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By David P. Shoemaker, Clara B. Shoemaker

It has been shown for an important class of complex transition intermetallic compounds (a, P, R, 6, and p phases) characterized by "normal" coordination [CN12 (icosahedral), CN14, CN15, CN16/ that interatomic distances nay be calculated to a good approximation as the sum of characteristic atomic radii. Two radii, one for major ligands and one for minor ligmds, are specified for each atom, except in the case of CN12 where only a miaaor-ligand radius is specified. The same appears to be true of transition-metal phases of simpler struc-ture: Laves phases (CN12, CN16), and p-tungsten phases (CN12, CN14). In the case of known examples of the more complex phases, a simple rule is given which specifies these radii. However, only a fraction of the known examples of the simpler phases obey this rule closely. To include the latter phases the rule may be modified by considering the radii as linear functions of the weighted average of the Pauling CN12 radii of the two kinds of atonzs, with the radii weighted according to the over-all chemical composition of the alloy. With very few exceptions interatomic distances for both tlze complex and the simpler transition phases can b$ predicted with this modified rule to within 0.06A. ManY intermetallic compounds are known of composition A,By, in which A is a transition element to the left of the manganese column in the periodic table and B is a transition element in or to the right of it. Frequently the coordination numbers (CN) found in these compounds are CN12 (icosahedral), CN14, CN15, and CN16 (called "normal" coordinations by Frank and Kasperl). Well-known examples are the cubic and hexagonal Laves phases which have CN12 and CN16, and the 0-tungsten (CrsO) phases which have CN12 and CN14. In the more complicated (often ternary) phases, such as the a phase,2 the Beck phases p3 and R~, the 6 phase,5 and the p p atoms occur with CN12, CN14, CN15, and (except for a) CN16; in many cases several crystallographically independent atoms of one particular CN occur in the asymmetric unit. A large number of independent interatomic distances are found in these complicated phases, varying from 20 in the a phase to 94 in the 6 phase. These distances show a large spread; they vary, for example, from 2.358 to 3.278A in the 6 phase. In our analysis of these distances we found that in each of these compounds every atomic position can be characterized by either one or two radii. The CN12 positions are characterized by a single radius, The higher coordinated positions are characterized by two radii, namely: the CN14 positions by 4 in the direction of the twelve "5-coordinated" ligands3 (called 'minor" by Frank and Kasperl) and by r:, in the direction of the two "6-coordi-nated" ligands (called "major" by Frank and Kasper); the CN15 positions by r15 for the twelve minor and r:, for the three major ligands; the CN16 positions by rlE for the twelve minor and r:, for the four major ligands. We have expressed the experimentally determined interatomic distances in observational equations as the sums of the appropriate pairs of these characteristic radii and the value of these radii have been determined by the method of least Squares. Despite their wide range, the interatomic distances could then be predicted by the sums of these atomic radii with an average deviation in any one compound of 0.06A or less. The results are summarized in Table I. Inspection of the radii thus obtained shows that in the structures in Table I the radii (in A) are given to a first approximation by the simple relationship: Where CN is the coordination number (12, 14, 15, or 16), and A = 1 for major ligands and = 0 for minor ligands. The interaLomic distances can be predicted within about 0.1A by sums of these atomic radii. Another phase belonging in this group with CN12, 14, 15, and 16 is the y phase & B7, in which A is molybdenum or tungsten and B is iron or cobalt. Recently the M%C phase has been refinedE and the observed distances also agree well with those calculated with Eq. [I]. (In the original determination of the structure of W6FeV7 the F$(II)-W(II1) distance was erroneously given as 2.84A, but we have recalculated it fro? the published parameters and found it to b? 2.57i4, in good agreement with the value of 2.6A predicted with Eq. [I.].) Many binary transition alloys are known to crystallize with the simpler structures having "nor-

Jan 1, 1964

By Ross Dimmock

The productivity of a mine has the same goals as the quest to complete a tunnel project both safely and within time. A key aspect to achieving this goal is to excavate and support the working face as quickly as possible, allowing early re-entry to start construction of the next advance in safety. As with tunnels, the use of high performance wet-mix sprayed concrete has increased in mines dramatically over the last few years, and year on year has seen a stepwise increase in shotcrete performance, particularly in the first few hours. Shotcrete early age strength development clearly offers mining teams enormous advantages by allowing early, safe re-entry to the face. This paper illustrates that in the hard rock tunnelling field, modern shotcrete approaches do not cause delays in re-entry, but allow a continuous construction cycle. Furthermore, the paper identifies the most suitable, up-to-date shotcrete admixture and equipment technology available to the mining community to permit early re-entry.

May 1, 2003

By Gilbert H. Cady

HE application of geology to problems arising A in coal mining engineering and coal preparation has, in general, been somewhat remote, or the geological problems have involved such simple forms of geological knowledge that the attention of specialists in this field has not been commonly thought necessary. Furthermore, the geology of coal beds and coal mining has received but scant attention in our educational system, even in mining education; so that coal mining engineers have become somewhat conditioned against geological thinking. Geologists, on the other hand, have commonly failed to realize that there are geological aspects to coal mining and coal preparation problems. A further reason why geology receives so little consideration in coal mining undertakings in this country lies in the fact that our coal supplies are, or have been thought to be, almost unlimited, have been easily accessible, and very cheaply mined. Conditions have been changing within recent years. Failures can be less easily endured. Great inroads have been made on our bonanza deposits of easily mined coal and the increasing cost of coal and the increasing difficulty of finding it in easily accessible and large quantities places greater and greater importance on accurate information and good technique in exploration. It seems probable, therefore, that the opinions and aid of geologists will be more commonly sought than in the past in the exploration for coal and in the development and operation of coal mines, and analyses of mining conditions, preparation, and utilization.

Jan 1, 1951

By Gilbert H. Cady

HE application of geology to problems arising A in coal mining engineering and coal preparation has, in general, been somewhat remote, or the geological problems have involved such simple forms of geological knowledge that the attention of specialists in this field has not been commonly thought necessary. Furthermore, the geology of coal beds and coal mining has received but scant attention in our educational system, even in mining education; so that coal mining engineers have become somewhat conditioned against geological thinking. Geologists, on the other hand, have commonly failed to realize that there are geological aspects to coal mining and coal preparation problems. A further reason why geology receives so little consideration in coal mining undertakings in this country lies in the fact that our coal supplies are, or have been thought to be, almost unlimited, have been easily accessible, and very cheaply mined. Conditions have been changing within recent years. Failures can be less easily endured. Great inroads have been made on our bonanza deposits of easily mined coal and the increasing cost of coal and the increasing difficulty of finding it in easily accessible and large quantities places greater and greater importance on accurate information and good technique in exploration. It seems probable, therefore, that the opinions and aid of geologists will be more commonly sought than in the past in the exploration for coal and in the development and operation of coal mines, and analyses of mining conditions, preparation, and utilization.

Jan 1, 1951

It is perhaps somewhat unusual for a contributor to comment on the authors' reply to his critique. However, I should like to return to a specific comment made by the authors. Award to Bob Laburn The Federation of Societies of Professional Engineers (FSPE) is pleased to announce that the 1984 FSPE Award for Services to the Engineering Profession was presented to Dr R. J. (Bob) Laburn at a function held on 14th February, 1984.

Jan 1, 1984

By David Muir, Slobodanka Vukcevic

Gold is commonly associated with copper minerals, particu­larly in the more geologically recent rocks of Northern Australia, Chile and the Pacific Rim. Traditionally, oxidised copper-gold ores are selectively mined and processed for gold by cyanidation, ensuring that levels of reactive copper in the ore are kept low to minimise cyanide consumption; whilst sulphide copper-gold ores are floated and gold is ultimately recovered as the by-product from copper smelting and refining (La Brooy, 1992). Very few process­ing options exist for treating copper ores which cannot be selec­tively mined or floated, and for treating floation tailings which often contain significant gold (Muir et.al.,1989). The ammonia-cyanide leach system stands out as a unique method of selectively extracting gold without copper using economic levels of cyanide (1-2 kg/t NaCN) and ammonia (1-5 kg/t). Although first patented in 1904, it proved difficult to control and predict per formance with different ores. However, recent research and development in Western Australia by Ruane (1991), Hayes and Corrans (1992), La Brooy et.al.(1991), Muir et.al.(1993), Muir and La Brooy (1993), has led to an under­standing of the mechanism, and the commercialisation of the process at the Paris Dump (W.A.), Akjoujt (Mauritania), and in the Eastern Transvaal (Laxen,1994). Efforts are now underway to pilot and develop a tailings treatment plant at Telfer following successful laboratory trials. To date, process optimisation has relied on trial and error and large numbers of tests covering a range of conditions. Thus the results are specific to the ore. At Murdoch University, process optimisation is now focused on measuring and control­ ling Eh, pH, NH3 [Cu(II)], and Cu-CN species at the optimum levels identified from the recent mechanistic studies. In this way, the optimum composition required to process any ore should be readily established and maintained.

Jan 1, 1995

By H. E. Mussey

WHEN the American Institute of Mining Engineers visited the Birmingham district in May, 1888, the four Ensley furnaces (Fig. 1) then FIG. 1.-BLAST-FURNACE DEVELOPMENT IN ALABAMA. completed were referred to as monumental.1 Their dimensions are given in Table 1. Mr. Gordon stated, with considerable satisfaction, that on the preceding day one furnace had produced 165 tons. The blast was

Jan 10, 1924

A case-study is presented of the tailings dam of Nairne Pyrites Pty. Ltd., at Brukunga, South Australia. The methods of-construction and operation of the dam are outlined over the whole working life of the mine. Procedures of soil mechanics used to estimate the stability 'of the face of the dam are described, and seepage problems are dis- cussed. It is concluded that the dam is basically stable, and enabled Nairne Pyrites Pty. Ltd. to dispose of tailings economically, although more attention to seepage control may have been ad- vantageous. Suggestions are made on the construction and operation of tailings dams elsewhere.

Jan 1, 1975

By Donald Barton

THE theory of gravitation is based on Newton's law that any two bodies exert a mutual attraction which is proportional to the product of their masses and inversely proportional to the square of the distance between them; i. e. A= K MM/R2 (1) where K is a constant, M and m are the respective masses of the two bodies, and R the distance between them. In the earth's gravitational system, the earth is one of the bodies; the other may be any body within or without the earth. In theoretical discussions and calculations in regard to gravity, that other body usually is taken as a unit of mass: in the C. G. S. system, a body of one gram in mass.

Jan 1, 1928

By Eric Brandner

Expansive soil formations can be found throughout the United States. When subjected to wetting, many of these formations have the potential to swell and exert large uplift forces which can significantly damage lightly-loaded structures. Designing an economical foundation that can resist uplift forces is critical to prevent damage to these structures. The current solutions to control uplift due to swelling soils, such as over-excavation and replacement of the expansive material, or drilled shafts, can be costly and problematic. Piles made from recycled polymer materials may provide a solution. Due to a lower coefficient of friction along the interface than piles made from traditional materials, solid recycled plastic piles can allow expansive soils to move nearly independently from the pile when wetted. This results in a much smaller magnitude of uplift force being transferred to the structure which minimizes the risk of significant structural damage. This paper presents the preliminary results of research conducted on the use of recycled plastic piles in an expansive shale environment. The preliminary phase of the project involved the installation of six 13 in. (330 mm) diameter recycled plastic piles at a test site on the South Dakota School of Mines and Technology campus. The piles varied in length from 15 ft. to 25 ft. (4.6m to 7.6 m). Two of the piles were subjected to a full-scale compression load test in order to determine ultimate capacity, while the additional four piles are being subjected to long-term monitoring of uplift movement. A cast-in-place concrete pile, with a diameter of 6 in. (152 mm) and length of 15 ft. (4.6 m), was also installed at the test site for monitoring. The preliminary results indicate that the use of solid recycled plastic piles is a viable alternative for support of lightly-loaded structures in expansive soil environments.

Jan 1, 2009

By W. E. Anderson

As part of a larger study to identify factors influencing the practical operating life of wire rope used on large draglines in surface coal mining, field trips to operating surface coal mines were made during late 1975. Wire rope performance information was obtained from personnel at thirteen mine sites west of the Appalachians. Seventeen pieces of equipment, utilizing buckets ranging from 30-to 220-cubic-yard capacity, were documented. We have judged that U.S. surface coal mining draglines, 30 yards and larger, can be represented as 120 machines having 60-cubic-yard buckets, moving 1.8 x 10 yards of overburden during 6,650 hours of productive availability per year. Based on our limited field study, we have calculated that downtime resulting from rope-related causes averages 105.6 hours per year for each (typical 60-yard) dragline. The total lost production from this source alone is thereby estimated at about 25 x 10 yards annually. Although study findings did not reveal anything about dragline rope life that wasn't known or practiced by one operator or another, most operators could expect improved rope life by periodic review of their practices and by adopting or adapting one or more life-improvement measures employed at other sites. Since rope productivity was found to vary by about five to one, among the sites studied, we believe considerably improved average performance is possible. As little as ten percent overall improvement would mean increased national productivity exceeding two million yards of solid overburden removal, and associated savings in rope costs alone of some two million dollars annually, not to mention any reduction of labor-related expenses. This report outlines preliminary findings which may prove useful to many operators in extending wire rope life, thereby lowering expenses and increasing surface coal mining productivity. Some of these modifications or adjustments in maintenance/operating practices would not require capital investment. We did not find anyone who had tried cost reductions by using presocketed dump

Jan 1, 1977

By Brown GA

Results are presented which demonstrate the feasibility of employing electrolytic membrane technology to process leach liquors derived from alkaline pressure leaching of scheelite concentrates and to recover and recyle sodium carbonate. Thus the problem of disposal of sodium sulphate is avoided. In a further application of the technique sodium tungstate is converted to tungstic acid which can be further processed by three possible routes to crystalline or amorphous tungstic acid or tungsten powder. In each route sodium hydroxide is produced which on carbonation can be recycled as soda ash to the pressure leach stage. Further testwork is required to determine long term operational conditions in the membrane cell and to confirm the effect and deportment of impurities on products. The process has been patented.

Jan 1, 1986

The range of environments which control the level of ground support required vary greatly in terms of rock type, rock structure and the mining method used. At the operating mines visited during this review the level of ground support was such that incidence of rock-fall- related accidents were rare. It was also found that methods existed to support most of the conditions encountered. The main problem areas were weak rock, major geological structures, areas of heavy jointing, high development density and areas affected by high mining-induced stresses and blasting. With stope support the level of success was much lower than that achieved in development; the larger spans and more rapid changes in geometry of open stopes compared with cut and fill stoping (where cables were originally used) led to significant problems. Before a useable design method for cable support of stope walls and pillars can be obtained the precise failure mode of the walls and pillars, and the interaction of the support and the rock mass must be investigated.

Jan 1, 1982

By Michel Chouteau

"A very conductive zone was revealed in 1977 and 1978 by magnetotelluric (MT) measurements carried out near Ste-Mathilde, 6 km northeast of La Malbaie . In order to identify the structure causing the anomaly, thirty-five MT soundings were recorded in 1980 and 1981 on and around the conductor within a radius of4 km. Results confirmed that the conductor is of limited extent (less than 2 km by 0.4 km). The proposed model is a highly conductive vertical slab, the top of which is within 200 m from the surface. At a depth of approximately 825 m this structure joins a conductive layer which extends to the northwest but not to the southeast. The large conductivities and the depths involved can only be explain ed by a fractured zone flooded with electrolytic solutions, by graphite veins or by metallic mineralization (sulphides). The former seems to be the most likely hypothesis because an EW fault running across this zone could have allowed percolation of water and the leaching of disseminated pyrite out of a mylolisthenite filling the fault.IntroductionLa Malbaie is located 130 km northeast of Quebec City on th e North Shore o f the St. Lawrence River (Fig. I). Four major groups o f rocks have been mapped in this area: charnockitic rocks to the west , granitic rocks in the north east and southeast, gneiss and pegmatites northwest and south of La Malbaie , and Paleozoic sediments in the Clermont-La Malbaie Valley and along the shore of the St. Lawrence River (Rondot, 1966). Two major features dominate the structure of the region: Logan ' s line , a major thrust fault beneath the St. Lawrence which separates the Grenville Province to the north from the Appalachian regime to the south, and the Charlevoix Crater , a large Paleozoic impact crater that created an almost perfect annula r structure centred on Mont des Eboulements (Rondot, 1970). Ste-Mathilde is a village lying 6 km northeast of La Malbaie, just outside the ring-like graben zone caused by readjustments after meteorite impact. The survey area spreads over a granite body which is more than 2 km long and 0.6 km wide, surrounded by a wide migmatite zone which is injected by many bodies of pegmatite, the latter likely related to the granite body (Fig. 2). A zone of leptynites lies west of the area. An east-west trending fault (FA1) related to the Charlevoix Crater runs mid -way across the survey area; a second parallel fault (FA2) south of FAI separates the gneissic rocks from the Paleozoic sediments. The overburden is usually thin with outcrops frequently encountered except for the centre of the survey are a where 10 m of glacial sediments are expected (E. Gaucher, 1982, personal communication)."

Jan 1, 1985

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract S0122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine.

Jan 1, 1974

By W. C. McClain

In the design of underground excavations, rock mechanics considerations are nearly always based on an elastic behavior of rock. Most rocks do exhibit a certain amount of elasticity, and the application of principles and concepts of elasticity to rock mechanics problems has been largely responsible for progress in the field over the past 10 or 15 years. NO doubt the theory of elasticity will remain the most useful analytical tool available for both the design of underground openings and the interpretation of phenomenological data. Dr. Cook's analysis of rock behavior based on energy considerations represents a significant new approach to mining rock mechanics problems. Although the foundations of this analysis are somewhat broader and more general than elastic analysis, the development and applications are grounded almost entirely in the theory of elasticity. It has long been known1,2 that all rocks, even granites and dense limestones, exhibit nonlinear time-dependent strain properties to a greater or lesser degree. Creep strain (that is, deformation under constant stress) in salt, potash, and trona can be several orders of magnitude greater than instantaneous elastic strain. Design of underground workings in these materials must incorporate provisions for these strains and must therefore go considerably beyond elastic analysis. Some of the principles of underground design in highly plastic materials will be discussed in this paper. Since all rocks, especially when highly fractured, exhibit a certain amount of creep-type strain, these concepts should be at least recognized in any rock mechanics problem. The discussion will be illustrated largely, but not entirely, by examples drawn from

Jan 1, 1967

By C. -T. Mutale, A. S. Tuling

Titanium can exist in three different oxidation states. Its oxides are numerous and in presence of iron and oxygen, iron-titanium oxide compounds can also form. Some of the oxides are non-stoichiometric, making the determination of the thermodynamic properties of titanium and its oxides in molten steel and in slag difficult. Therefore, for the assessment of titanium activity in molten steel using the electrochemical measurements of oxygen partial pressure, the identification of oxides in equilibrium with titanium is important. This paper reports on an investigation of solid titanium oxide inclusions, which have been identified by combining different methods of analysis on quenched samples. These samples were taken from a Fe-Ti-melt at 1600°C, quenched in cold water then mounted and polished for optical microscopy. The oxide inclusions were analysed using transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS). Both single crystal and polycrystalline diffraction patterns were used to identify the oxides by comparing the d spacings with those in the ICDD X-Ray Diffraction (XRD) database. XRD was used to analyse the oxide particles on the top of slow cooled samples. It was found in the TEM study that the similarity of the diffraction patterns of the various phases meant that unique identification was difficult to achieve in some of the diffraction patterns. However, TiO, Ti2O3, Ti3O5, Ti4O7were identified in quenched samples, while TiO2, FeO.TiO2and iron oxides were seen in slow cooled samples. It was also confirmed that the type of oxides is related to titanium content of the samples. Keywords: Titanium, Titanium Oxides, Iron, TEM, XRD, thermodynamic.

Jan 1, 2004

By R. E. Smallman, J. C. Terry

J. C. Terry and R. E. Smallman (Llniuersity of Birmingham, England)—In a recent publication53 Wood and Westbrook have reported the results of an investigation of the tensile behavior of fl-phase AgMg alloys. These results agree in broad outline, but differ in the details, with those obtained in the above laboratory and, consequently, some discussion of their paper would seem appropriate. In our experiments, tests were carried out on extruded wires, 2 mm diam, in a hard-beam tensile machine, and while an oil bath was used for the tests up to 150°C, above this temperature the oil bath gave rise to serious contamination of the specimens and hence tests above 150°C were made in vacuo. This procedure is different to that adopted by Wood and Westbrook. The ß-phase alloys exhibit differences in mechanical behavior when they are tested in different temperature ranges. In agreement with Wood and Westbrook, three characteristic ranges are observed which may be classified as low, intermediate, and high temperatures, respectively. Our experiments show that in the low-temperature region, the shape of the stress-strain curves is similar to that reported. However, in addition, it is observed that the temperature at which the low-temperature region ends is markedly dependent on strain rate, and increase with increasing strain rate as shown in Fig. 18. The temperature at which a transition from the low to the intermediate temperature takes place is about 0.4 to 0.45 of the absolute melting point, Tm. This transition temperature coincides with that at

Jan 1, 1963

By F. H. Newell

Measurements of the amount of water flowing in many of the larger rivers of the west have been made by the United States Geological Survey, and by this means the daily discharges of these rivers have been computed for a period of over two years. These measurements have been confined mainly to that part of the country commonly known as the arid region, where the rainfall is insufficient for the needs of plants most useful to man, and the supply of water, not only for agriculture, but also for mining and all other purposes, falls below the demands made upon it. In such localities flowing water has a great value, for without it many industries are impossible. Experience has shown that in the western part of the United States, over an area a little less than two-fifths of the whole extent of the country, there are great bodies of fertile land enjoying a genial climate, and in every way adapted to the support of a large population, except in the one particular of water-supply. By utilizing the water available, portions of this rich land can be rendered valnable. In other words, the laud-values rest directly upon the prospects of a continuous artificial water-supply. The same is true of many mineral lands, which require for hydraulic mining, or for the supply of concentrating-works, stanip-mills, etc., a certain water-supply, and are impaired in value if this supply is inadequate or irregular. The pressure of this need upon the mining industry is not so widespread, or in the first instance so severe as upon agriculture; but as different regions become more thickly settled, and the two industries compete for a water-supply not sufficient for both, it, is probable that the miner will suffer. But he can snspend operations with less inconvenience than the farmer. Agricuitural land, if the watersupply is not continuous, becomes a desert; on the other hand, the profit of mining is greatly enhanced by the presence of agricultural

Jan 1, 1892

By G. A. Wancheck

Shear tests were performed on several prepared samples of granular and powdery bulk materials to investigate the following parameters: Particle size and distribution, particle movement, moisture content, consolidation of material, bulk density, void ratio, porosity, volume change, and strain rate. A series of shear tests was performed with weight-percent-ratios of minus 0.185-inch tertiary sand and 1-1/2-by l/2-inch tertiary gravel mixtures, and weight-percent-ratios of minus 200-mesh limestone (rock dust) and minus 200-mesh bituminous float coal dust. A comparison was made for shear test results obtained with rectangular and circular shear cells utilizing the large and small direct shear testers. Specifically, the shear results obtained include the angle of internal friction or shear strength of the tested material under known consolidating pressures, and the kinematic angle of friction or coefficient of friction between the interface of a bulk material and a sample wall material. The experimental procedure, tests, and results are given for each parameter investigated.

Jan 1, 1973