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By C. G. Bieber, R. F. Decker

The effects of minor constituents on the malleability of nickel alloys are described. These effects are related to the atomic diameter, valence, and position on the Periodic Table. The basic methods for removal or neutralization of deleterious elements are then reviewed. Finally, practical methods for melting nickel alloys are described in detail and related to minor constituent control. L HE first malleable nickel was produced by Fleit-man in about 1870 by the addition of manganese and magnesium to the molten metal to counteract the harmful effects of sulfur. Merica and Waltenbergl explained the mechanism by which these elements accomplished the desired result. They showed that sulfur in concentrations in excess of about 0.005 pct produced films of a brittle low melting eutectic of nickel-nickel sulfide which completely surrounded the grains. When manganese was added to molten nickel it reacted with the sulfur to form manganese sulfide which precipitated as widely scattered globules in the grain boundaries. The further addition of small amounts of magnesium converted the sulfur to a very stable sulfide of magnesium which was relatively insoluble in both the liauid and solid states and therefore occurred as finely divided particles within the grains where it had relatively little detrimental effect upon the malleability of nickel or its alloys. The practice of treating nickel with manganese and magnesium came to be called "deoxidation" and was employed without appreciable modification for the commercial production of wrought nickel and high nickel alloys (in this paper—50 pct or more nickel) until about 1930 even though the results were never entirely satisfactory. At that time a more extensive study was made of the effects of minor constituents on malleability and metallurgical quality. The results, small portions of which have been published,2-4 are presented here with other pertinent data. EFFECTS OF MINOR CONSTITUENTS UPON NICKEL Systematic additions were made of 0.5 pct or less of each of most of the elements of the periodic ta- ble. It was established in this study that some minor constituents other than manganese and magnesium were extremely influential. The malleability, as evaluated by the reduction of area in tension tests, depended roughly on temperature as shown in Fig. 1. Four temperature zones are of interest; the cold malleable zone (up to about 1000° F), the red short zone from roughly 1000° to 1500' F, the hot malleable zone around 2000° F and the incipient melting zone. Most of the malleability problems are associated with the red short zone and the discussion will concern this mainly. The reduction of area in normal tensile tests on high-purity nickel (see curve A of Fig. 1) appeared to have no

Jan 1, 1962

By J. A. Brierley, C. L. Brierley

The history, current applications and future of biotechnical developments in the metals' extraction industry are reviewed. Bioleaching of copper minerals continues to be the most significant application. Uranium bioleaching was successfully demonstrated at industrial scale. Developments are now being made in biooxidative pretreatment of refractory gold concentrates, ores and low-grade materials. Advancements are forthcoming in water and solid mine waste bioreclamation, including metals' biosorption, wetland treatment of acid mine drainage, and biodegradation of cyanide in spent, heap-leach operations. Better understanding of the types and functions of microorganisms involved in metal interactions could advance genetic engineering applications in bioleaching and bioreclamation.

Jan 1, 1993

By J Cahill, M Lee

Leinster Nickel Operations, located in Western Australia, consists of an underground and three open pit mines in relatively adverse ground conditions. This paper reviews our ground control practices in the open pits, covering aspects of ground support, wall control and monitoring. These methods have been effective in allowing mining operations to continue beneath unstable slopes. In particular, the use of Groundprobe?s Slope Stability Radar has enabled the Harmony Open Pit to safely operate for months following indication of failure from traditional methods. This case study highlights the benefits of investing in appropriate slope stability monitoring systems.

Jan 1, 2006

LUTHER B. EAMES, Pueblo, Colo. (written discussion*).-In reading Mr. North's interesting paper, several points have been noted that appear to warrant discussion. With a feed all through 20 mesh, I feel inclined to question the use of steel balls as large as 2 in. in a tube mill. I have seen balls as small as-3/4 in. used for the dry grinding of cement clinker, and surely many more points of contact would result from smaller balls. This would seem to be desirable in a mill as short as 6 ft. The heavy load in the classifiers would also indicate a high proportion of returned pulp. I hope that some discussion by Mr. North -and others may develop this point. The flow sheet on page 1181 shows the solution returning from the dam valued at 40 c. per ton being added to the last decantation tank. Theoretically, this solution should not be added to that of a lower value. As I calculate it, if this solution were added to tank X the solution finally discharged from tank Z would be reduced in value by nearly 4 c. per ton.

Jan 10, 1919

By D. G. Foot, J. D. McKay, R. A. Ynchausti

The increasing popularity of column flotation as an efficient and profitable mineral beneficiation technique has resulted in the need to perform a study of basic column operating parameters in order to understand mineral behavior in a column. Variation of column rougher flotation parameters on the Nevada Fish Creek fluorite and Utah Collins manganese ores enabled characterization of four beneficiation zones within a column flotation cell. Although specific mineral behavior in each zone was peculiar to the mineral system involved, particle retention time predominantly affected both manganese and fluorite recoveries in the collection zones of the column while enhancing mineral grades in the cleaning zones. Column parameters such as column length, feed injection location, and tailings recirculation velocity were inherently linked to particle retention time and retention time distribution, both of which affected mineral recovery. Froth depth had a discernible effect on fluorite concentrate grades; as froth depth increased, fluorite grades increased. Wash water additions affected both fluorite and manganese recoveries and fluorite grade. Axial mixing drastically reduced fluorite and manganese recoveries due to short circuiting of some of the feed slurry in the column.

Jan 1, 1988

By Colin G. Wilson

This paper considers the heavy liquid laboratory tests used to determine the amenability of a potential ore to the heavy media process. The results of the laboratory testing are correlated to actual plant performance and establish design parameters for the heavy media process. These parameters are used in the development of the metallurgical flow sheet and in the sizing of equipment in the metallurgical plant design.

Jan 1, 1978

By C. R. Pelley

This paper describes the analytical characteristics of Western subbituminous coal and the manner in which these characteristics apply to their use in a utility-sized steam generator. It compares these characteristics with those of typical Midwestern coal and Eastern bituminous coal. The paper also reviews in detail the design considerations that must receive attention when various blends of these three coals, or any combinations thereof, are planned to be used. This research paper describes variations in analytical and utilization characteristics when coals from different origins are blended in order to achieve a predetermined sulfur content for the purpose of predicting sulfur oxides emissions as they affect environmental regulations and the resulting alterations in utilization characteristics such blending would cause, and how such blends of coal would affect a utility-sized steam generator.

Jan 1, 1979

By C. R. Pelley

Abstract-This paper describes the analytical characteristics of Western subbituminous coal and the manner in which these characteristics apply to their use in a utility-sized steam generator. It compares these characteristics with those of typical Midwestern coal and Eastern bituminous coal. The paper also reviews in detail the design considerations that must receive attention when various blends of these three coals, or any combinations thereof, are planned to be used. This research paper describes variations in analytical and utilization characteristics when coals from different origins are blended in order to achieve a predetermined sulfur content for the purpose of predicting sulfur oxides emissions as they affect environmental regulations and the resulting alterations in utilization characteristics such blending would cause, and how such blends of coal would affect a utility-sized steam generator.

Jan 1, 1978

By W. C. Elmore

THE magnetic powder method, long used. for roughly mapping mag-netic fields, has recently been refined 1,2 for investigating the microscopic variations in the surface magnetization of ferromagnetic crystals. Bitter2 first discovered regular powder patterns connected with the crystal structure of such specimens. Several other investigators3 have used Bitter's original technique, with slight modifications, to study the varia-tion of the patterns with variations in the magnetizing field applied parallel to the surface, and their dependence upon the state of strain, of polish and of crystal cut. All of the explanations of these patterns on metallic ferromagnetics have been couched in general terms. In a preliminary report we have described an improvement in the powder technique which led us to the discovery of a new effect throwing con-siderable light on the magnetic secondary structure of alpha iron4 and of nickels single crystals. We now report additional evidence confirming the existence and stability of a magnetic block secondary structure.

Jan 1, 1936

By W. C. Elmore

THE magnetic powder method, long used for roughly mapping mag-netic fields, has recently been refined 1,2 for investigating the microscopic variations in the surface magnetization of ferromagnetic crystals. Bitter2 first discovered regular powder patterns connected with the crystal structure of such specimens. Several other investigators3 have used Bitter's original technique, with slight modifications, to study the varia-tion of the patterns with variations in the magnetizing field applied parallel to the surface, and their dependence upon the state of strain, of polish and of crystal cut. All of the explanations-of these patterns on metallic ferromagnetics have been couched in general terms. In a preliminary report we have described an improvement in the powder technique which led us to the discovery of a new effect throwing con-siderable light on the magnetic secondary structure of alpha iron4 and of nickel5 single crystals. We now report additional evidence confirming the existence and stability of a magnetic block secondary structure.

Jan 1, 1935

By F O. Otuonye

Full-face blasts were fired in a 12 x 8 ft drift of an underground hardrock mine in a basalt formation with porphyry copper to study the effects of drill pattern and explosive type on the size distribution of the resulting muckpile. Each muckpile produced by five full-face blasts was sampled four times with a scooptram equipped with a 5-cu yd bucket and the size distribution of the broken rock in each bucket was determined by screen analysis. Results show a strong dependence of the fragment size distribution of muckpile on the blast pattern and explosive type for a given rock type. The mean fragment size of the broken rock was compared with the predictive equations of other investigators. Random sampling of the muckpile from full-scale blasts and screen analyses of the samples are recommended in assessing the size distribution of the broken rock because of scaling errors that are inherent in full-scale blasts when designed from results of small-scale tests.

Jan 1, 1985

Biologically-mediated phenomena are involved in many of the natural processes by which mineral deposits are formed and ore bodies transformed and degraded. They may facilitate the environmentally-damaging effects of mining and mineral-processing operat- ions. Under contrived and controlled conditions, however, these phenomena can form the basis for economically- attractive processes for the recovery of metals from low-grade deposits by dump, heap or in situ leaching. They have application also in processes for the regeneration of leaching reagents and some potential for'-the recovery of metals from dilute solution. The micro- organisms concerned are potential sources for the production of novel flotation and solvent-extraction reag- ents. Perhaps the greatest opportunity for biotechnological processes in min- ing and metallurgy lies in the possib- ility of the evolving of novel proced- ures for the substantially complete recovery of metals from process tail- ings by the unlocking of recalcitrant and complex mineral assemblages, and for the beneficiation of some mineral materi,hls.

Jan 1, 1982

By Bunting S. Crocker

In the summer of 1961, the Anaconda Research staff and Kilborn Engineering Ltd. began a study to investigate the possibilities of using some form of autogenous grinding in the new concentrator which Anaconda was planning to erect at Butte, adjacent to their Berkeley pit. The following criteria applied to the project: 1) The Butte mill was to be able to handle 36,000 to 42,000 tpd of copper ore, taken from the Berkeley pit and adjacent underground mines. 2) The plant was to be built in six units. 3) It would be started up two units at a time. 4) Equipment from the Anaconda mill was available for use in the new location. 5) Tonnage would be maintained at Butte and Anaconda, with equipment being moved down as required. 6) The ore from the Berkeley pit was known to vary widely from place to place in the pit and to be generally soft and friable.

Jan 5, 1964

By W. C. Elmore

THE magnetic powder method, long used for roughly mapping mag-netic fields, has recently been refined 1,2 for investigating the microscopic variations in the surface magnetization of ferromagnetic crystals. Bitter2 first discovered regular powder patterns connected with the crystal structure of such specimens. Several other investigators3 have used Bitter's original technique, with slight modifications, to study the varia-tion of the patterns with variations in the magnetizing field applied parallel to the surface, and their dependence upon the state of strain, of polish and of crystal cut. All of the explanations of these patterns on metallic ferromagnetics have been couched in general terms. In a preliminary report we have described an improvement in the powder technique which led us to the discovery of a new effect throwing con-siderable light on the magnetic secondary structure of alpha iron4 and of nickel5 single crystals. We now report additional evidence confirming the existence and stability of a magnetic block secondary structure.

Jan 1, 1936

By K. A. Natarajan, Abha Kumari

In this paper, electroleaching and electrobioleaching of ocean manganese nodules are discussed along with the role of galvanic interactions in bioleaching. Polarization studies using a manganese nodule slurry electrode system indicated that the maximum dissolution of iron and manganese due to electrochemical reduction occurred at negative DC potentials of -600 and -1,400 mV(SCE). Electroleaching and electrobioleaching of ocean manganese nodules in the presence of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans at the above negative applied DC potentials resulted insignificant dissolution of copper, nickel and cobalt in IMH2S04 and in sulfuric acid solution at pH 0.5 and 2.0. Mechanisms involved in electrobioleaching of ocean manganese nodules are discussed. Galvanic leaching of ocean manganese nodules in the presence of externally added pyrite and pyrolusite for enhancement of dissolution was also studied. Various electrochemical and biochemical parameters were optimized, and the electroleaching and galvanic processes thus developed are shown to yield almost complete dissolution of all metal values. This electrobioleaching process developed in the laboratory may be cost effective, energy efficient and environmentally friendly. Keywords: Ocean manganese nodules, Electroleaching, Electrobioleaching, Galvanic interactions

Jan 1, 2003

By Kevin Peacocke

The future of Gravity ? Primary mineral recovery ? Enhancement of existing process efficiency ? Pre-Concentration ? Alternative? or ?New? production

Jan 1, 2006

By K. A. Lewandowski

Agglomeration of ore used in heap leaching allows for the immobilization of fine particles that would otherwise migrate and cause permeability problems in the heaps. For copper ore, binders are needed in order to make stable agglomerates. However, the majority of binders break down when introduced to an acidic environment, allowing fine particles to be released from the agglomerate surfaces. These particles migrate through the heap impeding solution flow, leading to a decrease in metal recovery rates. The authors have developed a series of testing procedures to determine the acid resistance of several binders. Only five binders were shown to be acid resistant in soak tests, decreasing fines migration by up to 93%, compared to tests which were agglomerated with leach solution, raffinate, as a binder. Flooded percolation column testing also showed that these binders were able to reduce the "slump" of the ore by up to 82% and increased the hydraulic conductivity by up to 90%, when compared to agglomerating with leach solution alone. The use of binders in the agglomeration of copper ore also showed no negative effects on the bacterial populations throughout a leach cycle.

Jan 1, 2007

By Osamu Yamamoto

In antibacterial evaluation of carbon-ceramic composites, we prepared two type composites with emphasis on carbon-ZnO system; one was porous carbon materials containing ZnO nano-particles and another was porous ZnO coated with carbon thin film. Porous carbon samples containing ZnO at highly dispersed state were prepared by carbonizing the resin exchanged by Zn2+ ion. Porous ZnO coated with carbon thin film was obtained by the pyrolysis of poly (vinyl alcohol). Antibacterial activity of these composites obtained was evaluated by measuring the changes in electrical conductivity with bacteria growth. The antibacterial activity on the composites increased with the increase of t he amount of ZnO in composite and decreased with the increase of carbonization temperature. The antibacterial activity for Staphylococcus aureuswas found to be stronger than that for Escherichia coli. No activity of the carbon samples without ZnO was observed. The occurrence of antibacterial activity was supposed to be due to the generation of hydrogen peroxide from ZnO in composite. In the present work, antibacterial activity of carbon-ZnO composites was studied in the details.

Jan 1, 2006

By M. K. Larson

The U.S. Bureau of Mines and Cyprus Shoshone Coal Corp. conducted a study of deformation mechanisms around a longwall gate-road system in an underground coal mine. Of particular interest was roof deformation over the headgate entry. The strata above and below the coal seam are very weak, carbonaceous mudstones that have planes of weakness oriented along the bedding. Visual observations of previous gate roads over several years suggested that deformation was time dependent and resulted in creep along joints or crack growth. Instruments were installed at a test site to measure deformation around the entry, strew changes in the pillar, and loads transferred to support systems. Multipoint extensometers, instrumented bolts, instrumented trusses, biaxial stressmeters, borehole pressure cells, and single-point extensometers were installed. Monitoring continued until the longwall face passed the test site by 38.7 m (127 ft). Results show that fracture zones arched over the entry from both ribs, most bolts and trusses were loaded past their yield point, and the largest change in secondary principal stress was almost horizontal in the pillar. Displacement measurements in the roof showed classic primary creep.

Jan 1, 1995

The sedimentery basins of this region developed in the collision zone of the Pacific Ocean plate and the continent. Stresses were transmitted thorough wedge-like lithospheric blocks, such as the Okotsk Sea, East Kamchatka, Aleutian and 2 other smaller blocks. Compression and inversion were more active at the boundaries: P ; P3 ; N1 ; and Z N in places. ? K2 P2 P3 N2 Tension, rifting and the increase in the rate of sedimentation were marked in '-2 , P3, Ni - N2, and also N2 - Q in places. Structural plan changes of the sedimentary basins and possible oil, gas and fluid migration occurred more actively 2 3 1 2 at the boundaries: ; P3 . N? , N1 N1 NZ N2 P2 P3 1 N1 'N 2 N3 Ni 1 1

Jan 1, 1995