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By John R. Weeks, Dan McLachlan, John R. Lewis

DURING the operation of the iron blast furnace, aggregates of hard, infusible, yellow, cubic crystals frequently form in the interstices of the lining and on the hearth of the furnace. These were first examined by Wohler&apos; and were identified by him as a complex cyanonitride of titanium, having a formula Ti(CN)2 • 3Ti3N2, or more simply Ti10C2N8. However, recent investigators have suggested that this complex compound does not exist. Recent work by Hume-Rothery, Raynor, and Little2 on the carbide and nitride particles in titanium steels suggests that a complete series of solid solutions of the general type Ti<0+y>C0Ny exists between titanium carbide (Tic) and titanium nitride (TiN). Assuming this to be true, it seems likely that Wohler&apos;s cyanonitride of titanium is in reality a solid solution of 20 mol pct Tic in 80 mol pct TiN, .the nearly consistent carbide-to-nitride ratio probably resulting from temperature and pressure conditions in the blast furnace. The object of the present work was to investigate thoroughly this possibility of a solid solution by using the single-crystal methods of X-ray analysis. A spectrographic qualitative analysis of a sample of the yellow crystals furnished by the Geneva Steel Co. sh&apos;owed, in addition to the titanium, strong lines of vanadium and moderate to weak lines of iron, magnesium, silicon, aluminum, and calcium. The last five were probably slag impurities, but the vanadium was possibly included in the yellow crystals, owing to a great structural similarity of its carbide (VC) and its nitride (VN) to the titanium compounds, Table 11. A chemical analysis was made

Jan 1, 1952

By Angus M. Henderson, Charles R. Lilley

Underground mining at Kanowna Belle commenced in July 1998, using a sublevel open stoping method. The use of this stoping method necessitated the use of a cemented fill material for filling primary and secondary stope voids. A detailed engineering study recommended the construction of a cemented aggregate fill (CAF) system for Block A, in favour of paste fill. The CAF system consisted of a crushing and screening plant, a surface binder preparation plant and an underground fill station. Conventional underground dump trucks were used for CAF delivery. Since CAF plant commissioning in March 1999, 1.2 million tonnes of CAF have been placed underground. CAF segregation was the most significant quality control issue during CAF system operation. At the hangingwalls of filled stopes, CAF segregation sometimes occurred to such the extent that the resulting fill material was essentially uncemented coarse aggregate. This caused some CAF dilution during the extraction of adjacent secondary stopes. Numerous CAF were prepared on site for strength testing. A relationship has been formulated that allows estimation of the CAF uniaxial compressive strength in MPa, based on the cement content (c) and porosity (n), as follows. [ ] Practice at Kanowna Belle has confirmed that laboratory testing results cannot be applied for optimising the mix design of cemented rock fills that do not exhibit debris flow behaviour during placement. The grain flow characteristics and consequent marked segregation dominate the in situ fill strength. A detailed review of backfill requirements for the lower mine indicated that the total net present cost of CAF and paste systems was similar. Several significant operational advantages offered by a paste system have resulted in its selection for the remaining mine life. The construction of a paste fill system at Kanowna Belle is currently in progress.

Jan 1, 2001

By Larry Schneider

"0 ne of the incentives that led to the development of non-electric shock tube initiation systems was the desire within the industry to improve detonator safety. And to the extent that nonelectric initiators are immune to the hazards of stray current and radio frequency energy found on normal blast sites, an advancement in safety has been accomplished. However, as a cautionary note, it is important to realize that there are still many hazards associated with any initiation system. While some of these hazards may differ from those associated with electric detonators, others are identical to those associated with any type of initiation system. For instance, contrary to what some uninformedblasters may believe, lightning remains a hazard when using nonelectric initiation as well as electric initiation."

Jan 1, 1995

By C. R. Sandberg, L. S. Gournay, R. F. Sippel

The effect of fluid-flow rate and fluid viscosity on oil-water relative permeability determinations was studied using the "dynamic flow technique." In this work relative per-nleability curves were obtained for homogeneous small core .samples from several sandstorle outcrop form-utions. Radio-tracers were used for the determination of fluid saturation and for the detection of saturation gradients. Cobalt-60 in the form of cobaltous chloride was used as a water-phase tracer in some of the experiments. Iodine-131 in the form of iodobenzene and Mercury-20-3 in the form of mercury diphenyl were used as oil-phase tracers in other experiments. Flow rates for each phase were varied within a range of 2.5 to 140.6 ml/hr. Oil-phase vis-cosities under flowing condition,> were varied from 0.398 to 1.683 cp. The relative permbilities ob-tained were found to he solely a function of saturation and independent of flow rare, provided there was no .Saturation gradient induced in the core sample by "boundary effect." Even though equilibrium with re-sped to flowing conditions was obtained at the lower flow rates, where a saturation gradient exists, this equilibrium is of a "contingent"-type rather than the "steady-state" equi-librium implicit in the relative per-meability concept. The only effect of increasing the oil or non-wetting phase viscosity was to decrease the flow rate required for the elimina-tion of the boundary effect. Fairly good agreement between experimentally determined and calculated values of the boundary effect was obtained when the non-wet-ring oil phase was the only Flowing phase. INTRODUCTION In the characterization of reservoir rock, as well as in the solution of reservoir production problems, it is most desirable to have reliablc rela-tive permeability measurements for the rock and fluids of interest. Many techniques have been developed for the laboratory determination of the relative permeability of both large and small core samples. In varying degree, difficulties attend the use of all of the methods. Each of the methods requires the metered flow of fluids of known viscosity through the core sample under conditions wherein the pressure drop in the individual flowing phases can be measured or closely approximated. Since the relative permeability is a function of the saturation and distribution of the flowing fluids, some means of obtaining such information is also required. The laboratory determination of the relative permeability of a sample should give the same relative permeability saturation relationship that would exist if the sample were in place in the oil reservoir. The attainment of this objective is complicated by the fact that the use of small core samples for laboratory measurements is usually necessary. As a result, errors in measuring the relative permeability arise from boundary effects at either the fluid input or output ends of the sample; no significant boundary effect is anticipated at the sides of the sample normal to direction of fluid flow. At the input end of the sample a boundary effect exists if the flow fluids are not com- mingled as they would be in the reservoir. At the output end of the sample a boundary effect exists as a result of discontinuity of the capillary properties of the system. Here the flowing fluids leave the small flow channels and enter a collecting system having much enlarged flow channels. Thus, there is a tendency for the wetting phase to be retained by the core sample because of the attraction of the core sample for the wetting fluid. No reference is made to these boundary effects in either Darcy&apos;s equation or in the relative permeability concept. As a consequence the saturation effect peculiar to the input end of the core sample may cause an error in the effective permeability measurement, since some portion of the core sample must be utilized for commingling of the flow fluids. At the output portion of the core sample a saturation gradient or a saturation change along the axis of flow results. Since relative permeability is a function of fluid saturation, this saturation gradient may cause a variable permeability measurement, especially since extent and character of the saturation gradient can vary with fluid-flow rate. The most convenient method of minimizing the boundary effect, especially at the output end of the sample, is to flow the fluids of interest through the core sample at such high rates that the capillary forces arc insignificant as compared to the viscous forces involved in the fluid flow. Since recent work of a preliminary nature has indicated that fluid dispersion in the porous medium increases with the flow rate, the high flow minimizes the boundary effect at the input end of the core sample by enhancing the mixing of the fluids.

By J. L. Lytton, T. E. Tietz

The recovery of flour stress of recrylstallized are-cast molyhdenum after 10 pet prestrain at 150°C was studied for recovery temperatures of 725o 801o and 901oC. The yield phenomenon observed after recovery was such that the yield drop diminished and disappeared as recovery proceeded. A fractional flow-stress recovery parameter fr, was developed and it was shown that, independent of recovery ternperatzwe, equal f, values of about 0.16 produced superposition of stress-strain curves except for the initial yield phenomenon. The activation energy for low degrees oj recovery was found to he 32,600 cal per mole, in close agreement with a reported valzie for difjzdsion of carbon in molybdenum. For values of fr greater than about 0.15 where recovery was thought to predominate over strain aging, the activation energy varied from 43,600 to 82,500 cal per mole and increased with increasing recovery and recovery temperature. A 10 pet pre-strain shifted the ductile-brittle transition temperature, as indicated by tensile elongation, from 10°C. to about -22"C. A 100-hr recovery anneal at 801oC was shown to shift the transition temperature to about —5oC, the major shift occurring during the first hour of recovery. ThE recovery of cold-worked metals is accompanied by changes in the arrangement of the dislocations generated during cold work. In recent years, the use of transmission electron microscopy has allowed direct observation of some of the dislocation configurations formed, such as "tangles", networks, cells, subboundaries, and loops. These observations have recently been reviewed by Keh and Weissmann.&apos; Accordingly, some understanding has been gained concerning the nature of the dislocation rearrangements involved. The relationship between recovery and the decrease of mechanical strength, however, has only recently been explored. Previous efforts of the authors were directed toward investigating the decrease of tensile flow stress of aluminum and Al-1 pet Mg during recovery2 and the effects of concurrent elastic and plastic strain on the flow-stress recovery of aluminum.3 In addition, an investigation of the effect of four different solute additions on the tensile flow-stress recovery of aluminum has been made.4 Many important metals, however, have the bee crystal structure, e.g., iron, molybdenum, tungsten, vanadium, columbium, tantalum, and chromium. These metals might be expected to behave differently during recovery from those with other crystal structures for two reasons. First, the previous and present investigations of aluminum and its alloys have shown that tensile flow-stress recovery is strongly affected by foreign atoms in the lattice. In the bee metals, interstitial impurities are usually present and might be expected to have various effects upon both flow behavior and recovery. For example, heterogeneous yielding might occur during prestraining. The diffusion of these interstitials can also relock dislocations during recovery so that a yield point might be obtained upon restraining (strain aging). Second, some of the bee metals (e.g., iron, molybdenum, and tungsten) undergo the familiar structure-sensitive ductility transition and exhibit brittle fracture at suitably low temperatures. It is of considerable interest to determine the effects of recovery on the transition temperature of such metals. The purpose of the present investigation was to extend our knowledge of flow-stress recovery to the bee metals and to study the effects of recovery on the ductile-brittle transition temperature. Unalloyed recrystallized are-cast molybdenum was chosen as a test material, since it exhibits a well-defined ductility transition near room temperature. As in the previous studies, the degree of recovery was measured in terms of the decrease of tensile flow stress. Prestraining and restraining were carried out at 150°C to avoid the possibility of brittle fracture. EXPERIMENTAL PROCEDURE The are-cast molybdenum sheet used in this investigation was obtained from the Climax Molybdenum Co. of Michigan. It was 0.060 in. thick by 10

Jan 1, 1964

By Nelson B. Russell, Donald C. Bond

The effects of various antifreeze agents on the formation of hydrogen sulphide hydrate have been studied. On a molar basis the relative lowering of Tm (the maximum temperature at which solid hydrogen sulphide hydrate can exist in equilibrium with the given solution) for the various agents is: sodium chloride 1.00, calcium chloride 1.71, methyl alcohol 0.57, ethyl alcohol 0.68, ethylene glycol 0.73, diethylene glycol 0.73, sucrose 0.87, dextrose 0.71. On a weight basis the relative lowering of TM is: sodium chloride 1.00, calcium chloride 0.91, methyl alcohol 1.08, ethyl alcohol 0.89, ethylene glycol 0.69, diethylene glycol 0.41, dextrose 0.23, and sucrose 0.15. Introduction The solid hydrate of hydrogen sulphide, H2S.6H20,1 is in equilibrium with water and liquid hydrogen sulphide at 85°F at a partial pressure of hydrogen sulphide approximately equal to the vapor pressure Of hydrogen sulphide at that temperature. At temperatures below 85°F, in the presence Of excess hydrogen sulphide (greater than the amount required to react with the water present) the hydrate is in equilibrium with liquid hydrogen sulphide at approximately the vapor pressure Of hydrogen sulphide. In the presence of excess water, the solid hydrate is in equilibrium with liquid water, containing dissolved hydrogen sulphide, at a pressure lower than the vapor pressure of liquid hydrogen sulphide at the same temperat~re.2 The lower the temperature, the greater the difference between the decomposition pressure of the hydrate and the vapor pressure of liquid hydrogen sulphide at that temperature. Conditions conducive to the formation of solid hydrogen sulphide hydrate may exist in wells producing a gas containing a high percentage of hydrogen sulphide under high pressure, or in the lead lines from such wells. This paper gives the results of tests made with various antifreeze agents which might be useful in decomposing the hydrate or in preventing the formation of the hydrate of hydrogen sulphide Apparatus Fig , shows a diagram of the apparatus used. The sample under observation was contained in a glass tube 34 cm long, having a 6 mm id and a wall thickness of 2.5 mm. The lower end of this tube was closed- with a plug of butyl rubber. The upper end of the tube was connected to a diaphragm gauge, with a stainless steel diaphragm, a manometer, a vacuum pump, and a cylinder of hydrogen sulphide, The tube was held nearly horizontal, with the liquid resting along the lower side of the tube. It was found that when the tube was held in a vertical position, it broke with ex. plosive violence as soon as it became filled with solid hydrate. Presumably this was caused by the expansion which occurred on solidification of the hydrate. The difficulty disappeared when the tube was held in an inclined position during the tests.

Jan 1, 1949

By S. -H. Chang, C. -I. Lee, Y. -K. Lee

Based on results from triaxial compressive tests, an experimental damage model to simulate post-peak behaviours as well as nonlinear behaviours before peak strength was developed. In order to consider pre-peak behaviours, variations of elastic constants at each damage level were regressed by functions of confining pressure. In addition, post-peak behaviours were simulated successfully by using Hoek-Brown constants. As results, the experimental model could predict nonlinear behaviours, peak strengths and stiffness changes observed in experiments. Basé sur des résultats des essais compressifs à trois axes, un modèle expérimental de dommages pour simuler des comportements de poteau-crête aussi bien que des comportements non-linéaires avant la force maximale a été développé. Afin de considérer des comportements de pré-crête, des variations des constantes élastiques à chaque niveau de dommages ont été régressées par des fonctions de pression d&apos;emprisonnement. En outre, des comportements de poteau-crête ont été simulés avec succès en employant des constantes de Hoek-Brunes. Comme résultat, le modèle expérimental a pu prévoir des comportements non-linéaires, des forces maximales et des changements de riidité observés dans les expériences. Auf Basis der Ergebnisse des dreiaxialen Drucktests wurde das experimentelle Schadensmodell, das sowohl das nicht-lineare Verhalten vor der maximalen Stärke als auch das Verhalten nach der maximalen Stärke simulieren kann, entwickelt. Um das Verhalten vor der maximalen Stärke zu berücksichtigen, wurden die Veränderungen der elastischen Konstante bei dem jeweiligen Schadensniveau durch die Funktionen des begrenzten Drucks zurückgegangen. Außerdem wurde das Verhalten nach der maximalen Stärke unter Benutzung von Hoek-Brown Konstanten erfolgreich simuliert. Schließlich konnte das experimentelle Modell das nicht-lineare Verhalten, die maximale Stärke und die Veränderungen bezüglich der Steifigkeit während der Experimente voraussehen.

Jan 1, 2003

The Crown Minerals Act provides a new+framework for the management of Crown owned minerals and requires that regard be had for the principles of the Treaty of Waitangi. The Act requires the preparation of Minerals Programmes to achieve the Act&apos;s objectives of efficient allocation of rights and the recovery of a fair financial return on its minerals. Efficient allocation requires that a permit is allocated to the party which values it most highly. A fair financial return to the Crown must be considered in the context of the economic rent available from individual mineral projects, with the proviso that a nil return to the Crown as the owner of the resource will not be considered a fair return from the community&apos;s perspective.

Jan 1, 1992

By James W. Reil, Douglas A. Anderson

Blast vibration monitoring has generally been regarded as a necessary evil. New instrumentation and computer programs can change this. Rather than the usual trial and error methods to control vibration problems, an integrated, intelligent approach is possible. There is also the possibility of diagnosing problems with the blast vibrations.

Jan 1, 1989

By Eisele TC

Horizontal perforated-plate baffles were shown to improve the cleaning efficiency of a flotation column when processing coal from two sources. The baffles consisted of flat plates with holes large enough to avoid plugging problems, and they improved the washing efficiency by making the flow patterns in the column closely approach plug flow. Tests with varying amounts of baffle open area showed that the optimum was between 30 and 40 per cent open area, which effectively prevented backmixing without seriously reducing capacity. The baffled column had previously been tested under ideal conditions with good results (87 per cent pyrite rejection at 85 per cent combustiles recovery), and so the tests reported here were intentionally run with difficult-to-float coals to determine the benefits of baffling under adverse conditions. For an original coal feed containing 38 per cent ash and 3.23 per cent total sulphur, the baffled column could recover 84 per cent of the combustibles while rejecting 84 per cent of the ash and approximately 54 per cent of the pyritic sulphur. Without baffles, the column recovered 88 per cent of the combustibles while rejecting only 76 per cent of the ash and 45 per cent of the pyritic sulphur. Subsequent tests with a dye tracer showed that the baffles reduced entrainment by approximately a factor of five, while the recovery was reduced by only a few per cent. Overall, the loss of capacity due to the baffles was more than offset by the improvement in product quality.

Jan 1, 1993

By Liu Hongkang, M. J. Virnig, Yang Xianwan, Zhu Yun

A new technology for recovery of gold from loaded carbon developed by Kunming Institute of Technology is introduced. The principle, production practice and results are described.

Jan 1, 1993

By J. Wright, R. J. Tyler

Abstract-Changes in the pore structure of hematite pellets during reduction to iron were investigated under a variety of experimental conditions. Pore structures were determined by a mercury penetration technique. The reduction temperature was found to be the major influence on structure, the pore system being bimodal below 750°C and unimodal above 900°C. Pore sizes ranging from 0.04 to 20 [um] were observed in completely metallized pellets produced over the temperature range 650-1050°C. Gas composition and reduction rates also influenced the pore structure of the metallized pellets, although to a lesser extent than the reduction temperature. An apparent activation energy of 24 kcal/mole was derived for the pore formation ptocess.

Jan 8, 1978

By Rob Farnfield, Mike Kelly, Toby White

There are a variety of sources of dynamic stress which can affect a building and give rise to cracking. A two-storey house, situated in the middle of a surface coal mine was monitored for a period of 30 months to attempt to identify the major causes of cracking. The factors described as environmental include internal and external temperature, humidity, wind speed and direction, rainfall and water table level. These were monitored using a weather station and piezometer and recorded every 20 minutes. The other factors are vibratory and include normal household movement (walking, shutting doors etc.), vehicle vibration and blast vibration. All the significant vibrations in the house were recorded using four sets of velocity transducers and accelerometers.

Jan 1, 1993

By F. Seymour

A dynamic programming algorithm is presented that takes a series of nested phases, a fixed mining-rate schedule and a fixed plant-production-capacity schedule, and, from these, finds the mining and cutoff grade sequence that maximizes the net present value. This tool allows the mining engineer to quickly look at project sensitivity to various production capacities, commodity prices and costs. A description of the algorithm is given along with examples of how it has been used at Newmont Gold.

Jan 1, 1996

In 1976, The Zinc Corporation Limited Broken Hill set up a plant to re-process a hill of tailing (Mt. Keast) from the original treatment operations. With the likely disappearance of this source of feed in 1985, an investigation was initiated to determine what other feed sources might be available. This involved searching through old records and photographs as well as a subsequent drilling campaign. The paper briefly covers the history of treatment operations and describes, as a result of the information obtained, the likely future sources of feed.

Jan 1, 1983

By R. W. Raymond

RECENT literary labors have led me to the compilation of the following tables and estimates, which may possess interest for my colleagues in the Institute, and which are here submitted without comment.

Jan 1, 1876

By Freeman Bishop

The Interior Department has been in a state of disarray for many months. At first this was attributed to Interior Secretary Walter Hickel&apos;s inability to anticipate how his words would be interpreted by Press-Radio-TV. But then the already disquieted ernployees in the Department became aware that plans were afoot to take bits and pieces of the various antipollution programs from Interior; Health, Education and Welfare: the Atomic Energy Commission and other agencies and lump them together into a new Federal agency. Interior, many predicted, would be a shell of its former robust self. Hardly had this rumor started to add to employee uneasiness before the other big shoe hit the floor. The new rumor had it that the Bureau of Mines was being stripped of most of its research functions and that the Office of Coal Research and allied research groups would be abolished altogether.

Jan 1, 1970

By Nicholas J. Grant, Laszlo J. Bonis

Two dilute nickel alloys in each of the systems Ni-Al, Ni-Ti, Ni-Cr, and Ni-Si u:ere internally oxidized at 700° to 900°C for time periods up to 100hr to establish the oxide particle size, depth of oxide penetration, and the change in oxide particle size with depth. Fine (-270) mesh alloy powders were then intevruzlly oxidized, hydrogen sintered, compacted, and extrmded, yielding bar stock for tensile tests at room temperature and creep-mpture tests at 815° to 1093°C. Recrystallization studies were made up to 1400OC. ReCENT studies have clearly indicated that oxide dispersion strengthened alloys exhibit outstanding elevated temperature properties, espe- cially in long-time tests. Certain structural parameters must be observed to achieve optimum properties, namely, micron or submicron interpar-ticle spacing, submicron oxide particle size, and a high level of stored energy.&apos;-5 A number of processes have been utilized to obtain the desired structures, but certain of them appear to offer greater promise. Thus far the most promising method is the internal oxidation of dilute alloys consisting of a relatively noble solvent metal and a readily oxidizable solute element.3&apos;6)7 Several important principles governing internal oxidation have been established in earlier studies;&apos; however, these principles are as yet not adequate to permit alloy development studies. Much of the earlier work was performed on relatively coarse wires or in idealized systems. As a result, there are still a number of unanswered questions which require considerable additional work: a) How does oxide particle size change with depth of penetration of the oxide? How does this vary with the specific type of solute element? b) What is the effect of solute content on the average oxide particle size?

Jan 1, 1962

By Guy Brouillard

A bow-tie analysis is a safety review methodology that uses a structured approach that can be qualitative or quantitative to document the potential risk of safety incidents. The bowtie diagram itself provides a powerful graphical representation of the threats barriers, events, and recovery measures which are readily understood by the "non-specialist". This presentation will discuss how mining operations can use this valuable tool within their operations to understand the risks and apply the appropriate safeguards toward reducing these risks to acceptable levels.

Jan 1, 2014

By Eduardo Berger

This paper describes a mechanized loading system, the HYDRODOSE, which allows the use of pumpable emulsions in underground mining. It also describes a pumpable emulsion explosive for small diameter holes, HYDROMITE PDB. Included are test results carried out in two Chilean underground mines.

Jan 1, 1991