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By J M. F Clout, E Donskoi

The ability to design a beneficiation process for a new orebody based on particular feed characteristics is a powerful and practical tool. A new technique has been developed where beneficiation outcomes can be calculated by combining feed size-by-size chemical analysis, mineralogy, liberation and particle characteristics with a series of simple theoretical unit separation models rather than a simple mass balance approach or an exhaustive beneficiation test program. The new technique provides the ability to rapidly identify ore types that have the potential to meet product specifications whilst also rejecting others that will not meet specification even if a perfect separation was achieved. Beyond the broad scale decision making process, practical mineral separation curves from actual plant data can be used to more closely simulate the proposed process. This approach reduces the amount of laboratory and pilot plant work necessary by targeting what process stages will be required, increases early rejection of uneconomic options, identifies problematic ore types or unit operations and is a step towards estimation of final grade and recoveries achievable in potential circuit configurations.

Jan 1, 2004

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By Bhudeo N. Sinha, Paul Dean Proctor

Heavy metal contents in stream waters, sediments, and selected aquatic algae were determined for the upper Meramec River basin, Missouri, of 3905 km2 (1508 sq mi) area and site of the proposed and controversial Meramec dam and reservoir. Six distinct drainage areas within the basin are: (1) a lightly industrialized and farm area, (2) a primitive forested- ranch area, (3) an area which includes the Northern New Lead Belt, (4) the westward drainage of an old and extensive barite mining area, (5) the main trunk of the Meramec River, and (6) short north-divide tributaries of the Meramec River. Lower Paleozoic sediments rest nonconformably upon eroded and hilly Precambrian igneous basement. This locally rises as major inliers and also makes up the St. Francois Mountains to the east. Major lead, and lesser zinc, copper, cobalt, and nickel mineralization occurs in the buried Cambrian Bonneterre dolomite. Residual barite is present along the eastern fringe of the basin and is derived from the Potosi formation. Some 62 water samples, active stream sediments (AS), bank samples (BS), and 11 selected aquatic algae samples were collected in the various drainage areas and analyzed for copper, lead, zinc, cadmium, nickel, arsenic, and mercury contents. Heavy metals in water have a maximum range of 1-120 ppb (parts per billion), and this for zinc. The AS and BS sediments have orders of magnitude greater acid leachable metal contents in the -80 mesh fraction, with lead hawing the greatest range of 11-1028 ppm. Heavy metal content of stream-algae approaches that of the sediments in which they grow. Most anomalous heavy metal accumulations occur near mining and milling activities and in the streams draining such areas. Significant distortions of the primary dispersion pattern militate against geochemical exploration for hidden ore zones, but do demonstrate the mining, milling, and smelting activities of man, and sporadic mineral occurrences in younger horizons.

Jan 1, 1980

The discovery of economic uranium miner alisation in unique geological conditions at Yeelirrie, 700 km NNE of Perth, presented Western Mining Corporation Limited with a num- ber of sampling and evaluation problems. Carn- otite mineralisation occurred in a porous cal- crete-clay lithology in close proximity to the water table; background information on such a deposit was non-existent and sampling in these conditions could be difficult. The deposit was sampled initially by aug- er drilling with X-ray fluorescence analysis of drill cuttings, followed by reverse circulation and diamond drilling with analyses by X-ray fluorescence and gamma logging of the holes. Two costeans provided lithological and grade distribution data and mining experience in the deposit. Spoil from the costeans was stockpiled according to location in the first costean and according to location and grade in the second costean. Samples from the various stockpiles were analysed by X-ray fluorescence. No. 1 costean was extensively sampled by channel sampling of the walls and by pit sampling of the floor of the benches of the costean by back hoe. No. 2 costean was sampled by Geiger counters mounted in T-probes and by the gamma logging of auger holes to establish the valid- ity of the T-probe results. Samples were taken

Jan 1, 1976

By Jaime E. Sepúlveda

Semiautogenous grinding (SAG) operators have been realizing the very significant impact of fresh feed particle size distribution on the mill grinding capacity. In actual practice, this impact may be quite difficult to assess because of the natural process variability that may also involve- concurrently other critical factors such as ore hardness. Recognizing the limitations of the empirical approach, the current publication proposes the use of mathematical models and simulators to explore and assess the net effect of feed particle size only, independent of any other factors. The simulation analysis here reported provides a basis to claim that the size distribution of the particles being ground (simply characterized by a % - 2" or similar measurement) is one of the most relevant controlling variables of the overall mill performance, regardless of the SAG circuit configuration.

Jan 1, 2005

By William Y. Mo

The OPEC oil embargo and the subsequent higher prices for oil have drawn public attention to the critical problems associated with security of supply of oil and other key industrial materials, especially nonfuel minerals. This concern has stimulated the interest of decisionmakers in analyzing policy options to cope with the emergency situations resulting from a sudden foreign- induced supply interruption or a cartel price increase. Several policy options are available to counteract foreign-initiated embargoes or cartel price actions. The type of response will differ depending on the commodity action intiated. A mathematical model that measures the impact of foreign-induced commodity actions on the domestic economy is formulated. The paper also presents a computer method that can be used to determine the optimum policy response to counteract such actions.

Jan 1, 1977

By Masaru Nakamizu, Tetsuya Fujii, Tatsuo Saeki, Ken-ichi Yokoi

Methane hydrate, a solid compound formed from methane and water, occurs naturally in permafrost regions on-land and in deep continental slopes offshore and has been examined as future energy resources. The existence of methane hydrate in the eastern Nankai Trough region, offshore Japan, was confirmed by drilling the MITI well “Nankai Trough” in 1999. Aiming commercialization of methane hydrate production, the Research Consortium for Methane Hydrate Resources in Japan (MH21, core associations: JOGMEC[*1], AIST[*2] and ENNA[*3]) under METI [*4] has been executing geological and geophysical surveys around the eastern Nankai Trough since 2001 as a nation project.

By R. W. Heckel, R. A. Tanzilli

Treatment of the finite, diffusion-controlled, two-phase, moving-interface homogenization problem has been carried out by numerical methods for a wide range of input parameters. Solutions have been obtained for planar, cylindrical, and spherical diffusion geometries. The effects of parameters such as the interdiffusion coefficients (concentration-independent) of- both phases, the concentrations (time-independent) of each phase at the interlace, mean composition, initial size of the dissolving- phase, and initial composition of- the two phases are considered. The results are displayed to show both the position of the interjace and the degree of homogenization (expressed in terms of concentration at the matrix phase symmetry boundary) as a function of diffusion time. Typical exaw~ples to which the results may be applied are discussed. A limited number of exact, closed-form solutions to the multiphase, diffusion-controlled, moving-interface problem exists in the literature, e.g., Refs. 1 to 7. The exact, closed-form solutions generally consider the outermost phases to be infinite in extent and also assume an interfacial velocity function. It is through use of such boundary conditions that closed-form solutions are readily obtained. An extensive literature also exists on numerical solutions to the mathematically analogous solidification problem, e.g., Refs. 8 to 12. In addition, a numerical solution involving mass transfer with spherical interfaces and infinite boundaries has recently been carried out.13 A practically important class of diffusion problems exists, however, in which the boundaries of each phase away from the interface are finite. For example the finite boundary condition arises when one sets up a model for analyzing the homogenization behavior of two-component powder compacts in two-phase systems or for studying the solution behavior of precipitates. Although exact, closed-form solutions have as yet not been found to this class of problems, solutions are possible using numerical methods. The purpose of this paper is twofold: 1) to describe a numerical method for treating the two-phase, diffusion-controlled, moving-interface problem involving finite boundaries with planar, cylindrical, and spherical interfaces; 2) to present the results of a parametric study which identifies the role played by each variable appearing in the analytical model. R. A. TANZlLLI,Student MemberAIME,onleaveofabsence from the General Electric Co., Re-entry Systems Department and A. W. HECKEL, Member AIME, are Graduate Student in Materials Engineering, and Professor, Department of Metallurgical Engineering, respectively, Drexel Institute of Technology, Philadelphia, Pa. Manuscript submitted May 6. 1968. IMD MATHEMATICAL MODEL The three geometries analyzed are shown in Fig. 1. For each configuration a symmetry element is shown, across whose boundaries the mass transfer is zero. Mean composition, C, and the characteristic solute-rich phase half-thickness (or radius), 1/2, are the independent variables while the characteristic symmetry element half-thickness, L/2 (measured from solute-rich phase center to the matrix phase plane of zero mass transfer), is a dependent variable. The symmetry element for a planar interface accurately represents a real diffusion situation involving the stacking of symmetry elements of constant size. Because cylindrical and spherical symmetry elements of constant size cannot be stacked to fill space, the meaning of the dimension, L/2, for these situations may be considered in terms of the following approximations: and where NA is the number of parallel cylindrical elements per unit area on a surface normal to the cylinder axes and Nv is the number of spherical elements per unit volume. The model consists of a solute-rich phase matrix phase composite of limited mutual solubility. The concentrations at the interface are assumed constant with time; no assumption of local equilibrium at the interface is necessary except for the case where the

Jan 1, 1969

By Ignacio González, Marcos Monroy, Valerie Bertrand, Roel Cruz

Results of an electrochemical study using carbon paste electrodes of pyrite and pyrrhotite samples suggest that the mineralogical impurities associated with these minerals are the determinant factor on their reactivity under alteration systems. These results were supported by mineralogical and leachate chemistry data from leach cell tests run on these samples. Pyrite reactivity decreases in the presence of associated impurities due to a galvanic effect whereas pyrrhotite reactivity appears to be controlled by the formation of a passivating layer, which overcome impurities effect. Electrochemical responses of sulfide-bearing samples provided valuable information on the prediction of ARD generation.

Jan 1, 2000

By R. Y. Wan

Recent research efforts have shown have shown selective solvation extraction of a gold cyanide ion-pair complex from alkaline cyanide solution is possible with organic phosphorus esters. These alkyl phosphorus esters such as tributyl phosphate (TBP) and di-n-butyl n-butyl phosphonate (DBBP) can selectively load gold to rather high levels, even in excess of 30 gpl. However, traditional stripping techniques are not particularly effective. In this regard, gold recovery by direct electrolysis of the organic phase has been found to be an interesting possibility. Further, the rate of direct electrodeposition from the organic phase can be improved significantly by using an aqueous/organic mixture. Direct electrodeposition of sheet gold from loaded DBBP was successfully accomplished at a current density of 8x10 4 amp/cm2 and 55°C from such a two-phase mixture with the aqueous phase as the continuous phase. No appreciable degradation the DBBP was found after 5 cycles of extraction and, electrodeposition. Finally, the applicability of the process strategy for an industrial situation was demonstrated by the successful treatment of waste gold cyanide electroplating solutions.

Jan 1, 1986

Aspects of sampling are becoming more complex, involving a correct statistical approach to collection as well as geological and possibly pedological control. Advanced chemical techniques and techniques of rapid analysis need to be understood. Results may require statistical analysis. The elementary aspects of sampling still need constant attention by those controlling a programme of sampling. No one person will have sufficient knowledge of statistics, geology, pedology and chemistry to be fully conversant with all the aspects of sampling but, by developing a correct approach, problems can be identified and solved.

Jan 1, 1976

By Edward E. Johnson

The U.S. economy boomed in 1965, completing its fifth consecutive year of expansion. Although the advance was somewhat irregular, previous records for production, sales, employment, and income were topped. During the first few months of 1965, as the economy recovered from the depressing effects of the automobile strikes of late 1964, increases were unusually large. The gains moderated in early spring, but were stimulated at midyear by sharply rising capital outlays, excise tax cuts, in? creased Social Security payments, and accelerated Viet-Nam defense expenditures. Gross national product (GNP) in cur-rent dollars rose $49.5 billion or 7.8 percent, to a total of S681.2 billion. In constant dollars (effects of price changes eliminated), GNP increased 5.9 percent, a rate considerably higher than the historical postwar annual average growth of 3.5 per-cent. Demand increased in most final markets and was especially strong for business fixed investment and consumption expenditures. With the exception of construction, most of the increases in GNP were real, since prices increased less than 2 percent.

Jan 1, 1966

By T. Ito, N. Tokashiki, H. A. Bilgin, Ö. Aydan, T. Akagi

This study is concerned with the electric potential induced by deformation, fracturing and sliding of non-piezoelectric geomaterials. In experiments, the acoustic emissions together with electric potential measurements were also measured in order to see how the so-called seismic electric signals are associated with new fracture occurrence and propagation and sliding in case of existing discontinuities. The outcomes of this experimental study may explain why such electric potential variations may occur during the fracturing and sliding of non-piezoelectric geomaterials. On the basis of these outcomes, their possible implications in geo-engineering and geo-science are discussed. Ce travail concerne 1e potentiel électrique produit par la déformation, 1a fracture ou le glissement du matériel géologique non-piézoélectrique. Aux expérimentations, on a mesuré 1es émissions acoustiques avec le potentiel électrique afin de constater la relation entre les phénomènes de glissement ou de formation et de propagation de nouvelles fractures le long des discontinuités existantes. Les résultats de ce travail expérimental expliquent pourquoi de telles variations de potentiel electrique se produisent durant le glissement ou la fracture du matériel non-piézoélectrique. Sur la base de ces résultats, on a discuté de leurs éventuelles implications dans les domaines de 1a géologie et de 1a géo-ingénierie. Diese Studie befasst sich mit dem elektrischen Potential das durch die Deformation, Bruchbildung und Gleiten von nicht-piezoelektrischen Geomaterialien induziert wird. In Experimenten wurden die akustischen Emissionen zusammen mit elektrischen Potentialmessungen gemessen, um zu sehen, wie die so genannten seismischen elektrischen Signale mit neuer Bruchbildung und Ausbreitung sowie Gleiten im Falle von vorhandenen Diskontinuitäten verbunden sind. Die Ergebnisse dieser experimentellen Untersuchungen könnten erklären warum elektrische Potential Schwankungen während der Bruchbildung und dem Gleiten von nicht-piezoelektrischen Geomaterialien entstehen. Auf der Basis dieser Ergebnisse, wurden ihre möglichen Implikationen in Geoingenieurwissenschaften behandelt.

Jan 1, 2003

By Alain Blanchier

Because in Europe and in many other countries as well every new project (quarry, mine, public work) needs a risk estimation to prove its feasibility, a model to estimate flyrock risks became necessary. This paper presents the basic hypothesis which should underlay such a model to estimate statistical flyrocks range for not only some single blasts but a whole project and in particular the way to take into account rockmass or blast pattern parameters variability. It describes a first usable quantitative flyrock model based on the characteristics of the blasting plan and of the generic laws utilised in casting and selective blasting operations and on a statistical approach of rockmass. In a second step, this paper discuss an approach of risks estimation compared to the classical one used in pyrotechnics studies for explosive magazine risks assessment.

Jan 1, 2013

By Earl Greiner

THE constitution of the iron-silicon alloys containing from 14 to 33.4 weight per cent silicon has been studied by a number of investigators, whose results have been reviewed in a monograph published by the Engineering Foundation1. In these previous researches, the solubility of silicon in iron was determined by thermal, microscopic or magnetic methods and the compound Fe3Si2 was reported to be stable at tempera-tures from 0 to approximately 1030° C. This paper describes the results of an X-ray investigation of the solubility of silicon in iron and gives data which prove that the Fe3Si2 phase is unstable below 825° C. In order to obtain the present results on the solubility of silicon in iron, the authors have utilized the lattice constants of the alpha-phase iron-silicon alloys given in a previous publication2, and also some addi-tional data which will subsequently be described.

Jan 1, 1936

he Wyalong goldfields were discovered in September, 1893, Messrs. Neeld and Sons, owners of the principal mine, being the pioneer prospectors. During the earliest days of the field the ore was sent to Barmedman, a distance of eighteen miles, for treatment at a battery there. The field rapidly increased in importance, and it was not long before a public battery was established on the spot. After some considerable quantity of ore was treated by this process, it became apparent that battery treatment was quite unsuitable for the richer ores, involving, as it did, considerable loss in the tailings. Recognition of this fact led to the erection, in 1895, of plants by the Wyalong Chlorination and Cyanide Works, owned by Mr. Walter Sully, for treatment by their processes; followed, at a later date, by Messrs. Neeld and Sons Chlorination Works. The Wyalong Chlorination and Cyanide Works, after a delay of twelve months in the erection of their plants, have since catered continuously up to the present time for the requirements of the field.Their plant consists of a No. 3 Gates' rock·breaker, a revolving dryer, a No. 5 Krupp mill, revolving roasting furnace with finishing hearth, two chlorination vats of 20 tons capacity each, "nine cyanide vats of 30 to 100 tons capacity, two Wheeler pans and three chlorine generators. The ores are purchased outright on assay at a fixed scale of charges, and treated by the owner of the works on his own account.

Jan 1, 1903

By Charles F. Herbert

Placer mining in Alaska had a desultory inception at Sumdum in 1869 and, during the years 1880 to 1896, received thin nourishment from the readily exhausted gold placers at Juneau and the longer- lived deposits in the Circle, Fortymile, and Rampart Districts. Finally, in 1897, the great Klondike discovery in Canada's Yukon Territory brought thousands of gold seekers to the Far North. These men, in successive, far-reaching gold rushes, found the large, rich gold deposits at Nome, Fairbanks, and Iditarod, as well as many smaller placers. The hectic rushes during the years from 1898 to 19 10 were comprised of hundreds, sometimes thousands, of "stampeders," as they were called. Since very many Alaskan creeks, from the crest of the Brooks Range in the north to the Pacific Ocean in the south, carry at least a few flakes of gold, there was ample seed to start a new stampede. Of the 100s of reported "strikes," nearly 50 became more or less important placer mining districts; by 1910 they had produced about 184.2 fine Mg (6.5 million fine oz) of gold; the all- time peak production year was 1906. A few of the miners and prospectors prospered, but the total value of all gold produced failed, by a wide margin, to cover the aggregate costs incurred by them in the undeveloped Territory of Alaska. On the other hand, the traders with their readily salable supplies of food, tools, and hardware and the freighters with their teams of dogs or horses and boats of all kinds profited throughout the era of stampede.

Jan 1, 1991

By A. D. Pelton

The evolution of thermodynamic models of molten salts and slags, starting with Temkin in 1948, has culminated in today?s sublattice models. These modern models have permitted the development of large thermodynamic databases of model parameters, which can be used to calculate and predict accurately the properties of multicomponent solutions. The model parameters are mainly obtained by the critical evaluation and optimization of available thermodynamic and phase equilibrium data for binary and ternary subsystems. The models are then used to estimate the properties of multi component slags and salts from these assessed binary and ternary parameters. When used in conjunction with thermodynamic databases for solids and solid solutions (salts, oxides, sulphides, metals, etc.), other liquid solutions (such as liquid metals),and gases, these databases permit the calculation of complex multiphase equilibria in multicomponent systems, with applications in a wide variety of industries. These calculations can be performed with general commercial software for Gibbs energy minimization, which can also be incorporated into process simulation software packages. Keywords: slags, salts, solution models, thermodynamics, phase diagrams, oxide systems, molten salts

Jan 1, 2004

Coal mining in the Illawarra commenced in 1848. By the early twentieth century mining operations were spread over quite a distance along the coast centred on Wollongong. By this time there were already numerous tunnel mines and one shaft mine. Coal was first reported in Illawarra by Lieutenant Flinders on a voyage of exploration, southerly along the coast from Sydney in 1796. Because of the topography, particularly the escarpment and the narrowness of the coastal plain, access from Sydney was not easy by land and the normal access was by sea. It was not until some coastal areas had been developed for agricultural purposes that the mining of the seams on the South Coast commenced for the supp- ly of fuel. The most important mines in the early nineteenth century were Bulli and Osborne Wallsend. In general, coal was won from the tunnel mines and was transported directly, usually by tramway, to the nearest shipping point. Considerable hardship attended the earliest attempts at mining coal in regard to materials for mining and the way of life of the miners in the vicinity of the mines. With the growth of production and the installation of coke ovens at some mines the area, hitherto virgin bush- land, began to take on a more industrialised appearance. The mines were necessarily small,

Jan 1, 1976