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By E. V. Potter, H. C. Lukens

The volume of hydrogen released from electrolytic manganese at various temperatures and pressures was determined in a previous investigation1 as part of a study to determine the most practical procedure for removing the hydrogen from electrolytic manganese metal. No attempt was made to determine the absolute volume of gas in the metal at any temperature and pressure; the volume of gas released showed only the variation in solubility with temperature and pressure. The results were very similar to those obtained by Sieverts and Moritz.² Both sets of data show a minimum solubility between 500' and 700°C., but they differ in certain respects; on cooling from 500°C., our results showed an increase in solubility of about 7 C.C. as compared with an increase of 34 C.C. per 100 grams shown by Sieverts. Furthermore, the transition temperatures, as indicated by sharp breaks in the solubility curves, did not agree well with Sieverts' data. This information was of secondary importance in the earlier investigations, and the solubility at low temperatures and the transition temperatures were subject to considerable error. Therefore, a subsequent investigation, reported in this paper, was made to measure the absolute solubility at temperatures from room temperature through the melting point and make more accurate observations of the transition temperatures. Apparatus and Method The apparatus and method were essentially the same as those described in the previous work,' as shown in Fig. I. At high temperatures, the small tube containing the thermocouple in the sample container A frequently broke off, so for some of this work the thermocouple was placed outside the sample container and protected by a quartz tube of about the same wall thickness as the sample container. No significant difference was found in the transition temperatures obtained in the two ways. The automatic temperature controller was used in these tests in the regions where there was little change in solubility with temperature. In the neighborhood of the transition points a continuously variable autotransformer was used instead of the automatic controller, and the power input to the furnace was adjusted so that the temperature increased or decreased at a very slow, uniform rate through the transition range. This procedure was followed because the temperature oscillations produced by the controller were too great compared with the transition range, and the transi- . tion points determined under such conditions were less accurate. Absolute Solubility Procedure ad Results The absolute solubility of hydrogen in manganese could be determined most

Jan 1, 1947

By Stephen D. Cramer

The Bureau of Mines conducted a series of in situ linear polarization measurements in high-temperature, high-pressure hypersaline geothermal brines at the Bureau of Mines Geothermal Test Facility in the Imperial Valley of California. The measurements represented an evaluation of the linear polarization technique for obtaining instantaneous corrosion rates of materials of construction in flowing hypersaline hydrothermal fluids that rapidly form scales on exposed surfaces. A special method was devised for use with the linear polarization technique that resulted in obtaining corrosion rates for 1020 carbon steel, 316 and 430 stainless steel, titanium, various nickel-based alloys, and aluminum 6061 under strong scale-forming conditions. The measurements also provided information on scale-deposition rates in various geothermal environments. Exploratory in situ potentiostatic polarization measurements were made in the flowing brines to qualitatively determine scale-deposition effects on the electrochemical measurements.

Jan 1, 1978

By S. G. Galbraith

We have used the principles of supramolecular chemistry to develop reagents to transport metal salts. These reagents have separated charged "compartments" which recognize a metal cation and its attendant anion(s). They are easy to manufacture as they are structurally related to the commercial hydroxy-oxime extractants for copper. Efficient protocols for loading and stripping of these extractants depend on the novel feature that they bind the metal salt in a zwitterionic form of the ligand. Transfer of the phenolic protons to the pendant amines generates the charged "compartments" to accommodate the metal cation and its attendant anion(s). This paper focuses on how these types of reagent can be used to recover base metals from sulfate and chloride media in flowsheets in which solvent extraction effects separation and concentration operations, interfacing between conventional leach and electrowin/reduction processes. Work on the development of reagents that have high selectivity for metal chloride/sulfate transport, convenient stripping protocols and appropriate hydrolytic stability will be described.

Jan 1, 2003

By Ennio Bonetti

The technological applications of MgH2 hydrides for hydrogen storage demand the overcoming of some critical issues: an improvement of the reaction kinetics and a reduction of the desorption temperature. The synthesis of nanocrystalline MgH2 by reactive milling and inert gas condensation and a proper metal catalyst addition, constitute recently employed strategies. In the investigation of the hydrogen short and long-range dynamics, sorption kinetics and nanostructure stability, the mechanical spectroscopy offers some specific advantages. In the present research this technique was employed with other experimental approaches (XRD DSC) to investigate relaxational and structural damping processes in nanocrystalline MgH2 with added catalysts (Fe). Time/temperature variation of the dynamic elasticity moduli and mechanical quality factor are correlated to hydrogen anelastic relaxation processes and concomitant structural transformation of MgH2 to Mg associated to long range H diffusion. Results are discussed with reference to microstructural modification strategies able to assist hydrogen release.

Jan 1, 2006

By A. C. Maffei, M. V. Lins Gonçalves

Ore concentration processes are a function of the respective particle size distribution; however, most of them do not use an efficient operational method to determine it. From a practical point of view, the surface area can be calculated for any size analysis. The physical principles for determining the size distribution in each method are different, for the results will not be compared directly. During the development of the research project of the sulfide ore flotation method using inert gas, different methods for calculating the specific surface area have been used, such as sieving, sedimentation/X-ray, laser diffraction and BET, i.e. specific techniques to determine the specific surface area of copper and gold ore concentrates. The statistical method of minimum squares was used to achieve practical correlation equations among them. Regarding these two ores, if one knows a specific surface area value using one of the methods above, one can predict the result of the others. Diminution of the reagent consumption was so controlled and it could be even decreased by using inert gas.

Jan 1, 2003

By G. S. Nus

Technology for treating man-made metal-containing raw materials in DC electric furnaces with polarization of the bottom phase (PDF furnaces) has been developed and proven on a semi-commercial scale. PDF furnaces permit processing of man-made raw materials, i.e. current and accumulated intermediate products with rather high contents of valuable metals (i.e. slags, sludge, residues, Waelz slag, etc.), as well as secondary raw materials and virtually any type of waste using an environmentally safe technique based on sublimation of volatile metals and transfer of non-volatile metals and sulfur into the bottom phase in the furnace. Processes developed on the basis of the use of PDF furnaces make it possible to take advantage on a full commercial scale of electrolysis of molten materials, including electrochemical reduction of metals, intensification of their settling into the bottom phase and sublimation of volatile components, as well as to significantly improve recoveries of nonferrous metals, resolve the problem of excessive accretion formation in slagging processes and substantially improve the environmental situation. The low-grade discard slag obtained can be utilized in the construction industry; in particular, slag can be added to the limestone feed for cement manufacture.

Jan 1, 2006

By Wilbur Nelson

THE year 1924 showed even less drilling in Kentucky and Tennessee than the preceding year. The operators in this section, however, are anxious to resume development work and are only waiting for a higher market for crude oil before starting such a program. In Kentucky, during 1924, 1605 wells were completed, the combined initial daily production of these wells being 25,599 bbl. Of the total number of wells drilled 1176 were oil wells, 61 gas wells, and 368 were dry holes. The average initial production of the oil wells was 21.8 bbl. per well. In Tennessee, 28 wells having an initial daily production of 1199 bbl. were completed during 1924. Of these, 3 were oil wells, 6 were gas wells, and 19 were dry holes. The initial production of the three oil wells was 400 bbl. Of the total number of wells drilled in Kentucky in 1924, 73 per cent. came in as producing wells; and of those drilled in Tennessee, 10 ½ per cent. came in as producing wells and 20 per cent. as gas wells. In Tennessee, during 1924, wildcatting dropped off considerably and only about one-half as many wells were drilled as in the preceding year; in Kentucky, on the other hand, there was only a slight curtailment in drilling, there being 1943 wells drilled in 1923 as against 1605 in 1924.

Jan 3, 1925

DR. E. E. SOUTHARD,* Boston, Mass.-As Director of a Psychopathic Hospital, I am a sort of "voice in the wilderness" speaking to mining engineers. I suppose that I am here because Major Gilbreth had prevailed upon me to speak on a kindred topic before the mechanical engineers at the annual meeting of their Institute. You might wonder why a psychopathic hospital, a state institution for the first care of mental cases and especially for incipient, acute and curable cases, should have any part or lot in the industrial problem. We have obvious contacts in our institution with the retarded and exceptional children of the schools, with the defective and non-defective

Jan 4, 1918

By Cyril Smith

A STUDY of the precipitation-hardening of copper steels1 led the authors to investigate malleable iron containing copper, for the low-carbon ferritic matrix in malleable iron should lend itself admirably to precipitation-hardening. It was soon found that in addition to rendering malleable iron susceptible to improvement by precipitation-hardening treatments, copper has another potentially useful effect as an accelerator of graphitization. Brief mention of these effects was given in a general paper by Lorig and one of the present authors2; the present paper gives further details on the graphitization and precipitation-hardening effects only. After the completion of this work a paper by L. Lykkin3 appeared, confirming the authors' conclusions regarding graphitization.

Jan 1, 1935

By Paul R. Coyle, Anthony T. Iannacchione

A close look at the Loyalhanna Limestone of southwestern Pennsylvania reveals a complex structural environment. Most exposures of the Loyalhanna occur along Chestnut Ridge and LaurelHill within the Allegheny Mountain Section of the Appalachian Plateaus Province. Because the Loyalhanna is rated as a super-pavement aggregate by the Pennsylvania Department of Transportation and because of its proximity to the population centers of southwestern Pennsylvania, the Loyalhanna has been extensively mined along these prominent anticlinal structures. Geologic and engineering analyses were performed using gas well and core logs, outcrop examinations, underground observations, and mine maps. Strata exposures from both outcrops and quarries were used to construct geologic maps, stereo net, and rose diagram projections so that the Loyalhanna’s structural environment could be understood better. Many of these structural conditions cause ground control problems at local quarries. These problems ranged from small-to-moderate sized rock falls associated with roof jointing to pillar failures associated with dipping discontinuities. Stresses ranged from tensional on structural domes where weathering dominates, to high levels of compression within structural saddles. A greater understanding of these characteristics is a prerequisite to develop engineering controls, such as improved mine layouts, pillar sizes, etc., that lessen miner exposure to these hazards.

By L. Bichler, A. Siebert-Timmer

In this research, novel YSZ ceramics doped with 5 mol% Nd2O3 were manufactured via Spark Plasma Sintering (SPS) process. The sintered Nd2O3-YSZ ceramics were subjected to a static supercritical water environment at a temperature and pressure of 400 °C and 31 MPa, respectively. The weight loss and microstructure development of the sintered ceramic before and after exposure to supercritical water was studied. The results suggested that Nd2O3 addition significantly improved the degradation resistance of the YSZ ceramics. This was attributed to the improved phase stability of the 5 mol% Nd2O3-YSZ ceramics, since X-ray Diffraction (XRD) studies showed that the cubic stabilized matrix in these ceramics was retained after exposure to supercritical water. In comparison, pure YSZ ceramics exhibited a rapid degradation behavior as well as a phase change.

Jan 1, 2014

By M Simpson, K Brodie, J L. Mauk

Subaqueous water-rock reactions that occur at the pit wall/lake water interface can affect the pH of pit lakes. Many pit lake water chemistry models neglect subaqueous reactions, which may create inaccurate predictions over time. A mineral quantification method is presented that defines the wall rock mineralogy of active open pit mines, using samples collected from the Martha Mine, a low-sulfidation epithermal Au-Ag deposit in Waihi, New Zealand. The mineral quantification method has five components: field observations and sampling, X-ray diffraction analyses, selection of representative samples, geochemical analyses, and mineral accounting. Predicted mineral concentrations closely match observed mineral concentrations visually estimated using petrographic techniques. Results of the method can be incorporated into a geochemical model of long-range pit lake water quality resulting from subaqueous water-rock reactions.

Jan 1, 2003

By Keith Orgeron, Tibor Rozgonyi, Graham Mustoe, Vilem Petr

This paper presents the results of an experimental and numerical investigation of the shock wave energy transmission and reflection through boundary layers (joints, fractures) or between inhomogeneous geomedium with different physical properties. The conclusions drawn significantly clarify the dynamic failure mechanics because of shock wave energy transmission and reflection through different rock materials and their jointed interfaces. Thorough studies were performed to document the transient, two dimensional deformation characteristics, the normal and shear stress fields for inhomogeneous geomedium focusing on the influence of the internal geometrical shapes, relative density variations and packing of the grain boundaries.

Jan 1, 2002

By C. A. Mezger

DURING my stay at Raposos, State of Minas Geraes, Brdzil, I had the opportunity of making some observations, which, in the shape in which I am able to lay them before the Institute, are only to be considered as an experience which may possibly have important consequences. The ore-bodies worked there for gold are exclusively chimneys, mostly cylindrical, following the dip of the argillaceous slates (about 45° E.), without any visible connection with each other, without veins, and only exceptionally with some small stringers along the stratification, pinching out at short distances from the chimneys. They are composed of quartz with about 8 to 10 per cent. of pyrite and pyrrhotite, and different iron oxides.

Jan 1, 1895

By Roberto Folchi

"This article deals with the excavation of a tunnel below the town of Isola LIRI, nearFrosinone, in central Italy. The tunnel was driven into a conglomerate formation, of lacustrine_fluvial origins, consisting in carbonate clasts with a sandy_silty matrix and calcitic cement. ""Drilling andblasting"" had to be adopted in place of a tunnel boring machine which had showeduneconomical performances. Good advance speed rates were achieved notwithstanding thepresence of some above structures to safeguard. The nearest structure (an old votivechapel) was less than 10 meters (33 ft.) far from the tunnel crown; the nearest residentialstructure was at about 15 m (49 ft.)."

Jan 1, 1993

By J. Wright, R. J. Tyler

Changes in the pore structure of hematite pellets during reduction to iron were investigated under a variety of experimental conditions. Pore structures were determined by a mercury penetration technique. The reduction temperature was found to be the major influence on structure, the pore system being bimodal below 7.50°C and unimodal above 900°C. Pore sizes ranging front 0.04 to 20 m were observed in complete metabolized pellets produced over the temperature range 650 - 1050°C. Gas composition and reduction rates also influenced the pore structure of the metabolized pellets, although to a lesser extent than the reduction temperature. An apparent activation energy of 24 kcal/mole was derived for the pore formation process.

Jan 1, 1979

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By T. A. Read, H. M. Otte

THEORETICAL analysis by Wechsler, Lieberman and Read of the crystallography of martensite formation has shown that the requirement for the existence of a macroscopically undistorted plane between austenite and martensite permits a calculation of the indices of the habit plane of the marten-

Jan 1, 1958

By Peter J. Clarke

Afghanistan's mineral industry continued to be dominated by the production and export of natural gas, although several mining and related industrial projects, all under the supervision of Soviet technicians, were in the planning stage in 1982. Afghanistan produced minor quantities of barite, cement, coal, fertilizer materials, iron, and lapis lazuli, all for domestic consumption.2 Large-scale projects being investigated were a copper mine and concentrating plant at Ainak, extensive mining of the Hajigak iron ore deposit near Kabul, construction of an oil refinery at Angot, increasing production and processing of natural gas, and implementing an intensive geologic prospecting and exploration program for areas of mineral potential. Afghanistan's gross domestic product (GDP) was estimated at $2.76 billion3 and has remained stagnant for the past several years. Total exports in 1982 were estimated at $700 million, only a marginal increase from the 1981 figure of $694 million. Exports of natural gas to the U.S.S.R. earned $385 million in 1982, representing just over one-half of Afghanistan's total exports. Natural gas revenues were down approximately 11% from the 1981 level, owing primarily to increased antigovernment activity in the northern part of the country.4 About 90% of the country's natural gas production was exported to the U.S.S.R.5 About 38% of Afghanistan's development budget had been earmarked for mining and industrial projects in 1982.6

Jan 1, 1984

By Christopher W. Schram, Allan B. Tanner, Frank E. Senftle, George R. Boynton, Philip W. Philbin

Abstract-A borehole sonde wing a 252Cf neutron source and a Ge(Li) gamma-ray detector was field tested in a coal bed in Belmont County, Ohio, to ascertain whether such a device could be useful as a coal-exploration tool. As the sonde was lowered into the borehole, successive spectra were accumulated over short time intervals. The intensities of the capture gamma rays from hydrogen and of decay gamma rays from aluminum were determined simultaneously in each spectrum. A log of the intensities versus depth shows the depth and thickness of the coal bed.

Jan 6, 1978