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By M. C. Fuerstenau, J. J. Fitzgerald

Aluminum silicate hydrosol synthesis and characterization are discussed. Plausible polymeric aluminosilicate species are presented together with their effect on electrokinetics of selected minerals and flotation response of various ores. The addition of aluminosilicate hydrosol to porphyry and oxide copper ores and to a tungsten ore resulted in enhanced flotation recoveries ranging from about 1.5 to 5 percent. A significant portion of the nation's mineral resources are presently lost in the form of particles with very fine grain size. In the case of copper, for example, approximately 225 million tons of ore are concentrated by flotation per year in the United States. Total losses from porphyry ores are generally 15 to 20 percent with half of these losses being finely-divided copper sulfide minerals which do not respond to flotation. The additional 5 to 10 percent loss is the result of copper oxide minerals which are not floated. The losses of copper sulfide minerals are thought to be due in part to the lack of appropriate dispersion of the finely-divided solids less than 20 microns in size. To effect dispersion in flotation systems, sodium silicate is commonly added. Enhanced dispersion effectiveness is achieved when polyvalent metal salts are combined with sodium silicate. Since originally described by Patek (1), numerous workers have explored the utility of metal silicates. Makrousov (2), Belash et al. (3), and Eigeles (1950) (4) showed the applicability of these reagents to calcite/apatite and fluorite/calcite ores. Mercade (5, 6) reported depression of calcite in the presence of 3.33/1 mole ratio Al/Si hydrosols prepared from Type N sodium silicate (Si02/Na20 ratio 3.22/1) and 1% A12(SO4) 3•18H20 solutions. He importantly observed that the colloidal precipitates did not play a significant role in dispersion and depression but that the soluble species were responsible for this action. Patented work by this author described metal silicates used to depress calcite in scheelite flotation using 1% metal salt (FeSO4•7H2O, CoSO4•7H2O, etc.) and 5% Type N sodium silicate solutions to produce hydrosols with Si/Fe or Si/Co ratios of 8.79/1. Aluminum (III) ion systems were less effective as depressants than the iron and cobalt systems. Yang (8, 9) has studied metal silicate sols for use in the flotation of lithium and ultra-fine hematite ores. Using 10/1 Si/Fe mole ratio hydrosols prepared from 2% ferric nitrate, Fe(NO3)3.9H20, and 5% Type N sodium silicate solutions, solutions, he showed that the hydrosols either modify the slime particle surfaces or are adsorbed on the slime particles preventing anionic collector adsorption. In a subsequent patent, Yang also reported the use of these hydrosols as dispersants for beneficiation of lithium ores. Recent studies of aluminum silicate hydrosols in the flotation of chalcocite, chalcopyrite and scheelite have been reported using Si/Al dispersants prepared from 5% Type N sodium silicate and 0.1 M aluminum chloride (A1C13.6H20) solutions. Dispersant properties were shown to be dependent upon the method of synthesis, supernatant pH, and the hydrosol Si/Al mole ratio. Polymeric soluble species in these hydrosolsupernatants have been proposed as the active dispersant species. Aluminosilicate hydrosols are synthesized by the general reaction scheme presented in Figure 1. Commercial sodium silicates are available with ratios of SiO2 to Na20 of 1.60-3.25. The sample which is most frequently employed is Type N whose ratio of Si02/Na20 is 3.22/1.00. Gel filtration chromatography and NMR studies have shown that these sodium silicates contain numerous species of molecular weight from 325-2,000 gm/mole. Monomeric, oligomeric and higher molecular weight linear polymeric arrangements of these structures are found in these solutions.

Jan 1, 1989

Some major mineral deposits in northern Australia are found in preconsolidation slump disturbances in the sediments.In the retransported marine sediments at Tennant Creek, breccia beds and disturbances are found which have localized later mineral deposits such as the Peko copper orebody. These disturbances are thought to result from slumping, turbidity flow and various types of "semi-fluidized" subaqueous slides intermediate between slumps and turbidity currents.Movements are found to ~ause widespread disturbances in the sediments such that subsequent mineralization can spread through a large volume of rock giving rise to orebodies greater than those localized by tectonic structures.A similarity is noted between the sedimentary disturbances at Tennant. Creek and those at Mount Isa and Mary Kathleerr. It is suggested that disturbed beds which are host rocks to ore minerals in these mines may also be due to movements of the sediments before compaction.Certain characteristics of the slumped rocks can be recognized and limited generalizations can be made about the shape, extent and habit of these host rocks and the orebodies they contain.INTRODUCTIONSubmarine slumping and· turbidity current retransport are almost entirely responsible for some types of deep marine sediments.However, little attention has yet been drawn to slump deposits and associated disturbances bedded in the sediments as features localizing later mineralization.A study. has been made by the writer of the slump and associated phenomena of the ,Tennant Creek field where many mineralized bodies, including some gold and copper orebodies, occur as replacements of coarse fragmental slump...

Jan 1, 1960

By Gordon B. J. Fader

A regional assessment of the aggregate potential of the Scotian Shelf is presently being funded through a Canada-Nova Scotia Cooperation Agreement on Mineral Development. This assessment includes testing of seabed materials for their suitability in a variety of concrete, asphalt and other specialized applications. The glacial and postglacial Holocene history of the Scotian Shelf has been favourable for the formation of large deposits of sand and gravel that have potential for use as marine aggregate resources. Large banks and inner shelf areas of the seabed consist of basal transgressive sand and gravel of the Sable Island Sand and Gravel Formation. These sediments accumulated during the late Wisconsinan postglacial transgression, through sorting of glacial materials that were originally deposited beneath marine terminating glaciers. Some sandy deposits occur as low-stand deltas on the inner shelf at 70 m water depth and were formed during the maxi- mum low sea level stand, in early postglacial time, at approximately 12 000 yBP. Modern sediment transport processes have contributed to the formation of areas of large sand bedforms, such as the Cape Split sand wave field and other isolated sand waves of the inner Bay of Fundy, and Eastern Shoal on Banquereau. Sandy sediments, found in many transverse channels in the nearshore, offer a potential for placer gold where proximal to adjacent onshore epithermal gold deposits. Lithothamnion covered gravel occurs as a thin lag overlying glacial sediments in much of the nearshore. Relict gravel beach ridges have been eroded and redistributed through sub-littoral processes after passage of the transgressing beach front. Multibeam bathymetry, sidescan sonograms and high-resolution seismic reflection profiles are the main survey tools. Ground truth consists of large volume seabed samples, vibrocores and photographs. A preliminary assessment of the aggregate potential indicates that very large volumes of suitable aggregate lie in the offshore of southeast Canada.

Jan 1, 1995

The growth of the mining industry around Australia over the last ten years has seen many open cut mines developed on shallow oxide reserves. Most of these have been gold operations, although there are some copper mines in the list, too. Many of these have exhausted their oxide reserves and have made the transition to underground mining to access their deeper sulphide ores. Other operations have reached or are approaching the point where the decision has to be made to go underground or cease mining. This paper discusses the issues involved in making the transition from surface to underground mining. The aim is not to discuss each of the issues exhaustively. This would take a conference in its own right. Nor is it intended to provide a primer on underground mining. Instead the aim is, firstly, to flag the issues which must be addressed when planning to make the transition from surface to underground mining and, secondly, to identify critical aspects of mine development.

Jan 1, 1997

By J. H. Nantel, J. F. Archibald

"The presence of radon from uranium-bearing ores, waste and from backfill material introduced underground to provide ground support, work platform and waste disposal functions, requires that ventilation controls be established to maintain safe working level concentrations. One approach has been developed at Queen's University to quantify radon and radon daughter source level s and to estimate ventilation requirements necessary to maintain these safe levels.Knowledge concerning the sources of radioactive contaminants and their production quantities is of value for planning and design stages of ventilation control systems. For any given mine layout, radiation level estimates may be forecast and modified by ventilation network design where excessive production quantities may exist.Behaviour of Radon Gas in MinesRadon gas, produced from the decay of Ra-226 in a host medium, will diffuse through porous media. In areas adjacent to mine workings, radon will be liberated into the mine atmosphere. The rate of radon emanation is proportional to the rate at which radon is produced within the host material (a function of the ore grade of U308) , to the radon concentration gradient in the host pores and to the diffusion properties of the material.The radon source concentration is determined by the rate at which Rn-222 is produced by the decay of Ra-226, and by the emanating coefficient (E), or fraction of the radon which escapes from the source matrix and is free to diffuse through the pore spaces."

Jan 1, 1984

By M. Lahtinen, B. Saxén, M. Latva-Kokko

The conventional jarosite precipitation process with neutralization by zinc calcine is widely utilized in the zinc industry. However, it has a significant drawback of causing losses of valuable metals like zinc, lead and silver to the jarosite. This comes mainly from the content of these metals in the calcine used for neutralization. As the zinc plants today want to maximize metal recoveries and minimize the amount of residues, this matter has become more and more relevant for zinc producers. Outotec developed and patented in early 2000 an improved version of the jarosite precipitation process in which the need for neutralization can be minimized, thus the metal losses to the jarosite also can be minimized. At the same time, the iron content of the jarosite increases and the amount of produced jarosite is smaller. The main feature of this process is to start the precipitation from ferrous iron after having reduced all the iron by zinc concentrate in a separate step before jarosite precipitation. Iron is then oxidised back to the ferric form simultaneously with jarosite precipitation. By this method, the formation of sulphuric acid is only half that compared to the conventional method and the need for calcine for neutralization can be avoided. High mixing and oxygen dispersion capability are needed in this jarosite precipitation process. Such capabilities are found in the Outotec OKTOP® reactor series. High performance reactors are not only needed to generate high quality precipitates, but also to maximize oxygen utilization; i.e., to minimize operation costs. Outotec’s latest development in this area is the OKTOP® plant product in which not only the reactors, but also all the accessories are designed, manufactured and delivered by Outotec. One responsible supplier ensures efficient and fast delivery and can provide mechanical and performance guarantees for the entire plant unit.

Jan 1, 2016

By Jason M. Ryan

"Along with recent advances in computer technology have come cost-effective systems desiiedto evaluate fragmentation distributions through digital images of particles. In mining operations andmineral processing plants, important data from these systems is obtained through monitoring sizedistributions at key stages of the comminution process. Blast engineers apply this technology as atool for the validation of empirical fragmentation models so that predicted results are more meaningful."

Jan 1, 1998

By E. Gilpin

Any estimate of the economic mineral value of an unvisited district is to the mining engineer largely a comparative one. If he knows that certain minerals characterize any given geological horizon he naturally draws upon his experience of the same ores as met by him cinder similar geological conditions. And if he has not had the personal experience, the investigation of the geology of a similar district as given in a trustworthy report enables him to lay a fair basis for conclusions. In a general way these conclusions are of value, and while they pronounce on the possible mineral fecundity of a given district, they

Jan 1, 1890

By Henry R. Joesting

DURING the past year and a half, the Territorial Department of Mines in Alaska has conducted a modest experimental program for the purpose of determining the extent to which magnetic and resistivity methods can be used in interior Alaska in connection with prospecting, mining and geological studies. Since little information is available concerning previous work,1,2 and since conditions differ considerably from those in most other regions, it was considered advisable to make a general study of the possibilities and limitations of the two methods, rather than a detailed study of any single problem. PROBLEMS One of the most serious handicaps to prospecting and geological study in interior Alaska, especially in the mature regions, is a cover of unconsolidated deposits ranging in thickness from a few feet to several hundred feet. These deposits, some of which are permanently frozen, consist of silt with varying proportions of vegetation and windblown material in the valleys and of residual deposits on the hills.3,4 The problems treated here are caused by the existence of this overburden: I. Location of buried placers. 2. Determination of depth and areal distribution of permanently frozen and of thawed unconsolidated deposits. 3. Location of water-bearing beds under unconsolidated deposits. INSTRUMENTS AND METHODS Magnetic and direct-current resistivity methods were used because they are relatively simple, rapid and inexpensive and because generally they are well suited to the study of the problems indicated. The instruments used were a vertical Schmidt-type magnetometer and a direct-current resistivity instrument similar to those used by the Geophysical Branch of the U. S. Geological Survey.5 For placer surveys with the magnetometer, a sensitivity of about 25 gammas per scale division was found suitable. For resistivity studies of frozen and thawed overburden and of underground water, the Lee partitioning method6 was found to be most generally suitable. In the Lee method a central potential electrode is placed midway between the two potential electrodes of the Wenner four-electrode configuration.7 Nonpolarizable electrodes were made from unglazed porcelain pots about 10 cm. high and 5 cm. in diameter. In order to retard evaporation of the electrolyte the sides of the pots were glazed, inside and out, with clear Duco lacquer. For resistivity work in cold weather, a nonfreezing electrolyte consisting of equal parts of ethylene glycol and a saturated water solution of copper sulphate proved satisfactory. Stainless steel rods of 3/4-in. diameter made excellent current electrodes because their bright finish enabled good ground contacts to be made.

Jan 1, 1941

By M. J. Ferrante

The Bureau of Mines investigated the applicability of the freeze-drying technique for preparing dispersion-strengthened tungsten powders suitable for conversion by powder metallurgy into materials which might have improved high-temperature strength. Extruded rods from compacts of tungsten-5 vol pct thoria had at 1,650° C a tensile strength of 30,300 psi and a 10-hour stress-rupture strength of 12,700 psi, These are slightly below those measured for swaged rods of commercial tungsten-3.7 vol pct thoria. Only those tungsten-thoria dispersions containing a stoichiometric deficiency of oxygen yielded a significant strengthening effect. A low-melting eutectic formed in extruded tungsten dispersions containing either zirconia or yttria, which caused a lowering of the tensile strengths. These tensile strengths were only slightly higher than strengths of elemental tungsten made from commercial powder having a particle size of 2.4 microns (Fisher subsieve). Sheet made from this commercial tungsten had a slightly higher tensile strength than tungsten made by freeze drying, but the freeze-dried tungsten sheet had a lower recrystallization temperature, a lower ductile-to-brittle transition temperature, and a higher purity.

Jan 1, 1971

By Ludovico Sebastiao Costa, Luis Albano Tondo, Bonzi Yokomizo Santos, Nelson Roberto Garcia Munhoz

This paper focus on the productivity, cost efficiency and training programmes that have enable RPM to rank as a world class operation in production efficiency and safety achievements. The first step was to commit all senior managers to implementing the NOSA Industrial Safety System based on Management by Objectives. This focused the workforce in a specific, results-driven direction which greatly promoted subsequent performance improvements. The early operations concentrated on increasing throughput via process simplification and removal of bottlenecks. Efforts were simultaneously directed to environment, health and safety as a means to improving the quality of operations. In the last two years, improvements in mining and in-tailings dam management have further improved the cost competitiveness of RPM such as to assure its future in treating the remaining CTBl ore reserves. Promissing progress is being made in developing a viable process to exploit a remaining large resource of B2 mineralisation.

Jan 1, 1993

By M. D. Johnson

Mina Santa Rosa, in west central Panama, is the first large-scale gold mine in Panama and will soon be the largest single-mine gold producer in central America (Fig. 1). At full production, the mine will process 1.8 Mt/a (2 million stpy) of ore and produce more than 1.8 t/a (60,000 oz/year) of gold and 9.3 t/a(300,000 oz/year) of silver. Mina Santa Rosa is a subsidiary of Greenstone Resources of Toronto, Ontario. Freeport-McMoRan geologists first visited the area in 1985. Their rock chip sampling adjacent to old shafts and adits confirmed widespread gold and trace element geochemistry anomalies. Surface mineralization appeared to be localized in and adjacent to narrow veinlets. However, they recognized astructural setting similar to the Nevada Tertiary volcanic-hosted epithermal gold systems.

Jan 1, 1996

By Erdal Unal

In order to define the support parameters, by use of empirical approaches, it is particularly important to analyze the rock-load height that should be controlled by supports. The controlling mechanism however, depends on the type of support used there- fore, the rock loads should be treated differently. In this paper, an empirical equation is introduced which relates the rock-load height (ht) to a quantitative rock quality index (REIR), and roof span (B) as fallows:

Jan 1, 1986

By Wm. Hamilton Merritt

With the exception of the Vancouver Island coal, all the western coal-fields owe their present development to the completion, in the autumn of 1886, of the Canadian Pacific railroad. While it could not be expected that a very great deal could be accomplished in three years, enough has been done to pretty thoroughly establish the coal-bearing areas and their correspondence with those which have been developed to the south of the boundary along the lines of the transatlantic railroads in the United States. This summer I visited some of the important developments in the coal areas of Washington Territory, largely with the object of being better able to appreciate the corresponding coal-bearing areas in British Columbia to the north. In Western Canada, coal-bearing rocks have been found in three zones: 1. In the plains to the east of the Rocky Mountains and in the eastern flanking ranges, the coal occurs in the Cretaceous formation (including the Laramie). 2. In the interior plateau of British Columbia, the coal is found in the Tertiary formation. 3. On the coast of British Columbia, Cretaceous and Tertiary rocks are found carrying coal, and on the Island of Vancouver the well known Nanaimo coal has been worked for years in the first named formation. In all of these zones, the coals vary from lignites up to higher grades, the factor determining quality being the amount of pressute to which they have been subjected. The intensity of this pressure is generally shown by the disturbance which the coals exhibit, and, in many cases, is almost directly in proportion to the distance of the deposits from mountain ranges. This seems to be also the opinion expressed by Mr. Bailey Willis in connection with his Census Report on the coals of Washington. It has been elsewhere stated

Jan 1, 1890

By John D. Morgan

The U.S. economy annually needs over 4 billion tons of new mineral supplies. The value of domestically produced energy and processed materials of mineral origin exceeds $175 billion annually, but domestic production of both raw and processed minerals is not keeping pace with demand.

Jan 1, 1974

Crushed limestone is now being "de-dusted" at the Warner Co. plant in Bellefonte, Pa., by a new high-efficiency classifier utilizing aerodynamic principles not previously employed in classifiers. Crushed limestone for certain glass industry requirements must not have more than 10 pct fines in the overall aggregate, and it is the function of the new-type classifier to separate these fines from the coarse material. During the development of this classifier by the Buell Engineering Co. of New York, it was found to have possible applications for separating pulverized coal, sintered metals, ores, mineral flours, and fillers, among other items. Limestone from Warner's deep mine is initially crushed and particles larger than 3/8-in. mesh are burned in kilns to provide calcium oxide for the chemical industry. The 3/8-in. screenings are dried and crushed to -16 mesh for use by the glass industry. For those applications requiring a minimum of fines, no more than 10 pct -100 mesh material is allowable in the end product. Hence the need for high-efficiency separation.

Jan 11, 1960

By Lennox A

In an attempt to increase underground productivity Coal and Allied has introduced a continuous haulage unit into it's Moonee colliery. A second unit is planned for Nallarah colliery in the near future. Both systems will be roof mounted or monorail type and manufactured by Joy Manufacturing Pty Ltd. The introduction of these machines is seen as a logical step in improving the efficiency of mining with continuous miners. This could be in conjunction with longwall mining in the rapid development of gate roads or, as in the case with these machines, as conventional development and extraction units. The advantages of the continuous haulage system are; Relatively low cost. 2 Ability to obtain high productivity in irregular or disturbed coal reserves not suitable for longwall mining. 3 Increased worker safety with the elimination of shuttle cars and the majority of trailing cables. 4 Increased productivity independent of soft or difficult floor conditions. At the time of writing the Moonee installation is 6 months old. The Nallarah machine is due for delivery March 1988.

Jan 1, 1988

By H. Mori

Construction of cast-in-place piles with enlarged bases has become popular in the cities in Japan facing to the sea coast, where the subground soil is soft alluvium deposited to depths often exceeding 30 m. The groundwater table is a few meters below the ground surface. Skin friction of piles may become negative due to ground subsidence or reduced due to liquefaction of loose sand during an earthquake. To support highrise buildings, depths of bearing strata to which piles are embedded often exceed 50 m. Due to such geotechnical conditions, methods and equipment to build cast-in-place concrete piles mainly built by the reverse circulation method have been developed since the 1970s. In the first half of this paper, the authors review the cur-rent practise of building cast-in-place piles with enlarged bases. Then they introduce the TFP system developed in recent years, and discuss about the procedures to control and monitor enlarging of bases.

Jan 1, 1989

By Jung-Hoon Ryu, Chang-Ha Ryu, Byung Hee Choi, Yang-Kyun Kim

Control of overbreak in tunnel blasting is one of the key factors affecting the construction expenses as well as safety. Overbreak causes an increase in the cost of construction by requiring an additional amount of shotcrete. In addition, blast damage to the final rock face may cause instability and rock fall hazards. For these reasons, controlled blasting is an indispensable routine in tunnel excavation in order to get a smooth face and to reduce damage to the final wall. We have experienced a very poor quality of excavation depending on the tunneling sites although a similar design of controlled blasting technique was applied. Field experiments over 40 rounds were carried out to investigate the cause of the poor results in tunnel blasting. In this paper, discussed are the parameters affecting the overbreak and some findings from the field experiments. Overbreak could be controlled considerably by adjusting some parameters before the efforts of developing a new blasting method.

Jan 1, 2004

By Blamey Stevens

The following paper aims to make a full explanation of the phenomena of rock jointing. It may be unnecessary to give any general description of what are termed joints in rocks, but Professor Geikie's clear and faithful generalizations are so illuminating that no excuse need be given for introducing the following and other quotations into this paper : " Almost all rocks are traversed by vertical or highly inclined divisional planes termed joints. These have been regarded as due in some way to contraction during consolidation (fissures of retreat) ; and this is no doubt their origin in innumerable cases. But, on the other hand, their frequent regularity and persistence across materials of very varying texture suggest rather the effects of internal pressure and movement within the crust." 1 General Explanation.—In this paper I show that the phenomenon of jointing may to a large extent be accounted for by the pressure of the water contained in the pores of the rock. To understand this, each constituent grain of the porous material may be considered to be separately compressed by the water which submerges it. As all the grains are held together by cohesion, the whole mass is contracted by this pressure. In an indefinitely extended mass, however, there must be a limit to the possible contraction without rupture, because the material is restrained from moving freely by other material around its boundariee. The mass of rock thus becomes broken up. This phenomenon is known as " shrinkage" jointing. The term " shrinkage " is an apt one, if it be understood that the shrinkage of the rock is often brought about by change of stress. Stresses.—The compressive component of water stress on the individual grains is evidently the same as that of the water with which it is in contact. This is so, both before and after the jointing is formed. Before the jointing is formed there is, however, a tensile stress in one or more directions which keeps the material from contracting. At the moment of the formation of joints this stress is equal to the cohesive compressive stress. This is more commonly known to engineers as the tensile breaking stress.

Jan 1, 1914