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By Donald L. Katz, Leslie J. Noaker

Experimental data are presented for hydrate formation conditions for mixtures of hydrogen sulfide and methane. Vapor-solid equilibrium constants for hydrogen sulfide are also presented. Equilibrium constants, defined here as the ratio of the mole fraction of hydrogen sulfide in the vapor phase (dry basis) to the mole fraction of hydrogen sulfide in the solid phase (dry basis), were calculated using the vapor-solid equilibrium constants for methane presented in an earlier paper. The conditions at which a natural gas will form gas hydrates with water may be computed from its composition, when hydrogen sulfide is present in addition to carbon dioxide and the paraffin hydrocarbons. INTRODUCTION Many gases are known to form solid hydrates in the presence of liquid water at temperatures above 32°F. This hydrate formation is of importance to the natural gas industry inasmuch as most of the constituents found in natural gases will form hydrates. The attention of the industry was called to hydrates by Hammer-schmidtl0 in 1934. A number of papers have been written giving the temperatures and pressures at which these hydrates will form3,4,5,6,7,8,9,10,13,14,15,18,19 and a bibliography on the subject has been compiled13. Deaton and Frost4,5,6,7,8 report work for various pure gases and for some natural gases. Katz and co-workers3,4,13,14,18,19 have reported data for various gases at high pressure. They developed a method of predicting conditions for hydrate formation from equilibrium constants3,19 and from gab gravity." The effects of anti-freeze agents on the formation of hydrogen sulfide hydrate were reported by Bond and Nelson.' The hydrogen sulfide-water system, including hydrate, has been the subject of recent investigation by Sage and co-workers." Mixtures of hydrates behave as solid solutions and an equilibrium exists between the vapor phase and the solid phase that appears to be comparable to the equilibrium between vapor and liquid phases.3,10 By means of the vapor-solid equilibrium constants which have been published for methane, ethane, propane, iso-butane, and carbon dioxidel6 it is possible to determine the temperature and pressure at which hydrates will form for a specific gas mixture when water is present. Hydrogen sulfide which is frequently found in natural gases has a very strong tendency to form hydrate and must enter the solid solution when present in a natural gas forming a hydrate. To determine the effect of hydrogen sulfide when computing the conditions for gas hydrate formation, it is necessary to have the equilibrium constant giving the ratio of the concentration of hydrogen sulfide in the gas phase to the concentration in the solid phase. This paper presents data on hydrate formation for mixtures of hydrogen sulfide and methane and presents the equilibrium constants which were calculated from these data. EXPERIMENTAL PROCEDURE The apparatus used to determine the conditions of hydrate formation for the methane-hydrogen sulfide system was similar to that employed by previous investigators.3,18,19 A charge gas cylinder was used to supply the hydrogen sulfide-methane mixtures, called the charge gas, and to supply the pressure up to 1.000 psia. This

Jan 1, 1955

By E. E. Malouf

For centuries small amounts of copper have been recovered from acid mine-drainage waters. In recent years, the expansion of copper-bearing waste dump leaching for copper recovery has established a technological basis that is rapidly converting the art of copper leaching into a science. Copper leaching and recovery from solution has become an important adjunct of nearly all copper mining operations. Leaching of copper, whether from copper- bearing ore or waste, follows well established chemical reactions commonly in an acid circuit, but where leaching of copper is to be made in rock that is a high acid consumer, ammonia and ammonia carbonate, as well as cyanide leach solutions, can be used effectively. Current hydrometallurgical processes are being applied at an ever increasing rate to recover the trace amounts of copper in copper mine waste by in-place leaching. Currently approximately 300,000 tons of copper are produced annually in this manner while as recently as ten years ago, only one-eighth of this amount of precipitate copper was produced. Where copper occurs as an oxide in higher concentrations as to be classified as an ore rather than waste, then the hydrometallurgical processes are applied as percolation or agitation leaching in vats, pachuca tanks or prepared heaps. This approach gives better control over the recovery of the leach solutions, particularly in the processes where ammonia or cyanide leaching agents are to be used.

Jan 8, 1972

By H. Lyn Bourne

This is the 10th annual tabulation of US mineral royalties published in MINING ENGINEERING. The first year, 1982, the author solicited information about royalties and the cost of reserves. That column contained only a few royalties - not enough to tabulate. Since then, the response has been sporadic but the entries have grown to more than 300. Some have been deleted. Some of the older information has been deleted to make room for new entries. All indications suggest that the readers enjoy and use the information. But more information is needed. Russian practice In 1989, this column gave a brief history of mineral leasing and royalty payments as the concept applies to mining in the United States. This year's narrative deals with information about the mineral ownership in Russia. That country is in political and economic turmoil, including administrative systems and methods. And many laws are likely to change. What follows describes the Russian system of mineral ownership as of early 1992, according to Kirill Kavun. He begins "All the subsurface space of the Russian Federation with minerals contained belongs exclusively to the state. This forms the Common State Mineral Fund. Land parcels may be state, municipal, public or private property. They may be let to be owned and used by individuals, juridical persons, national/territorial or administrative/ territorial formations." This seems to apply to surface rights, as known in the US.

Jan 1, 1992

By Robert Corcoran, George Wiener

A study of the orientations and microstructure of 3 pct Si Fe alloys after deformation and recrystallization has been made. The components found after deformation agreed with recently published work on single crystals, being primarily (001) [110], (111) [110], and (111) {112}. A pronounced effect of temperature of recrystalliza-tion was found on microstructure and orientation. Low temperature recrystallization was interpreted in terms of low angle boundaries which resulted in the retention of a large amount of the deformation texture. High temperature recrystallization was interpreted in terms of high angle boundaries which gave rise to new components. No simple angular relation between the deformation and high temperature recrystalliza-tion textures could be detected. DEFORMATION and recrystallization behavior of 3 pct Si-Fe has been the subject of scientific investigation for many years. The fact that it is a single phase body-centered-cubic alloy from room temperature to the melting point permits study over a wide range of temperature without the complications of phase transformations. There is an important commercial interest in this material as well, since it is widely used in the electrical industry. In the present work the deformation and recrystallization behavior of poly crystal line silicon iron has been studied with the primary purpose of evaluating the effect of a second phase impurity on both processes as well as the effect of temperature on the recrystallization characteristics. With regard to deformation, the emphasis has been placed on a study of the crys-

Jan 1, 1957

By S. Dessureault

Computer Integrated Mining (CIMG) is a process of using computer networks to transform islands of enabling technologies into a highly interconnected mining system. CIMG involves the integration of advanced technologies at various levels in the mine business to achieve higher flexibility, better quality of processes and control, and improved profitability. Justifying the benefits of CIMG are difficult as many of the advantages are derived from improved flexibility, quality, and control. Justification is based on the evaluation of the benefits to be gained, compared to the required capital investment. Management tools used in mining are currently inadequate in assessing the value of advanced technology whose benefits are primarily qualitative. A key aspect of successful implementation is management acceptance, which has to be won through the capability to justify the technology's financial costs and the true value of all of its benefits. The manufacturing industry faced similar justification difficulties when adopting advanced technology in factories. A significant amount of funding and research was invested into developing management strategies and approaches to justification. Many of the problems that faced the transformation of the manufacturing industry in the late eighties and early nineties are now facing mining. The solutions derived for manufacturing may help mining in its transition to an increased reliance on integration technology. Reviewing the industrial history of computer integrated manufacturing identifies several tools and strategic frameworks that can be adapted for mining. Keywords: Computer integrated mining, justification techniques, CIM, information technology.

Jan 1, 2003

ATTENTION has recently been directed to the subject of dust production and methods of allaying same in the Broken Hill mines, so that the time would seem opportune for the local branch of the Institute to discuss certain features of an important phase of the health question in connection with underground work. Tests conducted in the Broken Hill South mine and at other mines at Broken Hill have shown that the ordinary operatioils of mining, such as boring, blasting, and shovelling, may be accompanied by the production of considerable dust unless water is judiciously used.In South Africa·dust particles under 5 microns size are regarded as dangerous, becailse they are so small as to be invisible to the naked eye, and wm esc'ape the protections set up by nature in the nose and throat, and thus may be inhaled in large quantity. A micron is 1 25000th part of an inch. This paper contains an account of the work done on the Broken Hill South mine chiefly, though some tests were done on other local mines.An acknowledgment is due to Mr. T. A. Reid, of the Broken Hill South mine, who conducted some of the tests herein mentioned, and under whose supervision most dust counts were made. Numerous dust samples have been taken by means of thekonimeter, an instrument designed by Dr. Kotze, the Government mining engineer of the Union of South Africa, and fully described...

Jan 1, 1921

By Robert L. Grayson

In small coal mining operations, little is done in controlling supply and material inventories and optimizing total inventory costs. Material Requirements Planning (MRP) is an efficient material control system which time-phases net material requirements based upon production plans, bills of material data, and inventory status records. Inventory levels and total inventory costs are optimized using a lot sizing technique in placing time-phased purchase orders. The MRP system has been applied in large manufacturing firms utilizing mainframe computers, but it can be adapted to micro-computers for inventory control. This paper presents an application designed to assist the coal mine manager in optimizing inventory costs.

Jan 1, 1985

By Terry S. Cory

This report describes a complete system design methodology for medium frequency (MF) wireless radio systems for use in coal mines. The emphasis Is on AC mines where no trolley wire exists and, for which, conventional trolley phone communications can not be used. The report constitutes an MF system design handbook and includes a compendium of all previous MF technology elements as well as a reference Index with abstracts of all pertinent literature. A particular strawman system design analysis is Included for the Helvetia Coal Co. Lucerne #8 mine In the Upper Freeport seam.

Jan 1, 1979

By Archer Wheeler

Introduction. THERE are two general methods in use for the production of metallic copper from matte which are worthy of consideration : (1) the Welsh blister process, and (2) the converter process.1 As practically all of the copper produced to-day is made in converters, we will give a brief outline of that process before proceeding with the special subject of this paper. Matte may be roughly defined as a mixture of the sulphides of copper, iron, nickel, silver, etc. In the converter process this is blown up to metallic copper in a modified type of Bessemer converter. The conversion of matte consists mainly in, (1) the removal of sulphur in the form of SO2, and (2) the slagging of the iron. With this brief statement we come to the two subdivisions of the process of converting mattes: Converting with acid linings. Converting with basic linings.

Jan 12, 1913

By Kwang-Ho Lee

The Onsan copper smelter of LS-Nikko Copper Inc. has operated the Mitsubishi continuous process along with Outokumpu process since 1997. Mitsubishi process is a bath smelting process which needs adequate melts for smelting reaction in the furnace. After a campaign shutdown it requires time to make a start melt. Onsan smelter has had much experience in flash smelting, including the improvement of the concentrate burner which is one of the most important parts in a flash smelting furnace. Based on this experience, the lances of the Mitsubishi smelting furnace were modified in order to making the starter melt with flash reaction. In 2004, the flash reaction in the Mitsubishi S-furnace was completed and was able to make the starter melt using these modified lances. Although at that time it was still under development it reduced the time required to make the initial bath-melt by about half.

Jan 1, 2006

The role played by lawyers in business has, in the course of the last 15 to 20 years, changed perceptively. This development has coincided with, and indeed has been a reflection of, the changing nature of Australian business, especially as the mining industry established its predominance in the Australian economy. The nature and extent of governmental regulation of business, too, has changed markedly. As a consequence, there has been a qualitative'change in the nature of commercial law practice. For the needs of business to be met, lawyers have had to develop specialist skills in new areas. Furthermore, there has been the emergence of the "in-house" lawyer, who increasingly plays a primary rather than a subordinate role in corporate law practice. There is no evidence to suggest that this trend, which is by now so well established, will prove to be ephemeral. Instead, with all indications pointing towards even greater governmental regulation of business activities, the intimate role of the lawyer in business seems entrenched.

Jan 1, 1980

By Robert L. Russell, Henry W. Zimmerman

The Bunker Hill mine in the Coeur d'Alene mining district at Kellogg, Idaho, has been a major producer of Pb-Ag-Zn ores since its discovery in 1887. The mine has produced over 29 million tons of ore from some 20 to 25 veins and ore zones and now covers an area approximately 1 mi long by 0.5 mi wide. The active section of the mine extends from 2500 ft above sea level to 1600 ft below sea level. Ore production is presently at the rate of about 1700 tpd. A 2-mi adit, the Kellogg tunnel, at the 2500 elevation provides access to the main shaft area. Ore is hoisted to the adit level through a 5000-ft. 50º-inclined shaft extending to the lowermost haulage level 1200 ft below sea level. Primary shaft service for men and materials is supplied by three major internal inclined shafts equipped with double-drum hoists. Present production requires ten levels to serve for main line track haulage. These range up to 5000 ft in length and are either 200 or 400 vertical ft apart. Also, many intermediate levels exist throughout the mine.

Jan 1, 1971

ABSTRACT- I Chemotrophic bacteria, capable of oxidising inorganic species such as Fe(II) and S(-]I) for their metabolic energy, have been known for many decades and interest in these bacterial species has increased since their ability oxidise auriferous arsenopyrite ores has been demonstrated. The rate at which bacterial cultures can oxidise a solid sulphide ore is of importance but a number of difficulties arise when attempting to evaluate this oxidative activity. The two major problems are counting the number of viable bacteria present in the reactor and identifying the types of bacteria that are active in both the solid and liquid phases. Enumerating the numbers of bacteria responsible for an observed change is necessary to compare the activity of different isolates. For selection and identification of bacteria during the development stages of a project, and for monitoring an operational process, the recognition of different species will be of importance. Methods for the taxonomic discrimination of bacterial species rely on observations, different culturing techniques, and the degree of DNA base homology between isolates. A method reported recently uses IR spectroscopy for comparisons between isolates. This spectroscopic method and its application is discussed.

Jan 1, 1991

By J. Donovan

Underhand cut and fill mining is being planned for selected areas at the David Bell Mine where high ground stresses have resulted in particularly challenging mining conditions. In order to test the placement and performance of a variety of underhand cut and fill paste mats three different designs have been installed and extensively instrumented along the A-Zone 9C ore sill. The sill is approximately 87m long, 4.0m high, and 5.0m average width. The sill was broken into 3 sections each of which will contain one of the sill mat designs. The underhand sill will be mined 3.75mW x 4.0mH, allowing for some overbreak while minimizing the risk of the back span exceeding the design limit of 4.0mW. Each test sill mat includes pre and post-support and includes 0.5m (18?) broken muck mat placed along the sill floor. Upon developing beneath these mats quantitative and qualitative measures will be used to determine which design is the most suitable for application in underhand mining at David Bell.

May 1, 2007

Modern technology and the need for published results have created the tendency for exploration to concentrate on drilling and assaying rather than building a broader geological understanding. Though grade is vitally important to a resource estimate, density and volume are also very important aspects that require equal consideration. Wet tropical nickel laterites are developed in humid environments over ultramafic bedrock where the nickel and cobalt are enriched to economic levels by weathering, leaching and supergene processes. These laterites often occur over rugged terrain at higher elevations where there is sufficient rain and stability for the long lateritisation process to occur. For nickel laterite profiles, the variable terrain and significant material type changes within the relatively thin profile make density and particularly volume estimation, just as significant as grade in resource estimation and assessment of resource risk. Drilling alone is generally not a cost-effective way to reduce the risk in laterite volume estimation to acceptable levels. Surface geological mapping, high resolution topographic data and other information such as ground penetrating radar (GPR) can be used very effectively to improve volume estimates. These data types are all differently structured, have different data density and quality and may potentially overlap. Integration of these disparate data types provide the most cost-effective approach to modelling wet tropical nickel laterite volumes and minimising risk. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Trevor Ames

Highwall instability, and sometimes referred to as ground failures, historically are a consistent contributor of mine injuries and fatalities within surface mines. To combat this several efforts, including those from NIOSH (CDC), to educate the mining community with insightful literature focused on hazard recognition and advances in ground monitoring systems have been performed. The question is can more be done or is this our last line of defense to manage potential dangers? Is there a more effective method to reduce hazards presented by ground failures including rockfalls?

Jan 1, 2015

By C. H. Wilson, J. W. Daly, J. J. Jakosky

Meteor Crater, Arizona, is a natural wonder which for years has been the subject of considerable discussion and study as to its origin and age (Fig. 1). Of the various theories advanced regarding the origin, two have been considered as most probable by a majority of investigators. The first theory is that the crater was formed by a meteorite or a swarm of meteoric material striking the earth at a high velocity and burying itself. The second theory is that the crater was formed by a "steam explosion" from hot solutions or gases coming from underneath the present sedimentary beds which overlie the area. In order to obtain more detailed information regarding the conditions existing at the crater, the present management decided to have a detailed geophysical examination made. The origin of the crater is of considerable scientific importance and interest. More or less active mining operations have been carried out during the past 20 years by various groups who believed that the crater was of meteoric origin, and who hoped that sufficient quantities of such material had been buried to be commercially valuable. Fragments of meteoric material found on the surface of the ground in the debris around the rim gave analysis of approximately 92 per cent iron and 8 per cent nickel, with some platinum and iridium. The material having a gross value of approximately $50 per ton, mining would be commercially profitable if sufficient quantities of the material existed in condition for mining. In the early work numerous drill holes and shallow shafts were put down, mainly in the northern portion of the crater. Pulverized material and debris caused considerable difficulty, and in an effort to overcome this the present management started a 1500-ft., two-compartment shaft on the south rim of the crater and outside of the fill zone. The intention was to sink the shaft in the solid rock outside of the crater, and then to crosscut toward the crater at a depth of 1500 ft. The work was finally stopped when a depth of 650 ft. was reached, because water poured into the shaft through large cracks and fissures in the rock. The enormous force responsible for the crater had also broken

Jan 1, 1932

This paper will discuss Fordertechnik dawatering screens and their application in process industries. Fordertechnik screens were designed for the dewatering of deslimed, wet fines materials encountered in the mineral beneficiation, sand and coal processing industries. However, these screens have also been used in such industries as municipal waste treatment, paper pulp, chemicals and the food industries. Fordertechnik screens are of simple design and, as a result, offer low capital and maintenance costs. The design is based on the use of twin counter-rotating vibratory motors which provide high frequency, low amplitude linear movement of the screen deck which is essential for high production requirements. Fordertechnik dewatering screens are engineered and manufactured in Australia by Mitchell Cotts Engineering under licence to Fordertechnik GmbH of Mulheim, West Germany

Jan 1, 1984

By Charles J. Speake, Dennis R. Haley, Thomas E. Finch

The tremendous interest in development of surface- mineable coal throughout the western US will bring with it a requirement for many manhours spent in mine planning and equipment selection. One problem in particular that engineers face during the planning stage is that of selecting a dragline with the proper reach capability. Reach, expressed in terms of operating radius and effective spoil radius, can be a major problem when mining deeper than originally planned, and aside from production requirements, the ability of a particular dragline to spoil across a strip is essential. Determination of dragline reach needed for a multiple-seam western coal operation can be simplified by use of an equation derived below that eliminates the need for tedious and repetitive calculations.

Jan 5, 1977

By P. R. Khangaonkar

The variety of intermediates, middlings, complex materials and wastes produced in the conventional processing of tin ores as experienced in the tin industry in South East Asia is reviewed. The problems associated with the treatment of these materials so as to produce useful products by hydrometallurgical or pyro-cum-bydrometallurgical approaches are discussed. Results of treatment of amang middlings consisting of cassiterite, struverite, ilmenite, zircon, monazite etc by chlorination with carbon tetra chloride are presented. The efforts to leach tin without letting iron coming in, by alkali leaching of certain wastes of tin processing are also briefly indicated. It is felt that pyro-cum-hydrometallurgical approach can help a viable treatment of these materials so as to obtain usable or value added products.

Jan 1, 1994