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By Mingju Liu

China has been suffering from coal and gas outbursts since 1950s. Nowadays, the situation has become worse than ever with the need to mine deeper coal deposits at higher production rates in a more complex underground mining environment. In the year 2006 alone, 37 outbursts occurred in underground coal mines with a death toll of 232. This paper describes a case study of an outburst event, which occurred in July 2006 during the shaft development of the Mengjin Coal Mine, Henan Province, China at a depth of 768m below surface. Detailed analysis of the possible causes that led to the occurrence of the outburst is reported. These include the study of complex geological features, gas storage conditions, possible improper technical management practice as well as incomplete prevention and control measures. Based on the case study and the observation of outburst occurrence in China in the year 2007, suggestions have been put forward to help prevent and control future coal and gas outbursts.

Jan 1, 2007

By N. Magdalinovic

Generally speaking, erosion, as a process which entails degradation of surface layers of earth under the influence of the mechanical energy of surface waters, and from the point of view of biosphere sustainability, is a harmful process. This is absolutely true when agricultural and forest areas are concerned. However, if erosion is viewed selectively, this general definition about its harm raises serious questions. In other words, the erosion which takes place in the terrains where there is no vegetation because of the geological composition of the soil, does no harm. On the contrary, if the mineralogical composition of such terrains is characterized by a presence of precious and rare metals, erosion can be very useful. It contributes to the creation of new alluvial deposits of these metals in the waters in the plain land. It is here that torrents from hills come down and cause erosion. And finally, if there were no erosion, there would be no renewable deposits of gravel and sand.

Jan 1, 2007

By Anil K. Ray

Roof falls are one of the greatest hazards in underground coal mines worldwide. Due to stringent safety measures and extensive support system development, roof falls have been reduced significantly but they still persist in many underground coal mines. Some of the roof falls initiate with cutter roof or guttering. In the past, many factors have been identified as being responsible for the development of cutters and roof fall. These responsible factors can be broadly classified as stress related or non-stress related. In this paper the finer details of mining technique have been taken into consideration for better understanding of cutter roof and roof fall problems. Three dimensional finite difference modeling has been used to explain the mechanism of cutter development. Strain softening material behavior has been used to realistically simulate the cutter formation, and common cutting sequences as implemented in the field have been simulated. This was done with an objective to determine whether the cutting sequence has really any significant control over cutter formation or not. In addition to cutting sequences, the effect of cut length is also studied. The effect of step cutting and turning of crosscut into and away from major and minor horizontal stresses is also examined to see its influence on cutter development.

Jan 1, 2009

By Hsun Hu, R. S. Cline

The formation of annealing textures during the course of recrystallization in 2 pct Al-Fe crystals rolled in the (111) [112], (112) [111], and (112) [Till orientations has hem studied in detail. When the rolling texture is composed of both (111) [121] and (001)[110] components, the annealing texture consists of mainly (110) [001] and (113) [332] components. As the (001) [110] component diminishes from the surface to the interior of the rolled crystal, the relative concentration of the (113) [332] component in the annealing texture decreases accordingly, whereas that of the (110)[001] component increases with the (111)[112] component in the rolling texture. Such dependence of the annealing texture on the composition of the rolling texture is in accmdance with the oriented growth mechanism. Grain-growth characteristics during recrystallization, hence the annealing texture, can he considerablv different in (112) [111]-type crystals depending sensitively on the initial orientation of the crystal. In a previous publication,' the formation of rolling textures in 2 pct A1-Fe single crystals with initial orientations of approximately (1ll)[112], (112)[111], and (112)[111] was studied in detail. The deformation texture of these crystals consisted of either a single (111)[112] or a combination of (111)[112] and (001)[110] components in various concentrations. For the (lll)[112] crystal, the deformation texture was a single (lll)[112] up to 70 pct rolling reduction, but it became (lll)[112] plus (001)[110] after -90 pct reduction. For the (112)[113.]-type crystals, the relative concentration of the (111)[ 112] and (001)[110] components varied with the depth below the surface of the crystal, as well as with the amount of deformation. These series of specimens, having deformation textures with a range of concentration of the (111)[112] and (001)[110] components, could therefore be used for a thorough investigation of the effect of deformation-texture components on the formation of annealing textures. In a study of rolling and annealing textures in Si-Fe crystals, Dunn and Koh3 noted that the addition of a (001)[110] component to the (111)[112]-type deformation texture had practically no effect on the recrystallization texture.* According to the ori- ented growth mechanism for the formation of annealing textures, nuclei related to the deformation texture by approximately 30-deg rotation around a common [110] axis have the highest rate of growth and the resulting annealing textures generally have such an orientation relationship with respect to the deformation textures.314 It was reasoned by Dunn and Koh3 that if the oriented growth mechanism operated the recrystallization texture developed from a deformation texture containing both (111)[112] and (001)[110] components should be strongly centered around (113)[332], because (113)[332] is approximately midway between the (111)[112] and (001)[110], and is related to both of these two orientations by [110] rotations of 25 to 30 deg. Hence, nuclei of (113)[332] orientation should have a high rate of growth in the deformed matrix. However, their results were not in accord with this prediction. It was felt by the writers that a detailed study was needed to clarify the effect of deformation-texture components on annealing-texture formation. For this reason, the present investigation was conducted. EXPERIMENTAL PROCEDURE Specimens used for the present investigation were taken from the crystals rolled previously for deformation-texture studies.' In order to follow the progress of annealing-texture formation during the course of recrystallization, a single specimen was taken from each rolled crystal and its textural changes examined after successive anneals until recrystallization was complete. The specimen was carefully cut from the rolled strip with a jeweler's saw. Prior to annealing, the sawed edges were etched to remove distorted metal, while both faces of the specimen were protected from the etching solution by acid-proof plastic tape. After annealing, the specimen was etched from the "bottom" face only (the reference or "top" face of the specimen was protected by plastic tape) to one half of its original thickness, so that the texture at the surface and at the central section of the strip could be determined by the reflection technique. The

Jan 1, 1965

By M. Rigaud, K. Sankaranarayanane, X. Zhou

The effect of varying fine alumina/ultra-fine alumina ratio on the Bingham to dilatancy transition in alumina based, self-flowing refractory castables has been studied in detail employing rheological tests and particle size distribution measurements. Analysis of flow resistance and torque viscosity values has shown that Bingham to dilatancy transition is strongly influenced by fine alumina/ultra-fine alumina ratio in the castable, as well as by the nature of ultra-fine alumina. The calculated values of rheological constants and the viscosity coefficient were found to increase at higher fine alumina/ultra-fine alumina ratios.

Jan 1, 2004

By K Heiskanen

Flotation is affected by several factors, part of which depends on the mineralogical characteristics of the ore and part on process variables. Sulfide Ni-Cu ores occur typically in mafic and ultramafic igneous rocks. Serpentine minerals are also common. As a consequence of metamorphosis, sulfides and secondary minerals may be finely disseminated in an altered ore matrix. The floatability of minerals depends also on process variables. Oxidation of sulfide particles, process iron and dissolved ions in process water affect the behaviour of sulfides. The effects of some essential factors on flotation of Ni-Cu ores are considered.

Jan 1, 2005

By J. D. Morgan

Introduction In 1986, the US economy passed the $4 trillion mark. However, the value of domestically processed materials of mineral origin fell slightly to $240 billion. The value of metals produced from US ores was unchanged at $5.6 billion, as was recycled scrap at $4 billion, while the value of industrial minerals rose slightly to $17.9 billion. Consumer demand strongly affects mining and the US economy is relatively saturated with longlived products. Moreover, in recent years there has been a steady increase in consumer, mortgage, and federal debt, inhibiting new purchases of goods. Motor vehicles and housing are major traditional markets for mineral materials. However, the 242 million US citizens already possess 170 million licensed motor vehicles and 92 million dwelling units. In 1986, domestic motor vehicle production fell 3%, to 11.3 million units, while new housing starts rose slightly to 1.8 million units. Nearly all mineral commodities move relatively freely in world trade. As detailed in Figs. 1 and 2, in the last three decades world production of major mineral materials has greatly increased. At present, substantial excess productive capacity exists not only in the US but also in many other countries. Consequently, the US mineral industry is encountering increasing competition from other sources, along with increasing competition from newer, engineered materials. For example, US production of plas¬tics has risen from 900 kt (1 million st) in 1950 to 22.7 Mt (25 million st) in 1986 - on a volume basis significantly greater than steel. Plastics, too, are mineral-based materials, some 7% of petrochemicals going to their manufacture. 1986 saw increased calls for protection. But President Reagan, in his 1987 State of the Union Message and Economic Report to the Congress, reaffirmed adherence to a policy of free and fair trade. However, he stressed the need for increased efforts to open foreign markets to US exports and to increase competitiveness of US industry US imports of mineral-based minerals in 1986 were valued at $40 billion and exports at $24 billion. Strategic minerals As detailed in Fig. 3, imports supplied a significant proportion of total US consumption of several important materials, including many classified as "strategic and critical." There were no changes in stockpile policy during the year. Congress debated the President's 1985 proposals to reduce stocks of World War II-type materials and to focus more on high technology materials needed for the cutting edge of future military material. But no final action resulted. However, Congressional concern about apartheid in South Africa did result in increasing pressure to limit imports of South African minerals. Meanwhile, the National Critical Materials Council in the Executive Office of the President intensified its efforts to be better able to advise the President. The Defense Production Act provides authority for priorities and allocations, supply expansions, voluntary agreements, and

Jan 5, 1987

By W. A. Longacre

IN the geophysical exploration program of the Cleveland-Cliffs Iron Co. on the Marquette Range of Northern Michigan, the vertical intensity magnetometer has been used to obtain magnetic anomaly maps of large areas. A network of magnetic base stations has been established and the relative vertical intensity at each station measured carefully with respect to a prime base. In the search for the relatively nonmagnetic soft red hematite ore, the magnetic exploration is indirect, involving the study of dikes, faults, contacts, and other structural features. It was found that the magnetometer, adjusted to a scale value of approximately 40 ? per scale division, was satisfactory for this type of exploration, although many magnetic anomalies were encountered that required the use of auxiliary magnets.

Jan 1, 1952

By J. R. Cobble

The Federal Bureau of Mines conducted static tests at 2,500° F on 39 refractory compositions, and dynamic tests at [2,825°35° F] on 31 commercial refractory brick specimens to determine their resistance to corrosion and erosion by a slag similar in composition to that used in producing insulating mineral wool. The static tests showed fireclay, low-alumina compositions (<70 percent A1203), zircon, zirconia, SiC, and clay-bonded graphite refractories to be unsuitable. Dynamic test results indicated that magnesia and chromia compositions were superior to high-alumina compositions (=70 percent A1203) as a furnace lining for melting mineral wool. Data from these tests indicated that magnesia and chromia compositions with low RO/R203 mole ratios were more resis tant to attack by mineral wool slags than ones with high RO/R203 mole ratios.

Jan 1, 1975

By R. H. Sprute

Underground accumulations of slimes in the Henderson mine are routed to two large collection pits where they are dewatered and consolidated by application of direct current. Densified material is then removed to ore cars by rubber-tired front-end loaders and transported out of the mine. This Bureau of Mines report describes the electrical dewatering installation and compares its efficiency of operation with that predicted from preliminary laboratory studies performed by the Bureau. Direct current from a 150-kw rectifier (applied for 44 hours at 400 amperes and 65 to 70 volts) converted slimes containing 25.3 percent solids to material ranging from 44 to 65 percent solids. Better results can be expected if the ramp and front sections of the pits are treated separately, using higher current density.

Jan 1, 1980

By V. R. Spironello

Operating variables affecting the efficiency of the basic oxygen furnace (BOF) and the level of contaminating elements in the steel product were investigated by the Bureau of Mines. Steel was made in a 400-lb-capacity BOF designed to rotate on its vertical axis to increase the area of hot metal surface subject to oxygen attack. Hot metal for the BOF was made by melting pig iron and scrap in an 18-inch (ID) cupola. The variables were BOF speed of rotation, rate of oxygen flow, number of jets and angle at which they were machined into the oxygen-lance tip, temperature of hot metal, reactivity of lime, and temperature of scrap for the BOF charge. Experiments were arranged according to a two-level fractional-factorial design. The effects of the seven variables were evaluated for 13 responses. The greatest ingot yield occurred while using the larger angle lance tip and jets. The most carbon burned per unit volume of oxygen resulted from rotating the BOF and using the smaller angle lance tip. The largest sulfur transfer to the slag occurred at the higher hot metal temperature levels and higher rate of oxygen flow.

Jan 1, 1970

The paper focuses on how rock bolts are loaded in different rock masses, as well as in pullout tests. Three analytical models for rock bolts are presented in brief, one for bolts in continuously deformed rock masses, one for bolts in blocky rock masses, and one for bolts in pullout tests. The bolt models are used to interpret measurement data for rock bolts from three sources and to help specify the modes of axial load in the rock bolts. It is found that in continuously deformed rock formations fully coupled rock bolts have only one axial stress peak. The position of the axial stress peak moves towards the far end of the bolts with increasing rock deformation. In blocky rock masses several axial stress peaks may appear in the rock bolt. The position of this kind of axial stress peak does not change during the entire loading process. For rock bolts in pullout tests, decoupling of the interface always occurs first at the loading point. The decoupling front moves towards the far end of the bolt with an increase in the applied pull load.

Jan 1, 2000

By D. R. Wardrop, G. Walton

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. A description is given of the approach that has been taken to the design of the 550 000 000 t superquarry with a planned life of 60 years that is proposed for development. The quarry has been designed to replicate a corrie and a sea loch and will include excavated slopes more than 570 m high. The main geological and physical controls on the layout and the choice of development method are outlined. The operation phasing is presented and the geotechnical constraints on slope design and the feasibility of alternative quarry limits are discussed. Environmental considerations have been dominant in planning and the quarry has been specifically designed for closure

Jul 1, 1996

By F. H. Kihlstedt

THE Larap iron deposits, 125 miles east of Manila, are the biggest high-grade iron deposits in the Philippines, and have in seven years produced nearly 4 million tons of 6o per cent ore. Magnetic surveying followed by churn and diamond drilling cheaply developed a score of million tons. The ore zone is a wedge of metamorphic rocks in fresh, Miocene sediments overlain by agglomerates, which seem to have filled a river valley eroded in the sediments. A mild overthrust of the competent agglomerates crumbled the shale in front. Solutions gradually turned it into more competent hornfels and deposited pyrite, then magnetite and pyrite in the pores. As the temperature rose large bodies of magnetite with some pyrite were deposited by replacement and in open cavities in tensional areas of overthrust shears. At still higher temperature magnetite and calcium-magnesium silicates formed other bodies in similar cavities, and finally the thrust zone was invaded by syenite porphyry, causing high-temperature alteration products. Possibly, as temperature abated, more high-grade ore was deposited. The complicated faulting indicates dynamic, chronological and spatial changes of mineralization rather than zoning in a static system. Noncommercial copper, molybdenum and some gold accompanied the iron mineralization. In the thirties the Philippines gained a justified reputation as a country of considerable mineral wealth. Traces of Chinese workings show that these earliest travelers and traders had in a small way exploited the latent gold resources in the Islands. The Spaniards continued this for centuries, but did not succeed in establishing any steady mining industry. Modern technology was required to get it started. The rapid development in the last decade before the war got its impetus from several financial factors, the return to sugar growers of previously collected taxes, the influx of Spanish capital during the civil war in [ ] Spain, the influx of Chinese capital when the Japanese started their "China incident," and others. Directly or indirectly much of this capital reached the mining industry; in particular, gold mining. Out of the turmoil of an exceptional mining boom emerged a sufficient number of good and well managed gold properties to send the production to a level above that of any single state in the United States at the time. Other ore deposits besides those of gold also received their share, and for a country without any heavy industries at

Jan 1, 1946

By C. Steve

ABSTRACT: In this paper, the stability evaluation and bifurcation criteria are presented for the Jinping arch dam structure. The bifurcation models in failure status of the arch dam are derived from the uniqueness of the controlling equation of dam behaviours, and the relative phenomena between positive definition of dam structural tangent stiffness and bifurcation are given in the paper. Then the structural collapse criteria for arch dam are discussed based on the energy mode. A stability criterion of dam based on the connection of yield zones is proposed according to the implementation of elasto-plastic FEM (finite element method) numerical analysis. In accordance with this judging method, nonlinear FEM analysis is used for Jinping arch dam. The failure process of the Jinping dam was simulated and yield zones were found under the overloading condition. Keywords: Stability evaluation, bifurcation, failure process, Jinping arch dam ZUSAMMENFASSUNG: In der Verliegenden Arbeit wird ein integrater geomechanisch Modellversuch fuer Jinping Bogenstaumauer Vorgesstellt. Die Bogenstaumauer liegt aut der komplizerten felsformationen. Der Zerstoerungsmechanismus, die Stabilitaetsfaktoren und die Interaktion zwischen der Bogenstaumauer und den Seiltichen. In der Vorliegenden Arbeit wird eine dreidimensionale finite element analyse fuer die seitlichen. Gestein sauflager mittels dem Bruchmodell Vorgestellt, da fuer Jiniping Bogenstaumauer angewandet wird. Ein Bruch mechanismus model einschliesslich der statistischen parameter der Gesteinfes tigkeit wird entauckeit. RÉSUMÉ: Das ce documènt a été faite une analyse d’elemt limité de trois dimensions dn fondement de construction de roche faisant appel au modéle de l’endommagemnet à fracture, analyse appliquée an fondement du bar ragevoute de Jinping. Ce documènt décrit le test de modéle géomecanique intégral pour le barrage-voûte de Jinping L’ampleur du modéle en question constitute l’une de plus importantes en China. Ils correspondent par faitement anx calculs des résultats.

Jan 1, 2003

By A. M. Cann, C. I. Godwin

"The Kemess porphyry copper-molybdenum deposit occurs in the Intermontane Belt of north-central British Columbia. The deposit is in andesitic to basaltic flows and tuffs which may be correlated with the Savage Mountain Formation of the Upper Triassic Takla Group. Most known chalcopyrite and molybdenite is associated closely with a 500-m-diameter zone of intense quartz-sericite-pyrite alteration. A zone of supergene enrichment, up to 30 m thick, underlies a leached capping about 20 m thick. The age of mineralization and the surrounding granodiorite and quartz monzonite pluton is Early Jurassic. K-Ar and Rb-Sr analyses indicate that the mineralization and alteration is slightly younger (l82±6 Ma) than the granitic intrusion (KAr: about 205±6 Ma; Rb-Sr: 190±4 Ma). The low 87Sr/J6Sr initial ratio for the granodiorite is typical of plutons in the Intermontane Belt.IntroductionKemess is a medium to small porphyry copper-molybdenum deposit with significant gold and silver values (Pilcher and McDougall, 1976). This paper describes the lithologies and alteration at this property; geochronology by Rb-Sr and K-Ar methods defines the ages of mineralization and surrounding plutons to be Early Jurassic.The property, located in the Thutade Lake area of northcentral British Columbia (NTS Map 94E; lat. 57°04&apos;N; long. 126°44&apos;W), is about 425 km northwest of Prince George (Fig. 1). Closest road access is 35 km southeast of Kemess. Final access must be by float plane or helicopter. The British Columbia Railway right of way passes 70 km to the southwest of theproperty.A prominent gossan zone at Kemess was staked in 1967 by Kennco Explorations (Western) Ltd. following detection of geochemical anomalies during stream sampling the previous year. During 1968, 1969and 1971, Kennco completed 232 m of X-ray diamond drilling, conducted geological mapping and carried out geochemical sampling of silts and soils (Stevenson, 1969; B.C. Ministry of Energy, Mines and Petroleum Resources, G.E .M., 1969 and 1971). Getty Mines Ltd. optioned Kemess in 1975and 1976. They remapped the area and diamond drilled 12 BQ and NQ holes, totalling 2065 m (B.C. Ministry of Energy, Mines and Petroleum Resources, Expl. B.C., 1975)."

Jan 1, 1980

By M. T. Simnad, G. Derge, Ling Yang

A method is described for using radioactive tracer for the direct determination of ionic mobility in a molten electrolyte. The ionic mobility of Fe" in silica-saturated iron silicate is found to be 0.0009 (*0.0002) cm2 sec &apos; volt L at 1250°C. eLECTROCHEMICAL studies&apos;, &apos; of molten iron eE oxide and iron silicates have shown some ionic conductivity at all compositions. The current efficiency in electrolysis increases with the concentration of silica to a maximum of 90 pct at about 34 pet SiO,. In the silica-saturated melts the transport number of ferrous ions is near unity, indicating that

Jan 1, 1957

By S. Zhou

Since the hypothesis of coal and methane outburst mechanism based on elastic mechanics gives no consideration to time, it can not give a satisfactory explanation to the outburst occurrence and its development. A creep mathematical model of coal containing gas has been set up through creep tests and analysis under the condition of tri-axial compression. And the model can explain the phenomena of coal and methane outburst successfully. The tests proved that there is no essential difference between the rheological properties of prone outburst coal and non-prone outburst coal. Outburst can take place in any kind of coal if the rheological conditions of coal containing gas are met. The creep mathematical model provides a basis for establishing a comprehensive index of coal and methane outburst possibility.

Jan 1, 1991

By J. J. Davis, C. A. J. Fletcher, M. Li, T. Jancar

This paper summarises the experimental approach to spiral modelling at the Julius Kruttschnitt Mineral Research Centre, University of Queensland, involving the use of plastic density tracers to determine partitioning performance on three models of coal spiral. This work has led to phenomenological models of the three spiral profiles most widely used in the Australian coal industry. The results from a parallel computational fluid dynamics approach to spiral modelling currently underway at the University of New South Wales are also presented. The computational simulation has been successfully applied to generic spiral geometries and is capable of predicting the fluid phase three dimensional flow fields and corresponding free surface profiles for moderate Reynolds&apos; number and Froude numbers. Simulation predictions are compared with experimental results from a Mineral Deposits LD9 coal spiral.

Jan 1, 1995

By Fred H. Poettmann

The vaporization characteristics of carbon dioxide in a League City natural gas - Billings crude oil system were studied at three temperatures, 38°. 120°, and 202°F and for pressures ranging from 600 to 8,500 psi. Variation of carbon dioxide concentration up to 12 mole per cent in the composite showed no effect on the equilibrium vaporization ratios (K values) of the hydrocarbon constituents or on the K value of carbon dioxide itself. It was shown that carbon dioxide is more soluble in crudes than in distillates which is contrary to the behavior of methane. A working chart of carbon dioxide K values is presented. INTRODUCTION The study of the equilibrium vaporization ratios of mixtures of paraffin hydrocarbons has been rather thorough.2,6,7,8,9 In the past few years considerable attention has been paid to the vaporization characteristics of the so-called noncondensable gases such as nitrogen, carbon dioxide, and hydrogen sulfide in mixtures of hydrocarbons. since they usually occur to some extent in most crude oils and natural gases.1,3,4,5 Knowledge of this behavior is useful to both the production and refining phases of the petroleum industry. This paper reports the equilibrium vaporization ratios (K&apos;s) of carbon dioxide in a mixture of League City natural gas and Billings crude oil, and compares them to those obtained in a natural gas-distillate system. The equilibrium vaporization ratios for the hydrocarbon components in this system had previously been studied by Roland.&apos; In addition to the determination of the K values for carbon dioxide, the K values for methane and ethane were also determined in order to observe what effect, if any, the presence of carbon dioxide had on these K values. The concentration of carbon dioxide was also varied in order to observe the effect of this variable on the carbon dioxide K values. EXPERIMENTAL PROCEDURE The apparatus used in this study cotlsisted of a stainless steel equilibrium cell of about 2 liters capacity. The cell was mounted on trunions permitting rocking in a thermostatically controlled oil bath. Two high pressure valves fitted with steel tubing were mounted on the top of the cell. one was used for sampling the equilibrium gas phase and the other for sampling the equilibrium liquid phase by means of an induction tube within the cell. Stainless steel tubing from the bottom of the cell led to a mercury reservoir and manifold which was connected to a free-piston type pressure gauge manufac- lured by the American Instrunlent Ctr. and to a volumetric. putrip. The temperature of the oil bath was measured by means of a ralibrated mercury-in-glass thermometer. The recorded temperatures are believed to be accurate to ±0.5 °F. The pressures are correct to 22 psi. The crude oil used in this study was stock tank oil obtained from the Wilcox formation in the Billings Field, Noble County. Okla. The natural gas was obtained from the League City Field. Galveston County, Tex. The oil was treated with anhydrous calcium sulfate in order to remove the last traces of water. To insure a supply of constant composition gas at room temperature the cylinders of League City gas were cooled to about 30°F, inverted, and the condensed liquid was allowed to drain from the cylinders. The analysis of the gas and crude are tabulated in Table I. The carbon dioxide came from Pure Carbonic, Inc., and was .stated to have a purity of 99.5 per cent or better. The procedure used to obtain samples of the equilibrium liquid and vapor was similar to that employed by others making use of the rocking type equilibrium cell.6,7,8 The equilibrium cell was evacuated and calculated quantities of carbon dioxide, natural gas, and crude oil were charged to the cell to the desired pressure. In charging the equilibrium cell an attempt was made to maintain the ratio of the natural gas to crude oil as close as possible to that employed by Roland. After the cell was charged, samples of

Jan 1, 1951