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By R. D. Agrawal, M. L. Kapoor

Cementation has been used extensively by chemists and metallurgists as an economical process for the purification and recovery of metals from dilute solutions. The paper deals. firstly. with the thermodynamic aspects of cementation. and. secondly, with the effects of various process variables, such as temperature. stirring speed. initial concentrationof copper ions. pH of the solution, atmosphere, and surface area of the precipitant metal. on the kinetics of the process in the light of the rate expressions.

Jan 1, 1982

By D. C. Jillson

THE data on the critical resolved shear stress for zinc single crystals published by Rosbaud and Schmid1 showed many irregularities, as seen in fig. 1. There have been subsequent investigations,2,3 but no one has repeated this work with a wide range of orientations, with specimens of a higher degree of purity and perfection, and with improved experimental techniques in order to determine whether these variations were entirely experimental or whether they might have been due, at least in part, to some feature of the mode of deformation not known or understood. Mathewson4 and others have long felt that the glide observed in a [100]* direction between two (001)* planes in the zinc lattice might be actually the net effect of many consecutive unit glides or movements in two alternating [210] directions (fig.

Jan 1, 1951

By Persio de Souza Santos, Ayres Ferrelra Morgado

In this work, a sample (of about 100kg) of an ore considered as smectitic, not yet industrialized, from Lages-SC-Brazil, was tested for evaluation of its industrial applications. First, we characterize them by XRD, DTA, FRX, and CEC analysis. After this, the smectitic clay was changed to sodium form by treatment with sodium carbonate. Then, the homoionic sodium clay was tested for iron ore pelletizing agent, as binder of foundry sands, and drilling mud with good results.

Jan 1, 1998

By G. G. O. O. Uwadiale, E. G. Okafor

A study was performed to characterize the Ishiagu lead-zinc deposit prior to beneficiation. The study included the use of XRD, SEM and both reflected- and transmitted-light microscopy. The results showed that the ore consists mainly of galena (PbS), sphalerite (ZnS) and quartz (chert), with pyrite, siderite and chalcopyrite occurring as trace minerals. The textural relationships among the minerals, their grain sizes and their locking characteristics, coupled with the chemical analysis of the ore, indicated that the galena and sphalerite can be separated by conventional beneficiation methods.

Jan 1, 1998

By Q. G. Reynolds

The dual-electrode DC arc furnace, an alternative design using an anode and cathode electrode instead of a hearth anode, was studied at small scale using computational modelling methods. Particular attention was paid to the effect of two key design variables, the arc length and the electrode separation, on the furnace behaviour. It was found that reducing the arc length to brush arc conditions was a valid means of overcoming several of the limitations of the dual-electrode design, namely high voltages and arc deflection.

Jan 1, 2012

By Serhat Özdemir, Derya Öz Aksoy, Pınar Aytar Çelik, Ahmet Çabuk, Sabiha Koca, Hüseyin Koca

In carbonate flotation, oleate has been used for many years as a collector in industrial scale. Compared to sulfide minerals, the flotation of carbonate minerals requires more collector consumption and has lower yield and selectivity. It has been previously shown that surfactin provides higher yields in smaller amounts than oleate in the bioflotation of calcite as one of the carbonate minerals. In this study, the usability of surfactin as a flotation collector for magnesite was investigated. For this purpose, the adsorption of surfactin on the magnesite surface was inspected with analyses such as FTIR, SEM–EDS, contact angle, and zeta potential measurements. In addition, the effect of surfactin on the surface tension of water was also revealed. The same analyses were also performed for oleate as a reference point. All flotation experiments were performed without optimizing with both collectors. FTIR results showed that the surfactin, like oleate, was chemically adsorbed on the magnesite surface. Surface tension analyses showed that the surface tension of water decreased to approximately 32 N m− 1 at 10− 4 M oleate concentration, and this value decreased to below 25 N m− 1 at the same surfactin concentration. According to contact angle measurement results, the contact angle of magnesite was 85° after the surfactin adsorption of 2 × 10− 4 M concentration, while this value remained at 46° for oleate. Finally, according to flotation experiments, high temperatures and high collector dosages are necessary for acceptable flotation recovery with oleate, yet surfactin can produce the desired result at ambient temperatures and lower collector amounts.

Dec 13, 2022

By Reynold Q. Shotts

Data are presented which show that fractions of varying densities from the same coals are oxidized at different rates by nitric acid. From oxidation data, the approximate quantity of "bright" and "dull" components may be calculated. Definite relationships between oxidation rate and rank are shown for density fractions from at least two bituminous coals.

Jan 8, 1950

By Gordon Revey

The challenge of managing blasting risk, types of risk, public perception, and a system for managing risk were covered in the first part of this article in the May/June 2000 issue of the Journal of Explosives Engineering. This final part of this two-part series provides a method for identifying specific blasting risks and reviews the importance of community relations.

Jan 1, 2001

By A. S. Ibrado, D. W. Fuerstenau

The adsorption of the cyano complexes of Ag(I). Cu(l), Hg(II), Cd(II), and Zn(II) on activated carbon was investigated as a function of pH and correlated with the speciation diagram for each metal. The results show marked changes in uptake with pH, closely resembling the predominance profiles of their neutral and singly charged cyano complexes. Multicharged negative complexes are repelledby the negatively charged carbon surface. The sensitivity of activated carbon to the charge of the adsorbing species indicates that silver adsorbs as an anion, not chemically bound to the coadsorbing counterions. For the same reason, activated carbon is selective to metals that preferentially form neutral and singly charged cyano complexes, namely gold and silver.

Jan 1, 1990

Denver, the Mile High, Queen City of the Plains, your host for AIME's 99th Annual Meeting has many exciting and picturesque places for you to visit during your stay. A host of restaurants cater to every taste; supper clubs and theaters provide nighttime entertainment; there are sports facilities and a plethora of shops for the ladies. When it comes to dining out, there are many excellent restaurants within walking distance of the Denver Hilton --among them, three in Brooks Towers: the Gitana, the Boston Half Shell serving the finest seafood, and Marvelous Mary's. In the Larimer Square area there in the Bratskellar with a true Germanic atmosphere and Sperte's Laffite offering a typical New Orleans setting.

Jan 1, 1970

?Energy-related systems: wind, solar, electric are typically materials intensive. As new technologies are widely deployed, significant quantities of the elements required to manufacture them will be needed. However, many of these unfamiliar elements are not presently mined, refined or traded in large quantities, and, as a result, their availability might be constrained by many complex factors. A shortage of these ?energy-critical elements? could significantly inhibit the adoption of otherwise game-changing energy technologies. This, in turn, would limit the competitiveness of the U.S. industries and the domestic scientific enterprises and, eventually, diminish the quality of life in the US.? -Energy Critical Elements: Securing Materials for Emerging Technologies?- American Physical Society, 2011.

Jan 1, 2012

By D. W. Brunton

The object of the investigations and experiments here recorded was to obtain such information and data as would make it possible to determine the fineness to which crushing must be carried, in sampling gold- and silver-ores, in order to obtain results within an allowable limit of error.

Jan 1, 1896

By Li T

Mining of the southern 1900 copper Orebody presented a challenge due to the complex geology, geometry and simultaneous extraction of the nearby lead/zinc/silver orebody. An integrated and co-operative approach was adopted, involving geology, geomechanics, mine planning and production personnel. Successful extraction of the first 1900 Orebody stope, T496, together with the extraction of the first two lead/zinc/silver panel stopes in the immediate hangingwall of the 1900 Orebody stope was achieved as a result of this approach.

Jan 1, 1995

By R. A. Frith, M D. Goodz

Ore-bearing minerals that are located along microfractures are always susceptible to loss during the breakage and sampling of the material. Further losses occur with on-site sample preparation and splitting prior to laboratory analysis. In these cases solid whole rock channel or core samples should be handled with due care to ensure all fines and loose particles are collected and included in the sample for total chemical analysis.Similarly open hole and reverse circulation drill methods are not usable in areas containing old mine workings, heavily fractured ground or highly degraded/oxidised mineral assemblages. Nor are these methods usable to assess a bulk mineable target where the enriched zones were peripheral to or between old mine cavities.

Jan 1, 1993

Both blast furnace and steel furnace slags have been used extensively and successfully on main line railroads in the United States for more than 25 years. Annually, these slags are being used as ballast at the rate of about 4 million tonnes of blast furnace slag and 1 mil- lion tonnes of steel furnace slag, much of it on main line with 90 metric tonne car loadings. More steel furnace slag would be used if it was available. Both slags meet all the specification limits of the American Railway Engineering Association. Actual use on high density rail- roads has confirmed the long range economics of their use. Comparison of laboratory tests, such as Los Angeles abrasion, with actual field per- formance has shown conclusively that commonly used laboratory tests can not be used to accu- rately compare the quality of various types of ballast materials.

Jan 1, 1979

By Anis Farah, Khosrow Aref

Pull-out tests were conducted on cable bolts grouted with concrete, and cement paste. The influence of several parameters on the performance of these cables were studied under loading rates varying from very slow to relatively fast. These parameters include water-cement ratio, cable surface conditions, curing time and embedded length. In addition to being more economical, the results indicate that cables grouted with concrete have higher ductility and ultimate bond strength as compared to those with cement paste only.

Jan 1, 1986

By G. W. Heunisch

The properties of Neutra-Fix® and Neutra-Ment®, two new lime substitutes for treating acid mine drainage (AMD), have been compared with lime and Allcament®, two products presently in use for AMD treatment. The two new products are basically dolomitic byproducts and produce sludges that are more compact than those from lime. Sludge settling rates are faster than lime with iron concentrations after 24 hours that comply with Environmental Protection Agency (EPA) regulations. Material utilization and optimum pH are reported.

Jan 1, 1988

By Bolton G. C

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCi in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

By J. A. Rajala, R. W. Smith

The effect of increasing ionic strength, via monovalent and divalent ions, on alkyl sulfate flotation of hematite and quartz war investigated. The effects of collector chain length and pretreatment on this flotation were also studied. Sodium hexadecyl sulfate was shown to be a superior flotation collector to sodium dodecyl sulfate for recovery of hematite when there was no salt addition. Similar observation were made when sodium sulfate or sodium chloride was used to control ionic strength. Sodium dodecyl sulfate floated hematite better than its longer chutited counterpart under conditions of low pretreatment temperature and increasing calcium chloride concentration. The flotation recovery for all salt containing pulps was almost always improved after preboiling. Most of the results obtained when the pretreatment temperature was raised were attributed to increased solubility of the collector.

Jan 1, 1984