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By Joan C. Biordi

A molecular beam-mass spectrometer-low pressure flat flame apparatus has been constructed for the purpose of examining the chemical microstructure of normal methane-oxygen-argon flames and those inhibited with Halon extinguishants. Details of construction and performance of this apparatus and of related flame temperature measurements are given. Particular attention is paid to the empirical characterization of the perturbation to the flame caused by the sampling probes. The composition profiles obtained for normal flames are compared to those of flames inhibited by CF3Br. In addition to the usual stable species (CH4, O2, CO, CO2, H2O, H2, and H2CO), the inhibitor, its products and intermediates associated with its reactions could be followed. In particular, hydrogen bromide, bromine atoms, hydrogen fluoride, and carbonyl fluoride were observed. The relatively rapid disappearance of inhibitor and early appearance of fluorinated reaction products suggest a short lifetime for the CF3 radical in this system. Observation of COF2 suggests that CF3Br is effective as an inhibitor, at least in part, by virtue of its interference with the oxygen containing species of the normal chain reaction. Profiles of the 17+ peak at low electron energy suggests that the hydroxyl radical may also be sampled, but the profiles obtained are not yet sufficiently accurate to determine the effect of inhibitor on this important flame radical.

Jan 1, 1973

By D. B. Taliaferro

[Recovery of core specimens from subsurface formations and their subsequent analysis are important aids in efficient development and operation of oil and gas fields. Core specimen first were obtained mainly for the geologic information they revealed; now they are on analyzed to determine many of the physical characteristics and conditions of the subsurface formations as well. Cores recovered from the producing formations may be analyzed for porosity, permeability, oil content, "connate" water content, and other physical and chemical properties of the formation, all to the end of furnishing enough data for making reliable estimates of the quantity and availability of oil and gas within reservoir and in devising efficient means for their withdrawal.]

Jan 1, 1939

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By E. R. Cole

This Bureau of Mines investigation was prompted by the need forr a stable anode for electrowinning metals, particularly zinc and copper, from acid solutions. The polarization behavior of Pb-Ag (1 pct Ag) anodes in H2SO4 and fluoride solutions was determined as the first step in the development of such an anode. A Luggin capillary, dc power supply, high-impedance voltmeter, and other equipment standard to an electrochemical laboratory were used in this study. It was determined that during polarization, a relatively hard, stable coating of Pb02 was formed on the surface of the lead-silver anode and the rate of formation of this coating was considerably enhanced by the presence of fluoride ions in solution. Subsequent investigations at the Bureau of Mines Rolla Research Center resulted in the development of a Pb02-coated titanium (Pb02-Ti) anode. Results of this effort were presented in Bureau of Mines Report of Investigations 8111. Additional data resulting from extensive testing of the Pb02-Ti anodes, as well as process improvements and innovations, are included in this report. The anodes were considered generally unsatisfactory for zinc electrowinning because of lower conductivity, higher oxygen overvoltages, and shorter in-cell life as compared with the Pb-Ag anodes now being used in industry. However, the PbO2-Ti anodes were used successfully to oxidize waste chromium solutions and to electrowin copper.

Jan 1, 1981

By H. C. Fuller

Submerged combustion and inverse solubility methods were investigated as promising alternative means for crystallizing manganese sulfate from solutions produced by leaching manganese ores with either sulfuric acid or sulfur dioxide. Evaporation of water from typical manganese sulfate solutions by sub-merged combustion techniques enabled production of a slurry containing 32 to 39 pct MnSO4.H2O crystals suspended in a saturated solution of manganese sulfate. Such a slurry required further processing by thickening or filtration and drying to produce crystals of MnSO4.H2O. In a second approach, semicontinuous processing of manganese sulfate solu¬tions by thermal crystallization under pressure effected a recovery of 94.5 pct of the MnSO4.H2O as dry free-flowing crystals. Treatment of a solution containing about 100 grams manganese per liter at 189° C, produced a "barren" solution containing only 1.9 grams manganese per liter. Calculations made on comparable manganese sulfate solutions show that the heat requirement of the thermal crystallization method was about one-third to one-fourth that of the submerged combustion method.

Jan 1, 1966

By A. Mainza, H. Hill, L. Bbosa

"The main objective of ore breakage characterization is to quantify the relationship between the energy supplied for breakage and the size of the resultant progeny. In this study, the ore breakage characteristics of drill core particles and crushed particles were compared. Single impact breakage tests were conducted on a basalt ore sample using the JK rotary breakage tester. The size-dependent model by Shi and Kojovic was used to fit the breakage data because the effect of initial particle size is accounted for in the model. It was found that crushed particles consistently gave a higher degree of brokenness than drill core particles and the differences were attributed to the internal structure of the particle. Drill core particles contain a lower crack density (paths of weakness) than crushed particles which have been pre-weakened during the crushing process. An increase in crack density is directly related to a decrease in the minimum threshold energy. Upon application of a stressing force above the stress threshold, particles with a higher crack density will fracture more easily because of a higher rate of crack propagation due the numerous paths of weakness available. It was therefore concluded that under the same conditions, drill core particles are more competent than crushed particles. INTRODUCTION Comminution devices have commonly been reported as being the largest energy consumers in mineral processing circuits (Napier-Munn, 2015). Cleary (1998) reported that the inefficiency of comminution devices is a result of less than 5% of the supplied energy being utilized for breakage, with the majority being expended as heat and noise. With steadily declining fossil fuel supplies and a looming global energy crisis, the mineral processing industry has increased its focus on energy reduction measures. Ore breakage characterization plays a critical role in the design and optimization of comminution circuits (Tavares and King, 1998). The main objective of ore breakage characterization is to empirically quantify the relationship between the energy supplied for breakage (specific input energy) and the size of the resultant progeny through laboratory particle breakage tests (Napier-Munn, 1996). Commonly used laboratory breakage devices include the Drop Weight Tester (DWT), Split Hopkinson Pressure Bar (SHPB) and more recently, the JK Rotary Breakage Tester (JKRBT). Typically, a standard single impact breakage test procedure consists of a matrix of experiments on particles in four to five narrow size fractions each tested at low, medium and high energy levels. The resultant progeny of each test is sized to obtain a particle size distribution (PSD) from which the degree of breakage, usually in the form of a t10 value (percentage of the progeny material that passes 1/10 of the feed size) can be obtained for each size fraction and energy level (Napier-Munn, 1996)."

Jan 1, 2018

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0,5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that (1) the cost of slow cooling and crushing off-sets any advantages of higher copper recoveries from slow-cooled slag, and (2) water-quenched slag, which requires no crushing preparatory to grinding, could be treated more economically. Costs based on processing 1,000 tons of slag per day would be $1.85 per ton for quenched slag versus $2.37 per ton for slow-cooled slag.

Jan 1, 1971

By Mark A. Rohrbach, Timothy R. Kovacs, PhD Saidin

"Crosshole Sonic Logging (CSL) testing is commonly used to verify the integrity, quality and ultimately the acceptability of the concrete in structural elements such as drilled shaft foundations, secant pile cutoff walls, and secant/tangent pile earth retention structures. Besides concrete quality, many factors can impact CSL test results (e.g. laitance, air temperature, access tube spacing, access tube debonding, etc.). Effective use of CSL testing requires fully informed qualified practitioners capable of distinguishing between abnormal readings unrelated to deficiencies in the drilled shaft concrete and similar readings indicating the presence or possible presence of drilled shaft defects. Based on data and experience gathered from CSL testing of thousands of drilled shafts across North America, this paper discusses such factors and other information useful when evaluating CSL test results, and provides practical recommendations intended to reduce the potential for incorrect test data interpretation. The CSL testing industry is lacking in a clear, universally accepted guideline for the interpretation of CSL data and acceptance criteria of these concrete elements. This paper proposes terminology and a streamlined process for use when atypical results are obtained. The proposed terminology and method are intended to simplify and expedite the submittal review and approval process. Because construction activities for these elements are often on the project’s critical path, the benefits obtained in terms of project savings and reducing costly delays areundoubtedly valuable.1. INTRODUCTIONCSL testing is used extensively throughout the world on many projects to verify the quality of concrete used for drilled shaft foundations, secant pile walls, diaphragm walls, etc. In this paper, these structural elements will be referred to as “drilled shafts,” as they are the most common subject of this test method. In the United States, CSL testing is frequently specified by state and regional transportation agencies, ports, design builders, and others. Although other methods are currently available such as Gamma-Gamma Logging and low-strain Impulse-Echo or Sonic-Echo testing, and new methods are under development such as the Thermal Integrity testing, CSL testing is likely to remain one of the most useful tools for evaluating the acceptability of constructed drilled shafts for quite some time. The popularity of CSL as a testing method can be attributed to two main factors: 1) there is no depth limitation to the method and 2) the apparent ease of interpreting the results. A third advantage of CSL testing is that, when correctly interpreted and with adequate test coverage, it is unlikely to misrepresent a defective profile resulting in acceptance of a defective or inadequate drilled shaft. In other words, CSL testing is very likely to underestimate concrete quality/drilled shaft acceptability within its area of coverage."

Jan 1, 2017

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Lenore Rainey Christian, J. Feldermann

"Interest in the fine structure of soots and carbon blacks is motivated by a variety of possible applications. The structure provides information on the origins of the particles and on their adsorptive and reactive properties. This paper describes a method for quantification of the structure of soots and carbon blacks based on direct electron microscopic observation followed by image analysis of these materials. High-resolution transmission electron microscopy (HRTEM) provides a very detailed observation of particle structure. The differences in soot structure, because of its complexity, may not be easily quantifiable with the human eye; therefore, high-level computer software has been used to manipulate HRTEM images. This technique involves the application of fast Fourier transforms (FFT) to single particles and the measurement of characteristic parameters such as interplanar spacings and crystallite sizes from these particles. The methodology and application of this characterization technique are presented here. Results are shown for dif¬ferent samples obtained from soot and carbon black particles selected to illustrate the capabilities of the methodology. Quantitative information can be obtained on structural characteristics, e.g., interplanar spacing, circularity, orientation, elongation, and length distribution of lattice fringes, as well as on the fractional coverage of the extracted pattern. c 1996 Wiley-Liss, Inc.This paper presents a combination of techniques for recognizing and classifying different carbonaceous materials, using their structural morphology. A new method to assess and quantify the parameters which define such structures is proposed and discussed. The technique is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, cokes, chars, etc. possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure (Buseck and Bo-Jun, 1985; Buseck et al., 1987). The carbon structure has been variously described as turbostratic (Oberlin, 1989) or as crumpled sheets (Rouzaud et al., 1991) to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers, but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as on the composition of the source of the carbonaceous material. The value of the electron microscope in studying the morphology of such materials has been well-established, and abundant information is available (Ishiguro et al., 1991; Lahaye and Prado, 1978; Buseck, 1992).The use of HRTEM has brought further insight into this matter. Qualitative assessment of the structural order of such materials has been attempted over a long period of time in order to differentiate between various sources or treatments. There is, to date, no successful method available for quantifying the structural characteristics of various carbonaceous materials. This paper presents a technique which is able to recognize dif-ferent materials and to quantify the structural parameters of those materials using HRTEM and computational image analysis, including pattern recognition techniques.In the case of perfectly ordered graphitic crystals, electron diffraction is widely used for obtaining details on structure. Analysis of diffraction patterns can reveal parameters such as interplanar spacing, d002, crystallite size along the c-axis, Lc, crystal size in the plane of the layers, L., mean number of crystallites, Nc, etc.Complicated electron microscopy methods such as defocusing, tilted illumination, axial illumination, etc., often have to be used in order to characterize complex materials such as randomly oriented crystals in soots and carbons. Obtaining the right fo"

Jan 1, 1998

By Olli Haavisto, Lauri Koresaar, Navid Khajehzadeh

In recent times sustainable minerals processing is an important topic in research. Sustainable mining is linked with efficient use of energy and human resource in all process stages including beneficiation of the ore. Controlling and optimizing the recovery while preserving the grade of the concentrate is extremely important in flotation plants. This development requires new technological solutions and has given rise to the multitude of application areas for lasers. X-ray Fluorescence (XRF) and Laser-Induced Breakdown Spectroscopy (LIBS) are currently two of the predominant non-contact and direct analysing methods in industry. LIBS and XRF measurement techniques both have high capabilities for measuring elements. LIBS has a very simple and easy-to-implement spectroscopic setup, wider range of elements can be detected with online LIBS and measuring light elements is simpler by LIBS compared with XRF. It is of great interest to extract mineralogical information from the elemental results with no modification on the measurement setup. In order to achieve this, more advanced interpretation of the elemental peaks of LIBS spectra is required. Therefore, the major focus of this research is about measuring mineral concentrations from the elemental lines of LIBS spectra using advanced statistical methods. This accomplishment provides knowledge about mineral concentrations from the real-time assay data of the slurry LIBS analyzer. Consequently, this paper first discusses an analytical method called partial least squares regression leading to rapid mineral identification from the elemental contents of the LIBS technique. Then the technique is employed to analyze the mineral contents quantitatively through the information acquired from an on-stream LIBS slurry analyser. This can lead to many benefits such as rapid control of concentrate quality, enhanced recovery, saving time, energy and manpower.

Jan 1, 2016

By Chao Li, Qian Li, Yong-bin Yang, Kai Li, Qiang Xie, Yuan-yuan Zhu, Dong-ye Li, Qi-bing Tan

"The permeability of sintering mix is a vital technological property in sintering process. However, it can only be measured by off-line method on samples picked from the production. In order to acquire the properties of sintering mix accurately, on-line measuring of permeability is urgently required. Based on the reflection characteristics of bed permeability on pipe flowing parameters, a new method is presented in this paper for on-line measuring of sintering mix permeability. The measurement can be performed by blowing gas flow in the bed with the measuring pipe. Measuring results are obtained by picking the data on flowing rate and pressure in the pipe. The function of flowing rate to pressure may be certain for samples with the same permeability. Thus, the permeability was determined by contrasting this function to the result of off-line measuring, and the relative coefficient or R2 value was more than 99%.IntroductionThe permeability of sintering mix is a vital technological property in sintering process, which directly determines production and quality of sinter, or even determines whether the sinter production is carried out smoothly [1,3].The permeability have more obvious influence on vertical sintering speed, which is mainly related to air quantity passing through material bed. Under certain inducing capacity and negative pressure, the vertical sintering speed mainly depends on the permeability of sintering mix. Low permeability may make burning through point of sintering move back, and the sinter mix cannot be burnt through. High permeability may make burning through point of sintering move forward, improving production efficiency by increasing the speed of sintering machine [4] Good permeability means a small resistance of fan ,reduction of negative pressure of sintering machine, and full contact between air and sulfide, which can strengthen physical-chemical reaction during sintering process and increase desulphurization rate. In gas well through material layer process, gas-solid desulfurization reaction and gas-solid-liquid heat exchange are completed and hot gas through the combustion zone supplies the sintering process with heat. Finally uniform sintering of the material layer in height and width direction is achieved [5] While high permeability index leads to weak sinter strength, fast sintering speed, short residence time of high temperature region and little liquid phase. Moreover, liquid phase in the fast cooling process is too late to fully crystallize but forming glass phase which is harmful to sinter strength as well. Bad permeability means a big fan resistance and increase of negative pressure of sintering machine, which make the air pass through material layer difficultly. When air and mix contact difficultly, removal of sulfide reduces so that desulfurization is incomplete. Meanwhile, low caking efficiency, slow sintering speed and easily burnt sinter , reduce sinter output. Therefore appropriate permeability of sintering mix is the premise of stable burning through point and satisfactory sinter output and quality."

Jan 1, 2013

By E. K. Stanek

This volume describes software developed for programmable calculators that is useful in the analysis and design of mine electrical power systems. The programs are equally useful for any industrial or commercial power system. All programs are written for both the HP-97 and the TI-59 programmable calculators. Listings of both versions of the twelve programs that were developed appear in the report. The programs that were developed can be broken into two groups. The first group encompasses design-oriented programs. The second group encompasses analysis programs. For each program the following items are provided: a description of the program's capabilities, the solution technique used, instructions on how to use the program, a worked out example with data and results and, finally, listings of the programs for the HP-97 and TI-59 programmable calculators. Typical problems that can be attacked with these programs include ground bed design, selection of contactor size, fuse size, relay settings, instantaneous overcurrent trip settings for trailing cables, allowable cyclic cable loading, short circuit analyses, prediction of transient voltages and others.

Jan 1, 1979

By Evan Just

?We are certain there is need for research in every phase of mining." This statement by R. M. Crump of the Jones and Laughlin Steel Company (047) paraphrases opinion widespread among mining people. It is undoubtedly true. In preparation for this presentation, 193 organizations were asked to describe their mining research efforts. 60% responded, The meaning of "research" was taken in several different ways. The continual efforts of progressive companies to improve themselves were reported as research. We will call this and any effort to solve specific and immediate problems "practical research". The continuing investigation of subjects of long range interest will be called "basic research".

Jan 1, 1961

By Hewitt Wilson

A review is given of the nomenclature, sources, imports, statistics, common methods of preparation, and testing of mineral pigments. A description of the Deer Park-Spokane colored-clay district and the laboratory methods of preparation of these colored clays, others, and siennas follows. The mineral pigments were prepared by washing or grinding the original material as received and by calcination of the yellow ocher and brown sienna with and without manganese dioxide to produce red, brown, and black colors. These prepared powders were tested for fineness, oil absorption, and color as compared with well-known brands of commercial pigments. Similar tests were made with several basalt red clays occurring in the neighborhood of Salem, Oreg., and Kalama, Eatonville, and Clay City, Wash. The color particularly was studied, since this property is the most important commercial characteristic of the minerals. PURPOSE OF INVESTIGATION Since the development of the clay industry in the Pacific Northwest, some curiosity and interest have been aroused by the red and yellow clay or ocherouslike material that has often been found associated with the commercial clay deposits. These include the red and yellow "paint pots" near Deer Park and Spokane in eastern Washington, a red clay at Clay City, another close to Eatonville in western Washington, and red basalt earths near Salem, Oreg., and along the Columbia River near Kalama, Wash. Several companies have been organized to produce pigment colors from two of these deposits but have either discontinued or never started operations.

Jan 1, 1929

By J. D. Noll, J. A. Organiscak, A. B. Cecala

Significant strides have been made in optimizing the design of filtration and pressurization systems used on the enclosed cabs of mobile mining equipment to reduce respirable dust and provide the best air quality to the equipment operators. Considering all of the advances made in this area, one aspect that still needed to be evaluated was a comparison of the efficiencies of the different filters used in these systems. As high-efficiency particulate arrestance (HEPA) filters provide the highest filtering efficiency, the general assumption would be that they would also provide the greatest level of protection to workers. Researchers for the U.S. National Institute for Occupational Safety and Health (NIOSH) speculated, based upon a previous laboratory study, that filters with minimum efficiency reporting value, or MERV rating, of 16 may be a more appropriate choice than HEPA filters in most cases for the mining industry. A study was therefore performed comparing HEPA and MERV 16 filters on two kinds of underground limestone mining equipment, a roof bolter and a face drill, to evaluate this theory. Testing showed that, at the 95-percent confidence level, there was no statistical difference between the efficiencies of the two types of filters on the two kinds of mining equipment. As the MERV 16 filters were less restrictive, provided greater airflow and cab pressurization, cost less and required less-frequent replacement than the HEPA filters, the MERV 16 filters were concluded to be the optimal choice for both the roof bolter and the face drill in this comparative analysis case study. Another key finding of this study is the substantial improvement in the effectiveness of filtration and pressurization systems when using a final filter design.

Aug 1, 2016

A symposium on pneumatic transportation of solids was held at Morgantown, W. Va., October 19-20, 196'), under the cosponsorship of the Institute ref Gas Technology. Chicago, Ill., and the Bureau of Mines. Objective of the symposium was to present information on developments and projected programs in the technology of feeding, transporting, recompressing, and utilizing gas-solids mixtures Dr. Henry R. Linden, Director, Institute of Gas Technology and Harry Perry, Director of Coal Research, Bureau of Mines, in the initial addresses at the symposium welcomed more than 140 representatives of industry, educational institutions, and government from 16 states, Canada, Great Britain, etc.

Jan 1, 1966

A symposium on pneumatic transportation of solids was held at Morgantown, W. Va., October 19-20, 1965, under the cosponsorship of the Institute ref Gas Technology. Chicago, Ill., and the Bureau of Mines. Objective of the symposium was to present information on developments and projected programs in the technology of feeding, transporting, recompressing, and utilizing gas-solids mixtures. Dr. Henry R. Linden, Director, Institute of Gas Technology, and Harry Perry, Director of Coal Research, Bureau of Mines, in the initial addresses at the symposium welcomed more than 140 representatives of industry, educational institutions, and government from 16 states, Canada, Great Britain, etc.

Jan 1, 1966

By L. A. Conley

This report, covering the period January through December 1976, contains abstracts of articles related to cost engineering and economics for chemical and petroleum plants, mining, and other mineral industries from the following periodicals: 1. Air Pollution Control Association Journal 2. Chemical Engineering 3. Chemical Engineering Journal 4. Chemtech 5. Coal Age 6. Coal Mining and Processing 7. Combustion 8. Drilling-DCW 9. Electrical World 10. Engineering and Mining Journal

Jan 1, 1977

By Ronald S. Conti

Historically, underground mine rescue teams have received training only in the course of actual emergencies, or in simulated mine environments, usually on the surface, with placards to identify objects and hazards. Also, while U.S. Federal Regulations require all underground miners to walk escapeways and conduct fire drills every 90 days, this does not fully prepare them for the conditions that may be encountered in real escape situations, such as smoke filled entries. This paper describes technology and realistic training simulations that have been identified for the general workforce and mine emergency responders. Of all the technology evaluated by underground personnel, laser lights and lifelines were most beneficial in leading personnel to safety and out of the mine in smoke-filled passageways. These technological advancements can improve the state of readiness for rescue personnel and increase the chances of survival for personnel escaping from underground emergencies.

By Mohammed Ali Shah, Martin Waller

The mining industry depends to a large extent on the availability of high performance equipment. For drilling this means a requirement for well engineered, reliable machines with mechanised handling and widespread utilisation of automatic control. Such machines enable performance optimisation of drilling operations and integration into a high productivity mining system. A review is presented of the current status of drilling technology as applied to the mining and minerals industry. This covers developments in: drill bit materials and design; drilling techniques; machine design; mechanisation; automation; and drilling control. It also covers the ways in which current and future mining methods and practices will influence the applications and demands placed on drilling activities. The probable impact of current research on the industry is discussed.

Jan 12, 1992