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By James L. Kelly

Stripping of the Twin Buttes copper deposit started in 1965. Total material removed for the first 10 yr of operation is approximately 879 million tons. The sulfide concentrator has treated about 45 million tons. The Twin Buttes mineral zone was concealed under several hundred feet of recent alluvium. Beneath this post-minera1 cover, Paleozoic limestone, siltstone and quartzite, and Mesozoic metaarqillite, arkose, conglomerate, and volcanic rocks are intruded by an igneous complex of quartz monzonite and diorite. All rock units are erratically mineralized, principally with copper and molybdenum. Strongest copper mineral favors the Paleozoic calc-silicated limestone and siltstone, often preferential to individual beds.

Jan 1, 1978

By M. M. Fine

This report presents the results of laboratory mineral-dressing investigations by the Bureau of Mines of 14 individual or composite character samples from deposits in the Batesville manganese district. It will be noted that some concentrates have met or approached analytical specifications for metallurgical manganese ore although great variations in both physical and chemical composition from once deposit to another make each a new problem. In most cases it is evident that a substantial loss of manganese has occurred in the various slime and tailing products. An important aspect of this work is the research being conducted on manganese-bearing limestones. Recent reconnaissance indicates that this resource constitutes one of the major domestic reserves of manganese. Laboratory study has shown that ferrograde concentrates can be recovered from samples of manganese-bearing limestones from two properties. Research on samples from other areas is still underway.

Jan 1, 1957

By John H. G. Monypenny

The range of chromium content of stainless steel is, in most cases, included in the limits 11 to 14 per cent., or the middle part of the range, 9 to 16 per cent., specified by the discoverer. For some time after the steel was produced commercially, the carbon content was about 0.3 to 0.4 per cent. and occasionally higher; only rarely was material with 0.25 per cent. carbon or less produced. The reason for this is obvious from the nature of the alloys of chromium available for making such steels; as the lowest carbon content generally available was about 1 per cent., and this in conjunction with a chromium content of about 60 per cent., the production of a 12-per cent. chromium steel with less than 0.25 to 0.30 per cent. carbon was impossible. The advent, on a reasonable commercial scale, of carbonless ferrochromium has modified this condition, however, so that for the last three years stainless material containing 0.1 per cent. or less carbon and the normal amount of chromium has been on the market. As far as the author is aware, the material was first made on a commercial scale by the firm with which he is associated in June, 1920, when a 5- or 6-ton cast of material containing 0.07 per cent. carbon and 11.7 per cent. chromium was made and cast into 12-in. ingots. The necessity for using a totally different raw material, carbonless ferrochromium, instead of the ordinary low-carbon ferro (0.6 to 1.0 per cent. carbon) has led to the idea that stainless iron is a quite distinct product and quite different from stainless steel. While this may be true from a commercial aspect, it is wrong metallurgically. The name stainless iron is unfortunate as the material is a very mild stainless steel and forms the lowest carbon member of a series of steels of continuously varying content which are, in many respccts, the counterpart of the series of ordinary carbon steels ranging from "dead soft" to tool steels. In an article on stainless steel in the Journal of the Society of Chemical Industry, November, 1920, the author said "Just as in the far-off days 'steel' was regarded as a hard product of iron, and little or no attempt was made to grade it into harder or softer varieties, so at present stainless

Jan 1, 1924

By John H. G. Monypenny

The range of chromium content of stainless steel is, in most cases, included in the limits 11 to 14 per cent., or the middle part of the range, 9 to 16 per cent., specified by the discoverer. For some time after the steel was produced commercially, the carbon content was about 0.3 to 0.4 per cent. and occasionally higher; only rarely was material with 0.25 per cent. carbon or less produced. The reason for this is obvious from the nature of the alloys of chromium available for making such steels; as the lowest carbon content generally available was about 1 per cent., and this in conjunction with a chromium content of about 60 per cent., the production of a 12-per cent. chromium steel with less than 0.25 to 0.30 per cent. carbon was impossible. The advent, on a reasonable commercial scale, of carbonless ferrochromium has modified this condition, however, so that for the last three years stainless material containing 0.1 per cent. or less carbon and the normal amount of chromium has been on the market. As far as the author is aware, the material was first made on a commercial scale by the firm with which he is associated in June, 1920, when a 5- or 6-ton cast of material containing 0.07 per cent. carbon and 11.7 per cent. chromium was made and cast into 12-in. ingots. The necessity for using a totally different raw material, carbonless ferrochromium, instead of the ordinary low-carbon ferro (0.6 to 1.0 per cent. carbon) has led to the idea that stainless iron is a quite distinct product and quite different from stainless steel. While this may be true from a commercial aspect, it is wrong metallurgically. The name stainless iron is unfortunate as the material is a very mild stainless steel and forms the lowest carbon member of a series of steels of continuously varying content which are, in many respccts, the counterpart of the series of ordinary carbon steels ranging from "dead soft" to tool steels. In an article on stainless steel in the Journal of the Society of Chemical Industry, November, 1920, the author said "Just as in the far-off days 'steel' was regarded as a hard product of iron, and little or no attempt was made to grade it into harder or softer varieties, so at present stainless

Jan 1, 1924

National Energy Technology Laboratory ?Only DOE national lab dedicated to fossil energy -Fossil fuels provide 85% of U.S. energy supply ?One lab, five locations, one management structure ?1,200 Federal and support-contractor employees ?Research spans fundamental science to technology demonstrations

Jan 1, 2006

By G. Dale Cor, Will H. Coghill, M. F. Williams, I. L. Feld

"INTRODUCTION During the past several years the Southern Experiment Station of the Bureau of Mines, with the cooperation of the University of Alabama, has given attention to hydraulic classification. One of the things this work has revealed is a variability not generally recognized in the conditions of teeter at different depths. This report depicts the passage of material through a teeter column and its emergence as a classified product.The work was made possible through the development of a classifier for several hundred pounds per hour permitting a small quantity of coarse spigot material to be discharged without the usual interruptions caused by stop-pages. Previous designs of small classifiers have been unsatisfactory because the,orifice used to control the quantity of spigot product as subjectto stoppages, particularly when attempting to discharge a small quantity of although the classifier used in this work has been described in detail in a previous publication 6/ its principal features will be discussed briefly herein. The main subject matter of the paper is based upon the three figures that illustrate in panorama the conditions that exist in a classifier during the continuous classification of bituminous coal, anthracite coal, and an iron ore trailing."

Jan 1, 1946

By G. E. Tardiff, A. A. Hendrickson

THE objectives of this communication are to present the solid-solution strengthening data for silver-base zinc single crystals and to evaluate the importance of strength contributions from several mechanisms through the use of this data combined with that for the silver-base aluminum case.' Some features of the yield point behavior of silver-base zinc crystals were previously reported.' Silver-base zinc alloys were prepared by induction melting 99.99 pct Ag with 99.9 pct Zn in high-purity graphite crucibles contained in argon-filled quartz tubes. After the first melting, the ingots were cut into short lengths, redistributed in the molds, and remelted in order to reduce solute-concentration variations. Alloy single crystals were then grown from the melt through the use of a modified Bridgeman technique which consisted of lowering the graphite crystal mold through a hot zone at a rate of 3/8 in. per hr. As in the melting operation, the molds were contained in argon-filled quartz tubes. Gage lengths 2 cm in length were introduced by both spark machining (circular cross sections) and abrading and acid etching (rectangular cross section) followed by electropolishing (a comparison of the critical resolved shear-stress values prepared by the two techniques showed no differences in strength values). The final cross-sectional areas of the crystals were approximately 5 sq mm. Prior to testing, the crystals were annealed at 600°C for 20 hr in argon atmospheres, furnace-cooled, and lightly electropolished. Crystal orientations were determined using the back-reflection method. The tensile testing was done on a Model FM Instron at a strain rate of 1(T4 per sec. Test temperatures of 77", 200°, and 400°K were attained by immersing the specimens in liquid nitrogen, dry ice-acetone mixtures, and silicone oil, respectively. The critical resolved shear-stress (CRSS) values for silver-base zinc crystals as a function of composition and testing temperature are given in Fig. 1. It will be noted that the CRSS for silver-base zinc solid solutions, as in the silver-base aluminum1 case, depends on temperature in a manner typical of fcc solid solutions: at high temperatures (-300°K and above), the CRSS is relatively temperature-independent but becomes strongly dependent on temperature at lower testing temperatures. A reasonable picture of solid-solution strengthening for silver-rich solutions at room temperature based on "direct" strengthening mechanisms3 is as follows. Since silver alloys have low stacking-fault energies, extended dislocations are expected and it is possible that Suzuki locking4 makes the major contribution to the room-temperature solute strengthening. This provides essentially temperature-independent strengthening since thermal motions of the dislocation line are not large enough to aid the dislocation in escaping the solute atmosphere extending over the fault width. An estimate of the

Jan 1, 1964

By M. J. Scoble, N. Rowlands, L. Piciacchia

Pronounced non-linear behaviour of mine backfill arises from the influence of confining pressure, cementing agent content, curing time, void ratio and water content. Past research into backfill behaviour under stress is reviewed and related to the needs for constitutive laws which can be integrated into numerical modelling for mine design where structures employ backfill support. A method for representing non-linear backfill behaviour is proposed, which is based upon numerical regression treatment of triaxial laboratory data. The non-linear behaviour observed from a program of laboratory triaxial testing of cemented hydraulic backfill is presented. The particular influence of confining stress and curing duration is high- lighted. The paper concludes by considering the alternative means of accounting for such behaviour in mine design.

Jan 1, 1984

Gold bearing sediments at Scotland Point occur within the Quaternary Gibbston Fonnation, which underlies Cromwell Flat in Central Otago. Gibbston Fonnation unconformably overlies Teniary Manuherikia Group clays, sands and quartzose gravels. Gibbston Formation sediments are composed of a texturally diverse, multistoried lithostratigraphic succession of sandy/gravelly/bouldery lithofacies, deposited within a multiple channel (braided) depositional environment. Lithostatigraphic analysis indicate an upward overall decrease in average grain size, reflecting a concomitant reduction in stream competence. This trend results from progressive channel abandonment as major distributaries avulse across the outwash plain. Grade distribution of alluvial gold is controlled by aggradational and to a lesser extent degradational lithofacies deposited as distinctive braid bar forms near the base of the sequence. These lithofacies were deposited at different topographical levels on the outwash apron, under variable hydraulic conditions. Recognition of large-scale auriferous bedforms within the braid bar depositional system coupled with an understanding of lateral facies relationships, allows headgrade control on run of mine ore and quick determination of overburden to ore ratios.

Jan 1, 1988

By Hayel M. El-Naggar, Sherif A. Akl

Although grouted piles have been used for several decades since the idea was proposed in the 1970s, their design is mostly based on experience and unpublished proprietary methods. There is little research on grouting drilled shaft tips and even less on grouting shaft sides. This paper presents the analysis of 4 instrumented pile loads tests on base and shaft grouted piles from different sites in Egypt; with emphasis on one of the tests, to demonstrate the analysis process. The data from the tests are analyzed to model the development of unit side friction (USF) with relative displacement. A numerical model using the finite element software PLAXIS is used to investigate the effect of grouting on the surrounding soil stress state. The paper combines the observations from full scale pile load tests and results from the numerical model to suggest an idealized behavior of side friction development with relative displacement of the grouted part of the shaft. The suggested model considers an envelope of Unit Side Friction (USF) with relative displacement, initially dominated by the grout resistance then at higher relative displacements, the friction with radially pressured soil takes over. The grout provides very high USF values up to a relative displacement of 2mm. Then, the USF drops to a typical pile soil side friction behavior; however, this friction is affected by the contact stress between pile and soil, which significantly increases due to compaction grouting. INTRODUCTION Base and shaft pile grouting has been significantly developing in recent years to accommodate the unfavorable conditions in major projects such as the high loads in high rise building and founding on problematic soil formations. Grouting aims to decrease settlements and increase the capacity of the pile under axial load. The technique is first introduced by Kraft (1974) but gained popularity in the 1980s. Typically there are two types of grouting; compaction, and permeation. Compaction grouting is more common in pile foundations practice, and many researchers have provided case histories of pile load tests on base grouted piles and base and shaft grouted piles (Gouvenot and Gabaix,1975; Stocker, 1983; Ghazali et al., 1988; Fleming, 1993; Kusakabe et al., 1994; Robson and Wahby,1994; Joer and Randolph, 1998; Hamza and Leoni, 1998; Mullins et al. 2000; Littlechild et al., 2000; Suckling and Eager, 2001; Dapp and Mullins, 2002; Ho, 2003; Fu and Zhou, 2003; Brettmann and NeSmith, 2005; Ruiz, 2005; Mullins, 2006; Dapp and Brown, 2010; Beadman et al., 2012; Nguyen et al., 2013; Miller et al., 2013; Sinnreich and Simpson, 2015; Hui and Lin, 2015). Compaction grouting is meant to densify the soil around the pile and below the base rather than permeate this soil and increase its cohesion. Research showed that grouting increases the capacity of the piles by a factor of 2~5. The variation in capacity increase depends on pile type, grouting process, and especially grouting pressure. Although there are many case histories of pile load tests on grouted piles but there is no well-defined agreed-upon method to predict grouted pile capacity as typically done in ungrouted piles. Few lab experiments discussed the shaft grouting effects on the soil especially the compaction grouting. The experiments concluded that the compaction grouting forms a homogeneous layer between the pile and the soil, and a residual effective stress is achieved simultaneously with a significant densification of the soil around the pile with noticeable decreasing in void ratio. (Fattahpour et al., 2015; Wang et al., 2015). Recently, studies used numerical analysis to investigate the behavior of the grouted piles and the changes in the surrounding soil (Chiang et al., 2013). That study presents a simulation of the base pressure grouting with a simple FE model and predicts the reduction of the pile settlement by 10 to 20%. Another numerical study using a complex model conducted by Zhou et al. (2017), pr

Jan 1, 2018

At times the phosphate industry, in Florida, encounters phosphate rock that gives lower than expected P2O5 recovery in the rougher plant section. The drop in recovery is typically 10% and as much as 30% or more. Variations in feed quality from day to day, shift to shift and even from drag-line to drag line, represent a challenge to the beneficiation plant operators and reagents? suppliers. Therefore, this characterization study has been initiated to identify the reasons for the differences in flotation behavior of such feeds. The study involves many samples to cover such variations. The characterization work includes: ? Mineralogical and chemical analysis; ? Size, shape, surface roughness and porosity analysis; ? Surface charge and surface contamination with other phases (minerals); ? Clay content and its relationship to phosphate and silica particles. The results correlated with flotation data and adsorption density measurements clearly establish the statistically significant variability in characteristic features that influence flotation response. This article discusses results from the above listed studies. On the basis of the obtained data, recommendations of practical approaches to overcome the problem of feed variability in phosphate flotation plants are delineated.

Jan 1, 2014

By Gregory J. Kurras

In 1995 the Marine Minerals Technology Center (MMTC) of the University of Hawaii conducted a sidescan sonar survey and sampling expedition of the submarine geology and hydrothermal systems surrounding the active volcano White Island. The island is located in the Bay of Plenty, within the geothermally active Taupo Volcanic Zone off-shore of the North Island of New Zealand, and is the site of numerous shallow-water hydrothermal systems. The survey system, an EdgeTech DF1000 sonar, was a dual frequency 100 kHz & 500 kHz sonar capable of imaging the seafloor at better than 1 m resolution and possibly detecting gas bubbles within the water column. Sidescan imagery clearly shows sand channels, debris slumps, submarine landslides, and volcanic ridges all around the island to roughly 800 meters offshore. However, analyses of the both raw and processed acoustic data indicate that the sonar was not able to image any of the shallow-water hydrothermal gas seeps known to exist around the island. Vents were located using a commercial fish finder and knowledge from local tour guides and divers. Eleven gas samples from three different sites were collected by divers for analysis of chemical and isotopic composition. Rock samples were collected from thirteen underwater outcrops for correlation with existing data on subarial island flows sampled by previous investigators. Thin sections and XRF analysis were done for each rock to determine mineral assemblages along with major and trace elements, which were used to tie submarine samples to specific subarial stratigraphic layers.

Jan 1, 2011

Jan 1, 1951

By J. R. Low, M. B. Reynolds, L. O. Sullivan

The effect of neutron bombardment upon the stability of type 347 austenitic stainless steel has been investigated by a magnetic technique. The relation of the ferrite content of a stainless steel to its magnetic properties is given, and an apparatus suitable for the measurement of the ferromagnetic saturation induction of small specimens is described. Results of measurements on irradiated specimens are tabulated. Exposure to a neutron flux was found to cause a slight increase in the ferrite content of type 347 stainless steel, the change increasing with increasing length of exposure and with increasing initial ferrite content. The similarity of the effect of irradiation to the effect of annealing is pointed out. Possible effect of irradiation upon density of austenitic stainless steel is discussed. COMMERCIAL austenitic stainless steels are alloys of iron, chromium, and nickel, plus small quantities of other elements. Although these alloys are normally used in the austenitic condition, this state is thermodynamically metastable at ordinary temperatures and transformation to a more stable state takes place under favorable conditions. In the austenitic state, these stainless steels have the face-centered-cubic crystal structure characteristic of y iron, but the stable state at room temperature is a mixture of austenite and body-centered-cubic ferrite. The transformation from the pure austenitic condition may be brought about by cold working the alloy at a temperature below that at which the aus- tenite becomes thermodynamically unstable (about 400°C), the completeness of transformation increasing with increasing severity of cold work and decreasing temperature. The behavior of the austenitic stainless steels under ordinary conditions of use is rather well known. However, use of these alloys in a nuclear reactor introduces a new variable: the effect of neutron bombardment upon the transformation from the austenitic to the ferritic state. It was with this in mind that a study of the radiation stability of austenitic type 347 stainless steel was undertaken. Magnetic Technique for Ferrite Determination Commercial austenitic stainless steels such as type 347 undergo little transformation under normal conditions of fabrication and use. In view of this fact, it seemed likely that neutron irradiation would change the ferrite content of the alloy but little. The method chosen for measurement of the effect of neutron irradiation was thus limited to one which would be quite sensitive to small changes in the ferrite content of the alloy. Of the properties of the stainless steel which can be measured, the magnetic characteristics are most sensitive to the quantity of ferrite present.

Jan 1, 1956

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016

By T. E. SCHTVARZ

THE publication of the report by Mr. F. L. Ransome was welcomed by many engineers who had mined in the heart of the Sail Juan country, braved its long and snowy winters, climbed its lofty peaks, run the gauntlet of its snow-slides, and studied its problems of geology, while making dividends for their English or American clients. This report helps one to understand why the bonanzas occurred, and why the inevitable borrasca presents itself where least expected. The Red Mountain district of Ouray county, a very productive section from 1884 to 1893, occupies considerable space in the report mentioned.. The character of the ore-occurrence, being distinctive and presenting many features not existing elsewhere, has been deserving of special study. It is to be regretted that Mr. Ransome was .unable to observe the conditions underground, as all the principal properties, many of which I opened and developed, were closed at the time of his investigation: It has been my privilege to have contributed a few brief papers recording my observations in developing these properties ; and it is the object of the present paper to present certain sections of the Yankee Girl mine, which throw additional light on the geology of the section and make the available data more complete. The main Yankee Girl chimney or " stock" was the most productive for the first 500 ft. in depth of any chimney in the district.

Mar 1, 1905

By Chul Soo Park, Juhyung Lee, Duhyun Baek

"In this study the preliminary design of suction pile as the supporting system of the concrete floating structures was performed at the offshore pilot project area in Korea. The suction pile of the floating structures has to satisfy the lateral resistance against external force evaluated from the marine and structure conditions, as well as the penetration ability according to the soil and seepage conditions. In the design, the required penetration depths for lateral resistance were evaluated with different diameters of cylindrical steel suction pile, and the design suction pressures at each penetrating depths were assessed through the comparison of penetration forces and penetration-resistances. Finally, the optimal dimension of suction pile for the pilot project area was proposed.IntroductionInterests in sea spaces have rapidly increased around the world due to limitations in use of lands. Such increase has resulted in construction of numerous marine structures aimed at expanding the use of sea spaces and developing marine resources. South Korea also needs to secure construction technologies for floating infrastructures on its relatively deep seas. Foundations for floating structures consist of anchors and mooring systems rather than driven piles or cast-in-place piles, due to limitations in equipment operation or economic feasibility. Anchors and foundations used on the sea include drag anchors and suction piles, but the suction piles are more widely used for reasons regarding uncertainties of calculation of bearing capacity and construction. Large-diameter suction piles are generally used to utilize fully their penetration ability, which is proportionate to the square of the foundation diameter, and the length-diameter ratio (L/D) does not exceed 6 (Randolph et al., 2005; Andersen et al., 2005). Recently, a design and construction technology using group suction piles consisting of medium-diameter suction piles and concrete pile caps is being developed as an alternative to the conventional large-diameter mono suction piles. In addition, pilot projects involving the group suction piles of mediumdiameter are currently being reviewed for the southwest coast area in Korea. In this study, therefore, preliminary design for installation of medium-diameter mono suction piles as the supporting system of the concrete floating structures was performed, and suction pressures, penetration forces and resistances, and lateral loading capacity with diameters were reviewed."

Jan 1, 2017

By G. K. Dumbauld, B. E. Morgan

Kesults of laboratory investigations of the effects of drilling muds on oil well cements are presented which show that relatively large quantities of untreated muds do not seriously interfere with the setting of cement slurries, but that relalively small quantities of treated muds seriously retard the setting of cement slurries. Laboratory results also indicate that the harmful effects of contamination with treated muds can he counteracted by the addition of activated charcoal to cements. Also described is the successful use of cement containing activated charcoal for the placement of plugs in oPel hole after previous attempts with ordinary cement had been unsuccessful. INTRODUCTION The contamination of cement slurry by dilution with drilling mud has long been considered a cause of failure in oil well cementing. The cement slurry must displace the drilling mud from the annulus between the casing and the walls of the borehole. and it is probable that some mixing of the slurry and the mud occurs even under the most nearly ideal displacement conditions. Hole enlargement, failure to center the casing in the hole, and formation of gel structure in the drilling mud increase the probability of contamination. In some cementing operations, such as the placement of a cement plug in open hole, considerable mixing of the mud and slurry is likely. Many cement failures which can be attributed logically to no cause other than contamination of the cement slurry by the mud attest the need of a better understanding of this problem. Considerable attention was given to the problem of mud contamination of cements about 20 years ago.The effects of field mud upon cement slurries prepared with different amounts of mix water were investigated thoroughly, and the data obtained were invaluable in determining the causes of the high percentage of failure in oil-well cementing at that time and in bringing about improved cementing results. Since then, many aspects of the problem have changed, due primarily to advancements in cement and drilling mud technology. Today, several types of portland cement are used in well cementing and numerous chemical additives are used in drilling muds. An excellent report on the effects of drilling mud additives on oil-well cements was issued during 1951 by the American Petroleum Institute. Data in the report revealed that many mud additives, notably organic materials in relatively small amounts, produce a marked effect on the properties of cements. Prior to this time, little information has been available on the effects of chemicals commonly used in the treatment of drilling muds upon the properties of cements. Another aspect of the problem of mud contamination of cements, which has received no attention heretofore, is the possibility of producing a cement having properties unaffected by a reasonable amount of mud contamination. In view of the need for additional information on the contamination of present-day cements by currently-used drilling Muds, the investigation described herein was initiated Several years ago with a two-fold purpose: first, to determine the capacity of cement slurries to tolerate contamination by both untreated and treated muds without loss of ability to set and develop strength within a reasonable time; and, second, to investigate the possibility of enhancing the ability of cement slurries to withstand mud contamination by incorporating additives in the cement. The data for this study were obtained by mixing drilling mud with cement slurry and testing the resulting slurry-mud mixture for rate of set and development of strength. Also, several materials were tested for their possible improvement of the property of cement slurry to withstand mud contamination; these materials were tested in both contaminated and uncontaminated cement slurries.

Jan 1, 1952

In the time since the first trials in the mid-1980s, the Rare-Earth Magnetic Separators (REMS) are presently (year 2001) found in many heavy mineral sands plants around the world. Both the roll and the drum type are used from ilmenite concentration to cleaning high-purity zircon products. Chromium-bearing materials are removed from ilmenite more selectively than with electromagnetic separators. Greater flexibility and higher grades in ilmenite circuits are achieved. Cleaner rutile and zircon products, even with respect to levels of radioactive materials, are the result of superior magnetic force optimisation. Tailings from roaster plants can be reprocessed effectively, which is encouraging some operators to look at replacing old equipment in order to process roasted material plant feed or implement use of the new generation drum separators in new plants. Wet separation of ilmenite by using powerful wet REMS drum separators is now a possibility. This may be an alternative to at least a portion of the Wet High-Intensity Magnetic Separators (WHIMS) process for ilmenite preconcentration. A dry plant process flowsheet can often be modified by displacing a portion of high-tension separators with new high-temperature tolerant REMS.

Jan 1, 2001

By R. Silverman, H. Blumenthal

It was found that despite the similarity of chemical analyses of different titanium carbides used as base materials for cermets, the physical properties, especially transverse-rupture strengths, of test bars were different. Hence this metallographic study attempts to link physical properties to micro-structures. It is shown that microstructure, grain shape, and grain growth are functions of three interrelated factors: 1—powder production procedure, 2—surface conditioning of the particles, and 3—impurities either contained in the original powder or acquired during ball milling. An explanation is offered for the "coring effect," long observed, but heretofore of unknown origin. The explanation is based on assumption of an oxide film and on chemical analyses which substantiate these findings. TITANIUM carbide has become in recent years a material of great interest in the high temperature field. Consequently, many manufacturers in the United States and Europe are producing titanium carbide for cermet applications as well as for additions to the well known tungsten carbide tools. All present commercial processes of titanium carbide production utilize the chemical reaction of titanium dioxide and carbon to form as nearly as possible stoichiometric Tic. This reaction is carried out in three ways: 1—in a menstruum of molten metal,' 2—in the solid state, either in a protective atmosphere2 or in vacuum;" or 3—in an are-melting operation. In spite of the fact that the pure carbides obtained in these operations are almost identical chemically, the physical properties vary considerably when they are combined with a binder (Ni, Co) to form cermets. This fact led the authors to examine metal-lographically nickel-bonded titanium carbide in order to find the possible reasons for this behavior. Materials and Methods Five different titanium carbides were used in this investigation. They are identified in Table I. The first four materials were used in the as-received condition. Material E, received in lumps, was crushed to —100 mesh and carried through a flotation process in order to bring its graphite content in line with the other products. A Galagher flotation cell was used with pine oil as frothing agent. The chemical analyses of the investigated materials are given in Table 11. The binder used was carbonyl nickel of 9 to 14 microns particle size, supplied by A. D. Mackay. The materials were ball milled at a ball to charge ratio of 6:1 using procedures described under "Experiments and Results." All particle sizes mentioned are averages determined with a Fisher Sub-sieve Sizer. Test bars (lx0.40x0.16 in.) were prepared by 1—hot pressing to 85 to 95 pct of theoretical density at pressures between 1 and 1½ tsi and temperatures from 1600" to 1800°C, 2-—-cold presssing after 3 pct camphor had been added, or 3—wet pressing, both 2 and 3 at pressures between 5 and 10 tsi. All pressed bars were sintered in a vacuum of 105 to 10-6 mm Hg for 2 hr at 1350 °C. Transverse-rupture strengths were determined by breaking on a Baldwin Universal Testing Machine over a 9/16 in. span. Densities were measured by water displacement. The preparation of the specimens for micrographs was done according to Silverman and Doshna Luscz." All magnifications are at X1000. A sodium picrate electrolytic etch was used. Experiments and Results The influence of ball-milling procedure, ball-milling medium, pressing procedure, and sintering procedure on the microstructure of 80/20 — TiC/Ni were investigated. Ball Milling of Materials A, B, and C in a Steel Mill: Figs. 1 and 2 show microstructures of hot-pressed and vacuum-sintered test bars of materials A and B after the respective materials had been ball milled to 2.1 microns particle size in a steel mill and mixed with 20 pct Ni binder. Material A (Fig. 1) shows considerable grain growth. Also evident is a tendency of the carbide grains to coalesce. The density is 98 pct and the low transverse-rupture strength of 111,000 psi is probably caused by many large grains and an unfavorable packing factor. Almost all grains show a slight indication of "coring." Material B (Fig. 2), although showing grain growth, still has many small particles and a better distribution of binder and carbide due to the relative absence of the coalescing tendency. "Coring" can be observed in almost all grains. The high transverse-rupture strength of 179,000 psi and the density of 100 pct are believed to be due to the many small grains completely surrounded by the binder phase. There is also a preference to form spherical grains with material A, while most grains of material B preserve their angular shapes. Material C, of which no picture is given, stays between A and B in every respect. Rounding of some grains can be observed as well as coring, but the latter to a lesser degree than with material B. Its densification is good and the transverse-rupture strength obtained is 142,000 psi. Ball Milling of Materials A, B, C, and E in a WC Mill: When the Tic powders were ball milled to 2 microns particle size in a we mill, then ball-mill mixed with 20 pct Ni binder, hot pressed, and vacuum

Jan 1, 1956