Search Documents

By G. U. Greene

The various lead producers have given the subject of lead drosses much attention in recent years but the problem of their economical treatment is yet to be solved. Formerly the copper in the furnace feed was removed from the furnace in the form of matte. The speiss at that time consisted principally of the iron arsenide. The practice today is to roast off most of the sulphur and the copper in the feed forms a dross in the furnace, which is removed from the furnace with the lead. This material is poured into the drossing kettles and allowed to cool down to but slightly above the freezing point of lead. The copper dross, containing almost all of the arsenic and part of the antimony, is skimmed off and treated in a small reverberatory furnace at most plants. This is essentially a liquation process. The skimmed dross contains from 70 to 80 per cent lead, and much of this lead is liquated out. The products from this treatment are: (1) impure lead, (2) speiss and (3) matte. The speiss from the reverberatory furnace was studied in this research. The literature on the subject is of very little assistance, as almost no work has been done on the problem of establishing the exact identity of the various phases present. One author(1)† states that speiss consists of a series of isomorphous compounds of the general formula FexAsy in which the Fe may be replaced by Ni, Co, Cu, Pb, Ag, Au, Pt, Zn, Cd and the As replaced by Sb, S and Bi. Hofman(2) states that the iron arsenide present is Fe5As. Experimental Work In the present research, the author used for methods in an attempt to determine the composition of the various phases: (1) chemical, (2) microscopic, (3) roentgenographic and (4) thermal. Previous to this research, considerable time had been spent making analyses of different speisses, but unfortunately no very definite conclusions could be made as a result of these analyses.

Jan 1, 1937

By W. R. Strickler, P. Hazebroek, M. Prats

The pressure and production behavior of a homogeneous cylindrical reservoir producing a single fluid through a centrally located vertical fracture of limited lateral extent was determined by using mathematical methods to solve the appropriate differential equation. It is assumed that there is no pressure drop within the fracture — that is, that the fracture capacity is infinite. It was found that the production-rate decline of such a reservoir is constant (except for very early times) when the flowing bottom-hole pressure remains constant. The production-rate decline increases as the fracture length increases. Thus, the lateral extent of fractures can be determined from the production-rate declines before and after fracturing or from the decline rate after fracturing when the properties of the formation and fluids are known. The production behavior over most of the productive life of such a fractured reservoir can be represented by an equivalent radial-flow reservoir of equal volume. The effective well radius of this equivalent reservoir is equal to one-fourth the total fracture length (within 7 per cent); the outer radius of this equivalent reservoir is very nearly equal (within 3.5 per cent) to that of the drainage radius of the fractured well. The effective well radius of a reservoir producing at semisteady state is also very nearly equal to one-fourth the total fracture length. It thus appears that the behavior of vertically fractured reservoirs can be interpreted in terms of simple radial-flow reservoirs of large wellbore. INTRODUCTION An earlier report1 has considered the effect of a vertical fracture on a reservoir producing an incompressible fluid. That investigation of the fractured reservoir producing an incompressible fluid was started because of its simplicity. Thus, pertinent behavior of fractured reservoirs was obtained at an early date, while experience was being gained of value in the solution of more complicated fracture problems. One of these more complicated problems, and the one discussed in this report, considers the effect of a compressible fluid (instead of incompressible fluids) on the production behavior of a fractured reservoir. In the incompressible-fluid work mentioned, it was shown that the production rate after fracturing could be described exactly by an effective well radius equal to one-fourth the fracture length whenever the pressure drop in the fracture was negligible. Because of the simplification in interpretation, it is a matter of much interest to determine whether the production behavior of reservoirs producing a compressible liquid could be described in terms of an effective well radius which remains essentially constant over the producing life of the field. The details of the mathematical investigation are given in the Appendixes. IDEALIZATION AND DESCRIPTION OF THE FRACTURED SYSTEM It is assumed that a horizontal oil-producing layer of constant thickness and of uniform porosity and permeability is bounded above and below by impermeable strata. The reservoir has an impermeable circular cylindrical outer boundary of radius re. The fracture system is represented by a single, plane, vertical fracture of limited radial extent, bounded by the impermeable matrix above and below the producing layer (reservoir). It is assumed that there is no pressure drop in the fracture due to fluid flow. Fig. 1 indicates the general three-dimensional geometry of the fractured reservoir just described. When gravity effects are neglected, the flow behavior in the reservoir is independent of the vertical position in the oil sand. Thus, the flow behavior in the fractured reservoir is described by the two-dimensional flow behavior in a horizontal cross-section of the reservoir, such as the one shown in Fig. 2. Production is due to the expan-

By August V. Castelli

Drilling fluids have changed over the years from water and/or water frequently mixed with local clays to scientifically com- pounded materials (mud). This change has occurred due to changes in drilling methods from percussion to rotary: depth maximum from 21 m in the first oil well to more than 9 000 m; and variety in types of well or hole to gas, oil, water, and mineral exploration. Environmental concerns about the composition of the fluid as to heavy metals and oil on the cuttings has recently caused changes in the materials used in the mud. The drilling fluid should perform the following functions (Darley et al., 1980): 1) Carry cuttings from beneath the bit, transport them up the annulus, and permit their separation at the surface. 2) Cool and clean the bit. 3) Reduce friction between the drilling string and the sides of the hole. 4) Maintain the stability of uncased sections of the borehole. 5) Prevent the inflow of fluids-oil, gas, or water-from permeable rocks penetrated. 6) Form a thin, low-permeability filter cake which seals pores and other openings in formations penetrated by the bit. In addition to these, the fluid should: 1) Not injure drilling personnel nor be damaging or offensive to the environment. 2) Not require unusual or expensive methods of completion of the drilled hole. 3) Not interfere with the normal productivity of the fluid- bearing formation. 4) Not corrode or cause excessive wear of drilling equipment. A number of industrial minerals, chemicals, and other materials are used as additives in the drilling fluid to accomplish these functions. Industrial minerals make up the highest percentage of the additives in a drilling fluid. Drilling fluids are classified according to their principal components: water, oil, and gas. If the major component is either water or oil, the component along with the suspension of solids, cuttings and additives is referred to in the trade as a mud. The largest use of some industrial minerals, such as barite and bentonite, is in drilling muds. For other materials, such as gypsum and limestone, drilling usage is only a small percentage of total demand. RAW MATERIALS [Table 1] lists the industrial minerals used in drilling fluids, their form, specifications, and uses. Each raw material will be discussed as to its mineralogy, physical and chemical properties, and the location of major deposits with respect to drilling fluids. Attapulgite Attapulgite is a crystalline hydrated magnesium silicate clay mineral, prized for its viscosity in saline waters. The particles are needle-like rather than the platelets common to most clay minerals. The specific gravity is 2.5 and the Mohs hardness is 1 to 1.5. Attapulgite is one of the materials sometimes referred to as fuller's earth. The major producing areas in the United States are southern Georgia and northwestern Florida. It also is mined in Spain, Senegal, the Republic of South Africa, Turkey, India, and Australia. Barite Barite is crystalline barium sulfate. It has a high specific gravity for a non-metallic mineral, 4.5 when pure, and is used as a weighting agent. Generally, the specific gravity ranges from 4.20 to 4.35. It is relatively soft with a Mohs hardness of 3 to 3.5 and is not very abrasive. Barite is inert, non-toxic, and clean to handle. Common contaminants are quartz, iron minerals, gypsum, and calcium carbonate. If there is considerable gypsum in the barite, it will thicken the mud. The major deposits in the United States are in north central Nevada, near Battle Mountain. The major producing countries, other than the United States, are China, India, Mexico, the former USSR, Turkey, and Morocco. The major deposits in India and Nevada, and some in China, are stratiform, commonly quite pure bodies in bedded sedimentary rocks.

Jan 1, 1994

By W. W. Dudley

The U.S. Geological Survey, in support of underground testing of nuclear explosives, has developed a technique (Dudley, 1910) to predict the inflow of ground water to large underground chambers that are cylindrical in shape. By treating the chamber as a large-diameter well pumped at constant drawdown, the nonsteady discharge can be computed by the method of Hantush (1961) for analyzing flowing wells under leaky artesian conditions. In mining applications, whether for mineral recovery or for nuclear testing, the most serious departure from the conditions of Hantush's model results from the gradual enlargement of the opening under drained conditions. Inherent in the analytical technique is that the "well" is fully completed at the time that dewatering begins. Because safety is the prime concern, however, initial pumping systems or personnel evacuation procedures must be designed to handle the greatest conceivable inflow. DEFINITIONS Because somewhat different meanings are attached to similar words in different technical fields, the U.S. Geological Survey definitions (Lohman, 1970) of several hydrologic terms used in this report are given below. An aquifer is a formation, group of formations, or part of a formation that contains sufficient saturated permeable material to yield significant quantities of water to wells, and springs. A confining bed is a body of material lying stratigraphically adjacent to one or more aquifers and having a hydraulic conductivity distinctly lower than that of the aquifer. The total head (dimensions L) of a liquid at a given point is the sum of three components: (1) elevation head, he, which is equal to the elevation of the point above a datum; (2) pressure head, hp, which is the height of a column of static water that can be supported by the static pressure at the point; and (3) velocity head, hv, which is the height the kinetic energy of the liquid is

Jan 1, 1971

By Alan D. Randolph

INTRODUCTION The production of fines is an unwanted side-effect in most crystallization processes. The definition of “fines" is relative to the size of the desired product and varies from <30 mesh for coarse KC1 fertilizers to subsieve organic material produced by salting-out pro- cesses. Sometimes a well-developed fines distribution is necessary in the production of large crystals, e.g. the fines removal stream from a potash crystallizer. The production of fines is usually not desired in a crystallization separation step. However, product purity can either improve or degenerate with a decrease in crystal size depending on the relative importance of product washing vs mother liquor occlusions in determining over-all purity. Typically, both washing efficiency and mother liquor occlusions decrease with decreasing particle size. Fine crystal distributions have historically been difficult to measure and categorize; however this situation is changing rapidly with the use of electronic particle counters of the electrical zone- sensing or light scattering type. In fact, fine-crystal measurement is perhaps the key to better understanding and control of coarse- crystal crystallization processes. The fine-crystal distribution carries much useful information from which nucleation and growth rates can be inferred. The purpose of this paper is to briefly discuss a few crystallization processes in which production and/or measurement of fines is important and to categorize the process conditions which yield a fine- crystal product.

Jan 1, 1980

By James A. Beck

Phosphorus is essential to all life processes and therefore to the existence of man. In this role, there are no substitutes for phosphorus. In a commercial sense, phosphorus and its compounds are important to our entire economy, both in agricultural and in nonagricultural applications. The world&apos;s phosphate requirements are met by mining phosphate rock. Two general types of phosphate ore deposits are commercially important-igneous and sedimentary. Igneous deposits generally are more difficult and more expensive to mine than sedimentary deposits and are of importance mainly in the USSR, North Vietnam, and South Africa. Approximately 15% of current world production comes from these deposits. Over 80% of world production is from the pellet sedimentary deposits of Florida, North Africa, and elsewhere. Guano, the second type of sedimentary deposit, is produced in South America but is declining in world importance. Production Production of phosphate rock was reported in 31 countries during 1972. However, about 80% of world output is produced in three countries: the United States, the USSR, and Morocco (Table 15.2A.1). Throughout the past 20 years, between 75% and 80% of world output has been produced by these three leading countries. Between 1948 and 1972 world production increased at an average rate of 10% per year, from 21.5 to 103.9 million tons. Growth was quite steady at 6% per year through 1963, but in the 5 years from 1963 to 1968 production increased 11 1/2% per year. Since 1968 production has increased about 91/2 % annually. Since 1948 several new phosphate mining ventures have been developed in Senegal, Togo, Israel, and North Vietnam. In the same period, only one important phosphate deposit, on Makatea Island, has been mined out and closed. A number of other phosphate mining ventures are in various stages of planning and development. The most important new venture in phosphate mining is in the Spanish Sahara. New mining capacity is expected also in Syria, and serious investigation is in progress in Peru, India, Turkey, and Australia. Major expansion of existing operations is expected in Morocco, Russia, Tunisia, Israel, and Jordan. Consumption Historical data on world consumption of phosphate rock are not available in detail, but world consumption of phosphate has closely paralleled world production in the past two decades. The United States is the world&apos;s largest user of phosphate rock, accounting for 30%

Jan 1, 1976

By K. Bragg

During the last several years considerable discussion has taken place on the long term aspects of uranium tailings management. These discussions have centered around a variety of topics which in turn lead to a variety of opinions. In order to come to grips with the various differences of opinion and points of view, the Atomic Energy Control Board has decided to prepare, as an interim measure, a list of proposed close-out criteria for uranium tailings management facilities. It is important to keep in mind that the criteria set out in this paper are proposals and are intended to initiate a continuing dialogue between the uranium mining industry and the various regulatory and government agencies. It is envisaged that this dialogue would continue for a period of from six to twelve months after which some final form of these criteria would be issued and applied to the active uranium mining facilities. In attempting to understand the reasons why the Atomic Energy Control Board has decided to propose these criteria now instead of at some future point in time, it is necessary to look at a number of existing facts. One of the most important of these is that something in excess of one hundred million tonnes of tailings currently are placed in various tailings management facilities. Furthermore, the rate at which tailings are being deposited into such management facilities is on the increase and this increase is expected to continue over the next five to ten years. The management of these tailings is currently covered under the Mine Facility Operating Licences issued by the AECB. Implied within these licences and supporting documents leading to them, are requirements for the conceptual approach to be used at abandonment. There is however, no current requirement for a detailed study on the engineering or financial aspects of such abandonment procedures. This is a gap which the Board feels must be addressed. There are, at this time, various initiatives underway both in Canada and within the international community which are attempting to address the problems and concerns of the very long term management of tailings. For example, current research in Canada which is composed of two components, one by the AECB dealing with purely regulatory aspects and a second major coordinated program under the direction of the Department of Energy, Mines and Resources and in particular by CANMET is going to deal with the technical problems. On the international scene

Jan 1, 1980

Etching solutions containing hexavalent chromium ions (e.g., chromic acid) are used in brass finishing, printed circuit board etching, preparation of plastic for plating, anodizing, and various other industrial surface treatment operations. As the solutions are used, hexavalent chromium ions are reduced to their trivalent state, contaminants accumulate in the solution, and the effective acid concentration is reduced. When the etching rate becomes unsatisfactory for the particular operation, the solutions are discarded. This is a problem because the discarded solutions are pollutants, and because replacing the etching solution is expensive. The Bureau of Mines has developed a process for regenerating these spent solutions and returning them to the surface treatment operation without interrupting the etching process. An electrolysis cell containing anode and cathode compartments that are separated by permeable membranes, is used for regenerating the spent solutions. The spent chromic acid solution is fed to the anode compartment and sui (uric acid is circulated in the cathode compartment. Application of a steady electrical potential of a few volts dc across the electrodes causes the copper ions and other contaminants in the spent solution to migrate through the membrane to the cathode compartment where copper is plated onto the cathode. Zinc and the other contaminants remain in the sulfuric acid. At the same time, the complex, trivalent chromium ions in the spent solution are attracted to the anode where they are oxidized to their original hexavalent state. The regenerated solution in the anode compartment is then recycled back to the plant?s etching operation for reuse.

Jan 1, 1980

By Glenn C. Waterman

THE diamond drill is a very important tool in exploration and development testing and its use is increasing. In almost all cases results of diamond drilling are analyzed on the basis of grade and tons. A proper evaluation of core and sludge assays is important if drilling results are to be acceptable as a basis for geologic and engineering appraisal. The relatively wide variation in assay averages as calculated by various well-known combining methods indicates that the engineering choice of a method may affect the outcome of the drilling in terms of ore and waste. The problem of combining assay results from core and sludge samples has been discussed many times in conference and in the literature.&apos;" Most writers agree that the field of disagreement in methods is large and that the engineer on the job must consider features unique to his drilling, pick one of several combining methods, and depart from the rules when abnormal results come in. All the discussion to date can be summed up by the admission that as yet there is no fairly simple, generally acceptable combining method that is practicable over a wide range of drilling conditions, ground conditions, and ore occurrence.

Jan 1, 1955

By B. Ladanyi, G. Archambault

It is generally recognized to date that a rational stability analysis of slopes and foundations in rock masses is a desirable but still rather remote goal of rock mechanics.1 In principle, a slope analysis is possible provided the original state of effective stress in the ground is known and the shear strength of the earth material can be clearly defined. In a macroscopically continuous earth medium such as soil, the two basic ingredients of the stability analysis in most cases can be assessed with sufficient approximation. A much less favorable situation exists when the slope is composed of a macroscopically discontinuous medium such as rock mass containing one or more sets of geological planar structures. In such a case, both the original effective stresses and the overall shear strength of the mass are much more difficult to determine. As for the former, it is only recently that certain calculation methods and solutions concerning the stress distribution2 and the seepage forces3 in a discontinuous medium have been proposed. As the strength behavior of the rock mass is concerned, much valuable effort has been made in recent years toward reaching a proper understanding of the phenomenon of rock mass failure under stress. Probably one of the most complete investigations of the problem to date has recently been made at the University of Illinois. The study resulted in establishing a first useful working hypothesis of the shear behavior of a regularly jointed rock mass, proposed by Patton in 1966.4 The main purpose of the work described in this chapter is to establish a more general framework for the shear behavior of rock mass, one that would be directly related to some basic rock parameters and would also

Jan 1, 1970

By Ferri P. Hassani, Riadh Bouzaïene

"Selected methods of pressure loss predictions in horizontal slurry flow in pipelines are presented. For a given combination of flow velocity, solids concentration and particle size, the slurry and its flow conditions are described, and an appropriate method of pressure loss prediction is outlined. The wide range of conditions treated in this paper may be found in practice in areas varying from the hydraulic transport of low concentration slurries to dense-phase conveying of paste backfill in underground mines.IntroductionThe hydraulic conveying of solid particles in pipelines is a major component of the mining and mineral processing industry. Whether the objective is to transport ore to the processing plant or to make use of mill tailing as backfill material; the need for well designed, economical hydraulic conveying systems is recognized.The contribution of this paper is part of an on-going research program at McGill University involved in optimizing and developing techniques for total mine waste disposal. One of the main concerns in the conveying of solid-liquid mixtures is the prior knowledge of the pumping power input required. This energy requirement is directly proportional to the pressure losses incurred in the pipeline system. Understanding the sources of such pressure losses and predicting their magnitudes should enable the system designer to make informed decisions regarding the optimum mode of hydraulic transportation commensurate with the over-all requirements of the operation.This paper is an attempt to classify pressure loss prediction methods encountered in the literature for solid-liquid mixtures. In spite of the large number of publications spanning thirty years of research in the field of slurry transportation, it is sometimes difficult to correctly identify the appropriate methods applicable to a given situation. This is partly due to the inherent complexity of the mechanics of slurry flow and the ensuing uncertainty about the nature of the flow regime under investigation.Our approach is to use three fundamental parameters, namely: flow velocity, solids concentration and particle size (for solid particles with a given density) to characterize the slurry and the flow conditions, and to match them with an adequate pressure loss prediction method. For each combination of flow velocity, solids concentration and particle size, a description of the most likely prevalent flow conditions and some known methods of dealing with them will be presented. Qualitative definitions of ""high"" and ""low"" magnitudes of the aforementioned parameters will be given as a general guide to the classification scheme presented in this paper."

Jan 1, 1992

By C. J. Li, J. L. Feng

In the present study we focuses on developing the poroelasticity model that deals with adsorptioninduced permeability change mostly occurred in porous media constituted several phases such as coal. The underlying pressure induced by adsorption is obtained by Virial expansion form, which is substantially founded on statistical physics. The corresponding thermodynamic pressure applying on the pore surface is then used to detail the pore pressure and further to evaluate the macroscopic volumetric strain and the porosity. In the process of physical adsorption, the adsorbed phase is in thermodynamic equilibrium with the gas phase regardless of pore size, and the corresponding chemical potentials are all equal. The relationship between surface strain and volumetric strain is derived under infinitesimal deformation conditions to gain an explicit formulation of pore surface area with respect to volumetric strain and porosity. After the formulation of surface stress modified by the Langmuir isothermal adsorption is derived, the differential micromechanical constitutive equations of porous media are obtained. By supposing that the ratio of current permeability to initial is equal to the cubic ratio of current porosity to initial porosity, the differential equations for permeability change is consequently derived. The numerical simulations by the present model for permeability change of coal induced by adsorption of CO2 and CH4, respectively, are presented under confined stress conditions. The predictions from the model are good in agreement with the experimental data of sorption-induced permeability change of coals in the literature.

Jan 1, 2015

By Bowmaker MD

Zinc and lead sulphide flotation con centrates containing from 0.02 to 0.20% Cd are roasted on an updraught sinter machine at the Cockle Creek Works of Sulphide Corp- oration Pty. Limited to provide sinter for simultaneous smelting of zinc and lead in an Imperial Smelting Furnace (I.S.F.). The major portion (about 85%) of cad- mium in concentrate feed to the Sinter Plant is eliminated with sinter fume and is rec- overed by weak acid leaching in the Cadmium Plant&apos;followed by counter-current decantat- ion, ion exchange concentration, precipitat- ion of cadmium sponge and partial refining to caustic refined cadmium metal. Cadmium not eliminated during sintering is volatilised in the I.S.F. and subsequently recovered as zinc alloy by distillation in the zinc ref- ining columns of the Zinc Refluxer. The partially refined cadmium metal and cadmium- zinc alloy are blended as feed to the cadm- ium refining column where separation and recovery of cadmium is effected. Condensate from the column is further refined under caustic soda flux and cast into anode shapes. Production is 200 t.p.a. at 85% recovery of cadmium in concentrates. Emphasis is placed on changes from the practice described by Baker and Munro (1965) and upon operation

Jan 1, 1972

By R. V. Wheeler, F. V. Tideswell

The suggestion, which appears to find increasing favor, that the elementary composition of coals should be used as the basis of their classification, makes it important that our methods of expressing this elementary composition should be refined. It is doubtful whether many published ultimate analyses of coals are accurate within 1 per cent. carbon. Many are probably as much as 3 or 2 per cent. in error in carbon. It is, perhaps, not always realized that the extreme variation in carbon content over the range of bituminous coals is but 16 per cent. An error of 1 per cent. in carbon on analysis corresponds therefore with one-sixteenth of the whole range, an amount which is unjustifiable even for the application to commercial needs of a system of classification based on ultimate analysis. For the purposes of scientific research such limited accuracy is of little value. The object of this paper is to examine one important source of error in ultimate analysis, that due to the occurrence in coal of inorganic material, and to emphasize the need for the quantitative measurements (of carbon more particularly) on coals to be rendered independent of their contents of such material. Adventitious Mineral Matter When a determination of calorific value, for example, is made upon a coal, it is customary to correct the measured value with respect to the ash left by the coal on incineration, recording the result as being on an "ash-free basis." It is desirable, before discussing the adequacy of the correction thus made, to demonstrate its validity, which turns on whether the ash is present as an adventitious impurity in the coal and forms no part of the coal substance itself. The inorganic matter associated with coal has originated in several ways1: 1. The "inherent" inorganic materials, occurring as constituents of the plants from which the coal-forming deposits were derived.

Jan 1, 1928

C. M. Bishop (Aircraft Div., A. V. Roe Cnnada Ltd., Toronto)—Reference is made to the coherency hardening of ß due to ß&apos; and also to the hardening of ß due to a coherent precipitation of the a phase. What is meant by the term "ß&apos;?" Would not the coherency hardening of ß during cooling be due to precipitation of a sub-microscopic dispersion of a, as is the case during reheating a ß-quenched alloy? I feel that these two phenomena are essentially the same mechanism, i.e., precipitation of a from unstable or supersaturated ß. From the text, it would appear that Tables III and IV are intended to show the effect of the martensite transformation on the properties of Ti-Mn alloys. Referring to Table 111, the ß-quenched alloys would contain a greater proportion of retained ß than would the equilibrated alloy. Could not the increase in properties be attributed to this, along with possible coherency hardening of the ß? In the same way, the structures referred to in Table IV contain ß from which they could derive their hardness. It would appear to be difficult, if not impossible, to assess the role of the martensite transformation from the data contained in these tables. F. C. Holden, H. R. Ogden, and R. I. Jaffee (authors&apos; reply)—In reply to the first question raised by Mr. Bishop, the term "ß"&apos; designates an apparent retained-p structure which is harder than it is after the most rapid cooling from the ß field. It is thought to be the result of a coherent precipitation of a. The mechanism by which hardening takes place is undoubtedly the same as that involved in the early stages of aging of a re-tained-p structure, and we are in agreement with Mr. Bishop on this point. The term "ß&apos;" to designate the anomalously hard retained-ß structure was agreed upon at a symposium in 1953." The authors do not agree that the quantity of retained ß and/or ß&apos; in the ß-quenched specimens of Table III is necessarily greater than that of the 600°C equilibrated specimens. The ß-quenched specimen has a structure which appears to be completely a&apos; formed by the martensite reaction. It is recognized that there could be some retained ß (or ß&apos;) between the a plates if the M, temperature is below room temperature. This is unlikely for the 3.4 pct Mn alloy where the M, is known to be at about 640°C. Therefore, the increase in strength cannot be attributed to the presence of a greater quantity of coherency-hardened ß, but, rather, the increase in strength must be attributed to the transformation products formed, e.g., a&apos; (martensiti-cally formed a). Concerning the data in Table IV, we agree that it is difficult to estimate the role of the martensite reaction, since the 6.4 pct Mn alloy was retained ß in the quenched condition.

Jan 1, 1955

By A. J. Langhammer

A. J. Langhammer.—That is rather asking a question of the wrong man. However, I will reply to the question from our point of view. There is a considerable amount of iron powder available but the properties vary over a wide range. Powder metallurgy has progressed to the stage where we recognize certain requirements in powdered iron, and what may be a good powdered iron for one application will not necessarily fit the picture for the next one. Further, I believe that there is room for great improvement in the properties of powdered iron. Also, that there is only a limited quantity of powdered iron available having certain specific properties in which we are at the moment interested. F. P. Peters.—May I have a word? With all possible respect to the contributions of the Chrysler Corporation (and they have been tremendous) to the war effort, I think it is easy to get from part of Mr. Langhammer&apos;s discussion a false impression of vaster possibilities than really exist. It would be well if in addition to Mr. Langhammer some other manufacturers of machine parts&apos; might tell us in the next few minutes some of the limitations they have found. For example, what is the maximum tensile strength that is being produced in a commercial part in production today? And what is the actual size limitation on bearings that are in operation and are standing up well? We should always bear in mind the fact—and I think Mr. Langhammer will agree with me— that quoting on a particular part does not necessarily mean placing it in production. In many cases it may be several months before the quotation is resolved and we know whether the part can be made. Let us open up this thing for a little free-for-all discussion of some of the ceilings that do exist in the design of machine parts made by powder metallurgy. The ceiling is not unlimited, and Mr. Langhsmmer will agree with that, 3 am sure. H. Hendriks.*—I do not think that there is so much limitation in the making of powder metallurgic manufactured parts as mentioned. Last year we had the problem of making dies for a special machine used in the manufacturing of slide fasteners. This part was wearing out very fast. It was very hard to make, it had to be hobbed out of a special steel and it was a difficult thing to manufacture in general. The tolerances were one half of one thousandth of one inch on all dimensions. We submitted this die to a manufacturer of powder-metal parts. He thought that it was impossible, but we were not as skeptical as he was and decided to try it anyway. The Canadian General Electric Carboloy Division, in Toronto, gave us then the design for the dies, which we made to their specifications. When the first part was delivered, we submitted it to our Inspection Department and its check showed that all the tolerances were right on the dot. They delivered I9 parts of exact specification, then they went off the beam; they could not keep to the tolerances. It took them a long time to get back again. We do not know what happened, but the main point I want to&apos; make is that if a problem is attacked in the right may, the dies are made right and corrected as to dimensions found out by experiment, I do not think that there is so much diffculty in making powder-metal parts to close tolerances.

Jan 1, 1945

By James O. Elton

This paper covers, besides laboratory work, a study of actual operation at the Washoe Smelter over a considerable period of time, together with the results of a visit to the Midvale plant of the United States Smelting & Refining Co., near Salt Lake. For the latter privilege, as well as permission to publish the resulting data herein given, I am indebted to George W. Heintz, General Manager of the Midvale plant, and here take pleasure in expressing my appreciation for the many courtesies extended to me by Mr. Heintz and members of the technical staff at the smelter. Almost all of the world&apos;s supply of arsenic is recovered as a byproduct in the smelting of other metals. It is seen &apos;on the market in various forms, the most common being arsenic trioxide, the " white arsenic " of commerce, which is sold as a heavy white powder, or in white, glassy, translucent masses. The trioxide is used in the manufacture of pigment, glass, and insecticides. About 50 per cent. of the domestic consumption is supplied by imports. Statistics of Arsenic Trioxide in United States.&apos; Production. Consumption. Price Per Pound. Year. Tons. Tons. Cents. 1907..........1.010 5.471 5 1908,.........1,302 6,098 33/4 1909,.........1,007 4,600 2 7/8 1910,.........1,526 5,428 2 1/2 1911,.........3,081 6,539 2 1912,2........ 2,926 Closed at 4 7/8 Arsenic occurs in combitlation with sulphur and the metals in a large number of minerals. It is present in small amounts in many ores. In the roasting and smelting furnaces many of its compounds break down, liberating arsenic trioxide, which is volatilized and carried by the gases into the flue system, where a part is condensed and settles with the flue dust.

Jan 1, 1914

By Arthur B. Cummins

POWDERED nonmetallic minerals and rocks of many different types are used extensively in industry for incorporation in compositions and manufactured products The term "mineral filler" is commonly employed to designate a material that is used for a specific purpose but not as an essential or reactive component Such a definition is not without objections, and it is indeed difficult to define fillers in any fully satisfactory manner, since the term has come to have so many different meanings and to cover such a wide range of uses. A filler is defined, for the purposes of this chapter, as a substantially inert material not specifically employed as a reactive or essential component, the primary function of which is to modify the properties or processing of a composition of matter or fabricated article Emery1 has emphasized that fillers change the properties of the product but are themselves unchanged in compounding or use The term "filler" appears to be rather general when referring to usages m bituminous compositions, rubber, composition floorings, fertilizers, plastics, textile finishes, and some others. In paper manufacture, in the paint industry and with insecticides, other terms are frequently employed, as is indicated, herinafter By placing emphasis on the function of the material used in modifying the properties of the composition or article, it is believed that a more useful classification of filler products and their applications may be derived. FUNCTIONS OF MINERAL FILLERS All of the manifold functions of mineral fillers cannot be listed in a summary review. A survey of the uses for these materials, however, shows that in nearly all cases the powders are employed to modify the properties of a composition of matter or those of a fabricated article, or to perform some useful function In the manufacture of either. A generalized list of these useful functions may be given is follows 1 To Modify Optical Properties Color Surface texture Opacity Brightness and gloss (as in paper and plastics) Flatness (as in lacquers and paints)

Jan 1, 1949

By Robert W. Bartlett

Pretreatment of sulfidic refractory gold ore by biooxidation in coarse-crushed ore heaps is a promising new technology, especially for low-grade ores that cannot afford pressure leaching or roasting. An algebraic equation for determining the economically optimum biooxidation of the sulfide minerals in the ore is provided that is based on the empirical biooxidation rate constant for the ore, the project&apos;s financial discount rate, the ore grades of both refractory and non-refractory gold, and the gold price. Then, the economically optimum duration of bioheap pretreatment, t$, is determined from its logarithmic relation to the optimum fractional extent of ore biooxidation, F$, through the ore&apos;s biooxidation rate constant. In doing so, it is assumed that the ore is adequately crushed and amenable to bioheap pretreatment and that the cumulative oxidation of the ore with time is known from ore testing so that the rate constant can be determined.

Jan 1, 1995

By A. J. Miles, A. D. Topping

in this paper, the theory of elasticity has been applied to the rock about a deep well, It is assumed that the rock has a modulus of . elasticity and a Poisson&apos;s ratio and that the theory of elasticity applies. It is necessary to know or assume the state of stress existing in the rock before it is penetrated by the well drill. The application of this theory indicates that stress concentration of shear, tensions, and compressions about the bore hole are of a high order. This is particularly true when a horizontal compressive stress exists in one direction only in the formation before drilling. If such an initial state of stress exists before drilling, then the rock will have stress concentrations of both tension and compression at the same elevation and of such magnitude that failure of the rock is likely. Accompanying these is a shearing stress of large proportion which is likely to produce spalling of the well walls. Internal pressure applied to the well bore will relieve the extreme compression but not the tension and has little effect upon the shear. Plastic deformation of the rock through a geological time tends to mitigate the stress concentrations. IntroductioN It has long been known that the stresses about holes and re-entrant corners of elastic solids under the influence of loads are different and generally more intense than those imposed upon the body else- where. Stress concentration at a re-entrant corner can be reduced by increasing the radius of the fillet at the corner. Stress concentration at the end of a crack in a plate undergoing either tension or compression Can be relieved appreciably by drilling a hole at the very end of the crack. Also, stresses can be increased in an elastic body in tension or compression by making a hole in it. The stress concentration is greatest at the edge of the hole. Considerable knowledge of the stresses which exist about the bore hole of a deep well may be had by applying our knowledge of engineering mechanics; or more particularly the theory of elasticity. It is, of course, necessary to make the assumption that the rock is elastic and behaves as an elastic solid, that is, that it obeys Hooke&apos;s law, has a modulus of elasticity, and a Poisson&apos;s ratio. It is also necessary to know, Or assume, the state of stress which exists in the rock prior to the penetration of the drill. With this knowledge it is possible to compute the stresses about the bore hole. The problem can be simplified by considering several simple cases separately and then by applying the principle of superposition to solve the more complex cases which are made up of the simpler ones. Case i—Rock Strata in Compression Penetrated by a Hole This case was first worked out by G. Kirsch* for structural material, but applies equally well to a horizontal rock strata in a state of in in one direction

Jan 1, 1949