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By C. Tokoro, T. Kato

The objective of this study is to improve the shrinking core model for particles with a particle size distribution and clarify the activation mechanism of rare earth elements dissolution by mechanochemical activation. To achieve this objective, the method, called the doubly integrated micromodel, was applied for a shrinking core model in this study. This method consists of integrating the batch leaching rate of a single particle over the distribution of both feed particle size and reactor residence time to arrive at the fraction unleached. The usefulness of the shrinking core model improved by doubly integrated micromodel was confirmed by comparing it with a shrinking core model. To apply the shrinking core model improved by doubly integrated micromodel to rare earth elements dissolution from weathered residual rare earth ores by mechanochemical activation, leaching experiments were performed for grinding samples by planetary ball milling. The reaction equation of mechanochemical reaction by planetary ball milling for weathered residual rare earth ores was investigated by x-ray absorption fine structure analysis. As a result of a kinetics study, the rate-determining process of leaching changed from reaction to diffusion reaction control by planetary ball milling. Based on these results, it was revealed that the main mechanism of activated rare earth elements dissolution from weathered residual rare earth ores was a mechanochemical reaction by planetary ball milling. Keywords: Mechanochemical reaction, particle size distribution, shrinking core model

Jan 1, 2020

Nineteen eighty-seven was a year of significant change in the Bureau of Mines-change to help it better adapt and respond to the wide range of new challenges facing the U.S. mineral industry. The Bureau has been regarded as the world's premier mineral information and research agency. Its authoritative, comprehensive data and its pioneering research have contributed significantly to the minerals position of the United States. Yet no organization in today's complex, dynamic world, with its rapidly advancing technologies, can afford to rest on its laurels. Mission and program must be constantly fresh and relevant to the day's issues and problems. Moreover, rather than reacting to events, the organization must strive to anticipate and prepare for them. It must have a sense-a vision, if you will-for the future.

Jan 1, 1987

By Y. C. Kim

One-quarter of a century has passed since the "theory of regionalized variables" (geostatistics) was introduced by G. Matheron (1962, 1963) in France. Yet, only during the past decade has geostatistics found broad acceptance in the mining industry. Foremost among the reasons for this time lag was ignorance. The first English treatise on geostatistics was not written until Matheron (1971), and the first published text accessible to mining professionals did not appear until David (1977). Other significant reasons for the slow acceptance of geostatistics included the conservative nature of management in the 1970s minerals industry, and the fact that conventional ore reserve estimation performs reasonably well when confined to massive deposits of base metal and iron deposits having relatively low coefficients of variation in grades. In short, mine engineers and geologists were not willing to accept a new set of tools for problems that they did not see.

Jan 1, 1989

By I. O. Salyer

This research was conducted with the objective of suppressing the respirable dust in coal mines by foam application. A formulation was developed for making a water-based, high-expansion, and limited stability foam. A horizontal boring machine was used as a laboratory coal mining model for generating coal dust. A modified laboratory foam generator was built. Foam was applied directly to the point at which dust was being formed by the cutter of the boring machine working against a block of coal. Coal dust was sampled with an impinger and analyzed for the particle count and particle size distribution. Coal dust suppression test results on freshly generated dust have demonstrated very clearly that in laboratory scale experiments over 90% of the respirable coal dust can be suppressed by foam. These tests were run when initial coal du t concentrations were 10 and 70 million particles per cubic foot (mppcf).

Jan 1, 1970

By Mark Svinkin

To save time for construction of coal pits, the contractor decided to combine erection of the tower pitheads with digging of skip shafts to the depth necessary for placing proper coal pit equipment. It was obvious that blasts used in shaft faces and lifting machines installed at a lower part of the pithead could excite vibrations of an upper part of the pithead with curing concrete. The contractor was concerned about vibrations of pithead concrete structures and the disturbance of freshly poured concrete in forms at a top of the pithead as a consequence of structure vibrations. The results of a study of the tower pithead structure vibrations from blasting and operating machinery, and effects of structural vibrations on curing concrete are presented. Structural vibrations were measured at the tower pitheads of two coal pits from twelve blasts. Records of horizontal and vertical displacements were superposition of harmonic low-frequency damped vibrations and sporadic high-frequency damped vibrations with a variable frequency. Low frequency vibrations attenuated during 8-13 s after the last delayed blast. Measured values of the natural frequencies of pithead horizontal vibrations coincided with the calculated frequencies of horizontal bend vibrations. An increase of a face depth from 18 to 50 m diminished 16 times horizontal bending vibration displacements of concrete structures. Measurements of vertical structural vibrations from blasting demonstrated increasing of vertical pithead displacements with the rising of structure elevations. This is evidence of the pithead longitudinal tension. The holes with charges were not properly condensed for one blast. As a result of incompact stemming, the blast substantially increased the energy of airborne pressure waves, which triggered natural vertical vibrations of the pithead with high displacements.

Jan 1, 2004

By J. MacFadyen

The U.S. cement industry, including Puerto Rico, again set a record in terms of production and shipments. The increase in shipments came primarily from imports of portland cement as domestic production from produced and imported clinker gained only 1.9 Mt (2.1 million st). Clinker production as reported to the U.S. Geological Survey (USGS) was 88.6 Mt (97.6 million st), an increase of 1 percent. Gray and white portland cement production from domestic and imported clinker, estimated at 93.5 Mt (103 million st), was up 1.9 Mt (2.1 million st). Masonry cement shipments of 5.5 Mt (6 million st), which equates closely to production, was up 6.3 percent. Blended ce-ment shipments were up 35.9 percent from 2004 at 2.35 Mt (2.6 million st).

Jan 1, 2006

By John A. Kost

Previous work performed under Contract H0220003 suggested that the mean incombustible content could be obtained with fewer samples and smaller samples without greatly increasing the sampling error. Under Modification No. 4 additional surveys were made in twelve coal mines, representing six states. Same 2,500 samples were collected, analyzed for incombustible content, and statistically evaluated. The earlier findings were substantiated.

Jan 1, 1975

By G. A. Johnson

Basic management principles will be discussed (as they apply to minerals education efforts), especially in light of the changing nature of volunteerism in today’s society. Also, the “minerals education tree” will be presented, along with public opinion / public policy realities.

Jan 1, 2001

By D. E. Shanks

As part of its effort to produce cell-grade alumina from clay, the Bureau of Mines investigated the hydrogen chloride gas-sparging crystallization of aluminum chloride hexahydrate (ACH) from aluminum chloride liquor, to provide information for optimizing the crystallization operation. Four parameters important in controlling the crystallization of the aluminum chloride hexahydrate and the concentration of impurities, particularly phosphorus and magnesium, in ACH crystals are (1) aluminum chloride concentration in the feed solution to crystallization, (2) hydrogen chloride gas flow rate, (3) temperature, and (4) concentration of phosphorus and magnesium also in the feed solution. Parameters 1, 2, and 3 affect crystal formation. The combined effects are very important because the phosphorus and magnesium concentrate in the crystals during the early stages of crystal growth. Aluminum chloride hexahydrate of cell-grade purity was crystallized from saturated aluminum chloride solutions containing less than 0.003 wt-pct P205 and 0.010 wt-pct MgO. Crystallization temperatures less than 600 C decreased crystal purity.

Jan 1, 1981

By Susumu Tsubota

Three types of reference gold catalysts, i.e., 3wt%Au/TiO2 (Au-Ti: Type A), and 0.3wt%Au/Fe2O3 on alumina beads (AUS: Type B), and 5wt%Au/Fe2O3 (Au-Fe: Type C), were produced in a test plant scale by Sud-Chemie Catalysts Japan, INC. under the licensing of AIST. To evaluate the validity of the preparation methods and conditions used for the reference samples, elemental analyses by ICP, particle size measurements by TEM, and catalytic activity measurements for the oxidation of CO and H2 over these catalysts were made. Gold catalysts can be prepared in a large scale of ca 400g for the Au-Ti and Au-Fe catalysts, 5 kg for the AUS catalyst with good reproducibility. It was confirmed that they were available for useful as the reference gold catalysts of World Gold Council.

Oct 1, 2003

By J. C. Agarwal

Rare earth metal alloys are becoming increasingly important, particularly those of neodymium, because of their magnetic properties. This paper will present a generalized approach to the production economics of the metallic rare earth alloys. With appropriate regard for the chemistry of different rare earths and the large impact of economies of scale, it is possible to make fairly accurate estimates of the production costs of other rare earth alloys as well.

Jan 1, 1989

By Ovidiu Pasca

Several improvements in converter equipment and operation at BHP Copper have reduced the converter cycle time as necessitated by an increase in flash furnace output. The resulting higher intensity performance of the Peirce-Smith Converters has had a major impact on the dust handling and off-gas cleaning systems. This paper describes work carried out on the design of a new converter hood with particular reference to the thermal analysis and hood performance aspects. Changes in converter cycle time and campaign life as result of the process and equipment improvements are discussed in a separate paper.

Jan 1, 1999

Connecticut Geological and Natural History Survey, P O Box 1106, New Haven, Conn W. E Britton, Superintendent. A complete list of Bulletins available will be sent upon request. Address all inquiries for publications to: George S Godard, State Librarian, Hartford, Conn Fifty-one Bulletins have been issued, 15 of which are of particular interest, dealing with the geology of the state, and are available as follows; 4, The clays and clay industries of Connecticut, by G. F Loughlin (1905), 35 cents; 8, Bibliography of Connecticut geology, by H E Gregory (1907), 20 cents, 13, The lithology of Connecticut, by J Barrell and G. F Loughlin (1910), 45 cents, 18, Triassic fishes of Connecticut, by C. R Eastman (1911), 30 cents, 23, Central Connecticut in the geologic past, by J. Barrell (1915), 20 cents, 24, Triassic life of the Connecticut Valley, by R Lull (1915), 70 cents, 29, The Quaternary geology of the New Haven region, Connecticut, by F. Ward (1920), 60 cents, 30, Drainage modifications, and glaciation in the Danbury region, Connecticut, by Ruth S. Harvey (1920), 55 cents, 33, Geology of the Stonington region, Connecticut, by L H. Martin (1925), 60 cents, 40, The geology of the Shepaug Aqueduct Tunnel, Litchfield County, Connecticut, by W M. Agar (1927), 50 cents; 41, Guide to the geology of Middletown, Connecticut, and Vicinity, by W. N Rice and W. G Foye (1927), $1, 44, Report on the water resources of Connecticut, by R. H Suttee (1928), $1, 46, The physical history of the Connecticut shoreline, by H S Sharp (1929), 75 cents; 47, The glacial geology of Connecticut, by R F. Flint (1929), $2, 51, Minerals of Connecticut, by J F Schairer (1932), 75 cents Bulletin 51 explains the physical and chemical properties of minerals, their classification, and describes more than 100 common minerals found in Connecticut. A bibliography is included The Survey gratuitously distributes all its Bulletins to state residents, scientific institutions, etc. Prices quoted are to private citizens of other states

Jan 1, 1933

By Sheila Luchansky, F M. Babcock, Daniel M. Sanders

A cooperative effort between a blasting vibration consultant, a blasting contractor, and personnel from the City of Las Vegas has dramatically reduced complaints from residential areas near developmental blasting projects. The principal methods used involved the preparation of an informative video recording which presents various aspects of the blasting operations, the design of a distinctive flyer which is attached to residential doors, and pre-blast meetings for information dissemination.

Jan 1, 1993

By Francis O. Otuonye

An application of a time series and systems analysis modeling technique to blast vibration data is discussed. The vibration data was taken from a rock support structure and the surrounding rock mass at distances close (less than 15 feet) to a blast. The analysis technique provides quantitative information on the frequencies of ground motion as well as the frequencies and damping ratios of a near-field support structure.

Jan 1, 1994

By J. S. Lewis

Beneficiation and physical and chemical processing of non-terrestrial materials will borrow strongly from terrestrial experience but will also involve the necessity of handling literally unEarthly feedstocks, reagents and environmental conditions. The present state of scientific and engineering understanding of the processing of non-terrestrial minerals, gases and hydrocarbons is reviewed, with the production of rocket propellants, life-support fluids, structural metals and refractories as the goal.

Jan 1, 1994

By J. H. Weber

This Bureau of Mines publication describes the hardware system and software package for the semiautomatic acquisition and automatic processing of high-resolution mass spectrographic plates. The semiautomatic data acquisition allows a tenfold saving of time compared with manual data acquisition. Automatic processing of the high-resolution data to yield exact masses, intensity, and the corresponding empirical formulas is accomplished by efficient programming on a small, inexpensive, programmable calculator system.

Jan 1, 1974

By C. J. Kirkland

The paper describes the arrangements for the casting, curing and handling at the casting yard, of the concrete segments for the lining of the UK half of the tunnel, and the plant used for the handling of these linings at the construction site. An outline of the tunnel boring machines being used is given, with particular reference to lining handling and erection, and the extensive muck disposal systems installed. A general progress update will be given to the conference.

Jan 1, 1989

Copper heap leaching involves both the simultaneous and sequential leaching of very large tonnages of ore over long periods of time. It is not unusual to be leaching three or four million tonnes over periods of 12 to 18 months. As a consequenc

Jan 1, 1998

By Jim Bruce

This paper presents details of a slope stabilization scheme built in late 2003 at a 16m-high railway embankment in southern Ontario, Canada. The owner, faced with continuing maintenance and safety issues arising from numerous nuisance slides, and residential neighbors in close proximity to the slope, sought new proposals to replace a previous recommendation to cut down all trees and undertake a deep soil nailing scheme. A non-reticulated micropile array with surface cap beam was proposed and built on the south side of the embankment with no tree removal required. A detailed FLAC analysis was completed, using multiple iterations to arrive at the eventual, optimized micropile depth and spacing. Analysis predicted an 18% increase in the factor of safety. Short term inclinometer monitoring and performance evaluations in the months since construction so far corroborate the prediction.

Jan 1, 2004