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By E. O. Karenna, A. D. Smigelskas

This is the third paper in a series on the diffusion of zinc in alpha brass.' At the time of the first paper it was accepted that diffusion in a substitutional type of solid solution depended upon an equal interchange of solute and solvent atoms across the diffusion interface (or past a given lattice reference point). Discrepancies in the size of the areas under the diffusion curves on each side of the interface, if observed, were explained on some other basis than the fact that the solute atoms might cross the diffusion interface without an equal number of solvent atoms diffusing across the interface in the opposite direction. The second paper presented evidence indicating that zinc atoms in alpha brass diffuse across the interface more rapidly in one direction than the copper atoms diffuse across the interface in the opposite direction. This phenomenon forced the interface to move in the opposite direction of the diffusion of zinc atoms to provide space for the additional zinc atoms dissolved in the alpha brass. That the interface and columnar grain structure on one side would remain intact during this mass movement was not expected; how ever, it is gratifying that they did. While the evidence was sufficiently satisfying to the author, it was decided that additional experiments were in order to prove that zinc diffuses more rapidly than copper in alpha brass. It is the purpose of this paper to present the results of these experiments. Procedure A bar of 70-30 wrought brass was selected, to avoid the relatively large volume change in going from beta to alpha brass as in the previous investigation. A bar 7 in. (18-cm.)* long and about 3/4 in. (1.9 cm.) wide was surface ground and polished with abrasive paper on plate glass to 0.4184 0.0002 in. (1.062j + 0.0005 cm.) thick. Six0.00j-in. (0.013-cm.) diameter molybdenum wires, chosen because of their very low solubility in coppcr and alpha brass, were strctched lengthwise along each of the two plane surfaces. Glass tubes placed at right angles to the wires every 1/2 in. held the wires tightly against the brass. The sample was then emersed in an acid copper sulphate plating bath and electroplated to a depth of about 0.020 in. (0.050 cm.) copper on all sides. The glass tubes were no longer necessary to hold the molybdenum wires in place and were removed. The sample was then electroplated to a depth of

Jan 1, 1947

By Alan L. Sangster

Abstract -Auriferous, bedding-parallel veins occur in zones of carbonaceous, argillaceous and sulfidic turbidites in the Lower to Middle Cambrian sandy flysch of the Goldenville Formation. The ?34S values for vein and wall-rock arsenopyrite and pyrrhotite, and for regional pyrite and pyrrhotite, are highly positive. The values are similar to those from Cambro-Ordovician sediment-hosted deposits of other types, and display trends that increase upward in the stratigraphic sequence. The similarity in composition of vein and wallrock sulfides indicates a seawater-sulfate source for sulfur, derived from the enclosing rocks at the time of vein formation. The upward increase in ?34S values is consistent with closed system sulfate reduction in the anoxic portion of a stratified water-column. Published ?18C and ?18O values for Meguma Group vein carbonates are unlike those of other gold-vein carbonates, but are similar to those of diagenetic-metamorphic carbonates from the Meguma Group and elsewhere. These data indicate that the source for the vein-related sulfides and carbonates may be the host strata; possibly the arsenic and gold were derived from the same source.

Jan 1, 1992

By Alan L. Sangster

Auriferous, bedding-parallel veins occur in zones of carbonaceous, argillaceous and sulfidic turbidites in the Lower to Middle Cambrian sandy flysch of the Goldenville Formation. The 0348 values for vein and wall-rock arsenopyrite and pyrrhotite, and for regional pyrite and pyrrhotite, are highly positive. The values are similar to those from Cambro-Ordovician sediment-hosted deposits of other types, and display trends that increase upward in the stratigraphic sequence. The similarity in composition of vein and wallrock sulfides indicates a seawater-sulfate sourCe for sulfur, derived from the enclosing rocks at the time of vein formation. The upward increase in ?34S values is consistent with closed system sulfate reduction in the anoxic portion of a stratified water-colurnn. Published ? 13C and ? 18() values for Meguma Group vein carbonates are unlike those of other gold-vein carbonates, but are similar to those of diagenetic-metamorphic carbonates from the Meguma Group and elsewhere. These data indicate that the source for the vein-related sulfides and carbonates may be the host strata; possibly the arsenic and gold were derived from the same source.

Jan 1, 1992

By Larry M. Southwick

Processing of ores to recover metals usually generates large amounts of waste materials, such as rejects from concentrating operations, tailings from leaching and slags from smelting. These wastes often contain substantial amounts of iron and other metals, recovery of which are often considered to be of commercial value. Earlier versions of this paper investigated a number of processes built to recover iron from a variety of copper processing residues. This paper will extend that coverage to residues from nickel/cobalt, aluminum, asbestos and oil shale processing and coal plant fly ash. Products of interest are iron, ferroalloys, magnesium and aluminum. While none of these processes achieved long-term commercial success, their efforts cover the gamut of problems that must be addressed in treating dirty and difficult materials to recover generally low-value products. An Adept is an alchemist who can create a Philosopher's Stone, which could transmute base metals into gold. In 1701 in Berlin one Johann-Freidrich Böttger, a nineteen year old apothecary's apprentice, told King Frederick I that he could discover how to make the Stone. He failed and fled Frederick's wrath to Poland. He failed again, and King Augustus II threw him in jail. Then, in 1709, he discovered instead the secret of making Dresden china, certainly a more practical search. His failures in alchemy led to the nickname Adeptus Ineptus.

Jan 1, 2004

By R. D. Hagni

The following is a case study illustrating the use of thin sections and polished sections of crude ore to predict metallurgical response. By examining polished sections of the metallurgical products, the textural and mineralogical reasons for unsatisfactory separation can be explained. An area of oxidized Negaunee Iron-Formation located south of Negaunee, Michigan, in the Marquette Iron Range, has been considered for roast reduction-magnetic separation. Preliminary metallurgical studies and subsequent pilot plant testing produced varied results. These results prompted this microscopic study which began with an examination of 126 thin sections and 82 polished sections prepared from 126

Jan 1, 1967

By S. K. Kawatra, S. A. Moffat, K. A. DeLa’O, T. C. Eisele

It was observed that the efficiency of some autogenous grinding circuits was dependent on temperature, with the energy-efficiency of the grinding process decreasing in the winter months, accompanied by an increase in critical-size production. Several possible causes of this phenomenon were suggested, including: • Increased brittleness of the ore during blasting in the pit at low temperatures, leading to increased levels of internal cracking that would lead to rapid breakage to critical size in the mill; •Brittleness changes of the rock in the mill; and • Changes in the durability of the rock caused by either formation of ice on the surface, or freezing of water inside the pores and cracks of the rock. To determine which mechanisms were occurring, drop tests were carried out using frozen and unfrozen rock with varying degrees of porosity, both dry and water-saturated, and which had been blasted for mining in summer and in winter. These tests showed that there was no difference between the summer-blasted ore and the winter-blasted ore, and that durability changes in dry rock over the temperature range from 25ºC to -25ºC were negligible. However, water-saturated rock showed an increased resistance to breakage upon freezing, particularly when the rock was highly porous, or when a layer of ice formed on the surface. Seasonal changes in the durability of rock in grinding are therefore due to formation of ice in and around the rock.

Jan 1, 1995

By A. Koski

A pond rehabilitation and environmental education project were proposed by Cleveland-Cliffs Michigan Operations (CCMO) and approved by the Michigan Department of Environmental Quality (MDEQ) and the United States Environmental Protection Agency (USEPA) as partial fulfillment of conditions for a stream mitigation permit. The goals of the project were the rehabilitation of a pond on a tributary of a local trout stream, enhancement of public access and appreciation, and the initiation of a site-based environmental educational curriculum. Cleveland-Cliffs undertook a suite of actions to rehabilitate a pond created by a previous mining operation in 1912 and make accessible to local schools the aquatic and riparian ecosystems. Cleveland-Cliffs partnered with the local governmental unit and two local school districts. The rehabilitated pond and riparian zone provide an accessible natural area that local residents can use for such activities as hiking, biking, walking, fishing and nature study. Vegetative enhancement includes the planting of native shrubs, wildflowers and showy herbaceous plants in the pond, on the riparian fringe and the surrounding area. An interpretive trail was developed around the pond with signs created by a local master watercolor artist. Local schools built and installed picnic tables, benches and a kiosk. Cleveland-Cliffs created pond lesson plans tied to the Michigan Curriculum Framework, developed inexpensive teaching kits and hosted a workshop for teachers from nine local schools. Classes regularly utilize the pond during the school year conducting environmental studies. Nesting boxes, wildflower gardens, bat houses, frog deformity surveys and water quality studies are a few of the activities that classes have conducted at the pond.

Jan 1, 2007

By T. C. Sandford

Thermal conductivity measurements of intact rock specimens do not reflect the effects of natural rock discontinuities, and large scale insitu tests are location specific and costly. To allow extrapolation of laboratory measurements to rock masses with discontinuities, the effects of discontinuities on rock thermal conductivity were measured using divided-bar techniques. The introduced discontinuities lowered the thermal conductivity in all cases, and conductivity decreased systematically with increasing roughness of the discontinuity. Conductivity increased with increasing pressure on the discontinuity.

Jan 1, 1984

By Mats Keisu, Bengt Niklasson

The Sofia project has increased the level of knowledge and technique within tunnelling, drifting and contour blasting.

Jan 1, 1992

By C Wu, H Chen

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.The Halasu porphyry copper belt, located in the East Junggar basin bounded by Chinese Altay to the north and the Tianshan mountains to the south in the Central Asian Orogenic Belt, is one of the major porphyry copper belts in Xinjiang province, north-west China. Combined with previous studies in this area, the magmatism can be divided into three periods: pre-mineralisation activity of 390 Ma syn-mineralisation activity of 380–370 Ma post-mineralisation activity of 360–330 Ma.Through the comparison of zircon chemistry from ore-bearing and barren syn-mineralisation intrusions, negative correlation was identified between Ti-in-zircon temperatures and oxygen fugacity, corresponding to the fact that late-stage syn-mineralisation granitoids contain high water content, high oxygen fugacity and low temperatures with higher mineralisation potential. In addition, the relative low initial 87Sr/86Sr ratios, high eHf(t) and eNd(t) values and mantle Pb isotope characteristics in this study support that the magma forming these intrusions was probably derived from juvenile crust generated during subduction-accretionary processes.CITATION:Wu, C and Chen, H, 2015. Zircon trace elements and Sr-Nd-Pb-Hf isotope systematic of the Halasu porphyry Cu belt, north-east Xinjiang, China, in Proceedings PACRIM 2015 Congress, pp 637–640 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By E. Richard Randolph, Rolland L. Blake, Stanley H. Ward, Gerald J. Anderson

During the last 30 years the inductive electro- magnetic method has been used chiefly in the search for massive sulphide mineralization. This application has met with varying degrees of success and in recent years has resulted in discovery of several large orebodies. Little has been written concerning its use in exploration for soft iron ores, but one of the present authors has reported on experiments with massive magnetic deposits. To augment the exploration tools available to geologists in delineating iron orebodies, Cleveland-Cliffs Iron Co. and McPhar Geophysics Ltd. undertook in 1953 to apply the inductive electromagnetic method to Cleveland-Cliffs properties in the Lake Superior region. As a result of this project, equipment has been developed that enables simultaneous transmission of two audio frequency waves, and the field technique and interpretative procedure involved have furthered exploration in the district significantly.

Nov 1, 1955

By P. Malozemoff

I have no objection to using mathematics in the value appraisal of properties. The factor that is not emphasized in the paper is that very few important properties have a lifetime that reflects the initial ore reserves of the property divided by the rate of production adopted. In the majority of cases, major properties mine out several times the initial reserves. How much more will be mined out is not known, and only exceptionally gifted geologists can predict that additional reserves will be found. There is the further factor of metals price, which, over the long term, is not predictable. Another factor vitiating making calculations on initially established ore reserves is the speculative nature of exploration success. In my judgment, the life of a property, in addition to an established ore reserve, should include ample time for exploration to find additional reserves. The likelihood of additional reserves is based on the geological promise of the general area where the mine is established. This is especially important because of various risk factors associated with small orebodies, the economic life of which is about five to seven years.

Jan 1, 1993

By Willard P. Ward

I DESIRE to put on record a fact in relation to the effect of manganese on pig iron which I have never seen in print, and which may, perhaps, not have been observed by anyone except myself. In 1875, while experimenting on the production of ferromanganese in a blast furnace, I had burdened the furnace with a charge which I calculated would produce a 15-per cent spiegel. The furnace was very hot, having been running for a couple of days on a very light burden, and making a burnt iron, preparatory to the experiment I proposed to make to produce a high grade of spiegel. I calculated that the charge would begin to work in the furnace in about twelve hours after it was put on. After the lapse of that time I commenced to watch the furnace carefully, but found little or no. change in the appearance of the metal, although there was a very decided change in the cinder, showing that the manganese ore had come in work. The iron was quite gray and very tough. The character of the cinder was good for a spiegel cinder, and I could not imagine where the manganese was going to, as it (lid not appear to be in either metal or cinder in anything like the quantity indicated by the charge. The next morning things were still in, the same condition. The furnace was very hot, the cinder good, and the iron very gray. I was then sorely puzzled. I had never heard of a gray iron with over 4 or 5 per cent, of manganese, and had no notion that an iron with more manganese could be gray and tough. With great difficulty a piece for chemical test was broken from a pig. Not less than a hundred blows from a heavy sledge were required to break it off I took the specimen to the shop and directed that some borings from it should be brought to the laboratory, as soon as possible, whither I myself at once repaired -to put things in readiness for a rapid manganese determination. In about half an hour the machinist came in with the iron specimen in one hand and about, a dozen blunted and broken steel drills in the other, saying that it was impossible to drill the iron. There were several little depressions in the iron, which was malleable enough to be indented by the point of the drill, but not a chip had been cut from it. The metal was never subjected to further physical tests. A chip broken from

Jan 1, 1882

By Michael S. Wieland

This report discusses measurement techniques utilized in and trend results obtained from research on delay blasting malfunctions in underground coal shots at the U.S. Bureau of Mines. Charge malfunctions occur during delay blasting in underground or surface mines, rendering the explosive operations more hazardous and less productive. Modern instrumentation techniques reveal several types of reduced charge performance, resulting from cross-hole interactions. Two receptor (wave-target) charge malfunctions were detected in fourteen shots that were undeniable. There were other receptor charges that exhibited under-performance by registering out-of-tolerance or noticeably reduced detonation rates. Delay blasting generates tremendous shock waves and rifting forces that fracture and heave the surrounding stratum and unfortunately damage remaining unfired charges. This report contains two graphs, representing roughly 1% of total records, that show donor (wave-source) charge shock waves and rift (reaction-to-heave) compressions. These debilitating wave impacts precipitate modes of reduced charge performance ranging from weak detonations or misfires to sympathetic detonations. As recognized from previous research, impaired charges react poorly, perform less useful work, and yield fumes with atypical higher toxicity.

Jan 1, 1995

New method for processing of copper and nickel production feed has been developed and tested at pilot unit having 10 t/hr capacity. The process allows single-stage treatment of ore feed including that with high magnesium oxide content and resulting in the production of rich matte, high-grade matte, or moralised alloy for further leaching, as well as dump slag and off-gasses suitable for production of elemental sulphur, liquid sulphur dioxide, or sulphuric acid. Tests results and principal technical and economical parameters are presented.

Jan 1, 2006

By Clint Judisch, Ty Jahn

Nestled at the apex of Big Sky Resort's Lone Mountain, in Big Sky Montana, (3,400 m), making it the highest scenic overlook in the state. Boasting breathtaking views that span over 20 different mountain ranges, this engineering marvel replaces the original tram after a 28-year run that exceeded the original design life. The new tram consists of a top and bottom terminal, as well as a singular support tower that sits about three quarters of the way up the span. The project team consisted of Condon-Johnson & Associates as the general contractor who self-performed the construction of the foundations for the top terminal and tower, involving intricate processes such as blasting, excavation, drilling, installation of micropiles and tiebacks, and concrete. Doppelmayr manufactured and supplied the tram car plus components. Garaventa designed and erected the metal tram structure, built the ropeway and tram stations.

Apr 1, 2024

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By P R. G Milne

A risk-based approach to optimising pit wall slope angles was trialled in the design of a 60m deep open pit in extremely weathered and distinctly weathered materials in the Kalgoorlie area. The pit used for this approach was Stage 1 of a three-stage open pit project. The Stage 3 pit will require long term stability, as it will contain the portal for a long life underground project. Information from failures induced by steeper wall angles used in the Stage 1 pit would be valuable in predicting and preventing long-term stability issues in Stage 3. In this approach, the pit wall slopes are based not on the normal factors of safety, but on the assessment of the probability of failure and the direct and indirect costs of dealing with the failure when it occurs. In this example, the benefits and risks of adopting steeper wall angles were compared in a series of graphs. These charted the increasing probability of failure and simultaneous decreasing factors of safety with increasing pit wall slope, and the range in the possible volumes of circular failures for increasing wall angles. These were brought together in a graph showing the potential excavation savings (in BCM) and the probable cost of a failure (probability of failure times the probable volume of the failure). The resulting pit design was based on the project Mining EngineerÆs semi-quantitative assessment of where and when a higher risk of failure was acceptable and where it was not acceptable as it may have unduly affected the integrity of haul roads or production. The design incorporated wider than normal berm widths to accommodate anticipated failures and to enable modification of the wall configuration if required. Several re-designs were required during the life of the project in response to aggressively induced failures. It is considered that this risk-based approach provides a practical route to optimal pit design and operation but it requires an experienced, dedicated and efficient mining team for it to be implemented with benefit.

Jan 1, 2003

By R. J. Gochin, G. D. Schena

Mineral processing options and technical innovations should be financially assessed. Indeed technical feasibility alone does not offer an adequate process selection criterion. An appraisal by the use of engineering economics principles leads to a more efficient evaluation and selection of feasible mineral processing solutions. Financial consequences of different options synthesised by profitability indices allow better decision making. Selected examples derived from real world problems are used to illustrate the potential of engineering-economics methods applied to mineral processing.

Jan 1, 1995

By R. U. Fitting, A. C. Bulnes

Field experience with limestone and sandstone production indicates the existence of wide differences between the reservoir behavior of these two types of formation. Little attention appears to have been given to the separate study of the flow of fluids and the retention of fluids in limestones. This paper presents data and arguments to demonstrate the existence of a difference between the two types of formation, and urges the separate intensive investigation of limestone reservoirs. AH experimental data presented pertain to dolomitic limestone formations in west Texas and New Mexico. Two kinds of Porous media are recognized— intergranular and intermediate. Intergranular rocks are those in which the porosity and permeability are determined by the geometrical properties and the sorting of the sedimentary units; intermediate rocks, those in which there is no direct relationship between grain properties and the porosity and permeability. Limestones in general are intermediate media. The partial relationship between porosity and permeability of any class of Porous media is represelried by an area of .finite extent and definite shape on the permeability-porosity plane. The horizontal and vertical variations of porosity and of permeability in limestone and sandstone formations are discussed and compared. Comparisons are made of connate-water content, the relative permeability-saturation relationship, and capillary phenomena in the two kinds of rocks. A number of tentative conclusions are drawn relative to the reservoir properties of lime- stones; in particular, (I) dolomitic limestones are oil bearing and apparently are oil productive in zones of permeability less than 0.1 millidarcyj and (2) primary depletion (by gas expansion) oil saturations may be lower in dolomitic limestones than in sandstones. Introduction It is well known that the reservoir performance of limestones displays numerous irregularities when compared with that of sandstones, and that the departures from "normal" behavior of limestones are more frequent and generally more marked than in sandstones. This is particularly true of fractured limestones and those that have undergone considerable development of secondary porosity' A review of the literature of production research published during the past 15 years reveals a startling absence of theoretical and experimental investigations directed specifically toward explaining and predicting the performance of limestone reservoirs, even. though such problems as the prediction of water encroachment and the estimation of ultimate recoveries continue at the "inspired guess" stage. By far the greater part of the experimental data reported pertain to measurements on sandstone core samples, while the theoretical studies, almost without exception, are developed from the assumption of an ideal porous medium and therefore seldom are applicable to limestone formations. The chief cause of this situation appears to be the common belief that, to all practical intents and purposes, sandstones and the majority of producing limestone formations

Jan 1, 1945