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By George Burgess

I. INTRODUCTION THE suggestion has often been made that it would be highly desirable, at least for certain grades of steel, to be able to control more certainly, by pyrometric measurement or otherwise, the temperatures of the operation of the open-hearth and other furnaces used in the manufacture of steel and iron. That the properties of the ingot and finally of the finished steel product are intimately related to the final temperatures attained by-the metal inn the furnace and to the temperature of casting, has been recognized by metallurgists for a long time, and this question has been very thoroughly treated, especially by Prof. Henry M. Howe, and by A. W. and H. Brearley.1 It is the object of this paper to demonstrate that in so war as casting temperatures of furnaces, steel ingots, and similar operations involving the temperatures of streams of iron and steel are concerned, well-known pyrometric methods s may be easily applied-if certain recently determined corrections are made and precautions taken-with a relatively high degree of accuracy. Greater but not insurmountable difficulties will be encountered in. the case of open-hearth furnace temperatures, while for" those of the converter type a ready solution does not seem practicable. It appears that certain essential data have always been lacking in reporting observations such as those of Le Chatelier in 1892. Thus the correction to be applied for the characteristic radiation-or emissivity¬has hitherto not been adequately taken into account nor the limitations of the several possible pyrometric methods clearly recognized.

Jan 2, 1917

By Brian W. Mackenzie

Since mineral economics is often coupled with mining engineering in the solution of mineral industry problems, it is important that the principles of this science be a part of the mining engineer's education. Essentially, mineral economics is the application of economic principles to analysis of the multistage process by which minerals are converted from geologic resources to marketable products. In some instances, it may require only the analysis of case studies from a well- developed economics core. In others, however, it requires special skills, because some aspects of the mineral conversion process--such as mineral occurrence, exploration investment and depletion-have no complete parallel in general economics. The mining engineer has been an important contributor to the analysis of mineral economics problems because of his special knowledge of the mineral industry.

Jan 1, 1971

By V. B. Royer, C. H. Harty

"MANGANESE-SILOCON ALLOYS AS DEOXIDIZERSThe basic open-hearth process for steel mining requires large amounts of oxidized iron for oxidation of the elements carbon, silicon, manganese, and phosphorus which are to be removed from the metal. Some of this oxidized iron (FeO) dissolves in the metal during the refining process, Subsequent to the elimination of the elements named, a considerable amount of dissolved iron oxide must be removed before the metal may be cast into ingot form. The elements generally used, for iron oxide removal, or deoxidation, are silicon, manganese, and aluminum. Silicon and manganese are always alloyed with iron, either singly or in combinations of various compositions. Aluminum generally is used in a commercially pure state and sometimes in complex alloys. A double deoxidizer of manganese and silicon alloyed with iron for furnace deoxidation has been the subject of an extensive cooperative investigation between the United States Bureau of Mines, the Carnegie Institute of Technology, and the Metallurgical Advisory Board. Certain grader of steel, especially low-carbon rimming steels, require a low-carbon deoxidizer to keep the finished steel within the carbon specification after deoxidation. ACKNOWLEDGMENTThe authors wish to acknowledge the assistance of J. F. Sanderson and S. S. Johnston in the analysis of the alloys used in this work.PURPOSE OF WORKThe need for definite information as to which compositions of manganese and silicon within a certain manganese-silicon ratio and when alloyed with iron would have an allowable carbon content for the particular grade or type of steel on which the deoxidize is used, prompted the undertaking of this investigation to determine the solubility of carbon in manganese, silicon, and iron alloys within the region bounded by 10:1 and 4:l manganese to silicon ratios. These data should be of value to the manufacturer producing such"

May 1, 1934

By D. Cubicciotti

IT has long been known that some metals are capable of being dispersed or dissolved in certain of their fused salts.' Davy' and Bunsen³ were among the first to observe that in some fused salt electrolyses, a highly colored, strongly reducing salt phase appeared in the neighborhood of the cathode. Later workers found that the current efficiency of the electrolysis was markedly reduced when such a phase appeared. It was also found that the strongly reducing salt could be made by melting the metal and normal salt together. Chemical analysis showed that in such salts the metal ion to anion ratio was always larger than in the normal salt. From such observations arose two different explanations of the nature of metal in salt solutions. When a solution of this type is quenched, it is possible to find small globules of metal in the salt. From this and other observations, Lorenz' and co-workers assumed the metal in salt solution to be a colloidal dispersion of metal in the fused salt and called it "metallnebel" or metal fog formation. They made a number of experiments to substantiate this point of view. Another school felt that when the metal dissolved it reduced the salt partially to a mixture or solution of normal salt and subsalt. Both of these ideas could explain the strong reducing character of the salt formed and the low current efficiency of the electrolysis. If either a metal colloid or a subsalt were formed at the cathode and diffused to the anode, it would be oxidized to the normal salt. Thus a cyclic process of oxidation and reduction could be set up conducting the current without giving rise to a net change in the system. These facts led the author to investigate some of the properties of metal in salt solutions with the hope of elucidating their nature further. Among the metal-salt systems that form metal in salt solutions most markedly are the alkaline earth metal-halide systems and cerium, bismuth, and cadmium halides. Other systems of halides, oxides and sulphides form such solutions to a lesser degree. The first work undertaken was a study of the temperature-composition diagrams of some of the systems." From such diagrams it would be possible to distinguish between a subhalide formation or a colloid. A subhalide should give rise to characteristic changes in the phase diagram, while a colloidal dispersion of metal in salt would not alter the freezing point of the salt. The results obtained on a number of alkaline earth metal-halide systems were all quite similar. Fig. 1 shows the barium-barium chloride system. The other

Jan 1, 1954

By E. G. Valdez

Iron foundries that melt automobile scrap produce flue dusts averaging about 32 percent zinc and 6 percent lead. Some is sold to smelters, but because of the meager return and difficulty in handling, most of the dust is discarded. As part of the Bureau of Mines program to find uses for mineral wastes, research was initiated to develop an economical process to recover zinc and lead from the flue dust. Research encompassed the extraction of zinc and lead by fuming, leaching, and agglomeration. Controlled vacuum fuming of zinc to produce Prime Western zinc and a lead-rich residue was the most effective method for treating the dust. This process involved two distillations, or fumings, with carbon and methane as reductants, and resulted in recovery of 91.4 percent of the zinc in a Prime Western grade product, and 98 percent of the lead. Hydrometallurgical techniques involved several leaching methods, but the simultaneous extraction of iron, manganese, and copper resulted in contamination of the solution and made the zinc recovery processes too complicated. Agglomeration was done by pelletizing or briquetting the dust for possible use as feed to a zinc smelter.

Jan 1, 1975

By Max W. Bowen, A. J. Weinig

The important part that dissolved oxygen plays in the cyanide treatment of gold and silver ores is commonly recognized by most metallurgists and mill men. But heretofore there has been no simple method on which the mill man could rely for determining the amount of oxygen in the various mill solutions. A few methods are adaptable to the laboratory, such as the gasometric1 determination by actually measuring the oxygen, Winkler's2 iodometric method, and Schutzenberger's3 method, which depends on the reducing action of sodium hyposulfite on a blue solution of indigo carmine; but these are not readily adaptable to the needs of the mill man and cannot be applied to cyanide solutions without modification. The gasometric method is the most accurate but it takes too long to complete a determination. White's4 method (a colorimetric method that depends on the degree of coloration imparted to a solution of pyro-gallic acid in the presence of caustic soda) although much more rapid than any of the methods named, often gives misleading results on account of grading of colors of different solutions, which nearly always contain various kinds of salts. The method herein described was devised for the use of the mill man, the aim being to develop a simple, practical, accurate method. It is a modification of the Schutzenberger method and depends on the reducing

Jan 1, 1925

By Edgar Bain

THE results are presented of an investigation to discover the fundamental atomic conditions existing in Corson's high-copper alloys hardenable by means of silicide solution and reprecipitation. The study attracted the writer because it offered a very convenient example of the general type of hardenable alloys exemplified by duralumin, Sykes' iron-tungsten and iron-molybdenum alloys and the hardenable lead antimony. SUMMARY OF RESULTS AND CONCLUSIONS In brief, the investigation shows that very perfect crystallinity exists in the solid solutions prepared at high temperature to contain as much dissolved silicide as possible. The lattice parameter of copper is altered very little by the amount of cobalt, nickel or chromium, and silicon dissolved. The hardening by drawing at a temperature to initiate precipitation of excess silicon and metal produces a remarkable change in the atomistics of the solid solution. The old perfection of crystallinity in the solid solution is destroyed and the new atomic spacings are of variable magnitude even in one grain, and a condition in a measure resembling that found in martensite is observed. Were no particles whatever precipitated by the drawing action, still ample causes for hardness would be in evidence in the solid solution alone. The lack of plane continuity in the crystal grains would oppose slip in a very effective manner. Complete annealing restores the crystalline perfection in large measure. In these alloys even the most sensitive methods failed to reveal the characteristic pattern of the silicide precipitated by the anneal, but this was largely to be expected as the amount is relatively small.

Jan 1, 1927

By S. Banisi, J. A. Finch, A. R. Laplante

"A technique for on-line simultaneous estimation of gas and solids holdup (volume fraction), based on a combination of conductivity and pressure difference measurements, is proposed and tested in a laboratory flotation column (10cm in diameter and 447cm in height). Fundamental concepts underlying this technique and the effect of relevant parameters are discussed. In the studied range, 3-30 %v/v gas holdup and 2-18 % v/v solids holdup, experimental results showed good agreement between the estimated and actual holdup values (as determined by an isolating technique). The relative accuracy of the solids holdup estimation increased when solids density or solids concentration increased. Frequent re-calibration of pressure transducers was found necessary for accurate phase holdup estimation.IntroductionGas holdup is a key parameter in controlling the performance of flotation columns. For example, flotation rate is affected by bubble size and gas rate both of which, in turn, affect gas holdup. Moreover, gas holdup also determines the slurry residence time which indicates a direct influence of gas holdup on recovery.Gas holdup determination has been the focus of many studies (e.g., Castillejos, 1986; Marchese et al., 1992). Some of the techniques which have been used are given in Table 1."

Jan 1, 1994

By G. T. Adel

Hindered-bed separators are often used in the minerals processing industry to classify particles according to size and density. A new technology, known as the Eriez CrossFlow, was recently developed to overcome some of the limitations associated with hydraulic separators. The innovative feature of this unit is a novel feed presentation system that improves separation efficiency and capacity. In the present work, a detailed process engineering evaluation was conducted to determine the basis for the improved performance of this unit. The evaluation included controlled separation tests using well-characterized feeds, particle and liquid tracer experiments and mathematical modeling studies. Data obtained from this work show that the new separator is capable of maintaining good separation efficiencies at higher solid feed rates than traditional designs due to improved hydrodynamics in the separation zone. This paper reviews the operating principle of the Eriez CrossFlow separator, discusses the results of the tracer experiments and modeling studies and presents test data obtained from recent laboratory and plant trials. Key words: Size classification, CrossFlow separator, Hindered-bed separator, Hydraulic separator

Jan 1, 2003

By G. St-Amant, V. Cloutier, E. Ghali, S. Jin, G. Houlachi

During the casting of lead-silver anodes, variations in cooling rates result in the formation of an uneven microstructure. The slowly cooled areas (SCA) have a coarser microstructure than that of the remaining part (called "the general zone"). The effect of anode microstructure on the electrochemical behavior was investigated using galvanostatic, potentiodynamic and electrochemical impedance techniques. The results show that the resistances for the two steps of the oxygen evolution reaction on the slowly cooled areas of Pb- Ag anodes are higher than that on the general zone. The double layer capacitance for the first step of the oxygen evolution reaction (OER) and the pseudocapacitance of the second step of OER on SCA are smaller than those on the general zone. The potentiodynamic results show that the amount of lead dioxide formed on the SCA is greater than that of the general zone of the anode. The potential decay curves after 30 minutes of galvanostatic polarization at 45 mA/cm2 show that the corrosion potential of the SCA is 200 mV lower than that of the general zone. This can lead to perforation because of the formation of a galvanic cell with a small anode and a large cathode.

Jan 1, 2000

By Andrews S. J

Century is a shale hosted zinc, lead, silver deposit developed within gently folded, Proterozoic Lawn Hill Formation shales and siltstones, approximately 250 kilometres north-northwest of Mount Isa, comprising 118 million tonnes of stratiform mineralisation, averaging 10.2 per cent ,,inc, 1.5 per cent lead and 36 grams per tonne silver. The deposit is largely overlain by Cambrian limestone and younger Proterozoic sedimentary rocks, outcropping at only two places. Small discordant lode lead-silver deposits formed the basis of relatively small scale mining activity in the area for almost 100 years, exploration tenement covering the deposit being granted to CRAE exactly 100 years after the first mining leases were pegged in the area in 1887.Stratiform mineralisation occurs within three distinct blocks, bounded by normal faults and the unconformity between Lawn Hill Formation and overlying Cambrian limestones. The Termite Range Fault, a major northwest trending, regional scale fault system occurs adjacent to the northeast deposit boundary, while the Magazine Hill Fault, possibly a component of the east trending Little Range Fault system, forms the southern boundary of the deposit.

Jan 1, 1993

By E. L. Dougherty, J. W. Sheldon

Using the numerical techniques shown in this paper it is possible to compute the simultaneous dynamical behavior of multiple fluid-fluid interfaces in two dimensions. Hence, fluid-fluid inter face models of several oil recovery processes can be constructed which allow prediction of the effect of fluid flow in two dimensions on the behavior of these processes while taking into account various physical effects, such as saturation gradients, phase changes and thermal stimulation. Techniques for constructing fluid-fluid interface approximations for several oil recovery processes are reuiewed. The validity of these techniques is established by comparison to experimental results. The availability of a computer program for computing the behavior of multiple fluid-fluid interface problems makes the use of potentiometric models uneconomic. The results indicate the areal sweep efficiencies obtained from potentiometric model studies at high mobility ratios may be somewhat optimistic. The results also indicate that the areal sweep efficiency curves obtained at high viscosity ratios 2—4 using miscible fluids in porous media are misleading and that considerable care must be taken in defining the mobility ratio for a displacement process, especially for miscible fluids. INTRODUCTION Many of the methods used to estimate areal sweep efficiency assume that the oil recovery process can be represented by one or more fluid-fluid interfaces. When the mobilities of the displaced and displacing phases are assumed equal, this quantity can be computed using analytical mathematical methods.l.2 For non-unit mobility ratio, experimental methods based upon the fluid-fluid interface concept include potentiometric and electrolytic blotter models. Scaled models of porous media have also been used to study this problem. Fay and Prats3 and Aronofsky4 used numerical techniques to compute breakthrough sweep efficiency, but neither of these studies were extended beyond breakthrough. Numerical techniques which have been developed for solving a general fluid-fluid interface problem are presented in a companion paper.5 These techniques have been incorporated into a program for a large-scale digital computer which can treat simultaneously the dynamical behavior of as many as six fluid-fluid interfaces. Thus it is possible to simulate the behavior of several oil recovery processes taking into account such effects as saturation gradients. Techniques for representing several oil recovery processes by fluid-fluid interfaces are presented. Processes considered are conventional water flooding with and without a mobile gas phase, hot water flooding, miscible flooding and enriched gas drive. Other processes, whose effects could be studied by this technique, but are not considered in detail here, are underground combustion and steam injection processes and various slug processes such as gas-water injection and alcohol-solvent processes. Theoretical results obtained with single interfaces for mobility ratios of 0.25, 1, 2, 4, 8, 16, 32 and 64 in a repeated five-spot are compared to experimental results for this geometrical configuration obtained using miscible fluids and conductive analogs. Predicted recovery curves for water flooding in a repeated five-spot are compared to experimental results reported in the literature. Example calculations are shown for a conventional water flood in the presence of a free gas phase and for a hot-water flood. MATHEMATICAL PRELIMINARIES We assume that the rock matrix is homogeneous with constant thickness, absolute permeability and porosity. The fluids are incompressible. We also neglect the effects of gravity.

Jan 1, 1965

By O’Brian. Daniel T.

Ore reserve determinations supporting property appraisals and economic analyses leading to investment decisions typically require many repetitive calculations. Computers have become well-accepted tools for accomplishing these computations, and are partly responsible for the development of new evaluation methods during the last decade. Excellent descriptions of manual ore reserve may be compared with current computer reserve methods1,2 in North America2 and South Africa3. A comparison indicates that computers are used in two cases: a) when a cost savings can be achieved by the simple conversion of a manual method to a computer processed equivalent, and b) when the quantity of data and ore reserve estimation purpose justifies adoption of a complex ore reserve computational method not feasible on a manual basis. Ore reserve computations essentially consist of using sample data and a mathematical method to arrive at an estimated geometry, tonnage, and grade for a mineral deposit. The mineral deposit is then subdivided, if necessary, into ore and waste components. This separation is based on economic factors which may be explicitly introduced in the computation or incorporated in a numerical cutoff grade4. Computer methods for accomplishing these tasks are presented in three papers. "The Use of Contour Surfaces as Predictive Models for Ore Values" discusses the requirements for a satisfactory value prediction model and the importance of considering auto -covariance. A weighted moving average method is described and compared to other mathematical surface development methods. In the second paper, "The Applications and Limitations of Computer Techniques in the Evaluation of Hypothermal Tin Lodes," particular problems encountered in estimating geometrically erratic economic deposits with a low valuable mineral content are documented. Economics and probabilistic concepts are introduced, allowing a comparison of risk and speculative value for a deposit. Economic considerations are integrated with ore estimation techniques in the third paper, "Method of Calculation of the Iron Ore Reserves in the Lorraine Deposit." The prediction model

Jan 1, 1969

By H. Ramazi, A. Amini

"This article is devoted to the introduction of a new technique of electrical resistivity data processing called residual resistivity (RR). We define RR as measured resistivity minus background resistivity. To determine the background resistivity, the data acquired from electrical resistivity measurements along a given survey line is evaluated, and then an equation is fitted to the data corresponding to a chosen measurement station as a function of current electrode spacing (or array length). The RR technique was applied to several synthetic models to compare the conventional resistivity inversion of each model with its RR-based inversion. A case study was carried out in a karstic area in Zarrinabad, Lorestan Province, western Iran, to detect the location and geometry of probable cavities by conventional resistivity inversion and RR-based inversion. The results showed that the anomalous zones are better highlighted in the RR-based inversion images in comparison with the conventional inversion images. In some cases, anomalies detected by the RR-based images were hidden in the conventional method. IntroductionThe geoelectrical resistivity method has been widely used since the early 20th century, and plays an important role in several fields such as groundwater and subsurface mineral exploration, geotechnical and environmental investigations, and archeological studies (Bayrak and Senel, 2012; Candansayar and Basokur, 2001; Fehdi et al., 2011; Hee et al., 2010; Osella et al., 2003; Wilkinson et al., 2010). The goal of geoelectrical resistivity surveys is to determine the distribution of subsurface resistivity by measuring the current-potential difference on the ground surface (Aizebeokhai et al., 2010). In the electrical resistivity method, an electrical current is injected into the ground by two electrodes, called current electrodes (AB), and the potential difference is measured between another pair of electrodes, the potential electrodes (MN). Several methods of interpretation are available for application to electrical resistivity data, the simplest being the graphical interpretation of the apparent electrical resistivity pseudo-sections along each survey line. A second method, electrical resistivity inversion, has been developed to create relatively accurate two- and threedimensional computational resistivity models of subsurface sections (Loke and Barker, 1996; Niwas and Mehrotra, 1997; Nordiana et al., 2014; Oldenburg and Li, 1994; Papadopoulos et al., 2009; Yilmaz and Narman, 2014). In the inversion method, models of subsurface objectives are mathematically inverted to reach optimal solutions subject to prescribed objective functions, constrains, and convergence criteria. A common problem when using the electrical resistivity inversion method is that the inversion model of an electrical resistivity profile may be non-unique because different inhomogeneities in the investigation media can result in the same electrical response (Smith and Vozzof, 1984)."

Jan 1, 2016

By Qun Wang, Elena A. Alonso, Janusz S. Laskowski

Primary normal long-chain amines are insoluble in saturated brine. Their colloidal solubility (dispersion) in concentrated electrolyte solutions is strongly affected by the presence of surfactants (frothers). This paper shows that a better usage of alcohol type surfactants, which are commonly used in potash ore flotation as frothers, can significantly improve the flotation of both coarse and fine sylvite particles. A new process of potash ore flotation is developed, which includes premixing an effective frother with an aqueous solution of amine or emulsion of extender oil containing amine. With such a combination of flotation reagents, KC1 particles up to 5 mm in size float very well in the short flotation column, and particles up to 2 mm float in a mechanical cell; when used to treat fine fraction-containing sample, this method may as well provide an improved concentrate grade.

Jan 1, 1995

Pillars with width-to-height ratios of less than 1.0 are frequently created in underground hard rock mines. The strength of slender pillars can be estimated using empirically developed equations. However, the equations can provide variable results when the width-to-height ratios approach 0.5. This paper investigates some of the issues affecting pillar strength at low width-to-height ratios in hard brittle rock. The investigation includes an evaluation of empirical pillar strength data presented in the literature and observations of pillar performance in underground limestone mines in the eastern United States, supplemented by numerical modeling in which failure processes and sensitivity of slender pillars to variations in rock mass properties are evaluated. The results showed that the strength of slender pillars is more variable than that of wider pillars. The numerical model results demonstrated the increasing role of brittle rock failure in slender pillar strength. The absence of confinement in slender pillars can result in a fully brittle failure process, while wider pillars, fail in a combined brittle and shearing mode. The onset of spalling in slender pillars occurs at or near the ultimate strength, while this is not the case for wider pillars. Slender pillars are shown to be more sensitive to the presence of discontinuities than wider pillars, which can partly explain the increased variability of slender pillar strength. Two examples are presented that illustrate failure initiation by brittle spalling and the sensitivity of slender pillars to the presence of discontinuities.

By Paul Weir

DURING the past decade, methods of producing bituminous coal in the State of Illinois, which ranks third in production among the states in which bituminous coal is mined, have undergone great changes. From less than one million tons in 1923, the strip-mine production has gradually increased to a high of 11,725,870 tons in 1937. From a negligible amount prior to 1927, the amount of coal mechanically loaded underground had increased to a high of 28,374,362 tons in 1937. The amount manually loaded in 1937 reached a low of 12,332,023 tons. In this same year, this state ranked first in strip-mine production, also in mechanically loaded production. For this reason a study of the influence of mechanization on location of production in Illinois may be helpful in anticipating what may happen in other producing states. The reason for the changes in methods lies in the differences in costs of production. The Bureau of Research and Statistics of the National Bituminous Coal Commission has made public the following costs of pro-duction by various methods in the State of Illinois (district 10) for the last nine months of 1937: all mines, $1.7602 per ton; strip mines, $1.4319; mechanical loading mines, $1.7457; hand loading mines, $2.1793; all underground mines, $1.8703. These are weighted averages for the entire district. Inasmuch as production in 1937 was reported from 58 counties scattered over two-thirds of the area of the state and from five different seams varying in thickness from less than 3 ft. to as much as 12 ft., it is apparent that the location of production must be influenced by the extent of mechanization possible in the various producing counties.

Jan 1, 1939

By Frank W. Cramer

THE operator's panel is the control center f or the operation of the electric-arc furnace. It contains the switches and meters that control and indicate the power supply and in a way gives a picture of what is going on during the meltdown and refining periods. Regardless of manufacture, these panels are very similar with respect to equipment and position of apparatus. A typical panel is shown in Fig I. The three lights at the top of the panel are connected from the electrodes to ground and give a visual measure of the voltage across each arc. The ammeters underneath the lights show the current passing through each electrode. Directly underneath are the voltmeter, the watt-hour meter and the wattmeter and under these the three current-adjusting rheostats. In the center of the panel is the master electrode-control switch, which controls the movement of all three electrodes, with the individual electrode-control switches directly underneath. Next from left to right is the six-position voltmeter switch, which can be positioned to show on the voltmeter above the voltage between phases and to ground, the tap-changer switch with its indicating lights, and the main circuit-breaker control switch.

Jan 1, 1947

By Marion Rice

THE copper-mining district of Jerome, Ariz., is of such economic importance that the following brief notes may be of interest. The ore deposits are said by Ransome1 to be pre-Cambrian, and are contained in the pre-Cambrian schists of the region. In the vicinity of the mine (the United Verde) the schist stands nearly vertical .and strikes a little west of north. At least three varieties are distinguishable-(1) a green rock, schistose, on its margins but grading into massive material, which is evidently an altered dioritic intrusive; (2) a rough gray schist with abundant pheno-crysts of quartz, apparently an altered rhyolite; and (3) a satiny, greenish gray, very fissile sericitic schist that may be a metamorphosed sediment. The ore occurs in varieties (2) and (3), the main belt of dioritic rock (1) lying just west of the orebodies. The ore is said to follow as a rule the layers of fine sericitic schist. T. A. Rickard2 says that the ore at the United. Verde Extension mine is found at the contact of diorite and schist, that both diorite and ore are earlier than the regional metamorphism, and that the quartz porphyry (" rhyolite" of Ransome) is of post-Cambrian age.

Jan 9, 1918

By G. M. Ritcey, A. W. Ashbrook, E. G. Joe

Solvent-in-pulp extraction of uranium from acid leach slurries of flotation concentrates is described. Solvent extraction was carried out in a 10 in. diam pulsed-plate column. The extractant was a 0.1 M tertiary amine (General Mills Alamine 336) in a kerosene diluent containing isodecanol as an emulsion suppressor and third phase inhibitor. In pilot plant operation at the Beaverlodge mill of Eldorado Mining and Refining, Ltd., slurry feeds containing up to 35% solids were processed at a throughput rate of 13.5 tpd of dry feed. Uranium extraction obtained was as high as 98%. Amine losses to the raffinate were approximately 0.07 lb amine per ton of original dry feed. The Beaverlodge Mill of Eldorado Mining and Refining employs a carbonate leach for the extraction of uranium from the ore.',' Prior to carbonate leaching sulphides are removed by flotation to reduce reagent consumption. This flotation concentrate containing some uranium is then leached with sulfuric acid, filtered, and the uranium precipitated with magnesium hydroxide. The precipitate is then returned to the carbonate leach circuit. Although the tonnage of flotation concentrate treated by acid leaching is low, reagent costs are relatively high. Also maintenance costs on the acid leach filtration circuit were beginning to show significant increases. The choice of solvent extraction-in-pulp as an alternative to the present circuit was influenced by the following factors: 1) elimination of acid pulp filtration, 2) increase in overall recovery because of soluble loss elimination, 3) reduction of reagent cost (mill sodium carbonate solutions are used as strip), and 4) production of higher purity precipitate at the mill site. Because a solvent-in-pulp process would be difficult to test on a bench-scale, the Eldorado experience in the use of pulse columns,3-5 mixer-settlers,6 and solvent-in-pulp operations in particular7 was applied directly to the initial pilot plant carried out during the summer of 1965 and followed by the second pilot plant in 1966. The latter work, which is presented in this paper, determined the following factors for anticipated scale-up to plant production: 1) overall uranium recovery by this process, 2) tonnage throughput expected, and 3) solvent losses anticipated for the full-scale plant. The equipment used consisted of a 10 in. diam extraction pulse column and three mixer-settlers for scrubbing, stripping, and acid equilibration. All equipment was designed by Eldorado and much of the pilot plant was built at the mill site. PROCESS CHEMISTRY Feed to the acid leach plant consists of a sulphide flotation1,2 concentrate containing mainly pyrite, uranium and graphite, with a particle size of 90%

Jan 1, 1968