its amplitude at seven levels of operating pressure and eight levels of thrust. The longitudinal strain energy was found to be approximately 14 ft lb less than the maximum piston energy at comparable operating conditions.

Jan 1, 1969

By Dave Price

"Canada is scheduled to become the 4th highest diamond revenue producing country in the world by year 2004 with the already operating Ekati Mine and the anticipated operation of the Jericho Mine in 2002 and the Diavik Mine in 2003.This paper provides an overview of worldwide diamond production statistics and a brief introduction to a diamond processing plant. The dense medium separation (DMS) extraction process is presented and this process is discussed in more detail with respect to the extraction of diamonds in terms of feed preparation, dense medium, dense medium cyclones, ferrosilicon recovery and dense medium cyclone operating efficiencies.INTRODUCTIONThe Ekati Diamond Mine in the Northwest Territories started commercial production of diamonds in the 4* quarter of 1998. At full production, the mine is anticipated to produce annually some 3 million carats of diamonds. The Jericho Mine in Nunavut Territory and the Diavik Mine in the Northwest Territories are anticipated to come into production in the 1'' quarter of 2002 and 1st half of 2003 respectively. The combined annual diamond production of these three mines will total approximately 10.34 million carats by 2004, making Canada the 4~ highest diamond revenue producing country in the world.A diamond processing plant initially utilizes crushing, scrubbing and screening in the beneficiation process to liberate diamonds from kimberlite ore and size the product for further treatment through DMS. Alluvial diamond operations do not require initial crushing and scrubbing but incorporate a feed preparation and sometimes a recrush facility with the DMS plant. The heavy sink product from the DMS, which contains diamonds, is further upgraded through x-ray separation and high intensity magnetic separation prior to producing the final diamond product.DMS is a relatively simple separating principle. A mixture of particles of different density is immersed in a dense fluid, so that particles having a density lower than that of the fluid will float while those of heavier density will sink. The translation of the float-sink principle from a laboratory method to continuous industrial practice offers the prospect of very precise mineral separations based on density differences alone."

Jan 1, 2000

By G. J. McDougall, M. J. Nicol, O. L. Wellington, R. G. Copperthwaites, R. D. Hancock

X-ray photoelectron spectroscopy showed that the adsorption of gold cyanide on carbon in the presence or absence of electrolytes and acids proceeds by the same mechanism. Although the identity of the gold cyanide adsorbate is not known, the mechanism appears to have an initial adsorption stage that involves the adsorption of an ion pair: Mn+[Au(CN)-2]n where Mn+ is a metal ion (for example Na+, K+ and Ca2+) that has a lower solubility than the Au(CN)-2 anion in the adsorption medium, followed by a reduction step in which either a sub-stoichiometric Au(CN)x surface species or a cluster-type compound of gold is formed.

Jan 1, 1980

By R. K. Simpson, C. S. Eldridge, M. H. Tyler, J. P. Hodgkison

The WMC Olympic Dam Operation in South Australia is an integrated site, involving brown fields exploration through to production of copper cathode, uranium oxide, gold and silver bullion. The Geology and Analytical Services (GAS) Department reflects this totality and, therefore, is perhaps a unique construct in the industry. It comprises Geology, the Metallurgical Laboratory and the Analytical Laboratory, offering a single point of contact in matters of metal discovery and tracking through mine design, production, beneficiation and final product certification. This structure promotes value adding by removing traditional barriers between groups that can deliver more, collectively, than as individual units. This approach to value adding by bringing disparate groups together is echoed in each of the three sections where enhancements in the traditional value adding activities have been delivered by multi-skilling and encouraging overlapping involvement.

Jan 1, 2002

By Dario Libano, Luis Carlos Tenuta, Juliano Penteado

"Subway Line Number 4 is one of the newest additions to the Rio de Janeiro subway network. Built for the 2016 Olympic Games, the 16 km (10 mi) subway line connects the south of the city, with the famous beaches Copacabana and Ipanema, to Barra da Tijuca, west of the city, where the Olympic Village and Park are located. This new line, which is estimated to cost USD 2.2 billion, is composed of six new stations: Jardim Oceanico, São Conrado, Gavea, Antero de Quintal, Jardim de Alah (JA) and Nossa Senhora da Paz Station.Brasfond participated in the construction of foundations and retaining structures for all the stations, and each presented unique challenges. This is not surprising considering the difficulties present in a highly-dense urban environment including utilities, nearby buildings, traffic limitations and noise.Of all the stations, JA Station was the most challenging to construct. It was located in the middle of an avenue between residential high rises supported on shallow foundations as well as below sea level in sands with high groundwater. The other five stations were located in small parks and squares, with no buildings in the immediate proximity.The interaction between designer, owner, and the general and foundation contractors during execution was key in safely reducing the construction schedule. This was significant given the unforeseen construction delays the client, Linha 4 Sul JV, faced due to permitting, utility and traffic relocation so that the owner could fulfill their final goal: making the line operational by the Olympic Games. The GeologyGeologically, the state of Rio de Janeiro is formed by Pre- Cambrian crystalline basement rock. Its geological formation is very old and comprises two major orogenic cycles, a Mid-Precambrian formation, called “Transamazonian” (Proterozoic Era), and an Upper-Precambrian to Cambrian called “Brasiliano” (Proterozoic-Paleozoic). The soil structure of the city of Rio de Janeiro is represented by a core of crystalline rocks, usually granite-gneiss, covered with a layer of residual soil and/or partially weathered rock.JA Station is located in a Rio de Janeiro neighborhood called Ipanema, between the Atlantic Ocean and Lagoon Rodrigo de Freitas. Local geology is composed of a superficial soil, consisting of medium to coarse grained sands. Top of rock varied significantly from 20 m (66 ft) deep on one side of the station to 33 m (108 ft) on the other. Water is at a depth of 3 m (10 ft)."

Jan 1, 2016

By F. W. Wood

The Bureau of Mines has sought clarification of the Ti-TiN system by studying the phases formed by diffusion reactions between titanium and titanium nitride. Reaction couples were prepared by embedding pockets of TiN powder in arc-melted buttons of titanium. Specimens were vacuum annealed at nominal temperatures of 800°, 950°, 1,200°, and 1,500° C. Metallographically mounted cross sections from reacted specimens and from some that were not annealed were examined optically, with an electron microprobe, with an election microscope, and by X-ray diffraction. Each annealed specimen contained a segregated core primarily of d-phase material, an ?-phase diffusion layer, an a-phase diffusion layer, and host metal. On the basis of corresponding microprobe analyses, and considering results of certain other research, a new phase diagram is proposed. It contains no qualitative innovations, only quantitative adjustments. Results were also analyzed from the viewpoint of diffusion behavior. Diffusion coefficients calculated for the ? phase were sufficiently scattered that the parameters are very tentative. Nevertheless, the diffusion behavior reported is in reasonable agreement with one of two prior studies if it is assumed that the earlier investigators were mistaken in their identification of the nitride phase in which the diffusion occurred.

Jan 1, 1974

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 1/8-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965