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By James H. Cobbs

Blind boring of shafts is becoming an increasingly important part of shaft sinking. Blind-bored shafts have reached diameters of 25 It in Europe and 16-1/2 ft in the United States. Much of the technology developed for blind boring has evolved from the technology of drilling wells for oil and gas production. Blind boring offers economic advantage in a number of situations where conventional shaft sinking either is extremely difficult or very expensive by virtue of large-capacity aquifers which must be penetrated, unstable ground or where very rapid sinking is required. In sedimentary rocks, blind boring is cost competitive with conventional sinking, in diameters of about 12 ft or less. Blind boring is not competitive with raise boring where conditions are favourable for raise boring. Blind boring does, however, offer greater flexibility than raise boring and can be performed in situations where raise boring is inefficient or impossible. Combination machinery has been developed to perform both blind boring and raise boring, so that the machine can be used effectively in situations where only the near-surface portions of the shaft are unfavourable for raise boring. Development work is being supported by the United States Bureau of Mines for blind boring equipment capable of boring shafts up to 30 feet in diameter.

Jan 1, 1979

By D. C. McDonald

"IntroductionTHE GIANT YELLOWKNIFE property is on the west side of Yellowknife bay, Great Slave lake, N.W.T., some 600 air miles north of Edmonton. This paper deals with the underground development and mining of the complex system of orebodies which have produced, in the first fifty-six months of operation (May, 1948, to December, 1952), 652,464 tons of ore with an average grade of 0.80 ounces of •gold per ton (1).The mine has been developed from three vertical shafts designated A, B, and C. Figure l shows the positions of these openings with respect to the known ore-bearing zones and the surface plant.A shaft was sunk to a depth of 522 feet in 1945-46, primarily as a prospect shaft for investigation and development of the East Zone orebody. Drifting was carried out on the 200-and 325-foot levels. Before this development had been completed it was clear that the funds immediately available made it imperative to get revenue from production as soon as possible. By the beginning of 1946, the remarkably high-grade character of the ore in the present B Shaft area had been established by surface drilling, and the decision was made to obtain initial production from this source. Since known orebodies at shallow horizons were to be developed quickly, the choice of a suitable rock outcrop for the shaft was something of a problem."

Jan 1, 1953

By N. Arbiter, C. C. Harris

In 1961, a research program started at Columbia into the mechanical aspects of flotation,* and certain ends are now in view. The purpose of this note is to explain these tentative conclusions in the hope of stimulating discussion and eliciting new data, especially industrial data, with which to test the views expressed. The variables presently under consideration are impeller rotational speed, N, volumetric air rate, Q, and impeller diameter, D, the latter being the parameter chosen to designate cell size. The most favorable *The latest work 1 references all previous publications. chemical environment is not under discussion since the procedures for establishing it are better understood than those for optimizing N and Q by virtue of a longer history of more intensive investigation. THE GRADE AND RECOVERY SURFACES With a given ore, chemical treatment, and flotation machine, both grade, G, and recovery, R, are functions of N and Q. The GNQ and RNQ relationships are best viewed in terms of three-dimensional surfaces (Fig. 1) which are experimentally determinate.2 TO maintain grade at an acceptably high level, it is necessary for N and Q to lie within certain limits, and similarly with recovery. However, the ranges of N and Q for grade on the one hand and recovery on the other are rarely the same. Selecting the single N

Jan 1, 1970

By C. N. Eze, C. K. Ezeh, O. Nnabuife, N. M. Ugwoju, S. C. Enemuor, V. Okechukwu

In this study, the efficacy of Providencia vermicola KUBT-1 in the leaching and beneficiation of Agbaja iron ore was evaluated under varying conditions of temperature, ore particle size, and pH. Agbaja iron ore is a Nigerian low-grade ore containing about 43%–52% iron and a high amount of gangue materials, including phosphorus (1.4%–2.0%) and sulphur (0.12%). The study was organised in triplicate in shake flasks with 48 samples. One millilitre of washed cells of Providencia vermicola KUBT-1 suspended in normal saline at 0.5 McFarland standard (108 cells ml-1) was introduced into each flask containing 50 g of sterilised ore in 100 ml of bioleaching medium, and the samples incubated at room temperature for eight weeks. The levels of upgraded iron, mobilised sulphur, and phosphorus were determined by atomic absorption and ultraviolet spectrophotometric analyses, respectively. Results showed that a particle size of 0.8 mm was optimal for iron upgrading and sulphur mobilisation while 1.0 mm ore size was optimal for phosphorus mobilisation. Up to 89.60% of the iron was upgraded while phosphorus and sulphur were mobilised, leaving residual values of 0.223% and 0.02%, in the ore, respectively. The organism produced best beneficiation results at a pH of 2.5 and a temperature of 3ºC. Correlation analysis with the Pearson’s correlation model showed a positive correlation between iron upgrading and sulphur-phosphorus removal (r =1.000, and r =0.967), respectively. These results present Providencia vermicola KUBT-1 as a promising candidate for large scale leaching and beneficiation of Agbaja iron ore.

Dec 15, 2025

By M. C. Bekker, T. Govindasamy

The potential benefits of implementing the Last Planner System (LPS) on mining infrastructure projects were explored through two case studies in the South African mining industry. The first part of the study involved measurement of the impact of LPS through earned value techniques on secondary project data. The second part sought to establish the lean construction success factors leading to improvements in construction performance. This was done by means of a research questionnaire distributed to the project owner’s teams, contracted parties, and the LPS facilitators. The results revealed a positive correlation between LPS application and planned percentage complete. However, the performance achieved during the LPS pilot was not sustained. The success factors and benefits considered most evident in the case study pilot differed among the three stakeholder groups. The findings are expected to guide construction stakeholders to better define performance measures and focus on factors required to make LPS implementation more effective in the South African mining sector.

Feb 12, 2024

By Forrest T. Moyer

To keep the mineral and allied industries informed of trends in the causes of accidents, and to point out the need for corrective measures, the Bureau of Mines collects, analyzes, and periodically publishes health and safety statistics. This report includes data for 1963 on injury experience, with related employment statistics, at coal mines in the United States. These data are presented in tabular form under the following headings: General Injury Experience Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location.

Jan 1, 1966

By J. William Ganser

This paper is one of a series being prepared by the United States Bureau of Mines describing mining and milling methods and costs at cement-plant quarries throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs may in some instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1931

By Carl C. Nesbitt

A study was conducted to investigate the claims of early observers who noted an increase in the rate of gold dissolution when chlorine was chemically produced in the leach vessel compared to sparging with chlorine gas. This "nascent" chlorine was presumed to be an active intermediate in the production of chlorine (C1,l from chloride ions. The study used UV light to produce an activated chlorine atom intended to recreate the observed increase in the gold dissolution rate. Although no change in the kinetic rate was observed, the reaction mechanism by which chlorine reacts with particulate gold was instead determined. Various concentrations of multivalent cationic chloride salts were added to the leach solution to demonstrate that the increased dissolution rate was due to the increased concentration of the chloride ion and ionic strength of the solution.

Jan 1, 1992

By B. Kyslinger

"In underground mining, machine design is predominantly dictated by mine conditions and individual customer desires. In partnership with Foresight Energy, J. H. Fletcher & Company was tasked to design and manufacture a new roof bolting machine with six independent drilling apparatus on board capable of drilling and bolting the roof and ribs with material handling. This is the first Fletcher® six head machine to be designed and built for the mines in the United States. The machine is intended to work in the Illinois Coal Basin. The objective was to produce a machine capable of drilling and installing six bolts simultaneously with a limited number of operators. The goal of the mine is to decrease the time to bolt a cut to improve the safety level of the current roof bolting method, improve efficiency and to improve the bottom line cost of entry development. The customer wanted four mast feed drills at the front of the machine dedicated to installing roof bolts and then another two mast feed drills behind them dedicated to rib bolts. This dictated the requirement of latched controls, which would allow the operator to start drilling one hole and then latch the controls to be able to move on to the next. To accomplish this, we developed a unique hydraulic latch circuit to maintain operator safety and compliance. Guarding was added to prevent an operator from coming into accidental contact with a latched drill. The result of the design is a machine with a single platform and six independent masts with drillheads: four masts strictly for drilling and installing roof bolts on the front of the platform and then two masts on the back of the platform for rib bolts. The feed and rotation controls at each operator’s station include a latch control for drilling. The latch control will allow the operator to lock in the feed and rotation once the hole has been collared, allowing the operator to move on to the next hole. The rear of the machine is equipped with material handling. There are two material pods with winch controls as well as a mesh rack that includes mesh lift, mesh tilt and mesh sump. The six-head roof bolter allows fewer operators to drill and install roof and rib bolts, which in turn lowers the miners’ roof exposure per cut. This design reduces the operator’s exposure from the inherent pinch points and rotary hazards once he has engaged the latch drilling. Therefore the machine will help to decrease the time to bolt a cut, improving productivity while enhancing the ability to operate the machine safely. INTRODUCTION When mining underground it is necessary to support the roof quickly to prevent it from collapsing after an area has been mined. Since the 1950s, the primary method for supporting the roof has been the installation of roof bolts. Roof bolting is one of the most basic functions yet one of the dangerous jobs in the underground mining operation (1). The Mine Safety and Health Administration’s (MSHA) Health and Safety Accident Classification injury database showed an average of 660 roof bolter operator accidents per year over a 5-year period (1999-2003) (2). The numbers show that roof bolting is the most hazardous machine-related job in underground mining. It represents 39 percent of all machine-related accidents in underground coal mines. In 1993, the U.S. Bureau of Mines conducted a study that has shown the activity of drilling as the most hazardous job task performed by a roof bolter operator, accounting for 31 percent of all roof bolting injuries (3). Almost half (46%) of these drilling injuries were due to falling rocks or coal from the roof. All of these injuries occurred under supported roof. The majority of these injuries (about 99%) are not caused by a major roof collapse but from falls of smaller rock from the immediate roof. This type of roof failure has also been termed “skin fall.”"

Jan 1, 2017

By Atmesh K. Sinha

Death and injury rates in mining have been the highest of any industry; the injury severity rates in mines have also been the highest. Tentative figures reveal that 1971 was the best year yet for the bituminous coal indus¬try with the lowest number of fatal accidents. Nevertheless, 177 men were killed at a frequency rate of 0.76 per million man hours. Coal mine accident statistics have been described at various times as unacceptable and intolerable and recently resulted in the enactment of massive legislation. The 1969 Coal Mine Health and Safety Act was passed by Congress "to improve the working conditions and practices in coal mines and to prevent accidents and occupational diseases originating in the coal mining industry." The prevention of accidents in coal mines is the statutory responsibility of mining engineers and the moral responsibility of all who have any part to play in mining coal. The questions to be answered by these men may well be - What are the reasons for the high accident rate? Are the mines as safe as they can be? Are our mines sufficiently manned to insure proper supervision of production cycles and safety requirements? Are our plans for safety committees, safety campaigns, and safety inspections sufficient? Are they producing the results intended? If not, how can these be reorganized to have a greater impact? What is the real cost of an accident? What are the immediate and long-term plans for further improvements? These questions are in no way exhaustive, and the answers are not easy. There are many aspects of mine safety, and any one of them can be the subject of a lengthy discussion. The aim of this paper, therefore, is to limit the analysis to documented fatal electrical accidents in mines so that meaningful conclusions for improvement in electrical accident-experience statistics can be made. In doing this, it is also the intention to emphasize areas of missing information and propose a few suggestions for better hazard analysis.

Jan 1, 1972

By Sanket Rawat, Ravi Kant Mittal, Vikash Prasad

"The understanding of the response of pile foundations under various types of loads is a necessary prerequisite to analyze and design them properly. Therefore, this paper highlights and compares the provisions available in Indian Standard IS 2911:2010 to estimate the capacity of laterally loaded pile foundation with the provisions available in different country codes and existing literature. Comparisons are made between the Indian standard method, Broms method and Matlock & Reese method for the analysis of laterally loaded piles due to popularity and prevalence of the later methods in design offices worldwide. This has been achieved using a parametric study on pile embedded in pre-consolidated clay and sand for both fixed head and free head case in terms of displacement and ultimate load capacity. It has been found that there are various limitations to the Indian Standard method associated with various cases such as short pile analysis, complete moment distribution etc. Therefore, suitable recommendations have been made on the basis of the above comparison to improve the accuracy of the design in Indian perspective. The proposed comparison and subsequent area of improvements will present the design engineers all across the globe, a broad sight of design specifications of laterally loaded piles.INTRODUCTIONPiles in groups are very often subjected to both axial and lateral loads. In the 1960’s, designers used to assume that the piles could carry only axial loads and the lateral load is to be carried by batter piles. However, later, a large number of load tests authenticated that vertical piles also can transfer lateral loads through shear, bending, and lateral soil resistance rather than purely acting as axially loaded members. Initial attempts to analyze laterally loaded piles used the finite-difference method, as described by Howe (1955), Matlock and Reese (1960), and Bowles (1968). Matlock and Reese (1956) used the finite difference method to get a series of non-dimensional curves to enable the user to input the appropriate curve with the given lateral load and estimate the ground-line deflection and maximum bending moment in the pile shaft. Later, Matlock and Reese (1960) extended the earlier curves to include selected variations of soil modulus with depth."

Jan 1, 2017

By Wei Gao, Qing-cai Liu, Cun-fang Lu, Jian Yang, Hinmi Zheng

"The mode of occurrence of sulfur and mercury in 57 Chinese bituminous coals have been examined using X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), and Zeeman atomic absorption mercury spectrometer. Mercury levels in coal are related to the geographic location of the coals and types of the coals. A synthesis of result indicated that most likely occurrence modes of mercury in high-sulfur and high-mercury coals are in solid solution in pyrite. Our study from 57 coal samples showed that most values of mercury concentration in coal varied from 100 to 1000 ng/g with an average of approximately 500ng/g, and mathematical model about correlation between mercury and sulfur was gained by mathematical statistics. This is apparent that mercury and sulfur vary concomitantly from coal data (table 3) , the high correlation between them in all coals at confidence of 95% ( a=0.05 ) .1. INTRODUCTIONThere contained about one trillion ton abundant coal resources in China. As a leading level of proven coal reserves in the world, the coals mainly distributed in north China and northwest China, especially in Shanxi, Guizhou, Shanxi provinces and Inner-Mongolia autonomous region. At the same time, China has the largest production and consumption of coal, and has the output of coal nearly accounted for 37 percent of the world's production. Coal-fired power plants are the major source of energy generation in China, and the proportion of coal combustion is up to 75 percent in the total energy configuration. Therefore, the mercury pollution caused by coal-fired has become a topic of wide-spread discussions since 1990. The contamination of mercury of human activities accounted for 10 to 30 percent [1], and the mercury emissions of coal-fired flue gas has made the greatest contribution to the pollution of atmosphere[2] In the past 30 years, the global increasing concentration of mercury pollutant in atmosphere maybe result from coal combustion[2]. The mercury emissions caused by coal-burning has become the main reason of China's mercury pollution, and the characteristics of mercury pollution is closely related to China's energy configuration, additionally, the features of mercury pollution have changed from the point pollution in 1970's to diffused pollution today[3]. Mercury can be found in various types of coals, and it is evaporated into gas phase during the combustion process."

Jan 1, 2011

By T Honeyands, L Jelenich

We are currently witnessing large fluctuations in the relative price of ironmaking raw materials brought on by changes in the dynamics of supply and demand, market conditions, environmental regulations and technical factors affecting the iron and steelmaking process. From a customer perspective, it is the behaviour of iron ores in downstream processing that give them their value; their impact on the sintering or pelletising process and subsequently blast furnace ironmaking. It is therefore important to consider this value when developing projects, making mine planning/cut-off grade decisions and in setting price differentials for differing quality.This paper describes the use of the Marx value-in-use model to quantify the downstream value of lump iron ores. The Marx model consists of heat and mass balance modules for sintering and pelletising and a rigorous two-stage heat and mass balance model of blast furnace ironmaking. Mass balance and cost models are applied for steelmaking, casting and rolling. The use of a heat and mass balance allows accurate comparison of the impact of raw material properties on blast furnace operation. The impact of minor elements, such as alumina, silica and phosphorus, and metallurgical properties on ironmaking is described, and examples are given for the calculation of a lump premium.CITATION:Honeyands, T and Jelenich, L, 2015. Lump ore properties and their impact on value-in-use in ironmaking, in Proceedings Iron Ore 2015, pp 359–362 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Cassandre Nowicki, Louis Gosselin, Carl Duchesne

"Quebec's primary aluminium production industry consumes roughly 39 TWh of electricity per year and is accountable for roughly 7 million tons of CO2 equivalent. By tapping only a small portion of waste heat and integrating it inside the production facility itself, we can significantly reduce GHG emissions and energy consumption. Although the amount of thermal waste can be adequately estimated by applying an energy balance to production processes, this provides very little information on the quality of waste heat and its potential for integration. A measure of exergy is required. Waste heat streams characterized by high exergy content may generally offer valuable incentives for recovery and integration. More generally, exergy values limit integration possibilities. An exergy analysis is provided for the aluminium electrolytic reduction process. This is meant to guide future heat recovery initiatives and energy efficiency measures.IntroductionCanada is one of the world leaders in primary aluminium production and 92% of its aluminium production capacities are located in the province of Quebec. In 2007, production capacity reached 2,786,000 tons in Quebec alone. Since it is estimated that 2.5 equivalent tons ofCO2 are released for each ton of aluminium produced in Canada, Quebec's aluminium production industry is accountable for roughly 7 million tons of CO2 yearly [1, 2]. Furthermore, with an average electricity consumption of 14 MWh per ton, primary aluminium accounts for 39 TWh of electricity per year in Quebec and this energy consumption represents 350 thousand tons ofCO2 equivalent [3, 4]. Natural gas consumption associated with primary aluminium production accounts for less than 1 TWh, but it represents an additional 350 thousand tons of CO2 equivalent [ 4].This work is meant to provide a tool to guide future efforts towards heat recovery and energy efficiency in the primary aluminium industry. Waste heat recovery and thermal integration can cut down both energy consumption costs and GHG emissions. In a primary aluminium production facility, waste heat represents roughly half of the energy input into the Hall-Heroult process. Tapping only a small portion of this energy could reduce natural gas and electricity consumption significantly. In order to evaluate how much of this energy is actually usable, we propose to apply an exergy analysis to individual transformation processes in an aluminium production facility, such that a potential to do work can be assigned to every waste heat flux. The approach will be described in the next section."

Jan 1, 2012

By Peter G. Chamberlain

Many mining engineers considering in-place leaching for the first time are uncertain as to how to evaluate ore bodies for potential leachability. Evidence presented in this report emphasizes the critical role of permeability in such evaluations. Whether an engineer is considering leaching "tight" formations typified by the porphyry copper deposits of the southwest or the permeable uraniferous sandstones of Texas and Wyoming, permeability measurements are the keystone of any testing program. Permeability tests range from cheap and easy to highly expensive and sophisticated operations. Constant head, variable head, and pumping tests all have application in evaluating ore bodies for in-place leaching. Costs of these tests will not unduly deflate the pocket- books of most mining companies. The basic procedures for selecting and running these field tests-including preparing suitable wells--are reviewed for the benefit of newcomers to in-place leaching.

Jan 1, 1979

By Robert L. Russell

The Bunker Hill Mine, located in the Coeur d'Alene Mining District at Kellogg, Idaho, has been a major producer of lead-silver-zinc ores since its discovery in 1887. The mine has produced over 29 million tons of ore from some 20 to 25 veins and ore zones, and now covers an area approximately one mile in length and one-half mile in width. The active section of the mine extends from 2500 ft above sea level to 1600 ft below sea level. Production is presently at the rate of about 1700 tons of ore per day. A two-mile adit, the Kellogg Tunnel, at the 2500 elevation, provides access to the main shaft area. Ore is hoisted to the adit level through a 5000-ft, 500-inclined shaft, extending to the lowermost haulage level 1200 ft below sea level. Primary shaft service for men and materials is supplied by three major internal, inclined shafts equipped with double-drum hoists. Present production requires ten levels to serve for mainline track haulage. These range up to 5000 ft in length and are either 200 or 400 vertical feet apart. Also, many intermediate levels exist throughout the mine. The conventional and autoloader mechanized square-set and cut-and-fill mining methods used throughout the mine have been the subject of a recent paper(l). One-third of current production is from vein-type ore bodies which are long distances from main shaft areas. Such veins generally dip about 450, have relatively narrow widths of from 3 to 20 ft, and usually contain less than 500,000 tons of ore. For many years, ore bodies thus situated have been developed by means of a separate inclined, timbered service shaft-raise connecting two or more main haulage levels. These commonly range from 400 to 1000 ft in vertical extent and are equipped with 25 to 50 hp electric, single-drum hoists. Intermediate levels are driven as conventional track drifts at 100-ft vertical intervals between the haulage levels. Ore and waste from the intermediate levels are trammed to orepasses for delivery to the lowermost haulage level servicing an ore body. The final result may be visualized as a number of small mines within a large mine. The problems of high development costs and high total development time, and the large amount and high cost of providing materials handl ing and ore haulage service while producing from this isolated type of stope block, made it desirable to consider totally new approaches in developing and mining a number of similar areas.

Jan 1, 1971

By Boyd Guthrie

Methods of distilling topped crude oils and distillates under vacuum, accompanied by good fractionation, have taken a place of major importance in the refining industry. In the refining of petroleum products it is generally desirable to produce a distillate of good quality, and this objective is attained by fractionation of a high degree. The laboratory and commercial practice have proved that by varying the amount of fractionation the quality of the distillate can be changed, and refiners are cognizant of the advantages of good fractionation. Distillation under high vacuum, however, is a relatively new practice in petroleum refining, and only during the last few years has there been an indication that this method may become a general practice in the industry. Vacuum distillation offers many advantages over older methods of distilling petroleum products. Vacuum combined with steam distillation, for example, is replacing straight-steam distillation because the quality of the products of vacuum and steam distillation surpasses that of those produced by straight-steam distillation. Although the injection of varying amounts of steam in a vacuum unit is common practice, the amount of steam used is becoming loss as the vacuum within the unit is increased. This report describes the construction of a visible-action laboratory batch still and fractionating column and gives certain data pertaining to the operation of the apparatus under vacuum for the production of lubricating distillates. The apparatus was designed and built to produce lubricating distillates under as nearly ideal conditions as possible, in order that a subsequent study of the characteristics of the distillates could be made. For example, a study could be made of the distillates obtained up to the point of cracking of the charge if a topped crude were charged to the still; if the still was used as a rerun unit for lubricating distillates a study of nearly the entire charge could be made. Only topped crude has been charged to the still so far, and therefore this paper is limited to the results obtained from the distillation of such a charge. The results so far obtained indicate that such an apparatus is valuable in a study of different crude petroleums as sources of lubricating distillates.

Jan 1, 1932

By J. E. Nesset

Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right 'strength' is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry may also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.

Jan 1, 2009

By H. R. Manouchehri

"Pyrrhotite (Po) is one of the most abundant sulfide minerals in processing industry and must be rejected in most cases. Particularly, Po rejection and its selectivity against pentlandite (Pn) have long been a challenge due to similarities in the mineral composition of the two minerals and the collectorless flotation characteristics of Po. Xanthates have been widely used to promote sulfide mineral flotation; however, in the presence of xanthates, the redox potential established at the mineral/solution interface is most important, determining the flotation performance. In this paper, the importance of electrochemistry in Po and Pn flotation has been demonstrated and a comprehensive study was conducted on two different feed streams (i.e., magnetic concentrate and scavenger cleaner streams, containing magnetic and nonmagnetic forms of Po, respectively), from Vale’s Clarabelle Mill in Sudbury, Ontario, with an objective to determine if improvements in Po rejection and Pn recovery could be achieved by controlling pulp electrochemistry. By conducting a series of flotation tests under different Eh conditions and reagent usage schemes, it was revealed that higher Po content in the magnetic stream may protect Pn from being oxidized, improving Pn recovery. The results indicated that at low oxidizing pulp chemistry, the rest potential for the Pn is still high enough to allow the formation of dixanthogen to promote its flotation. Using a Pt electrode, it was found that by controlling pulp potential at -50<Eh< +50 mV, the Pn recovery and Po depression would be satisfactory. The results, using mineral electrodes (Outotec Chena analyzer), indicated that selective separation can be achieved if low-to-moderate oxidation potentials (0 to 100 mV) or reduction (0 to -100 mV) potentials are monitored using Pn and Po electrodes. Mixing two streams at 50:50 wt % would be possibly beneficial in selective separation.IntroductionPyrrhotite (Po), Fe1-xS, is one of the most abundant sulfide minerals in the processing industry. It is an iron-deficient sulfide that occurs either in monoclinic or hexagonal form. The monoclinic one is richer in sulfur and is ferromagnetic, whereas the hexagonal Po is poorer in sulfur and has no magnetic properties. In general, the ferromagnetic properties of natural Po increase with increasing sulfur content. Although Po holds significant iron content, it is not used as a feedstock for the iron and steel industry due to the difficulty in achieving complete removal of sulfur. The common availability of iron oxide ores makes the iron sulfides irrelevant for the steel industry."

Jan 1, 2015

By François Larouche

Since their commercialization in the early 1990s, lithium-ion batteries (LIBs) have become ubiquitous for powering a myriad of portable electronics. Their usage now extends to the automotive industry and stationary energy storage market. With an average life of 6.2 years and the strong demand, the volume of spent LIBs has increased exponentially, making recycling mandatory. Currently, recycling/ recovery of spent LIBs is limited in comparison to all other types of batteries. The current processes focus mainly on the recovery of the most valuable metals such as cobalt and nickel, leaving lithium and phosphate in a low value end-product. It is necessary that new advanced recycling technologies are developed for the recovery of spent LIBs both from an economic and environmental perspective. In this paper, the current R&D status of LIBs recycling is reviewed with the emphasis placed on hydrometallurgical processing opportunities for Li-ion and Li-solid state batteries.