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By Y. H. Tang, H. Y. Zhang

"Tailings from lead-zinc mine contain plenty of dolomite and low-grade fine-grained barite, which is difficult to enrich by mineral processing. Since the density of barite and dolomite has some differences due to the fine dissemination size in a complex sedimentary, the gravity separation tests were conducted with no results obtained. The magnetic separation was conducted to remove the magnetic gangues, and the results were not satisfactory because of the gangue minerals such as limonite and others were low in content. The results of floatation tests showed that the mineral separation of barite and dolomite is quite difficult because that they have similar mineral floatability. Experimental research shows that the good results can be obtained by “desulfurizationbarite floatation” processing with the new depressant TS. The barite concentrate containing BaSO4 91.27%, BaSO4recovery is 70.25% when sodium dodecyl sulfonate serves as a collector and TS as the depressant.INTRODUCTIONBarite is an important mineral material. Often associated with other minerals, it usually needs to be separated by mineral processing in order to meet the application requirements. The main barite beneficiation methods include hand sorting, gravity separation, floatation, magnetic separation, acid leaching, etc. Usually barite associated with oxide ore such as fluorite dolomite, quartz ore etc. are also associated with sulfide ore such as pyrite, sphalerite and galena. The separation between barite and sulfide ore (such as pyrite) is easy. On the other hand, the separation between barite and oxide ore (such as dolomite and fluorite) is very difficult. There are quite a lot of reports on the separation between barite with fluorite dolomite however the separation between barite and dolomite is seldom discussed.The ore properties are quite complex attributable to mineral assemblage containing a large amounts of dolomite. As the density of barite and dolomite has some differences, gravity separation between them is usually easy. The gravity separation tests were conducted with no results obtained due to the fine dissemination size in a complex sedimentary. The magnetic separation was conducted to remove the magnetic gangues, and the results are not satisfactory as the gangue minerals such as limonite and others were low in content. Due to the fine dissemination and intimate association of minerals, and barite and dolomite contain the same group ions of Ba2+, Ca2+ and Mg2+, the results of flotation tests showed that the mineral separation between barite and dolomite by flotation means problematic. Previous studies have been conducted by several institutions but none to date has come up with a satisfactory process in dealing with the deposit. This may be attributable to: high cost of reagents; unsatisfactory performance. Therefore, the key to the flotation separation of barite and dolomite is the application of selective inhibitors. Based on previous test observations and years of extensive research experience in barite processing technology, with the new depressant TS has selectivity inhibition on dolomite developed and used, good results can be obtained by “desulfurization-barite flotation”, which allows barite in the lead-zinc tailings to a comprehensive recovery."

Jan 1, 2018

By T. B. Braun

Cathode contamination is the principal factor affecting the quality of electrorefined copper. It is commonly accepted that annealability is unfavorably affected by the following elements, in decreasing order of adverse effect: tellurium, selenium, bismuth, antimony, and arsenic. Silver in cathodes has importance as it represents a nonrecoverable loss of silver to the refinery. Mechanisms for the contamination of cathodes by these elements are examined and the effect of operating variables on contamination, including anode composition, electrolyte composition, electrolyte temperature, addition agent practice, and electrolyte discard rate, are discussed.

Jan 1, 1976

By W. A. Jones

THE Ross mine, a subsidiary operation of Hollinger Consolidated Gold Mines, Limited, is situated near the north end of lot 1, concession 2, Hislop township, Ontario. The property comprises the north half of lot 1, concession 2, and the south one-third of lot 1, concession 3. It is readily reached by a good motor road from the village of Ramore, 7.5 miles to the southeast on the Temiskaming and Northern Ontario railway. The-mine has been developed to a depth of 900 feet and the current daily production rate is about 260 tons. From the inception of operations in March, 1935, until December 31st, 1942, 455,720 tons of ore with a total value of $4,169,-316 have been milled. The silver to gold ratio of 1.48 to 1 is unusually high for Ontario gold mines. The deposit is interesting because the relationship between hydrothermal metamorphism and three successive stages of fracturing and mineralization is marked with considerable clarity. During the past seven years, detailed geological maps of the mine have been kept up to date, many thousands of feet of diamond-drill core have been logged, and numerous thin and polished ore sections have been studied. The present paper describes the structure and mineralogy of the orebodies.

Jan 1, 1944

Mineral sands are different to almost any other commodity; however, it shares similarities with other commodity types, such as the importance of quality constraints of iron ore and coal or the importance of physical properties of diamonds. The mineral sands industry consists of two principal product streams; titanium dioxide minerals û in the form of rutile, ilmenite and leucoxene, and zircon. The principal valuable heavy minerals (VHM) include ilmenite, leucoxene, rutile and zircon. Variations of other titanium minerals occur between the end members of ilmenite and rutile, including pseudo rutile and anatase. Most mineral sands deposits are found in unconsolidated fossil shorelines several hundreds of metres to tens of kilometres and occasionally hundreds of kilometres inland from the present coastline. Mineral sands orebodies essentially fall into two categories based on the mode of deposition: alluvial or aeolian. Alluvial deposits are further split into marine beach placers (or strandlines) and lacustrine heavy mineral (HM) accumulations. Exploration for mineral sands involves the positive identification of key criteria leading to the focus of exploratory surface sampling, augering and drilling. Assaying is primarily focused around determining the percentage of HM contained within a given sample. Other results of interest include clay fines, sand and oversize. Metallurgical/mineralogical assessment is often undertaken via laboratory scale bench tests that replicate the wet concentration and dry mill processing routes. The most critical component in resource assessment for mineral sands is about quantifying HM grade, then mineralogical assemblage and then quality of those mineral species. This will determine whether a mineral sand final product is marketable or not. Mining of mineral sands is conducted either wet or dry. Wet methods are generally preferred for large tonnage, unconsolidated and low clay orebodies. Where ground conditions are hard and orebodies are small, high grade and discontinuous, dry mining techniques are generally employed. Concentration of mineral sands from the primary ore is carried out in two sections; wet, utilising sizing and gravity differentiation between HM, VHM, clay and quartz, and dry, exploiting the magnetic, electrostatic and to a lesser extent specific gravity (SG) properties of the minerals of interest. Mineral sands exploration, mining and processing faces the same operating challenges as the rest of the resource sector. Added to this are the issues that are unique to mineral sands and to which the industry devotes considerable resources to developing solutions.

Jan 1, 2009

By Herbert Clark Hoover, Lou Henry Hoover

MOST illustrious Princes, often have I considered the metallic arts as a whole, as Moderatus Columella2 considered the agricultural arts, just as if I had been considering the whole of the human body ; and when I had perceived the various parts of the subject, like so many members of the body, I became afraid that I might die before I should understand its full extent, much less before I could immortalise it in writing. This book itself indicates the length and breadth of the subject, and the number and importance of the sciences of which at least some little knowledge is necessary to miners. Indeed, the subject of mining is a very extensive one, and one very difficult to explain ; no part of it is fully dealt with by the Greek and Latin authors whose works survive ; and since the art is one of the most ancient, the most necessary and the most profitable to mankind, I considered that I ought not to neglect it. Without doubt, none of the arts is older than agriculture, but that of the metals is not , less ancient ; in fact they are at least equal and coeval, for no mortal man ever tilled a field without implements. In truth, in all the works of agricul- ture, as in the other arts, implements are used which are made from metals, or which could not be made without the use of metals ; for this reason the metals are of the greatest necessity to man. When an art is so poor that it lacks metals, it is not of much importance, for nothing is made without tools. Besides, of all ways whereby great wealth is acquired by good and honest means, none is more advantageous than mining ; for although from fields which are well tilled (not to mention other things) we derive rich yields, yet we obtain richer products from mines ; in fact, one mine is often much more beneficial to us than many fields. For this reason we learn from the history of nearly all ages that very many men have been made rich by the

Jan 1, 1950

those who are to lie in the torn fields of France. Today we read of Lieut. William Hague, whom we said good-by to hardly more than a month ago-—so clean, ao young, so strong—who, abandoning the professional career in which he had won such commendation and which held for him such promise, leaving his wife and his little boy to whom he was so dear, answered at once the call for men of his training, and is now dead "in the service of his country." There are many friends of that courtly and dignified gentleman James D. Hague who recall, both here and in Stockbridge, the parental pride in the promising lad of such a little time ago—the eager schoolboy at Milton, the rather grave youth at Harvard, his entry into new experiences in the Western mining world, and who, seeing him during his stay at Camp Upton, realized that the old Puritan stock was still sound and true—and now with him the struggle is over and the sacrifice made. Captain William Teasdale Hall Captain Hall, who was admitted to Junior Membership in the Institute in 1915, while still a student of mining at the University of Toronto, was killed in action in France on May 19, 1917. Captain Hall was born in Toronto in 1893, and received his academic training at Harbord College, from 1908 to 1911, when he entered the University of Toronto, School of Practical Science. During the three summer vacations of his university course, he was employed by the O'Brien mine at Gowganda, next by the McIntyre Mining Co., at Porcupine, and finally by the Mines Branch of the Geological Survey, which was conducting magnetic surveys to the north of Port Arthur. When war was first declared, Mr. Hall endeavored to join the artillery as an officer, and for the purpose secured a provisional lieutenancy with a Hamilton battery, but he did not receive an overseas appointment, and on being graduated as a mining engineer in 1915, he was offered a position in Chile, which he accepted. He left Toronto on May 27, 1915, and was engaged in Chile as a mining engineer for nearly a year. In the latter part of April, 1916, he decided to offer himself again for service at the front. He crossed the Andes and sailed for LiverpooI, where he landed on May 13, 1916. On May 27, 1916, Captain Hall was given a commission as a lieutenant in the Royal Flying Corps, 21st Squadron. He went to the front on Sept. 1, 1916, and remained there continuously. His

Jan 1, 1920

By N Boughen, P Ashworth, S Johns, C J. Yeats, A Littleboy

The ocean floor, often called the last frontier, is increasingly discussed in terms of its resource potential û from near shore building aggregate and placer deposits to massive sulfide orebodies in the deeper ocean. Consequently there is an increasing incentive to mine the seafloor. But, do we have the social license to explore and mine the seafloor? Does this nascent industry have support amongst the wider community? If not, why not? And what should be done? To answer some of these questions, the Wealth from Oceans National Research Flagship has explored the social viability of an expanded seafloor exploration and mining (SEM) industry inAustralia. The results show that there are significant geological and environmental data gaps and that, in the absence of sufficient information, stakeholder reaction to the prospect of an SEM industry expansion may be reactionary and negative. This uncertainty means that the perception of risk from the industry is variable and often dependent on individual values. The acceptability of an expansion to the SEM industry is currently precarious, in particular due to the high levels of uncertainty regarding the environmental impacts of seafloor activity. While there are existing federal regulatory frameworks and government processes for the licensing of seafloor mineral exploration and extraction, there is little precedent in the application and implementation of these regulations. The future viability of the industry will be highly dependant on AustraliaÆs ability to improve the knowledge-base underpinning its regulatory regime and also to generate open and transparent communication channels between stakeholders. It will also be dependent on the SEM industryÆs ability to communicate an acceptable value proposition to society. This proposition will need to include the relative impacts of terrestrial and marine mining, the alternative potential uses of the ocean and the multi-use conflict that SEM might engender. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Rollin Farmin

Rock pressure against the supports for underground workings in certain mines becomes sufficiently severe to crush sound timbers. The cost of maintenance of these mines increases critically as the workings are extended. "Heavy ground " and "swell-jng ground" are terms commonly applied to a condition of excessive pressure from the wall rock. Defined for the purposes of this paper, "heavy ground" delivers gravi-tative pressure on the supports of a mint opening; "swelling ground" delivers pressure arising from expansion of the wall rock. Mining problems created by heavy ground have been studied extensively by mining engineers, as in the recent Symposium on Block caving.' A parallel study of rock bursts2 attacks the field of ground that ruptures under strain. The problem of swelling ground, which has received less current attention, is the subject of this paper. An ExaMPLe of Swelling Ground Severe cases of swelling ground are found in the gougy shear zones in mines along the western Sierra Nevada, where the veins are accompanied by faults through altered serpentine, schist and slate. For example, along troublesome stretches in the ldaho Maryland mine, Grass Valley, California, swelling ground continues to crush drift timbers, with diminishing intensity, for 3 to 10 years after entry. During this period, from five to nine generations of crushed timber sets must be replaced and a large additional tonnage of scaly rock and wet gouge must be removed from the drift to make room for this succession of new timbers. After "the squeeze has been taken out of the ground" the timbers will stand for years, until they collapse from decay. Heaving of floor and footwall along drifts develops soon after the timber sets are placed and frequent grading down of the track is necessary to keep it serviceable and to maintain headroom. If sills are placed under the drift posts, the sets break more quickly and the track becomes impassable at once. When the floor is left Open? and the bottoms of posts and stulls are pencil-pointed, the scaly ground of the fault zone swells up around the timbers (Fig. I) instead of breaking them (Fig. 2). A foot or two of this encroaching ground is trimmed from the floor and lower sides of the drift several times before complete retimbering is necessary. when a set of timber fai1s under the Pressure of swelling ground, there is no immediate fall of timber and broken rock to fill the drift, as is customary in heavy, caving ground. Instead, ground swelling from sides, top and bottom gradually closes the opening, over a period of weeks or months, and no especial hazard to workmen is present while they have room to walk through the narrowing drift. Most

Jan 1, 1946

By K. Heindlhofer

ESTIMATES of the "plasticity" of a metal are commonly deduced from three types of test-tensile, torsion and impact. The several results have been more or less at variance, though this disparity has attracted little notice, largely perhaps because they have been expressed in different terms. The discrepancy between the results of the three tests becomes obvious when each is made at a series of low temperatures, for the temperature range within which the "plasticity" of iron largely disappears proves to be very different in the three types of test. The rather abrupt disappearance of "plasticity" of iron within a narrow temperature range cannot be due to any physicochemical change (such as a precipitation) taking place in the material at that time, because the original plasticity is immediately regained when the temperature of the material is brought above the sensitive range. Accordingly this differ-ence in behavior shows that the "plasticity" of a metal depends upon the mode of action of the stresses which produce the deformation, and there-fore upon the method of test. Analysis of the stresses leads to the conclusion that the observed plasticity of a metal is determined by the relation between its resistance to rupture by separation and its resistance to shear (slip), on the one hand, and between the effective normal and shearing stresses on the other; and that the relation between the two resistances does not in general remain constant with change of temperature, and may somehow be altered to some extent by the previous treatment of the specimen. This suggests the view that the results of none of the usual mechanical tests are directly comparable even for a single metal tested at a series of tem-peratures, or for a series of metals at one temperature, because the propor-tion of the total resistance of the metal to the test contributed by the

Jan 1, 1934

By Richard S. Allen

"The casual visitor is not apt to think of the Adirondacks as a one-time hive of mining and manufacturing activity. However, where there are mountains there are usually minerals and northern New York State is no exception.The Adirondacks are a rocky shield, a great stone cap pulled down over what is now northern New York. The bedrock consists of layered metamorphic rocks which were once sandstones or limestones on the bottom of a shallow sea that covered the region 1000 million years ago. The highlands are composed for the most part of the igneous rock anorthosite. Ancient earth upheavals at temperatures of at least 750°C mixed molten masses of anorthosite and the minerals it contained with the older metamorphic rock, resulting in deposits of iron-titanium oxide s, red garnet and other valuable minerals. Of these, the most readily recognizable was iron.The first hint of the existence of iron ore in the Adirondack Lake Champlain region of upper New York State seems to have come from a Swedish naturalist, Peter Kalm (1716-1769), who travelled through French Canada and visited the military outpost of Fort St. Frederic in 1749. In July of that year, Kalm wrote:""Among the kinds of sand which are found on the shores of Lake Champlain; one is black and the other garnet-colored... and they sparkle when the sun shines. All the grains of this sand without exception are attracted to the magnet, the uppermost or black sand being about a quarter inch deep...""Concerned primarily with the fur trade, the officers and men who occupied this remote bastion of La Belle France were apparently unaware of the industrial and commercial possibilities beneath their feet. No deposit of iron was then known to exist any closer than the Three River s area in Lower Canada."

Jan 1, 1983

By B. W. Madsen

To help maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines developed a mathematical model that describes acidic ferric sulfate leaching of copper from sulfide ores. The leaching model can aid in maximizing minerals and metals recovery from primary sources by giving operators and management a better understanding of the copper leaching process. This will aid in improving dump leaching operations. The model is based on a steady-state approximation of the continuity equation for diffusion of ferric ions in the rock pores and the intrinsic leaching kinetics of the various sulfide mineral particles. Ore characteristics included in the model were ore particle-size distribution, particle shape, grade, mineral content, mineral particle size, porosity, and tortuosity. The continuity equation was used with ferric ion concentration gradients and a fixed value for the diffusion coefficient. Except for effective diffusivity, each of these factors was either measured experimentally or estimated from theoretical considerations. The effective diffusivities were determined by fitting calculated leaching curves with experimental leaching data. Vertical variations in leach solution composition and temperature within a dump are not considered in this model. The model accurately predicted copper extractions for several large-scale tests during nearly 500 days of leaching.

Jan 1, 1981

By Yanping Xiao

In submerged-arc furnace (SAF) for smelting chromite ores into ferrochrome, there exist large temperature gradients and wide distributions of mineralogy and compositions in the furnace, due to the complexity of feed structure and electrical-thermal-chemical interactions. This leads to various zones in the furnace and thus different reaction mechanisms. In the present paper, the behaviour of chromium in the submerged arc furnace is discussed in various reaction zones, including solid state chromite reduction in the packed bed zone, chromite dissolution and reactions in the smelting and coke bed zone, and recovering chromium from slag to metal. In the gas-solid reaction zone, the reaction mechanism is discussed based on the experimental observations and analysis. In the smelting zone, the behaviour of partially reduced chromite and slag formation are analyzed based on the information in literature. The slag in FeCr process contains mainly Al2O3, MgO, SiO2, CaO and CrOx, featured by chromium with both divalent and trivalent oxidation state, which plays an important role for chromium recovery into metal. The factors influencing the slag and metal interfacial reactions and the chromium recovery are addressed.

Jan 1, 2006

By D. T. Kinard, A. A. Schweizer

An operational 9 meter (30-foot) high gold heap leach pile was investigated by excavating test pits up to 6 meters (20 feet) deep, obtaining bulk and relatively undisturbed thin wall drive samples, and observing the ore distribution patterns exposed in the test pit walls. The clayey ore is crushed, agglomerated with lime and cement, and deposited on the leach pads using a radial stacker. Laboratory tests performed included moisture-density, gradation, compaction, Atterberg limits, permeability (constant and falling head), and triaxial strength tests. Discussion is presented on the effects of agglomeration on the permeability and strength characteristics of the in-place ore. Also discussed is the effect of deposition of the ore using the radial stacker.

Jan 1, 1987

Provide long-term measurement of mine sidewall closure in backfilled stapes subject to flooding. Approach A water resistant extensometer is made by enclosing a rod-actuated transducer in a telescoping tube which is enclosed within an oil-filled outer housing. How It Works To assemble a water resistant extensometer, a cylinder -shaped transducer and two support rings are pushed into the small-diameter section of the telescoping tube where the transducer is held in place by friction. The outside of the small-diameter section of the telescoping tube is then greased and slid into the slightly larger-diameter section. See drawing. The cylinder-shaped transducer contains a potentiometer whose actuating arm is attached to a stainless steel extension rod that passes through one end of the telescoping tube. A similar rod is attached to the opposite end of the transducer body, and extends through the other end of the telescoping tube. A coil spring inside the large diameter end of the telescoping tube extends the tube

Jan 1, 1978

By W. H. Chang

The phase identification results on several Mg-base alloys are presented. These results have been correlated with strength data and microstructural studies to indicate that carbide dispersion may contribute significantly to raising the recrystallization temperature and strength of Mo alloys. Evidence is presented to show that the degree of carbide dispersion, and hence the extent of strengthening, is governed by the "metal/carbon" ratio which, in turn, depends on both the carbon content and the presence of stable -carbide-forming alloying elements. IN recent years, Mo-base alloys containing small additions of C, Ti, and/or Zr have been developed, which exhibit much higher recrystallization temperature and strength than those of unalloyed Mo. The superiority of these alloys undoubtedly results from simultaneous operation of more than one strengthening mechanism. In the present paper, the strengthening effect of carbide dispersion will be discussed. Although the role of carbide dispersion is being increasingly recognized, the nature of the carbides has, to the author's knowledge, not been well es- tablished. In Table I are presented some of the phase identification results on representative Mo alloys. These results have been obtained by X-ray diffraction of residues electrolytically extracted from an ethyl alcohol solution containing 7 pct HC1.

Jan 1, 1961

By E. Forssberg, Y. Zeng

Fine crushing and rod grinding have been investigated using a laboratory-scale jaw crusher and a rod mill. The net energy consumption in both crushing and grinding was evaluated from torque measurements. An empirical relationship was established between energy consumption, particle size and operating parameters. When the mill feed size is reduced, through fine crushing, to about 80% passing 3 mm, the energy consumption will be minimized in a comminution chain of fine crushing and coarse rod grinding. The results in fine crushing were compared with a large-scale test.

Jan 1, 1993

By R. J. Davidson

The mechanism of gold adsorption on activated charcoal by R. J. DAVIDSON: M.Se., Ph.D. (Rhodes) (Visitor) The adsorption of gold onto activated charcoal is most dependent on the concentration and character of the 'spectator' cations present in the adsorption medium. In the presence of calcium ions, gold is adsorbed as the calcium aurocyanide complex. The degree to which the aurocyanide complexes are adsorbed follows the series Ca> Mt:> H> Li> Na> K, calcium aurocyanide being the most stable complex and potassium aurocyanide the least firmly bound. If a loaded charcoal, where the gold is present as the calcium complex, is treated initially with either sodium carbonate or potassium carbonate solutions, the gold can subsequently be eluted from the charcoal with hot deionized water as either the sodium or the potassium complex respectively. The elution of gold with deionized water appears to be most attractive practically and economically, and has several potential applications in the recovery of gold from dilute solutions.

Jan 10, 1974

By W. A. Backofen, D. H. Avery, G. A. Miller

An evaluation has been made of the relative importance of yield strength (?) and stacking-fault energy (y) to the rate of fatigue-crack growth in materials of fcc structure. Pure copper and its solid-solution al-loys with aluminum and nickel were chosen for the study because they provided sufficient range in both quantities of interest that either could be varied independently of the other. Experiments involved alternating tension and compression of flat specimens which were prepared with sharpened internal notches so that most, if not all, of the crack-nucleation interval could be eliminated. Growth rate (dC/dN) was concluded to be proportional to the square of the plastic-strain amplitude (€,,) over a strain range of approximately 6x 10-4 to 6 x 10-3. The factor, k, linking dC/dN and ep in dC/dN = kEp2 increased and decreased with corresponding variations in y, but it did not respond syste?>/atically to change in ay, indicating that y is the significant variable in crack growth at constant plastic-strain amplitude. In polycrystalline material, k varied by a factor of 5 over the available range of y. In a few single-crystal experiments on Cu-A1 alloys the growth rate responded less strongly to change in y. It has been suggested that single crystals behave somewhat differently than poly crystalline material because there is more extetnsive substructure near the grain boundaries in the latter, and this facilitates crack advance by separation along subgrain boundaries. A point of some controversy in current work on fatigue relates to the effects of strength and stacking-fault energy on crack growth. In recent experiments a separation was made between the cycling intervals for crack nucleation and the subsequent growth that eventually ends a specimen's fatigue life.' The study was carried out on Cu-A1 alloys primarily, fatigued in alternating four-point bending to constant deflection. A nucleation interval of about 10' cycles (at a total strain amplitude = 0.2 pct) was found to be insensitive to aluminum content in the range 0 to 7.5 wt pct, while the growth period was increased approximately forty fold over the same compositional range. The increase was not in any sense linear, however. Rather, most of the change occurred below 4 pct A1 or a stacking-fault energy, ?, of about 15 ergs per sq cm. It was argued that the plastic-strain amplitude was approximately constant, and therefore the effect of composition must have grown out of the reduction in stacking-fault energy. Several studies have shown that, with high ?, cross slip is encouraged, subgrain structure is introduced during fatigue, and cracking is aided through propagation along subgrain boundaries.1-5 Therefore, lowering ? sufficiently to interfere with substructure formation would be expected to retard growth rate. On the other hand, it is a general rule that resistance to fatigue cracking increases as strength is raised. Accordingly, there might still have been some doubt that Y was the controlling variable, since strength would be increased as y was lowered by the aluminum additions. To help in dispelling that doubt, an experiment was made on a polycrystalline Cu-Ni alloy similar in strength to the Cu-A1 alloys but of higher ?; the crack-growth interval was found to be essentially that of pure copper.' Further support for this position on stacking-fault energy as it relates to crack growth is derived from work by Boettner and McEvily,6 in which the actual crack-growth rate was measured on samples previously notched so as to minimize the nucleation period. Unfortunately, it was necessary in isolating strength level to compare different alloy systems and grain sizes. Recognizing the complication, it was still concluded that growth may be retarded by a reduction in y, per se. A related study has also been made by Roberson and Grosskreutz.7 The zinc content of a brass was systematically changed to alter strength and stack-ing-fault energy, although not below the 15 ergs per sq cm at which pronounced change in growth interval was found in the earlier work. The results were limited to more or less conventional S-N diagrams so that nucleation and growth events could not be separated. No definite conclusions were drawn, but

Jan 1, 1967

By Allnutt S. L, Radojkovic A. M

Century, a major shale hosted zinc deposit in the Riversleigh Fold Zone of northwest Queensland's Mount Isa Basin, was discovered by CRA Exploration in 1989. A total of 322 drill holes, completed by the end of 1992, define a resource of 118 Mt of mineralisation averaging 10.2 per cent zinc, 1.5 per cent lead and 36 grams per tonne silver. Mineralisation is developed in the upper portion of Lawn Hill Formation Unit 4 (Pmh4). The intersection of the Termite Range and Little Range Faults, major regional structures, may have been important in controlling mineralisation development. Three listric normal faults, and an unconformity between Proterozoic rocks hosting mineralisation and overlying Cambrian carbonates, divide the deposit into three distinct blocks. The deposit is essentially blind, outcropping in only two places. The deposit is characterised by an extremely simple sulphide mineral assemblage, sphalerite being the most common sulphide phase. Pyrite, the most common phase in many other shale-hosted zinc-lead deposits, accounts for only five per cent of all sulphides present. Siderite is the principal non-sulphide phase present. Both sphalerite and galena have near stoichiometric compositions. Sulphides are confined to carbonaceous shale horizons. Intervening siltstones are essentially barren. Shale and siltstone beds forming the mineralised sequence can be correlated across the entire deposit area. Systematic grade variation occurs within each mineralised shale bed. Although sulphide laminae parallel primary lithologic layering, the point of most intense mineralisation development transgresses stratigraphy. Bituminous material is intimately associated with sulphide mineralisation.

Jan 1, 1993

By A. Gene Collins

The demand for lithium may increase because of its potential use id lithium batteries and in the generation of electrical power by fusion. Therefore, lithium abundance in some United States oil-field brines was surveyed. Oil-field brines from numerous locations were found to contain more than 100 mg/l lithium and several exceeded 500 mg/l. An area of 25,000 km2, with a reservoir thickness of 60 m, an effective porosity of 5 percent, and a brine with a specific gravity of 1.2 containing 100 mg/l of lithium, contains about 0.75 x 106 tonnes (1 tonne = 1 metric ton = 1,000 kg) of lithium in 7.5 km3 of brine. It is postulated that the brines were enriched in lithium by lithium-rich spring water or lithium leached from volcanic rocks followed by evaporation sequences.

Jan 1, 1978