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By Nathaniel Arbiter, A. F. Taggart

The chemical reaction occurring in collection of nonmetallic minerals with amine-type collectors was early postulated by students of flotation phenomena to be metathesis between the mineral and the collector, involving exchange between the amine-bearing (aminium) ion and the cation of the mineral, and formation at the mineral surface of an oriented film of the amine salt of the mineral anion. Qualitative evidence of exchange has been obtained on several occasions at Columbia. Thus 1000 C.C. of a solution containing 495 mg of laurylamine hydrochloride was shaken 17 min. with 100 grams of barite and ground in a porcelain mill to pass a 200-mesh screen; the mixture was then set aside for 48 hr. Filtrate therefrom analyzed 476 mg. per liter of laurylamine hydrochloride. There was no substantial loss of chloride ion (78.4 mg. per liter in the original; 74 in the filtrate). No successful analyses were concluded for barium ion. Earlier, confessedly rough work with scheelite indicated a solution gain in Ca++ equivalent to about one-half the aminium ion lost. Real quantitative roof of the exchange, in the form of an established stoichiometric balance, is unknown to the authors. The data of the present paper, however, obtained from experiments designed on the basis of the exchange hypothesis, constitute strong evidence of its truth, and at the same time point the way to economic utilization of the expensive nitrogen-bearing collectors in concentration of the low-priced nonmetallic minerals. The basic postulate underlying the experiments performed was that, if the collecting reaction is of the type R+ + Y- + MX = RX + M+ + Y- where R = aminium ion, Y = the anion of the amine salt, and M and X are, respectively, the cation and anion of the mineral, the reaction should obey qualitatively the implications of the mass-action and solubility-product laws. This is to say that coating and collection should be aided by the addition to the solution of either ion (R+ or X-) of the collector-coating compound, and hindered by the addition of either of the ions M+ or y-. Experimental work comprised determination of (,) the relative solubilities of the laurylammonium salts of a variety of nonmetallic-mineral anions; and (21 the contact angles' of various minerals in solutions containing different concentrations of the postulated controlling ions. Semiquantitative flotation tests were run With barite as checks on the diagnostic character of the contact angles. The amine

Jan 1, 1947

By C. A. Pickles, S. J. Splinter

Silicon oxynitride, Si2N20, has many of the intrinsic properties of a potential high temperature engineering ceramic material. Some of these properties are similar to those of silicon nitride, which has been more intensively studied. However, although silicon nitride ceramics are approaching a state of microstructural refinement for various engineering applications, silicon oxynitride has received little attention. This has been mainly due to a lack of an economical and reproducible method of producing pure crystalline Si2N2O. Several reports exist on the preparation of crystalline Si2N2O from SiO2 and Si3N4, yet very little kinetic data exist. Even less is known about the carbothermic reduction of SiO2 in a nitrogen atmosphere to produce Si2N2O. In this paper, a review of the properties and methods of preparing silicon oxynitride will be presented. In addition, results obtained by reactively sintering SiO2 and Si3N4 will be discussed. The overall reaction is as follows:

Jan 1, 1990

By E. Beril

This may be a most unnecessary paper—from what does crude oil come and how was it formed. Many people, inside and outside of the petroleum industry, believe that we have actually enough oil, and that we can easily produce very important products from this extremely valuable raw material. The writer believes, however, that the answer to this question concerning the parent material and the formation of oil is of broader interest, because it may be that from the answer to these problems it would be possible to get answers to other important industrial questions. Therefore, a study in this line seems to be justified, and the writer will submit some of the results which he has collected during more than ten years with many very capable collaborators, to whom his thanks may be expressed on this occasion. Older Theories There is no doubt that plants were the parent material of coals, but opinion is divided as to the parent material of crude oil and asphalts. One group of specialists believed that they were formed from dead fish. The hydrocarbons of crude oil were formed by the splitting off of CO² from fatty acids formed by the saponification of the fat (glycerides) of fish. Enormous quantities of crude oil are present in many places on the earth, very often in several nonconnected horizons at the same location. This could hardly be explained by the so-called "catastrophe theory," which states that fish died through the entrance of salt water into fresh water, and vice versa. Furthermore, this theory cannot explain the presence of aromatic hydrocarbons, which can be found in nearly all oils, especially in the oil of the Netherlands Indies, which has more than 50 per cent of aromatics. Geological and chemical observations both lead to the belief that the temperature of formation of asphalt, crude oils and coals, perhaps with a few exceptions, did not exceed 200° C. Chlorophyll and haemin derivatives, which decompose above 200° C., have been found in all these materials by Treibs and others. Thermodynamic considerations show that the temperature necessary for the conversion

Jan 1, 1938

By Barro L

There is currently a world wide interest in coal-oil technology as the search continues for alternative energy sources to reduce the consumption of petroleum crude. An important aspect of this coal-oil technology study is to obtain information on the flow properties of coal-oil slurries. While some work has been reported on the flow behaviour of black coal-oil suspensions, very little work on brown coal-oil suspensions has been reported. In this paper flow charac- teristics of brown coal-oil suspensions for various coal concentration and temperatures have been presented. A Capillary rheometer, designed to handle settling suspension, has been used for deter- mining rheological properties. Brown coal of 0 0725 mm average particle diameter has been used in this work. The oil was a coal derived product having a boiling point range of 234¦- 319¦C, Apparent viscosity of all suspensions was found to increase on storage due to ageing. Ageing might have occurred due to physico- chemical interactions between coal and oil. Flow behaviour of some suspensions changed from Newtonian to non-Newtonian on storage.

Jan 1, 1980

Experimentation with new methods, materials and machines to improve primary drilling and blasting is a continuing practice in the hard rock quarry operations of the BMI Group. These experiments will continue in the remote hope that one day we may produce a perfect feed for the primary crusher. As this day is still a long way off, the necessity to break oversize boulders will be a problem to be faced for the foreseeable future. To gauge the efficiency of primary blasting from this point of view, BMI monitor the tonnes of material crushed in the primary crusher for each boulder requiring secondary breaking. Over a period of about 10 years, this figure has improved from 30 tonnes througi the primary crusher per boulder, to 100 tonnes per boulder at our largest operation, which produces in excess of 2 million tonnes per year. Evan with this improvement, 25,000 boulders require secondary breaking each year This paper does not provide the solution to this problem, as like primary blasting, it will have to be constantly reviewed as new products and techniques become available. The paper sets out all of the methods tested or considered for test by BMI and our nnnn1iicinnq nn Chair PffPr.tivPness . Economic

Jan 1, 1978

By Artieda JJ, Catalina JC

- The aim of this paper is to analyse the possibilities of applying signal processing and artificial vision techniques to the ore sorting problem. In order to overcome the limitations imposed by the classical approach to the problem, which essentialy cons

Jan 1, 1985

By T. Cutard, H. Marzagui, E. Ouedraogo, M. Roosefid, M. Prompt, C. Deteuf

The present work is achieved in the framework of a French national program on modeling and experimental characterization of the thermo-mechanical properties of refractory materials (PROMETHEREF). This research program is aimed to establish fair models and experimental database and to make it available to industrial partners for numerical simulation of industrial structures made of these materials. The present paper focuses on two silica-alumina refractory castables, an andalusite based one and a bauxite based one. We will present the first rheological characterization results achieved at room on normal and preheated samples of these two refractory castables. Refractory castables are characterized with the help of four points bending tests, compression tests and tensile tests.

Jan 1, 2004

By Robert W. Hunt

There are certain physical characteristics of steel resulting from its treatment while being formed into useful products which have been, and are, well known to its manipulators ; but under the stress of business competition and other controlling influences, all knowledge is not always given either full sway, or even full acknowledgment. Such has been the case in the making of steel rails. It is universally acknowledged that steel rails of heavy sections, made during the last tell years, have not given as good service as the rails of lighter sections produced before that time. While certain fundamental principles of steel-making have been acknowledged, their application to the steel-rail manufacture has been, if not actually denied, completely ignored.

Jan 1, 1902

By C. B. Manula, R. L. Sanford, R. A. Rivell

The large amount of computer code required for this simulation model dictates that reasonable limitations be placed on some of the input variables. The program permits the following maximum sizes: 1. Ten mine car stations 2. Twenty track intersections 3. Three hundred mine cars 4. Eight motors 5. One hundred profiles 6. Twelve intersections between stations 7. Forty-five profile changes between stations 8. Thirty station pairs (routes) These may be changed by the user providing the particular computer in use has available core storage. Major Array Descriptions This section is a detailed description of four of the major arrays used in the rail haulage simulator for data storage and logical control. Other arrays are used; however, they may be considered sub¬servative to the major ones. These major variables are explained on the following pages. Motor Control Array (XXXDEF). The first 99 locations in this array are arranged according to and are developed by data input. Unit conversions are made at input time which include: 1. Tons to pounds. 2. Rolling resistance in pounds/ton to percent/100. 3. Miles per hour per second (mphps) to feet per min. per minute. 4. Miles per hour to feet per minute. The following information is stored for each motor at the array

Jan 1, 1974

By J. L. Gregg

RECENTLY there has been considerable interest in the production and use of, extra hard alloys composed primarily of tungsten and carbon. Dr. Hoyt's recent paper1 gives a good description of these alloys and describes their performance when used as tools. There are a number of these alloys on the market sold under various trade names, and it is the purpose of this paper to describe the results of an investigation of the structure of five of these alloys by means of microscopic and X-ray methods. The samples studied were in the form of small tools or wire-drawing dies, which were either purchased or supplied as samples. They were in some cases not supplied by the original makers but were furnished by the agents in this country, and we wish to call attention to the fact that they may not be truly representative of the materials supplied under the various trade names. No performance data are given and no inference as to the inferiority of one alloy as against any other is made K Schröter2 recently described methods for polishing alloys of this type for microscopic examination and has presented photomicrographs of several alloys. However, he did not identify their constituents or describe methods for their identification.

Jan 1, 1929

By E. Topuz

Productivity is the most important determinant in the economics of underground coal mining operations. Lower labor productivity increases labor requirements per ton. This, in turn, increases the unit cost of production. Intensive labor requirements may also affect miner injuries and fatalities by increasing man-hours of exposure necessary to produce a given amount of coal.

Jan 1, 1988

By D. Kump

The Bullfrog Mine is an underground gold mine that uses the underhand-cut-and-fill mining method. The portal was established on June 18, 1991. Mining is expected to be completed by the summer of 1999. This paper starts by discussing what it took to get from nothing to 2000 tons-per-day backfill, and ends with a hindsight commentary on things that did and did not help.

Jan 1, 1999

By William S. Dershowitz

INTRODUCTION Numerical methods commonly used in rock mechanics, such as finite element, displacement discontinuity, and boundary integral equation methods, offer solutions to problems which can be described by differential equations subject to boundary conditions. These numerical methods use approximations leading to solutions in terms of matrix algebra and numerical integration. Many rock mechanics problems which are beyond the scope of such approximations can be treated effectively by application of techniques developed in the field of artificial intelligence (AI). Among the possible applications are: site characterization (Duda, 1975), geological interpretation (Smith and Baker, 1983), solution of problems involving rock joint networks, and underground construction. Each of these applications utilize particular features of Al. Here we shall present results of AI applications which utilize primarily search and to lesser extent learning or pattern recognition. Specific examples presented are in the field of rock fracture network problems and underground construction. ARTIFICIAL INTELLIGENCE Artificial intelligence techniques attempt to achieve human-like reasoning and learning capabilities. This reasoning capability is valuable in applications where repetition, complexity, or tediousness makes human-like intervention impractical. In rock mechanics this occurs, for example, in stochastic rock mass modeling applications where some complex decision-making is required for each of a large number of iterations.

Jan 1, 1984

By Stephen H. Chung, Kevin Atherton

The main purpose behind this preliminary study was the reduction of costs while maintaining productivity. Finding a way to achieve this balance without compromising controls on safety and quality of blasting results is of continual interest to the mining industry and of particular interest when ore of lower grade is being mined.

Jan 1, 1998

Discussion of the paper of CHARLES H. MACDOWELL, presented at the New York meeting, February, 1915, and printed in Bulletin No. 98, February, 1915, pp. 103 to 114. GEORGE S. RICE, Pittsburgh, Pa.-I am especially interested in the mining side of this important question. In 1911, when in Europe investigating mining matters, giving special attention to subsidence clue to mining, for there is a very big problem of that kind, as many of you know, in the Pennsylvania anthracite region, I visited Stassfurt, which is one of the chief centers of potash mining, and which was pointed out as the place to see surface subsidence. We found the town much askewsome of the streets having sunk from 15 to 30 ft., leaving many ancient buildings pitching at various angles. One old church, 500 or 600 years old, has been sunk about 20 ft., cracking it badly. I understand that this condition came about because in early mining clays they were careless about leaving proper supports and used no filling or packing. The Stassfurt mines work along a buried anticline the sides of which pitch at 45° on the average. Through this careless mining they had a break of the hanging wall which let in water from the overlying marls and sands. The water rapidly dissolved the salts in the pillars, and spreading through the entire chain of mines, caused their complete loss, with serious trouble for the old city. They had to start new mines some distance away, and take care to prevent roof caves. The packing system is of interest. They were driving large rooms into the rock-salt foot wall and using the rock salt as dry filling. The application of hydraulic filling, using a saturated solution, was under contemplation at some plant nearby. Whether 6r not the plan was carried out I do not know. I was reminded of the plan by Mr. MacDowell's remarking on the use of a saturated salt solution in the core drilling. His reference to the apparent breakdown of the potash syndicate raises an interesting question. We have had the German system of syndicates pointed out as perhaps one means of solving our troubles in the soft-coal mining industry due to overproduction. It seems to have worked out admirably in the case of the Westphalian coal-mining syndicate and also in the syndicate of Upper Silesia; but apparently the syndicate plan did not work in the potash industry. .

Jan 5, 1915

By W. C. Carter

In mid 1978 Inland Cement Industries Ltd. brought on-line their new one million megagram (Mg) per year cement plant at Tilbury Island, Delta, British Columbia. The Plant--Its Philosophy of Design The design of this plant began in 1974, at the beginning of the rapid rise in petroleum costs later referred to as the "energy crisis". The trend in fuel costs was clear, so one of the basic criteria for the selection of process equipment was high thermal efficiency. Throughout the process of selection of materials handling and process equipment, energy consumption was a factor in decisions. A second factor which influenced the design of the plant was its location on navigable water. The plant is designed to make maximum use of this means of transport to minimize transportation costs. All raw materials (and some fuel) are received by water, and a major portion of the cement and clinker is sent out by barge. Extensive modern dock and material handling facilities were provided to accomplish the shipping and receiving functions. A plant meeting stringent environmental regulations was the third major factor which formed the basis for design. To meet this requirement, all storage facilities had to be covered, 53 bag type dust collectors were applied throughout the plant, and materials handling equipment was designed to minimize dust and spillage.

Jan 1, 1979

By Kam Ng

For bridges or buildings that may be subjected to large vertical and lateral loads, drilled shafts offer an economic foundation solution. While the current drilled shaft design practice is considered adequate, introducing a performance-based approach to designing the drilled shafts will make their design more cost-effective and produce more dependable response. This concept was examined using analysis of 41 drilled shaft load test data from several states. This process identified the challenge with the lack of information from the Osterberg (O-cell) load test method to characterize the full top load-displacement response. When a typical single O-cell is utilized in a drilled shaft test, depending on the location of the O-cell and the geomaterials present along and beneath the shaft, the load test result typically quantifies either the side resistance or end bearing reaching the ultimate load-displacement curve but not both components. This limitation hinders the determination of a suitable shaft resistance as a function of a target top displacement. To overcome this challenge, an improved procedure is proposed for establishing the full load-displacement curve based on data gathered from one O-cell. The method will be presented in the paper for three different cases (i.e., side resistance reaches the ultimate during the test, end bearing reaches the ultimate during the test, and neither components reach the ultimate values). Because it allows the characterization of the full load-displacement curve, the proposed procedure will allow performance-based design of drilled shafts with due consideration to settlement while satisfying the Load and Resistance Factor Design.

Jan 1, 2013

By C. P. Mangelsdorf, Richard A. Allwes

At the request of the U.S. Department of Labor, Mine Safety and Health Administration (MSHA), the U.S. Bureau of Mines evaluated the suitability of using tri-sets for protecting mine personnel in roof-fall prone areas. A steel-set arch provided by MSHA served as a basis for evaluating the performance of the tri- set. All tests and analyses were conducted according to the arch canopy test and design procedures developed by the Bureau. Theoretical resistance functions were established for the steel-set arch and tri-set and were representative of their experimental behavior. The resistance functions were used to determine the energy absorption capacity of the structures and to predict their dynamic response to impact loading. The dynamic tests demonstrated that the arch canopy design procedure is appropriate for tri -sets and yields conservative designs for both steel-set arches and tri-sets. As a result of this work, it is recommended that tri-sets may be considered for protection against roof falls, provided that the arch canopy design procedure is utilized for each application and that the principles underlying the design procedure are understood.

Jan 1, 1992

By Hugo Meggitt, Damian R. Siebert, Wystan Carswell

Excavation-induced ground movements are a critical component in the design and construction of deep excavations in urban settings due to the potential adverse effects on adjacent structures and infrastructure. Ground movements are influenced by soil stratigraphy, soil properties, adjacent structures, and construction means and methods. The use of empirical relationships, computer models, and reliance on experience with similar excavations in similar soil conditions often provides a basis for predicting excavation-induced ground movements. In this paper, data from 21 deep excavations approximately 20 ft to 75 ft deep supported by concrete diaphragm “slurry” walls in the Greater Boston area are compared to published literature, considering how different foundation systems (e.g. shallow foundations, caissons, and piles) of abutting structures have been affected by adjacent excavations. The influence of construction method (conventional vs. top-down) on adjacent foundation movements indicate that top-down construction typically results in smaller foundation movements. INTRODUCTION Estimation of ground movements due to excavation is a challenging endeavor, even with complex three- dimensional finite element modeling and high-order constitutive models that are increasingly available in modern engineering practice. Aside from the expense of the soil exploration and testing used to inform these higher-order models, the challenges of modeling past stress history, adjacent structures, and the groundwater conditions during excavation require not only large investments of time during design but also validation from past experience (to avoid a “garbage in, garbage out” paradigm). While site conditions such as soil stratigraphy, soil properties, groundwater conditions, and as-built conditions of adjacent structures can be obtained, measured, and estimated, the effects that means and methods of construction have on ground movements are difficult to quantify. During early phase design, assessments of predicted ground movement are unable to account for all aspects of project construction, nor is it cost-efficient to fully design an excavation while project parameters such as site size and excavation depth are under consideration by the design team. While construction is in progress, benchmarking support of excavation performance and associated ground movements in the context of successfully completed projects allows for a more nuanced view of system performance and provides the opportunity for more informed decision-making (if required) as construction proceeds. For these reasons, the use of empirical relationships and the collection of historical support of excavation performance holds high value for the practicing geotechnical engineer at all phases of the project.

Jan 1, 2019

The panic bars (and associated linkages and electrical circuitry) that are defined in this document are a machine operator-actuated control for the emergency deenergization of the tram motors on self-propelled, electric and diesel face equipment; including haulage equipment such as shuttle cars. There are nine basic types of panic bars (and several variations) that are recommended in this document, but all of the panic bars are characteristically of the "fire door" type that is frequently encountered on outside exit doors of many public and some commercial buildings. It is also the intent of the following panic bar designs that, when emergency brakes are added to the face equipment machinery for which they arc required, that they be designed and hooked up so that actuation of the panic bar will result in automatic application of the emergency brakes (immediately following the deenergization of the tram motors). The following panic bar design requirements are a restatement of the proposed requirements defined in the Federal Register, requirements cited in "Guidelines for the Design and Installation of Devices for Deenergization of Self-Propelled Electric Face Equipment/Automatic Emergency Brakes" by G. E . Lester and J. D. Greenhalgh of MESA, and Bendix recommendations that were formulated as a result of discussions with personnel at the various machine manufacturers and underground coal mines that we surveyed, discussions with G. L. Judy (our consultant), etc:

Jan 1, 1974