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By Roberto Parreiras Tavares, Frederico da Costa Fernandes, Guilherme Antonio Defendi, Vangleik Ferreira da Cruz, Júlio César de Sousa Pena

"Near-net-shape casting is an important area of research in the iron and steel industry today. Among the near-net-shape casting processes, the single-belt caster seems to be the most promising, since it is the only one that can achieve levels of productivity similar to those obtained with conventional continuous casting machines. One of the most important aspects in the single-belt casting is the feeding system used to deliver liquid metal over the belt. This system determines the velocity distribution and the levels of turbulence of the liquid metal and affects the quality of the strips. In the present work, a metal delivery system having a simple geometry was proposed. Using the CFD code CFX 5.6, a mathematical model to simulate three-dimensional turbulent fluid flow and heat transfer in that system has been developed. This model was used to analyze different configurations of the metal delivery system and the free surface shape of the fluid was also determined. A physical model of the feeding system was built and used to validate the predictions of the mathematical model. The fluid flow calculations have been validated by dye injection experiments and laser doppler anemometry. Measurements of the free surface levels have also been performed. These experiments provided supporting evidence for the predictions of the mathematical model.IntroductionTo maintain its competitiveness in the present market, the metallurgical sector, particularly the steelmaking companies, are developing new techniques of production. Some of these new processes are focussed on the strip casting technologies. Among these technologies, the SingleBelt process is considered the most interesting option, reducing the number of rolling steps and, consequently, the final cost of the product, especially the part associated to the energy consumption (fuel and/or electric energy). This process can also reach levels of productivity that can not be matched by other strip casting methods(1). One of the most important aspects concerning these new processes is related to the liquid metal delivery system. This system can have a significant effect on the final quality of the strips, since it determines the velocity distribution and the levels of turbulence of the liquid metal."

Jan 1, 2004

By H. P. Holmes

Tonnage quantities of hafnium metal have been prepared in Kroll-process equipment designed for producing zirconium. Some slight process modifications have been necessary, but overall operation is the same as for zirconium. Hafnium oxide is chlorinated in the presence of carbon and the resultant hafnium tetrachloride reduced by magnesium metal. Byproduct magnesium chloride is removed in a high-vacuum distillation step and the hafnium sponge metal crushed for further use. Arc-melted metal can be forged and rolled to sheet, but the best material produced to date would not be considered cold ductile. INTRODUCTION This investigation is part of the program for the production of pure metals from domestic and foreign ores that has been underway at the Bureau of Mines for several years. It was done in cooperation with the Atomic Energy Commission and the Bureau of Ships.

Jan 1, 1955

By Spencer Waganaar, Katherine Winters, John Murphy

Hundreds of miles levees cutoffs have been placed in USACE levees in the Sacramento CA, Houston TX, and Southern Florida regions in the past 40 years, with smaller projects in additional regions. Many of these cutoff walls are designed for infrequent loading as they that are critical infrastructure for extreme flood events. With this infrequent loading, there are no widely accepted ways to monitor and quantify the condition and functionality of seepage cutoff walls for levees over multiple decades. The potential for deterioration is not well known. Lack of data on the longevity/design life of cutoff walls adds uncertainty to levee risk assessments, operational and maintenance costs, and community risk. USACE-ERDC is conducting a comprehensive review of existing research regarding cutoff wall longevity and deterioration to address these uncertainties. The potential mechanisms of deterioration are cracking, chemical reactions, vegetation growth, or animal burrows. This paper includes documenting experiences from USACE levee safety experts, pertinent failure mechanisms identified from engineering literature, whether and how these considerations for cutoff walls are currently incorporated into risk assessments, and assessing the need for need for further research to reduce uncertainty. The findings presented in this paper will include uncertainties and potential risks to levee performance due to levee cutoff wall deterioration and suggest areas for further field investigation. Findings could contribute to improving recommended potential post-construction QC practices, operations and maintenance practices, identifying early warnings of reduced functionality, reducing costly invasive/destructive testing, and informing risk assessment methodology.

Oct 7, 2024

By M. Sunkpal, K. C. Kocsis

"An underground environment with high air temperature and humidity conditions generated from various heat and moisture sources can significantly affect the thermoregulation processes of the human body. This can lead to a series of heat-related illnesses such as heat exhaustion, heat cramps and heat stroke. The majority of the metabolic energy of a mine worker results in the production of heat. If the human body is to maintain thermal equilibrium, then this metabolic heat must be transferred to the ambient surroundings at the same rate. The heat loss from the human body occurs through a combination of heat transfer processes, such as respiratory heat exchange, convection, radiation and evaporation. If the heat loss from the human body to the ambient surroundings is less than the metabolic heat produced, the excess will be accumulated within the human body, which will result in a rise in the core and skin temperatures. This can ultimately lead to a heat-related illness or a combination of heat-related illnesses. This paper aims to discuss major heat-related issues and provide an overview of various mine ventilation and cooling systems, which can be employed to overcome high levels of heat and humidity in underground mines. In this paper, the effects of heat exposure on the health, safety and productivity of the mine workers are also highlighted. IntroductionMining in the United States remains one of the most hazardous industries, despite significant reductions in fatal injuries over the last century (Coleman and Kerkering, 2007; Saleh and Cummings 2011; Jacklitsch, Musolin and Kim, 2016). Occupational health hazards within the mining industry include hazards that are physical, such as traumatic injury or hearing loss; chemical, such as silica or diesel particulate matter; biological; ergonomic; and psychological (Donoghue, 2004; Saleh and Cummings, 2011). The effects of some of these hazards can be diagnosed immediately, while many, like black-lung and silicosis, will have long-term effects on the health, safety and life quality of mine workers (Donoghue, 2004; National Institute for Occupational Safety and Health, NIOSH, 2000). Among these hazards, exposure to heat and humidity can significantly affect the safety, health and productivity of mine workers, particularly in deep and hot underground mines (Roghanchi, Sunkpal and Kocsis, 2015). Short-term acute heat exposures can cause a rise in the core temperature of the human body, which can result in a heat-related illness or combination of heat-related illnesses. Adverse long-term chronic heat exposure can generate serious occupational heat-related illnesses, such as cardiovascular diseases, mental health problems and chronic kidney diseases. High core body temperatures coupled with dehydration can generate negative behavioral effects such as physical fatigue, irritability, lethargy, impaired judgment, loss of dexterity and loss of concentration (Xiang et al., 2014)"

Jan 9, 2017

By Connor Langford, Murray Gant, Ken Massé

For public organizations, preparing accurate project cost estimates is a critical component in capital project planning. Project delivery methods provide a structured approach to moving projects through the design and construction lifecycle, and typically use cost estimates as key inputs at each stage to determine if the project will advance. As design stages can occur years or even decades before construction contracts are awarded, estimates need to make reasonable assumptions about how the work may be executed (means and methods) as well as potential future market trends so that appropriate values for material pricing, labour costs, escalation, and owner’s costs can be included. This process is challenging enough during stable markets, as historic trends can often be misleading and require a suitable understanding of economic factors to use appropriately. When you mix in the market volatility that has been observed since 2020, developing accurate project cost estimates becomes even more challenging. In cases such as this, having a structured approach to cost estimating that includes an adequate risk-based reserves cannot be overstated as it provides the basis for ongoing project decisions. This paper explores some of the historic and more recent market trends that have impacted key aspects of project cost estimates for capital project planning. It also provides recommendations on how to develop cost estimates for infrastructure projects, with examples from Metro Vancouver, which plans for and delivers regional-scale services to 2.6 million residents. A brief commentary on the use of escalation clauses in contracts is also presented.

Jun 13, 2023

By W. N. Lacey, R. H. Olds, B. H. Sage

The volumetric behavior of five mixtures of black oil and natural gas and of two mixtures of condensate and natural gas from a field in the San Joaquin Valley was experimentally established. This work was carried out at roo°, I9o° and 250°F in the pressure interval between 400 and 5000 psi. The viscosity of the liquid phase of four mixtures of black oil and natural gas was experimentally measured in the above-indicated temperature and pressure intervals. The effect of methane upon the precipitation of bitumen from the black oil was studied at 230°F. Introduction The solution of a number of the economical and technological problems which arise in connection with petroleum production is dependent upon the availability of the necessary quantitative information covering the materials involved. This requires data concerning physical properties of naturally occurring hydrocarbon mixtures at the pressures and temperatures characteristic of underground petroleum reservoirs. The experimental determination of the desired data for each situation encountered is relatively time-consuming. However, it is considered to yield results sufficiently more reliable than those obtained from correlations to justify the effort. For these reasons there was undertaken a laboratory investigation of the viscosity of the liquid phase and the volu- metric and phase behavior of mixtures of oil and gas samples obtained from wells in a field located in the San Joaquin Valley. Terminology The nomenclature of petroleum engineering is not at present entirely standardized. Many commonly used technical terms are not everywhere given the same meanings. For the purposes of this paper the following definitions will be adopted: Black oil refers to the dark-colored, hydrocarbon liquid obtained when the producing horizon of the well lies partly in the condensed hydrocarbon phase of the reservoir. Condensate is the term applied to the relatively volatile, pale yellow or amber-colored hydrocarbon liquid that is often obtained from the surface separator system when the producing horizon of the well lies in the gas cap of the reservoir. The gas obtained from the surface separator system is called natural gas regardless of whether the well is producing black oil or condensate. As might be expected from the multi-component character of naturally occurring hydrocarbon materials, the compositions of black oil, condensate and natural gas are subject to considerable variation depending upon the temperatures and pressures prevailing in the surface separator system as well as upon the overall composition of the material produced from the reservoir. In order to obtain samples capable of reproducing the total hydrocarbon material produced by the well, all oil and gas mixtures used in this investigation were com-

Jan 1, 1949

By G. Roy, D. R. Lentz, A. O. Wills

"Abstract - Diamond-drill hole DDH-B357, located 1.5 km north of the Brunswick No. 6 Zn-Pb- Cu-Ag volcanic-sediment-hosted massive sulfide (VSHMS) deposit, intersects three exhalative horizons within variably altered felsic volcanic rocks of the Nepisiguit Falls and Flat Landing Brook formations. These three petrographically indistinguishable iron formation intervals (Fe2O3T = 21.4 wt.%) likely represent cogenetic hydrothermal sedimentary units because they display a common geochemical signature: Fe2O3T = 42.9 ± 10.5 wt.%, MnO = 5.4 ± 3.1 wt.%, elevated base metal values (Zn+Pb = 1999 ± 1091 ppm), strong enrichment in additional exhalative components (CaO = 5.3 ± 3.9 wt.%; P2O5 = 1.43 ± 1.00 wt.%), oxidized signature (Fe/Mn = 10 ± 6), as well as a common immobile element signature (Zr/TiO2 = 0.025 ± 0.007) representative of a pelagic source. The calc-alkaline to transitional host volcanic rocks can be discriminated by Zr/TiO2, and to a lesser extent by Th/Nb: Nepisiguit Falls Formation: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Flat Landing Brook Formation: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. A symmetrical repetition of the footwall-iron formation-hanging wall stratigraphic sequence is observed in DDH-B357, with distinct felsic volcanic rock domains separated by the three iron formations. This is best explained by parasitic F2 folds on the west flank of the south-plunging Brunswick antiform, similar to the fold closures known to host massive sulfide accumulations in the Brunswick No. 6 and No. 12 mines. Iron formation geochemistry and felsic volcanic rock chemostratigraphy from drill core sampling can provide an effective mineral exploration tool for the structurally complex rocks of the Bathurst Mining Camp. Sommaire - Le forage au diamant DDH-B357, situé à 1.5 km au nord du gisement de Sulfures Massifs à Encaissant Volcanique et Sédimentaire (SMEVS) de Zn-Pb-Cu-Ag Brunswick No. 6 recoupe trois horizons exhalatifs au sein des roches volcaniques felsiques diversement altérées des formations de Nepisiguit Falls et de Flat Landing Brook. Ces trois intervalles de formation de fer, impossibles à distinguer pétrographiquement les uns des autres, représentent vraisemblablement des unités sédimentaires hydrothermales cogénétiques sur la base de leur signature géochimique commune: Fe2O3T = 42.9 ± 10.5 % poids, MnO = 5.4 ± 3.1 % poids, des teneurs élevées en métaux usuels (Zn+Pb = 1999 ± 1091 ppm), un fort enrichissement en composantes exhalatives additionnelles (CaO = 5.3 ± 3.9 % poids; P2O5 = 1.43 ± 1.00 % poids), une signature oxydée (Fe/ Mn = 10 ± 6), ainsi qu’une signature d’éléments immobiles communs (Zr/TiO2 = 0.025 ± 0.007) indicative d’une source pélagique. Les roches volcaniques encaissantes calco-alcalines à transitionnelles peuvent êtres reconnues par leur rapport Zr/TiO2, et à un moindre degré par leur rapport Th/Nb: Formation de Nepisiguit Falls: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Formation de Flat Landing Brook: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. Une répétition symétrique de la séquence stratigraphique Mur-Formation de Fer-Toit a été observée dans le forage DDH-B357, avec des domaines distincts constitués de roches volcaniques felsiques séparés par les trois formations de fer. La meilleure explication est que le flanc ouest de l’anticlinal Brunswick à plongée sud est affecté par des plis parasites F2, similaires aux zones de charnière contenant les sulfures massifs des mines Brunswick No. 6 et No. 12. La géochimie des formations de fer et la chimiostratigraphie des roches volcaniques felsiques en forage peuvent fournir un outil d’exploration minérale efficace dans les roches structuralement complexes du Camp Minier de Bathurst."

Jan 1, 2006

By Jos. R. Guiteras

The present discussion first presents data to justify the fireproofing of mine shafts. This is followed by a brief outline of fireproofing methods with examples from practice. A summary of authoritative recommendations on fire prevention concludes the discussion. Acknowledgment is made to D. J. Parker, district engineer, Mine Safety Station, Salt Lake City, Utah, for his valuable criticism of the paper. Fireproofing a mine shaft implies lining the shaft with fireproof material or rendering fireproof the material already composing the shaft lining. A brief study of the part mine shafts and shaft stations have played in disastrous end tragic underground fires furnishes convincing evidence that every possible effort to make all mine shafts fireproof is amply justified. The fire hazard in coal minus obviously is much greater than in metal mines. In this discussion the point of views is mainly that of the metal miner; it is tine opinion of the writer that all fires in metal mines are preventable.

Jan 1, 1939

By A Marta

Geomembrane (GMB) liners are being used more frequently for the storage or capping of mine waste due to stricter regulatory requirements relating to environmental protection. The longevity of any liner system will be a function of environmental conditions, design (including materials selection), construction and condition monitoring during operations or closure. Based on experience and case studies, this paper presents a review, from design to handover, of some of the smaller and often overlooked details that can have significant impacts on the performance of the GMB and the project overall.The topics covered will include approaches to selecting and testing GMBs to ensure they are suitable. Design considerations to aid installation and quality assurance during construction. Understanding action leakage rates and the consequences of leakage when it creates whales. Construction quality control and assurance procedures, including a brief discussion on non-destructive liner integrity testing. CITATION:Marta, A, 2018. Geomembranes – from design to handover and some of the lessons learnt, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 190–207 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Walter K. Utt

The vibration levels of the heavy machines used in surface mining are much greater than for vehicles used on highways. In order to assure the proper functioning of electronic equipment placed on the surface mining vehicles, the U.S. Bureau of Mines has conducted a program of field measurements to define their vibration environment. The information in this report is for a class of vehicle that has a blade for scraping and wheels with rubber tires. The statistical information derived from these measurements can be used as a basis for laboratory testing to qualify equipment for a surface mining vehicle of this class. The envelope that would encompass 99 pct of the vibrations encountered in normal operations is presented for each location on the vehicle. The five locations for which data were recorded are the floor of the cab, the engine, the frame, the drive train (gear, differential, and torque converter), and the axle. Tabulated data are provided for those who wish to use a different probability level. The appropriate test profile for the laboratory testing can be determined from the information presented in this report.

Jan 1, 1993

By I. J. Geldenhuys

South Africa’s mining and metals industries have an illustrious history dating back to the Late Iron Age. We live in a complex and data-intensive world that has already fundamentally changed how we work and live. The outbreak of the global COVID-19 pandemic in 2020 resulted in immeasurable suffering worldwide, but the crisis also accelerated many technological developments and altered the way we think about, and experience, technology and work. Problem-solving requires new and rapidly changing skills to manage the data tsunami. Whether at the rock face or on the processing plant, the fundamentals have not changed, although how we interact with minerals and their properties has changed dramatically. Sustainable processing and design are non-negotiable if we genuinely want to achieve the aim of the cradle-to-cradle principle. As we venture forth, what can scientists, engineers, technologists, and mathematicians learn from history? History is data presented in a context; sometimes, the context is also important. We exist in an age of data, with most of the world’s data created in only the past two years. History can enhance our understanding of the present and enhance our future outcomes. Lessons from history can help provide insights into making ethical and sustainable choices related to technology or engineering in the mining and metallurgical industry. Shifting the perspective of mining and metallurgy professionals from a narrow focus on complex technical solutions towards a broader context for problem-solving and designs that includes the entire ecosystem is crucial. In other words, using or reflecting on historical process development is, at its core, systems thinking.

Sep 1, 2021

By James Westfield

A brief résumé follows of activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction of injuries at coal mines: 1. The Federal Mine Safety Code fur Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consulting with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous-coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior on October 8, 1953, after further consultations with representatives of management and mine workers and was incorporated by reference in the 1952 and subsequent bituminous -coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reportin; to the Coal Mines Administrator any violations of the Federal Minis Safety Code. Federal coal-mine inspectors also had temporary authority to close mines found to be imminently dangerous, but such authority under Executive Order 9728 was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1960

By M. Fall

The progressive depletion of ore available at shallow depths in several underground mines around the world means that underground mining operations would increasingly be carried out at greater depths and therefore at higher temperatures. However, our understanding of the effect of hot temperatures on the response (mechanical, economical, environmental) of cemented paste backfill (CPB) is still limited. Hence, an extensive laboratory investigation was conducted to study the performance of young and aged CPB, in response to deep mine temperatures. Several CPB samples with different compositions, cured at different temperatures (20 to 50°C) and different times (7 to 160 days) were tested regarding their mechanical properties, economical performance (binder consumption) and microstructural properties. The results show that hot temperatures significantly affect the performance properties of CPB at young and advanced ages. An increase in the curing temperature leads to a considerable improvement of the rate of gain of CPB strength and also to a significant increase of the strength of CPBs studied. CBP samples cured at hot temperatures show lower binder consumption and finer pore structure. Results of this study could serve as background information for the development of optimal mine backfill design procedures.

May 1, 2007

The objectives of mining grade control are presented and examples of the techniques used in various open pit and underground mines are used to define the attributes of good grade control. Reasons are discussed for the success of various improved practices. The progressive development of grade control is presented and the balance between quantitative and qualitative data is analysed. The skills and resources required for grade control on mine sites that are using best practice are also presented. A number of problems in grade control have been solved recently however there are still issues that need to be addressed. Examination of the grade control process frequently stops after sample quality has been examined. There is much more beyond this that can now be optimised using conditional simulation models. Other future directions of mining grade control are also suggested. An extensive bibliography of published papers on grade control is included that will be maintained and updated on a website.

Jan 1, 2000

By Duncan Chalmers, Rob Nowell, Miguel Araos

Australian underground mines produce in excess of 60 mtpa of coal. Most of these use the longwall method, and they require the use permitted explosives (which are called “permissible” in other countries) for challenges that appear during the day-to-day activities. To obtain the approval for these explosives, they should pass Testing Memorandum #2 (TM-2), which sets out the test required for each category of permitted explosive. These categories are P1, P3, and P5. With P5 being unrestricted use and P3 and P1 have conditional use in underground mines. The TM-2 test was originally set up for NG-based permitted products around 1900. With the closing of NG plants around the world, ammonium nitrate explosives were the natural replacement, and therefore these explosives need to pass the TM2. Australia does have a P1-emulsion based explosive available. For high-risk scenarios (like blasting coal), no P5 explosives are available. The lack of P5 explosives has been prolonged for more than 25 years, since the phasing out of nitroglycerine-based permitted explosive products around the world. The main problem has been that when emulsion based permitted products are tested in the deflagration cannon, the results obtained were not considered in the TM2 criteria and therefore the tests were invalid. A research work on permitted explosives began in 2005 funded by the Australian Coal Association Research Program (ACARP). The aim of the project was to address the lack of P5-type permitted explosive (and, potentially develop them further, i.e., develop safer explosives) and understand the behaviour of emulsion explosive and the results they presented in the tests. Both bureaucratic and technical barriers appeared along the way. On the bureaucracy side, the facility was shut down, reopened, and shut down again. In view of these difficulties, assistance was sought overseas. On the technical side, from the very start the results of the tests when using emulsion-based permitted explosives were not established in the criteria, ignitions occurred for trial samples that were expected to be P5-type, etc. The aim of this document is to present the painful journey in the Australian industry to have a P5-type emulsion-based permitted explosive, for use in UG coal. Also, the technical learning acquired about emulsion explosives and the ignition path of mixtures methane / air will be shown.

Jan 21, 2025

By T. V. Nethery

Introduction A brief account of the East Malartic fire is essential if this paper is to serve the purpose implied by its title. The fire originated in the timbers of No. 4 shaft at the 10th, or 1,570-foot, level; this was the top or collar of the underground sinking operations. At the time, sinking was in progress and the shaft bottom was 242 feet below the 12th station horizon, or 618 feet 'below the l0th level. Above the l0th level, the shaft was not in use as the surface plant was not yet completed. The shaft crews descended from surface in No. 3 vertical shaft to the l0th level, where they transferred to No. 4 shaft, a distance of 1,450 feet. Of the sixteen shaftmen mucking at the shaft bottom, four were able to reach safety. One shaftman was overcome by fumes midway between the two shafts on the l0th level, while attempting his escape. The remaining eleven men climbed as far as the 11th station and there succumbed to carbon monoxide. No. 4 shaft, inclined at 61 degrees, bad been raised and timbered from the 10th level to surface; this bad been followed by sinking operations below the l0th. Two air hoists had been set up in the footwall of the shaft, 110 feet above the 10th level, and directly behind compartments No. 2 and No. 4. The waste from the shaft bottom was hoisted in 28-cubicfoot buckets on mono rails and dumped over standard shaft sinking doors into waste chutes built into No. 1 and No. 3 compartments. The five-compartment shaft, 7 ft. 8 in. by 34 ft. 6 in. overall size, was heavily timbered. In addition to the standard shaft timbers of 8 in. by 8 in. and 8 in. by 10 in. B.C. fir, the hanging-wall and ends of the shaft were laced with 4-inch spruce lagging. This represented approximately 300 board feet of timber in placee for every foot of shaft. The cause of the fire bas never been determined, despite every effort to do so. The inquest held for those who lost their lives in the fire was an extremely thorough one, but only the location of the origin, and not the cause, was established.

Jan 1, 1950

By N. Ono, H. Fujiwara, S. Otsuka-Yao-Matsuo, T. Omata

"The electrical conductivity and the oxygen release and uptake of sintered indium tin oxide (ITO) upon heating and cooling under the condition that P(O2)/P*=4.9X10-4 (P* = atmospheric pressure), :when P(O2) was approximately 50Pa, were simultaneously measured by using a closed-system oxygen-gas analyzer. A large increasing in -the electrical conductivity - upon the· oxygen release detected in 1130<T<1273K was observed. Quantitative relationship between the number of oxygen atom released from ITO and the conduction electron density in ITO was studied. The release of one oxygen atom agreed with the generation of two conduction electrons, i.e., the efficiency-carrier-generation for the oxygen release from the ITO was almost one. The oxygen atom released must be originally at the quasi-anion site in the C-type rare-earth lattice, i.e., the 16c site in the space group of Ia3, as an interstitial excess oxygen, Oi"". It was concluded that the mechanism of conduction carrier generation and compensation upon SnO2 doping into In2O3 can be expressed by the defect equation, 2SnO2-2Sn1n +2(1-z)e'+zOi""+3O0 x+(l-z)/2O2, and that the oxygen release bringing the increase in the electrical · conductivity can be expressed by the equation, Oi""-1/2O2+2e'.IntroductionThin films of SnO2-doped In2O 3 (generally designated as ITO, for indium tin oxide), which have high optical transparency for visible light and high electrical conductivity, have been used as transparent electrodes for liquid crystal and electrochromic displays. It is well known that the electrical conductivity of ITO depends on the content of SnOi-dopant and oxygen. However, a reliable relationship between electrical conductivity and the absolute oxygen content in ITO has yet to be reported. The elucidation of such a relationship is one of the important clues for realizing extremely highly conductive ITO electrodes."

Jan 1, 2000

By Joseph W. Horne

This report presents the results of an investigation by the U. S. Bureau of Mines in cooperation with the State of Colorado, on the yields and properties of oils produced from oil shale, lignite and subbituminous coal using the standard assay method developed by the Bureau for oil-shale testing,. The purpose of this work, which is part of the general study of oil shales being conducted by the Bureau of Mines and cooperating agencies, was to obtain information on the amount and character of the yield of crude oil or tar from different typical oil shales, the yield of light oil or naptha that might be suitable for use in motor fuels, and other products of shale oil. As the west has large resources both of oil shale and low-grade non-coking coals, it is of interest to know the relative yields of tars, light oils, and combustible gases that can be produced from these coals when retorted under conditions similar to those suited for oil-shale retorting. Source of Samples The coal samples were obtained from deposits on or adjacent to the public lands in the States of the Rocky Mountain region. Many of the mines sampled are operating under Government leases or permits. The number of coal samples secured from the various states are: Colorado, 6; Montana, 9; north Dakota, 6; New Mexico. 1; South Dakota, 1; Wyoming, 9. Of these samples, 14 were lignite coal, 16 subbituminous coal, and a bituminous coal. The standard channel method of the Bureau of Mines was used for sampling. Coal samples received at the Boulder Office weighed about twelve pounds each, and duplicate samples were sent to the Pittsburgh Station for proximate and ultimate analyses. The origin of the samples and description of the deposits are given in Table 1.

Jan 1, 1927

By J Pearce, M Barteaux, S Pearce

The prediction of how waste materials will evolve geochemically within waste storage facilities has been the subject of hundreds of thousands of hours researched by geoscientists globally. Despite the quantity of research there are a number of significant areas of uncertainty that remain as partially resolved issues. One of the most significant issues is the applicability of scaling laboratory test results to field conditions, and the use of laboratory data for predictive calculations to determine geochemical evolution of waste materials in the field. This issue has arisen predominantly as a result of the relative paucity of field monitoring data from waste rock storage facilities (WRSFs) and the fact that laboratory test methods are not typically linked to specific field conditions; rather they are based on generic standardised methods and designed primarily to simulate accelerated weathering conditions that do not relate to field conditions in a linear manner.To address these specific issues the authors have in the last two years made significant progress in the development and deployment of advanced field monitoring equipment within numerous WRSFs. O’Kane Consultants (OKC) has previously reported the findings from data collected from these monitoring installations in a number of papers presented throughout 2013–2014. This valuable site data has subsequently been used by OKC as the basis to design and engineer advanced customisable site-specific kinetic leach columns at OKC’s geochemistry research laboratory. These columns represent an important advancement in kinetic column assessment methodology as they have been designed to replicate the field internal conditions within waste facilities.Key features of the columns include their capacity, size and technical specifications; including fully programmable solenoid-controlled air supply with variable flow and pressure control and in-line heating option, automated temperature control and monitoring, automated oxygen consumption and carbon dioxide production monitoring, and soil moisture/matric suction monitoring.This flexibility of the design not only allows for more accurate field-based assessment of pyrite oxidation rates (POR) but also assessment of the potential effectiveness of waste management options such as deposition within a reduced oxygen environment, for example, as simulations of reduced net percolation rates or oxygen ingress rates can be accommodated.CITATION:Pearce, S, Pearce, J and Barteaux, M, 2015. Advanced customisable leach columns – a new kinetic testing method to simulate site-specific conditions, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 137–144 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Frederick G. Clapp

SINCE oil journals commenced to feature the progress of Iraq pipe-line developments and since newspapers undertook to follow the discussions between a certain large oil company and an Asiatic nation, I have repeatedly been asked questions that are only answerable by setting forth the essential geographic and historical facts of concessions in that part of the world. In so doing effort will be made to correct erroneous statements made in various quarters: and mistakes herein are being kept as low in number as possible. Perhaps the best-known concession in the Middle East is the one of the Iraq Petroleum Co., covering the greater part of the portion of the kingdom of that name- lying east of the Tigris River. West of the stream is the concession of the British Oil Development Co., which takes in all presumed petroliferous areas in western Iraq. No other important oil concessions exist in that country, except for the lands of the Khanikin Oil Co., which operates in "Transferred Territories" on the border of Persia. East of and continuous with the Iraq fields are those of Persia where the Anglo-Persian Oil Co. holds the well-known D&apos;Arcy concession comprising three-quarters of the country, omitting the five northern provinces. This is the only valid existing concession in Persia, so far as known, except certain old firmans that permit development at Semnan in central Persia and possibly also certain regional grants to a French banking syndicate in eastern Mazanderan Province.

Jan 1, 1933