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By Walter Miller

Although confident of its ability to meet any demands that may be made, the petroleum-refining industry is not complacent about the situation and realizes that the quantities of petroleum products to be furnished are so enormous and so far beyond what was previously estimated that the full cooperative effort of the industry must be exerted. Establishment by the President in May of the Office of Petroleum Coordinator for Defense with Secretary of the Interior Ickes at its head, plus the formation of the Petroleum Industry Council for Defense, in November, provide the channels for united endeavor within the industry and the means for gearing that endeavor in full harmony with the nation's needs. Great strides have been made and a rapid understanding of the situation and the magnitude of the task is being attained by all concerned. Refining, by constant study and development, by willingness to experiment and install new processes, and to replace older plants with more efficient equipment, had kept on a high plane of efficiency and progress. Working under the free competitive system, it built up its establishments until, as expressed in last year's report, it was easily able to supply any domestic demand that might be placed on it. Turning the United States into the arsenal not only of itself but of the united nations resisting aggression, however, in- creased the call for practically all petroleum products and in particular 100-octane aviation gasoline and high-viscosity aviation lubricating oils. Refining Capacity With over four million barrels a day of crude oil being charged to stills at the year's end, oil refining had broken all records and faced the necessity of further increasing its size to supply the ever-increasing demand for products, some of which, like 100-octane aviation gasoline, were research laboratory curiosities a few years ago. Although the refining capacity of the United States is listed at 4,860,000 bbl., about 800,000 bbl. of this is economically unavailable because of plant location or type. To meet the increasing needs, additional capacity of another half million barrels may have to be built in suitable locations and designed with an eye toward maximum production of aviation gasoline but with inherent flexibility to make it possible to vary and interchange with production of motor gasoline, furnace oils, and other products as necessity dictates. An interesting side light on this refining capacity question was an enquiry from official Washington for knowledge as to any idle refineries of something of the order of 10,000-bbl. daily crude capacity that might be purchased for bodily removal to Russia. 100-Octane Aviation Gasoline Largest of the tasks confronting refiners at the year's end was that of raising

Jan 1, 1942

By Walter Miller

Although confident of its ability to meet any demands that may be made, the petroleum-refining industry is not complacent about the situation and realizes that the quantities of petroleum products to be furnished are so enormous and so far beyond what was previously estimated that the full cooperative effort of the industry must be exerted. Establishment by the President in May of the Office of Petroleum Coordinator for Defense with Secretary of the Interior Ickes at its head, plus the formation of the Petroleum Industry Council for Defense, in November, provide the channels for united endeavor within the industry and the means for gearing that endeavor in full harmony with the nation's needs. Great strides have been made and a rapid understanding of the situation and the magnitude of the task is being attained by all concerned. Refining, by constant study and development, by willingness to experiment and install new processes, and to replace older plants with more efficient equipment, had kept on a high plane of efficiency and progress. Working under the free competitive system, it built up its establishments until, as expressed in last year's report, it was easily able to supply any domestic demand that might be placed on it. Turning the United States into the arsenal not only of itself but of the united nations resisting aggression, however, in- creased the call for practically all petroleum products and in particular 100-octane aviation gasoline and high-viscosity aviation lubricating oils. Refining Capacity With over four million barrels a day of crude oil being charged to stills at the year's end, oil refining had broken all records and faced the necessity of further increasing its size to supply the ever-increasing demand for products, some of which, like 100-octane aviation gasoline, were research laboratory curiosities a few years ago. Although the refining capacity of the United States is listed at 4,860,000 bbl., about 800,000 bbl. of this is economically unavailable because of plant location or type. To meet the increasing needs, additional capacity of another half million barrels may have to be built in suitable locations and designed with an eye toward maximum production of aviation gasoline but with inherent flexibility to make it possible to vary and interchange with production of motor gasoline, furnace oils, and other products as necessity dictates. An interesting side light on this refining capacity question was an enquiry from official Washington for knowledge as to any idle refineries of something of the order of 10,000-bbl. daily crude capacity that might be purchased for bodily removal to Russia. 100-Octane Aviation Gasoline Largest of the tasks confronting refiners at the year's end was that of raising

Jan 1, 1942

By Edward A. Barrett, Lynn L. Rethi

Recent studies have shown that miners performing construction, maintenance, and repair (CMR) work activities in the conduct of their jobs incur from 39 to 65 percent of all reported injuries in the mining industry, The number is particularly high at surface aggregate operations; however, the problem exists at all mining locations and commodities. To address this issue, an interactive, (3-D) slides training exercise, Hazard Recognition Training Program for Construction. Maintenance and Repair Activities, was developed. The purpose of the exercise is to teach work& to recognize CMR hazards in the workplace and to deal with them using accepted safe work procedures. It was field tested using a total of 340 persons from surface mining operations in six states. The subjects were tested before and after the training intervention to determine if objectives of the instruction were achieved. Results indicated that 7 1 percent of the participants showed improvement in ink test scores. Following the posttest, subjects responded to a seven question Likert scale. These questions related to the validity of the exercise and the utility of the training program. More than 93 percent of the miners reported that they "learned something new from the training" and over 94% said they "would use these practices to work more safely".

By L. W. Saperstein

In this paper, a number of novel hypotheses that provide a fresh perspective on the characterization of strata movements associated with longwall mining are developed by analyzing subsidence measurements with an influence-function-based computer program. Using an inverse application of the traditional influence-function technique, easily obtained surface displacements are used to analyze some of the complicated, expensive, and difficult-to- measure movements of the intermediate roof strata in a longwall panel. The primary hypothesis developed by this analysis proposes the existence of an area of partial roof caving near the edge of a panel called the "edge effect." A secondary hypothesis, interrelated with the first, promotes the importance of the effect of gate-entry closure on the observed strata movements. Both the primary edge-effect hypothesis and the secondary hypothesis concerning gate-entry closure are justified and quantified in an extensive analysis of surface subsidence that uses supporting information from related theories, design criteria, and in situ measurements. Next, the edge effect and the gate closure hypotheses are extended further and used to provide an explanation of the complex subsidence interaction of adjacent longwall panels in what is termed a "redisturbed" effect. Finally, the importance of accurately understanding these longwall strata movements for proper subsidence prediction or gate design is stressed.

Jan 1, 1988

By R. M. Bowen

To help solve problems associated with the optimization of complex coal preparation systems, a mathematical model has been assembled which can simplify calculations pertaining to the core of the plant, i.e. the coal cleaning section. It uses algebraic expressions, derived by fitting hyperbolic equations to Mayer curves, to calculate optimum settings for a specified array of coal cleaning units and feeds. This is done without search procedures, and with usually only minor iteration of a simple calculation to specify optima within 0.02% of specified product ash contents. The key to the calculation is a relationship derived via the analytical geometry of conic sections facilitating easy application of the incremental ash theory of separations. The model has been assembled in a generalised form to cater for N processes in parallel, each giving M separations to produce P final products. Examples are given involving assessment of some complex circuit options.

Jan 1, 1986

By T Weldon

In the last 15 years, it has become increasingly popular to win gold and silver from carbon strip solutions with electrolytic æsludgeÆ cells. The precious metal sludges produced in the cells are washed to the cell bottom and pumped into filters. Most new operations are specifying sludging cells, and many older operations are being retrofitted with up-to-date electrolytic sludge cells and filters. The new sludging cells are generally more energy efficient than older cells, but more importantly, the cell operations to remove product are much less labour intensive, cleaner, and the operator need not have physical contact with the electrolytically produced metal. A case study of a major North American gold producer (50 000 kg/yr) that removed old style stainless steel wool cathode cells and installed new sludging cells and sludge filters is presented. The effect of various impurities is discussed.

Jan 1, 2005

By Simon D. Strauss

This article is part of a presentation Strauss made Dec. 3, 1988 at the sixth annual American Mining Hall of Fame (AMHofF) banquet in Tucson, AZ. At the banquet, the Mining Club of the Southwest honored Strauss by naming him the 1988 recipient to the AMHofF. (Industry newswatch, page 6). Introduction In the last two decades, there have been two previous periods of sharply rising copper prices. One was in 1973-74; the other in 1979-80. In both cases, a short period of high copper prices was followed by steep and prolonged periods of low prices. In the language of the market analyst, the high prices were called spikes. Is it likely, then, that three or four years from now the present price of copper will show up as a spike in the charts? There are substantial differences between the current position and the markets of 1973-74 and 1979-80. In 1973-74, US copper prices were subject to government-imposed price ceilings of $0.60 per lb through early December, 1973. These were increased to $0.68 per lb through May, 1974. Meanwhile, mines outside the United States were free of restraint. Rising demand in London pushed the price above $1 per lb in the third quarter of 1973. In early April 1974, it reached a peak of $1.50 a lb. In May of that year, the US ceilings were removed and the domestic price began to rise. What were the causes of this price strength? While ceilings held the domestic price below the world market, domestic consumers acquired all the tonnage offered by US mines. Meanwhile, in the world market, buyers feared prolonged shortages. The Club of Rome had warned that world economic growth would be limited by impending depletion of mineral resources. There was al so concern about a copper cartel that might increase copper prices even more. In early 1974, at a special United Nations session, developing-country spokesmen warned the industrialized world to expect high commodity prices. Also adding to the concerns of copper buyers was the fear that when US wage contracts expired in mid-1974, protracted strikes might ensue. The combined effect of this atmosphere was that consumers accumulated large amounts of copper, far above their normal carry. By midsummer, the position changed radically. While some strikes did occur in the United States, they proved short-lived. The most significant development was a massive economic recession. The energy crisis was causing enormous dislocations in the world economy. Construction activities were sharply reduced and automobile sales plummeted. Public confidence was shaken. Copper sales fell precipitately as consumers decided to draw down their swollen inventories. The price came down too. In April 1974, the London price- as noted-was $1.50 per lb. By the end of the year, it was down to $0.57 per lb. In 1973-74, the copper price rise was fed by fears of shortages, cartels, and strikes. In 1979-80, the market rose on the strength of good demand plus political and military instability. The price rise was also fed by inflationary trends, exemplified by speculation in precious metals. Prior to this second spike in copper prices, the market had been depressed despite economic recovery. Despite reduced US output, copper production in the rest of the world was increasing. Though consumption was rising, surplus stocks reached unprecedented levels. At the end of 1977, the aggregate of stocks at the refineries and in the exchange warehouses was 1.5 Mt (1.67 million st). That was more than three months' shipments at then rates of consumption. In 1978, the statistical position improved. Shipments of refined copper that year were 8% greater than in 1977. The result was reduced visible stocks but -just as was to be the case in 1984-86 - the price remained depressed. In 1979, an even sharper drop in visible stocks occurred as shipments rose by another 4%. This time, though, the price responded. In December 1978, the price in current dollars had been less than $0.70 per lb. By the end of 1979, it was above $1 per lb. And in the first quarter of 1980, it averaged more than $1.20 per lb. Military and political developments were a factor. The hostage crisis in Iran was followed by the Soviet invasion of Afghanistan. To many, it appeared that war might result if the Soviets pushed on into Pakistan. At the same time, speculation drove gold and silver prices to incredible levels. As silver prices rose above $40 per oz), copper above $1 per lb did not seem unreasonable. Then, in March 1980, the precious metals price boom collapsed. Copper prices also retreated, though not as much. In February 1980, the copperprice averaged $1.32 per lb. By December, it had dropped to $0.85 per lb. In 1981 and 1982, the decline continued. The present copper situation Why is the current situation different from these two previous episodes of high prices? First of all, today's inventories are far lower than they were in either 1974 or 1980, when the price declines began. The stocks at refineries and in exchange warehouses are substantially less than they were then. More significantly, consumers today have very limited holdings compared with stocks they carried in 1974 and 1980. Even if faced with a downturn in their own business, copper consumers will not be able to stay out of the market. To the extent they have any business at all, they will have to buy copper. And on the supply side, there is also a significant difference. The year 1988 has been unusual. US production is up sharply, responding to higher prices. But production is little changed in the rest of the Free World. Indeed, several of the major producing countries have mined less copper this year than in 1987 despite the prices increases. Peru has had labor problems that have cut its output. Zambia and Zaire suffer from shortages of expatriate technicians, not to mention spare parts. They also suffer from the failure to maintain equipment or perform adequate development. In Chile, the two largest mines, Chuquicamata and El Teniente, have not met their production targets. Chuquicamata is struggling with high arsenic content in its ore. And, in late 1987, severe rockbursts hampered operations at El Teniente. In addition, depletion of some mines in Australia and South Africa has offset rising output at other properties. Indeed, when final mine output figures for 1988 become available, it may well be

Jan 1, 1989

Featured at the 1977 SME-AIME Fall Meeting in St. Louis is a Lead-Zinc Update, organized to complement the 1970 AIME World Symposium on Mining and Metallurgy of Lead and Zinc, also held in St. Louis. The 21 papers comprising the Update are to be presented during four technical sessions at the Fall Meeting; in addition, the papers have been collected in a bound book available at meeting time.

Jan 9, 1977

By M Armstrong, S J. Coward, A Galli

Mine management is often expected to make rapid evaluation decisions at different stages of projects based on limited and uncertain data. The challenge is exacerbated by having to distil technical complexity into a financial model that is usually designed to produce only one or two key indicators, eg net present value (NPV), internal rate of return (IRR). Mining is a complex environment with many sources of uncertainty ranging from sampling to economics. In order to optimise investment decision-making, an appropriately structured evaluation framework must be utilised. An evaluation framework should be designed to encapsulate and integrate the complexity across the evaluation cycle, ie sampling, resource estimation, mine planning and treatment, and financial and economic modelling. This complexity is diverse and ranges from sampling support, scale effects to understanding the impact of variability, uncertainty and flexibility on operational efficiency and economic viability. These complexities, combined with time and capital constraints, usually do not allow all facets of evaluation to be integrated into the model. The model must strike a balance between simplified estimation techniques and sufficient incorporation of aspects of the project that will make a material difference to the investment decision. This paper demonstrates the impact of the scale of measurement on the valuation of a mineral project. Comparisons are made between global estimation averages using a top-down approach and local estimates using a bottom-up approach. Three sampling campaigns were conducted on a virtual orebody to compare the relative NPV accuracies. Stochastic forward models were run on foreign exchange rates and are compared with the results from a fixed foreign exchange rate model.

Jan 1, 2006

By Cz. Mazanek

Specific biostimulating and anticancerous properties have been observed in peat, Ash Vacanta, and in an amorpous silica that is obtained as a by-product of alumina production from Turow clay in Poland. The anmphous silica was characterized and found to have a large specific surface area. This property may account for the beneficial characteristics of the material.

Jan 1, 1989

A tough Conservation Act has been in force in Pennsylvania since January, 1964. Known as the Bituminous Coal Open Pit Mining Conservation Act, it is now under study by other coal producing states, and seems likely to serve as the blueprint for similar legislation elsewhere. It provides for the conservation and improvement of areas of land affected by open pit mining to decrease soil erosion, prevent pollution of rivers and streams, prevent combustion of unmined coal and generally improve the use and enjoyment of such lands. The cost of backfilling may go to as much as 40[c] or more per recovered ton and is cutting deeply into already reduced profit margins brought on by rising labor and equipment costs, static coal prices and less accessible coal. As a result, operators will be forced to seek greater efficiency.

Jan 7, 1965

By Amirhossein Molavi Tabrizi

In this paper we introduce a realistic model for mine openings that explicitly considers the effects of local irregular topography. Also, we consider the effect of entry orientation and rock anisotropy on the induced stress fields around mine openings under the given in-situ stress field. A triangular mesh formulation is derived for representing complicated irregular surface topography and underground openings. Each element contains three internal collocation nodes. Parts of the surface which are far from the mine openings are discretized by infinite elements. The rectangular infinite elements with three internal nodes are introduced specifically for this problem so they are compatible with the triangular elements. With the corresponding boundary element method (BEM) formulation, we then investigate the combined effect of the topography and entry orientation on the stress fields induced by openings in anisotropic rocks under in-situ stresses. A single rectangular opening in the anisotropic ground with topography and in-situ stresses is simulated using data from the Carroll Hollow mine in Ohio. The results of these simulations show that topography, rock anisotropy, orientation of the regional stress field and mine opening geometry all have appreciable effects on the stress fields around underground openings, yet these factors can all be accounted for in an efficient code with no need to discretize the model domain. Future applications using this new BEM formulation will provide useful guidance on selecting the optimal opening orientation in the mine in order to minimize undesirable stress concentrations around underground mine workings.

Jan 1, 2014

By Robert B. Parsons

"The new Ontario Liberal government introduced its first budget in October. The changes to The Mining Tax Act proposed in the budget are mean t 10 simplify the current system without any loss of revenue to the government. It goes without saying that some operators will benefit from the changes while others will pay more taxes after 1985.With regard to ongoing matters at the federal level, the proposed carve-out legislation and the issue of northern allowances are being discussed with government officials, and a small victory has recently been scored with regard 10 the laxation of certain share transactions of prospectors and grubstakers. A report on these issues is provided herein.Ontario BudgetOn October 24, 1985, Ontario Finance Minister Robert F. Nixon tabled a budget proposing several significant changes to both the Ontario Mining Tax Act and the province’s income tax legislation.Mining Tax ActA flat rate of tax and reduced processing allowances highlight proposed changes to The Mining Tax Act. The proposed changes, with a comparison to the existing system, are set out in Table I.The most significant change is the replacement of the graduated tax rate schedule with a flat 20010 tax rate. This is a welcome change for most mine operators who viewed the high rate of 30% on profit over $20 million as counter-productive.However, the flat rate of ta x may not be welcome to all operators. Generally speaking, operators with less than $ 10 million annual profit are better off under the graduated rate system, while operators with annual profit exceeding $10 million will benefit from the 20010 tax rate."

Jan 1, 1986

By Liang Yu, Yuhua Li, Yuanchi Dong

"High alumina slag, with alumina normally more than 15 pct, is encountered with blast furnaces in China because of high alumina/silica ratio in iron ore as well as sinter and high ash content in coke for cost reason. High alumina slag with high viscosity and high liquidus temperature would lead to higher slag volume and thereby, furnace productivity. In the present work, liquidus temperature of high alumina slag, based on Meishan factory, Baosteel China, were investigated. A liquidus temperature model was introduced in the present work based on basic physical chemistry theory and focused on the chemical composition area used in Meishan factory(pct): Al2O3 from 14 to 17.5 and MgO from 8 to 12, so that the blast furnace slag could be designed for optimum blast furnace performance.IntroductionBlast furnace slag composition[1] has very important bearing on its physicochemical characteristics which affects smoothness of operation, slag handling, coke consumption, the degree of desulphurization, hot metal productivity and its quality etc. The slag properties which affect most are liquidus temperature, viscosity, sulphide capacity and alkali capacity. Variation of these slag characteristics with composition and temperature has been a field of active researches as these its great influence on the blast furnace operation. In the early years, most of these studies were carried out over low alumina blast furnace slags with alumina normally less than 15 pct. High alumina slag was first introduced in India because of its high alumina/silica ratio iron ore as well as sinter and high ash content in coke[2]. And then this problem becomes common as higher alumina/silica ratio iron ore imported and used [2-5]. The most important problem caused by high alumina content is liquidus temperature and then viscosity of the slag.Generally speaking those reported works [2-5] investigated a pretty wide range of chemical compositions and then obtained complex model, respectively. In fact, every factory has its own interest because of different resources. For example, the Al2O3 content from 20% to 30% pct was studied in Tata Steel India [2], but it is too high for Baosteel Meishan. A very lower percentage of alumina content, 14-18 % pct, was mainly used."

Jan 1, 2008

By Catherine Johnson, Kelly Williams

The ability to measure the overpressure of a shock wave is necessary for explosives research such as shockwave focusing and field testing of blast-resistant designs for buildings and vehicles. To record the peak overpressure of the nearly instantaneous pressure rise at the shock front, pressure transducers with a fast response rate and streamline pencil design are needed. Time spent setting up sensors coupled with the expense of high-frequency data acquisition systems, and the inconvenience of low impedance cables can make the process challenging. Additionally, only small inaccuracies in sensor position can drastically change the measurement recorded. Advances in high-speed video imaging make it possible to see the refraction of light due to the high-density gradient at the shock front without the need for parabolic mirrors or additional light sources necessary for Schlieren or shadowgraph imaging. The average shock front velocity between two points can be calculated by dividing the change in position by the elapsed time between the images. Using the Rankine-Hugoniot relationship demonstrated by Swisdak the peak overpressure of the shock wave can be calculated from its velocity eliminating the interference of the gage and mount. This paper investigates the accuracy of this method by setting dual transducer pencil probesat0and180 degrees perpendicular to the central axis of a285-gram(0.63-pound)cylindrical charge to record pressure versus time for comparison to the high-speed video. The axis of the camera lens is aligned with the central axis of the charge with both pencil probes in view. The pencil probes have two pressuretransducersset100millimeters (3.9 inches)apart to measure the time of arrival and are used to validate the velocities calculated from the high-speed images. This method can be used to evaluate the shock wave propagation from more complex prismatic charges with different cross-sectional shapes where precise placement of cumbersome pencil transducers in the near field is almost impossible.

Prediction of fragmentation in Taconite Mining is an important aid to blasting engineers. A simple theory relates the intensity of radial fracture per unit length to distance from the borehole, from which a power law for mass fraction passing versus size is derived. For the lower end of the size distribution, the equation agrees well with several published examples of fragmentation from sieving of full scale blasts. Large size fragments arise from interaction of fractures from neighboring holes and pre-existing joints. Analysis of two assumptions regarding radial fracture interaction shows that complex fragmentation distributions can arise from the simple mechanisms proposed. Measured fragmentation falls between the two extremes calculated.

Jan 1, 1996

By John E. Udd

I N Part I of this paper, Professor Morrison suggested that our technique of causing cracks to develop around openings in a sheet of photoe1ashc plastic is, in effect, a laboratory-scale rockburst. Our investigations have indicated that the location and direction of these cracks are predictable, and that their growth can be controlled. On several occasions, we have been able to cause these cracks to propagate sufficiently slowly to be followed, with the naked eye. In practice, the rate of growth, gradual or sudden, would depend upon rock properties. This part of the paper presents an analysis of the stresses surrounding the openings before and after failure and also this author's views on the causes and after-effects of cracking. An attempt is made to correlate the stress patterns with those deter-mined from pure mathematics. Considering that the openings, except for the central enlargement, are long apertures with somewhat rounded corners, they might be compared with elongated ellipses having axes ratios of about 20:1 or with

Jan 1, 1963

By T. G. Decker, A. F. Witt, A. M. Gaudin

The historical development of the concept of contact angle hysteresis is reviewed. The measurements of contact angles reported in literature have all been made under static conditions. For the measurement of dynamic advancing and receding contact angles, four methods are described together with an evaluation of their precision. Three of these methods were adapted from devices already used for the measurement of static contact angles. The fourth method uses a new principle and apparatus and is the most accurate. While the relationship between surface tensions and the contact angle was extablished as early as 1805 by T. Young,' it was only in 1890 that the existence of contact angle hysteresis was reported by Lord Rayleigh. His observations, however, remained almost unnoticed. With the invention of froth flotation, the contact angle and its behavior became the subject of investigation. In 1907, L. Sulman and collaborators investigated the cause of discrepancies between recorded values of contact angles. They found that certain variations existed in most cases, but that definite maximum and minimum values of contact angles are obtainable. The difference between the maximum and the minimum contact angle in a given system was termed "hysteresis" by Sulman. First attempts to explain hysteresis were made by E. Edser. In the following years extensive studies of contact angles in various three-phase systems

Jan 1, 1963

By G. E. Agar

The energy required for dry grinding of phosphate rock in ball and roller mills has been analyzed by the method suggested by Charles and others. The findings are not wholly in agreement with Charles' predictions; but, nevertheless, the method of analysis is shown to be sound. Some of the deviation is probably attributable to the characteristics of a dry grinding system. Many laboratory and pilot plant scale experiments have been made to determine the energy requirements for size reduction. This topic was recently reviewed by Agar and Brown' and it was apparent that very little if any data exists in the literature which permits one to apply the Charles 2-Holmes3 analysis to industrial size systems. More recently, the idea has been put forward that the postulate of comminution by impact used by Charles and others was not sufficient to explain size-reduction throughout the grinding operation. The opportunity exists in the grinding operations of International Minerals and Chemical Corp. (IMC) to analyze the energy-size relationship for dry grinding phosphate rock in both ball and roller mills. This situation arises because the mills are used for custom grinding and make products from 50% to 85% minus 200 mesh. BACKGROUND A correlation of particle size in a comminuted material with the energy expended in size reduction was proposed by charles2 to be of the form

Jan 1, 1965

By Wendell H. Wiser

A comparison is presented of coal pyrolysis at temp¬eratures ranging from 4090 to 497°C and thermal dissolution of coal in tetralin at temperatures ranging from 350° to 450,°C, both utilizing a Utah high-volatile bituminous coal. The initial coal pyrolysis reactions are second order with an enthalpy of activation of 35.6 kcal per mole. The fraction of total product yield produced under second order conditions ranges from 67% at 409°C to 96% at 497°C. The process then gradually deteriorates to a first order reaction in the later stages with enthalpy of activation of 4.1 kcal, per mole. The initial reactions of solution of coal in tetralin are second order with an enthalpy of activation of 28.8 kcal per mole. The fraction of total product produced under second order conditions ranges from 63% at 350°C' to 94% at 450°C. The dissolution process then gradually changes to first order in the later stages with enthalpy of activation of 15.6 kcal per mole. A model is presented which relates the two processes and explains, the significance of the above similarities.

Jan 1, 1967