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A comparison of gold, platinum and sulfide ion selective electrodes was made in this investigation for determination of Eh in solutions containing sulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. In addition, the sensitivity of each electrode towards changes in sulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration of sulfide ions. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion, HS-, concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion, S-, activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of sulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1990

By J. E. Gebhardt, D. McBride, T. N. Croft, M. Cross

"Heap leaching is well-established as a relatively low-cost and low-energy method of extracting metals from low grade ores. However, the design methodology, attention to the engineering details during heap construction and the long time scale in metal recovery makes the process susceptible to significant variation in the success of a heap leach operation. Often the laboratory predicted recovery rates are not achieved on site due to poor understanding of the complex physics of flow and coupled solid-liquid-thermal reactions within the multi-dimensional heterogeneous ore body. Given the large scale of commercial operations, small changes in metal recovery can substantially change the operating profitability. While there are a variety of approaches to heap leach modeling, computational fluid dynamics (CFD) modeling coupled with leach kinetic models offers a methodology to describe and understand the complexities of heap leaching. The CFD model uses leach kinetics specific for the mineralogy of the ore, including gangue chemistry, and provides an energy balance to calculate and predict temperature. Coupled with the CFD model’s inherent capability for modeling complex fluid flow, the physics and the chemistry of the heap can be simulated. This provides a tool for engineering design, as well as forecasting heap production under different scenarios. The calibrated model is used to simulate a three-dimensional test heap under fluctuating meteorological data, such as precipitation events, periodic solution application, and notably temperature. These simulations provide support for a methodology to design and engineer heap leaching of low grade copper sulfide ore. INTRODUCTION Worldwide copper ore reserves are faced with decreasing head grades with copper sulfides, particularly chalcopyrite being the predominant mineralogy (Nesse, 2000). Heap leaching offers an economical way to recover copper from low grade ore. The ore is stacked and a leach solution is applied and allowed to trickle though the porous bed of ore to extract target metals. The heap can be built with run of mine material or crushed ore and is constructed in order to achieve percolation of the leach solution to all regions. Bartlett (1998) provides an authoritative overview of the solution mining process where the leach solution interacts with the solid, the lixiviant dissolves the target minerals from the solid into the solution, and the dissolved species are transported out of the heap for subsequent recovery. Petersen (2016) provides a recent review of heap leach technology and emerging and potential future applications, and Ghorbani et al. (2016) summarizes the current state and challenges of the technology. Early applications of heap leaching offered a low cost technique to achieve high recoveries from oxide ores, typically greater than 70% depending upon the kinetics of reaction. As world copper resources transition to mainly copper sulfide mineralogy, such as chalcopyrite based ores, achieving high recovery from these copper sulfide deposits is proving more difficult due to the complexity of the leach kinetics, which leads to low leaching efficiency."

Jan 1, 2018

By T. Koulomzine, R P. Jaeggin

The claims now held by Mount Wright Iron Mines Co. Limited were acquired by staking in 1956, 1957 and 1958, i.e., some time after the major deposits of the Quebec Cartier Mining and Normanvi!le Mining Co. (formerly Quebec Cobalt & Exploration Ltd.) were already discovered and partly outlined. The choice of the location of the Mount Wright hold-ings was governed simply by the -availability of ground still open to staking and by its proximity to properties held by major iron companies. Mount Wright Iron Mines had no previous knowledge of the geology and no aeromagnetic results were available to it to guide the choice of areas to be staked. In order to explore the newly ac-quired claims it was decided to make a grid of widely spaced magnetic profiles on the ground rather than use aeromagnetics. This afforded the possibility of making some geological observations simultaneously with the geophysical measurements.

Jan 1, 1961

By B. W. Frazier

At a recent meeting of the North of England Institute of Min ing and Mechanical Engineers, during a discussion upon the com pression of air, attention was called to an apparent anomaly in the phenomena attending the compression. At a subsequent meeting this apparent anomaly was explained by Prof. Herschel, and all the facts observed shown to be strictly in accordance with the laws of thermodynamics. Upon reading the report of the discussion in the published transactions of the society, it occurred to me that an attempt to determine mathematically the amounts of energy (whether in the form of heat or of work) expended and absorbed in compressing air, and causing it to perform work by expansion, might prove of use to some who have not access to any treatise upon the application of the laws of thermodynamics to the compression of air, and who have not the time or the inclination to make such application for themselves. The apparent anomaly noticed was this: If air be compressed, and at the same time, by the sufficient application of a cooling medium, kept at a constant temperature, the indicator diagrams in the

By Timothy W. Ellis, John A. Howes, Roger D. Feldman

The new generation of more powerful, energy-intensive devices for communications, industrial production, energy storage and other purposes is creating new challenges to guard against environmental harm and protect national security. Many devices are designed, used and disposed of in a linear, rather than circular manner. This causes scientific, legal and economic issues because the life-cycle costs of components are not adequately considered. Dealing with these issues in isolation from each other can lead to unintended consequences. New models to confront these issues are being defined. This paper suggests a fundamental tool for dealing with material science issues while taking into account the engineering, economic and policy perspectives. That tool is the development of a true, levelized cost of energy storage model with a wide spectrum of inputs for comprehensive analysis. This paper will discuss inputs and the process which can yield meaningful, useful comparisons among batteries and energy-intensive products.

Mar 1, 2018

By Hugh M. Roberts

DEVELOPMENT at Steep Rock lake has given rise to renewed interest in the geology of the iron ore deposits in the Lake Superior Region and has implications of no small moment bearing upon methods of exploration in the Precambrian Shield generally. Following upon the Regional Lake Superior meeting of the American Institute of Mining and Metallurgical Engineers in August, 1941, the authors prepared a paper on the Steep Rock deposits, which appeared in the A.I.M.E. publication, Mining Technology, for January, 1943. Between Januar7 and April, 1943, exploration at Steep Rock was continued by means o vertical, Mesabi-type churn-drill holes put down from the ice. This drilling has enlarged the tonnage of ore previously known and has disclosed further facts relating to the origin of the ore. The added evidence, we believe, goes to support the hypothesis that the deposits were formed by a process of replacement due to upward-moving, iron-bearing solutions which came in as igneous after-effects. Accordingly, in presenting the subject to the Canadian Institute of Mining and Metallurgy, it seems best not to change our first explanation, but to prefix the original paper with an interpretation of the results of the more recent explorations completed after its publication.

Jan 1, 1943

In exploiting the ultra-deep, narrow reef ore bodies of the Witwatersrand, the ventilation and cooling systems within the stopes play a critical role because of high concentrations of active workers. This paper examines the heat, ventilation and cooling effects of a number of different stoping layouts for narrow reef mining in ultra-deep operations in very hot rock. The stope ventilation and cooling needs are driven primarily by the difference between the air temperature and that of the rock front being excavated. These needs depend on the face utilization, geometry, face advance (rate and direction), layout, backfill, use of water and machinery1,2,3. Detailed studies of different stoping configurations have been undertaken for mining operations extending to depths of 5000m below surface, where virgin rock temperatures approach 70°C. Extensive work has been completed with regard to evaluating ventilation and cooling requirements to maintain air reject temperatures of 28°C wet-bulb and better. This knowledge is being used to determine overall cooling requirements, reduce operational costs and maximize the efficiency of cooling systems. These issues are important when considering both the local and regional air conditioning systems and the most effective application of in-stope chilled water.

Jan 1, 2001

By A. F. Jolly

In an effort to better predict the useful service life of friction rock stabilizer mine roof bolts in coal mine environments, the Bureau of Mines has evaluated the corrosion resistance of stabilizer steels in air-saturated and deaerated waters from seven Eastern and Midwestern underground coal mines. Accelerated electrochemical corrosion tests were used to estimate corrosion rates for the two high-strength, low-alloy (HSLA) steels used to fabricate Split Set stabilizers and for galvanized steel. Long-term static-immersion weight-loss tests were also conducted with the HSLA steels. Corrosion rates developed from the weight-loss tests (steady-state air dissolution) were roughly comparable to rates determined from electro-chemical testing in aerated waters. Although the highest rates occurred in waters with the highest chloride contents, rates in the other waters were low (<2.0 mpy) and exhibited little correlation to the widely varied chloride contents of the waters. The generally low corrosion rates are attributed in part to the tendency to deposit a protective CaC03 film, reflecting susceptibility to carbonate precipitation as indicated by positive Langelier (saturation) index values for the waters. With one exception, corrosion rates for the galvanized steel were (2.0 mpy. Rates with aerated waters were higher than those with deaerated waters. Pitting tendencies of the steels were also estimated.

Jan 1, 1987

By Veliko Kertikov

Complicated processes of heat exchange and evaporation, leading to changes in the temperature and humidity of the ventilating air flow, take place during the driving of headings. In the case when virgin rock temperature is high, the increase in air temperature and humidity is significant. This causes a deterioration of climatic conditions in the headings. Procedures for predicting the changes in air temperature and humidity are discussed, together with appropriate calculations and computer programmes. Predicted results for example scenarios are used as a background for the selection of approaches and means to improve the climatic conditions in a dead-end heading using auxiliary ventilation.

Jan 1, 1997

By M. R. Geer

This report presents the results of washability examinations of seven coals from the principal coal-producing fields of Montana. A complete performance test of the Baum-type jig operated at one of the mines is included, as are the results of cleaning tests made on two of the coals in a dense-medium pilot plant. The coals examined from the Red Lodge, Bull Mountain, and Forsyth fields are comparatively easy to clean. Ash contents of 5 to 10 percent can be obtained at yields of washed coal ranging from 90 to 95 percent. The coal from the Great Falls field, however, could not be cleaned readily to less than 14 percent ash, and the rejection of impurity would amount to over 25 percent. The two coals treated in the dense-medium pilot plant were characterized by sharp separation of impurity, high recovery efficiency, and satisfactory reduction in ash content.

Jan 1, 1955

By G. W. Grove, O. V. SIMPSON

During the years 1945, 1946 , 1947 , and up to July 1, 1948, only one death was caused by mine fires in bituminous - coal mines of the United States . The one fatality occurred in an Illinois mine in December 1945, and , therefore, there had been a period of 2-1/2 years in which no deaths occurred as the result of mine fires . Moreover, 1946 was the first year since 1930 in which no deaths occurred from mine fires . This record is markedly better than that of 1944 , when 89 fatalities and great property damage were caused by mine fires in bituminous - coal mines and 16 additional men were killed by an explosion that occurred while they were attempting to seal a mine fire .

Apr 1, 1949

By Noel Jarrett

Energy consumption and distribution in aluminum production, conservation accomplishments, and future goals are presented. Electrolysis and electrode manufacture show the greatest promise for major improvements. Means are proposed for reducing waste heat generation in smelting and for conserving energy in anode manufacture by furnace design and substitution of other materials for petroleum coke. Hall-Heroult Process modifications, alternative designs, and the Alcoa Smelting Process are discussed as energy savers. Scrap recycling, more use of aluminum in transportation, and the installation of offshore smelters in less developed countries are shown to be additional means of coping with possible energy dislocations.

Jan 1, 1981

By D. J. Robertson

"THE copper smelting operation of the Hudson Bay Mining and Smelting Company, Limited, at Flin Flon, Manitoba, generates a gas flow of 350,000 c.f.m. at n.t.p. This gas stream passes to atmosphere through a 20-foot diameter by 250-foot brick stack, carrying with it an appreciable dust burden in the form of metallic oxide fumes. The flow constituents during the period 1952 and 1953 and •before gas filtration was included in the treatment scheme are shown in Table I. This paper describes the gas filtration treatment which was installed in 1957, using glass cloth media to recover this dust burden, and discusses the associated problem as its treatment for recovery of zinc and cadmium.The metallurgical details associated with the problem are illustrated by a description of the material flow sequence of the Company's hydrometallurgical zinc plant and copper smelter. In this ore processing complex, the zinc plant and copper smelter form an integrated unit within which intermediate zincrich products of each operation enter the treatment circuit of the other."

Jan 1, 1960

By William X. Chavez

The Mantos Blancos copper-silver district, a major copper-producing area since 1961, is located on the Tropic of Capricorn about 45 kilometers northeast of the northern Chile port city of Antofagasta, as shown in Figure 1. Copper oxide minerals occurring as atacamite (Cu C1(OH)3) and chrysocolla (copper silicate-hydrate) were discovered in the district in the early 1900&apos;s (Knobler and Joseph, 1962). The mine is situated in the northern Atacama Desert, one of the most arid regions on earth, and presently receives less than 1 cm per year of precipitation. The extreme aridity of the Atacama Desert is thought to have prevailed since at least Middle Miocene time (Mortimer et al., 1978) when development of important supervene copper enrichment was slowed in many areas of northern Chile (e.g., Chuquicamata, Exotica). Despite the paucity of precipitation, landform development is mature, with large alluvial fans and alluvial-filled valleys covering much of the region. In addition, the aridity and presence of salts have led to the formation of a sub-surface cementing of alluvium and colluvium by halite-rich caliche ranging from a few centimeters to over 3 meters in thickness. These factors, resulting in poor outcrop exposure, make even reconnaissance mapping difficult.

Jan 1, 1983

By J Moffatt, T Payten, N Spooner, L Teixeira, L A. Balzan, G Wilkie, G Tsiminis

Fluorine is a penalty element due to its reactive nature. In acidic environments many fluorine minerals dissolve to form hydrofluoric acid (HF), changing processing conditions. When smelted HF can be released, causing negative effects to nearby people and the environment, as well as potentially damaging the smelter. Sale of ore with high fluorine levels elicit a financial penalty or are banned outright. Real-time sensors create the opportunity for instantaneous decisions on ore processing due to changing conditions. A fluorine sensor would allow rises in fluorine concentration in a processing stream to be flagged, and decisions on processing conditions or diversion to stockpile before processing could be undertaken. As fluorine is a light element, it is difficult to detect with in-field XRF devices and does not work well with PGNAA. There are currently no existing sensors to quantify the presence of fluorine in real-time, and thus decisions based on fluorine grade cannot be made at minute- or even hour-scales. Sensors designed to measure the presence of minerals that contain fluorine are a possible avenue to enable the real-time detection of this element. Mineral-based sensing may also give an added advantage of additional information about how the fluorine will react under different processing steps. The authors were given a grant under CRC ORE II (project number P1–005) to search for mineralspecific signatures suitable for real-time analysis. The work focused on novel regimes and applications of fluorescence as a means to detect specific minerals. The aim was to exploit fluorescence responses unique to minerals of interest in mining systems in order to produce sensors that address gaps in existing capability. After the successful discovery of signatures specific to two major fluorine minerals an additional grant (P1–014) was funded to develop the research into a prototype on-belt sensor, in partnership with Scantech International Pty Ltd. This paper details the development of a sensor package through multiple Technology Readiness Levels (TRLs) through collaboration with government/industry grant schemes, academics from university, and a sensor-focused Mining Equipment and Technology Services (METS) company. We give a brief description of the new sensor technique and provide a case study of multi-disciplinary collaboration.

Aug 24, 2022

By W. H. Tuttle, H. R. Ahlquist, A. J. Carlson

Variations of the EVOP technique are accepted as the foun- dation in the development of Erie Mining Company&apos;s mining, concentrating and pelletizing complex at Hoyt Lakes, Minnesota. The basic one-variable- at-a-time technique served its purpose through the laboratory pilot plant as well as the full-scale production sized pilot plant. However, recognition by Erie Mining Company management of the potential of computer application and statistical experimentation in plant operation and testing led to acquisition of an IBM 1620 computer in 1961. Adaptation of established techniques in statistically designed experimentation and analysis of results is presented in actual case form including the following: 1. Determination and use of variance, standard deviation, standard errors; application of t-test in determining true differences between daily aver ages of product assays; formulation of quality control limits; determining sample size; and application of normality tests will be discussed. 2. Use of mathematical modeling and regression analysis for establishing mill storage conditions based on bin level indicator lights. 3. Polyvariable random balance design of a balling circuit test and resultant identification of primary control variables.

Jan 1, 1969

"Many advances in glass technology and processing are being made and the possibilities for glass as a material in the future appear unlimited. Float glass, glass-ceramics, high-strength sheet and container glass, glass-reinforced plastics, glass for electronic equipment, aerospace glass, glass fibres, glass vehicles, glasses with selective-reflective coatings and glare-reducing glasses, to name a few, provide areas of significance at present and for the future. There appear to be great opportunities, in certain localities of Canada, to develop new sources of raw materials for an expanding Canadian glass industry.New developments in the structural clay products industry have centered around facing brick as a structural load-bearing material, prefabricated brick panels, large-sized units, isostatic pressing of sewer pipe and auto-matic settmg of brick. Fast-firing techniques, using prefired or calcined raw materials, and the development of high-strength products will result in the use of a wider range of raw materials in the whiteware and structural clay products industries.Porcelain enamel, a material used for many years in domestic appliances and for sanitary ware, now is used extensively in architecture, agriculture, water tanks, highway signs and reflectors, and in products where resistance to corrosion-plus-temperature is important. Exotic composites of ceramics and metals, and specialized ceramic coatings applied on metals by various techniques such as flame spray, plasma jet, or vapour and chemical deposition have proved useful in materials for aircraft power plants, rockets, missiles and nuclear applications."

Jan 1, 1967

By D. B. Paterson

In view of decreasing head grades, the relatively high gold price, and recent developments in metal evaluation, an exercise was initiated to determine the extent of gold concentration, the mode of occurrence, and the areas of concentration within the run-of-mine milling circuits of Randfontein Estates Gold Mining Company (Witwatersrand) Limited. The total gold content of three of the thirteen run-of-mine mils in the Group was measured as a typical lock-up of approximately 200 kg per mil. The majority of this gold was concentrated either behind the grid-type body liners or within the pockets of the body liners. This paper is an account of the experimental procedure and the results obtained, and highlights possible means of limiting gold lock-up in future.

Jan 1, 1988

By G. G. Morgis

A reasonably clear and broad definition of occupational disease as originated by the Supreme Court of Ohio is: "A disease contracted in the usual and ordinary course of events which from the common experience of humanity is known to be incident to a particular employment." An ailment does not become an occupational disease simply because it is contracted on the employer&apos;s premises. It must be one that is commonly regarded as natural to, inherent in, and concomitant of the work in question. The important distinction between accidental-traumatic injuries and occupational-disease injuries is that accidents occur at specific times, ordinarily are discovered readily, and usually leave no question as to the particular employer it whose development the accident occurred. On the other hand, occupational diseases may develop slowly, unknown to the employer and employee until disability occurs, and the injuries sustained are continuing disabilities over an extended period of time and may be incurred while the employee is working for one of several employers.

Jan 1, 1952

By Donald L. Everhart

The National Uranium Resource Evaluation (NURE) program since 1974 has been designed to accomplish a comprehensive coverage of the 48 conterminous States and Alaska to evaluate the total uranium resources of the USA. This resource base includes both ore reserves and potential resources. Techniques include airborne radiometric and magnetic surveys, by hydrogeochemical surveys, surface and subsurface geologic studies, and the application of improved geochemical exploration and resource assessment methods (Table 1). In brief review, the current status of each of the five basic NURE elements is as follows: In the Aerial Surveys, in the conterminous 48 states, the flying has been completed in 89 of the NTMS 10 x 2° NURE quadrangles, and is in progress in 39 more (Figure 1). Complete quadrangle data have already been open filed for 46 additional quadrangles, for a total of 174 for which data gathering is either complete or in progress. In Alaska, the flying is complete in 42 quadrangles, and quadrangle data have been open filed for 34 more, for a total of 76 (Figure 2).

Jan 1, 1979