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By Robson Jacinto Coelho

A equipe da Coqueria identificou a possibilidade de reduzir o Burn Loss, que é a perda de material por queima durante o processo de coqueificação. Após uma série de estudos, utilizando a metodologia Seis Sigma, identificou-se oportunidades de melhorias operacionais que trariam mais eficiência, estabilidade operacional e consequente aumento na produção de coque e vapor, tais como: maior controle na admissão de ar, controle das perdas de coque e carvão, vedação dos fornos de coque e execução de paradas programadas específicas para Preservação Refratária, com foco na redução do back log e consequente prolongamento da vida útil das baterias de fornos de coque. A redução Burn Loss aumenta o rendimento coque/ carvão, com consequente redução do consumo específico de carvão e aumento na produção de coque e vapor. A implantação desse projeto permitiu a redução de 2,5 dólares por tonelada de aço produzida no Fiscal Year 16/17.

Oct 30, 2017

By R. Kramer, A. Habibi

A ventilation survey was conducted in an underground longwall trona mine. The mine is relatively shallow and categorized as a gassy mine. The ventilation system includes three intake and six exhaust shafts, and three surface axial fans ventilate the mine in a blowing configuration. Airflow quantity, pressure losses and air psychrometric characteristics were quantified, and the influence of moving cages and skips in the shaft examined. The benefits of utilizing high-accuracy digital pressure transducers and advanced psychrometers were seen when undertaking a “leapfrogging” survey to gather data needed to build a computer ventilation model. Two underground booster fans with VFDs are idle but available at the mine. The ventilation model was used to determine the optimal booster fan locations to decrease operating cost by reducing the load carried by the main fans. A leakage study was conducted to evaluate the effects on the system of additional pressure from a booster fan. The study finally prepares a future ventilation model for the next 15 years of mine operation and investigates the effect of proposed scenarios.

Jan 1, 2014

By G. I. Mathieu

Research and development studies were carried out at the Canada Centre for Mineral and Energy Technology to produce a synthetic forsterite sand from asbestos tailings for Les Sables Olimag Inc. The National Research Council of Canada also supported and collaborated to the project. Theoretically, the technological approach consists of a heat at over 1300°C; however, the process without additive would result in the production of an enstatite-rich product (MgSiO3) having a fusion temperature less than 1600°C. The purpose was to foster the formation of forsterite (Mg2SiO4), a more refractory compound. The fabrication of the forsterite product requires pre-agglomeration of serpentine-MgO with a binder, which is stable at high temperature, to prevent the loss of the powdered magnesium oxide as dust in the kiln off gases and to maintain the mixture homogeneous during the process. Characterization of the end products with respect to mineral composition and thermal resistance are described. The synthetic forsterite in sand form was tested with success under a bath of liquid steel maintained at 1700°C for up to two hours. The advantages of the new sand and its potential applications will be reviewed.

Jan 1, 1992

By A. S. Nowick, E. S. Machlin

ONE of the main criteria used to rate the heat-resisting properties of alloys is stress rupture.1 During a stress-rupture test a tensile specimen is held under a constant load at a constant temperature until it fractures. The chief measurement made during this test is the time required for rupture at the specific test stress and temperature. It was found empirically from a series of stress-rupture tests at a constant temperature that when the logarithm of the time for rupture is plotted against the logarithm of stress a straight line is obtained within experimental error.2~3 This method of showing stress-rupture data has been adopted by many investigators and the KACA.4 By interpolation and extrapolation from these plots, values of the stresses required to rupture the specimens (the rupture strengths) in 10, 100, and 1000 hr are obtained for specific temperatures. Alloys are then rated for a particular application on the basis of their rupture strengths at the rupture life that most nearly represents the application. Inasmuch as stress rupture is an important criterion in rating heat-resisting alloys, it would be advantageous to know the quantitative dependence of the time for rupture on stress, temperature, com- position, and structure. In order to obtain this information, an investigation was made at the KACA Cleveland laboratory during the spring of 1945. The theory of rate processes was used because it has been found to apply to certain processes such as chemical reactions, viscous flow, and creep that occur at a definite rate for given conditions. It was thought that stress rupture was such a process. An equation was derived that gives, for a given com- position and structure, the dependence of the time for rupture on stress and temperature. The investigation is part of a general program to provide information that will lead ultimately to the development of better alloys in order that the efficiency and power output of gas turbines used in aircraft propulsion can be increased. THEORY The theory of rate processes will first be discussed as a general theory. It will then be shown that if stress rupture of heat-resisting alloys can be treated as a rate process, certain equations must be satisfied. Later sections will then show that these equations are satisfied. General Theory of Rate Processes The theory of rate processes5 eveloped by Eyring and others has been applied to chemical reactions as well as to other processes such as viscosity of liquids and diffusion. In every case in which rate- process theory can be applied, there is a small subdivision, so that the macroscopic process is the net effect of all the small processes. This smallest subdivision is called the "unit process.'' For example, in a chemical reaction the unit process is

Jan 1, 1947

By A. S. Nowick, E. S. Machlin

One of the main criteria used to rate the heat-resisting properties of alloys is stress rupture.' During a stress-rupture test a tensile specimen is held under a constant load at a constant temperature until it fractures. The chief measurement made during this test is the time requird for rupture at the specific test stress and temperature. It was found empirically from a series of stress-rupture tests at a constant temperature that when the logarithm of the time for rupture is plotted against the logarithm of stress a straight line is obtained within experimental error This method of showing stress-rupture data has been adopted by many investigators and the NACA.' By interpolation and extrapolation from these plots, values of the stresses required to rupture the specimens (the rupture strengths) in 10, roo, and 1000 hr are obtained for specific temperatures. Alloys are then rated for a particular application on the basis of their rupture strengths at the rupture life that most nearly represents the application. Inasmuch as stress rupture is an important criterion in rating heat-resisting alloys, it would be advantageous to know the quantitative dependence of the time lor rupture on stress, temperature, composition, and structure. In order to obtain this information, an investigation was made at the NACA Cleveland laboratory during the spring of 1945. The theory of rate processes was used because it has been found to apply to certain processes such as chemical reactions, viscous flow, and creep that occur at a definite rate for given conditions. It was thought that stress rupture was such a process. An equation was derived that gives, for a given composition and structure, the dependence of the time for rupture on stress and temperature. The investigation is part of a general program to provide information that will lead ultimately to the development of better alloys in order that the efliciency and power output of gas turbines used in aircraft propulsion can be increased. Theory The theory of rate processes will first be discussed as a general theory. It will then be shown that if stress rupture of heat-resisting alloys can be treated as a rate process, certain equations must be satisfied. Later sections will then show that these equations are satisfied. General Theory of Rate Processes The theory of rate processes5 developed by Eyring and others has been applied to chemical reactions as well as to other processes such as viscosity of liquids and diffusion. In every case in which rate-process theory can be applied, there is a small subdivision, so that the macroscopic process is the net effect of all the small processes. This smallest subdivision is called the "unit process." For example, in a chemical reaction the unit process is

Jan 1, 1948

By A. S. Nowick, E. S. Machlin

One of the main criteria used to rate the heat-resisting properties of alloys is stress rupture.' During a stress-rupture test a tensile specimen is held under a constant load at a constant temperature until it fractures. The chief measurement made during this test is the time requird for rupture at the specific test stress and temperature. It was found empirically from a series of stress-rupture tests at a constant temperature that when the logarithm of the time for rupture is plotted against the logarithm of stress a straight line is obtained within experimental error This method of showing stress-rupture data has been adopted by many investigators and the NACA.' By interpolation and extrapolation from these plots, values of the stresses required to rupture the specimens (the rupture strengths) in 10, roo, and 1000 hr are obtained for specific temperatures. Alloys are then rated for a particular application on the basis of their rupture strengths at the rupture life that most nearly represents the application. Inasmuch as stress rupture is an important criterion in rating heat-resisting alloys, it would be advantageous to know the quantitative dependence of the time lor rupture on stress, temperature, composition, and structure. In order to obtain this information, an investigation was made at the NACA Cleveland laboratory during the spring of 1945. The theory of rate processes was used because it has been found to apply to certain processes such as chemical reactions, viscous flow, and creep that occur at a definite rate for given conditions. It was thought that stress rupture was such a process. An equation was derived that gives, for a given composition and structure, the dependence of the time for rupture on stress and temperature. The investigation is part of a general program to provide information that will lead ultimately to the development of better alloys in order that the efliciency and power output of gas turbines used in aircraft propulsion can be increased. Theory The theory of rate processes will first be discussed as a general theory. It will then be shown that if stress rupture of heat-resisting alloys can be treated as a rate process, certain equations must be satisfied. Later sections will then show that these equations are satisfied. General Theory of Rate Processes The theory of rate processes5 developed by Eyring and others has been applied to chemical reactions as well as to other processes such as viscosity of liquids and diffusion. In every case in which rate-process theory can be applied, there is a small subdivision, so that the macroscopic process is the net effect of all the small processes. This smallest subdivision is called the "unit process." For example, in a chemical reaction the unit process is

Jan 1, 1948

In ilmenite smelting, the FeO content of the feed material (nominally FeO.TiO2) is decreased by reduction with carbon. In a parallel reaction, a significant amount of the TiO2 is reduced toTi2O3. One of the striking features of these reactions is a consistent relationship between the extents of FeO and TiO2 reduction; this relationship is independent of furnace size. It was recently proposed that this relationship follows from the solidification behaviour of the slag, where the final slag composition corresponds to the minimum melting point (?eutectic groove?) in the FeO-TiO2-Ti2O3 phase system; the hypothesis is that solidification equilibrium with the freeze lining stabilizes the slag composition. If this is the case, the system of slag and freeze lining must be capable of correcting two types of disturbances: thermal and compositional. Thermal disturbances result from incorrect power input, for the feed rates of ilmenite and reductant. For example, excessive power input will tend to overheat the slag, causing the freeze lining to melt partially, establishing a new steady-state heat loss from the furnace. Compositional disturbances result from an incorrect reductant input for the given power and ilmenite input. In this work, the dynamic response of the slag and freeze lining to different inputs (flow rates of ilmenite and reductant, and power input) is modelled. The model is based on solidification equilibria, and quantified heat loss through the freeze lining. The conclusion is that the solidification equilibrium cannot constrain the composition to the eutectic groove for typical operating conditions. Keywords: ilmenite smelting, freeze lining, solidification, high-titanium slag

Jan 1, 2004

By F. G. Schora

The Institute of Gas Technology (IGT), under sponsorship of the U. S. Department of the Interior, Office of Coal Research (OCR), and the American Gas Association (A. G. A. ), has been undertaking the development of one of several processes to convert coal to high-Btu gas as a means of supplementing natural gas supplies. It is anticipated that there will be a significant need for such gas in the foreseeable future in order to meet the ever increasing demands for this preferred fuel form. HISTORY The development of the HYGAS® Process is based on various studies conducted at IGT starting back as far as 1945. Initial work was directed toward production of synthesis gas with subsequent catalytic methanation. By 1964 the concept of the direct hydrogenation of coal to produce methane noncatalytically was well-founded and the chemistry was reasonably well established. Work up until this point in time was financed by the American Gas Association. In 1964 the U. S. Department of the Interior, Office of Coal Research joined with A. G. A. to support the program. The objective at that time was to develop the necessary know-how to enable the design of a pilot plant, a necessary step in the ultimate commercialization of the process. Work for the next three years (1964-1967) emphasized investigation of fluidized-bed technology in the hydrogasification step, where moving-bed technology had been previously employed, as well as identification of commercially available catalysts acceptable for catalytic methanation of the CO and hydrogen in the hydrogasifier effluent under operating conditions in the system. By 1967, the preliminary design of a 3 ton/hr pilot plant had been finalized, and IGT received authorization from OCR to proceed with the detailed design and construction of that facility. The pilot plant was designed to study the following problems:

Jan 1, 1972

By Amir Rehmat

The Institute of Gas Technology has developed a fluidized-bed process for recovering direct reduced iron from blast furnace flue dust a material currently considered to be a waste from the iron and steel industry. In the process, a portion of the carbon in the flue dust is combusted to supply energy for the endothermic reaction between carbon and steam. The reaction produces reducing gases comprised of carbon monoxide and hydrogen both of which react with iron oxides to produce reduced iron. Up to 95 percent of the iron oxides contained in the waste stream can be reduced to elemental iron. The vitiated reducing gases emanating from the process can be used as fuel in the plant. The yield of iron depends upon the quantity of iron oxide present in the flue dust and generally ranges from 20 to 30 percent of the waste stream. The investment cost estimated for a single processing train dedicated to one steel plant can be recovered in less than one year.

Jan 1, 1996

By Y. H. Su, C. Y. A. Tsao

"The solidification behaviors and velocity of atomized droplets during flight is formulated by a mathematical model, in which the concept of transient nucleation is applied. During the flight, the droplet velocity shows a maximum, followed by an inflection phenomenon. The velocity of large droplet is lower than that of small droplet at shorter flight distance, and higher than that of small droplet at longer flight distance. The effect of the gas flow pattern is more significant at longer flight distance than at shorter flight distance at a given flight distance, large droplet has higher temperature than small droplets prior to nucleation. Large droplet has higher nucleation temperature than small droplet. Medium size droplet flies over the shortest flight distance before the nucleation starts. At the end of recalescence, large droplet has less solid fraction than small droplet has.IntroductionTraditional concept of steady state nucleation was used in all the previous models describing the solidification of molten droplets. [1-5] However, during atomization, the solidification rate of the molten metal droplets is very high, and therefore there is very little time for the nucleation event to occur. In the present work, the concept of transient nucleation [6] is considered to model such short nucleation event during solidification of the atomized droplets. The solidification behaviors and velocity of atomized droplets are modeled and the effects of the atomization gas flow pattern are also presented."

Jan 1, 1997

By Claudio Parra De Lazzari

The determination of the governing step of the deoxidation rate and the effects of the hydrogen content of the mixtures (C), the diameter of the delivery orifice (4) and the Reynolds number of the orifice (Re.) on the product Av kjg were investigated. A,, is the total surface area of the interface between the bubbles and the melt and kjg is the mass transfer coefficient in the gas phase. The design of the experiments was based on a two level statistically fractionated, factorial planning. Oxygen in the melt was measured as a function of time. It was found that the governing step of the deoxidation rate was the transport of hydrogen in the gaseous phase and that {Ay kjg} increases with C, {o} and Reo.

Jan 1, 1997

By T. J. A. Smith

This paper provides an overview of some of the key issues in design of smelter gas handling systems, with particular reference to smelter smelting plants. In both primary smelting and converting, gas handling and treatment systems often represent the major capital cost component. There is also ample evidence that poor system design can be a major cause of smelter down time, lost production and unforeseen high maintenance costs. The paper discusses these issues and offers guidance for improved design.

Jan 1, 1992

By T. J. A. Smith

This paper provides an overview of some of the key issues in design of smelter gas handling systems, with particular reference to sulphide smelting plants. In both primary smelting and converting. gas handling and treatment systems often represent the major capital cost component. There is also ample evidence that poor system design can be a major cause of smelter down time, lost production and unforeseen high maintenance costs. The paper discusses these issues and offers guidance for improved design.

Jan 1, 1992

By A. Martins, L. Goulart, E. Araujo, R. Batista, A. Costa e Silva

Steel cleanness is of great importance to the performance of almost all steel products. From very clean steel for bearings to long products used in civil construction, processing variables – in special those in steelmaking operations- must be properly balanced to achieve adequate cleanness for the desired performance. With the present complexity of steels as alloy systems, it is not efficient nor appropriate to develop these processes on empirical basis alone. Computational thermodynamics can greatly improve process development to achieve the desired cleanness level at reasonable costs. In this work, examples of these calculations and their applications to real steel processing are presented and discussed. The advantages, limitations and areas in which improvement in these calculations is desired are highlighted and discussed.

Jan 1, 2015

By D. I. Davidov, D. A. Shishkin, M. B. Rigmant, E. P. Romanov, N. N. Stepanova, N. V. Kazantseva

The Co-19 at.%Al-6 at.%W alloy was prepared by two methods of casting. We used arc melting under an argon atmosphere with casting into a copper water-cooled casting mold and induction melting furnace with casting into a ceramic Al2O3 mold. According to the X-ray and SEM analyses, phase compositions depend on the cooling rate of the ingot after melting. After arc melting, the cast alloy has a three-phase structure, consisting of  cobalt (FCC), intermetallic phases CoAl (B2) type, and Co3W (DO19) type. After the induction melting, the alloy has a three-phase structure, consisting of  cobalt (FCC), intermetallic phases CoAl (B2) type, and Co7W6 () type. All phases in the investigated ternary alloy at the room temperature are ferromagnetic. Curie temperatures of all obtained phases were defined. It is shown that the magnetic properties of the studied alloy are typical for soft magnetic materials.

Jan 1, 2015

By D. P. Cook, M. I. Bloch, J. A. Dantzig

"In this article, we describe a combined experimental and computational program to study the filling of automotive wheels during low pressure die casting. Experiments are performed by placing thermocouples into the mold walls of a production caster for the Ford F 113 wheel to measure the temperature profiles in the die during processing, and to infer the filling pattern. Computational models are also developed using a 36° section of the wheel pattern, taken directly from CAD data files. We use these models to simulate the filling and heat transfer processes. Comparison between experimental and computational results are presented, demonstrating the viability of this procedure.IntroductionAutomotive companies are using increasing amounts of aluminum in production vehicles: While the main driving force is improved fuel economy through weight reduction, replacing steel wheels by aluminum also offers the potential for improved vehicle performance by reducing unsprung mass. For these reasons, many new vehicles are now supplied with cast aluminum alloy wheels, and the aftermarket for these wheels continues to grow.The most common production process for these wheels is low pressure die casting. The process is subject to numerous defects, including microporosity, cold shuts, cold folds, misruns and inclusions. Scrap rates at the caster of the order of 10% are not uncommon. Many wheels also have large production runs, into the hundreds of thousands of wheels per year. Thus, the cost savings from even small reductions in scrap rate have the potential to be quite significant.Most of the defects are associated with the filling and solidification processes in the mold. The molds are air cooled, and the placement and sizing of cooling passages is currently as much art as science. The ultimate goal of this project is to improve that situation, by implementing simulation procedures that enable engineering design methods to be used in die and process specification."

Jan 1, 2000

By Toshiyuki Hashida, Victor M. Lopez-Hirata

"Small-punch tests and determination of fracture toughness JIC were conducted at 4 and 77 K on new cryogenic JN1, JJ1 and JK2 austenitic stainless steels, after isothermal aging. Equivalent fracture strain ?qf determined by measuring the reduction of thickness in the small-punch test specimen. A linear dependence of JIC on ?qf was found in these new materials. Regression analysis of experimental data produced the following linear relation JIC = 1304.1 ?qf + 8.09 [kJm-2]. An analysis of present work relation was pursued on the basis of material properties and evaluation method of he. Results showed that the slope value has a strong dependence on material yield strength and JIC evaluation method. This linear relation is useful for the evaluation of fracture toughness JIC, measuring the equivalent fracture strain ?qf by means of small-punch test. Thus it can be useful for assessing the degradation of fracture toughness in small areas such as, the heat-affected zone in welded components.IntroductionCryogenic structural materials for superconducting magnets of fusion nuclear reactor are required to possess a good combination of strength and toughness. The mechanical properties are required beyond the capability of conventional austenitic stainless steels [1]. New cryogenic JN1, JJ1 and JK2 austenitic stainless steels were developed by the Japan Atomic Energy Research Institute (JAERI) [1]. The structure of superconducting magnets is constructed by welding of 200 = thick plates of these steels, which are solution treated at high temperatures and then water-quenched to avoid intergranular precipitation. However, the welding process involves heating and cooling [2], which cause microstructural changes in both base metal and weld. In this heterogeneous microstructure, it is important to estimate the fracture toughness of these materials at cryogenic temperatures. Therefore, it is necessary to evaluate the effect of aging process on the fracture toughness behavior of these new steels. To determine the cryogenic fracture toughness, the elastic-plastic JIC value has been co=only used [2]; however, the specimen size is much larger than heat-affected zones in welded components. Small-punch (SP) testing method, employing miniature specimens, has permitted to evaluate the fracture toughness behavior at different temperatures in different nuclear reactor materials [3,4]. Mao et al. [5,6] and Misawa et al. [7] found a linear relation between JIC value and equivalent fracture strain ?qf, determined by SP method in non-ferrous alloys and ferritic steels at room temperature and austenitic stainless steels at 4 and 77 K, respectively. So that, this kind of correlation would be very useful to assess the fracture toughness JICe values by means of SP test in small zones of welded components."

Jan 1, 2012

By Shadia J. Ikhmayies

"Cadmium telluride (CdTe) is a very interesting material that has many applications. Thin films of p-type CdTe can be used as the absorber layer in the heterojunction CdS/CdTe thin film solar cells in which n-type cadmium sulfide (CdS) works as the window layer. A review of the photoluminescence (PL) spectra ofp-type CdTe thin films prepared by different techniques was performed. The presence of defects and impurities such as oxygen and chlorine influence the PL spectrum. Copper and other dopants change the PL spectra and enhance the defects band. Chemical-heat treatment especially with CdCh is known to improve the quality of CdTe thin films because it decreases the Cd vacancies and quenches deep traps, so it enhances the PL signal. A discussion of chemical-heat treatment especially with CdCh, the effect of the ambient atmosphere, and that of the measuring temperature is performed.IntroductionCadmium telluride (CdTe) is a II-VI compound semiconductor that has a cubic zincblende (sphalerite) structure with a lattice constant of 0 A4~11]. Other than all of II -VI semiconductors, CdTe can be made both n- and p-type. But due to self compensation it is not easy to get p-type CdTe films [2]. Polycrystalline CdTe thin films are interesting because they have a lot of applications. Most of the problems associated with the use of these films are attributed to inhomogeneity, self-compensation, and the difficulty of forming a stable and lowresistivity ohmic contact [3]. CdTe technology has been established for a large number of applications, including solar cells, optical and nuclear detectors, and thermal- and radiationimaging devices [3]. At present, the highest demonstrated conversion efficiency for a CdTe based heterojunction (ID), with CdS as a window layer, is 16.5% [4, 5]. CdTe thin films can be prepared by different experimental techniques, such as thermal evaporation [l], electrochemical deposition (ED) [3], close-spaced sublimation (CSS) [3, 4, 6], physical vapor deposition (PVD) [3], chemical molecular beam deposition (CMBD) [7], and close space vapor transport (CSVT) [8].The objective of this paper is to make a review of the photoluminescence (PL) spectra ofp-type CdTe thin films prepared by different techniques and discuss the factors that influence the PL spectra. The composition of the film is very interesting in determining its PL spectrum. Different kinds of defects, impurities and dopants have their finger prints in the PL spectrum. Deposition techniques and deposition parameters such as the deposition temperature and ambient atmosphere also have their influence. Heat and chemical treatments which are known to improve crystallization and reduce the defects change the PL spectrum."

Jan 1, 2013

By E Ferrow, R Herbert, M E. Malmstr, M Fuchs

The study of microbial sulfide oxidation and oxidation rates of tailings requires the use of sterile control samples in laboratory experiments for comparison purposes. The need for sterile tailings sand is also apparent in the study of microbial communities and processes. This study compares six different methods with regard to sterilisation efficiency and investigates chemical and mineralogical changes in the samples as the result of sample treatment. In addition, the effect of sterilisation on mineral weathering rates is also studied. The efficiency of the different methods with regard to sterility is estimated by most probable numbers (MPN) of both sulfur and iron oxidising bacteria. The sterilisation methods that were compared are: washing with sterile water, washing with ethanol, applying antibiotics, repeated heating to 70¦C, autoclaving, and γ-irradiation. There are several possible drawbacks with the different methods, including the risk of an applied chemical acting as a substrate for micro-organisms in the system, and the risk of altering the tailings. The results show a substantial difference in sterilisation efficiency between the treatments. For example, autoclaving, repeated heating, ethanol and irradiation efficiently kill micro-organisms, rendering an undetectable amount of bacteria after one month of incubation, whilst washing with water exhibits virtually no microbiological effect, with a bacterial content comparable to the control. The use of antibiotics for sterilisation ranks intermediate: the lag-phase was twice as long in the antibiotics treatment compared with the controls. X-ray diffraction, optical and electron microscopy, M÷ssbauer spectroscopy, and mineral magnetism indicate no significant change in the bulk mineralogical composition. However, X-ray photoelectron spectroscopy analyses show that with some of the treatments, sulfides are partially oxidised, as indicated by the formation of sulfate and partially û oxidised sulfur species at the tailings surfaces. Aerated batch weathering experiments performed on sterilised tailings samples and untreated controls indicated that while the initial rates of element (S, Fe, Cu, Zn, Mg, Na, K, Ca) release may differ between the samples, over the course of ~100 days of experiment at pH 2 and room temperature, the rates declined toward a similar value for all samples. To conclude, there does not appear to be one perfect method for tailings sterilisation. Autoclaving and heating damage the mineral grain structure and oxidise the sulfide surfaces. Ethanol, antibiotics and rinsing greatly alter the pore water chemistry through the washing procedure. In addition, ethanol and denatured antibiotics might serve as a substrate and also, in the case of antibiotics, adhere to mineral surfaces thus obstructing chemical reactions. Irradiation seems to be the preferable method on an overall basis, although the formation of surface Fe3+ was suggested by M÷ssbauer spectroscopy.

Jan 1, 2003

By J. H. Viljoen, J. F. Morrison, C. H. Wyndham

SYNOPSIS Heart rates, oral temperatures, shovels/min and number of 3/4 ton cars/hour trammed over distances of up to 350 ft were measured in samples of 6-10 miners, engaged in tram-shovelling, at 76°, 84°, 86°, and 89°F wet bulb temperatures in stopes in a mine. From the results it has been concluded that a man with an 'average' maximum oxygen intake capacity of about 2. 8 litres/min should be able to work: at 6 shovels/min, or 30 cars/shift per two men, at 76°-84°F; at 5 shovels/min, or 27 cars/shift per two men, at 86°F; and at 4 shovels/min, or 24 cars/shift per two men, at 89°F wet bulb air temperatures. INTRODUCTION A number of gold mines in South Africa still use tram-shovelling extensively. In this method of rock removal from the face of the stope, Bantu mine workers load rock into cars and tram the cars to a centre gulley where they are emptied. Previous studies from this Laboratory3 have shown that tram-shovelling is one of the most arduous tasks underground. The rate of energy expenditure is relatively high, being an oxygen consumption of about 1.4 litres/min over a period of some hours. In cool air conditions the upper limit to the rate of production of the well-motivated men employed on tram-shovelling has been shown1 to depend upon their capacities for physical work of an endurance nature (as measured by their maximum oxygen intakes). However, in hot conditions the factors which set the upper limit to the rate of production are different. They are primarily the ability of the body to maintain a heat balance between the rate of heat production, due to physical work, and the hot atmosphere, so that the men do not develop excessively high body temperatures8. In order to give mine managers guidance on the 'optimum' rate of production of Bantu mine workers engaged upon tram-shovelling under different temperature conditions underground a study was carried out in a mine. The number of shovels per minute and cars per hour were recorded and heart rates and oral temperatures were measured throughout the duration of the shift on samples of 6-10 Bantu mine workers in different air conditions. The results of the study are recorded in this paper and conclusions are drawn as to the number of shovels per minute and cars per hour which Bantu mine workers of 'average' maximum oxygen intake capacity should be able to produce at wet bulb air temperatures of between 76° and 89°F without either excessive fatigue or danger of heat illness.