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By F. P. Haver, M. M. Wong

The Federal Bureau of Mines has developed a leach= electrolysis method for recovering lead from galena (PbS). Flotation concentrate is leached with ferric chloride (FeCl3) solution to obtain lead chloride (PbC12) and elemental sulfur, PbS + 2FeC13 -+ PbC12 + 2FeC12 + Sº. Over 99% of the P~S in the condentrate is converted to PbC12. The leach solution, composed of brine (NaC1) and FeC13, dissolves the PbC12 as it is formed, leaving a residue of elemental sulfur plus gangue. Very pure PbC12 (>99.9%).is crystallized from the leach filtrate on cool- ing and is subsequently electrolyzed in a fused-salt bath to obtain molten lead metal (>99.9% Pb). Spent leach solution (FeC12) is regenerated for further use by reaction with the chlorine obtained in the electrolysis of lead chloride, and other values, such as Ag, Cu, Zn, and Sº, are recovered by additional treatments of the leach solution and leach residue. This paper discusses results and conditions of the leaching and electrolysis operations.

Jan 1, 1976

By Teague JWS, Jung RF, Kadletz O, Jones DR, Jones CJ

A study of the passive treatment system for Hilton minewater revealed that it consists of four main process steps. The water, which contains soluble and particulate iron and zinc and is supersaturated with CO , is pumped to the surface and then passes throuqh a degassinq unit into settling ponds where larger particles of iron hydroxide, containing some adsorbed zinc, can settle out. The still turbid supernatant is pumped to the top of a hill, from where it is allowed to trickle in a broad sheet, releasing CO , towards an earthen channel in the valley below. Consequently the pArises from around 6 to 7.5. This in turn promotes further decrease in the concentration of soluble zinc by increased adsorption of zinc on to iron hydroxide particles. The channel then transports the water to the third process in the system - a 53 ML pond acting primarily as a flocculation-sedimentation basin. The clarified water overflows into a second channel, downstream of the pond, which constitutes the fourth process in the system. Here, copious quantities of filamentous algae further reduce zinc concentrations to acceptable levels before the water is collected for recycle into mine operations. The work reported here represents a detailed study of this system and describes the optimisation of the operation of each of the individual steps involved.

Jan 1, 1988

By S. Svoronos, B. Moudgil, R. Stana, A. El-Midany

Due to their similar surface properties, it is not always easy to separate carbonate minerals from other salt type minerals by froth flotation. A particular example is the difficulty of separating dolomite impunities from phosphate minerals. Such challenging fundamental and practical problems have inspired several research efforts in various laboratories around the globe to find methods for economically removing the dolomite. However, a universal and cost effective process is not in commercial use. In this paper, a new process for separation of carbonate minerals (dolomite or calate) from other associated minerals is presented. Differential solubility of carbonates in slightly acidic solution is utilized to generate micro GO, bubbles at the carbonate mineral/ water interface. Particle (e.g., dolomite)/ bubble aggregates float to the surface leaving phosphate concentrate with low MgO content. Interestingly, up to 6.0 mm particles can be floated by such micro bubble/particle aggregates. Different sutface-active agents were tested to stabilize the bubbles. Results of these tests are presented and the mechanisms involved are discussed.

Jan 1, 2005

By Jianhui Wu, Jing Zhan, Chuanfu Zhang, Zhijian Wang, Chu-ping Xia

"A novel technology about interactive roast of complex bismuth sulfide ore with low grade and Pyrolusite was put forward using the low-grade bismuth sulfide ore and pyrolusite as raw materials. The predominance diagram of Bi-Mn-S-O system was drawn by thermodynamic calculations. Stable coexistence area ofBizO3 and MnSO4 and its control condition was obtained. The interactive roast conditions including roasting temperature, roasting time, the ratio of n(MnO2)/n(S), ventilation rate and so on are investigated systematically. The results show that the sulfur-retained ratio reaches about 98%, in which formation rate of MnSO4 was 94.04%, most of the residual sulfur in the ore exist in the form of BhsO32(SO4)10 in the roasting products The optimum roasting conditions were as follows: roasting temperature of 650°C, roasting time of2h, 1.4 for n(MnO2)/n(S) and 140L/h for ventilation rate.IntroductionBismuth is a ""green"" rare metal with the characteristics of safe, nontoxic and low melting point[l].The use of bismuth and its oxides is extending from traditional fields such as pigment, fusible alloy, bismuth class of drugs and metallurgical additives to the high-tech fields such as semiconductor, high-temperature superconducting materials and nuclear power and so on. Bismuth is one of the precious advantageous resources in China which owns the most abundant bismuth resources in the world. Bismuth metallurgical process is divided into the pyrometallurgy and hydrometallurgy [2-4]. Hydrometallurgy for bismuth is mainly used for the processing oflow-grade complex bismuth ore, whose key steps are oxidative leaching process of the bismuth sulfide ore by strong oxidants(FeCb, Clz, HNO2 etc) in hydrochloric acid system. Therefore, the corrosion of strong oxidants, high demand for equipments and poor operating environment are its inherent disadvantages. Pyrometallurgy for bismuth is mainly used for the processing of high-grade bismuth raw materials or concentrate, which is the main method for bismuth metallurgy at present."

Jan 1, 2013

The phenomenon of Instantaneous Outbursts, although not new to Australia, was sharply drawn to the attention of the local coal-mining industry by two isolated fatal occurrences on widely separated fields, both late in 1954. An outburst is the eruption of apparently solid coal from the face, aided by vast quantities of gas released from the coal, as the coal fails under mining stresses additional to its natural stressing.The gases involved are principally methane and carbon dioxide. The various factors which combine to produce outburst conditions range from external factors such as stresses arising from depth of cover and other causes, to inherent factors such as strength of coal,and its capacity to retain gases (sorption). Of the localities where instantaneous outbursts occur the Gard Basin in Southern France has had the greatest number and the most serious occurrences. By contrast, local outbursts have been minor.Experimental work into some influencing factors has been carried out by various overseas authorities and some research has been accomplished in Australia. Practices used in some overseas areas to improve safety of working are largely empirical, as are the local rules and recommendations for work in affected areas.The appearance of further outburst areas is anticipated as mining becomes more extensive and deeper.INTRODUCTION"Instantaneous Outbursts" can be described as violent eruptions of coal from the solid accompanied by considerable gas evolution. The projected coal is usually of small size, and a high proportion is pulverized, and may be carried and deposited over great distances by the gases, liberated from the outburst. This outburst coal is of bituminous to anthracitic rank, and the gas involved is essentially methane or carbon dioxide, or a mixture of both. Outbursts involving carbon dioxide are usually more violent and dangerous. The phenomenon is relatively unusual, being confined to probably sixteen known areas in the entire world, these areas comprising only portion of the coalfields in which they occur. Usually only one or two mines on each field are affected.

Jan 1, 1958

The Cadia mine is shifting from the open pit operation to the Cadia East underground block cave. The resulting increase in milled tonnes and the decrease in fines production through shifting to block caving require an increase of over 25% in installed power. This expansion is being accomplished via the installation of up-front crushing and HPGR milling of the ore, with the SAG mill receiving a secondary crushed feed. This design, criteria and rationale for selection is presented. Over the coming years, the mine will further expand capacity. The target is to accomplish this with minimal addition of installed power or use of fresh water. This presents a challenge that epitomizes the future constraints on our resource dependent and intensive industry. The approach and proposed options to this longer-term expansion are also presented.

Jan 1, 2012

By Cocker A

Pre-splitting for smooth highwall formation is conducted in around 75 per cent of surface coal operations within Australia. The CMTE (Centre for Mining Technology and Equipment) in conjunction with BHPAC (BHP Australia Coal) initiated a project to look at pre-splitting and to investigate the notching of blastholes for fracture plane control. The notching was specifically for pre-split initiation and also for discing of the toe of the production holes to minimise coal loss from the top of the coal seam. There are currently a number of factors which are driving the introduction of new pre-splitting technologies and products. The first is the ever increasing bench height being employed in strip mines which require a higher quality wall with less blast damage to maintain stability. Currently depths of 55 metres are common place with depths of 70 - 80 metres fast approaching. The second factor is the introduction of new technologies or methods which require a high quality highwall produced, eg highwall mining. This paper discusses the current state-of-the-art in pre-splitting and the main issues facing successful pre-splitting in the future. The use of a blasthole notching technology to promote fracturing along the pre-split line is also analysed. The review indicates that most pre-splitting challenges in the future can be addressed through better use and developments of current drill and blast technology. It is also concluded that a blasthole notching technique may find niche applications in improving final walls within a surface coal mine, especially where a high quality wall is required. The notched blasthole method may also allow pre-splitting in ground conditions and adverse rock structure which currently cannot be pre-split by existing technology.

Jan 1, 1995

INCREASE OF CATASTROPHE FREQUENCY AND SEVERITYIn the last couple of decades the frequency of natural catastrophes has increased dramatically. This realization results from the statistical analysis of the comprehensive loss data that we have been collecting constantly over the last 30 years and have evaluated in connec-tion with the preparation of our "World Map of Natural Hazards", which is now in its second edition (Munich Re, 1988). Each month brings data on between 30 and 50 new loss events. Fortunately, however, only a few of these have to be added to the list of major natural catastrophes, that is only those involv-ing damage that considerably exceeds what the country or region concerned can handle itself so that substantial na-tional or international aid is required. That is generally the case if the number of dead runs into the hundreds or thousands, if tens or hundreds of thousands of people are rendered home-less and if the total economic loss is in the region of US$ 100 million. These major catastrophes, about which we have fairly comprehensive data even in the case of those that occurred farther back in the past, numbered only 14 in the 1960s but 70 in the 1980s; they there-fore increased over a period of 30 years by a factor of 5. The trend is also very clear when we consider the total economic loss, which - adjusted for in-flation - increased during the same period from an average of US$ 3.7 bil-lion per year to US$ 11.4 billion, i.e. by a factor of 3.1. The insured losses, finally, increased by as much as a fac-tor of 4.8.

Jan 1, 1990

Sodium is added to aluminum-silicon eutectic alloys to modify the structure. The ideal amount is about 100 ppm but due to the fact that sodium is lighter than aluminum and can float to the surface where it bums, oxidizes ad volatilizes, a far greater amount is usually added. Furthermore, as the sodium is continually lost from the alloy the optimum amount is only present for a limited time. The net result is a process which is hard to control, produces fumes and a considerable amount of dross. It is shown that by electrochemically titrating sodium through a tube of sodium beta alumina electrolyte that the sodium can be added continuously in a controlled way. As the sodium is added to the bulk of the aluminum, there is no sodium on the surface of the alloy so that little surface oxidation occurs, and no fumes and dross are produced. This leads to an improved product and working conditions.

Jan 1, 1995

By Kimio Itagaki

Thermodynamics and rate process fundamentals are two of the important principles involved in nonferrous production processes. The process configuration establishes whether thermodynamics or rate process behavior is most relevant in a particular application. In this paper, thermodynamic theory and rate process fundamentals are used to analyze the main characteristics of smelting and converting processes. The effect of increased oxygen potential .is examined with emphasis in view of the increased use of highly oxygen-enriched gas in modem smelting processes. Phase equilibrium and the distribution of minor elements between copper or nickel matte and FeOx-SO2- or FeOx-CaO-based slag are reviewed. The use of oxygen-rich gas has no serious effects on 'the recovery of valuable copper and silver in the matte phase, while the recovery of nickel and cobalt is adversely affected. The oxygen content in the gas also strongly affects the distribution behavior of arsenic, antimony and bismuth. Analysis of the rate processes occurring in the shaft of flash smelting, and converting furnaces by a 3-D computational fluid-dynamics model is also discussed. After being validated with experimental data collected in a large laboratory furnace, the computer model has been used to simulate the main features of an industrial flash converting operation. The results present quantitative features of the improved mixing of the particle-gas suspension and increased oxygen efficiency obtained with a distributor-cone burner compared with those with a single axial entry burner. The role of basic principles in the engineering analysis of high-intensity matte smelting processes is also discussed.

Jan 1, 2002

By Thomas M. Baraak

This paper evaluates factors which influence longwall support and strata interaction. The longwall system is composed of an immediate and main roof structure and three supporting foundations: 1) longwall panel, 2) powered roof supports, and 3) gob waste. The main roof forms a structure that is generally supported by all three foundations, while the immediate roof acts as a beam that cantilevers from the coal face to the powered support. In most cases, shield loading involves a complex interaction of both main roof and immediate roof behavior and is a combination of loads produced from subsidence of the main roof and displacements of the immediate roof caused by deformations of the cantilevered roof beam. Since the shield stiffness remains constant for all leg pressures and main roof convergence is irresistible in terms of shield capacity, the shield must be able to control the behavior of the immediate roof or floor structure for shield loading to be sensitive to setting pressures. If the goal is to minimize total shield loading, any active setting force must be offset by reduced passive shield loading to justify the active setting loads. Field data suggest that the typical reductions in passive loading do not justify the required increases in setting pressure in some applications.

Jan 1, 1990

By F. H. Allen, R. P. Roe

The performance history of a volumetric gas condensate reservoir is presented. Curves depict the pressure-production relation and illustrate the phace behavior of the reservoir fluid. This performance is compared to calculated performance. This Bacon Lime Reservoir was discovered in 1941 and has been produced to field separators and gas sales. Reservoir performance has been observed by periodic bottom hole pressure sur. veys and companion sample analysis of well effluents, in addition to gas and condensate production data. , The pressure-production history demonstrates that the reservoir has produced under volumetric control. The "retrograde" behavior of the reservoir fluid is illustrated by decreasing butanes-plus content of the well effluent, followed by revaporization as the reservoir pressure approaches abandonment. Calculated performance predictions are compared to actual performance and some discussion offered on apparent discrepancies. INTRODUCTION Since the late 1930's, many gas condensate reservoirs have been developed, the retrograde theory of phase behavior has been generally accepted, and a number of cycling programs have been initiated. Numerous technical papers have since appeared in the literature dealing with the theory and application of cycling the gas condensate reservoirs. Some cycling operations have now advanced to a stage where it is possible to determine performance characteristics to a fair degree of accuracy. Field performance data for gas condensate reservoirs operated by pressure depletion have not been so extensively reported in the literature, although their probable behavior has been discussed in explanation of the retrograde theory. It is the purpose of this paper to compare calculated theoretical reservoir performance with field observations and well stream analyze; which have been obtained throughout the practical producing life of a small volumetric gas condensate reservoir. The reservoir under study is the Bacon Lime Zone of a field located in East Texas. The Bacon Lime occurs in the Lower Glen Rose Formation of Cretaceous Age. This Bacon Lime Reservoir is encountered at an average depth of 7600 ft (7203 ft subsea elevation) and comprises approximately 3100 acres located on a structural high with 80 ft of productive closure. The producing formation consists of approximately 50 ft of dense crystalline fossiliferous dolomite of generally low permeability with typical wide variation in both permeability and porosity, the more permeable stringers measuring 30 to 40 millidarcys. The average porosity is extimated to be 10 per cent with a connate water saturation of approximately 30 per cent of the pore space. The reservoir temperature was found to be 220°F and the original pressure was 3691 psia at -7200 ft elevation. The re ervoir was discovered in November, 1.941, and is now essentially depleted, Throughout most of its productive life, from the standpoint of cumulative withdrawals, the reservoir has been produced by five wells. During its latter stages of depletion, 16 wells were completed in the Bacon Lime.

Jan 1, 1950

By Howard Eavenson

IN a discussion in the Transactions of the Institute (vol. xl, page 835 et seq.) the writer gave some data about explosions of gas and dust in the coal mines of the United States, Canada, and Mexico, among which was a table showing all explosions in the countries mentioned, in which five or more fatalities occurred, which had been reported from Oct. 2, 1871, to Mar. 28, 1908. Since the elate of publication of this discussion, as opportunity has presented, this table has been extended by the addition of explosions occurring since that time, by including several explosions which occurred prior to 1871, and by adding to the list all explosions of gas or dust in which less than five fatalities occurred, this having been clone by a search through the various mine reports, partly by the author and partly by the Librarian of the United Engineering Societies, and by correspondence with mine inspection officials of the various States, to all of whom acknowledgment of assistance is made: The accompanying list, Table I, is believed to be as nearly correct as such a statement can be made, and, while only extending to Dec. 20, 1912, contains all of the data now available in reports. An analysis of Table I, showing the occurrence by months of all explosions of gas or dust, including those in which less as well as those in which more than five fatalities occurred, is given in Table II. The statements are frequently made, in technical papers, that the number of explosions, particularly the larger ones, is increasing more rapidly than the number of mines, and that the number of fatalities caused by mine explosions, particularly the more disastrous ones, is increasing faster, proportionally, than the production of coal. To investigate the correctness of these statements Table III was prepared, in which the number of accidents and fatalities is taken from Table I, using those in the United States only, on account of lack of other data for Canada and Mexico; the production is from the records of the U.S. Geological Survey, and the number of mines, from 1909, from the same source; previous to 1909, the number of mines, for the decennial periods, was furnished by the U. S. Census records.

Jan 10, 1914

By R. Fraher

The control of mine roof is of vital interest in underground coal mining not only for reasons of safety, but also to avoid the high costs of cleanup, resupport and production losses that can result from roof falls. The difficulty in determining roof stability mine-wide is due in large part to the broad variation of geologic and structural conditions that typically exist throughout a mining area. To ensure a stable roof over the entire mine, support systems must be selected to minimize the possibility of failure. The magnitude and cost of the support selected is a trade off against the cost of the number of falls that can still occur after it is installed. Because of the large number of variables involved in analyzing and optimizing roof stability versus support, a digital computer simulation was selected to find a cost effective solution to roof support design. A total cost approach is used which includes the actual cost of the roof support as well as the cost of the roof fall in terms of resupport and loss of production (Fraher 1990a). A Monte Carlo simulation program called ROCSIM (Roof control Optimization Cost SIMulation) has been developed for determining the optimum roof control system and design layout for underground room-and-pillar mining.

Jan 1, 1992

By Denise de La Corte Bacci

The Brazilian Regulation NBR 9653 is a guide intended to evaluate mine and quarry blasting effects in urban areas. The first version, written in 1986 by the Committee of the Brazilian Associate of Technical Norms, is currently being revised. Current regulations specify a maximum PPV limit of 15 mm/s (0.59 in/s) without consideration of frequency or type of structures being protected. The present regulation is still a draft and it is not validated. Several different agencies and institutions have participated in the Committee such as the Environmental Agency from the State of São Paulo (CETESB), University of São Paulo (POLI-USP), University of Rio Grande do Sul (UFRGS), National Department of Mineral Resources (DNPM), Aggregate Industry (ANEPAC and SINDIPEDRAS), besides a number of industry representatives, explosives manufactures and independent consultants. The present regulation proposes to modify the limits of particle velocity and introduces new definitions and criteria for evaluation of vibrations, as well recommendations to address blast vibration complaints.

Jan 1, 2005

By W. L. Dennen, V. H. Wilson

THIS paper is a description of the opera¬tion and results of a Humphreys Spiral Silt Cleaning Plant at the Powderly Colliery of The Hudson Coal Co. during the first nine months of operation and follows a pre¬liminary description given at the Anthracite Institute in May, 1947, in a paper titled "Preparation of Anthracite Sift for Boiler Fuel in a Humphreys Spiral Test Plant" by H. H. Otto, V. H. Wilson and W. L. Dennen. This plant is considered a full size operating test plant and, like all new plants, numerous minor changes in the methods of operation have been made from time to time to secure the results desired. Views of the silt preparation plant and of the screening house are given in Fig 1 and 2. This plant consists of 48 spirals in 8 batteries of 6 spirals each, 36 of which were to be operated as primary spirals and the remaining 12 as secondary spirals. A brief description of the plant and its operation follows. The only material cleaned at the plant during 1947 was that carried in the underflow from the Thickener which handles the Breaker waste water. This underflow, amounting to approximately 2000 gpm of water and containing 12.6 pct of solids, is pumped .to vibrating screens where the plus 316-in. material is removed. (Fig 3). This oversize material drops into a pocket from which it is trucked to the run-of-mine

Jan 1, 1948

By C. van der Poel, R. L. Chuoke P. van Meurs

When an initially planar interface between two im-ttitcihle liquids is displaced at constant rate, U, nor-mat to the front, instability will occur for all rates greater than a critical rate. U, given by provided the Fourier decomposition of the spatial pertmrbcrtiott or deformation of the moving displacetment front contains modes with wavelengths. A, greater than a critical wavelength, given by tit there expressions, p, p and k, with the subscripts I and 2 distinguishing the two 1iquids under consideration, are density, viscosity and effective pemeability coefficients respectively; g is the absolute value of the acceleration due to gravity; and cos (zz') is the direction cosit7e between the vertical carlesian coordinate z' (positive upward) and the z coordinate norma1 to the initially plane macroscopic interface taken positive in the direction from Liquid I to Liquid 2. U is the average volumetric velocity (injected volume of liquid pet. unit time per unit of area normal to Z) and is positive for Liquid I displacing Liquid 2, negative for the reversc displacement and r2 is an effective inter-fucial tension (for displacements between parrallel plates, t0= s the ordinary bulk interfacial tension). further, there is a wavelength of maximum instability given by For natural perturbations, this wavelength will preclotninate and characterize the form of the instability as a quasi-sinusoidal deformation, i.e., viscous fitzgers of peak-to-peak separatiotr, A,,. Comparison of experitient with theory rei'eals tltat these considerations are recsonably valid for displacements in hoth parallel plate chantzels and nnconsoli-clutt'd glass ptnvder packs. These results are. tij particular interest for interpretation of data from laboratory experiments with regard to fielil applica/iotz.s. It is quite possible for A,, although st7zall relative to the large lateral dimension of the reservoir, to rxceed the greatr.st lateral extent of the lahoratory sample or model. If it does, frontal displace- ment occurs in the laboratory experiments, and oil INTRODUCTION Thc puposes of this paper are to present theoretical and experimental evidence for occurrence of macroscopic instabilities in displacement of one viscous fluid by another immiscible with it through a uniform porous medium and to compare available experimental data with some predictions of a theory of instability developed by the first author. The instabilities are referred to as macroscopic in the sense that spatially quasi-sinusoidal, growing fingers of the displacing liquid are formed, the width and peak-to-peak separation (wavelength) of which is large relative to a characteristic length of the particular permeable medium such as grain size. Visual models of two kinds have been used to obtain observations: displacement of oil by water-glycerine solutions through the flow channel formed by closely spaced parallel plates and displacement of oil by water with and without initial interstitial water through unconsolidated glass powder packs, employing the technique of matching indices of refraction. In all cases we have observed macroscopic instabilities or fingers under conditions predicted by the theory to be favorable for their occurrence. The phenomenon discussed here is not the production of streamers due to gross inhomogeneities such as permeability stratification of the porous medium. It is our object to show, on the contrary, that a quantitative prediction of finger spacing is possible in a porous medium known to be macroscopically homogeneous and isotropic throughout. The importance of the phenomenon in its influence on the configuration of oil and water with respect to oil production behavior was noted earlier by Engel-berts and Klinkenberg' who coined the term "viscous fingering". THEORY Necessary and Sufficient Conditions ior Instability anc Initial Kinematics There are several levels of increasing complexity in the theoretical description of instabiIity of fluid displacements in permeable media. Of these, the simplest description, ;tdapted to low permeability systems, is selected for presentation.' More inclusivc tlescriptions are reserved for separate publication.

By Rossiter W. Raymond

I DESIRE to call the attention of the Institute to an interesting experiment, which may turn out to be an indication of a valuable improvement in the manufacture of steel. As the members are aware, the addition of ordinary spiegeleisen, in the open hearth or Bessemer converter, to a bath of decarbonized iron, has a twofold object,-the recarbonization of the bath to a desired degree, and the remedy of the red shortness otherwise found to be inevitable in the final product. This red shortness is ascribed to the presence of oxide of iron in the molten metal ; and it is supposed that the manganese of the spiegeleisen, uniting with the oxygen of such oxide, carries it into the slag. At the same time there is a small percentage of the manganese usually left in the cast steel, probably to the improvement of its quality. Whatever be the true explanation the effect of the manganese is acknowledged to be not only beneficial, but necessary. But the use of spiegeleisen containing high percentages of carbon limits the quantity that can be introduced, because the carbon must be limited if soft steel is desired. This inconvenience becomes so serious as to prevent the use of ordinary spiegeleisen in the manufacture of steel containing more than, say two-tenths per cent. of phosphorus; since the quality of the steel can be made tolerable only by reducing its contents of carbon in proportion as the

Jan 1, 1875

By Rossiter W. Raymond

I desire to call the attention of the Institute to an interesting experiment, which may turn out to be an indication of a valuable improvement in the manufacture of steel. As the members are aware, the addition of ordinary spiegeleisen, in the open hearth or Bessemer converter, to a bath of decarbonized iron, has a twofold object,—the recarbonization of the bath to a desired degree, and the remedy of the red shortness otherwise found to be inevitable in the final product. This red shortness is ascribed to the presence of oxide of iron in the molten metal; and it is supposed that the manganese of the spiegeleisen, uniting with the oxygen of such oxide, carries it into the slag. At the same time there is a small percentage of the manganese usually left in the cast steel, probably to the improvement of its quality. Whatever be the true explanation the effect of the manganese is acknowledged to be not only beneficial, but necessary. But the use of spiegeleisen containing high percentages of carbon limits the quantity that can be introduced, because the carbon must be limited if soft steel is desired. This inconvenience becomes so serious as to prevent the use of ordinary spiegeleisen in the manufacture of steel containing more than, say two-tenths per cent. of phosphorus; since the quality of the steel can be made tolerable only by reducing its contents of carbon in proportion as the

By W. M. Myers

[Utilization of small stone is recognized as one of the important problems of the lime industry. The term ?small stone' is used to designate material that is too small for calcination in tie shaft kilo. The maximum dimension A such stone rosy be placed at four inches. The introduction of any considerable quantity of stone having demensions lee: than this into the charge of a kiln impedes the draft and readers successful operation of the kiln difficult on impossible. Attempts design a shaft kiln which would calcine stall stone satisfactorily have not been successful to date. Thousands of tons of this small stone arc produced daily, and while part of it finds a market, for it has many uses, the profit is usually small an competition is teen and prices are low. Production of the material is, however, so greatly in excess of market that surplus of hundreds or possibly thousands of Jose axe place daily in stock piles and classified as waste. in a few instances a fortunate combination of circumstances, such as a program of or other work requiring large quantities of concrete aggregate, may mate it possible some quarries to market this stone later at a profit, teat in general the chances A profitable utilization are slight, and the quarry operator has the expense of handling this waste stone and providing a storage site for it. The brittle nature of limestone makes it impossible to quarry the stone and crush, it to size suitable for the shaft kilns without producing an excess of undesirable fines. Elimination of fines by changes in quarrying or crushing practices cannot lee expected. On the contrary, the adoption of more modern methods of quarrying in recent years has increased the proportion of small material. The tendency is to blast the roan with large charges of explosives and crush it with mechanical crushers, which produces more fines than the older methods of careful blasting with small char yes and sledging the rock by hand.. We increasing use of underground mining of limestone has also increased the production of small stone, as blasting in the confined space of an underground stope shatters the rocs more completely than quarrying in the open. The use of the very friable limestones, such as the limestone of Florida for the manufacture of lime adds a new factor to the calcination of small stone. These friable lime limestones have a low tensile strength and crumble in the kiln, causing trouble. Successful calcination of these stones is accomplished in specially]

Jan 1, 1926